G q CHEMISTRY

1. ATOMIC q
STRUCTURE G
EXERCISE 3) As temperature increases the wavelength
corresponding to maximum intensity increases
1. Which of the following is incorrect statement.
4) At very large wavelength intensity is less.
1) Protons are obtained when discharge tube is
filled with Hydrogen gas. 6. The wave length of certain radiation is
2) Helium usually gives line spectrum 6625 A0. Then the number of Quantas present
3) The ratio of wave numbers of two radiations in one J of energy of that radiation is
is 1 : 2, then the ratio of their velocities is 1:1 1) 3.3 × 10–19 2) 3.3 × 1018
4) Black body radiation will give discontinuos 3) 6 × 1010 4) 3.3 × 1020
spectrum
7. A light of wavelength M strikes a metal surface
2. The value of charge on the oil droplets
and ejects photoelectrons, with KE = 1eV.
experimentally, observed are –1.6 × 10–19 and
–4.8 × 10 –19 coulomb. The value of the
M
Another light of wavelength strikes the same
electronic charge, indicated by these results is: 3
metal surface and ejects photoelectrons, with
1) –1.6 × 10–19 2) –2.4 × 10–19
KE = 4eV. The work function is
3) –4 × 10–19 4) –0.8 × 10–19
1) 1 eV 2) 2 eV 3) 0.5 eV 4) 3 eV
3. The electronic configuration of a dipositive ion
M2+ is 2, 8, 14 and its mass number is 56. The 8. Which of the graphs shown below does not
number of neutrons present is represent the relationship between incident light
1) 32 2) 42 3) 30 4) 34 and the electron ejected form metal surface ?
4. Some statements are given below. The correct
Number
statements are of e’s
A)Planck’s quantum theory can explain
photoelectric effect. 1)
B) Photoelectric effect explain wave nature of
0 Frequency of light
light.
C) Photoelectric effect explain particle nature of
light.
K.E. of
D)According to planck’s quantum theory e’s
radiations propagate as wave.
1) All are correct 2)
2) Only A, C and D are correct 0 Intensity of light
3) Only C and D are correct
4) B, C and D are correct
5. Incorrect statement among the following K.E. of
e’s
regarding the following graph.
3)
T3
0
Intensity Frequency of light
T2
K.E. of
T1 e’s
M
1) As wavelength increases intensity first 4)
increases and then decreases
2) T3 > T2 > T1 0 Energy of light

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 q CHEMISTRY q
9. Light of wavelength M shines on a metal surface 15. The ground state energy of hydrogen atom is
with intensity x and the metal emits y electrons –13.6 eV. The energy of second excited state
per second of average energy, z. What will He+ ion in eV is :
happen to yand z if x is doubled ? 1) –6.04 2) –27.2
1) y will be doubled and z will become half 3) –54.4 4) –3.4
2) y will remain same and z will be doubled
16. Which among the following is incorrect
3) both y and z will be doubled
combination?
4) y will be doubled but z will remain same
1) The radii ratio of first orbits of H, He+ and
10. Which among the following incorrect statement? Li2+ is 6 : 3 : 2
1) Bohr’s atomic model is against to Heisenberg
2) The ratio of energies of first orbits of H, He+,
uncertainity principle
Li+2, Be+3 is 1 : 4 : 9 : 16
2) The ratio of energy to frequency of electro-
3) Order of emission of energies: 2 to 1 > 10
magnetic radiation is called Planck’s constant
to 2
3) The ionization energy of hydrogen atom in
terms of Rydberg constant (RH) is given by 4) wave length of infinity line in lyman series
the expression: RHhc of Hydrogen spectrum is ‘R’
4) Bhor’s theory explains Zeeman and stark 17. The ratio of the wavelengths of the first line in
effect the Lyman series of the spectrum of hydrogen
11. The orbital angular momentum and orbit angular and first line in the Balmer series of the spectrum
momentum (classical, analogue) for the electron of He+ is
of 4p - orbital are respectively, equal to 1) 20/27 2) 27/20 3) 27/5 4) 20/21
h h 2h
1) 12 and 2) zero and 18. The velocity of electron in the first orbit of
2Q 2Q Q
Hydrogens is 2x cm/sec velocity of electron in
h 2h h 2h the third orbit is ____ (in cm/sec)
3) 6 and 4) 2 and
2Q Q 2Q Q
x 2x
12. When Z is doubled in an atom, which of the 1) 2) 3) x 4) 3x
3 3
following statements are consistent with Bohr’s
19. Find the value of wave number (v) in terms of
theory ?
Rydberg’s constant, when transition of electron
1) Energy of a state is doubled takes place between two levels of He+ ion whose
2) Radius of an orbit is doubled sum is 4 and difference is 2
3) Velocity of electron in an orbit is doubled 8R 32R 3R
4) Energy of a state is halved 1) 2) 3) 4) 3R
9 9 4
13. The difference in angular momentum associated 20. If the shortest wavelength in Lyman series of
with the electron in two successive orbits of hydrogen atom is A, then the longest wavelength
hydrogen atom is in Paschen series of He+ is:
h h 5A 9A 36A 36A
1) 2) 3) zero 4) 1 1) 2) 3) 4)
2Q Q 9 5 5 7
14. An electron in H atom jumps from the third 21. Hydrogen like ion has the wavelength difference
energy level to the first energy level. The change between the first lines of Balmer and Lymen
in the potential energy of the electron is series equal to 33.4 nm. The atomic number of
1) 12.09 eV 2) 6.04 eV that ion equal to
3) 24.18 eV 4) 32.1 eV 1) 4 2) 3 3) 2 4) 6

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 q CHEMISTRY q
22. For emission line of atomic hydrogen from 29. In a certain transition in H spectrum from 5th
ni = 8 to nf = n the plot of wave number ( H ) orbit to ground state, incorrect statement is:
¥ 1 ´ 1) 10 lines are formed, if transition takes place
against ¦§ 2 µ¶ will be (The Ry dberg constant,
n in multiple steps
RH is in wave number unit). 2) 3 lines are formed in Balmer series, if
1) Linear with slope – RH transition takes place in multiple steps
2) Linear with intercept – RH 3) 4 lines are formed, if sample contains one
3) Non linear hydrogen atom only with in multiple
4) Linear with slope RH transitions
23. Heat treatment of muscular pain involves radia- 4) 5 to 1 transition has maximum wavalength
tion of wavelength of about 900 nm. Which among all possible transitions
spectral line of H-atom is suitable for this 30. The velocity of an e– in exited state of H-atom
purpose ? [RH = 1×105 cm–1, h = 6.6×10–34 Js, is 0.5465 × 10 6 m/sec. What is the circum-
c = 3 × 108 ms–1]
1) Paschen, 5 3m 2) Paschen, d m 3
ference of orbit?
1) 3.32 × 10–10 m 2) 3.32 × 10–8 m
3) Lyman, d m 1 4) Balmer, d m 2
3) 53.2 × 10–10 m 4) 53.15 × 10–8 m
24. Wavelength of high energy transition of H - atom
is 91.2 nm. The corresponding wave-length of 31. The radius of hydrogen atom in its ground state
He+ ion is is 5.3 × 10–11 m. After collision with an electron
1) 91.2 nm 2) 22.8 nm it is found to have a radius of 21.2 × 10–11 m.
The principal quantum number of the final state
3) 45.6 nm 4) Cannot be pridected
of the atom is
25. The radius of which of the following orbit is 1) 2 2) 3 3) 4 4) 5
same as that of the first Bohr’s orbit of hydrogen
atom 32. If the wavelength of the electron is numerically
1) He+ (n = 2) 2) Li2+ (n = 2) equal to the distance travelled by it in one
3) Li2+ (n = 3) 4) Be3+ (n = 2) second then
h h h h
26. The frequency corresponding to n = 2 to n = 1 1) M  2) M  3) M  4) M 
2 m p m
p
transition of hydrogen atom O1 . Then freque-
ncy corresponding to n = 4 to n = 2 of the same 33. The wavelength of a moving body of mass
atom is O 2 . Then O1 and O 2 are related as 0.1 mg is 3.319 s 10 20 m . Its kinetic energy is
1) O1 = O 2 2) 4 O1 = O 2 1) 2 s 10 21 J 2) 2 s 10 7 J
7
3) O1 = 4 O2 4) None 3) 1 s 10 7 J 4) 5 s 10 J
27. What transition of Li2+ can emit a photon with 34. If the de Broglie wavelength of a particle of
same wave number as n = 2 to n = 1 transition mass m is 100 times its velocity then its
of hydrogen atom wavelength value in terms of its mass(m) and
1) n = 6 to n = 4 2) n = 6 to n = 3 planck’s constant (h) is:
3) n = 4 to n = 2 4) n = 5 to n = 2
1 h h h 10m
28. How many spectral lines are formed in the 1) 2) 10 3) 4)
10 m m m h
hydrogen spectrum when electrons in 6th orbit
in a sample of hydrogen get de excited in all 35. What is the de-Broglie wavelength associated
possible ways in 1st case and in 2nd case no lines with He atom at room temperature 250C.
in paschen series are observed? 1) 6.34 × 10–11 m 2) 6.34 × 10–8 m
1)15, 10 2) 15, 9 3) 14, 10 4) 12, 10 3) 7.34 × 10–11 m 4) 7.34 × 10–8 m

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 q CHEMISTRY q
36. What possibly can be the ratio of the de Broglie 43. The uncertainities in the velocites of two
wavelengths for two electrons each having zero particles A and B are 0.05 and 0.02 m/sec
initial energy and accelerated through 50 volts respectively. The mass of A is 5 times to that of
and 200 volts ? mass of B. What is the ratio of uncertainties in
their positions ?
1) 3 : 10 2) 10 : 3 3) 1 : 2 4) 2 : 1
25 2
37. The speed of a photon is one - hundredth of the 1) 2) 3) 22 4) 1
2 25
speed of light in vacuum. What is the de Broglie
wavelength ? Assume that one mole of protons 44. Uncertainty in the position of an electron
has a mass equal to one gram. h = 6.626 × 10–27 (mass = 9.1 × 10–31 kg) moving with a velocity
erg sec 300 m/sec accurate upto 0.001% will be (h =
o o 6.6 × 10–34 JS)
1) 3.31 × 10–3 A 2) 1.33 × 10–3 A
o o
1) 19.2 × 10–2 m 2) 5.76 × 10–2 m
3) 3.13 × 10–2 A 4) 1.31 × 10–2 A –2
3) 1.92 × 10 m 4) 3.84 × 10–2 m
38. If the de Broglie wavelength of the electron in 45. Assume that you are travelling at a speed of
nth Bohr orbit in a hydrogenic atom is equal to 90 km / h in a small car with a mass of 1050kg.
1.5 Q a0 (a0 is Bohr radius), then the value of If the uncertainty in the velocity of the car is
n/z is: 1% (%v  0.9 km / h) , what is the uncertainty (in
1) 1.0 2) 0.75 meters) in the position of the car?
3) 0.40 4) 1.50 1) %x r 10 35 m 2) %x r 2 s 10 37 m
36
3) %x r 2 s 10 m 4) %x r 4 s 10 38 m
39. If radius of Bohr’s first orbit is x. Then de
Broglie wave length of electron and the 46. Which one is the wrong statement?
h
circumterence of the 3rd orbit of hydrogen atom 1) The uncertainty principle is %E s %t r
4Q
will be 2) Half filled and fully filled orbitals hae greater
1) 3Q x, 9 Q x 2) 6 Q x, 18 Q x stability due to greater exchange energy,
3) 9Q x, 9 Q x 4) 12 Q x, 9Q x greater symmetry and more balanced
arrangement.
40. The number of waves produced by a Bohr’s
3) The energy of 2s-orbital is less than the
electron in an orbit of maximum magnetic
energy of 2p-orbital in case of hydrogen like
quantum number as +2 in one revolution is
atoms.
1) 2 2) 3 3) 4 4) 5 h
4) deBroglie’s wavelength is given by M  ,
41. Which among the following is incorrect mv
where m = mass of the particle, v = group
expression of Heisenberg’s uncertainty velocity of the particle.
principle?
47. The uncertainity in position for an electron is
h h
1) %x s %P r 2) %t s %E r M
4Q 4Q where M is the deBroglie wavelength. The
4Q
%x s %V r
hm M2 uncertainity in velocity will be
3) 4) %x s %M r
4Q 4Q V V
1) 2) V 3) 3V 4)
42. Uncertainity in the position of an electron and 2 4
deutron is equal, the ratio of their uncertainities 48. Which among the following is correct set of
in velocity is quantum numbers?
1) 1 : 1 2) 1 : 1836 1) 2, 3, –1, 1/2 2) 4, 2, –3, +1/2
3) 3672 : 1 4) 1 : 3672 3) 3, 2, –1, 0 4) 3, 1, 0, +1/2

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 q CHEMISTRY q
49. Which one represents an impossible arrangment 55. The magnetic momentum of Mnx+ is 5.8 B.M.
1) 2, 1, ±1, ±1/2 2) 3, 2, ±1, ±1/2 The value of ‘x’ is
3) 4, 2, +3, +1/2 4) 4, 2, 0, ±1/2 1) 2 2) 4 3) 5 4) 3
50. Among the following the correct statements are 56. In an atom with 2K, 8L, 11M and 2N electrons
1
a) For a given principle quantum number the the number of electrons with m = 0; s  are
total number of ‘m’ values are n2 2
1) 2 2) 7 3) 8 4) 16
b) For a given principal quantum number the
total number of ‘l’ values are (n – 1) 57. Which of the following statement concerning
c) For a given azimuthal quantum number the probability density ( Z 2 ) and radial distribution
total number of m values are 4l + 2 function (4 Qr 2 drZ 2 ) for a p-orbital of H-like
d) For a given magnetic quantum number the species is correct ?
1) Z is minimum at nucleus but (4 Qr 2 drZ 2 ) is
2
total number of electrons are 2n2
1) all are correct maximum at nucleus
2) only a and b are correct 2) Z 2 is maximum at nucleus but (4 Qr 2 drZ 2 ) is
minimum
3) only a is correct
3) Both Z and (4 Qr 2 drZ 2 ) are maximum at
2
4) only a and c are correct
nucleus
51. How many electrons in an atom with atomic 4) Both Z and (4 Qr 2 drZ 2 ) are minimum at
2

number 105 can have (n+1) = 8 nucleus

1) 30 2) 17 3) 16 4) 15
58. Which among the following is correct wrt
52. Which among the following is incorrect energy of 2s orbital in H, Li, Na and K is:
sttaement? 1) E2s(H) > E2s(Li) > E2s(Na) > E2s(K)
1) The total number of orbitals that are possible 2) E2s(H) = E2s(Li) = E2s(Na) = E2s(K)
with (n + l) value equal to 6 are ‘9’
3) E2s(H) < E2s(Li) < E2s(Na) < E2s(K)
2) Wave function of electrons in atoms and
4) E2s(H) < E2s(Li) > E2s(Na) = E2s(K)
molecules are called orbitals
3) The maximum number of electrons that can 59. Which among the following is incorrect
be accommodated in orbitals with quantum statement?
numbers n = 3, l = 1 and m = +1 are ‘2’ 1) Ø3,1,0 represents 3p- orbital
4) Spin quantum number can be derived from 2) Energy and angular momentum are quantised
Schroedinger wave equation in Bohr’s atomic model
3) The energy of electron in the ground state
53. The orbit angular momentum and orbital angular hydrogen atom interms of R H is given as
3h 3 h –RH. h.c
momentum for electron are and .
2Q 2 Q 4) Order of e/m values : neutron > alpha >
Then the number of radial nodes and angular proton > electron
nodes for that atomic orbital will be 60. The quantum numbers of four electrons e1 to e4
1) 1, 1 2) 0, 1 3) 0, 2 4) 2, 0 are given below.
54. In a multi electron atom, which of the following n l m s n l m s
orbitals will have the same energy in the absence e1 3 0 0 –1/2 e2 4 0 0 –1/2
of electric and magnetic fields e3 3 2 2 –1/2 e4 3 1 –1 –1
A) n = 1, l = 0, m = 0; B) n =2, l = 0, m = 0; The correct order of decreasing energy of these
C) n = 2, l = 1, m = 1; electrons is
D) n = 3, l = 2, m = 1 and E) n = 3, l = 2, m = 0 1) e4 > e3 > e2 > e1 2) e2 > e3 > e4 > e1
1) A, B 2) B, C 3) C, D 4) D, E 3) e3 > e2 > e4 > e1 4) e1 > e4 > e2 > e3

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 q CHEMISTRY q
61. Which of the following statements is incorrect? 66. In which of the following Aufbau principle is
1) In hydrogen atom, shapes of 2s and 2p violated?
orbitals are different but energy is same.
2) In hydrogen atom, order of energies of 1) ln ln l l
orbitals: 1s < 2s = 2p < 3s = 3p = 3d 2S 2P
3) ‘+’ and ‘–’ sign of the lobes of p y orbital
represents geometric sign of wave functions 2) l ln l l
4) Energy of E2s(H) = E2s(Li) = E2s(Na) 2S 2P
62. Which of the following pairs of d-orbitals will
have electron density along the axes? 3) ln l l l
1) d z2 ,d xz 2) dxz, dyz 2S 2P
3) d z2 ,d x2 y2 4) d xy ,d x2 y2
4) ln ln ln l
63. The number of d-electrons in Fe2+ (Z = 26) is 2S 2P
not equal to the number of electrons in which
one of the following? ANSWERS
1) d-electrons in Fe (Z = 26)
2) p-electrons in Ne (Z = 10) 1) 4 2) 1 3) 3 4) 3 5) 3
3) s-electrons in Mg (Z = 12) 6) 2 7) 3 8) 3 9) 4 10) 4
4) p-electrons in Cl (Z = 17)
11) 4 12) 3 13) 1 14) 3 15) 1
64. The 71st electron of an element X with an atomic
number of 71 enters into the orbital: 16) 4 17) 1 18) 2 19) 2 20) 4
1) 4f 2) 6p 3) 6s 4) 5d 21) 1 22) 4 23) 2 24) 2 25) 4
65. Which of the following statements is not correct? 26) 3 27) 2 28) 1 29) 4 30) 3
1) Special stability of half-filled and fully-filled
atomic configurations amongst s- and 31) 1 32) 4 33) 1 34) 2 35) 3
p- block elements is reflected in ionization 36) 4 37) 2 38) 2 39) 2 40) 2
potential trends along a period
2) Special stability of half-filled and fully-filled 41) 3 42) 3 43) 2 44) 3 45) 2
atomic configurations amongst s- and
46) 3 47) 2 48) 4 49) 3 50) 3
p- block elements is reflected in electron
affinity trends along a period 51) 2 52) 4 53) 3 54) 4 55) 1
3) Aufbau order is not obeyed in cases where
56) 2 57) 4 58) 1 59) 4 60) 3
energy difference between ns and (n–1)d
subshell is large 61) 4 62) 3 63) 4 64) 1 65) 3
4) Special stability of half - filled subshell is
66) 2
attributed to higher exchange energy of
stabilization

TTT

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