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  • Haloalkene and Haloarenes Reaction

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    Sjk Sabbir
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    1) n-Butyl bromide reacts with potassium cyanide to form n-butyronitrile and potassium bromide. The cyanide ion acts as a nucleophile, attacking the primary carbon of n-butyl bromide. 2) The C-C bond is stronger than the C-N bond, resulting in cleavage of the C-N bond and formation of n-butyronitrile and potassium bromide as products. 3) This reaction demonstrates a nucleophilic substitution reaction mechanism where the cyanide ion acts as the nucleophile.

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    1) n-Butyl bromide reacts with potassium cyanide to form n-butyronitrile and potassium bromide. The cyanide ion acts as a nucleophile, attacking the primary carbon of n-butyl bromide. 2) The C-C bond is stronger than the C-N bond, resulting in cleavage of the C-N bond and formation of n-butyronitrile and potassium bromide as products. 3) This reaction demonstrates a nucleophilic substitution reaction mechanism where the cyanide ion acts as the nucleophile.

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    © All Rights Reserved
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    6 views5 pages

    Haloalkene and Haloarenes Reaction

    Uploaded by

    Sjk Sabbir
    1) n-Butyl bromide reacts with potassium cyanide to form n-butyronitrile and potassium bromide. The cyanide ion acts as a nucleophile, attacking the primary carbon of n-butyl bromide. 2) The C-C bond is stronger than the C-N bond, resulting in cleavage of the C-N bond and formation of n-butyronitrile and potassium bromide as products. 3) This reaction demonstrates a nucleophilic substitution reaction mechanism where the cyanide ion acts as the nucleophile.

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    © All Rights Reserved
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    of 5

    Halolkaues Haloae nes' CHeMCAL ReACTIoN

    what happens eshen + KCN =?


    Thy clsude
    3) Emy chloile treated
    aq koH 2 14) 2-bomo pemtae
    Ieated ith.
    JtHeatod
    Ceuth alc
    CHCoce uu pPesemeQ anly Atel, CHy-OH
    15)
    5)
    Methyt choide deated Pls
    6) Bremobemgeme dtreatRd H,- H = H
    presemce

    ehydohaloqemtisn xeaction.
    8) Cuoobengene 9) Majss pioduct
    eaction.
    Soduum efoide
    CH-CHg kUty cicde
    br,/n,
    NO,

    18) 2CH3 Na friedel


    emes
    20) tO hepase -
    om
    dbdobutane
    - chlosobutane.
    )
    Ct, CH-B AqCN

    C
    13)
    2) unkelsten

    Ra) Comuest
    )
    Eyt chloride dHeated uath Chsobengene
    hopeme to
    to Bphemgl
    AqNo, ? () 2bonobutaue uodo propoane
    to but-2ene
    Oot

    3)13 i)
    Aialne
    NH,
    to Boomo bemgene
    B.
    NaNO, t CuBr)
    dil HCe
    HBr
    (3 DC) Brerno
    bengere
    )
    calObeneme to 2- uoso
    aceto phemene
    (üi) coehane to batame

    a) Mechanism
    n - BuBr + KCN
    n-BucN
    CATE

    + Aususes
    K'-CN CHa CN + KBI
    Nucdeophlic
    CN h
    Seeleshtute By NO NO,
    3) KOH
    (q) Na

    Sn2Ah

    +
    2-cWig0 acetophenona
    (mina

    s-ehloo acotophenone mano


    (maip
    B Agce
    B +AqCl.
    |+ CH@ auhy
    4
    Al 14)
    (-bsomo
    R-mehyt
    Beuzene (-bemo
    Br Beugene Br
    ae Koh
    alc
    CH;-CH-CHg KOH CH, -CH =(H
    a-bomopopane Brop--ee
    NO
    + i3)
    Ceuc HSoy

    NO,
    Shoon us
    CH,-HsC

    Esnkelstein
    CH,- CH,-C4y -CH,-Ce
    uly
    AHC tAetone
    CHg-cH, -CH,-CH2-I

    majas
    J8) ehes

    t Na0GHs
    biphenye
    2Nac!

    CH,CH= CH lersde
    + 2NaC.
    attat Acekona
    auty
    ale Koy
    1

    -CH=CH-lg
    22)

    + CHy-C-ca cuy auly


    AC,
    Reagemt KCN
    CN mucler piue

    [:N]

    K CN + CH, CH, CH, CH,81

    CH, CH, CH,-CN 4 KBr

    CN- cumlidemt nucleohile.


    attack trough C o N atom

    C-C sKenqes tham C-N

    ttace
    Heluga Ctoc

    Powered oyTieiarlert

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