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Marine and Petroleum Geology 145 (2022) 105883

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Marine and Petroleum Geology


journal homepage: www.elsevier.com/locate/marpetgeo

Diagenesis of continental tight sandstone and its control on reservoir


quality: A case study of the Quan 3 member of the cretaceous Quantou
Formation, Fuxin uplift, Songliao Basin
Qin Zhang a, b, **, Xin-Song Wu a, b, Ahmed E. Radwan c, *, Bo-Han Wang d, Kai Wang a,
Han-Yun Tian a, Shuai Yin e
a
College of Geosciences, China University of Petroleum (Beijing), Beijing, 102249, China
b
State Key Laboratory of Petroleum Resources and Prospecting, China University of Petroleum (Beijing), Beijing, 102249, China
c
Faculty of Geography and Geology, Institute of Geological Sciences, Jagiellonian University, Gronostajowa 3a, 30-387, Krakow, Poland
d
Sinopec Chongqing Fuling Shale Gas Exploration and Development Co.,Ltd., Chongqing, 408105, China
e
Xi’an Shiyou University, School of Earth Science and Engineering, Xi’an, 710065, China

A R T I C L E I N F O A B S T R A C T

Keywords: Research on the diagenesis of continental sandstone reservoirs can provide scientific guidance for the prediction
Songliao Basin of reservoir sweet spots. The low permeable-interbedded thin and thick sandstone reservoirs of the Cretaceous
Fuxin Uplift Quantou Formation’s Quan 3 Member in the Fuxin Uplift, Songliao Basin, were used as an example in this work
Cretaceous
to investigate the diagenesis of continental tight sandstone and its influence on reservoir quality. A large number
Continental tight sandstone reservoirs
Diagenesis
of thin section, scanning electron microscopy, granularity, X-ray diffraction, and petrophysical property mea­
Petrophysical properties surements were used to study the petrological characteristics and diagenesis. The reservoir space evolution mode
Pore evolution of continental sandstones in this area was constructed by combining diagenesis sequences and the evolution of
Reservoir quality petrophysical properties of the Quan 3 Member. The results show that the compositional maturity of the
sandstone reservoirs of the Quan 3 Member is relatively low and their lithologies are mainly lithic feldspar
sandstone and feldspar lithic sandstone, followed by lithic arkose sandstone, feldspathic litharenite and a small
amount of lithic sandstone. The average particle size of the target sandstones is 0.11 mm, and the fine sandstone
to coarse siltstone are favorable reservoirs. The studied sandstone reservoirs have undergone intense diagenetic
transformations, including compaction (pressure solution), cementation, dissolution, and metasomatism.
Moreover, the complex diagenetic environment changes in the Quan 3 Member include early alkaline-acid­
ic→mid-alkaline→late acidic. The shallow sandstones are in the meso-diagenetic A1 stage; when the burial depth
exceeds 800 m, they enter the meso-diagenetic A2 stage; and when the burial depth exceeds 1600 m, they enter
the meso-diagenetic B stage. It was found that diagenesis has significant control over the quality of continental
sandstone reservoirs. Compaction is the primary factor controlling the quality of the target reservoir. It controls
the differences in the petrophysical properties of the reservoirs in the eastern and western regions; that is, the
physical properties of the Quan 3 Member in the east are higher than those in the west. Cementation and
dissolution are secondary controlling factors of reservoir quality that control the differences in reservoir pet­
rophysical properties in the northern and southern regions; that is, the physical properties of the Quan 3 Member
in the north are better than those in the south. The most favorable reservoirs of the Quan 3 Member are
developed in the Fuyu Oilfield, which is distributed in the southeast region and develops fine sandstones of
branch channels and meandering river point sand bars of delta plains that suffer the least compaction and the
strongest dissolution. This study may provide crucial clues for predicting the sweet spot reservoirs of the Quan 3
Member in the study area. Furthermore, the study provides a reference for the different diagenesis controls on
the pore space evolution of continental tight sandstone reservoirs.

* Corresponding author. Faculty of Geography and Geology, Institute of Geological Sciences, Jagiellonian University, Gronostajowa 3a, 30-387, Krakow, Poland.
** Corresponding author. College of Geosciences, China University of Petroleum (Beijing), Beijing, 102249, China.
E-mail addresses: zhangqin@cup.edu.cn (Q. Zhang), radwanae@yahoo.com, ahmed.radwan@uj.edu.pl (A.E. Radwan).

https://doi.org/10.1016/j.marpetgeo.2022.105883
Received 6 July 2022; Received in revised form 11 August 2022; Accepted 18 August 2022
Available online 24 August 2022
0264-8172/© 2022 Elsevier Ltd. All rights reserved.
Q. Zhang et al. Marine and Petroleum Geology 145 (2022) 105883

1. Introduction (Bello et al., 2021; Li et al., 2020; Liu et al., 2019; Wang et al., 2019).
The diagenetic stages of reservoirs are usually divided into three stages:
Reservoir geology hotspot research areas include reservoir hetero­ early diagenesis, meso-diagenesis, and late diagenesis (Santosh and
geneity, reservoir densification mechanism, genesis of secondary pores, Feng., 2020; Xi et al., 2019). Diagenesis is closely related to the diage­
quantitative evaluation of diagenesis intensity, and classification of netic environment, fluids, facies, and sequence stratigraphy (Hijaz et al.,
reservoir sweet spots (Haile et al., 2018; Liu et al., 2020a; Lv and Li, 2020; Khan et al., 2020; Mahmi et al., 2018; Su et al., 2022; Xi et al.,
2021; Ma et al., 2019; Qiao et al., 2019; Yang et al., 2013; Cui and 2019; Xiao et al., 2019). With the development of reservoir geology
Radwan, 2022; Zhang et al., 2022). With the continuous development of theory, diagenesis is not only limited to petrology and mineralogy, but
new research and testing methods in reservoir geology, it has become has developed into multiple disciplines such as sedimentology, petro­
possible to quantitatively characterize the diagenetic evolution paths of leum geology, petrophysics, and mineral deposit sciences (Liu et al.,
reservoirs from various perspectives (Gao, 2021; Hong et al., 2020; Jabir 2020c; Radwan, 2021a; Radwan et al., 2021a,b; Nabawy et al., 2022;
et al., 2021; Li et al., 2005; Wang et al., 2020). In recent years, great Boutaleb et al., 2022; Kassem et al., 2021; Wang et al., 2019; Zhang
progress has been made in the field of reservoir diagenesis (Lai et al., et al., 2020; Abdel-Fattah et al., 2022).
2018b; Radwan, 2022). Field practices in different oilfields and the The study area is located in the Fuxin Uplift Belt in the south part of
introduction of some new concepts (such as tectonic diagenesis, diage­ the Songliao Basin (Fig. 1a). The Cretaceous Quantou Formation in this
netic facies etc) have greatly promoted the development of sedimentary area had developed interbedded thin and thick sandstone reservoirs
diagenesis (Santosh and Feng, 2020; Wang et al., 2019; Yin and Wu., with low permeability. At present, there are few studies on the diagen­
2020; Zhao et al., 2021). In addition, the combined application of esis of continental sandstone reservoirs in the Quan 3 Member in this
experimental techniques, such as cathodoluminescence, trace element area, which restricts the efficient prediction of reservoir sweet spots
testing, X-ray diffraction, and isotopic analysis, provides new data (Mei et al., 2019; Tang et al., 2009; W. Wang et al., 2016; Zang et al.,
support for the fine and quantitative characterization of reservoir 2020; Zhao, 2015; Zhu et al., 2020). In this paper, taking the Quan 3
diagenesis (Dong et al., 2020; Mirzaei-Paiaman and Ghanbarian, 2021; Member of the Cretaceous Quantou Formation in the Fuxin Uplift as an
Wei et al., 2021; Zhao et al., 2021). example, the petrological characteristics, diagenesis and their influence
Internal structures and mineral distribution characteristics of sedi­ on the quality of the reservoir have been systematically studied based on
ments tend to change under the action of temperature, pressure, and a large number of thin sections, scanning electron microscopy, granu­
water-rock fluids to reach an equilibrium state (Mahmud et al., 2020). larity, X-ray diffraction and petrophysical property tests. The study also
This regular evolution sequence is called the “diagenesis hierarchy” highlights the relationship between the diagenetic sequences and the

Fig. 1. Location and stratigraphic synthesis histogram of the study area. Notes: (a) The study area is located in the Fuxin Uplift in the southern Songliao Basin, China;
(b) Stratigraphic units and sedimentary cycles of the Cretaceous in the study area (After Mei et al., 2020, modified).

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porosity evolution of sandstone reservoirs in different diagenesis stages (total 399 groups). Ordinary and cast thin sections were completed with
of the Quan 3 Member. Moreover, the relationship between petrophys­ a Nikon Eclipse LV100N POL polarizing microscope. Scanning electron
ical properties and burial depth was investigated. Finally, the favorable microscopy was performed with an FEI Quanta 200F field emission
reservoirs are predicted, which will provide the scientific basis for the environmental scanning electron microscope. The equipment is equip­
further exploration deployment in the study area and other oil fields ped with an energy dispersive spectrometer (EDS) with an accelerating
with similar reservoirs. voltage of 20 kV, a working distance of 15 mm, a probe current of 200
nA, and a beam spot diameter of 1 μm.
2. Geological background The laser particle size analyzer Mastersize 3000 was selected for
particle size testing. The light source of the laser diffraction technique
The Fuxin Uplift Belt is a secondary structural unit located in the was a helium-neon laser. A laser beam was irradiated onto a sample of
southern Songliao Basin (Fig. 1a) (Mei et al., 2020; Tang et al., 2009; dispersed particles, and a detector measured the scattered light intensity
Zhao, 2015). The study area is located in the northern part of the Fuxin of the particles at a rate of 10,000 standard scans per second. The
Uplift Belt, which covers the Xinbei, Xinmiao, Xinmin, Xinli, Mutou, and Mastersize3000 software was used to calculate the particle size distri­
Fuyu Oil Fields (Li et al., 2013; Sun et al., 2013; Zhang et al., 2014), with bution, which was measured in the range of 0.01 μm–35,000 μm.
an area of about 1900 km2 (Fig. 1a). The terrain in this area is relatively The petrophysical parameter tests were completed with a PoroPDP-
flat, and the altitude of the surface is between 135 m and 150 m. 200 Overburden Porosity Permeability Tester. Among them, the pres­
The Fuxin Uplift Belt is a long-term paleo-uplift developed on the sure pulse decay method (unsteady-state method) was used to measure
basement. From bottom to top, the strata in the Fuxin Uplift Zone the permeability of the samples. The porosity was measured by the he­
include the Denglouku, Quantou, Qingshankou, Yaojia, and Nenjiang lium expansion principle and calculated using Boyle’s law. The working
formations (Mei et al., 2020). Hydrocarbons are mainly located in the medium of the petrophysical property tests was nitrogen and helium.
Quan 4 and Quan 3 members of the Cretaceous Quentou Formation The pressure sensor accuracy is 0.1%, and the power supply is 220 V/50
(Fig. 1b). Hz.
In 1959, the Jilin Oilfield produced industrial oil and gas flows in the The experimental instrument for X-ray diffraction was a D2 Phaser
Quan 4 Member of the Fuxin Uplift. Then, the Fuyu, Xinbei, Mutou, and diffractometer. For the whole rock analysis tests, fresh samples were
Xinli Oil Fields were discovered successively. In 1960, oil testing was crushed to 300 mesh. The whole rock slices were placed in a D2 Phaser
conducted in the Quan 3 Member for the first time, and good quantities diffractometer; the incident slit was 0.6 mm, the detector was 8 mm, the
of oil and gas were produced, showing a huge oil and gas potential. step size was 0.02◦ , and the time for each step was 0.5 s. For clay mineral
These hydrocarbons are mainly sourced from the mature lacustrine testing, fresh samples were pulverized to 200 mesh, and clay-oriented
shales in the Qing 1 Member. sheets were placed in a desiccator saturated with ethylene glycol. The
Previous researchers have carried out systematic research on dryer was heated to 50 ◦ C with an oven for 7–9 h, and then the clay
sequence stratigraphy and sedimentary facies of the Cretaceous in the oriented sheet was placed in a diffractometer for measurement (scan­
Songliao Basin. High-resolution sequence stratigraphic studies showed ning angle 2θ (3.5◦ ~30◦ )). After that, the clay oriented sheet was heated
that the Quan 3 Member developed as an ascending and descending base in a muffle furnace at 450–500 ◦ C for 2.5 h, and then placed in a
level semi-cycles (Fig. 1b) (Mei et al., 2019; Sun et al., 2014). The top diffractometer for measurement (scanning angle 2θ (3.5◦ –15◦ ).
boundary of the Quan 3 Member is a set of variegated mudstone with a When discussing the relationship between diagenetic sequence,
thickness of 10 m–20 m; while the thick sandstone at the bottom of the diagenetic environment, dissolution and secondary pore development
Quan 3 Member is superimposed on the mudstone of the Quan 2 zones, it is necessary to analyze the salinity of the original pore water
Member. The stratigraphic comparisons showed that the basement and the change law of its main ion types and mass concentrations. The
subsided stably during the depositional period of the Quan 3 Member. pore water data collected in this study was obtained through testing
The thickness of the Quan 3 Member of the Fuyu Oilfield ranges from with ion chromatography detection technology. During the drilling
285 to 340 m. process, when the original pore water enters the drilling fluids, it will
Based on the analysis of sedimentary structures, cores, logging re­ cause changes in the type and mass concentration of inorganic ions.
sponses, and fossils, combined with previous research results (Liu et al., Therefore, the ion chromatography detection technology can quickly
2021b; Mei et al., 2019, 2020; Sun et al., 2014; Tang et al., 2009), the and accurately detect the changes of ions in pore water. Moreover, the
Quan 3 Member of the Fuxin Uplift was dominated by meandering river type of pore water can be judged according to the mass concentration
facies in the early stage; while in the later stage, meandering river delta changes of anions and cations in the formation, combined with the
facies were developed in the central and northern parts. Point sand bars causal coefficient formula of the Surin classification method (Mei et al.,
of meandering rivers and branch channel sand bodies of delta plains are 2020).
the main reservoirs (Fig. 1b). However, the delta facies is mainly
developed in the Quan 4 Member, and the branch channels of the delta 4. Results
plain are the main reservoirs (Fig. 1b). The mud content of the Quan 3
Member is higher than that of the Quan 4 Member, but its oil content is 4.1. Petrological characteristics
much lower than that of the Quan 4 Member. For a long time, the pre­
vious studies on the Quan 3 Member were relatively low, and there were The development of high-quality reservoirs is limited by sedimen­
few studies on reservoir characteristics, diagenesis, and pore evolution. tation and diagenesis, while the evaluation criteria of reservoirs are
It restricts the oil and gas exploration process of the Quan 3 Member in controlled by petrophysical parameters (Chen et al., 2021; Haile et al.,
this area. 2018; Jafari et al., 2020; Radwan, 2022). According to the observations
of cores, ordinary and cast thin sections, the compositional maturity of
3. Materials and methods the reservoirs in the Quan 3 Member of the study area is relatively low.
Its lithologies are mainly lithic feldspar sandstone and feldspar lithic
In this study, a total of 520 m of cores from 35 wells in the Quan 3 sandstone, followed by lithic arkose sandstone, feldspathic litharenite
Member of the Fuxin Uplift were examined. Experimental tests include and a small amount of lithic sandstone (Fig. 2).
ordinary thin section (total 61), cast thin section (total 59), granularity The main components of the sandstones in the Quan 3 Member are
(total 559), scanning electron microscopy (total 10), petrophysical quartz, feldspar, and debris. The particle components of sandstone are
properties (total 52 in this test and about 3000 from previous tests), X- mostly debris (33%–45% in absolute content, 34.73% in average), fol­
ray diffraction (total 20) and pore water chemical composition tests lowed by quartz (29%–41% in absolute content, 33.23% in average) and

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Fig. 2. Triangular diagram of rock composition of the Quan 3 Member in the Fuxin Uplift.

feldspar (26%~31% in absolute content, 29.04% in average). In general,


the contents of the above three components are not much different
(Fig. 3a). Magmatic rock debris is the main component of debris. It in­
cludes medium-acid extrusive rock debris and a small amount of basalt,
schist, and phyllite debris. Feldspar is dominated by plagioclase and a
small amount of orthoclase. The matrix content of sandstones in the
Quan 3 Member is mainly concentrated at 5%–15%. Matrix components
include hetero-bases and cements (Khan et al., 2020; Zhang et al., 2014).
Among the cement components, carbonate content is the highest, about
44.83%, followed by siliceous cement, about 17.78%, and the content of
other cements such as feldspar, kaolinite, and illite is less (Fig. 3b).
According to the statistics of 559 grain size data of the target layer,
the average grain size of the sandstones in the Quan 3 Member is 0.11
mm. Fine sandstone to coarse siltstone are favorable reservoirs, while
fine siltstone and medium sandstone have less effective reservoir pro­
portions. The average grain size of the Quan 3 Member sandstones in
Xinli, Xinmu, Xinmiao, Fuyu, Xinmin, and Xinbei oilfields is 0.109 mm,
0.110 mm, 0.115 mm, 0.128 mm, 0.120 mm and 0.102 mm, respectively Fig. 4. Distribution of median particle size of sandstones in Quan 3 Member of
different oilfields.
(Fig. 4). The provenance of the Xinli, Xinmu, and Xinbei areas was
located in the southwest area, and water flowed from Xinli and Xinmu
areas to the Xinbei area, so the grain size of sandstones along this path water flowed from the Fuyu area to the Xinmin area, so the grain size of
gradually decreased. However, based on heavy mineral analysis and the sandstones is gradually decreased along this path. The Xinmiao area
previous studies (Mei et al., 2020; Sun et al., 2014), the provenance of is in a mixed source area, so its sandstone grain size is at a medium level.
the Fuyu and Xinmin areas was located in the southeastern area, and the The roundness of the sandstone reservoirs in the target layer is
dominated by the subangular type, which accounts for 92.64%, followed

Fig. 3. Distribution of main minerals and matrix components of sandstones in the Quan 3 Member in the Fuxin Uplift Belt. Notes: (a) Main rock mineral composition;
(b) Matrix composition.

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by the subangular-subcircular type (Fig. 5). Among them, the Xinli, (1) Intergranular dissolved pores
Xinmu, Xinmiao, and Xinmin areas are dominated by subangular type,
while the Fuyu area is dominated by subangular-subcircular type. Intergranular pores are formed by dissolution of primary intergran­
ular pores and residual primary intergranular pores between feldspar,
calcite, debris, and other particles (Fig. 8a). The pore size and distri­
4.2. Reservoir properties bution of intergranular dissolved pores are uneven, and the pore shape is
irregular. The percentage content is about 80%.
According to the statistics of about 3000 groups of reservoir property
data of the Quan3 and Quan4 members (Fig. 6), the reservoir properties (2) Intragranular dissolved pores
of the Fuyu Oilfield are the best, followed by the Xinli and Xinmin
Oilfields, and the reservoir properties of the Xinbei, Xinmu, and Xinmiao Intragranular dissolved pores are often developed along the cleavage
Oilfields are relatively poor. Fuyu Oilfield has developed medium- or crack of feldspar (Fig. 8a–d) and intermediate or acid extrusive rock
porosity and medium-permeability reservoirs, and the porosities are debris (Fig. 8a) in the study area, and they are often developed in
distributed between 3.0% and 34.9%. The Xinmin and Xinli Oilfields combination with intergranular dissolved pores to form ultra-large pores
mainly develop tight reservoirs with low-porosity and ultra-low (Fig. 8a). Mold pores are formed when the particles are completely
permeability properties, and the porosities are distributed between dissolved (Fig. 8a). The percentage content of intragranular dissolved
3.0% and 26.6%. However, the reservoir of the Quan 3 Member in pores is about 15% (Fig. 9g).
Xinmin Oilfield has weak heterogeneity, and the porosities are distrib­
uted between 7.3% and 15.2%. (3) Primary intergranular pores
From the perspective of the whole area, whether it is Quan 3 Member
or Quan 4 Member, the reservoirs properties tend to decrease gradually Primary intergranular pores are mainly developed in illite (Fig. 8e),
with depth (Fig. 7). The reservoir properties of the shallow reservoir chlorite and kaolinite in the study area. The size of such pores is often
above 1000 m are relatively good (porosity 20%~30%, permeability related to the size of crystals and the compactness of their accumulation.
1–1000 mD). However, the reservoir properties below 1000 m are In addition, a small amount of residual detrital intergranular pores can
relatively poor (porosity 10%~20%, permeability 0.1–100 mD). The be seen under thin-section and SEM (Fig. 8f and g). They are charac­
permeability has an obvious increase in the interval from 1100 m to terized by regular shapes and straight edges. The percentage content of
1400 m, the permeability has an obvious increase. Overall, there are primary intergranular pores is about 5%.
three abnormally increased porosity and permeability belts, which
correspond to three secondary pore development belts. (4) Micro-fractures
The variation law of reservoir properties with depth in different
oilfields is different. Among them, the reservoir of the Quan 3 Member in Micro-fractures are mainly small structural fractures formed by
the Fuyu Oilfield is shallower than 1000 m and it has the best petro­ compaction and various tectonic stresses (Fig. 8h). The fractures are
physical properties. As the depth increases, the porosity changes little relatively clean and often run through matrixes and plastic debris, which
and the permeability increases gradually (Mei et al., 2020; Zhang et al., significantly improves the permeability of the Quan 3 Member reservoir.
2021). However, the porosity and permeability of the reservoirs in Xinli, Occasionally, calcite, siliceous and other minerals are filled in the micro-
Xinmin, Xinmiao, and Xinmu oilfields gradually decrease with the in­ fractures.
crease of depth.

4.4. Diagenesis and diagenetic sequences of reservoir


4.3. Pore types of reservoir
4.4.1. Diagenesis types
The main pore types in the Quan 3 Member reservoir in the Fuxin The sandstone reservoirs in the Quan 3 Member in the Fuxin Uplift
Uplift Zone are mainly secondary dissolution pores, followed by a small had undergone intense diagenetic transformations, which included
number of primary pores and micro-fractures (Fig. 8). Secondary strong compaction (pressure solution), cementation, dissolution, and
dissolution pores include intergranular and intragranular dissolution metasomatism.
pores (including mold pores). The primary pores are mainly intercrys­
talline micropores of clay minerals, followed by a small amount of re­ 4.4.1.1. Compaction. Through thin section observations, some plastic
sidual clastic intergranular pores (residual primary intergranular pores). particles were significantly deformed by compaction, and some rigid
particles were even broken (Fig. 9a). Pressure dissolution or suture lines
were visible in the sandstone grains (Fig. 9b). These features indicated
that the Quan 3 Member reservoir in the Fuxin Uplift had suffered from
strong compaction.

4.4.1.2. Cementation. The sandstones of the Quan 3 Member in the


Fuxin Uplift Belt also experienced significant cementation, including
carbonate, siliceous, and clay mineral cementations. In areas with
equally strong compactions, the content of cement controls the devel­
opment of pores, which in turn affects the petrophysical properties of the
reservoir (Hong et al., 2020; Jabir et al., 2021; Yin and Ding., 2019).
Carbonate, secondary growth of quartz, and clay minerals are the main
cements in the target layer. The sandstones of the Quan 3 Member were
most significantly transformed by carbonate cements (Fig. 9c). The
content of carbonate cement was the highest, with an average value of
5.33%. Calcite is the main component in carbonate cement. As diagen­
Fig. 5. Distribution of particle roundness in the sandstones of the Quan 3 esis continued, some dolomite replaced calcite. In the late diagenetic
Member in the study area. stage, some ferrocalcite and ankerite were produced. Among them,

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Fig. 6. Distribution of reservoir properties of sandstones in the Quan 3 Member of different areas.

Fig. 7. Relationship between reservoir properties and burial depth of Quan 3 and Quan 4 Members in the study area. Notes: The porosity and permeability are
experimental results.

dolomite often coexisted with calcite and mostly filled the pores. Fer­ et al., 2021; Lai et al., 2018a, 2018b; Liu et al., 2021). Moreover, when
rocalcite and ankerite also filled the primary and secondary pores, and the diagenetic environment converted to an acidic environment, Si4+
metasomatized the grains and early carbonate cements. The siliceous began to precipitate and aggregate into enlarged edges of authigenic
cementation in the target layer is mainly manifested as quartz over­ quartz (Kashif et al., 2019; Khan et al., 2020). The enlarged edges of
growth (Fig. 9d). Grade II quartz overgrowth (edges) can be seen in most authigenic quartz can be grown to near grain size (Fig. 9d). Scanning
samples, and even grade III quartz overgrowth can be observed in some electron microscope observations showed that a large number of
samples. autogenous enlarged quartz are hexagonal columnar crystals growing
When flint and volcanic debris particles are dissolved by alkaline between the grains, and they are aggregated into a cluster-like structure.
fluids, large amounts of Si4+ will be produced (Guo et al., 2021; Jabir The clay mineral components that appear in the form of cements in

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Fig. 8. Development types of reservoir pores of the


Quan 3 Member in the Fuxin Uplift Belt. Notes: (a)
Intergranular and intragranular dissolved pores, J24
well, 495.4m; (b) Feldspar dissolved pores, J31 well,
493.1m; (c) Feldspar dissolved pores, clay mineral
intercrystalline pores, J41 well, 1369.76m; (d) Mold
pores, J+28-015.1 well, 1364.75m; (e) Clay mineral
intercrystalline pores, quartz overgrowth, X269 well,
1258.80m; (f) Residual primary intergranular pores
and dissolved intergranular pores, J30 well, 458.1m;
(g) Original intergranular pores between grains, Xin
211 well, 1901.52m; (h) Micro-fractures, Well
M+126-024, 961.72m.

the target layer mainly include chlorite, illite, imon mixed layer, and precipitation and the dissolution of organic acids (Mahmi et al., 2018;
kaolinite. Among them, chlorite is the most common, which is often Zhang et al., 2021). The leaching occurred primarily in the Fuyu Oil­
developed around the grains in the form of lining cementation (Fig. 9e). field’s high-structure and shallow-buried areas. It can be seen from
The imon mixed layers represent a transitional form from montmoril­ Fig. 10 that the kaolinite content in the clay minerals of the target layer
lonite to illite and retain the honeycomb morphology of montmorillonite in the Fuyu Oilfield decreased with the increase of depth, which indi­
(Hijaz et al., 2020; Hong et al., 2020; Li et al., 2005). Illite appeared as cated that the shallow sandstone reservoirs had suffered severe leaching.
an irregular wafer-like structure (Fig. 8f). Kaolinite was developed in the In addition, secondary pores originating from the strong dissolution of
shallow sandstones of Fuyu Oilfield, which reflected an acidic organic acids generated after the hydrocarbon generation stage were
environment. developed as well (Chen et al., 2021; Radwan et al., 2021c; Yin et al.,
2020a; 2020b).
4.4.1.3. Dissolution. The dissolution forms of the target layer were
mainly manifested in the dissolution of feldspar minerals, rock debris, 4.4.1.4. Metasomatism. Metasomatism is also very common in the
and carbonate cements (Fig. 9g). The dissolved feldspar is mainly albite, target layer of the study area. It is often manifested that unstable min­
while the dissolved debris is mainly volcanic debris. In addition, dis­ erals such as feldspar and debris in acidic media are replaced by car­
solved carbonate cements include early-formed calcite and a small bonate rocks and clay minerals (chlorite, kaolinite, etc.). In addition, the
amount of dolomite and quartz. mutual metasomatism between cement components can also be
The causes of dissolution include the leaching of atmospheric observed, such as dolomite for calcite, iron dolomite for dolomite, etc.

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Fig. 9. Microscopic structural characteristics of


different minerals in the target sandstones in the
study area. Notes: (a) Deformed mica, J+2–014 well,
1327.5 m; (b) Suture contact between particles,
J+28-015.1 well, 1326.2 m; (c) Carbonate cement,
J24 well, 431.15 m; (d) Quartz overgrowth, J+28-
015.1 well, 1310.4 m; (e) Chlorite-coated lining
cement, J+2–014 well, 1293.2 m; (f) Symbiotic illite,
chlorite and secondary quartz, X207 well, 1180.0 m;
(g) Feldspar and detrital dissolution pores, J+28-
015.1 well, 1310.31 m; (h) Dolomite metasomatic
calcite, J31 well, 493.15 m.

(Fig. 9h). the maturation of organisms and the chemical reactions of clay minerals
promoted the development of secondary pores in the sandstones.
4.4.2. Diagenetic sequences of reservoir According to the research results, the diagenesis stages of the Quan 3
The present burial depth of the reservoir in the Quan 3 Member of Member sandstone reservoir were divided as shown in Fig. 10. The
the Fuxin Uplift Belt is between 500 m and 2000 m. The target layer shallow sandstones are in the meso-diagenetic A1 stage; when the burial
suffered strong compaction, and the proportion of residual intergranular depth exceeds 800 m, they enter the meso-diagenetic A2 stage; when the
pores in the reservoir was low. In addition, general and strong secondary burial depth exceeds 1600 m, they enter the meso-diagenetic B stage
growth of quartz occurred in the reservoir, and the intergranular pores (Fig. 11).
were generally filled with various authigenic minerals. Under the mi­ According to the observation results under the microscope, the iron-
croscope, it was found that iron-bearing carbonate minerals were com­ bearing carbonate cements were formed after the enlarged edge of
mon in the target layer. The types of clay minerals in the target layer are quartz, but the siliceous cements were not obvious in the sandstones
mainly illite, imon mixed layers, and kaolinite, and the content of with developed secondary pores (Fig. 12).
smectite in the imon mixed layer minerals is distributed between 15% Based on this, it can be determined that the formation time of early
and 25%. Moreover, the large amounts of acidic water discharged from calcite cements was earlier than that of siliceous cements, while the

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Q. Zhang et al. Marine and Petroleum Geology 145 (2022) 105883

(1946) (Mei et al., 2020), the pore water of the Quan 3 Member in the
study area is mainly NaHCO3 type water. The various cations in the
samples satisfy: ρ(Na++K+)>ρ(Ca2+) >ρ(Mg2+), and the main anions
satisfy: ρ(Cl− )>ρ(HCO−3 )>ρ(SO2−4 ). According to the distribution of
HCO−3 concentration with depth, the distribution of formation water was
divided into five zones (Table 1). In turn, it leads to the reservoirs of the
Quan 3 Member having experienced these 5 diagenetic environmental
zones, namely early weak acidic→early weak alkaline→metaphase
acidic→metaphase alkaline→late weak acidic. Accordingly, the diage­
netic evolution sequence of the target layer is as follows: early light
compaction and atmospheric water dissolution of feldspar and
debris→early calcite cementation→intense compaction and early quartz
overgrowth and chlorite lining cementation→large scale dissolution of
feldspar and calcite, late quartz overgrowth→ cementation of
iron-bearing calcite and dolomite → late clay mineral transformation
and carbonate dissolution (Fig. 12).

5. Discussion

5.1. Evolution of pore space

After complicated diagenetic transformation, the secondary pores


Fig. 10. Relationship between kaolinite content and depth in shallow sand­
were developed in the Quan 3 Member in the study area. The evolution
stones in Fuyu Oilfield.
process of the reservoir space of the Quan 3 Member is shown in Fig. 13:.

(1) In the early diagenetic stage, with the increase in depth, the
compaction from overlying loads was continuously enhanced,
and the primary intergranular pores were continuously reduced.
Calcite cements were generated in the early alkaline water. Af­
terwards, intense compaction led to the formation of micro­
fractures in the feldspar component. Local atmospheric
precipitation leaching allowed some acidic pore fluids to enter
and dissolve feldspar and a small amount of debris, which
resulted in the formation of the first secondary pore development
belt. In addition, a large number of siliceous cements began to
develop, and the intergranular pores were reduced.
(2) In the meso-diagenesis A1 stage, organic matter began to mature
and a large amount of organic acid was discharged; debris and
feldspar were dissolved to form intragranular dissolved pores and
part of feldspar was completely dissolved to form mold pores. In
addition, some intergranular dissolution pores were formed in
the dissolution of calcite cements. A large number of secondary
pores were developed at this stage, which corresponds to the
second secondary pore development belt.
(3) In the meso-diagenesis A2 stage, dissolution still led to the for­
mation of a small number of secondary dissolution pores.
Meanwhile, the intergranular pores were filled with various
precipitated authigenic minerals. At this stage, some secondary
Fig. 11. Relationship between I/S and depth in the sandstones of the Quan 3 pores will be destroyed. However, the latter transformation of
Member in the Fuxin Uplift Belt. clay minerals will also produce some acidic water, which will
cause the dissolution of some late carbonate cements, and then a
formation of iron-bearing calcite and dolomite cements was later than small number of secondary pores will be formed.
that of quartz secondary enlarged cements. The compaction continued
during the deposition process, and the compaction became stronger as 5.2. Diagenesis control on continental sandstone reservoir quality
the burial depth increased. Early quartz overgrowth had occurred before
intense compactions, while chlorite films had occurred after siliceous Diagenesis has significant control over the quality of continental
cementations. After the feldspar was dissolved and the secondary sandstone reservoirs (Baiyegunhi et al., 2020; Lai et al., 2018c; Wang
enlarged edge of quartz was developed in the late stage, the dissolved et al., 2021; Zhang et al., 2021; Zhang et al., 2021, 2021). The current
pores or cast-film pores developed along the joints in the feldspar can study found that compaction is the primary factor controlling the quality
provide an effective space for oil and gas accumulation. It reflected the of the target reservoir. It controls the differences in the quality of the
transition of the diagenetic environment from weak alkaline to weak reservoirs in the eastern and western regions of the studied area (Figs. 6,
acid in the latter period (Fig. 12). Figure 9, Fig. 17). Cementation and dissolution are secondary control­
Changes in pore water properties affect the types and diagenetic ling factors of reservoir petrophysical properties, which control the
sequences of different types of diagenesis. According to the laboratory difference in reservoir petrophysical properties in the north and south
data of pore water (Table 1) and according to the Surin Classification regions (Figs. 6, Figure 9, Fig. 17). Different diagenesis influence and
restrict each other (Zhang et al., 2014, 2021; Radwan et al., 2021c; Wei

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Q. Zhang et al. Marine and Petroleum Geology 145 (2022) 105883

Fig. 12. Diagenetic evolution sequence of continental sandstone reservoirs in the Quan 3 Member in the study area.

Table 1
Distribution intervals of various ion concentrations in the target layer at different depths in the study area.
Ion concentration band Depth (m) Cation concentration range (mg/L) Anion concentration range (mg/L)
2+ 2+
Na +K
+ +
Ca Mg HCO3- Cl− SO2-
4

Shallow high concentration zone <550 733–4538 9.6–78.0 1.0–19.5 21–3033 808–3758 0–209
Shallow low concentration zone 550–800 1511–2191 80.0–137.0 9.2–13.0 67–333 2383–2659 24–389
Central high concentration zone 800–1500 982–11,087 2.8–390.8 0.6–48.4 120–20,571 1294–6399 2–2275
deep desalinating zone 1500–1900 1178–5500 5.0–258.5 1.2–65.4 61–6483 1260–3722 0–421
Deep concentration zone >1900 1532–2659 7.8–328.3 3.2–39.5 308–805 1873–4120 81–1511

et al., 2021; Yin et al., 2020a). permeability. Therefore, compaction is the main reason for the differ­
ence in reservoir physical properties between the eastern and western
5.2.1. Effect of compaction on reservoir quality regions. As shown in Fig. 14, even for the same sedimentary facies, such
Generally, the main factor affecting the intensity of compaction is the as point sand bars, branch river channels, with the increase of burial
burial depth. As the burial depth increases, the compaction becomes depth, both the porosity and permeability decreased obviously. This
stronger and the petrophysical properties of the reservoir will become feature reflects that compaction has a significant impact on the quality
poor (Lv and Li, 2021; Radwan, 2021a; Yu et al., 2019; Yin et al., of the target continental sandstone reservoirs.
2020b). Compaction has a negative effect on the petrophysical proper­ Compaction is also affected by lithology and cementation (Haile
ties of the reservoir. In particular, compaction has a significant effect on et al., 2018; Yang and Chen, 2001; Yin et al., 2020; Zhang et al., 2014,
sandstones with poor sorting and low cement content (Christopher et al., 2020). Lithological characteristics are closely related to sedimentary
2017; Wang and Yang, 2017; Yang and Chen, 2001; Zhang et al., 2021). facies. In this area, meandering river and delta deposits are mainly
The greater the burial depth, the stronger the compaction, and the developed (Mei et al., 2020) (Fig. 1b), and the physical properties of
higher the degree of porosity reduction (Fig. 7). The burial depth of the different microfacies reservoirs at the same burial depth are different
Quan 3 Member in the eastern Fuyu Oilfield is relatively shallow, and (Fig. 14). Among them, fine sandstones with good sorting are developed
the sandstone experienced weak compaction. This is the fundamental in branch channels and meandering river point bars of the delta plains.
reason for the overall best reservoir properties in this area (Fig. 17). The grains are mainly in point contact, the primary pores are developed,
However, the Quan 3 Member in the western region is buried relatively and the plastic matrix is less, so the later compaction is weak. In this
deep, so the compaction is strong, resulting in poor porosity and way, the primary pores are preserved, which facilitates the flow of pore

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Q. Zhang et al. Marine and Petroleum Geology 145 (2022) 105883

Fig. 13. Pore space evolution of sandstones in the Quan 3 Member in the Fuxin Uplift Zone.

Fig. 14. Effects of compaction on the degree of pore development in the Quan 3 Member of the study area.

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Q. Zhang et al. Marine and Petroleum Geology 145 (2022) 105883

Fig. 15. Effects of lithology and cementation on compaction of the target layer. Notes: (a) Delta plain branch channel facies, oil-bearing fine sandstone, well-
connected pores, Well J25, 389.72m; (b) Delta front underwater branch channel facies, siltstone, moderately developed pores with high content of miscellaneous
matrix, Well J30, 405.5 m; (c) Meandering river beach facies, fine calcareous sandstone, strong cementation, underdeveloped pores, Well J24, 495.45m.

Fig. 16. Relationship between carbonate content and petrophysical properties of sandstones in the Quan 3 Member in the study area.

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Q. Zhang et al. Marine and Petroleum Geology 145 (2022) 105883

Fig. 17. Variation of carbonate content and porosity with depth of the Quan 3 member in the study area.

water and further causes the development of secondary dissolution in carbonate cement development belt near 1200 m. The areas with higher
the later stage. For example, in Well J30 (368.1m), the delta plain cement content are located in the Xinli Oilfield in the southwest part. At
branch channel fine sandstone has very developed pores (Fig. 15a). the same burial depth, the compaction effect is not much different, but
However, the finer the rock particle size, the poorer the sorting, the the petrophysical properties of Xinbei and Xinli oilfields are quite
higher the content of matrix, and the less primary pores are developed. different. Therefore, the content of cement is the main reason for the
The plastic characteristics of the matrix make the rock subjected to differences in reservoir properties between the southern and northern
obvious compaction during the burial process, which further de­ regions.
teriorates the porosity and permeability. For example, in Well J24 In this study, the content of carbonate cement occurring in a single
(405.5m), siltstone-fine sandstone is developed in the underwater thick sand body was also analyzed, and it was found that it developed
branch channel of the delta front, and the pores in the sandbodies are “calcareous tops” and “calcareous bottoms” (Fig. 18).
extremely undeveloped (Fig. 15b). Calcareous tops and bottoms usually occur in sandstones sandwiched
In addition, early cementation can effectively resist compaction. For between two sets of thick mudstones (Zhang et al., 2014). It is related to
example, early calcareous cements were observed in the sandstones in the drainage of the mudstones adjacent to the top and bottom of the
the 495.4 m interval of Well J24 (Fig. 15c). The particles were in the sandstones. The formation water discharged from mudstones contained
form of floating-point contacts under pore-substrate cementation. The a large amount of carbonate ions, which precipitated with calcium ions
strong early cementation greatly limits the compaction between in adjacent sandstones to form calcareous tops and bottoms, while the
particles. middle parts of sandstones were less affected. It can be seen from Fig. 18
that the porosity and permeability of the calcareous top and bottom
5.2.2. Effect of cementation on reservoir quality parts are relatively low; while the middle parts of the sandstones are
The sandstone reservoirs of the Quan 3 Member contain a lot of relatively less cemented, and the porosity and permeability are rela­
carbonate cements. These cements severely reduce the porosity of the tively high. According to the statistical results, the thicknesses of the
reservoir and the connectivity between pores (Enayati-Bidgoli and calcareous top and bottom are between 0.2 m and 1.5 m and 0.6 m–1.2
Saemi, 2019; Zhang et al., 2014, 2021). From Fig. 16, it can be observed m, respectively. When the thickness of the sandstone is less than 2.7 m, it
that with the increase of cement content, the reservoir petrophysical is difficult to form an effective reservoir.
properties will become poor.
The carbonate cement content of the Quan 3 Member in different 5.2.3. Effect of dissolution on reservoir quality
areas of the study area changes significantly with the increase in depth. Dissolution has a great influence on the development degree of
It is negatively correlated with the pore development belt (Fig. 17). For secondary pores (Su et al., 2022; Radwan, 2022; Wang et al., 2019;
example, the content of cement in the Quan 3 Member of Fuyu Oilfield is Zhang et al., 2017). The stronger the dissolution, the better the petro­
relatively low (below 8%), while its porosity and permeability are the physical properties of the reservoir (Hong et al., 2020; Jabir et al., 2021;
highest. The porosity and permeability are up to 34.9% and 3167.15 mD Lai et al., 2018a; Yang et al., 2013; Radwan, 2022). Secondary pores are
respectively. Near the burial depth of 1200 m, the carbonate content an important pore type in the Quan 3 Member in the Fuxin Uplift Belt
increases significantly (Fig. 17). This is because the upper part of the (Fig. 8). It can be seen from Fig. 7 that there are three secondary pore
Quan 3 Member is covered with the huge thick mudstones of the Qing 1 development belts in the Quan 3 and 4 Members. The three secondary
Member. Meanwhile, thick mudstone interlayers also exist between the pore development belts are located in the intervals of 200 m–500 m,
sandstones. Under the strong compaction of the mudstones in the Qing 1 1100 m–1500 m and 1600 m–1800 m, respectively. The material basis
Member, the carbonate-containing fluid stored in the pores of the for dissolution is the presence of soluble substances in rocks (Y.Z. Wang
mudstones will migrate into the adjacent sandstones. Furthermore, the et al., 2016; Zhang et al., 2021; Zhao et al., 2021). A large amount of
water-rock reactions promoted the formation of carbonate cements. feldspars, volcanic rock debris and early calcite cements have developed
According to the diagenetic mode proposed in this study, there is a in the sandstones of the Quan 3 Member (Fig. 2). Therefore, the easily

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Q. Zhang et al. Marine and Petroleum Geology 145 (2022) 105883

Fig. 18. Relationship between cement content and petrophysical parameters in a single sedimentary cycle sand body in the Quan 3 Member (Well X 264).

soluble components such as feldspars, debris, and early calcite cements Fig. 19. Three high-concentration belts, namely the shallow
in the rock were dissolved (Figs. 8 and 12) due to the leaching of at­ high-concentration belt, the central high-concentration belt, and the
mospheric fresh water and the effect of organic acids produced by the deep desalinating belt, appear, which are consistent with the interval of
thermal evolution of the upper Qing 1 Member mudstones. In turn, these the three secondary pore development belts.
factors act together on deep reservoirs and promote the formation of The shallow high HCO−3 ion concentration belt is buried less than
secondary pore development belts. 500 m, which is a typical atmospheric freshwater leaching belt. The
The strength of dissolution is related to the concentration of various dilution of atmospheric fresh water and the dissolution of CO2 in water
ions in pore water, especially the concentration of HCO−3 (Jabir et al., caused the pore water to show weak acidity, which in turn led to the
2021; Mei et al., 2020; Wang et al., 2019, 2020). The vertical distribu­ dissolution of feldspar and debris in the target sandstones. Then the first
tion of HCO−3 ion concentration in the pore water of the Quantou For­ secondary pore development belt was formed (Fig. 19).
mation in the northern part of the Fuxin Uplift is shown in Table 1 and The high HCO−3 ion concentration band in the middle part is between

Fig. 19. Distribution of HCO−3 concentration and porosity at different depths in the target layer of the study area. The three high HCO−3 ion concentration intervals
correspond to the three secondary pore development intervals.

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Q. Zhang et al. Marine and Petroleum Geology 145 (2022) 105883

800 m and 1500 m, where HCO−3 ion increased sharply and reached a Therefore, the H+ released by the dehydration of organic acids and clay
maximum value (Fig. 19). It corresponds to the secondary pore devel­ minerals together caused the formation of the third secondary pore
opment belt. According to previous studies (Sun et al., 2013; Zhong development belt. Eventually, a deep ion concentration desalination
et al., 2009), the shales of the Qingshankou Formation in the upper part band formed.
of the Quantou Formation is the main source of hydrocarbons in the
Quan 3 and Quan 4 members. In addition, according to the diagenetic
stage division in this study (Fig. 11), the Qing 1 Member entered the 5.3. Prediction of favorable reservoirs
mature-high maturity stage at 1500 m–1750 m; at a depth of 800
m–1500 m, the Qing 1 Member source rock was generally in the Based on the analysis of reservoir physical properties, sedimentary
immature to low-mature transformation stage. A large amount of facies, diagenetic stages and diagenesis in the Quan 3 Member, the
organic acids and phenols were discharged from the source rock prior to distribution of favorable reservoirs is predicted. The comprehensive
the peak of hydrocarbon generation, and the soluble components in the analysis indicates that the branch channel and meandering river point
target sandstones, such as feldspar, feldspar-bearing volcanic debris, and bar fine sandstone of the delta plain in the Quan 3 Member are the best
early calcite cement, were massively dissolved. Thus, a second second­ reservoir types (Figs. 14 and 15). However, due to the different
ary pore development belt was formed. Therefore, the increase in the diagenesis experienced in different regions, there are obvious differ­
concentration of HCO−3 ions caused by organic acids is an important ences in reservoir quality. The high-quality reservoirs are mainly located
factor for the formation of secondary pore belts in the Quan 3 Member. in the Fuyu Oilfield in the southeastern region (Figs. 6, Figure 14,
Different ion concentrations can cause changes in pH, which is the Figure 17, Figure 19). The shallowly buried Quan 3 Member suffered
essential cause of dissolution (Ma et al., 2019; Mei et al., 2020; Zhang less compaction and preserved some primary pores (Fig. 8). Later, due to
et al., 2014). By comparing the distribution of porosity, permeability, the uplift of the crust, the reservoir suffered from leaching and disso­
and pH value of formation water below 1100 m (Fig. 20), it can be found lution, and a certain amount of secondary pores developed (Fig. 8). In
that a secondary pore development belt is developed in the Quan 3 this way, the development of mixed pores improves the quality of the
Member between 1300 m and 1500 m (Fig. 20a~b), and the pH value of reservoir. In the Xinmin Oilfield in the northeastern region, the sand
the formation water in this formation interval is around 6–7 (Fig. 20c). bodies are shallow in burial and suffer less compaction and weaker
However, with the further increase of burial depth, the pH value of the cementation, so reservoirs with better physical properties are devel­
formation water gradually increased; that is, it gradually became alka­ oped. In addition, in the northern part of Xinli Oilfield and the northern
line. Therefore, with increased compaction, the petrophysical properties area of Xinmiao Oilfield, the sand bodies encountered strong dissolution
of the sandstones that have not been transformed by dissolution will of organic acid in the later stage, which further effectively improved the
become poor. In contrast, the dissolution of organic acids is also an physical properties of the reservoir, so better types of reservoirs were
important factor controlling reservoir quality. also developed. However, the shoal sand bodies developed in the Xinli
In the buried depth range of 1500 m–1900 m, the concentration of Oilfield have a larger burial depth, and their diagenetic stage is mostly in
HCO−3 decreased. But it is still higher than the atmospheric freshwater the middle diagenetic A2 stage, which is strongly compacted. At the
leaching belt. The concentration of Cl− also decreased significantly, same time, the fecalcite formed in the later stage represents strong
indicating that the formation water in this belt was obviously desali­ cementation (almost no dissolution), so the reservoir physical properties
nated. The Cl− in formation water is thought to be very stable and does are the worst.
not precipitate due to water-rock interactions (Wei et al., 2021; Yu et al.,
2019; Zhang et al., 2014). The decrease of Cl− is mainly related to the 6. Conclusions
dilution effect caused by the massive dehydration of clay minerals. Since
the organic matter in the deep formation is in the over-mature stage, (1) In this paper, taking the Quan 3 Member of the Cretaceous
there are still some organic acids that can enter the sandstones. Quantou Formation in the Fuxin Uplift as an example, the
petrological characteristics, diagenesis, and their influence on the

Fig. 20. Distribution of reservoir petrophysical parameters and pH value of the Quan 3 Member at different depths. Notes: (a) Porosity of reservoirs buried below
1100 m; (b) Permeability of reservoirs buried below 1100m; (c) Relationship between pH of formation water and depth below 1100 m.

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Q. Zhang et al. Marine and Petroleum Geology 145 (2022) 105883

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