The document summarizes properties of elements in the s-block and hydrogen. For the first group elements, atomic mass and ionization enthalpy increase down the group, while metallic radius and reduction potential decrease. For the second group, ionization enthalpy decreases and boiling point increases down the group. Hydrogen isotopes follow trends in atomic mass, boiling/melting points, and density with increasing mass. Water properties are lower than heavy water counterparts.
The document summarizes properties of elements in the s-block and hydrogen. For the first group elements, atomic mass and ionization enthalpy increase down the group, while metallic radius and reduction potential decrease. For the second group, ionization enthalpy decreases and boiling point increases down the group. Hydrogen isotopes follow trends in atomic mass, boiling/melting points, and density with increasing mass. Water properties are lower than heavy water counterparts.
The document summarizes properties of elements in the s-block and hydrogen. For the first group elements, atomic mass and ionization enthalpy increase down the group, while metallic radius and reduction potential decrease. For the second group, ionization enthalpy decreases and boiling point increases down the group. Hydrogen isotopes follow trends in atomic mass, boiling/melting points, and density with increasing mass. Water properties are lower than heavy water counterparts.
1) Atomic Mass Li < Na < K < Rb < Cs 2) Ionisation Enthalpy Li > Na > K > Rb > Cs 3) Hydration Enthalpy Li > Na > K > Rb > Cs 4) Metallic Radius Li < Na < K < Rb < Cs 5) M.P and B.P Li > Na > K > Rb > Cs *6) Density Li < K < Na < Rb < Cs *8) Standard reduction potential Na > K > Cs > Rb > Li
SECOND GROUP ELEMENTS
1) Atomic Mass Be < Mg < Ca < Sr < Ba
2) Ionic Radius Be < Mg < Ca < Sr < Ba
*3) Ionisation Enthalpy Be > Mg > Ca > Sr > Ra > Ba 4) Hydration Enthalpy Be > Mg > Ca > Sr > Ba *5) B.P Mg < Sr < Ca < Ba < Be *6) M.P Mg < Ra < Ba < Sr < Ca < Be *7) Density Ca < Mg < Be < Sr < Ba < Ra *8) Standard Reduction potential Be > Mg > Ca > Sr > Ba = Ra HYDROGEN
1) Relative Abundance H>D>T
2) Atomic Mass H<D<T 3) B.P and M.P H<D<T 4) Density H<D<T 5) Enthalpy of fusion H<D 6) Enthalpy of Vaporisation H<D 7) Enthalpy Of bond dissociation H<D 8) Internuclear Distance H=D
1) M.P H2O < D2O
2) B.P H2O < D2O 3) Enthalpy of Vaporisation H2O < D2O 4) Enthalpy of fusion H2O < D2O 5) Dielectric constant H2O > D2O 6) Density and viscosity H2O < D2O
Coordination Chemistry—XIV: Plenary Lectures Presented at the XIVth International Conference on Coordination Chemistry Held at Toronto, Canada, 22—28 June 1972