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  • Trends Part 1

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    Sahar Anjum
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    The document compares various properties of group 15 elements (nitrogen, phosphorus, arsenic, antimony, and bismuth) and their hydrides and oxides. It lists trends in atomic mass, ionization energy, electronegativity, covalent radius, ionic radius, melting point, and boiling point that generally increase down the group. It also compares properties of the group 15 hydrides like melting point, boiling point, E-H distance, H-E-H bond angle, acidic strength, and reducing character that tend to increase with increasing element size. Furthermore, it notes the acidic strength of the group 15 oxides increases from N2O3 to Bi2O3.

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    The document compares various properties of group 15 elements (nitrogen, phosphorus, arsenic, antimony, and bismuth) and their hydrides and oxides. It lists trends in atomic mass, ionization energy, electronegativity, covalent radius, ionic radius, melting point, and boiling point that generally increase down the group. It also compares properties of the group 15 hydrides like melting point, boiling point, E-H distance, H-E-H bond angle, acidic strength, and reducing character that tend to increase with increasing element size. Furthermore, it notes the acidic strength of the group 15 oxides increases from N2O3 to Bi2O3.

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    © All Rights Reserved
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    5 views1 page

    Trends Part 1

    Uploaded by

    Sahar Anjum
    The document compares various properties of group 15 elements (nitrogen, phosphorus, arsenic, antimony, and bismuth) and their hydrides and oxides. It lists trends in atomic mass, ionization energy, electronegativity, covalent radius, ionic radius, melting point, and boiling point that generally increase down the group. It also compares properties of the group 15 hydrides like melting point, boiling point, E-H distance, H-E-H bond angle, acidic strength, and reducing character that tend to increase with increasing element size. Furthermore, it notes the acidic strength of the group 15 oxides increases from N2O3 to Bi2O3.

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    © All Rights Reserved
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    GROUP – 15

    1) Atomic mass N < P < As < Sb < Bi

    2) Ionisation enthalpy N > P > As > Sb > Bi

    *3) Electronegativity N > P > As > Sb = Bi

    4) Covalent radius N < P < As < Sb < Bi

    *5) Ionic radius Sb < Bi < N < P < As

    *6) Melting point N < P < Bi < Sb < As

    *7) Boiling point N < P < As < Bi < Sb

    8) Density N < P < As < Sb < Bi

    GROUP 15 HYDRIDES
    *1) Melting point PH3 < AsH3 < SbH3 < NH3
    *2) Boiling Point PH3 < AsH3 < NH3 < SbH3 < BiH3
    3) E-H distance (E = element) NH3 < PH3 < AsH3 < SbH3
    4) HEH angle (E = element) NH3 > PH3 > AsH3 > SbH3
    5) Acidic strength NH3 < PH3 < AsH3 < SbH3 < BiH3
    6) Reducing character NH3 < PH3 < AsH3 < SbH3 < BiH3

    GROUP 15 OXIDES
    1) Acidic Strength N2O3 > P2O3 > As2O3 > Sb2O3 > Bi2O3

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