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Future Allowable Air Contaminant Emissions (tons/year)

Source PM/PM10 SO2 NOx CO VOCs

Combustion Equipment - Fuel Type


Boilers - Natural Gas 0.16 0.01 2.10 1.76 0.12
Boilers - Fuel Oil 0.49 0.03 2.94 0.74 0.05
Other Gas-Fired Equipment Emissions for this equipment included as part of natural gas fired boiler emissions
Emergency Engine(s) 0.08 0.0004 1.08 0.23 0.09

Total Maximum Allowable Emissions 0.72 0.04 6.12 2.73 0.25


year)

Total Criteria HAPs

4.04 0.04
4.20 0.01
atural gas fired boiler emissions
1.38 0.0016

9.62 0.05
Estimated Emissions - Combustion Equipment
Fletcher Allen Health Care, Inc. - U.H.C. Campus

Fuel Oil % Sulfur Content by weight = 0.0015


Cleaver-Brooks boiler rating = 20.9 MMBtu/hr
Cyclotherm boiler rating = 4.0 MMBtu/hr
Other Natural Gas Combustion Equipment = ??? MMBtu/hr
Heat Value of Natural Gas = 1,020 Btu/cf
Heat Value of No. 2 Fuel Oil = 140,000 Btu/gal

Emission Factors
Annual Fuel
Source Description Fuel Heat Value Limit PM PM (§5-231) SO2 NOx
Natural Gas Boilers 1,020 42.0 7.6 0.3 0.6 100
million cubic ft
Natural Gas Units btu/cf /year lb/MMcf lb/MMBtu lb/MMCF lb/MMCF

No.2 Oil Boilers 140,000 294,440 3.30 0.3 0.213 20


No.2 Fuel Oil units btu/gal Gallons/yr lb/1000 gallon lb/MMBtu lb/1000 gallon lb/1000 gallon
Other Gas-Fired
Equipment 1,020 0.0 7.6 0.4 0.6 37.2
million cubic ft
Natural Gas Units btu/cf /year lb/MMcf lb/MMBtu lb/MMCF lb/MMCF

Estimated Annual Emissions (ton/yr)


Equipment and Fuel Source PM PM (§5-231) SO2 NOx
Boilers - Natural Gas 0.16 31.62 0.013 2.10
Boilers - Fuel oil 0.49 31.62 0.031 2.94
Other Gas-Fired Equipment (included in boiler emissions) 0.00 26.28 0.000 0.00

Hazardous Air Pollutants and Contaminants


Resulting From Natural Gas Fuel Combustion

Pollutant Emission Factor


lb/10 6 scf
2-Methylnaphthalene a 2.40E-05
3-Methylchloranthrene a 1.80E-06
7,12-Dimethylbenz(a)anthracene a 1.60E-05
Acenaphthene a 1.80E-06
Acenaphthylene a 1.80E-06
Anthracene a 2.40E-06
Arsenic 2.00E-04
Bariumb 4.40E-03
Benz(a)anthracene a 1.80E-06
Benzene 2.10E-03
Benz(a)pyrene a
1.20E-06
Benzo(b)fluoranthene a 1.80E-06
Benzo(g,h,i)perylene a 1.20E-06
Benzo(k)fluoranthene a 1.80E-06
Beryllium 1.20E-05
Cadmium 1.10E-03
Chromium 1.40E-03
Chrysene a 1.80E-06
Cobalt 8.40E-05
Copperb 8.50E-04
Dibenzo(a,h)anthracene a 1.20E-06
Dichlorobenzene 1.20E-03
Flouranthene a 3.00E-06
Flourene a 2.80E-06
Formaldehyde 7.50E-02
Hexane 1.80E+00
Indeno(1,2,3-cd)pyrene a 1.80E-06
Manganese 3.80E-04
Mercury 2.60E-04
Molybdenumb 1.10E-03
Naphthalene 6.10E-04
Nickel 2.10E-03
Phenanthrene a 1.70E-05
Pyrene a 5.00E-06
Selenium 2.40E-05
Toluene 3.40E-03
Vandiumb 2.30E-03
Zincb 2.90E-02

Total HAPs 1.89E+00

a
HAP because it is a Polycyclic Organic Matter (POM).
POM is a HAP as defined by Section 112(b) of CAA

HAC but not a HAP


b

Emission Factors from AP 42, Tables 1.4-3 and 1.4-4 (3/98)


ion Factors

CO VOC HAP Data Source


84 5.5 1.888 AP-42 - Section 1.4 (7/98)

lb/MMCF lb/MMCF lb/MMCF

5 0.34 0.062 AP-42 - Section 1.3 (5/10)


lb/1000 gallon lb/1000 gallon lb/1000 gallon
AP-42 - Section 1.4 (7/98); Nox and Co emission
298 5.5 1.888 factors are from vendor information.

lb/MMCF lb/MMCF lb/MMCF

CO VOC HAP Total Emissions by Fuel


1.76 0.12 0.04 4.2
0.74 0.05 0.01 4.3
0.00 0.00 0.00 0.0
Diesel Engine/Generator Emission Calculations

Facility: Permit number (#AP-14-010)


Fletcher Allen Health Care Inc., U.H.C. Campus

Engine Specs: Make and Model: CAT 3208


Engine bhp: 299 bhp prime rating
Calculated engine output kW: 223.1 kW prime
Engine max fuel use 14.8 gph
Calculated engine efficiency 37.5%
Generator rated output kW prime (not used in calculations)

Permit Limits: Diesel Fuel Cap (gal/year): 2,960 Fuel heating value (Btu/gal):
Fuel % sulfur by weight:
Fuel sulfur content (ppm):

CAT 3208 Diesel Engine Emissions1

AP-42 Section 3.3 AP-42 Section 3.4


(<600 hp) 10/96 (>600 hp) 10/96 5-271(b) and Tier 12
Pollutant lb/Mmbtu tpy lb/Mmbtu tpy g/bhp-hr lb/Mmbtu
NOx 4.41 0.89 3.2 0.65 6.9 2.24
CO 0.95 0.19 0.85 0.17 8.5 2.76
PM 0.31 0.06 0.1 0.02 0.4 0.13
SO23 0.00 0.0003 0.00 0.00 0.00
VOC4,5 0.36 0.07 0.08 0.02 0.1
HAPs 6.45E-03 0.0013
Total 1.22 0.86

Engine Specs: Make and Model: Detroit Diesel 3-71 Model 10347110
Engine bhp: 55 bhp prime rating
Calculated engine output kW: 41.0 kW prime
Engine max fuel use 3 gph
Calculated engine efficiency 34.1%
Generator rated output kW prime (not used in calculations)

Permit Limits: Diesel Fuel Cap (gal/year): 600 Fuel heating value (Btu/gal):
Fuel % sulfur by weight:
Fuel sulfur content (ppm):

Detroit Diesel 3-71 Diesel Engine Emissions1

AP-42 Section 3.3 AP-42 Section 3.4


(<600 hp) 10/96 (>600 hp) 10/96 5-271(b) and Tier 12
Pollutant lb/Mmbtu tpy lb/Mmbtu tpy g/bhp-hr lb/Mmbtu
NOx 4.41 0.18 3.2 0.13 6.9 2.04
CO 0.95 0.04 0.85 0.03 8.5 2.51
PM 0.31 0.01 0.1 0.00 0.4 0.12
SO23 0.00 0.0001 0.00 0.0001 0.00
VOC4,5 0.36 0.01 0.08 0.0034 0.1
HAPs 6.45E-03 0.0003 1.57E-03 0.00
Total 0.25 0.17

Summary Diesel Engine Emissions1


AP-42 Section 3.3
(<600 hp) 10/96
Pollutant lb/Mmbtu tpy
NOx 4.41 1.08
CO 0.95 0.23
PM 0.31 0.08
SO23 0.00 0.0004
VOC4,5 0.36 0.09
HAPs 6.45E-03 0.0016
Total 1.47

1
Use the respective emission column above based on engine emission rating as described.
2
CO emissions for Tier 1 are based on Tier 1 value of 8.5 g/bhphr not the 5-271 value of 3.0 g/bhphr.
3
SO2 emis. based on AP-42 Sect.1.3 Fuel Oil Combustion (142(s)/1000 gallons where S= sulfur content as %)
4
VOC emissions for Tier 1 based on AP-42 Section 3.4 Large Stationary Diesel Engines (>600 hp) 10/96
5
VOC emissions for Tier 2 & 3 included in NOx emission factor

You must enter fuel usage, heating value and sulfur % above.
lbs/mmbtu = g/bhphr x 1lb/453.6g x 1hp/2545btu x 1,000,000 x efficiency.
If the fuel usage rate (gph) is known, the efficiency can be calculated.
Engine efficiency varies from unit to unit but 0.33 is typical and reasonable for most. Use 0.33 in cell D10 if the efficiency canno
SO2 lb/mmbtu is calculated from heating value and % sulfur using following equation:
lbs/mmbtu = (7.05 lbs/gal density x (S%/100) x 64/32) / 0.14 mmbtu/gal

Document QA/QC Information


Date: 9/1/2009
By: Steve

THIS WORKSHEET IS PROTECTED. TO MAKE


CHANGES TO FORMULAS YOU MUST UNPROTECT THE
DOCUMENT. A PASSWORD IS NOT NECESSARY.
l heating value (Btu/gal): 137,000
Fuel % sulfur by weight: 0.0015
uel sulfur content (ppm): 15

1(b) and Tier 12 5-271(c) and Tier 2 Tier3


tpy g/bhp-hr lb/Mmbtu tpy g/bhp-hr lb/Mmbtu tpy
0.45 4.8 1.56 0.32 3.0 0.98 0.20
0.56 2.6 0.85 0.17 2.6 0.85 0.17
0.03 0.15 0.05 0.01 0.15 0.05 0.01
0.00 0.00 0.00 0.00 0.00
0.02 na 0 na 0
1.57E-03 0.000
1.06 0.50 0.38

l heating value (Btu/gal): 137,000


Fuel % sulfur by weight: 0.0015
uel sulfur content (ppm): 15

1(b) and Tier 12 5-271(c) and Tier 2 Tier3


tpy g/bhp-hr lb/Mmbtu tpy g/bhp-hr lb/Mmbtu tpy
0.08 4.8 1.42 0.06 3.0 0.89 0.04
0.10 2.6 0.77 0.03 2.6 0.77 0.03
0.00 0.15 0.04 0.00 0.15 0.04 0.00
0.0001 0.00 0.0001 0.00 0.0001
0.0041 na 0.0000 na 0
0.20 0.09 0.07

ulfur content as %)
00 hp) 10/96

33 in cell D10 if the efficiency cannot be calculated.


Steven Snook:
Facility: Permit #: Date:
MC = (wet wt - OD wt)/(wet wt)*100%
Green~ 40%, Air dried ~20%, Kiln dried~10%
Enter non-wood fuel data for each unit at the facility in ORANGE cells of
Table 1 (column E). If the facility has a wood boiler, then use the cells
to the right of Table 1 (column G&H) and enter the needed wood
information (raw wood wt and %MC).

Table 1. Stationary Source Fuel Combustion


Estimated
Reported %MC for
Source Source Quantity
Fuel Combusted wood usage raw wood
ID Description Combusted Units (raw tons) fuel
S1 example wood boiler Wood and Wood Waste 1,333 0 2000 40.0%
Distillate Fuel Oil #2 332,000 gallons 0 10.0%
Natural Gas 48,200,000 scf 0 0.0%
0 0 0.0%
0 0 0.0%
0 0 0.0%
0 0 0.0%
0 0 0.0%
0 0 0.0%
0 0 0.0%
0 0 0.0%
0 0 0.0%
Table 2. Total Company-Wide Stationary Source Fuel Combustion
Quantity
Fuel Type Combusted Units
Distillate Fuel Oil #2 332,000 gallons
Distillate Fuel Oil #4 0 gallons
Residual Fuel Oil #5 0 gallons
Residual Fuel Oil #6 0 gallons
Natural Gas 48,200,000 scf
Kerosene 0 gallons
LPG 0 gallons
Propane 0 gallons For wood - the calculations
Wood and Wood Waste 0 tons are based on tons of
reserved for LFG or cowpowe 0 scf wood at 10% MC
Table 3. Total Company-wide CO2, CH4 and N2O Emissions from Stationary Source Fuel Combustion
CO2 CO2 CH4 CH4 N2O N2O
Fuel Type (kg) (lb) (kg) (lb) (kg) (lb)
Distillate Fuel Oil #2 3,388,551 7,470,468 137.4 303.0 27.5 60.6
Distillate Fuel Oil #4 0 0 0.0 0.0 0.0 0.0
Residual Fuel Oil #5 0 0 0.0 0.0 0.0 0.0
Residual Fuel Oil #6 0 0 0.0 0.0 0.0 0.0
Natural Gas 2,627,120 5,791,801 49.5 109.2 5.0 10.9
Kerosene 0 0 0.0 0.0 0.0 0.0
LPG 0 0 0.0 0.0 0.0 0.0
Propane 0 0 0.0 0.0 0.0 0.0
Total Fossil Fuel Emissions 6,015,671 13,262,269 187.0 412.3 32.4 71.5
Wood and Wood Waste 0 0 0.0 0.0 0.0 0.0
Reserved for LFG or cowpower
Total Non-Fossil Fuel Emissions 0 0 0.0 0.0 0.0 0.0
Total Emissions for all Fuels 6,015,671 13,262,269 187.0 412.3 32.4 71.5

File: file:///conversion/tmp/activity_task_scratch/727980201.xlsx Calculator Revision Date: 9/28/2010


Global Warming Potential CO2 CH4
N2O CO2e
1.0 21.0 310.0 metric ton short ton
Total CO2 Emissions - Equivalent (Fossil CO2e + Biogenic CH4 & N2O) 6,029.7 6,646.6
All CO2e emissions at stack (Fossil CO2e + Biogenic CO2e) - for APCD Permit info 6,029.7 6,646.6

File: file:///conversion/tmp/activity_task_scratch/727980201.xlsx Calculator Revision Date: 9/28/2010


APCD started with:
Climate Leaders' Version Notes:
Tool release date: July 1, 2008
Revised: April 15, 2010 Version 2.9
10%
Then we modified it to match emission factors in Part 98 of the Green
House Gases Mandatory reporting rule.
6/16/2011 - Conversion factor error found and corrected in cell D47.
4/2/2013 - Proposed rule changes include GWP factor edits: CH4=25,
N2O=298; when these changes are finalized, this spreadsheet will be
updated.

CHOICES FOR FUEL COMBUSTED


Distillate Fuel Oil #2
Distillate Fuel Oil #4
Residual Fuel Oil #5
Residual Fuel Oil #6
Natural Gas
Kerosene
LPG
Propane
Wood and Wood Waste

Future fuel consideration:


Landfill gas engines
Cowpower - manure digesters/engines
Part 98 emission factors (Tables C-1 and C-2 of Subpart C of Part 98):
Default High heat value Default Emission Factors (kg/m
Fuel type HHV units CO2 CH4
Distillate Fuel Oil #2 0.138 mmBtu/gal 73.96 0.0030
Distillate Fuel Oil #4 0.146 mmBtu/gal 75.04 0.0030
Residual Fuel Oil #5 0.140 mmBtu/gal 72.93 0.0030
Residual Fuel Oil #6 0.150 mmBtu/gal 75.10 0.0030
Natural Gas 0.001028 mmBtu/scf 53.02 0.0010
Kerosene 0.135 mmBtu/gal 75.20 0.0030
LPG 0.092 mmBtu/gal 62.98 0.0030
Propane 0.091 mmBtu/gal 61.46 0.0030
Wood and Wood Waste 15.38 mmBtu/short ton 93.80 0.032

File: file:///conversion/tmp/activity_task_scratch/727980201.xlsx Calculator Revision Date: 9/28/2010


on Factors (kg/mmBtu)
N2O
0.00060
0.00060
0.00060
0.00060
0.00010
0.00060
0.00060
0.00060
0.0042

File: file:///conversion/tmp/activity_task_scratch/727980201.xlsx Calculator Revision Date: 9/28/2010


H8: Steven Snook:
MC = (wet wt - OD wt)/(wet wt)*100%
Green~ 40%, Air dried ~20%, Kiln dried~10%

File: file:///conversion/tmp/activity_task_scratch/727980201.xlsx Calculator Revision Date: 9/28/2010

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