1- Action of atmospheric air Reaction with mineral acids

6Li + N2 ………… NaOH +………. NaCl +……..

Li3N + 3 H2O ……..+………. 2NaOH + H2SO4 ……….+ ……….
2- With water :-
2Na + H2O …………. + …….. Sodium carbonate:
3- With oxygen :- Preparation :
..Li +……. 2 LiO In industry ( Solvay )method :- By
Li2O + H2O …………… passing ammonia and carbon dioxide
2Na + O2 ……………. gases in a saturated aqueous solution of
K + O2 ……………… sodium chloride to produce sodium
4 KO2 + 2 CO2 …… + …… bicarbonate which will decompose by
4- With acids heating to sodium carbonate , Water and
2Na + 2 HCl …… + ……… carbon dioxide
5- With hydrogen:- NH3 + ……..+ NaCl + …….
2Li + H2 …………. ……….. + ………..
2Na + H2 …………
NaHCO3 ……….. + …….. +
6- With halogens :-
2Na + …….. 2NaCl …….
2K + Br2 ………….. Properties :
7- With other nonmetals :- Na2CO3 + 2 HCl …………+
2Na + S …………………. ………
3K + P ……………….. How can you prepare :
8- The action of heat on its oxygenated 1- Ammonia gas from lithium
salt :- 2- Sodium hydroxide by two methods
1000
Li2 CO3 ………+ 3- Potassium carbonates from potassium super
……… oxide
b) Alkaline metal nitrates decompose 4- Oxygen from potassium
partially 5- Ammonium chloride from ammonia
heat 6- Sodium meta aluminates from aluminum
2NaNO3 …………….. +
chloride
……… 7- Black copper oxide from copper sulphate
Detection of Aluminum Al+3 What is the effect of heat on each of the
ALCl3 + 3 NaOH ………….+ following :
……….. 1- Lithium carbonate
Al (OH) 3 + NaOH ……….+ 2- Sodium nitrate
3- Copper hydroxide
………. 4- Sodium bicarbonate
- Detection of copperII (Cu++) What is the action of :
CuSO4 +2Na OH …………+ 1- Atmospheric air on lithium
……… 2- Hydrochloric acid on sodium metal
3- Bromine on potassium
Cu (OH)2 ………… +
4- Hydrogen on lithium
………..
 By double substitution reaction
CO2 + 2 NH4 OH …………… +
………..
(NH4)2 CO3 + Ca SO4 ……..+………..
Preparation of phosphor nitrogenous
fertilizers
Orthophoshoric acid firstly is prepared by :
Ca3(PO4)2 + 3 H2SO4 ……….+ ……..
Properties of nitrogen Then
1- With hydrogen: 3NH3 + H2 PO4 …………….

N2 + 3 H2 ……………. Preparation of nitric acid in lab

2- With Oxygen : 2KNO3 + H2 SO4 ………….. +……..
Action of heat
N2 + O2 ……………….. 4HNO3 ……..+………. +……….
3- With metals : Action of acid on metals
Fe + 4HNO3 ………….+……+
3Mg + N2 …………………….. ………
3Cu +8HNO3 ……….+……… +
Mg3N2 + 6H2O ………….+………. ………..
4- With calcium carbide : Cu + 4 HNO3 ………..+………+
……….
CaC2 + N2 ………… +………….. Detection of nitrate ion (NO3)-
2Na NO3 + 6FeSO4 + 4H2SO4
CaCN2 + 3H2O → …………+ ………… ……………. +……… + ……….. +………..
The nitrogenous compounds FeSO4 +NO …………………
1- Ammonia gas NH3 To differentiate between nitrite and
nitrate salts
Can be prepared in lab By the action of 5KNO2 + 2KMnO4 + 3H2SO4 → ………… +
heat on a mixture of ammonium chloride ………….. + …………..+ ………..
and slaked lime Important questions
4NH4 Cl + Ca (OH)2 ……….. + ……+ …….. How can you obtain
Ammonia can prepared in industry 1- Ammonia from calcium carbide
2- Ammonia from ammonium chloride
N2 + 3H2 ……………. 3- Ammonia from nitrogen
Detection of ammonia gas 4- Nitric acid from potassium nitrate
It gives dense white fumes of ammonium How can you differentiate between
chloride when subjected to a glass rod 1- Conc. Nitric acid and dilute nitric acid
wetted with conc. Hydrochloric acid 2- Iron and copper by using nitric acid
NH3 + HCl → …………….
3- Dil. Nitric acid and dil. Sulphuric acid by
Ammonia is an alkaline. using iron filings
NH3 + H2O →…………………
Haber's method 4- Sodium nitrate and sodium nitrite solution
Ammonia gas can be prepared 5- Nitrogen gas and ammonia gas
Detection of ammonia gas What is the effect of heat on each of
N2 + 3H2 Fe / Mo …………. 1- Nitric acid
500/200 2- The mixture of ammonium chloride and
NH3 + HCl …………….
Inorganic nitrogenous salts calcium hydroxide
NH3 + HNO3 →………………. What is the reaction of nitrogen with
2 NH3 + H2So4 → ………………. 1- Oxygen
 2- Hydrogen
3- Magnesium
4- Calcium carbide
What is the effect of water on the following
1- Magnesium nitride
2- Calcium Cyanamid
3- Ammonia gas
What is the reaction of ammonia with
1- Nitric acid
2- Sulphuric acid
3- Phosphoric acid