SAFETY DATA SHEET

1. Identification
Product identifier Pyro-Chem ABC 90
Other means of identification
Product code ABC 90
Recommended use Class A, B and C fire extinguishing dry chemical powder.
Recommended restrictions None known.
Manufacturer/Importer/Supplier/Distributor information
Company name Hasta-Mex S.A. de C.V
División del Golfo
Address 3308 La libertad
Victoria, Tamaulipas
C.P. 87019
Mexico

Contact person EH&S Manager

Telephone +52 (834) 318-7500
E-mail MariaDelSol.Garcia@kidde.com.mx

Emergency phone number +52 (834) 318-7502

2. Hazard(s) identification
Physical hazards Not classified.

Health hazards Not classified.

OSHA defined hazards Not classified.

Label elements
Hazard symbol None.
Signal word None.
Hazard statement The mixture does not meet the criteria for classification.
Precautionary statement
Prevention Observe good industrial hygiene practices.
Response Get medical advice/attention if you feel unwell.
Storage Store away from incompatible materials.
Disposal Dispose of waste and residues in accordance with local authority requirements.
Hazard(s) not otherwise None known.
classified (HNOC)
Supplemental information None.

3. Composition/information on ingredients
Mixtures
Chemical name CAS number %
Calcium carbonate 471-34-1 1-3

Mica 12001-26-2 1-2.5

Silicon dioxide, crystalline 7631-86-9 0.5-1

silica-free

Pyro-Chem ABC 90 SDS US

905293 Version #: 01 Revision date: - Issue date: 30-September-2016 1/7
Composition comments
4. First-aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important
symptoms/effects, acute and
delayed
Indication of immediate
medical attention and special
treatment needed
General information
5. Fire-fighting measures
Suitable extinguishing media
Unsuitable extinguishing
media
Specific hazards arising from
the chemical
Special protective equipment
and precautions for firefighters
Fire fighting
equipment/instructions
Specific methods
General fire hazards
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Methods and materials for
containment and cleaning up
Environmental precautions
7. Handling and storage
Precautions for safe handling
Conditions for safe storage,
including any incompatibilities
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components
Calcium carbonate (CAS
471-34-1)
Pyro-Chem ABC 90
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All concentrations are in percent by weight unless otherwise indicated.
Components not listed are either non-hazardous or are below reportable limits.
Dust irritates the respiratory system, and may cause coughing and difficulties in breathing. If
symptomatic, move to fresh air. Get medical attention if symptoms persist.
Contact with dust: Wash area with soap and water. Get medical attention if irritation develops or
persists.
Dust in the eyes: Do not rub eyes. Flush thoroughly with water. If irritation occurs, get medical
assistance.
Rinse mouth thoroughly with water. Get medical attention if symptoms occur.
Dusts may irritate the respiratory tract, skin and eyes.
Provide general supportive measures and treat symptomatically.
Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.
No specific measures are required as this product is a fire extinguishing medium.
None known.
Not a fire hazard.
Self-contained breathing apparatus, operated in positive pressure mode and full protective clothing
must be worn in case of fire.
No specific precautions.
Use standard firefighting procedures and consider the hazards of other involved materials.
Product is an extinguishing medium. It does not burn or support combustion.
Keep unnecessary personnel away. Wear appropriate protective equipment and clothing during
clean-up. Avoid inhalation of dust and contact with skin and eyes. Use a NIOSH/MSHA approved
respirator if there is a risk of exposure to dust/fume at levels exceeding the exposure limits. For
personal protection, see Section 8 of the SDS.
Avoid the generation of dusts during clean-up. Sweep, shovel, or vacuum up spillage and collect in
suitable container for disposal. Vacuums used for this purpose should be equipped with HEPA
filters. Following product recovery, flush area with water.
Avoid discharge to the aquatic environment.
Use work methods which minimize dust production. Use only in well-ventilated areas. Avoid
inhalation of dust and contact with skin and eyes. Avoid prolonged exposure. Wear appropriate
personal protective equipment. Wash hands after handling. Observe good industrial hygiene
practices.
Store in original tightly closed container. Store in a cool, dry, well-ventilated place. Store away from
incompatible materials (see Section 10 of the SDS).
Type Value Form
PEL 5 mg/m3 Respirable fraction.
15 mg/m3 Total dust.
SDS US
Issue date: 30-September-2016 2/7
 US. OSHA Table Z-3 (29 CFR 1910.1000)

Components Type Value

Mica (CAS 12001-26-2) TWA 20 mppcf
Silicon dioxide, crystalline TWA 0.8 mg/m3
silica-free (CAS 7631-86-9)
20 mppcf
US. ACGIH Threshold Limit Values

Components Type Value Form

Mica (CAS 12001-26-2) TWA 3 mg/m3 Respirable fraction.
US. NIOSH: Pocket Guide to Chemical Hazards

Components Type Value Form

Calcium carbonate (CAS TWA 5 mg/m3 Respirable.
471-34-1)
10 mg/m3 Total
Mica (CAS 12001-26-2) TWA 3 mg/m3 Respirable.
Silicon dioxide, crystalline TWA 6 mg/m3
silica-free (CAS 7631-86-9)
Biological limit values No biological exposure limits noted for the ingredient(s).
Appropriate engineering Provide sufficient ventilation for operations causing dust formation. Observe occupational
controls exposure limits and minimize the risk of exposure.
Individual protection measures, such as personal protective equipment
Eye/face protection Unvented, tight fitting goggles should be worn in dusty areas.
Skin protection
Hand protection It is a good industrial hygiene practice to minimize skin contact. For prolonged or repeated skin
contact use suitable protective gloves.
Skin protection
Other Wear suitable protective clothing. It is a good industrial hygiene practice to minimize skin contact.
Respiratory protection In case of inadequate ventilation or risk of inhalation of dust, use a suitable NIOSH approved
respirator with an appropriate particulate filter. Recommended use: Use respiratory equipment with
particle filter, type N95.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene Handle in accordance with good industrial hygiene and safety practice. Routinely wash work
considerations clothing and protective equipment to remove contaminants.

9. Physical and chemical properties

Appearance
Physical state Solid.
Form Fine powder.
Color Various.
Odor Slightly pungent.
Odor threshold Not available.
pH 4.5 (5% aqueous solution)
Melting point/freezing point Not available.
Initial boiling point and boiling Not available.
range
Flash point Not applicable.
Evaporation rate Not applicable.
Flammability (solid, gas) Product is an extinguishing media. It does not burn or support combustion.
Upper/lower flammability or explosive limits
Flammability limit - lower Not applicable.
(%)
Pyro-Chem ABC 90 SDS US
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 Flammability limit - upper Not applicable.
(%)
Vapor pressure Not applicable.
Vapor density Not applicable.
Relative density 1.8 (68 °F (20 °C))
Solubility(ies)
Solubility (water) Soluble in water.
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature Not applicable.
Decomposition temperature 356 °F (180 °C)
Viscosity Not applicable.
Other information
Bulk density 900 kg/m3
Explosive limit Not applicable.

10. Stability and reactivity

Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Stable under normal temperature conditions.
Possibility of hazardous No dangerous reaction known under conditions of normal use.
reactions
Conditions to avoid Contact with incompatible materials.
Incompatible materials Strong acids. Strong bases. Strong oxidizing agents. Alkali metals. Magnesium. Water.
Hazardous decomposition Ammonia. Oxides of phosphorus. Carbon oxides.
products

11. Toxicological information

Information on likely routes of exposure
Inhalation Dust may irritate respiratory system.
Skin contact Dust or powder may irritate the skin.
Eye contact Dust may irritate the eyes.
Ingestion May be harmful if swallowed in large quantities.
Symptoms related to the Dusts may irritate the respiratory tract, skin and eyes.
physical, chemical and
toxicological characteristics
Information on toxicological effects
Acute toxicity May be harmful if swallowed in large quantities.
Product Species Test Results
Pyro-Chem ABC 90 (CAS Mixture)
Acute
Oral
LD50 Rat > 4250 mg/kg
Components Species Test Results
Calcium carbonate (CAS 471-34-1)
Acute
Oral
LD50 Rat 6450 mg/kg
Silicon dioxide, crystalline silica-free (CAS 7631-86-9)
Acute
Dermal
LD50 Rabbit > 5000 mg/kg, 24 Hours

Pyro-Chem ABC 90 SDS US

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Components
Inhalation
LC50
Oral
LD50
Skin corrosion/irritation
Serious eye damage/eye
irritation
Respiratory or skin sensitization
Respiratory sensitization
Skin sensitization
Germ cell mutagenicity
Carcinogenicity
IARC Monographs. Overall Evaluation of Carcinogenicity
Silicon dioxide, crystalline silica-free (CAS 7631-86-9)
NTP Report on Carcinogens
Not listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
Reproductive toxicity
Specific target organ toxicity -
single exposure
Specific target organ toxicity -
repeated exposure
Aspiration hazard
Chronic effects
Further information
12. Ecological information
Ecotoxicity
Components
Calcium carbonate (CAS 471-34-1)
Aquatic
Acute
Fish
Persistence and degradability
Bioaccumulative potential
Mobility in soil
Other adverse effects
13. Disposal considerations
Disposal instructions
Local disposal regulations
Hazardous waste code
Waste from residues / unused
products
Contaminated packaging
Pyro-Chem ABC 90
905293 Version #: 01 Revision date: -
Species Test Results
Rat > 0.14 mg/l, 4 Hours
Rat > 3300 mg/kg
Dust may irritate skin.
Dust in the eyes will cause irritation.
Not a respiratory sensitizer.
Not a skin sensitizer.
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
3 Not classifiable as to carcinogenicity to humans.
This product is not expected to cause reproductive or developmental effects.
Not classified.
Not classified.
Not an aspiration hazard.
Frequent inhalation of dust over a long period of time increases the risk of developing lung
diseases. Prolonged and repeated overexposure to dust can lead to pneumoconiosis.
Pre-existing skin and respiratory conditions including dermatitis, asthma and chronic lung disease
might be aggravated by exposure.
The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Species Test Results
LC50 Mosquitofish (Gambusia affinis affinis) > 56000 mg/l
The product contains inorganic compounds which are not biodegradable.
The product is not expected to bioaccumulate.
The product is soluble in water. Expected to be mobile in soil.
None known.
Collect and reclaim or dispose in sealed containers at licensed waste disposal site.
Dispose in accordance with all applicable regulations.
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
SDS US
Issue date: 30-September-2016 5/7
14. Transport information
DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
Transport in bulk according to Not established.
Annex II of MARPOL 73/78 and
the IBC Code

15. Regulatory information

US federal regulations This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard
Communication Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - No
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous No
chemical
SARA 313 (TRI reporting)
Chemical name CAS number % by wt.
Ammonium dihydrogenphosphate 7722-76-1 >92
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
US state regulations
US. Massachusetts RTK - Substance List
Calcium carbonate (CAS 471-34-1)
Mica (CAS 12001-26-2)
Silicon dioxide, crystalline silica-free (CAS 7631-86-9)
US. New Jersey Worker and Community Right-to-Know Act
Calcium carbonate (CAS 471-34-1)
Mica (CAS 12001-26-2)
Silicon dioxide, crystalline silica-free (CAS 7631-86-9)
US. Pennsylvania Worker and Community Right-to-Know Law
Calcium carbonate (CAS 471-34-1)
Mica (CAS 12001-26-2)
Silicon dioxide, crystalline silica-free (CAS 7631-86-9)
US. Rhode Island RTK
Not regulated.
US. California Proposition 65
Not Listed.
Pyro-Chem ABC 90 SDS US
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International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Chemical Substances (AICS) Yes
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) Yes
Europe European Inventory of Existing Commercial Chemical No
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) No
Korea Existing Chemicals List (ECL) Yes
New Zealand New Zealand Inventory Yes
Philippines Philippine Inventory of Chemicals and Chemical Substances Yes
(PICCS)
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory No
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

16. Other information, including date of preparation or last revision

Issue date 30-September-2016
Revision date -
Version # 01
HMIS® ratings Health: 1
Flammability: 0
Physical hazard: 0
NFPA ratings
0
1 0

Disclaimer This information is based on our current knowledge and is believed to be correct as of the date
issued. The information is intended to describe the product for the purposes of health, safety and
environmental requirements only and no warranty, express or implied, is made. It should also not
be construed as guaranteeing any specific property of the product. In addition, information
obtained from a database is subject to change and may not be as current as the information in the
SDS available directly from UTCFS.

Pyro-Chem ABC 90 SDS US

905293 Version #: 01 Revision date: - Issue date: 30-September-2016 7/7