I.T.

S TUTORIALS{We Promise Success}

CHEMISTRY NUMERICAL FINAL PRACTICE

EMPIRICAL AND MOLECULAR FORMULA

Q1)An organic compound contains 40% of carbon , 6.67 % of hydrogen and rest oxygen. If its
molecular weight is 180 find its molecular formula. [ C6H12O6]

Q2)Find the molecular formula of a compound of V.D 22 if 4.4 gms of it contains 2.4 gms of carbon
and 2 gms of hydrogen . [ C2H20 ]

Q3)Empirical formula of a compound is XY2. If its empirical formula weight is equal to its V.D find
the molecular formula of the compound [X2Y4]

Q4)A hydrocarbon of V.D 28 contains 14.29% hydrogen . Find its molecular formula. [ C4 H8 ]

Q5) 4 grams of a metallic chloride contains 1.89 gms of metal X. Calculate the empirical formula

At wt of X=65 , Cl =35.5 [ XCl2 ]

Q6)An organic compound contains 54.54% of carbon , 9.09% of hydrogen and 36.36% oxygen. If its
molecular weight is 88 find its molecular formula. [ C4H8O2]

MOLE CONCEPT

Q7)Find the number of moles in 7 grams of nitrogen . [ 0.25 ]

Q8)Find the number of moles in (i) 25 gms of HCl (ii) 100 gms of KMnO4 . [ 0.685 , 0.633]

Q9)How many grams are present in (i) 0.5 moles of sulphuric Acid (ii) 10 moles of ammonia [49,170]

Q10)Find the volume occupied by (i) 100 grams of O2 (ii) 12.046 x 1023 molecules of H2 [ 70 , 44.8 ]

Q11)How many atoms of O2 are there in (i)32 g of O2 (ii) 66 g of CO2 [12.046 x 1023 , 9.03 x 1023 ]

Q12)Calculate volume occupied by a single molecule of carbon dioxide at STP. [7.305 x 10-23]

Q13)Calc. wt of (i) 1atom of C(ii) 0.1 gm atom of Ag (iii)0.56 mole of NH3 [1.99 x10-23 ,10.8 , 9.52]

Q14) (i) How many gram atoms of the magnesium are equal to 18 g ?

(ii) How many gram atoms of nitrogen are equal to 7 gram of it ? [ 0.75 , 0.5 ]

Q15)A flask contains 3.2 gms of sulphur dioxide .Calculate the following

(i) moles of SO2 in the flask (ii) number of molecules of SO2 (iii) volume occupied by SO2
[ 0.05 , 3.0115 x 1022 , 1.12 ]

CALCULATIONS BASED ON CHEMICAL EQUATIONS

Q15)Find the volume of oxygen required at S.T.P when 11.2 liters of ethane burns completely, all
measurements being at S.T.P . 2C2H6 + 7 O2  4 CO2 + 6 H2O [[39.2 l]

Q16) 2 C2H2 + 7 O2  4 CO2 + 6 H2 O

Calculate vol of oxygen required to react with 20 cc of ethane and vol of CO2 produced.[ 70 , 11.43 ]
Q17) 4 FeS2 + 11 O2  2 Fe2O3 + 8 SO2

5.6 dm3 of SO2 is produced at STP . Find (i) moles of SO2 formed (ii) moles of O2 required (iii) weight
of O2 required (iv) moles of Fe2O3 formed (v) wt of Fe2O3 formed [ 0.25 , 0.34 , 11 , 0.0625 , 10 ]

Q18)From the equation 2NaHCO3 ------ Na2CO3 + H2O + CO2

Find (i) mass of Na2CO3 produced (ii) vol of CO2 When 8.4 g of NaHCO3 was heated [ 5.3 , 1.12 ]

Q19) N2 + 3 H2  2 NH3 Find vol of ammonia formed when 200 lit of H2 was used [ 133.33 ]

Q20) C + 2H2SO4  CO2 + 2H2O + 2SO2

Calculate (i) the mass of carbon oxidized by 49 g of sulphuric acid (ii) The volume of sulphur dioxide
measured at S.T.P liberated at the same time [ 3 , 11.2 ]

Q21) 3CuO + 2NH3  3Cu + N2 + 3H2O

Given that the relative molecular mass of copper oxide is 80 what volume of ammonia is
required to completely reduce 120 g of copper oxide ? [ 22.4 ]

VAPOUR DENSITY

Q22)1.12 liters of hydrogen is found to weigh 0.10 g whereas the same volume of gas X at the same
temperature and pressure is found to weigh 2.2 g .Find the vapour density of the gas. [ 22 ]

Q23)The atomic weight of chlorine is 35.5 .What is the V.D of chlorine gas. [ 35.5 ]

Q24)A cylinder when filled with a gas weighs 85 g and when filled with hydrogen weighs 5 g. Find
V.D of the gas [17]

Q25)250 ml of a gas weighs 3.6 g at STP. Find the molecular weight ( 1 lit of H2=0.09g) [320]

Q26) A gas at a pressure of 700 mm and at 57 degrees occupies 700 ml. If at STP the mass of the gas
is 1.5 g find vapour density and molecular weight of the gas. [ 1 litre of H2 weighs 0.09 g][31.25,62.5]

PERCENTAGE COMPOSITION

Q27)Find the % of water of crystallization in CuSO4.5H2O . [ 36.07%]

Q28)Calculate the % composition of the underlined atoms in (a)NH4NO3(b) (NH4)2Cr2O7[60%,11.2%]

Q29)Calculate the % of aluminium in 10 Kg of ore which contain 90 % of pure Al2O3. [ 47.64%]

Q30)Calculate the weight of nitrogen supplied to soil by a quintal of ammonium nitrate [ 35 Kg ]

Q31)Which is a better fertilizer Urea or ammonium sulphate [Urea]

Q32)Complete the table :

Gas Weight Volume Molecules

Oxygen 8g V x
CO2 ? 2V ?
At. Wts : [ Pb=207 , O=16,C=12 , S=32 ,Cu=63.5 , N=14 , H=1 , Fe =56 ,

Na =23 , Mn=55,Ca=40, Al=27, Cl=35.5 , Cr=52 ]