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  • Taller 3 Ejerccio 4

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    Roxana
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    The document describes two redox reactions involving vanadium and tin ions in the first reaction, and iron and chromium ions in the second. Concentration and volume data is provided for each reaction, along with measured electrode potentials. Graphs are shown plotting the electrode potentials vs. volume of the reduced species for each reaction. The data is consistent with oxidation-reduction reactions occurring between the species.

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    The document describes two redox reactions involving vanadium and tin ions in the first reaction, and iron and chromium ions in the second. Concentration and volume data is provided for each reaction, along with measured electrode potentials. Graphs are shown plotting the electrode potentials vs. volume of the reduced species for each reaction. The data is consistent with oxidation-reduction reactions occurring between the species.

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    © All Rights Reserved
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    9 views5 pages

    Taller 3 Ejerccio 4

    Uploaded by

    Roxana
    The document describes two redox reactions involving vanadium and tin ions in the first reaction, and iron and chromium ions in the second. Concentration and volume data is provided for each reaction, along with measured electrode potentials. Graphs are shown plotting the electrode potentials vs. volume of the reduced species for each reaction. The data is consistent with oxidation-reduction reactions occurring between the species.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    of 5

    EJERCICIO REDOX

    C1V1=C2V2
    C1 vanadio 0.1 M E°= -0.255
    V1 vanadio 50 ml
    C2 estaño 0.05 M E°= 0.154
    V2 ?
    V2 estaño 50 mL
    GRÁFICA
    mL Sn4+ V2+ V3+ Sn4+ Sn2+ mL Sn4+ E
    1 4.9 0.1 1 -0.35505961
    2 4.8 0.2 2 -0.33670851
    3 4.7 0.3 3 -0.32574261
    4 4.6 0.4 4 -0.31779331
    5 4.5 0.5 5 -0.31149116
    6 4.4 0.6 6 -0.30622584
    7 4.3 0.7 7 -0.30167153
    8 4.2 0.8 8 -0.29763343
    9 4.1 0.9 9 -0.29398565
    10 4 1 10 -0.29064195
    11 3.9 1.1 11 -0.28754058
    12 3.8 1.2 12 -0.28463566
    13 3.7 1.3 13 -0.2818921
    14 3.6 1.4 14 -0.27928233
    15 3.5 1.5 15 -0.27678423
    16 3.4 1.6 16 -0.27437965
    17 3.3 1.7 17 -0.27205345
    18 3.2 1.8 18 -0.26979275
    19 3.1 1.9 19 -0.2675864
    20 3 2 20 -0.2654246
    21 2.9 2.1 21 -0.26329858
    22 2.8 2.2 22 -0.26120033
    23 2.7 2.3 23 -0.25912245
    24 2.6 2.4 24 -0.25705792
    25 2.5 2.5 25 -0.255
    26 2.4 2.6 26 -0.25294208
    27 2.3 2.7 27 -0.25087755
    28 2.2 2.8 28 -0.24879967
    29 2.1 2.9 29 -0.24670142
    30 2 3 30 -0.2445754
    31 1.9 3.1 31 -0.2424136
    32 1.8 3.2 32 -0.24020725
    33 1.7 3.3 33 -0.23794655
    34 1.6 3.4 34 -0.23562035
    35 1.5 3.5 35 -0.23321577
    36 1.4 3.6 36 -0.23071767
    37 1.3 3.7 37 -0.2281079
    38 1.2 3.8 38 -0.22536434
    39 1.1 3.9 39 -0.22245942
    40 1 4 40 -0.21935805
    41 0.9 4.1 41 -0.21601435
    42 0.8 4.2 42 -0.21236657
    43 0.7 4.3 43 -0.20832847
    44 0.6 4.4 44 -0.20377416
    45 0.5 4.5 45 -0.19850884
    46 0.4 4.6 46 -0.19220669
    47 0.3 4.7 47 -0.18425739
    48 0.2 4.8 48 -0.17329149
    49 0.1 4.9 49 -0.15494039
    49.5 0.05 4.95 49.5 -0.1368584
    49.7 0.03 4.97 49.7 -0.12362128
    49.9 0.01 4.99 49.9 -0.09527245
    50 0 5 50 0.01766667
    51 0.05 2.5 51 0.10371049
    52 0.1 2.5 52 0.11262098
    53 0.15 2.5 53 0.11783328
    54 0.2 2.5 54 0.12153146
    55 0.25 2.5 55 0.1244
    GRÁFICA

    0.2

    0.1

    0
    0 10 20 30 40 50 60

    -0.1

    -0.2

    -0.3

    -0.4
    CIVI=C2V2
    V1 Fe(CN)3- 50 E° fe(CN) 0.36
    C1 Fe(CN)3- 0.1 E° Cr -0.408
    C2 Cr2+ 0.1
    V2 50

    GRÁFICA
    mL cr 2+ Fe(CN)6^3- Fe(CN)6^4- Cr3+ Cr2+ mL Cr2+ E
    2 4.8 0.1 2 0.26047052
    4 4.6 0.3 4 0.28981031
    6 4.4 0.5 6 0.30408663
    8 4.2 0.7 8 0.31393345
    10 4 0.9 10 0.32164921
    12 3.8 1.1 12 0.32812726
    14 3.6 1.3 14 0.33381234
    16 3.4 1.5 16 0.33896105
    18 3.2 1.7 18 0.3437377
    20 3 1.9 20 0.34825663
    22 2.8 2.1 22 0.35260363
    24 2.6 2.3 24 0.35684787
    26 2.4 2.5 26 0.36104954
    28 2.2 2.7 28 0.36526531
    30 2 2.9 30 0.36955299
    32 1.8 3.1 32 0.37397648
    34 1.6 3.3 34 0.37861212
    36 1.4 3.5 36 0.38355805
    38 1.2 3.7 38 0.38895001
    40 1 3.9 40 0.39499102
    42 0.8 4.1 42 0.40201388
    44 0.6 4.3 44 0.41063478
    46 0.4 4.5 46 0.42222823
    48 0.2 4.7 48 0.44116722
    49 0.1 4.8 49 0.45952948
    49.5 0.05 4.85 49.5 0.47761689
    49.7 0.03 4.87 49.7 0.49085614
    50 0 4.9 0.01 5 50 -0.256
    52 0.02 5 52 -0.33702098
    54 0.03 5 54 -0.34223328
    56 0.04 5 56 -0.34593146
    58 0.05 5 58 -0.3488
    60 0.06 5 60 -0.35114376
    GRAFICA

    0.6

    0.5

    0.4

    0.3

    0.2

    0.1

    0
    0 10 20 30 40 50 60 70
    -0.1

    -0.2

    -0.3

    -0.4

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