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P.KATHIRVEL, M.Sc, B.Ed, P.G. TEACHER IN CHEMISTRY, GBHSS - ANTHIYUR, ERODE(Dt). Cell - 9150550110
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P.KATHIRVEL, M.Sc, B.Ed, P.G. TEACHER IN CHEMISTRY, GBHSS - ANTHIYUR, ERODE(Dt). Cell - 9150550110
116
The cleansing action of soap is directly related to the structure of palmitate ion
The structure of palmitate exhibit dual polarity
1. Polar - Carboxyl portion (hydrophilic). It is soluble in water.
2. Non polar - Hydrocarbon portion (hydrophobic). It is soluble in oils and greases
When the soap is added to an grease part of the cloth. The hydrocarbon part dissolve
in the grease, leaving the carboxylate end exposed on the grease surface.
At the same time the carboxylate groups are strongly attracted by water,
thus leading to the formation of small droplets called micelles
When the water is rinsed away the grease goes with it.
As a result, the cloth gets free from dirt and the droplets are washed away with water.
20. Write a note on vulcanization of rubber
Natural rubber is mixed with 3-5% sulphur and heated at 100-150˚C causes cross
linking of the cis-1,4-polyisoprene chains through disulphide (-S-S-) bonds.
The properties of natural rubber can be modified by the process called vulcanization.
1 to 3% sulphur rubber is soft and stretchy
3 to 10% sulphur rubber is harder but flexible.
21. Write a note on co –polymer.
A polymer containing two or more different kinds of monomer units is called a co-polymer
Buna –S, Buna –N
P.KATHIRVEL, M.Sc, B.Ed, P.G. TEACHER IN CHEMISTRY, GBHSS - ANTHIYUR, ERODE(Dt). Cell - 9150550110
117
Uses - blending with wool fibres and as glass reinforcing materials in helmets.
30. Preparation of Nylon 6,6
Hexamethylene diamine + Adipic acid Nylon 6,6
P.KATHIRVEL, M.Sc, B.Ed, P.G. TEACHER IN CHEMISTRY, GBHSS - ANTHIYUR, ERODE(Dt). Cell - 9150550110