M.

Prakash Institute F1 Advance Solutions

Matrices and Determinants 28 Jan 2024
Answer Key
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19
D B C A BCD ABCD AD 1 4 1 1 4 7 0 8 1 10 3 18

1
5

2
9

10

11

12

3
13

14

15

16

17

18

19

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MPI CHEMISTRY 28/JAN/2024

Answer key & solutions:

20=C 21=A 22=B 23=A 24=C 25=ABCD 26=BCD 27=1 28=4 29=2
30=4 31=3 32=8 33=13 34=14 35=6 36=6 37=4 38=0

Solution

32. 8

G.I. =2
O.I. = 2

G.I. =2 G.I. =2

34. 14

36. 6

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MPI CHEMISTRY 28/JAN/2024

Br
Br

O.I. = 2

Br
Br
O.I. = 2
38. The organic compound C3 H 2 Cl2 has zero geometrical and six optical isomers (four open
chain as allen and two cyclic due to chiral atom).
H H H H Cl
Cl
C C C C C C C C C
Cl Cl H H Cl
Cl
O.I. = 2 O.I. = 2 O.I. = 0

O.I. = 0 O.I. = 2 O.I. = 0

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 M. Prakash Institute
Answer Key:

Q39 Q40 Q41 Q42 Q43 Q44 Q45 Q46 Q47 Q48
A B A C A,B,C,D B,C,D C 4.00 3.00 2.00
Q49 Q50 Q51 Q52 Q53 Q54 Q55 Q56 Q57
9.00 6.00 9.00 0.50 1.25 0.25 0.50 1.00 0.75

Solutions:

39
𝑀= 4𝜋𝑟 𝑑𝑟 × 𝜌 = 4𝜋𝑟 × 𝜌 𝑒 𝑑𝑟

Substitute 𝛼𝑟 = 𝑡

3𝛼𝑟 𝑑𝑟 = 𝑑𝑡

Limits for 𝑡 are 0 to 𝛼𝑅 .

4𝜋𝜌 4𝜋𝜌
𝑀= 𝑒 𝑑𝑡 = 1−𝑒
3𝛼 3𝛼

4𝜋𝜌
𝑔(𝑟) = 𝐺 1−𝑒
3𝛼𝑅
40

41
42 ( ) ( )
𝐸 = , 𝐸 = , = = 3V/m

𝑟 = √3𝑟
3𝑘𝑄 3𝑘𝑄
𝑉 = = = √3 × 7
𝑟 √3𝑟
43

44
1 2𝐺𝑀𝑚
𝑚𝑣 − =0
2 𝑅

𝐺𝑀
𝑣=2
𝐿
45

46
47
1 𝐺𝑀𝑚 𝐺(2𝑀)𝑚 𝐺𝑀𝑚 𝐺(2𝑀)𝑚
𝑚𝑣 − − =− −
2 𝑅 5𝑅 4𝑅 2𝑅
Work done equals change in kinetic energy.
1 3 𝐺𝑀𝑚
𝑊 = 𝑚𝑣 =
2 20 𝑅
48

49
50

51
52

53

54
&
55

56
&
57