M.

Prakash Institute
STD XI

Test-27 Mains F1 Batch 27/1/2024

Marking Scheme

Sec 1: 20 questions Single Choice 4, -1

Sec 2: 5/10 questions Numerical Type 4, 0

Syllabus

Maths Chemistry Physics

11th - Batch F1 - Test - Mains - Matrices and Determinants - 27 Jan 2024

Section I - Single Option correct - 20 questions

" #
1 2
1. If A = , then An is equal to
0 1
" # " # " # " #
1 2n 2 n 1 2n 1 n
(A) (B) (C) (D) .
0 1 0 1 0 −1 0 1
 
cos α − sin α 0
2. Let F (α) =  sin α cos α 0  ,
 

0 0 1
 
cos β 0 sin β
G(β) =  0 1 0   , then [F (α)G(β)]−1 is equal to


− sin β 0 cos β
(A) F (α) − G(β) (B) −F (α) − G(β)
−1 −1
(C) [F (α)] [G(β)] (D) [G(β)]−1 [F (α)]−1 .
" # " #−1 " #
1 − tan θ 1 tan θ a −b
3. If = , then
tan θ 1 − tan θ 1 b a
(A) a = 1, b = 1 (B) a = cos θ, b = sin θ
(C) a = sin 2θ, b = cos 2θ (D) a = cos 2θ, b = sin 2θ.
" # " #
a b 2 α β
4. If A = ,A = , then
b a β α
(A) α = a2 + b2 , β = ab (B) α = a2 + b2 , β = 2ab
(C) α = a2 + b2 , β = a2 − b2 (D) α = 2ab, β = a2 + b2 .
 
0 0 −1
 0 −1 0  , then
5. If A =  

−1 0 0
(A) A is zero matrix (B) A2 = 1
(C) A−1 does not exist (D) A = (−1)I.
   
1 −1 1 4 2 2
 and A−1 =
1 
6. If A =  2 1 −3 

10 
−5 0 α ,
1 1 1 1 −2 3
then α =
(A) −2 (B) 5 (C) 2 (D) −1.

7. If A2 − A + I = 0, then A−1 =
(A) A (B) A + I (C) I − A (D) A − I.

1
 " # " #
1 2 a 0
8. Let A = and B = , a, b ∈ N, then
3 4 0 b
(A) there exists exactly one B such that AB = BA
(B) there exist infinitely many B 0 s such that AB = BA
(C) there cannot exist any B such that AB = BA
(D) there exist more than 1 but finite number of B 0 s such that
AB = BA.
" #
3
−1
9. If A = 2 , then A3 =
− 21 1
2
A A I
(A) 4
(B) 8
(C) 4
(D) I8 .
" #
1 0
10. If A = , then An =
1 1
(A) 2n−1 A − (n − 1)I (B) nA − (n − 1)I
(C) 2n−1 A + (n − 1)I (D) nA + (n − 1)I.

pa qb rc
11. If p + q + r = 0 = a + b + c, then the value of the determinant qc ra pb is
rb pc qa
(A) 0 (B) pa + qb + rc (C) 1 (D) None of these

12. |A3×3 | = 3, |B3×3 | = −1 and |C2×2 | = +2 then |2ABC| =

(A) 23 (6) (B) 23 (−6) (C) 2(−6) (D) None of these

13. If a determinant of order 3×3 is formed by using the numbers 1 or -1 then minimum
value of determinant is
(A) -2 (B) -4 (C) 0 (D) -8

14. If A is a diagonal matrix of order 3 × 3 is commutative with every square matrix of

order 3 × 3 under multiplication and trace (A) = 12, then
(A) |A| = 64 (B) |A| = 16 (C) |A| = 12 (D) |A| = 0
" # " # " #
2 1 −3 2 1 0
15. If A = , then A =
3 2 5 −3 0 1
" # " # " # " #
1 1 1 1 1 0 1 1
(A) (B) (C) (D) −
1 0 0 1 1 1 1 0

16. The homogeneous system of equations

 
2 a+b+c+d ab + cd
 a+b+c+d 2(a + b)(c + d) ab(c + d) + cd(a + b) 


ab + cd ab(c + d) + cd(a + b) 2abcd
 
x
 y  = 0 has non-trival solutions only if
 

2
 (A) a + b + c + d = 0 (B) ab + cd = 0
(C) ab(c + d) + cd(a + b) = 0 (D) for any a, b, c, d.
 
23 1+i −i
17. If A = 

1 − i −31 4 − 5i 
 , then det A is
i 4 + 5i 17
(A) complex number with positive real part
(B) complex number with negative imaginary part
(C) pure imaginary (D) real.
 
a−b−c 2a 2a
18. The matrix 

2b b−c−a 2b  is singular if


2c 2c c−a−b
(A) a = 0 (B) a + b = 0 (C) a − b = 0 (D) a + b + c = 0.
 
4 0 0
19. Let A =  0 4 0  , then An equals
 

0 0 4
4n 22n 0
   
0 0 0
n−1 2n
(A)  0 4 0  (B)  0 2 0 
 
 
n−2 2n
0 0 4 0 0 2
4n−1 |A|n
   
0 0 0 0
n−1 n
(C)  0 4 0  (D)  0 |A| 0 .
 

0 0 4n−1 0 0 |A|n
 
1 2 3
20. The characteristic roots of the matrix A =  0 −4 2  is/are given by
 

0 0 7
(A) 1, −4 (B) 1, −4, 7 (C) −1, 4, −7 (D) N.O.T.

Section II - Numerical Type Questions - 10 questions

(1 + x)a1 b1 (1 + x)a1 b2 (1 + x)a1 b3
21. Find the coefficient of x in the determinant (1 + x)a2 b1 (1 + x)a2 b2 (1 + x)a2 b3 ,
(1 + x)a3 b1 (1 + x)a3 b2 (1 + x)a3 b3
where ai , bj ∈ N

cos(x + α) cos(x + β) cos(x + γ) 25

X
1
22. If f (x) = sin(x + α) sin(x + β) sin(x + γ) and f (2) = 6, then find 5
f (r),
sin(β − γ) sin(γ − α) sin(α − β) r=1

x 1 1
23. Let f (x) = sin 2πx 2x2 1 . If f (x) be an odd function and its odd values is
x3 3x4 1
equal g(x), then find the value of λ, if f (1)g(1) = −4λ

3
 f (x + 1) f (x + 8) f (x + 1)
24. If f (x) satisfies the equation 1 2 −5 = 0 for all real x. If
2 3 λ
f is periodic with period 7 , then find the value of |λ|.

25. The maximum


value of a third order determinant each of its entries are ±1 equals
5 5α α
26. Let A =  0 α 5α  . If det(A2 ) = 25, then |α| is
 

0 0 5
 
1 0 0
27. If A =  1 1 2  then det(Adj(AdjA)) equals
 

3 −1 9
!
1 −3 4 7
28. The rank of the matrix A = is
9 1 2 0 2×4
" #k " #
cos 2π − sin 2π 1 0
29. If 3 3 = then the least value of k equals (k 6= 0)
sin 2π
3
cos 2π
3
0 1
 
1+a 1 1
1
30. If the matrix A = 
 1 1+b 1  is singular, then a
+ 1b + 1
c
=
1 1 1+c

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MPI CHEMISTRY 27/JAN/2024

Section-A: Only single option is correct

31. Tautomerism is not exhibited by:

CH = CH - OH O O
a) b)

O O

c) O d) O

32. Which of the following cycloalkanes involve maximum torstonal strain?

a) cyclopropane b) cyclobutane c) cyclopentane d) cyclohexane

33. Identify, which of the following molecule does not have ‘R’ configuration :

a) b)

c) d)

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MPI CHEMISTRY 27/JAN/2024

34. Which of the following is a trans isomer ?

a) b)

c) d)

35. Which of the following is more stable conformer of cyclohexane ?

a) b)

c) d)

36. Which of the following does not show chain isomerism

a) C4 H10 b) C4 H 8 c) C4 H 6 d) C4 H 9 OH

37. IUPAC name of the compound

a) 4,5 – dimethyloct – 4-ene b) 2,3 – dipropylbut – 2 – ene

c) 4 – methyl – 5 – propylhex – 4- ene d) 2 – propyl, 3 – methyl 2- hexene

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MPI CHEMISTRY 27/JAN/2024

38. Maximum enolisation takes place in:

a) CH 3COCH 3 b) CH 3COCH 2CHO

O
c) CH 3COCH 2COCH 3 d)

39. The compound whose stereo-chemical formula is written below exhibits ‘x’ geometrical
isomers and ‘y’ optical isomers:

The value of x and y are :

a) 4 and 4 b) 2 and 2 c) 2 and 4 d) 4 and 2

40. Which one of the following shows geometrical isomerism?

(A) Propenal (B) Propenol (C) Butanone (D) Butene

H3C H3C
NH

41. CH3 and NH CH3 are examples of

(A) Position isomers (B) Tautomers

(C) Metamers (D) Functional isomers

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MPI CHEMISTRY 27/JAN/2024

O CH3
OH

42. and are

(A) Position isomers (B) Chain isomers

(C) Metamers (D) Functional isomers

43. Two structures of cyanuric acid are shown below

These two structures are

(A) Rotamers (B) Stereoisoemers

(C) Metamers (D) Tautomers

44. Geometrical isomerism is possible about which of the following bond ?

(A) N  N (B) C C (C) C O (D) N  N

H3C
H3C
H3C CH3

45. H3C CH3 and CH3 are

(A) Position isomers (B) Chain isomers

(C) Metamers (D) Functional isomers

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MPI CHEMISTRY 27/JAN/2024

46. Most stable enolic form for ethylacetoacetate is

H CH2
O O H
H3C O
a) O b)
O O
CH3
CH3

O O
H3C O H H3C O H
c) d)
O O
CH3 CH2

47. Which one shows conformational isomerism?

H2C
a) b) H2C C CH2 c) H2C C O d) H3C CH
CH2

48. Correct order of stability among the three main conformations i.e. (Eclipsed,
Anti,Gauche) of 2- chloroethanol is:

a) Eclipsed > Anti > Gauche b) Anti > Gauche > Eclipsed

c) Gauche > Anti > Eclipsed d) Anti = Gauche > Eclipsed

49. Which has Z-configuration?

H3C
CH3 H3C Cl
Br CH3 H3C CH3
Cl
a) b) c) d) Cl
H3C
H3C Cl H3C OH
H2C Br

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MPI CHEMISTRY 27/JAN/2024

50. The most stable conformer of cis-1, 4-di-tertary-butylcyclohexane is

a) chair form b) boat form

c) twist boat form d) half chair form

Section-B: Numerical type problems

51. The number of structural isomers are possible for C7 H16

52. How many structural isomers of C5 H10 show geometrical isomerism?

53. How many structural isomers of C5 H10O show enolization ?

54. A hydrocarbon has the molar mass 86. Find the number of structural isomers possible for
the compound is

55. The number of structural isomeric compounds possible with molecular formula
C3H 6Cl2

56. How many structural isomers are possible with the formula C4 H10O ?

57. The number of structural isomers possible with the molecular formula C2 H 2 FClBrI

58. Number of possible position isomers for Dichlorobenzene is

59. Number of possible position isomers for tri substituted benzene assuming all three
substituents are of one kind?

60. Energy barrier between staggered and eclipsed ethane is x.y Kcal/mol. What is ‘X’?

6
Std:XI (F1) Mains Date - 27/01/2024 M. Prakash Institute
Section I - Single Option correct - 20 questions

61. If the gravitational force varies as r(−3/2) instead r−2 , then the P.E. of a particle at
a distance r from the particle would be proportional to
(A) r (B) r(−1/2) (C) r(1/2) (D) r(3/2)
62. Three particles of masses each m are placed at the vertices of an equilateral triangle
of side l. The work done to rearrange the masses at the vertices of an equilateral
triangle of side 2l is
3m2 G 3m2 G −3m2 G −3m2 G
(A) (B) (C) (D)
l 2l 2l l
63. A satellite of mass M is in a circular orbit of radius R about the centre of the earth.
A meteorite of the same mass, falling towards the earth collides with the satellite
completely inelastically. The speeds of the satellite and the meteorite are the same,
just before the collision. The subsequent motion of the combined body will be:
(A) such that it escapes to infinity
(B) in an elliptical orbit
(C) in the same circular orbit of radius R
(D) in a circular orbit of a different radius
64. When a satellite is going round the earth in a circular orbit of radius r and with a
velocity v. If during a cosmic event, it loses very small amount of the energy, then
(A) r and v both will increase (B) r and v both will decrease
(C) r will decrease and v will increase (D) r will increase and v will decrease
65. A thin uniform annular disc of mass M has outer radius 4R and inner radius 3R.
The work required to take a unit mass from point P on its axis to infinity is:

2GM √ −2GM √
(A) (4 2 − 5) (B) (4 2 − 5)
7R 7R
GM 2GM √
(C) (D) ( 2 − 1)
4R 5R

1
66. A test particle is moving in a circular orbit of radius R in the gravitational field
K
produced by a mass density ρ(r) = 2 . Neglect friction everywhere. Identify the
r
correct relation between the radius R of the particle’s orbit and its period T :
T T2
(A) is a constant (B) 3 is a constant
R R
T
(C) 2 is a constant (D) T R is a constant
R
67. A planet of mass m moves around the sun along an ellipse so that its minimum dis-
tance from the sun is equal to r and maximum distance R. The period of revolution
around the sun is (Mass of sun= M)
s s s s
(r + R)3 (r + R)3 (r + R)3 R3
(A) 2π (B) π (C) π (D) π
2GM 2GM GM 2GM
68. A satellite of mass m is circulating around the earth with constant angular velocity.
If radius of the orbit is R◦ and mass of the earth M , the ratio of angular momentum
of the satellite about the centre of the earth and its kinetic energy will be :-
s s s s
2 R◦2 R◦ 2 R◦ R◦3
(A) (B) (C) (D) 2
M Gm GM m GM GM
69. A meteorite approaching a planet of mass M (in the straight line passing through
the centre of the planet) collides with an automatic space station orbiting the planet
in a circular trajectory of radius R. The mass of the station is ten times as large as
the mass of the meteorite. As a result of the collision, the meteorite sticks in the
station which goes over to a new orbit with the minimum distance R/2 from the
planet. Speed of the meteorite just before it collides with the planet is :
s s s s
58GM 38GM 28GM 18GM
(A) (B) (C) (D)
R R R R
70. Orbital velocity of a satellite in its orbit (around earth) of radius r is v. It collides
with another body in its orbit and comes to rest just after the collision. Taking the
radius of earth as R, the speed with which it will fall on the surface of earth will be
q q
(A) v (r/R) − 1 (B) v 2(r/R) − 2
v q
(C) q (D) v 2(r/R) + 2
2(r/R) + 2
71. The bob of a simple pendulum has mass 2 g and a charge of 5.0 µC . It is at rest in
a uniform horizontal electric field of intensity 2000 V/m. At equilibrium, the angle
that the pendulum makes with the vertical is: (take g = 10 m/s2 )
(A) tan−1 (2.0) (B) tan−1 (0.2) (C) tan−1 (5.0) (D) tan−1 (0.5)

2
72. The given graph shown variation (with distance r from center) of:

(A) Electric field of a uniformly charged sphere

(B) Potential of a uniformly charged spherical shell
(C) Potential of a uniformly charged sphere
(D) Electric field of a uniformly charged spherical shell
√
73. Two point charges Q1 ( 10 µC) and Q2 (−25 µC) are placed on the x-axis at x = 1
m and x = 4 m respectively. The electric field (in V/m) at a point y = 3 m on
y-axis is,
1
(Take = 9 × 109 Nm2 /C2 .)
4πϵ◦
(A) (63î − 27ĵ) × 102 (B) (−63î + 27ĵ) × 102
(C) (81î − 81ĵ) × 102 (D) (−81î + 81ĵ) × 102
74. Three charges Q, +q and +q are placed at the vertices of a right angle isosceles
triangle as shown. The net electrostatic energy of the configuration is zero, if the
value of Q is:

√
− 2q −q
(A) +q (B) √ (C) √ (D) −2q
2+1 2+1
75. In free space, a particle A of charge 1µC is held fixed at a point P . Another particle
B of the same charge and mass 4 milligrams is kept at a distance of 1 mm from P .
If B is released, then its velocity (in m/s) at a distance of 9 mm from P is
1
(Take = 9 × 109 Nm2 /C2 .)
4πϵ◦
(A) 1.0 (B) 3.0 × 104 (C) 2.0 × 103 (D) 1.5 × 102

3
76. The potential depends on x- and y- coordinates as V = x2 − y 2 . Corresponding
electric field lines in x − y plane are as

77. Four equal point charges Q each are placed in the xy plane at (0, 2), (4, 2), (4, –2)
and (0, –2). The work required to put a fifth change Q at the origin of the coordinate
system will be :
Q2 1 Q2 1
   
(A) 1+ √ (B) 1+ √
4πϵ◦ 3 4πϵ◦ 5
2 2
Q Q
(C) √ (D)
2 2πϵ◦ 4πϵ◦
78. A charged particle moves with a speed v in a circular path of radius r around a long
uniformly charged wire, then
1 1
(A) v ∝ r (B) v ∝ (C) v ∝ √ (D) v is independent of r
r r

4
79. Two converging lenses have focal length f1 and f2 (f1 > f2 ). The optical axis of the
two lenses coincide. This lens system is used to from an image of real object. It is
observed that final magnification of the image does not depend on the distance x.
Whole arrangement is shown in figure. Final magnification is:

f1 f2 f1 f2
(A) − (B) − (C) − (D) −
f2 f1 f1 + f2 f1 − f2
80. A chain of mass M and length l is held vertically such that its bottom end just
touches the surface of a horizontal table. The chain is released from rest. Assume
that the portion of chain on the table does not form a heap. The momentum of the
portion of the chain above the table after the top end of the chain falls down by a
l
distance is
8
3 q 3 q 7 q 9 q
(A) M gl (B) M gl (C) M gl (D) M gl
14 16 16 14

5
 Section II - Numerical - 5 out of 10 questions

81. The eccentricity of the earth’s orbit is 0.017. Calculate ratio of maximum to that
of minimum speed.
q
82. The Period of a simple pendulum on the surface of earth is T = gl where l =
length of the pendulum and g = gravitational acceleration experienced by the bob
of the pendulum. At an attitude of half of the radius of earth (R) from the surface,
its period
√ will be nT√. Calculate n.
Take 2 = 1.41 & 3 = 1.73
83. The acceleration due to gravity on the surface of earth is g and radius of earth is
R. A ball is projected horizontally from point P1 on the surface of earth (as shown
in the figure). If the maximum height attained√by the ball above the earth surface
is 3R, then speed of projection V◦ is given by αgR. Calculate α. (neglect cosmic
dust resistance and earth’s rotation about its axis)

84. A ball of mass 1 g and charge 10−8 C moves from a point A(VA = 600 V) to the
point B whose potential is zero. Velocity of the ball
r at the point B is 20 cm/s. The
n
velocity of the ball at the point A is is given as m/s. Calculate n
100
→
−
85. The election field in a region is given by E = (Ax + B)î, where E is in N/C and x
in meters. The values of constants are A = 20 SI unit and B = 10 SI unit. If the
potential at x = 1 is V1 and that at x = −5 is V2 then calculate V1 − V2 (in V)
86. An electric field is acting vertically upwards. A small body of mass 1 gm and charge
−2µC is projected with a velocity 10 m/s at an angle 45◦ with horizontal. Its
horizontal range is 2 m then calculate the intensity of electric field in N/C. (g = 10
m/s2 )
87. Given electric potential at a point is: V = x2 y + yz, calculate the magnitude of
electric field at the point (1,3,1).
→
−
88. In an uniform electric field E = 2î + 3ĵ N/C, if the potential at the origin is 10V,
then calculate the potential (in V) at a point A (3m, 2m).
89. A solid sphere of radius R is charged uniformly. The distance from its surface
where the electrostatic potential is half of the potential at the center is given as nR.
Calculate 12n.
90. Five positive equal charges are placed at vertices of a regular hexagon and net electric
field at the center is E1 . A negative charge having equal magnitude is placed at
E2
sixth vertex and then net electric field is E2 . Find .
E1