Paper-1 Spotlight

Code-A Phase-2

Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005

Ph.: 011-47623456

MM : 180 SPOTLIGHT_WEEK-1_PAPER-1 Time : 3 Hrs.

JEE (Advanced)
Topic Covered :

Physics : Electrostatics, Capacitor, Current Electricity

Chemistry : GOC, Hydrocarbon, Haloalkane and Haloarene, Alcohol, Phenol & Ether

Mathematics : Function, Inverse Trigonometric Functions, Limits, Continuity and Differentiability

Instructions

1. Read each question carefully.

2. It is mandatory to use blue/black ballpoint pen to darken the appropriate circle in the answer sheet.
3. Mark should be dark and should completely fill the circle.
4. Rough work must not be done on the answer sheet.
5. Do not use white-fluid or any other rubbing material on answer sheet.
6. Student cannot use log table and calculator or any other material in the examination hall.
7. Before attempting the question paper, student should ensure that the test paper contains all pages and
no page is missing.
8. Before handing over the answer sheet to the invigilator, candidate should check that Roll No., Centre
Code and Date of Birth have been filled and marked correctly.
9. Immediately after the prescribed examination time is over, the answer sheet is to be returned to the
invigilator.
10. Pattern of the questions are as under:
(i) The question paper consists of 3 parts (Physics, Chemistry and Mathematics). Each part has 3
sections.
(ii) Section-1: This section contains 3 multiple choice questions which have one or more correct answer(s).
Each question carries +4 marks for correct answer and –2 marks for wrong answer. Partial +1 mark is
given for darkening a bubble corresponding to each correct option, provided no incorrect option is
darkened.
(iii) Section-2: This section contains 4 Multiple choice questions which have only ONE CORRECT
ANSWER. Each question carries +3 marks for correct answer and –1 mark for wrong answer.
(iv) Section-3: This section contains 6 questions. The answer to each question is a NON-NEGATIVE
INTEGER. Each question carries +4 marks for correct answer and there is NO negative marking
(v) Section-4: This section contains 4 multiple choice questions. Each question has two matching lists: (List -
I and List - II). In general, four options are given representing matching of elements from List-I and List-II.
Only ONE of these four options corresponds to a correct matching. For each question, choose the option
corresponding to the correct matching. Each question carries +3 marks for correct answer and –1 mark
for wrong answer.

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PART-I: PHYSICS
SECTION - 1
One or More Options Correct Type
This section contains 3 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D), for its
answer, out of which ONE OR MORE THAN ONE is/are correct.

1. A particle of charge +q approaches a grounded metallic sphere of radius R with a constant speed v as
shown in figure. As the particle goes nearer to the sphere (neglect any relativistic effects)

(A) A current flows into the ground

(B) A current flows out of the ground into the sphere
(C) Magnitude of current in connecting wire increases
(D) Magnitude of current in connecting wire decreases
2. Two batteries of emfs 1 and 2 and internal resistances r1 and r2 respectively are connected as shown in
figure. Choose the incorrect statement(s).

(A) If 2 <1, then VAB >1 (B) If 2 <1, then VAB <1
(C) If 2 = 1, then VAB <1 (D) If 2 = 1and r1 = r2, then VAB > 1
3. S is a solid neutral conducting sphere. A point charge q of 10–6C is placed at point A. C is center of
sphere and AB is tangent. BC = 3 m and AB = 4 m.

(A) Electric potential of conductor is 1.8 kV

(B) Electric potential of conductor is 2.25 kV
(C) Electric potential at B due to induced charges on the sphere is –0.45 kV
(D) Electric potential at B due to induced charges is 0.45 kV

SECTION - 2
Only One Option Correct Type
This section contains 4 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.

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4. Two identical small spheres of radius a are placed in a medium of resistivity  at large separation. The
resistance of medium between the spheres is
 
(A) (B)
4a 2a
 a
(C) (D)
a 2
5. A cell of internal resistance 1  is connected across a resistor. A voltmeter having variable resistance G
is used to measure potential difference across resistor. The plot of voltmeter reading V against G is
shown. What is the value of external resistor R?

(A) 5  (B) 4 
(C) 3  (D) 1 
6. Two parallel plate capacitors of equal plate area are connected as shown in the figure. Initially each
capacitor is charged to charge Q and separation between the plates is d. One plate of each capacitor
moves with constant speed v keeping the other plate of capacitor remain fixed, as indicated in the figure.
The current developed in the circuit is (resistance of connecting wire is zero)

Qv Qv
(A) (B)
2d d
3Qv 2Qv
(C) (D)
d d
7. In the shown figure, if all resistances are equal then current through the battery is I. If resistances of any
one pair of opposite arms of square are doubled, then the current through the battery will be

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2 3
(A) I (B) I
3 2

5 3
(C) I (D) I
6 7

SECTION – 3
Non-Negative Integer Type

This section contains 6 questions. The answer to each question is a NON-NEGATIVE INTEGER.

8. Two small electric dipoles of dipole moments p1 = p and p2 = 2p are located at separation l as shown in

np2
figure. The electric interaction energy between them is given as U  . Find the value of n.
40l 3

9. A non-conducting square plate of side a is uniformly charged with Q and a particle of charge q is placed

a
at distance from plate on an axis passing through centre of plate and perpendicular to it as shown.
2
2Qq
The electric force on the particle due to charge on the plate is given by F  . Find the value of n.
n 0 a 2

x
10. The ratio of equivalent resistances between terminals a and b of the following circuits is given by .
11
Find the value of 'x'. (All resistances are identical)

a
a b
b

(a) (b)
11. Five thin conducting plates each of breadth (b) are arranged parallel to each other as shown in figure.
The plates are arranged in increasing order of height. The height of the highest plate is h and the height
of successive plate decrease by a factor of 2. The equivalent capacitance between the first and fifth plate
 0 bh
is given by C  . Find 'x'.
xd

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12. Two small spheres each of mass 'm' and each with charge q lie inside a non-conducting smooth
hemispherical bowl of radius R placed on ground. The charge required for equilibrium at separation 2d is

n 0 mgd 3 
given by q  . Find 'n'.
R2 –d2

13. The voltage range of a galvanometer used as voltmeter is increased by n times by using a resistance of
16  and current range for the same galvanometer when used as ammeter is also increased by n times

by using a shunt of 4  resistance. Find the internal resistance of galvanometer (in ).

SECTION-4
Matching List Type
This section contains 4 multiple choice questions. Each question has two matching lists: (List-I and List-II).
In general, Four options are given representing matching of elements from List-I and List-II. Only ONE of
these four options corresponds to a correct matching. For each question, choose the option
corresponding to the correct matching.

14. Four identical capacitors are connected as shown in figure and are in steady state. Now a dielectric slab
is inserted in capacitor-4. Then select the correct match.

List-I List-II
(P) Capacitor-1 (1) Force between plates increases
(Q) Capacitor-2 (2) Force between plates decreases
(R) Capacitor-3 (3) Voltage across plates increases
(S) Capacitor-4 (4) Voltage across plates decreases
(5) Charge stored increases
(A) (P)  (2, 4), (Q)  (1, 3, 5), (R)  (2, 4), (S)  (2, 4, 5)

(B) (P)  (1, 3, 5), (Q)  (2, 4), (R)  (1, 3, 5), (S)  (1, 3, 5)

(C) (P)  (1, 3, 5), (Q)  (2, 4), (R)  (1, 3, 5), (S)  (1, 4, 5)

(D) (P)  (2, 4), (Q)  (1, 3), (R)  (2, 4, 5), (S)  (2, 3, 4)

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15. A cubical frame is made by joining twelve identical resistances, each R, as shown. When a battery of
e.m.f. E is connected, the frame draws current. Column-I contains the description of connection of
battery and Column-II contains the current through the branch 1–2. Match the entries of Column-I with
those of Column-II.

List-I List -II

(P) Battery connected across 1 and 2 (1)
Minimum among the given cases
2E
(Q) Battery connected across 1 and 3 (2)
5R
E
(R) Battery connected across 1 and 8 (3)
R
E
(S) Battery connected across 1 and 6 (4)
3R
E
(5)
2R
(A) (P)  (3), (Q)  (1, 2), (R)  (5), (S)  (4) (B) (P)  (3), (Q)  (5), (R)  (1, 2), (S)  (5)
(C) (P)  (3), (Q)  (5), (R)  (4), (S)  (1) (D) (P)  (2), (Q)  (4), (R)  (1, 2), (S)  (5)
16. List-I contains the current through the branch AB of the circuit (in steady state) shown in List-II. Match the
entries of List-I to that of List-II.
List-I List-II

(P) 3 A (1)

(Q) 4 A (2)

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(R) 2 A (3)

(S) 1 A (4)

(5)

(A) (P)  (2), (Q)  (3), (R)  (5), (S)  (4) (B) (P)  (3), (Q)  (1, 2), (R)  (5), (S)  (4)
(C) (P)  (3), (Q)  (5), (R)  (1, 2), (S)  (4) (D) (P)  (3), (Q)  (5), (R)  (4), (S)  (1, 2)
17. Three identical conducting plates, each of plate area A, are arranged such that adjacent plates are at
distance 3d and 2d respectively. If plates are connected to a source of emf V as shown in figure, then
match the following

List-I List-II
0 AV
(P) Charge on plate 3 (1)
2d
(Q) Charge on plate 5 (2) Zero
0 AV
(R) Potential difference between plates 2 and 3 (3) –
3d
V
(S) Potential difference between plates 2 and 5 (4)
2
(5) V
(A) (P)  (3), (Q)  (1), (R)  (5), (S)  (2) (B) (P)  (3), (Q)  (1), (R)  (4), (S)  (2)
(C) (P)  (3), (Q)  (5), (R)  (1), (S)  (2) (D) (P)  (2), (Q)  (3), (R)  (1), (S)  (5)

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PART-II: CHEMISTRY
SECTION - 1

One or More Options Correct Type

This section contains 3 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D), for its
answer, out of which ONE OR MORE THAN ONE is/are correct.

18. Which of the following is/are more reactive than benzene in electrophilic aromatic substitution reaction?

(A) (B)

(C) (D)

19. Consider the following statements

Ph

H3C OH
S1 : C2H5 C C is a Z-isomer
CH3
OH
C2H5

Ph
CH3
CH3
S2 : At least one of the conformers of Ph has a plane of symmetry
Ph
CH3
CH3
Ph
Ph
H
S3 : At least one of the conformers of H has centre of symmetry
C2H5
C2H5
S4 : Only one conformation of ethylene diammine has both centre of symmetry and plane of symmetry

simultaneously
S5 : The gauche form of meso tartaric acid is achiral

Which of the following options are correct?

(A) S1 and S5 both

(B) S2 and S3 both

(C) S3 and S4 both

(D) S2 and S4 both

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20. Consider the following molecules

The correct option(s) is/are

(A) Total 6 molecules are aromatic in nature, having electron in bonding molecular orbital only
(B) Molecules VII and IX are aromatic in nature
(C) Compound IV is non-aromatic in nature
(D) Compound II is anti-aromatic in nature

SECTION - 2
Only One Option Correct Type
This section contains 4 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.

21. In the reaction . The major product is

(A) (B)

(C) (D)

22. The product (Y) of the following sequence of reactions would be :

(A) (B)

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(C) (D)

23. Major organic product of the reaction will be?

(A) (B)

(C) (D)

24.

IUPAC name of the given compound is

(A) Tertbutyl-2-chloro-1-mercaptobenzoate (B) Isopropyl-3-chloro-4-mercaptobenzoate
(C) Tertbutyl-3-chloro-4-mercaptobenzoate (D) Isopropyl-5-chloro-4-mercaptobenzoate

SECTION – 3
Non-Negative Integer Type

This section contains 6 questions. The answer to each question is a NON-NEGATIVE INTEGER.

25. How many among the following reactions may give chiral carbon containing alkene?

(i) (ii)

(ii) (iv)

(v) (vi)

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(vii) (viii)

26. Trans-2-methyl cyclopentanol undergoes dehydration using POCl3 in pyridine, the major product is x-

methylcyclopentene. x is the locant number of methyl in IUPAC naming, the value of (x + 4)2 is
CH3MgBr  2 I CO ; H 
27. In a given reaction sequence H  C  C  H 
1 eqv   G  CH4 G 
II H O; Hg2  /H
 H  I
  2
III KMnO4

Let the number of –COOH group in compound H is x and number of (sigma) bonds in compound I is y.
Then find the value of (x2 + y2)
28. 1.70 g of an organic compound is subjected to Kjeldahl's method for the estimation of nitrogen present in
that compound. The ammonia evolved, neutralized 12.75 mL of 1 M H2SO4. The percentage of nitrogen in
the compound is
29. What is the degree of unsaturation of the final product (C) formed in the following reaction?
SOCl2
HOOC C6H4  CH2  C6H5 
 Ortho 
 A  
AlCl3
Anhy
 B  
Zn Hg
HCl C
30. Enatiomerically pure pentan-2-ol is heated with H2SO4, so that X number of total alkenes (including
stereoisomers) are obtained. This mixture of alkenes gives Y number of dibromoalkanes (including
stereoisomers) on reaction with Br2/CCl4. Find the value of (X + Y).
SECTION-4
Matching List Type
This section contains 4 multiple choice questions. Each question has two matching lists: (List-I and List-II).
In general, Four options are given representing matching of elements from List-I and List-II. Only ONE of
these four options corresponds to a correct matching. For each question, choose the option
corresponding to the correct matching.
31. Match the reactions given in List-I with their reaction mechanisms or characteristics of major product
given in List-II and choose the correct option.
List-I List-II

(P) (1) Saytzeff product

(Q) (2) Carbocation

(R) (3) E1CB elimination

(S) (4) Hoffmann product

(5) E1 elimination
(A) (P)  (4), (Q)  (4), (R)  (3), (S)  (1)
(B) (P)  (3), (Q)  (1), (R)  (4), (S)  (1, 2)

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(C) (P)  (1, 5), (Q)  (4), (R)  (1), (S)  (1, 5)
(D) (P)  (3, 4), (Q)  (4), (R)  (1), (S)  (1, 2, 5)
32. Match the compounds given in List-I with their isomerisms given in List-II and choose the correct option.
List-I (Compounds) List-II (Isomerisms)
(P) C4H8 (1) Structural
(Q) C4H9OH (2) Functional
(R) C2H5 – O – C5H11 (3) Positional
(S) C2H4Cl2 (4) Metamerism
(5) Geometrical
(A) (P)  (1, 3, 5), (Q)  (1, 2, 3), (R)  (1, 2, 4), (S)  (1, 3)
(B) (P)  (1, 5), (Q)  (2, 4, 5), (R)  (1, 5), (S)  (1, 3, 4, 5)
(C) (P)  (3, 5), (Q)  (3, 5), (R)  (1, 2, 5), (S)  (4, 5)
(D) (P)  (1, 5), (Q)  (2, 4), (R)  (1, 2, 5), (S)  (1, 5)
33. Match the compounds given in List-I with their characteristics given in List-II and choose the correct
option.
List-I (Compounds) List-II (Characterisation)
(P) H3C – C  CH (1) Decolourise Br2aq

(Q) (2) Reacts with NaOH to form salt

(R) (3) Reductive ozonolysis product gives positive

Tollen’s test

(S) (4) Gives aromatic product with hot iron

(5) Hydrogenation gives open chain alkane

(A) (P)  (1, 2, 4), (Q)  (1, 3), (R)  (5), (S)  (2)
(B) (P)  (1, 3), (Q)  (1, 2, 5), (R)  (1), (S)  (3)
(C) (P)  (1, 4, 5), (Q)  (1, 2), (R)  (1, 5), (S)  (2, 3)
(D) (P)  (1, 3, 4, 5), (Q)  (1, 2, 3), (R)  (1, 5), (S)  (3)
34. Match the compounds given in List-I with their characteristics given in List-II and choose the correct
option.
List-I (Compounds) List-II (Characteristics)
 i HI
 ii AgNO
(P) R – OH (1° alcohol) (1) Colour appears on reaction with  2
 iii HONO
 iv  NaOH

(Q) R – OH (2° alcohol) (2) Gives hydrocarbon on reaction with Cu at

300°C
(R) R – OH (3° alcohol) (3) Changes colour of litmus
(S) Ph – OH (Phenol) (4) Changes colour of chromic acid
(5) Colour change on reaction with
(NH4)2[Ce(NO3)6]

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(A) (P)  (1, 4), (Q)  (4), (R)  (1, 5), (S)  (5)
(B) (P)  (1, 4, 5), (Q)  (1, 4), (R)  (2, 4), (S)  (3, 5)
(C) (P)  (1, 4, 5), (Q)  (1, 4, 5), (R)  (2, 5), (S)  (3, 5)
(D) (P)  (1, 3, 4, 5), (Q)  (1, 4, 5), (R)  (2, 5), (S)  (3, 5)

PART-III: MATHEMATICS
SECTION - 1
One or More Options Correct Type
This section contains 3 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D), for its
answer, out of which ONE OR MORE THAN ONE is/are correct.

  1  
35. Given a function f(x) is continuous x  R such that lim  f  x   log  1  f  x    log  f  x     0 , then f(0) is
x 0
  e  
less than
(A) –1 (B) 1
(C) 2 (D) 3

  k 2  4k  3 
36. Let  cosec 1

 k 2  k 
   , then (where [·] denotes the greatest integer function)
k 1
 

  tan1 2 
d  1  2x    3  2 2

(A)  sin  2 
at x  tan     is  (B)   tan x  dx   tan1 2
dx   1  x   4  3 0
2
 3 
tan2   
 4 
x

1  sin  x  2 
2
  e
  tan1 x  dx  1
2
(C) lim tan x  2
(D)
 3 
x  tan    0
 4 

 n 
37. If f(x) = sgn((cos2x + cosx – 1)(cos2x + cosx + 1)) has exactly 6 points of discontinuity for x   0, , n
 2 
 N, then (where sgn (·) represents signum function)
(A) Sum of digits of value of n is 3
(B) Sum of digits of value of n is 4
(C) Number of prime factors of n is 3
(D) Number of prime factors of n is 2

SECTION - 2
Only One Option Correct Type

This section contains 4 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.

sin  x  ln 1   x  
38. If lim  1 , then  + 2 can be equal to
x 0 e3 x  3 x  1

(A) 1 (B) 4
(C) 9 (D) 16

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39. Let A = {–3, –2, –1, 0, 1, 2, 3}, then number of functions from A to A which are odd and f(i)  i (i = –3, –
2, –1, 1, 2, 3) is/are

(A) 126 (B) 216

(C) 261 (D) 162

1 1
40. If f(x) be a continuous function over [0, 1]  R+ such that  f  x  dx  1 and L   x 2021f  x  dx , then the
2

0 0

maximum value of L is

1 4
(A) (B)
2022 4043

1 1
(C) (D)
4043 2023
N
 n3  1 
41. lim
N 
  3
n 2  n  1 
 is equal to

1 3
(A) (B)
3 4

2 1
(C) (D)
3 2

SECTION – 3
Non-Negative Integer Type

This section contains 6 questions. The answer to each question is a NON-NEGATIVE INTEGER.

  1   2   n 
42. If lim  sin  2   sin  2   ...  sin  2   is t, then 2t is equal to
n 
 n  n
   n 

x3
cos2 x  cos x  e x cos x  e x 
43. If lim 2  L , (where L is non-zero finite number) and n  N, then the
x 0 xn
value of (nL) is



 
44. Number of points at which f  x   sin   x   sgn x 2  3 x  2
 2
 is discontinuous in x = [0, 3] is (where [·]

and sgn (·) denotes greatest integer function and signum function respectively)

45. If f(x2 – 6x + 6) + f(x2 – 4x + 4) = 2x x  R then f(–3) + f(9) is

46. Let f(x) be an odd function on R and f(x) = x2 for x  0. Suppose for any x  [a, a + 2], f(x + a)  2f(x). If


the complete range of real number a is   ,  , then  is equal to

1
 x
 log5 
  5 x   4
 log5  
47. If L  lim   4  , then [L] is (where [·] denotes greatest integer function)
x 4  20 
 log5 x 
 

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SECTION-4
Matching List Type
This section contains 4 multiple choice questions. Each question has two matching lists: (List-I and List-II).
In general, Four options are given representing matching of elements from List-I and List-II. Only ONE of
these four options corresponds to a correct matching. For each question, choose the option
corresponding to the correct matching.


 12  2 x 2 
48. Consider f  x   tan1  4

 and m and M are respectively minimum and maximum value of f(x)
 x  2x 2  3 
 
and x = ( > 0) is the point in the domain of f(x) where f(x) attains its maximum value. Then match the
elements of List-I with List-II.
List-I List-II

 
(P) If sin1 2 y  3 tan1  tan  m  M   , then 80y (1) –2

is greater than
  7M   3  
(Q) If cos 1 t  cos 1 y  3  tan1  tan  tan1  m  tan   ,(2) –1
  2   8 
then t + y is greater than or equal to
  2  
(R) tan  sec 1  2   M  is greater than or equal to (3) 1
   
(S) If p and q are roots of the equation (4) 2
t2 – (tan(3sin–1(sinM)))t + a4 = 0, then p + q is less than
or equal to
(5) 3
Which of the following option is correct?
(A) (P)  (1, 2, 3, 4, 5), (Q)  (1), (R)  (1, 2, 3), (S)  (3, 4, 5)
(B) (P)  (1, 2), (Q)  (4), (R)  (5), (S)  (2, 3, 5)
(C) (P)  (1, 2, 3, 4, 5), (Q)  (1), (R)  (5), (S)  (3, 5)
(D) (P)  (1, 2), (Q)  (4), (R)  (3), (S)  (1, 5)
49. Match the limit of the following sequences <an> as n  .
List-I List-II
(P) a1 = 1, an = sin(an – 1) (1) 2
(Q) a1  1, an  2an 1 (2) 0

(R) a1  1, an  2  an 1 (3) 1

 1  1  1  1  1 
(S) an   1    1  2   1  4   1  8  ...  1  n  (4) 2
 2  2  2  2   22 
1
(5)
2
Which of the following option is correct?
(A) (P)  (2), (Q)  (1), (R)  (1), (S)  (1) (B) (P)  (1), (Q)  (2), (R)  (3), (S)  (5)
(C) (P)  (2), (Q)  (5), (R)  (5), (S)  (2) (D) (P)  (1), (Q)  (5), (R)  (2), (S)  (5)

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50. Let f : R  (0, ) satisfies the relation f(x + y) = f(x)f(y), f(x)  0 for any x and f(x) is differentiable on R
such that f (0) = ln 2
List-I List-II
f x 1 0
(P) 2 f  x  1  0 , then x equals (1) 0
3 1 2

f x 1
(Q) lim equals (2) 1
x 0 x
(R) Number of points of non-differentiability of (3) 2
g(x) = min(f(x), 5x – 2) is
(S) Number of points of non-differentiability of (4) 3
h(x) = min(f(x), [x]), for x  (–1, 3) is (where [·]
denotes the greatest integer function)
(5) ln 2
Which of the following option is correct?
(A) (P)  (2), (Q)  (5), (R)  (3, 4), (S)  (2)
(B) (P)  (4), (Q)  (3), (R)  (5), (S)  (1)
(C) (P)  (1), (Q)  (5), (R)  (3), (S)  (4)
(D) (P)  (3), (Q)  (5), (R)  (1), (S)  (4)
51. Match the List-I with List-II
List-I List-II
(P) If A = (1, 2, 3, 4) and B = (1, 2), then number (1) 212
of onto functions from A to B is a factor of
(Q) Let f be a real valued function such that (2) 4096
 64 
f  x   2f    3 x for x > 0, then value of
 x 
f(4) is divisible by
(R) Number of reflexive relations that can be (3) 28
defined on A = {1, 2, 3, 4} is
(S) Number of bijective functions from A = {1, 2, 3} (4) 14
to B = {6, 9, 12} is divisible by
(5) 6
Which of the following option is correct?
(A) (P)  (3, 4), (Q)  (1, 2), (R)  (4, 5), (S)  (5, 3, 4)
(B) (P)  (3, 4), (Q)  (3, 4), (R)  (1, 2), (S)  (5)
(C) (P)  (1, 2), (Q)  (1, 2), (R)  (4, 5), (S)  (1, 2)
(D) (P)  (1, 2), (Q)  (3, 4), (R)  (5), (S)  (1, 3)



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