Chemistry Mohamed khir all….

) C( ‫) والسرعة‬ ( ‫والطول الموجي‬ ( ‫العالقة بين التردد‬

c =  x

Wave length ( ‫ الطول الموجي‬Frequency( ‫التردد‬

The wave length of the green light from a traffic signal is centered at 522nm .

What is the frequency of this radiation ( Answer = 5.74 × 1014 Hz)

What is the wavelength (in nanometer) of light having frequency of 8.6 × 1013 Hz ?

( Answer = 3.5 × 103 nm )

E : is the energy of a photon )‫ طاقة (الفوتون‬

h : Plank’s constant , h = 6.63 x 10-34 J.s ‫ ثابت بالنك‬
 : wave length ( m) ‫ الطول الموجي‬

 : frequency of radiation Hz (s-1 ) ‫ التردد‬

Calculate the energy (in J) of a photon with a wavelength of 5.00 x 104 nm (IR region)

( Answer = 3.98 × 10-21 J )

The blue color of sky result from scattering of sunlight by air molecules .the

blue light has a frequency of about 7.5 × 1014 Hz .Calculate the energy in

joules of a single photon associated with this frequency ( Answer = 5.0 ×10-9 J )

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‫‪Chemistry‬‬ ‫‪Mohamed khir all….‬‬

‫طيف ذرة الهيدروجين ‪Bohr’s Theory of Hydrogen Atom‬‬

‫‪ ‬يتكون الطيف نتيجة انتقال االلكترونات المثارة من مستوي الطاقة العالي الي مستوي الطاقة المنخفض ‪:‬‬

‫‪ :‬تنبعث عند انتقال االلكترونات من المستويات المثارة الي المستوي ‪. 1‬‬ ‫‪Lyman Series‬‬ ‫•‬

‫‪ :‬تنبعث عند انتقال االلكترونات من المستويات المثارة الي المستوي ‪.2‬‬ ‫‪Ballmer Series‬‬ ‫•‬

‫‪ : Panchen Series‬تنبعث عند انتقال االلكترونات من المستويات المثارة الي المستوي ‪.3‬‬ ‫•‬

‫‪ : Brackett Series‬تنبعث عند انتقال االلكترونات من المستويات المثارة الي المستوي ‪.4‬‬ ‫•‬

‫‪ :‬تنبعث عند انتقال االلكترونات من المستويات المثارة الي المستوى ‪. 5‬‬ ‫‪pfund Series‬‬ ‫•‬

‫‪ In the case of hydrogen atom spectra , the energies that the electron can possess‬‬

‫‪Calculate the value of the energy level (n =3 ) of the Hydrogen atom according to‬‬

‫‪Bohr _ Theory .‬‬

‫𝟏‬
‫𝒉𝑹‪∆𝑬 = −‬‬
‫𝟐𝒏‬
‫𝟏‬
‫𝟖𝟏‪∆𝑬 = −𝟐. 𝟏𝟖 × 𝟏𝟎 −‬‬ ‫‪= - 2.42 ×10 -19 J‬‬
‫𝟐𝟑‬

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Chemistry Mohamed khir all….

In the case of Electron transfer from ground state to excited state then return back to ground state

𝟏 𝟏
∆𝑬 = 𝑹𝒉 −
𝒏𝟐𝒊 𝒏𝟐𝒇
What process will be observed in a hydrogen atom when its electron drops from n=5

state to the n= 3 state .

-19 -19
a- A photon with energy 1.55  10 J will be absorbed . b- A photon with energy 1.55  10 J will be emitted

The second line of the Paschen series occurs at a wave length of 1282.4 nm . What

is the energy difference between the initial (n=5) and final levels of the hydrogen atom

in this emission process? ( Answer = - 1.55  10 -19 J )

Calculate the frequency and wave length of hydrogen atom spectrum when electron

transfer from n = 5 to n= 2 .

The energy of a photon of light is ......... proportional to its frequency

and ............ proportional to its wave length

a- directly , directly b-inversely, inversely

c- inversely, directly d) directly, inversely

Quantum Numbers ‫أعداد الكم‬ ‫فيديوهات حماتي أم دنيا‬

1. S sub shell ) ‫ ( الشقه‬have an angular quantum number ( L ) have value :

a- 0 b- 1 c- 2 d- 3

2. p sub shell have an angular quantum number ( L ) have value :

a- 0 b- 1 c- 2 d- 3

3. d sub shell have an angular quantum number ( L ) have value :

a- 0 b- 1 c- 2 d- 3

4. f sub shell have an angular quantum number ( L ) have value :

a- 0 b- 1 c- 2 d- 3

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Chemistry Mohamed khir all….

5. The angular quantum number ( L ) ‫ عدد الكم الثانوي‬is 3 in ................ orbitals . ) ‫( مهم‬

a) s b) p c) d d) f

6. The number of orbital’s ) ‫ ) عدد الغرف‬in S sub shell )‫( الشقة‬ is :

a- 1 b- 3 c- 5 d- 7 ‫نبغا في‬
‫السؤال عدد‬
7. The number of orbital in P sub shell is : ‫الغرف لشقه‬
S
a-1 b- 2 c- 3 d-5

8. The number of orbital in d sub shell is :

a-1 b- 2 c- 3 d-5

9. How many 2p orbital's are there in an atom ? ) ‫ ثابت‬3 ( ‫ في اي دور‬p ‫عدد الغرف في‬

a-1 b- 2 c- 3 d-5

10. The number of orbital in f sub shell is :

a-1 b- 2 c- 3 d- 7 ‫نبغا في السؤال‬

‫عدد االلكترونات‬
11. How many electrons can be placed in the S sub shell ? S ‫لشقه‬

a-2 b- 6 c- 10 d- 14

12. How many electrons can be placed in the P sub shell ?

a-2 b- 6 c- 10 d- 14

13. How many electrons can be placed in the d sub shell ?

a-2 b- 6 c- 10 d- 14

14. How many electrons can be placed in the f sub shell ?

a-2 b- 6 c- 10 d- 14

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Chemistry Mohamed khir all….

‫ أيش هو القانون ال يحسب لنا االلكترونات كلها في كل الدور الرئيسي بالكامل‬: ‫معني السؤال‬

15 .The maximum number of electrons that can occupy an energy level described by

the principal quantum number n is

a) n + 1 b) 2n c) 2n2 d) n2

) 3 ‫ بالكامل ( الدور‬3 ‫نبغي عدد االلكترونات في المستوي الرئيسي‬

16. What is the total number of electrons associated with the principal quantum number n = 3 ?

a) 8 b) 2 c) 18 d) 32

 n = 3 : for know the maximum number of electrons in principal shell : 2n2 = 232 = 18

17. What is the total number of electrons associated with the principal quantum number n = 2 ?

a) 8 b) 2 c) 18 d) 32

18. What is the total number of electrons associated with the principal quantum number n = 3 ?

a) 8 b) 2 c) 18 d) 32

) 3 ‫ بالكامل ( الدور‬3 ‫نبغي عدد االلكترونات في المستوي الرئيسي‬

‫ أيش هو القانون ال يحسب لنا االلكترونات كلها في كل الدور الرئيسي بالكامل‬: ‫معني السؤال‬

20 .The maximum number of electrons that can occupy an energy level described by

the principal quantum number n is

a) n + 1 b) 2n c) 2n2 d) n2

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Chemistry Mohamed khir all….

‫ أيش هو القانون ال يحسب لنا الغرف كلها في كل الدور الرئيسي بالكامل‬: ‫معني السؤال‬

21. The maximum number of orbital that occupy energy level described by principal

quantum number n is :

a-n b- n+1 c- n2 d- 3n2

) 2 ‫ بالكامل ( الدور‬2 ‫نبغي عدد الغرف في المستوي الرئيسي‬

22. What is the total number of orbital's associated with the principal quantum number n = 2 ?

a) 1 b) 3 c) 4 d) 9

 n = 1 : for know the maximum number of orbital's in principal shell : n2 = 22 = 4

23. What is the maximum number of electrons described by the quantum numbers : n = 3

a) 1 b) 3 c) 18 d) 9

24. What is the maximum number of electrons described by the quantum numbers : n = 3 l = 0

a) 1 b) 3 c) 2 d) 9

25 What is the total number of orbital's associated with the principal quantum number n = 3 ?

 n = 3 : for know the maximum number of orbitals in principal shell : n2 = 32 = 9 .

) 3 ‫ بالكامل ( الدور‬3 ‫نبغي عدد الغرف في المستوي الرئيسي‬

‫ فقط‬S ‫ ) الشقه‬3 ‫ ( الدور‬3 ‫نبغي عدد الغرف في المستوي الرئيسي‬

26. What is the maximum number of orbitals described by the quantum numbers : n = 3 l = 0

a) 1 b) 3 c) 5 d) 9

27. What is the maximum number of orbital s described by the quantum numbers : n = 3 , l = 2

a) 7 b) 14 c) 5 d) 48

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Chemistry Mohamed khir all….

Give the values of the quantum numbers associated with the 3S sub shell :

 n=3, L =0 , Ml = 0

 List the values of n , l and ml for orbital's in 3d sub shell .

 n:3 , L : 2 , ml : -2 ,-1 , 0 , 1 , 2 , ms : +1/2 , -1/2 .

Which one of the following sets of quantum numbers is not possible ?

n L mL ms
Row 1 4 3 -2 + 1/2
Row 2 3 0 1 - 1/2
Row 3 3 0 0 + 1/2
Row 4 2 1 1 - 1/2
Row 5 2 0 0 + 1/2
a- Row 1 b- Row 2 c- Row 3 d- Row 4

Which of the following is not a valid set of four quantum numbers? (n, ℓ, mℓ, ms)

a) 2, 0, 0, + ½ b) 2, 1, 0, - ½ c) 1, 1, 0, + ½ d) 1, 0, 0, + ½

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Electron configuration ‫التوزيع االلكتروني‬

֍ auf bau principle : Filled electrons with less energy and then top it up .

֍ Hund's Rule : Electrons first occupy these orbital’s singly with parallel spins rather than in
pairs .

֍ The Pauli exclusion principle : No two electrons can have identical values for all four of their
quantum numbers .

Electron configuration ‫التوزيع االلكتروني المختصر‬

The electronic configuration of Fe is:

a- [Ar] 4s2 3d6 b- [Ar] 4s1 3d5 c- [Ar] 4s2 3d4 d- [Ar] 3d6

The electronic configuration [Ne] 3s2 3p3, corresponds to

a- N b- Si c- S d- P

The element that has the valance electron configuration 3s2 3p3 is:

a-Carbon b-Nitrogen c-Phosphorus d-Neon

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What are the possible quantum numbers for the last (outermost) electron in Cl ?

1s2 , 2s2 , 2p6 , 3s2 , 3p5 .

3p : n:3 , L : 1 , ml : 1 , 0 , 1 , ms : +1/2 , -1/2 .

The orbital diagram for aground - state Oxygen atom is :

1s 2s 2p

a- Row 1

b- Row 2

c- Row 3

d- Row 4

The electron configuration of Cu 29 atom is :

a- 𝐴𝑟 4s2 4d4 b- 𝐴𝑟 4s2 4p63d3 c - 𝐴𝑟 4s2 3d9 d- 𝐴𝑟 4s1 3d10

The electron configuration of Cr 24 atom is :

a- 𝐴𝑟 4s2 4d4 b- 𝐴𝑟 4s2 4p6 3d3 c- 𝐴𝑟 4s2 3d9 d- 𝐴𝑟 4s1 3d5

Paramagnetic & Diamagnetic

How many unpaired electrons does selenium(Se) have?

a) 0 b) 2 c) 4 d) 6

A ground-state atom of nickel has …………. unpaired electrons and is …………. .

a) 0, diamagnetic b) 6, diamagnetic c) 3, paramagnetic d) 2, paramagnetic

How many unpaired electrons does chromium(Cr) have?

a) 0 b) 2 c) 4 d) 6

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Chemistry Mohamed khir all….

Complete this sentence : Atoms absorbed visible and ultraviolet light

a- as electrons jump from lower energy levels to higher levels .

b- as the atoms condense from a gas to a liquid .

c- as electrons jump from higher energy levels to lower levels .

d- as they are heated and the solid melts to form a liquid

The transition (n = 4 to n = 2 ) in the hydrogen atom belongs to the series of :

a-Lyman b- Ballmer c- Panchen d-Bracket

How many quantum numbers are necessary to designate a particular electron in an atom ......... ?

a- 3 b-4 c- 2 d- 1

The n = 1 shell contains ………… p orbitals. All the other shells contain ………. p orbitals.

a- 3, 6 b- 0, 3 c- 6, 2 d- 3, 3

Which of the sub shells below do not exist due to the constraints upon the angular quantum

number ?

a- 2s b- 2d c- 2p d- none of the above

Which electron configuration represents a violation of the Pauli exclusion principle ?

a-

b-

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