Sri Chaitanya IIT Academy.,India.

KPHB PRATIBHA-HYD
SR CHEMISTRY 1:5 IMP QUESTIONS 2023-24
I VERY SHORT QUESTIONS:
QUESTION NO-1 SOLUTIONS
1. Define osmotic pressure.
2. What are isotonic solutions? Give example.
3. Calculate the molarity of a solution containing 5gm of NaOH in 450ml solution
4. State Henry’s law.? What are colligative properties, Give examples.
5. State Raoult’s law and give its two limitations?
6 Calculate the mole fraction of H2SO4 in a solution containing 98% H2SO4 by mass ?
QUESTION NO:2 ELECTRO CHEMISTRY
1. State faraday”s first law of electrolysis ?
2. State faraday”s second law of electrolysis?
3. Write the cell reaction taking place in the cell Cu(s) / Cu+2 // Ag+ (aq) / Ag (s)
4. What is standard hydrogen electrode?
5. What is a primary battery? Give one example.
6. What is metallic corrosion? give one example
(OR)
CHEMICAL KINATICS
1. Give two examples for zero order reactions?
2. Define order of a reaction? Illustrate your answer with an example?
3. What are pseudo first order reactions? Give one example?
4. Write the integrated equation for a first order reaction in terms of R, R0 and t?
5. A reaction has a half-life of 10 minutes. calculate the rate constant for the first order reaction?
QUESTION NO:3 METALLURGY
1. What is the role of cryolite in the metallurgy of aluminium?
2. Give the composition of the following alloys.
a) Brass b) Bronze c) German silver
3. State the role of silica in the metallurgy of copper
4. What is blister copper? Why is it so called?
5. What is matte? Give one example.
6. What is role of cryolite in metallurgy of aluminium?
QUESTION NO:4 P-BLOCK ELEMENTS
1. What is tailing of mercury? How is it removed?
2. Nitrogen molecule is highly stable. why?
3. What is inert pair effect?
4. Ammonia is good complexing agent explain with an example.
5. What happens when white phosphorus is heated with conc. NaOH solution in an inert atmosphere of
CO2 ?

6. H2O is neutral while H2S is acidic - explain

QUESTION NO:5 P-BLOCK ELEMENTS

1. Chlorine acts as an oxidising agent-explain with two examples?
2. Write the shapes of XeO3 and XeF2?
3. Write the reaction of “F2” and “Cl2” with water?

4. In modern diving apparatus, a mixture of He & O2 is used. why?

5. Give any two uses of Argon?
QUESTION NO:6 D&F - BLOCK ELEMENTS & CO- ORDINATION COMPONDS
1. CuSO4.H2O is blue in colour whereas anhydrous CuSO4 is colourless. Why?

2. Why Zn2+ is diamagnetic whereas Mn2+ is paramagnetic?

3. What is misch-metal give its composition and uses ?

4. Aqueous Cu2+ ions are blue in colour whereas aqueous Zn2+ ions are colourless. Why?
5. What is an ambidentate ligand? Give example?
6. Calculate the spin only magnetic moment of Fe+2 (aq) ion?
QUESTION NO:7 POLYMERS
1. Mention the structures and names of the monomers used for preparing the following polymers.
a) Bakelite b) Poly styrene c) Teflon d) Poly vinyl chloride
e) Nylon - 6,6 f) Glyptal g) Terylene
2. What is PHBV? How is it useful to man?
3. What is vulcanization?
4. What is Ziegler Natta catalyst?
5. What are monomers? Give example.
6. What is poly merisation? Give an example.
QUESTION NO:8 POLYMERS
1. What is Bio-degradable polymer? Give two examples.
2. What is an addition polymer? Give an example of an addition polymer.
3. Write the names and structures of the monomers of the following polymers
(i) Buna-S (ii) Buna-N (iii) Dacron (iv) Neoprene.
4. Explain natural of synthetic polymers(rubbers)mention their monomers
5. What do you mean by polydispersity index?
QUESTION NO:9 CHEMISTRY IN EVERYDAY LIFE
1. What are analgesics? How are they classified? Give one example for each.
2. What are disinfectants? Give example.
3. What are food preservatives? Give example.
4. What are antihistamines? Give example.
5. What are artificial sweetening agents? Give example.
6. What are antacids? Give example.
7. What are antiseptics? Give example.
8. What is tincture of iodin? what is its use.
(OR)
BIOMOLECULES
1. What is Zwitter ion? Give an example.
2. What are essential and non-essential amino acids? Give one example for each.
3. What are the ambident nucloephiles
4. Name the vitamin responsible for the coagulation of blood?
5. What is denaturation? Give an example?
6. What are fibrous proteins? Give example?
QUESTION NO:10 CHEMISTRY IN EVERYDAY LIFE
1. What are tranquilizers? Give example.
2. What are antibiotics antiseptics? Give example.
3. What are the main constituents of dettol
4. What are narcotic analgesics? Give example.
5. What is the difference between a soap and a synthetic detergent?
II. SHORT ANSWER QUESTION:
QUESTION NO:11 SOLID STATE
1. Derive Bragg’s equation.
2. What are Schottky Frenkel defect
3. Classify each of the following as either a p-type or a n-type semiconductor.
(i) Ge doped with In (ii) Si doped with B.
4. In terms of band theory, what is the difference between a conductor and a semiconductor?
5. Explain why ionic solids are hard and brittle.
QUESTION NO:12 SOLUTIONS
1. What is relative lowering of vapour pressure? How is it useful to determine the molar mass of solute?
2. State Raoult’s law. Calculate the vapour pressure of a water at 293K is 17.535 mm.Hg Calculate the
vapour pressure of the solution at 293 K when 25g of glucose is dissolved in 450 g of water.
3. Calculate the mass of non-volatile solute (molar mass 40g mole -1) which should be dissolved in114g
 Octane to reduce its vapour pressure to 80%.
4. Define mole fraction? Calculate the mole fraction of H2SO4 in a solution containing 98% H2SO4 by mass.
5. A solution of glucose in water labeled as 10% W/W. What would be the molarity of the solution?
QUESTION NO:13 SURFACE CHEMISTRY
1. What is an emulsion? Explain the classification of emulsions with examples?
2. What are different types of adsorptions? Give any four differences between characteristics of the
different types.
3. What is catalysis? How is catalysis classified? Give two examples for each.
4. Write any four enzyme catalysed reactions.
5. Explain the following terms
(a) Electrophoresis (b) coagulation (c) Tyndall effect
QUESTION NO:14 METALLURGY
1. Explain the purification of sulphide ore by froth floatation method.
2. Giving examples to differentiate roasting and calcination.
3. Explain briefly the extraction of aluminium from bauxite.
4. Outline the principles of refining of metals by the following methods.
a) Zone refining b) Electrolytic refining c) Poling d) Vapour phase refining
5. Write any two ores with formulae of the following metals:
a) Aluminium b) Zinc c) Iron d) Copper
QUESTION NO:15 D&F – BLOCK ELEMENTS & CO- ORDINATION COMPOUNDS
1. Explain Werner’s theory of coordination compounds with suitable examples.
2. Write the characteristic properties of transition elements
3. Using IUPAC names write the formulae for the following:
(i) Tetrahydroxozincate (II) (ii) Hexaamminecobalt(III) sulphate
(iii) Potassium tetrachloropalladate (II) and (iv) Potassium tri(oxalato) chromate (III)
4. Using IUPAC names write the systematic names of the following:
3
Co  NH 3 6  Cl3  Pt  NH 3 2 Cl  NH 2 CH 3   Cl Ti  H 2O 6 
(i) (ii)  (iii) 

K 2  Pd Cl4  K 3  Fe  CN 6  Fe4  Fe  CN 6   Ni  CO 4 
(iv) (v) (vi) 3 (vii) 
5. Explain geometrical isomerism in coordination compounds giving suitable examples.
QUESTION NO:16 BIOMOLECULES
1. Give the sources of the following vitamins and name the diseases caused by their deficiency.
a) A b) D c) E and d) K
2. What are hormones? Give one example for each.
i) Steroid hormones ii) Poly peptide hormones and iii) Amino acid derivatives.
3. Explain the denaturation with suitable examples.
4. What are enzymes? Give examples.
5. Write important of carbohydrates?
QUESTION NO:17 HALOALKANES AND HALOARENS

1. Explain SN 1 & SN 2 reactions

2. Explain the acidic nature of phenols and compare with that of alcohols.
3. Explain the following reactions
4. i) Reimer-Tiemann reaction ii) Williamson’s ether synthesis
5. a) Write the isomers of the compound having molecular formula C 4H9Br
b) What are Enantiomers?
QUESTION NO:18 ORGANIC COMPOUNDS COTAINING C, H, O AND NITRO COMPOUNDS
1. Explain the following named reactions:
i) Sandmeyer reaction ii) Gattermann reaction
2. Explain the following a) Diazotisation b) carbylamines reaction?
3. How do you prepare ehtyl cyanide and Ethyl isocyanide from a common alkyl halide?
4. Define the following:
i) Racemic mixture ii) Retention of configuration iii) Recemisation
5. Compare the basicity of the following in gaseous and in aqueous state and arrange them in increasing
order of basicity. CH 3 NH 2 , (CH 3 ) 2 NH , (CH 3 ) 2 N and . NH 3

6. What is tollens reagent? explain its reaction with Aldehydes

II. LONG ANSWER QUESTIONS:
QUESTION NO: 19 ELECTRO CHEMISTRY & CHEMICAL KINETICS
1. (a) What is electrolysis? and State Faraday’s laws of electrolysis.
(b) A solution of is electrolysed for 10 minutes with a current of 1.5 amperes. What is the mass of
copper deposited at the cathode.
2. (a) State and Explain Kohlrausch’s law of independent migration of ions.
(b)Give the applications of Kohlrausch’s law of independent migration of ions.
3. Give a detailed account of the collsion theory of reaction rates of bimolecular gaseous reactions.
4. (a) What are galvanic cells? Explain the working of a galvanic cell with a neat sketch taking Daniel cell
as example?
(b) What is “molecularity” of a reaction? How is it different from the “order” of a reaction? Name one
bimolecular and one trimolecular gaseous reaction.
QUESTION NO: 20 P- BLOCK ELEMENTS
1. How is ammonia manufactured by Haber’s process? Explain the reactions of ammonia with
(a) ZnSO4 aq  (b) CuSO4 aq (c) AgCl(s)
2. How is ozone prepared from oxygen? Explain its reaction with
a) C2H4 b) KI c) Hg d) PbS e) Ag

3. How is nitric acid manufactured by Ostwald’s process? How does react with the following?
a) Copper b) Zn c) S8 d) P4
4. How is chlorine prepared in the laboratory or Deacon’s method? How does it react with the following?
a) Iron b) NaOH c) Acidified FeSO4 d) Iodine e) H2S

f) Na2S2O3 g) Excess NH3 h) Ca  OH 2

QUESTION NO:21 ORGANIC CHEMISTRY

1. Explain the following with one example
a) Decarboxylation.
b) Kolbe’s reaction
c) Hell - Volhard - Zelinsky (HVZ) reaction
d) Aldol condensation
2. Explain the following
a) Cannizzaro reaction.
b) Acetylation
c) Wurtz reaction
d) Cross aldol condensation
3. a) Write the equation involved in the reaction of nitrous acid with Ethylamine and Aniline
b) How do you carry out the following conversions:
i) Benzoic acid to Benzamide, ii) Aniline to p-bromo aniline