SR CHEMISTRY IMP VSAQ’S 2023-24

SOLUTIONS
1. Define osmotic pressure
2. What are isotonic solutions? Give example.
3. Calculate the molarity of a solution containing 5gm of NaOH in 450ml solution
4. State Henry’s law.? What are colligative properties, Give?
5. What is emulsifying agent? Give one example.
6. Define molarity.
7. What are colligative properties, Give examples.
8. Calculate the mole fraction H2SO4 in solution containing 98% H2SO4 by mass
9. Sate Raoult’s law and give its two limitations?
SURFACE CHEMISTRY
1. What is autocatalysis? Give one example.
2. What is Tyndal effect?
3. What is Brownian movement?
4. What is protective colloid?
5. Sky appears blue in colour. Explain.
d &f BLOCK ELEMENTS& CORDINATIONS COMPOUNDS
1. What is lanthanoid contraction?
2. What is meant by chelate effect?
3. CuSO4 .5H 2O is blue in colour whereas anhydrous is colourless. Why?
4. Zn2+ is diamagnetic whereas Mn2+ is paramagnetic
5. Calculate the spin only magnetic moment of Fe+2(aq) ion
6. What is an ambidentate ligand? Give example.
7. Aqueous Cu+2 ions are blue in colour where as aqueous Zn+2 ions are colourless. Why?
8. What is misch-metals give its composition and uses
9. Write Zeglar-natta catalyst
POLYMERS
1. What is PHBV? How is it useful to man?
2. What is vulcanization.
3. What do you mean by polydispersity index?
4. What is Bio-degradable polymer? Give two examples.
5. Give the structure of Nylon-2-Nylon-6
BIOMOLECULES
1. What are essential and non-essential amino acids? Give one examples for each
3. What are enzymes?
4. Name the vitamin responsible for the coagulation of blood.
5. What is Zwitter ion? Give an example.
6. What is denaturation? Give an example.
CHEMISTRY IN EVERYDAY LIFE
1. What are food preservatives? Give example.
2. What are antacids? Give example.
3. What are artificial sweetening agents? Give example.
4. What are disinfectants? Give example.
5. What are antibiotics? Give example.
6. What is tincture of iodine? What is its use?
7. What is the difference between a soap and a synthetic detergent?
8. Name two most familiar antioxidants used as food additives.
GENERAL PRINCIPLES OF METALLURGY
1. Give the composition of the following alloys.
a) Brass b) Bronze c) German silver
2. Write any two ores with formulae of the following metals:
a) Aluminium b) Zinc
3. What is matte? Give its composition.
4. What is the role of cryolite in the metallurgy of aluminium?
5. What is blister copper? Why is it so called?
GROUP 15 ELEMENTS
1. NH3 forms hydrogen bonds but PH3 does not -why?
2. What is allotropy? Write any two allotropes of phosphorous.
3. What is inert pair effect?
4. What are the Neutral oxides of Nitrogen?
5. What is laughing gas? Why it is so called?
6. PH3 has lower boiling point than NH3.Why?
GROUP 16 ELEMENTS
1. Why is H2O a liquid while H2S is a gas
2. H2O is neutral while H2S is acidic - explain
3. What is tailing of mercury? How is it removed?
GROUP 17 ELEMENTS
1. Write the reaction of “F2” and “Cl2” with water?
2. What happens when Cl2 reacts with dry slaked lime?
3. How is chlorine manufactured by Deacon’s method?
GROUP 18 ELEMENTS
1. Write the shapes of XeO3 and XeF2 ?
2. In modern diving apparatus, a mixture of He & O2 is used-why?
3. How is XeOF4 Prepared? Describe its molecular shape?
ELECTROCHEMISTRY&CHEMICAL KINETICS
1. What is a primary battery? Give one example.
2. What is metallic corrosion? give one example
3. State Faraday’s 1st and 2nd law of electrolysis.
4. What are pseudo first order reactions? Give one example?
5. Give two examples for zero order reactions?
6. A reaction has a half-life of 10 minutes. Calculate the rate constant for the first order reaction.
SOLID STATE
1. How do you distinguish between crystal lattice and unit cell?
2. What is Schottky defect
3. What is Frenkel defect?
4. What are f-centres?
ORGANIC CHEMISTRY
HALOALKANES AND HALOARENES
1. What are the ambident nucleophiles?
2. What are Enantiomers?
3. Briefly explain Wurtz & Wurtz-Fitting Reaction.?
4. Explain the reaction of Aniline with nitrous acid. (Diazotisations)
5. Explain the Kolbe’s reaction
6. Explain Reimer-Tiemann reaction.
7. Explain Williamsons ether synthesis.?
8. Compare the acidic strength of acetic acid, chloroacetic acid, benzoic acid and phenol?
9. What is Tollens reagent? Explain its reaction with Aldehydes.
10. Write the Sandmeyer, Gattermann reaction?
11. Write the carbylamine reaction
12. Explain Decarboxylation.
13. Grignard Reaction.