02 冷媒替代趋势

Refrigerant phase out analysis

1430 1770 3.3 1
R407C R290 CO
R134 2088
2

R410A
a
Phasing out
HFC
Systemically
New
REACH 4
HFO blends
Limitation R1234yf 148
Area R1234ze R454C GWP 750

HFO blends HFO blends 670

547 573 467 676 R32
R450A/R513A R454B/R452B

limited Limited limited Limited

GWP 150

1. Short time: Blend refrigerant：R134a==> R513A, R410A=>R32/R452B

2. Long time: Natural Refrigerant：R1234ze/R1234yf, R290、R454C、CO2
 Low GWP refrigerant
HOT

Refrigerant R134a R1234yf R1234ze R450A R513A R290 R152a

ODP 0 0 0 0 0 0 0
GWP 1430 4 4 547 573 3.3 124
Critical temp.(℃) 101 109.4 94.7 105.6 97.5 96.7 113.2
Temperature slip n/a n/a n/a 1K 0 n/a n/a
Flammability A1 A2L A2L A1 A1 A3 A2
Compatibility OK OK OK OK OK OK TBD
High Pressure 1.470 1.444 1.114 1.285 1.530 1.883 1.312
at A/T (MPa)
Discharge Temp. at A/T 84.9 76.4 78.3 81.1 80.0 84.2 94.3
(℃)
Capacity@ ASHARE/T 100% 96.6% 76% 87% 102.7% 130.4% 92.8%
COP @ ASHARE/T 100% 99.1% 101.9% 99.0% 100.5% 98.3% 101.1%
 Low GWP refrigerant
HOT

Refrigerant R410A R32 R452B R454B R454C R290

ODP 0 0 0 0 0 0
GWP 2088 675 676 466 148 3.3
Critical temp.(℃) 72.5 78.4 77.1 77 97.5 96.7
Temperature slip n/a n/a 4K 3K 6K n/a
Flammability A1 A2L A2L A2L A2L A3
Compatibility OK OK OK OK OK OK
High Pressure 3.389 3.473 2.927 2.845 1.888 1.883
at A/T (MPa)
Discharge Temp. at A/T 101.3 119.4 108.4 108.9 88.1 84.2
(℃)
Capacity@ ASHARE/T 100% 107.4% 91.1% 89.2% 60.1% 60.2%

COP @ ASHARE/T 100% 100.1% 104.1% 104.9% 112.1% 110.5%

 欧洲冷媒替代方向

应用 最新拟定的法规要求（2023.4.5) 执行时间

额定能力≤50KW，需充注GWP<150的冷媒 2027/1/1
整体式空调和热泵
额定能力>50KW，需充注GWP<150的冷媒 2030/1/1
分体式空调和热泵
充注量小于3kg的分体机，需充注GWP<750的冷媒 2025/1/1
<3kg冷媒
分体式ATW
12KW以下的分体机，需充注GWP<150的冷媒 2027/1/1
≤12KW
分体式空调和热泵 12KW以上的分体机，需要充注GWP<750的冷媒 2029/1/1
>12KW
12KW以上的分体机，需要充注GWP<150的冷媒 2033/1/1

类别 现行主要制冷剂 替代制冷剂

汽车空调 R134a、R410A、 R1234yf、R152a、 制冷剂 R410A R134a R32 R454B R290 CO2
R407C等 R744等
环境 ODP 0 0 0 0 0 0
房间空调器和 R22、R410A、 R32、R290 影响
热泵热水器 R32、R290 因素 GWP 2088 1430 675 466 3 1
工业空调 R134a/R410A R513A/R290