#@SOLENIS. Page: t SAFETY DATA SHEET Revision Date: 08/11/2015 Print Date: 10/11/2015 ‘SDS Number: 000000255629 “Ameroyal™ 710 ANTISCALANT ™ Trademark, Solenis or ite subsidiaries or affiliates, registered in various countries [100405 29 CFR 1910.1200 (OSHA HazCom 2012) SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product identifier Trade name Ameroyal™ 710 ANTISCALANT. Version. 1.0 ‘Trademark, Solenis or its subsidiaries or affiates, registered in various countries Recommended use of the chemical and restrictions on use [ Dolalls ofthe supplier of tho safety data RegulatoryRequestsNA@solenis.com pl |OLENIS (844-765-9647) / 606-329-5705 shoot 1-84 Solenis LL ‘500 Hercules Road Product information Wimington, Delaware 19808 1-844-SOLENIS (844-765-9647) United States of America SECTION 2, HAZARDS IDENTIFICATION GHS Classification ‘This material is not considered hazardous under the OSHA Hazard Communication Standard (HazCom 2012), GHS Label element ‘This material is not considered hazardous under the OSHA Hazard Communication Standard (HazCom 2012). Other hazards None known, ‘SECTION 3, COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture Mixture Hazardous components. ‘Chemical Name CAS-No. [Classification | Concentration G2) ‘ORGANIC ACID /254504001-5139 Tis material is not [>= 15.00 - < 20.00 |considered hazardous lunder the OSHA [Hazard WePage:2 #@soLenis. SAFETY DATA SHEET Revision Date: O81 72015 Print Date: 10/1 1/2015 a ‘SDS Number: 000000255629, “Ameroyal™ 710 ANTISCALANT Version 1.0 ™ Trademark, Solenis or its subsidiaries or affiliates, registered in various countries. 100495 |communication {Standard (HazCom i204). “Trade Secret Composition - Conceal the Identily + Concentration SECTION 4, FIRST AID MEASURES General advice 2 Move out of dangerous area, Consulta physician. ‘Show this safety data sheet to the doctor in attendance. Do not leave the vietim unattended. inhaled If breathed in, move person into fresh ai. |f unconscious place in recovery position and sesk medical advice, If symptoms persist, call a physician Incase of skin contact, + First ald is not normally required. However, itis recommended thal exposed areas be cleaned by washing with soap and water. Wash contaminated clothing before re-use. Incase of eye contact Flush eyes with water as a precaution. Remove contact lenses. Protect unharmed eye. If eye ittation persists, consult a specialist. If swallowed Get medical attention immediately Rinse mouth with water, Do not give milk oF alcoholic beverages. "Never give anything by mouth to an unconscious person. I symptoms persist, call a physician Most important symptoms ‘Signs and symploms of exposure to this material through ‘and effects, both acute and breathing, swallowing, andlor passage of the material through delayed the skin may include: stomach or intestinal upset (nausea, vomiting, diarrhea) leritaton (nose, throat, airways) Notes to physician No hazards which require special frst aid measures, SECTION 6. FIREFIGHTING MEASURES Suitable extinguishing media: Use extinguishing measures thal are appropriate to local circumstances and the surrounding environment. Water spray Biz4 SOLENIS. Page: 3 | SAFETY DATA SHEET Revision Date: 06/11/2015 Print Date: 10/11/2016. ‘SOS Number: 000000285629 ‘Ammeroyal™ 710 ANTISCALANT ‘ogistered in various countries 1100495, ‘™ Trademark, Solenis or its subsidiaries or affiates, Version 1.0 Unsuitable extinguishing media Speoific hazards during firefighting Hezardous combustion products, Specific extinguishing methods Further information Special protective equipment for firefighters. Foam Carbon dioxide (602) Dry chemical High volume water jet + Do not allow run-off from fire fighting to enter drains or water courses, corrosive vapors toxic fumes Oxides of phosphorus ‘carbon dioxide and carbon monoxide phosphine hydrogen chloride Sodium oxides Product is compatible with standard fire-fighting agents. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with focal regulations. {In the event of fre, wear self-contained breathing apparatus, ‘SECTION 6, ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and ‘emergency procedures Environmental precautions Methods and materials for containment and cleaning up Other information Persons not wearing protective equipment should be excluded fom area of spill until clean-up has been completed. + Prevent product from entering drains. Prevent further leakage or spillage if safo to do so. Ifthe product contaminates rivers and lakes or drains inform respective authorities. Keep in suitable, closed containers for disposal Comply with all applicable federal, state, and local regulations, ‘SECTION 7. HANDLING AND STORAGE Advice on safe hancling +: Do not breathe vapoursidust. Do not smoke. 11243 SOLENIS. Page: 4 SAFETY DATA SHEET Revision Date: 06/1172076 Print Date: 1071172076 ‘SDS Number: 000000256629 “Ameroyal™ 710 ANTISCALANT ‘Trademark, Solens or its subsidiaries or afiliates, ragistered in various counties | 100495 Conditions for safe storage Container hazardous when empty. ‘Smoking, eating and drinking should be prohibited in the application area. For personal protection see section 8, Dispose of rinse water in accordance with local and national regulations. Keep container tighlly closed in a dry and well-ventilated Place. ‘Observe label precautions. Electrical installations / working materials must comply with the technological safely standards, ‘SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Engineering measures Personal protective equipment Hand protection Remarks Eye protection ‘Skin and body protection Hygiene measures. Provide sufficient mechanical (general andior local exhaust) ventilation to maintain exposure below exposure guidlines (if applicable) or below levels that cause known, suspected or apparent adverse effects, The suitability for a specific workplace should be discussed vith the producers of the protective gloves. Not required under normal conditions of use. Wear splash proof safety goggles if material could be misted or splashed into eyes. + Wear resistant gloves (consult your safety equipment supplier), Wear as appropriate: impervious clothing Safety shoes ‘Choose body protection according to the amount and Concentration of the dangerous substance at the work place. Discard gloves that show tears, pinholes, or signs of weer. ‘Avoid contact with skin, eyes and clothing ‘Wash hands before breaks and immediately after handling the product. ‘SECTION 9, PHYSICAL AND CHEMICAL PROPERTIES. Physical state Colour liquid amber, light yellow arte Version. 1.0[#SOLeNIS. Page: 5 SAFETY DATA SHEET Revision Date: O6/1 172076 Prin Data: 10/1 772015 "SDS Number: 000000255629 “Ameroyal™ 770 ANTISCALANT ™ Trademark, Solenis or its subsidiaries or affiliates, registered in various countries 100495 Version. 1.0 Odour (Odour Threshold pH Melting pointfreezing point Bolling pointiboling range Flash point Evaporation rate Flammability (solid, gas) Upper explosion limit Lower explosion fit Vapour pressure Relative vapour density Relative density Density Solubiltyies) ‘Wealer solubility ‘Solubilly in other solvents Parltion coefficient: n= octanollwater Thermal decomposition Viscosity Viscosity, dynamic Viscosity, kinematio, Oxidizing properties No data avilable No data available 40-55 sear 177°C No data avallable 212.0°F 11000 °C Not applicable No data avaiable No data available No data avalabie + No data available 2 17.600 mmHg No data available No data available 4.24 glomd ‘completely soluble No data available No dala available : No dala avallable No data available + No data available > No data available ‘SECTION 10, STABILITY AND REACTIVITY Reactivity + No decomposition if stored and applied as directed. arta4 SOLCNIS. — Page: 6 SAFETY DATA SHEET Revision Date: 06/11/2015 Print Date: 10/11/2015 ‘SDS Number: 000000255629. “Ameroyal™ 770 ANTISCALANT ‘Trademark, Solenis or its subsidiaries or affiliates, rogistered in various counties 400495 Version. 1.0 Chemical stably Possibility of hazardous reactions Incompatible materials Hazardous decomposition products ‘Stable under recommended storage conditions. + Product will not undergo hazardous polymerization. Oxidizing agents, ‘Strong acids | carbon dioxide and carbon monoxide corrosive vapors hydrogen chloride phosphine Oxides of phosphorus Sodium oxides. SECTION 11, TOXICOLOGICAL INFORMATION Information on likely routes of exposure at toxicity Product: Acute dermal toxicity ‘Components: ORGANIC ACID: Aout oral toxicity Acute dermal toxicity ‘Skin corrostoniirritation ‘Components: ‘ORGANIC ACI Result: Milly irritating to skin + Inhalation ‘Skin contact Eye Contact Ingestion Remarks: Fatal in contact with skin, LD 50 (Rat): > 4.164 ghkg Remarks: Information given is based on data obtained from similar substances. LD 60 (Rabbi): > 4,605 mg/kg Remarks: Information given is based on data obtained from similar substances, Serious eye damage/eye irritation Product: Remarks: Unlikely 10 cause eye inttation or injury. ‘Components: ‘ORGANIC ACI Result: Mildly irritating to eyes ere@SOLENIS. Page:7 SAFETY DATA SHEET Revision Date: OTTO Prinl Date: 1071172075 ‘SDS Number: 000000255629 “Ameroyal™ 710 ANTISCALANT Version. 1.0 ‘™ Trademark, Solenis or its subsidiaries or affiliates, registered in various countries 100495 ORGANIC ACI ‘Test Type: Maximisation Test (GPMT) ‘Species: Guinea pig ‘Assessment: Did not cause sensitisation on laboratory animals. Germ cell mutagenicity ‘Components: ‘ORGANIC ACI Genotoxicity in vitro Test Type: Ames test Result: negative Genotoxicity in vivo Test species: Rat Cll typa: Bone marrow Method: Mutagenicity (in vivo mammalian bone-marrow ‘cytogenetic test, chromosomal analysis) Result: negative Carcinogenicity Reproductive toxicity 'STOT - repoated exposure ‘Gomponents: ORGANIC ACI Assessment: The substance or mixture isnot classified as specific target organ toxicant, repeated exposure. Aspiration toxicity Further information Product: Remarks: No data available Carcinogenicity: TARC No component ofthis product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC, ‘OSHA No component ofthis product present at levels greater than or ‘equal to 0.1% ie identified as a carcinogen or potential carcinogen by OSHA, NTP No component of this product present at levels greater than or equel to 0.1% is identified as a known or anticipated carcinogen by NTP. 772@solenis. rar SAFETY DATA SHEET Revision Dale. 06/11/2015 | Ameroyal™ 770 ANTISCALANT 1% Trademark, Solenis or its subsidiaries or affiliates, registered in various countvies 400495 ‘SBS Number: Print Date: 10/11/2015 700000255629, Version 1.0 ‘SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Product: Toxicity tofien Toxicity to daphnia and other aquatic Invertebrates Ecotoxicology Assessment ‘Acute aqualic toxicity Chronic aquatic toxicity Persistence and degradal ORGANIC ACID: Blodegradabilty Bioaccumulative potential ORGANIC ACID: Pariton coefficient: n- coctanoliwater Mobility in soil No data avaliable Other adverse effects No data avaliable Product: ‘Additional ecological information LC 60 (Oncorhynchus mykiss (rainbow trout): > 10,000 mgt Exposure time: 96 h Test Type: static test LC 50 (Pimephales promelas (fathead minnow): > 10,000 mg/l Exposure time: 96 h Test Type: static test EC 50 (Water flea (Ceriodaphnia dubia): 4,061 mg Exposure time: 48 h Test Type: static test Not classified based on available information. Not classified based on available information. Biodegradation: 0% Exposure time: 28 d Remarks: Not readily biodegradable. Remarks: No data available No data available SECTION 13, DISPOSAL CONSIDERATIONS Disposal methods Goneral advice + Donot dispose of waste into sewer. ariaPage: 9] ‘=SOLeNIS. SAFETY DATA SHEET Revision Date: 06/11/2015 "SDS Number: 000000255620 “Ameroyal™ 710 ANTISCALANT Version: 1.0 ™ Trademark, Sotenis or its subsidiaries or affiliates, registered in various counties 100695 See Do not coniaminate ponds, walerways or ditches with, ‘chemical or used container. ‘Send to a licensed waste management company. Dispose of in accordance with all applicable local, state and federal regulations. Contaminated packaging Emply remaining contents. Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recyciing or disposal Do not re-use emply containers, ‘SECTION 14, TRANSPORT INFORMATION International transport regulations REGULATION IDNUMBER | PROPER SHIPPING NAME | HAZARD | SUBSIDIARY | PACKING] MARINE CLASS | HAZARDS =| GROUP_—| POLLUTANT/ LTD. QTY. S. DOT - ROAD i ‘Nol dangerous goods a US, DOT - RAIL Nol dangerous goods U.S. DOT - INLAND WATERWAYS Not dangerous goods | TRANSPORT CANADA - ROAD Not dangerous goods a | ‘TRANSPORT CANADA - RAIL = é ‘Not dangerous goods z ‘TRANSPORT CANADA - INLAND WATERWAYS é ‘Not dangerous goods INTERNATIONAL MARITIME DANGEROUS GOODS. Not dangerous goods _| INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO Ore@solenis. rae SAFETY DATA SHEET Revision Dale: 08/11/2015 Print Date: TOM12015 a a ‘SDS Number: 000000255628 ‘Amveroyal™ 710 ANTISCALANT Version. 1.0 "Trademark, Solenis oils subsidiaries or afflates, registered in Various counliies 100495 Not dangerous goods INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER Not dangerous qoods MEXICAN REGULATION FOR THE LAND TRANSPORT OF HAZARDOUS MATERIALS AND ‘Not dangerous goods aes *ORM = ORM-D, CBL = COMBUSTIBLE LIQUID Marine pollutant 70 Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific ‘exceptions that can be applied. Consuit shipping documents for descriptions that are specific to the ‘shipment, ‘SECTION 15, REGULATORY INFORMATION SARA 311/912 Hazards No SARA Hazards SARA 313 ‘This material does not contain any chemical components with, ‘Component(s)SARA 313, known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title Ill, Section 313. California Prop 65 Proposition 65 warnings are not required for this product ‘based on the resulls of a risk assessment, Tho components of this product are reported in the following inventories: TSCA 1: On TSCA Inventory pst + This product contains one or several components that are not ‘on the Canadian DSL nor NDSL. AUSTR Not in compliance with the inventory NCS + Not in compliance withthe inventory Keo. Not in compliance with the inventory PHIL ‘Not in compliance with the inventory lecso Not in compliance with the inventory 10112(esouenis ro SAFETY DATA SHEET Revision Date: 06/11/2015 Print Date: 4071172016 ‘SDS Number: 000000256629 ‘™ Trademark, Solaris or its subsidiaries or affiliates, registered in various countsies. 100495 | Ameroyal™ 770 ANTISCALANT Version. 1.0 Inventories AICS (Australia), DSL. (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL ‘Gapan), KECI (Korea), NZI0C (New Zealand), PICCS (Philippines), TSCA (USA) Registration: Trade Secret ‘Chemical Name. [Identification number. ‘ORGANIC ACID. [254504001-5139 SECTION 16, OTHER INFORMATION Furthor information Revision Date: 06/11/2015 NEPA: HMIS TE Flanmnatiy faa GEN IV CIMiag PHYSICAL HAZARD a4 NFPA Flammable and Combustible Liquids Classification Not applicable Full toxt of H-Statorents roforred to under sections 2 and 3, +300 Fatal if swallowed Further information ‘Sources of key data used to compile the Safety Data Sheet Key literature references and sources of data SOLENIS Internal data ‘SOLENIS internal data including own and sponsored test reports The UNECE administers regional agreements implementing harmonised classification for labelling (GHS) and transport. ‘The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advanco of need that the information is current, applicable, and sullable to their circumstances. This MSDS has been prepared by the Solen’s Environmental Health and Safety Department, ne[@sovenis. ree SAFETY DATA SHEET Revision Dale: 06/11/2015 “Ameroyal™ 710 ANTISCALANT ‘™ Trademark, Solenis or its subsidiaries or affiliates, registered in various counties 100495 r Pink Date: 107112015 SBS Number 000000785620 Version. 1.0 Lis of abbreviations and acronyms thal coud be, bul not necessary re, used in Ns safely data sheet ACGIH : American Conference of Industrial Hygienists BEI : Biological Exposure Index CAS : Chemical Abstracts Service (Division of the American Chemical Society). CMR : Carcinagenic, Mutagenic or Toxic for Reproduction FG : Food grade GHS : Globally Harmonized System of Classification and Labeling of Chemicals. H-stalement : Hazard Statement IATA: International Air Transport Associaton. IATA-DGR : Dangerous Goods Regulation by the “International Air Transport Association” (ATA). ICAO : International Civil Aviation Organization ICAO-T1 (CAO) : Technical Instructions by the “International Civit Aviation Organization MDG : international Maritime Code for Dangerous Goods 180 : International Organizalion for Standardization logPow : cclanol-water partition coefficient LCxx : Lethal Concentration, for xx percent of test population LDxx : Lethal Dose, for xx percent of test population. Cx: Inhibitory Concentration for xx of a substance Eoxx : Effective Concentration of xx N.O.S: Not Otherwise Specified ECD : Organization for Economic Co-operation and Development CEL : Occupational Exposure Limit P-Slatement : Precautionary Statement PBT : Persistent , Bioaccumulative and Toxic PPE : Personal Protective Equipment 'STEL : Short-term exposure limit STOT:: Specific Target Organ Toxicity TLV : Threshold Limit Value TWA: Time-weighled average PVB : Very Persistent and Very Bioaccumuiative WEL ; Workplaco Exposure Level CERCLA : Comprehensive Environmental Response, Compensation, and Liability Act BOT : Department of Transportation FIFRA : Federal Insecticide, Fungicide, and Rodenticide Act HMIRC : Hazardous Materials Information Review Commission Hills : Hazardous Materials Identification System NEPA : National Fire Protection Association NIOSH : National Institute for Occupational Safety and Health ‘OSHA : Occupational Safety and Health Administration PMRA : Health Canada Pest Management Regulatory Agency RTK: Right fo Know WHMIS : Workplace Hazardous Materials Information System 212