Eng.

Subject final (2023)

Chemistry, Written, Set-B

imvqb Chem
01 10
nvB‡W«v‡R‡bi AvqbxKiY wefe 13.6 eV/atom| 25mg If the ionization potential of hydrogen is 13.6 eV/atom,
nvB‡W«v‡Rb cigvYy †_‡K H + Avqb Drcbœ Ki‡Z Kx cwigvY then what is the energy required to produce H + from 25mg
kw³i cÖ‡qvRb wbY©q Ki| hydrogen atoms?
2510−3 2510−3
25mg H cigvYy = mole H cigvYy 25mg H atom = mole H atom
1 1
= 25 × 10−3 × 6.023 × 10 H cigvYy
23
= 25 × 10−3 × 6.023 × 10 H atom = 1.50575 ×
23

= 1.50575 × 1022 cigvYy 1022 atom

myZivs, †gvU kw³ cÖ‡qvRb = 1.50575 × 1022 × 13.6 × Therefore, total energy required = 1.50575 × 1022 ×
1.6 × 10−19 J 13.6 × 1.6 × 10−19 J
= 32765.12 Joule = 32.76512 kJ (Ans. ) = 32765.12 Joule = 32.76512 KJ (Ans. )

b¤^i eÈb: Marks distribution :

25mg H cigvYy = 1.50575 × 1022 cigvYy wbY©‡qi Rb¨ 04
b¤^i|
†gvU kw³ cÖ‡qvRb = 32.76512 kJ wbY©‡qi Rb¨ 06 b¤^i|
[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv
n‡e|]
For determining 25mg H atom = 1.50575 × 1022 atom
; 04 marks.
For determining total energy required = 32.76512 KJ ; 06
marks
[Note: 01 mark will be deducted if unit is not written or
wrong unit is written.]

imvqb Chem
02 10
(a) Kx N‡U mgxKiYmn wjL: Al Gi mv‡_ Kw÷K †mvWvi Rjxq (a) Write with reactions what happens: if aqueous
`ªeY †hvM Kiv n‡j| solution of caustic soda is added to Al.
(b) [Zn(CN)4 ]2− Gi msKivqb I AvK„wZ wPÎmn e¨vL¨v Ki| (b) Explain the hybridization & shape of
[Zn(CN)4 ]2−with figure.
(a) (a)
Al + H2 O → Al2 O3 Al + H2 O → Al2 O3
Al2 O3 + NaOH → NaAlO2 Al2 O3 + NaOH → NaAlO2
cvwbi mv‡_ Al wewµqv K‡i Dfagx© Al2 O3 ˆZwi K‡i I Zv Al reacts with water and forms amphoteric Al2 O3 which
NaOH ÿv‡ii mv‡_ wewµqv K‡i NaAlO2jeY ˆZwi K‡i| then reacts with base NaOH to form salt NaAlO2.
(b) (b)
CN- CN-

Zn2+ Zn2+

CN- CN- CN- CN-

CN- CN-

GLv‡b AvqbwU nj Zn2+ Here, the ion is Zn2+

Zn2+ = 1s 2 2s2 2p6 3s2 3p6 3d10 4s0 4p0 Zn2+ = 1s 2 2s2 2p6 3s2 3p6 3d10 4s0 4p0
GLv‡b msKivqb n‡e 𝑠𝑝3 | d‡j, MVb KvVv‡gv n‡e PZy¯ÍjKxq| The hybridization is sp3 and so, the shape will be
tetrahedral.
[Zn(CN)4 ]2− [Zn(CN)4 ]2−

b¤^i eÈb: Marks distribution :

(𝐚) Al2 O3 + NaOH → NaAlO2 ; †jLvi Rb¨ 04 b¤^i| (𝐚) For writing, Al2 O3 + NaOH → NaAlO2 ; 04 marks.
(𝐛) [Zn(CN)4 ]2− Gi msKivqb I AvK„wZ wPÎmn e¨vL¨v Kivi Rb¨ (𝐛) For explaining the hybridization & shape of
(03+03) = 06 b¤^i| [Zn(CN)4 ]2−with figure ; (03+03) = 06 marks.

imvqb
03
(a) bvB‡UªU jeY n‡Z Mvp HNO3 cÖ¯‘wZ‡Z Mvp
H2 SO4 I Mvp HCl Gi g‡a¨ †KvbwU e¨envi Kiv DwPZ
Ges †Kb?
(b) weøwPs cvDWvi cÖ¯‘wZ Ges Gi weiÄb wµqvi
wewµqv wjL|
(𝐚) Mvp H2 SO4 e¨envi Kiv DwPZ
Δ Δ
NaNO3 + H2 SO4 (Conc. ) → NaSO4 + HNO3
G‡ÿ‡Î Mvp HCl e¨envi Ki‡j Zv HNO3 Gi mv‡_
wewµqv Ki‡e| ‡Kbbv Mvp HCl weRviK Ges Mvp
HNO3 RviK|
Avevi Mvp HCl DØvqx nIqvq Drcbœ nIqv HNO3
ev‡®úi mv‡_ wg‡k hv‡e|
40C
(𝐛) Ca(OH)2 + Cl2 → Ca(OCl)Cl + H2 O
ব্লিব্ল িং পাউডার
Ca(OCl)Cl(s) + H2 O(l) → Ca(OH)2 (aq) + Cl2 (g)
H2 O(l) + Cl2 (g) → HCl(aq) + HOCl(aq)
HOCl(aq) → HCl(aq) + [O]
iwOb e¯‘ + [O] → weiwÄZ e¯‘|
b¤^i eÈb:
(𝐚) Mvp 𝐻2 𝑆𝑂4 e¨envi Kiv DwPZ ; †jLvi Rb¨ 01 b¤^i|
mwVKfv‡e e¨vL¨v Kivi Rb¨ 03 b¤^i|
(𝐛) weøwPs cvDWvi cÖ¯‘wZi wewµqv †jLvi Rb¨ 03
b¤^i|
weiÄb wµqvi wewµqv †jLvi Rb¨ 03 b¤^i|
Chem
10
(a) Between concentrated H2 SO4 and concentrated HCl which one
should be used for the preparation of concentrated HNO3 from nitrate
salts? Why?
(b) Write down the reaction of preparation & bleaching action of
bleaching powder.
(a) Concentrated H2 SO4 should be used.
NaNO3 + H2 SO4 (Conc. ) → NaSO4 + HNO3
In this case, if concentrated HCl is used, it will react with HNO3 .
Because, concentrated HCl is reductant and concentrated HNO3 is
oxidant.
Hence, concentrated HCl volatile, it will get mixed with produced
HNO3 vapor.
40C
(𝐛) Ca(OH)2 + Cl2 →
Ca(OCl)Cl + H2 O
Bleaching powder
Ca(OCl)Cl(s) + H2 O(l) → Ca(OH)2 (aq) + Cl2 (g)
H2 O(l) + Cl2 (g) → HCl(aq) + HOCl(aq)
HOCl(aq) → HCl(aq) + [O]
Colored Compound + [O] → Bleached Compound.
Marks distribution :
(𝐚) For writing, concentrated H2 SO4 should be used ; 01 mark.
For correct explanation ; 03 marks.
(𝐛) For writing down the reaction of preparation of bleaching
powder ; 03 marks.
For writing down the reaction of bleaching action of bleaching
powder ; 03 marks.

imvqb Chem
04 10
(a) e¨vL¨v Ki: CuSO4 . 5H2 O eY©hy³ wKš‘ CuSO4 (a) Explain: CuSO4 . 5H2 O is colourful but CuSO4 is colourless.
eY©©nxb| (b) Show the mechanism of formation of sigma () bond by the
(b) `ywU cigvYyi s − s, s − p Ges p − p AiweUvj overlap of s-s, s-p and p-p orbitals of two atoms.
AwaµgY K‡i wmMgv (σ) eÜb MVb-Gi cÖwµqv †`LvI|
(a) H2 Ö GLv‡b wjM¨vÛ wn‡m‡e wµqv K‡i| wjM¨vÛ (a) H2 Ö acts as ligand here. Due to the effect of the ligand H2 O,
H2 O Gi cÖfv‡e Cu2+Gi 3d AiweUv‡j kw³i wefvRb division of energy occurs in 3d orbital of Cu2+. As a result, the
N‡U d‡j Aÿ eivei _vKv dx2 −y2 I dz2 Gi e− ¸‡jv D”P e− along the axis dx2 −y2 and dz2 remains in higher energy level
kw³¯Í‡i I dxy , dyz , dzx Gi e− ¸‡jv wb¤œ¯Í‡i Ae¯’vb and the e− of dxy , dyz , dzx remains in lower energy level. The e−
K‡i| wb¤œ kw³¯Í‡ii e− ¸‡jv kw³ †kvlY K‡i D”P¯Í‡i hvq of lower energy level goes to higher level absorbing energy, while
I wewKiY K‡i wb¤œ¯Í‡i Av‡m d‡j wewKwiZ kw³ eY© it comes down to lower level and releases energy. As a result, the
AvKv‡i jÿYxq nq| ZvB CuSO4 . 5H2 O eY©hy³ †hLv‡b emitted energy is observed as colour. So, CuSO4 . 5H2 O is
CuSO4 eY©nxb| colourful while CuSO4 is colourless.
(b) (b)
S S S S
S-S s eÜb S-S bond

S-P bond
S-P s eÜb
P-P bond

P-P s eÜb
Marks distribution :
(𝐚) For correct explanation ; 05 marks.
b¤^i eÈb:
(𝐛) For showing the mechanism of formation of sigma () bond
(𝐚) mwVKfv‡e e¨vL¨v Kivi Rb¨ 05 b¤^i|
by the overlap of s-s, s-p and p-p orbitals of two atoms ;
(𝐛) `ywU cigvYyi s − s, s − p Ges p − p AiweUvj
(01+02+02) = 05 marks.
AwaµgY K‡i wmMgv (σ) eÜb MVb-Gi cÖwµqv
‡`Lv‡bvi Rb¨ (01+02+02) = 05 b¤^i|

imvqb Chem
05 10
BDwiqv cvwb‡Z `ªexf~Z n‡q GKwU Av`k© `ªeY ˆZix K‡i| Urea forms an ideal solution when dissolved in water.
fi wnmv‡e 10% BDwiqv we`¨gvb Ggb GKwU Rjxq `ªe‡Yi Determine the vapor pressure of an aqueous solution
ev®úPvc 40o C ZvcgvÎvq wnmve Ki| [40o C ZvcgvÎvq containing 10% urea by mass at 400 C temperature. [Vapor
cvwbi ev®úPvc = 55.3mmHg] pressure of water at 400 C temperature = 55.3 mm Hg.]
10 10
BDwiqvi †gvj msL¨v = 10 g = 60 mol = 0.167 mol; Mole numbers of Urea = 10 g = 60 mol = 0.167 mol
cvwbi †gvj msL¨v = 90 g = 5 mol Mole numbers of H2 O = 90 g = 5 mol
5 5
AvswkK fMœvsk, X A = X A = (5+0.167)
(5+0.167)
5 5
Avgiv Rvwb, Pvap = PAo X A = (55.3 × (5+0.167)) mm Hg We know, Pvap = PAo XA = (55.3 × (5+0.167)) mm Hg
= 53.516 mm Hg. (Ans. ) = 53.516 mm Hg (Ans. )

b¤^i eÈb: Marks distribution :

5 5
X A = (5+0.167) ; ‡jLvi Rb¨ 03 b¤^i| For writing, X A = (5+0.167) ; 03 marks.

Pvap = PAo X A ; ‡jLvi Rb¨ 02 b¤^i| For writing, Pvap = PAo X A ; 02 marks.
Pvap = 53.516 mm Hg ; wbY©‡qi Rb¨ 05 b¤^i| For determining, Pvap = 53.516 mm Hg ; 05 marks.

imvqb Chem
06
50 mL 0.1 M CoCl2 . 6H2 O Gi Rjxq `ªe‡Y AgNO3 `ªeY
†hvM Kivq 6 × 1021 wU Avqb Aatwÿß nq| G‡Z
[Co(H2 O)5 Cl]Clx H2 O ms‡K‡Zi RwUj †hŠM Drcbœ
nq| x Gi gvb wbY©q Ki|
n n
S=V;
50×0.1
n = SV = 1000
= 5 × 10−3 mole
21
NCl = 6 × 10
6×1021
nCl = 6.02×1023 = 9.97 × 10−3
nCl 9.97×10−3
n
= 5×10−3
=2
∴x=2
∴ †hŠMwU [Co(H2 O)5 Cl]Cl2 H2 O
b¤^i eÈb:
n = 5 × 10−3 mole ; wbY©‡qi Rb¨ 03 b¤^i|
nCl = 9.97 × 10−3 ; wbY©‡qi Rb¨ 03 b¤^i|
x = 2 ; wbY©‡qi Rb¨ 03 b¤^i|
†hŠMwU [Co(H2 O)5 Cl]Cl2 H2 O ; †jLvi Rb¨ 01 b¤^i|
imvqb
07
C7 H8 AvYweK ms‡KZ wewkó GKwU ˆRe †hŠM (A)|
Gi g‡a¨ m~h©v‡jv‡Ki Dcw¯’wZ‡Z AwaK cwigvY
†K¬vwib M¨vm Pvjbv Ki‡j C7 H5 Cl3 AvYweK ms‡KZ
wewkó GKwU †hŠM (𝐵) Drcbœ nq hv‡K Py‡bi
cvwbi mvnv‡h¨ Av`ª© we‡køwlZ Kiv n‡j C7 H6 O2
AvYweK ms‡KZ wewkó Aci GKwU †hŠM (𝐶) MwVZ
nq| 𝐴 †hŠM‡K K 2 Cr2 O7 I Mvp H2 SO4 mn‡hv‡M
RviY Kiv n‡jI 𝐶 †hŠM cvIqv hvq| 𝐴, 𝐵 Ges 𝐶 †hŠM¸wj
Kx n‡Z cv‡i? wewµqvmn wbY©q Ki|
cªkœvbyhvqx mn‡RB Aby‡gq (𝐴) †hŠMwU
A¨vwjd¨vwUK nIqv m¤¢e bq| GwU A¨v‡iv‡gwUK
nvB‡WªvKve©b ev †ebwRb RvZK C6 H5 − R; ‡h‡nZy
†hŠMwUi AvYweK ms‡KZ C7 H8 ; AZGe 𝑅-g~jKwU
CH3 -g~jK| myZivs (𝐴) †hŠMwU C6 H5 − CH3 A_©vr
UjyBb|
m~h©v‡jv‡Ki Dcw¯’wZ‡Z †K¬vwi‡bi mv‡_ wewµqv
K‡i C6 H5 CCl3 Drcbœ nq| myZivs 𝐵 †hŠMwU
UªvB‡K¬v‡iv †ebwRb| Py‡bi cvwbi mvnv‡h¨ Bnv
Av`ª©-we‡køwlZ n‡q †ebRwqK GwmW Drcbœ K‡i|
UjyB‡bi GwmWhy³ K 2 Cr2 O7 Øviv Rvi‡YI †ebRwqK
10
AgNO3 solution is added in the aqueous solution of
50 mL 0.1 M CoCl2 . 6H2 O. When, 6 × 1021 ions are precipitated.
As a result, complex compound [Co(H2 O)5 Cl]Clx H2 O is formed.
Determine the value of x.
S=V;
50×0.1
n = SV = 1000
= 5 × 10−3 mole
21
NCl = 6 × 10
6×1021
nCl = 6.02×1023 = 9.97 × 10−3
nCl 9.97×10−3
n
= 5×10−3
=2
∴x=2
∴ The compound is [Co(H2 O)5 Cl]Cl2 H2 O
Mark Distribution:
For determining, n = 5 × 10−3 mole ; 03 marks.
For determining, nCl = 9.97 × 10−3 ; 03 marks.
For determining, x = 2 ; 03 marks.
For writing, the compound is [Co(H2 O)5 Cl]Cl2 H2 O ; 01 mark.
Chem
10
A is an organic compound having molecular formula C7 H8 . If
excessive amount of Chlorine gas is flowed in presence of sunlight
in A, another compound B is formed having molecular formula
C7 H5 Cl3 . It is hydrolysed with milk of lime and further produces
another compound C having molecular formula C7 H6 O2 .
Moreover, if A is oxidized by K 2 Cr2 O7 and conc. H2 SO4, it can
produce compound C. What can the compounds A,B,C be?
Determine with reactions.
According to question, it is easily assumed that A cannot be an
aliphatic compound. It must be a Benzene derivative or Aromatic
Hydrocarbon C6 H5 − R; As its molecular formula is C7 H8.
Therefore, the R is CH3 - group. So, A is Toluene (C6 H5 − CH3).
In presence of sunlight, Toluene reacts with Chlorine and produces
C6 H5 CCl3 . Thus, B is Trichlorobenzene (C6 H5 CCl3 ). It is
hydrolysed by milk of lime and produces Benzoic Acid. Again,
toluene is oxidized by acidified K 2 Cr2 O7 produces benzoic acid.
So, C is benzoic acid.
Related Reactions:
GwmW Drcbœ nq| myZivs 𝐶 †hŠMwU †ebRwqK
GwmW|
mswkøó wewµqv¸‡jv:

Therefore A = Toluene, C6 H5 CH3 ; B = Benzo-trichloride,

C6 H5 CCl3 ; C = Benzoic acid, C6 H5 COOH

myZivs [𝐴] = UjyBb, C6 H5 CH3 Mark Distribution:

[B] = †eb‡RvUªvB‡K¬vivBW, C6 H5 CCl3 For showing related reactions; (02 × 03) = 06 marks.
[C] = †ebRwqK GwmW, C6 H5 COOH. For determining, the compounds 𝐴, 𝐵, 𝐶 ; (02 + 01 + 01) = 04
marks.
b¤^i eÈb:
mswkøó wewµqv¸‡jv †jLvi Rb¨ (02×03) = 06 b¤^i|
𝐴, 𝐵 Ges 𝐶 †hŠM¸wj wbY©‡qi Rb¨ (02+01+01) = 04
b¤^i|

imvqb Chem
08 10
(a) wewµqvi mvnv‡h¨ †`LvI- (a) Show with reactions-
(i) †m‡KÛvix A¨vj‡Kvnj †_‡K wK‡Uvb (i) Ketone from secondary alcohol
(ii) A¨vwmwUK GwmW n‡Z A¨vwm‡Uvb (ii) Acetone from acetic acid
(iii) jNy HCl Gi Dcw¯’wZ‡Z 3-hydroxy butanal ‡K DËß KiY (iii) 3-hydroxy butanal is heated in presence of dil. HCl.
(b) †i‡Rvb¨vÝ Øviv †`LvI, −NO2 g~jK †gUv wb‡`©kK| (b) Show through resonance that −NO2 is a meta director.
(a) (a)
Cu/Ag ,3000 C Cu/Ag ,3000 C
(i) CH3 − CH(OH) − CH3 → CH3 − CO − CH3 + (i) CH3 − CH(OH) − CH3 → CH3 − CO − CH3 +
H2  H2 
(ii) 2CH3COOH+Ca(OH)2 → (CH3COO)2Ca+ 2H2O ; (ii) 2CH3COOH+Ca(OH)2 → (CH3COO)2Ca+ 2H2O ;
distillation distillation
(CH3COO)2Ca → CH3COCH3 (CH3COO)2Ca → CH3COCH3
dil.HCl dil.HCl
(iii) H3C − CH(OH) − CH2 − CHO → CH3 − CH = (iii) H3C − CH(OH) − CH2 − CHO → CH3 − CH =
Δ Δ
CH − CHO + H2O CH − CHO + H2O
(b) (b)

‡`Lv hvq †h, †gUv Ae¯’v‡b B‡jKUªb NbZ¡ Zyjbvg~jK †ewk| It can be seen that the electron density in the meta position
d‡j 𝑁𝑂2 -GKwU †gUv wb‡`©kK| is relatively high. So, NO2 is a meta director.

b¤^i eÈb: Mark Distribution:

(𝐚) wewµqv¸‡jv mwVKfv‡e †jLvi Rb¨ (02×03) = 06 b¤^i| (𝐚) For writing the correct reactions ; (02 × 03) = 06
(𝐛) †i‡Rvb¨vÝ Øviv †`Lv‡bvi Rb¨ 04 b¤^i| marks.
(𝐛) For showing through resonance ; 04 marks.
imvqb Chem
09 10
GKwU evdvi `ªeY cÖ¯‘wZi j‡ÿ¨ 2 wgwj †gvj CH3 COOH Ges 2 mili mole of CH3 COOH and 0.02M 50 mL NaOH is
0.02M 50 mL NaOH †gkv‡bv n‡jv| evdvi `ªeYwUi pH KZ? mixed in order to prepare a buffer solution. What is the pH
evdvi `ªe‡Y (i) mvgvb¨ HCl I (ii) †ewk cwigv‡Yi HCl †hvM of the buffer solution ? If (i) a small amount of HCl and (ii)
Ki‡j cÖwZ‡ÿ‡Î pH gv‡bi †Kv‡bv cwieZ©b n‡e Kxbv ; Zv large amount of HCl is added to this buffer solution, for
e¨vL¨v Ki| [pK a = 4.6] each case, explain if the pH will be changed or not. [pK a =
4.6]
mvg¨ve¯’vq : Equilibrium :
CH3 COOH NaOH
(2−1)mili mol
+ (1−1)mili mol
→ CH 3 COONa
1 mili mol
H2 O
+ 1 mili mol
CH3 COOH
(2−1)mili mol
NaOH
+ (1−1)mili mol
→ CH 3 COONa
1 mili mol
H2 O
+ 1 mili mol

[CH3 COONa] 1 [CH3 COONa] 1

pH = pK a + log [CH3 COOH]
= 4.6 + log 1 = 4.6 pH = pK a + log = 4.6 + log = 4.6
[CH3 COOH] 1
[ nNaOH = 0.02 × 50 =1 mili-mole ] [ nNaOH = 0.02 × 50 =1 mili-mole]

(i) G evdvi `ªe‡Y mvgvb¨ HCl `ªeY †hvM Ki‡j pH (i) In this buffer solution, if a small amount of HCl is added
AcwiewZ©Z _vK‡e| KviY evdviwUi pH gvb 4.6 hv n‡jv the pH will remain same. Because, the pH of the buffer is
CH3 COOH Gwm‡Wi pK a Gi gv‡bi mgvb| ZvB G‡ÿ‡Î evdvi 4.6 which is equal to pK a of CH3 COOH. So, pH will remain
ÿgZv Øviv pH w¯’i _vK‡e| same by the buffer capacity.

(ii) wKš‘ †ewk cwigv‡Yi HCl †hvM Ki‡j evdvi `ªe‡Yi evdvi (ii) If a large amount of HCl is added, then the buffer range
†i‡Äi AwZµg NU‡e| d‡j evdvi wµqv ev evdvi ÿgZv AKvh©Ki will be crossed. As a result, buffer capacity will not be
n‡e| ZLb †hvM Kiv HCl Gi cwigv‡Yi Dci wbf©i K‡i H `ªe‡Yi effective. Then, if HCl is added, pH of that solution will
pH Kg‡Z _vK‡e| decrease depending on the amount of HCl.

b¤^i eÈb: Marks distribution :

[CH COONa] [CH3 COONa]
pH = pK a + log [CH3 ; m~Î †jLvi Rb¨ 03 b¤^i| For writing formula, pH = pK a + log [CH3 COOH]
; 03
3 COOH]

evdvi `ªeYwUi pH=4.6 ; wbY©‡qi Rb¨ 02 b¤^i| marks.

mwVKfv‡e e¨vL¨v Kivi Rb¨ (02+03) = 05 b¤^i| For determining, pH = 4.6 ; 02 marks.
For correct explanation (02+03) = 05 marks.

imvqb Chem
10 10
2NO2 (g) ⇌ N2 O4 (g); 25o C ZvcgvÎvq wewµqvwU‡Z 2NO2 (g) ⇌ N2 O4 (g); at 25°C temperature initially 3 mole NO2
cÖv_wgK Ae¯’vq 3 mole NO2 †bIqv nj| mvg¨ve¯’vq were taken. If the pressure at equilibrium is 1 atm, what is the
cv‡Îi Pvc 1 atm n‡j N2 O4 Gi cwigvY KZ? nVvr Pvc amount of N2 O4 ? If the pressure is made 2 atm suddenly, what
2 atm Kiv n‡j bZzb mv‡g¨ N2 O4 Gi cwigvY KZ n‡e? will be the amount of N2 O4 at new equilibrium? [At 25°C
[25o C ZvcgvÎvq K P = 2] temperature K P = 2]
2NO2 (𝑔) ⇌ N2 O4 (𝑔) 2NO2 (𝑔) ⇌ N2 O4 (𝑔)
3 0 3 0
3−2a a 3−2a a
a a
3−a 3−a
∴ KP = 3−2a 2
∴ KP = 3−2a 2
( ) ( )
3−a 3−a
 a(3−a) a(3−a)
⇒ 2 = (3−2a)2 ⇒ 2(9 − 12a + 4a2 ) = 3a − a2 ⇒ 2 = (3−2a)2 ⇒ 2(9 − 12a + 4a2 ) = 3a − a2
⇒ 18 − 24a + 8a2 = 3a − a2 ⇒ a = 2, 1 [∵ a = 2 ⇒ 18 − 24a + 8a2 = 3a − a2 ⇒ a = 2, 1 [∵ a = 2 is not
MÖnY‡hvM¨ bq] acceptable]
∴ a = 1mole; mvg¨e¯’vq, nN2 O4 = 1 mole ∴ a = 1 mole
Avevi, 2NO2 (𝑔) ⇌ N2 O4 (𝑔) At equilibrium, nN2 O4 = 1 mole
1 1
1−2a 1+a Again, 2NO2 (𝑔) ⇌ N2 O4 (𝑔)
1+a 1 1
×2 (1+a)(2−a) 1−2a 1+a
2−a
⇒2= 2 ⇒2= 1+a
(
1−2a
×2) 2(1−2a)2 ×2 (1+a)(2−a)
2−a
2−a ⇒2= 1−2a 2 ⇒2= 2(1−2a)2
2) 2)
⇒ 4(1 − 4a + 4a = (2 + a − a (
2−a
×2)

⇒ a = 0.86, 0.14 [a ≠ 0.86] ⇒ 4(1 − 4a + 4a2 ) = (2 + a − a2 )

a = 0.14 mole
∴ nN2 O4 = 1.14 mole (Ans.)
b¤^i eÈb:
a = 1mole ; wbY©‡qi Rb¨ 03 b¤^i|
mvg¨e¯’vq nN2 O4 = 1 mole ; wbY©‡qi Rb¨ 02 b¤^i|
a = 0.14 ; wbY©‡qi Rb¨ 03 b¤^i|
nN2 O4 = 1.14 mole ; wbY©‡qi Rb¨ 02 b¤^i|
[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b
Kiv n‡e|]
⇒ a = 0.86, 0.14 [a ≠ 0.86]
a = 0.14 mole
∴ nN2 O4 = 1.14 mole (Ans.)
Marks distribution :
For determining, a = 1 mole ; 03 marks.
For determining, at equilibrium nN2 O4 = 1 mole ; 02 marks
For determining, a = 0.14 mole ; 03 marks
For determining, nN2 O4 = 1.14 mole ; 02 marks
[Note: 01 mark will be deducted if unit is not written or wrong
unit is written.]

imvqb Chem
11 10
25 g bgybv CaCO3 Gi `ªe‡Y 0.5 M 200 mL HCl Ges When 0.5 M 200 mL HCl and 0.3 M 400 mL H2 SO4 are mixed
0.3 M 400 mL H2 SO4 `ªeY †gkv‡bv n‡j m¤ú~Y© with 25g CaCO3 sample solution, it is neutralized completely.
cÖkwgZ nq| bgybv CaCO3 G †fRv‡ji kZKiv cwigvY Determine the percentage of impurity of the CaCO3 sample .
wbY©q Ki|
CaCO3 + 2HCl → CaCl2 + CO2 + H2 O CaCO3 + 2HCl → CaCl2 + CO2 + H2 O
CaCO3 + H2 SO4 → CaSO4 + H2 O + CO2 CaCO3 + H2 SO4 → CaSO4 + H2 O + CO2
nHCl = 0.1 mole, nH2 SO4 = 0.12 mole nHCl = 0.1 mole, nH2 SO4 = 0.12 mole
0.1 0.1
∴ nCaCO3 = 2
+ 0.12 = 0.17 mole = 17 g ∴ nCaCO3 = 2
+ 0.12 = 0.17 mole = 17 g
25−17 25−17
∴ †fRv‡ji cwigvY = 25
× 100% = 32% (Ans.) Amount of impurity = 25
× 100% = 32% (Ans.)
b¤^i eÈb: Marks distribution :
nHCl = 0.1 mole ; wbY©‡qi Rb¨ 02 b¤^i| For determining, nHCl = 0.1 mole ; 02 marks.
nH2 SO4 = 0.12 mole ; wbY©‡qi Rb¨ 02 b¤^i| For determining, nH2 SO4 = 0.12 mole ; 02 marks.
nCaCO3 = 17 g ; wbY©‡qi Rb¨ 03 b¤^i| For determining, nCaCO3 = 17 g ; 03 marks.
†fRv‡ji cwigvY = 32% ; wbY©‡qi Rb¨ 03 b¤^i| For determining, amount of impurity = 32% ; 03 marks.
[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv [Note: 01 mark will be deducted if unit is not written or wrong
n‡e|] unit is written.]

imvqb Chem
12 10
298K ZvcgvÎvq GKwU cwievwnZv †m‡j 0.05M NaOH At 298K temperature, the resistance of a 0.05M NaOH solution
`ªe‡Yi ‡iva 31.6 ohm | †mj aªæeK 0.367cm−1 n‡j in a conductive cell is 31.6 ohm. If the cell constant is
NaOH `ªeYwUi †gvjvi cwievwnZv wbY©q Ki| 0.367cm−1 then determine the molar conductivity of the NaOH
solution.
0.05M NaOH `ªeY, gv‡b, 0.05 mole NaOH Av‡Q 0.05M NaOH solution means 0.05 mole NaOH is present in
1000 cm3 `ªe‡Y 1000 cm3 solution
1000 1000
∴ 1 mole NaOH Av‡Q cm3 `ªe‡Y = 20,000 cm3 ∴ 1 mole NaOH is present in cm3 solution = 20,000 cm3
0.05 0.05
`ªe‡Y solution
l l
∴ Vmolar = 20,000 cm3 Ges †mj aªæeK = A = ∴ Vmolar = 20,000 cm3 and cell constant = A = 0.367 cm−1
0.367 cm−1 [cÖkœg‡Z] [according to the condition]
RA 1 RA 1
Ges `ªeYwUi Av‡cw¶K †iva = ρ = = R. = and the specific resistance of the solution = ρ = l
= R. l =
l l
( ) ( )
A
A
31.6 31.6
ohm cm 0.367
ohm cm
0.367
1 0.367
∴ Av‡cw¶K cwievwnZv, κ = ρ =
1 0.367
ohm−1 cm−1 ∴ Specific conductivity, κ = ρ = 31.6
ohm−1 cm−1
31.6
∴ `ªeYwUi †gvjvi cwievwnZv, μ = κ × Vmolar = ∴ Molar conductivity of the solution, μ = κ × Vmolar =
0.367
0.367
20000 cm2 ohm−1 mole−1 20000 cm2 ohm−1 mole−1
31.6
31.6
= 232.278481 ohm−1 cm2 mole−1 (Ans. ) = 232.278481 ohm−1 cm2 mole−1 (Ans. )
b¤^i eÈb: Marks distribution :
31.6 For determining the specific resistance of the solution =
Av‡cw¶K †iva = 0.367 ohm cm wbY©‡qi Rb¨ 03 b¤^i| 31.6
0.367 0.367
ohm cm ; 03 marks.
Av‡cw¶K cwievwnZv, = ohm−1 cm−1 wbY©‡qi 0.367
31.6
For determining the specific conductivity, = 31.6
ohm−1 cm−1
Rb¨ 03 b¤^i|
; 03 marks.
†gvjvi cwievwnZv = 232.278481 ohm−1 cm2 mole−1
For determining molar conductivity of the solution =
wbY©‡qi Rb¨ 04 b¤^i|
232.278481 ohm−1 cm2 mole−1 ; 04 marks.
[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv
[Note: 01 mark will be deducted if unit is not written or wrong
n‡e| m~Î bv wj‡L mivmwi gvb emv‡jI M«nY‡hvM¨
unit is written. Direct input of values without writing the
n‡e|]
formula is also acceptable.]

imvqb Chem
13 10
jNy Kw÷K †mvWvi Dcw¯’wZ‡Z B_vb¨vj I †cÖvcvb¨v‡ji In presence of diluted caustic soda, if the mixture of ethanal
wgkÖY‡K DËß Ki‡j wewµqvi mvnv‡h¨ cÖavb Drcv`mg~n and propanal are heated, show the major products obtained in
‡`LvI| along with the reactions.
Dfq †hŠ‡M α-nvB‡Wªv‡Rb _vKvq `yBfv‡e A¨vj‡Wvj Since α -hydrogen is present in both the compounds, aldol
wewµqv msNwUZ n‡e| GK av‡c B_vb¨vj wbDwK¬IdvBj reaction will occur in two ways. In one step, ethanal will act
MÖvnK Ges Aci av‡c †cÖvcvb¨vj wbDwK¬IdvBj MÖvnK as nucleophile receiver and in the other step propanal will act
wn‡m‡e KvR K‡i| as nucleophile receiver.
CH3 CHO CH3 CHO
dil.NaOH ∆ dil.NaOH ∆
+ CH3 CH2 CHO → CH3 CH2 CH(OH)CH2 CHO → CH3 + CH3 CH2 CHO → CH3 CH2 CH(OH)CH2 CHO → CH3
− CH2 − CH = CH − CHO − CH2 − CH = CH − CHO
CH3 CHO
dil.NaOH ∆
+ CH3 CH2 CHO → CH3 CH(OH)CH(CH3 )CHO → CH3
− CH = C − CHO
|
CH3
CH3 CHO Marks Distribution:
dil.NaOH ∆ For writing the reaction and the main product correctly ;
+ CH3 CH2 CHO → CH3 CH(OH)CH(CH3 )CHO → CH3
(05×02) = 10 marks.
− CH = C − CHO
|
CH3
b¤^i eÈb:
mwVKfv‡e wewµqv I Drcv` †jLvi Rb¨ (05×02) = 10 b¤^i|

imvqb Chem
14 10
(a) DO Kx? (a) What is DO?
(b) †Kv‡bv bgybv cvwb‡Z O2 Gi cwigvY cwigvc Ki‡Z wM‡q (b) While measuring amount of O2 of a sample
†`Lv †Mj 0.4M 40mL I2 e¨eüZ nq| bgybv cvwb‡Z DO Gi water, 0.4M 40mL I2 was used. Determine the amount of
cwigvY wbY©q Ki| [bgybv cvwbi AvqZb 400 mL] DO in sample water. [Volume of sample water is
400mL]
(a) DO ej‡Z cvwb‡Z `ªexf‚Z Aw·‡Rb †evSvq| (a) DO means dissolved Oxygen in water.
(b) 2I2 ≡ 4S2 O2−
3 ≡ O2 (b) 2I2 ≡ 4S2 O2−
3 ≡ O2
2 nI 2 0.4×40 2 nI 2 0.4×40
∴ = ⇒ nO 2 = ∴ = ⇒ nO 2 =
1 nO 2 2×1000 1 nO 2 2×1000

⇒ nO 2 = 8 × 10−3 mole = 256 mg ⇒ nO 2 = 8 × 10−3 mole = 256 mg

256 256
∴ NbgvÎv = = 640 ppm (Ans. ) ∴ Concentration = 0.4
= 640 ppm (Ans. )
0.4
b¤^i eÈb: Marks distribution :
(a) DO Gi msÁv †jLvi Rb¨ 02 b¤^i| (a) For writing the definition of DO ; 02 marks.
(b) 2I2 ≡ 4S2 O2−
3 ≡ O2 †jLvi Rb¨ 01 b¤^i|
(b) For writing 2I2 ≡ 4S2 O2−3 ≡ O2 ; 01 mark.

nO 2 = 256 mg wbY©‡qi Rb¨ 04 b¤^i| For determining nO 2 = 256mg : 04 marks.

NbgvÎv= 640 ppm wbY©‡qi Rb¨ 03 b¤^i| For determining the concentration = 640ppm ; 03
[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e|] marks.
[Note: 01 mark will be deducted if unit is not written or
wrong unit is written.]

imvqb Chem
15 10
125o C ZvcgvÎvq wb‡Pi †KvlwU mvg¨ve¯’vq _vK‡j CuSO4 Gi Determine the concentration of CuSO4 if the following
0 cell remains at equilibrium at 125°C temperature. [
NbgvÎv wbY©q Ki| [Fe ZworØv‡ii Eox = 0.44V, Cu ZworØv‡ii
0 0 0
Eox = −0.337V] Fe Electrode Eox = 0.44V, Cu Electrode Eox =
Fe(s)|FeSO4 (0.1M)||CuSO4 (aq)|Cu(s) −0.337V]
Fe(s)|FeSO4 (0.1M)||CuSO4 (aq)|Cu(s)
0 RT [Fe2+ ] 0 RT [Fe2+ ]
Ecell = Ecell − nF ln [Cu2+ ]
Ecell = Ecell − nF ln [Cu2+ ]
(0.1) (0.1)
⇒ 0 = 0.777 − 0.017ln [Cu2+] [∵ mvg¨ve¯’vq E = 0] ⇒ 0 = 0.777 − 0.017ln [Cu2+] [∵ At equilibrium, E =
(0.1) 0]
⇒ 45.71 = ln
[Cu2+ ] (0.1)
⇒ 45.71 = ln
⇒ [Cu2+ ] = 1.40 × 10−21 M (Ans. ) [Cu2+ ]
b¤^i eÈb: ⇒ [Cu2+ ] = 1.40 × 10−21 M (Ans. )
0 RT [Fe2+ ] Marks distribution :
Ecell = Ecell − nF ln [Cu2+ ]
m~Î †jLvi Rb¨ 01 b¤^i|
gvb emv‡bvi Rb¨ 04 b¤^i|
[Cu2+ ] = 1.40 × 10−21 M wbY©‡qi Rb¨ 05 b¤^i|
[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e|
m~Î bv wj‡L mivmwi gvb emv‡jI M«nY‡hvM¨ n‡e|]
imvqb
16
e¨vL¨v Ki :
(i) 2d I 3f AiweUvj m¤¢e bq, wKš‘ 2p I 3d AiweUvj m¤¢e|
(ii) Sc †gŠjwU d-eø‡Ki AšÍf©y³ n‡jI Ae¯’všÍi †gŠj bq|
(iii) Ae¯’všÍi †gŠjmg~n cwieZ©bkxj RviY Ae¯’v cÖ`k©b K‡i|
(i) 2d Gi †ÿ‡Î n = 2 Ges l = 2 wKš‘, n = 2 n‡j, l = 2 nIqv
Am¤¢e| †Kbbv †m‡ÿ‡Î ïaygvÎ l = 0,1 cvIqv hvq Ges l = 1 Gi
Rb¨ p AiweUvj m¤¢e| ZvB 2d bv n‡jI 2p m¤¢e|
Abyiƒcfv‡e, 3f Gi †ÿ‡Î, n = 3; l = 3 wKš‘, n = 3 n‡j l = 0,1,2
nIqv m¤¢e|
A_©vr, 3s, 3p, 3d nIqv m¤¢e wKš‘ 3f Am¤¢e|
(ii) Sc(21) = 1s 2 2s2 2p6 3s 2 3p6 3d1 4s2
Sc 3+ = 1s 2 2s2 2p6 3s2 3p6 3d0
Sc 3+ myw¯’Z Avq‡bi 3d − orbital G e− k~b¨| hv Ae¯’všÍi
†gŠ‡ji msÁvi wecixZ| ZvB Sc †gŠjwU d − block n‡jI Ae¯’všÍi
bq|
(iii) Ae¯’všÍi †gŠ‡ji (n − 1)d I ns AiweUv‡ji g‡a¨ kw³i cv_©K¨
Lye mvgvb¨ e‡j Dfq AiweUv‡ji e− eÜb m„wó‡Z AskMÖnY
Ki‡Z cv‡i| ZvB Giv cwieZ©bkxj RviY Ae¯’v cÖ`k©b K‡i|
b¤^i eÈb:
3wU cÖ‡kœi DËi mwVKfv‡e †jLvi Rb¨ (04+03+03) = 10 b¤^i|
imvqb
17
w w
GKwU 30% (w) H2 O2 Gi Rjxq `ªe‡Yi NbZ¡ 1.11 g ∕ mL
| G `ªe‡Y H2 O2 Gi †gvjvwiwU I ‡gvj fMœvsk wbY©q Ki|
30% (w/w) A_©vr, 100 g `ªe‡Y H2 O2 Av‡Q 30g
0 RT [Fe2+ ]
For writing the formula Ecell = Ecell − nF ln [Cu2+ ]
; 01
mark.
For putting the values ; 04 marks.
For determining [Cu2+ ] = 1.40 × 10−21 M ; 05 marks.
[Note: 01 mark will be deducted if unit is not written or
wrong unit is written. Direct input of values without
writing the formula is also acceptable.]
Chem
10
Explain:
(i) 2d and 3f orbitals are impossible but 2p and 3d
orbitals are possible.
(ii) Though Sc is a d-block element, it is not a transition
element.
(iii) Transition elements show variable oxidation
numbers.
(i) In case of 2d , 𝑛 = 2 and 𝑙 = 2 but if 𝑛 = 2, 𝑙 = 2 is
impossible. Because, in that case, only 𝑙 = 0,1 is
obtained and for 𝑙 = 1, p orbital is possible. So, 2p is
possible inspite of 2d being impossible.
Similarly, in case of 3f, 𝑛 = 3, 𝑙 = 3 but if 𝑛 = 3 , 𝑙 =
0,1,2 is possible.
That means, though 3s,3p, 3d is possible, 3f is
impossible.
(ii) Sc(21) = 1s 2 2s2 2p6 3s2 3p6 3d1 4s2
Sc 3+ = 1s 2 2s2 2p6 3s2 3p6 3d0
Stable Sc 3+ ion has 0 e− in 3d-orbital, which is opposite
to the definition of transitional elements. So, though Sc is
a d-block element, it is not a transition element.
(iii) The energy difference between (n − 1)d and ns
orbital of transitional elements is very small and so e−
can take part in bond formation. That is why they show
variable oxidation numbers.
Marks distribution :
For answering 3 questions correctly; (04 + 03 + 03) =
10 marks.
Chem
10
The density of 30% (w) H2 O2 aqueous solution is 1.11 g ∕
mL. Determine the molarity and the mole fraction of H2 O2 in
the solution.
30% (w/w) that, in 100 g solution the amount of H2 O2 is 30g
 100 100
ev, (1.11) mL `ªe‡Y H2 O2 Av‡Q 30g or, in (1.11) mL solution the amount of H2 O2 is 30g
30×1.11×1000 ∴ In 1000 mL solution the amount of H2 O2 =
∴ 1000 mL `ªe‡Y H2 O2 Av‡Q = 100×34
mole =
30×1.11×1000
9.794 mole 100×34
mole = 9.794 mole
∴ cÖ`Ë `ªe‡Y H2 O2 Gi †gvjvwiwU = 9.794 M (Ans. ) ∴ molarity of H2 O2 in the given solution = 9.794 M (Ans.)
Avevi, 100g `ªe‡Y H2 O2 Av‡Q 30g ∴ cvwb Av‡Q Again, in 100g the amount of H2 O2 is 30g ∴ amount of water
(100 − 30) = 70g is (100-30) =70g
30 30
34
∴ H2 O2 Gi †gvj fMœvsk = 34
30 70 = 0.185 (cÖvq) ∴ mole fraction of H2 O2 is = 30 70 = 0.185 (approx.)
( + ) ( + )
34 18 34 18

(Ans.) Marks distribution :

b¤^i eÈb: For determining in 1000 mL solution the amount of H2 O2 =
1000 mL `ªe‡Y H2 O2 Av‡Q 9.794 mole wbY©‡qi Rb¨ 9.794 mole ; 03 marks.
03 b¤^i| For determining molarity of H2 O2 in the given solution =
`ªe‡Y H2 O2 Gi †gvjvwiwU = 9.794 M wbY©‡qi Rb¨ 02 9.794 M ; 02 marks.
b¤^i| For determining the amount of water is =70g ; 02 marks.
For determining the mole fraction of H2 O2 is = 0.185
cvwb = 70g wbY©‡qi Rb¨ 02 b¤^i|
(approx.) ; 03 marks.
H2 O2 Gi †gvj fMœvsk = 0.185 (cÖvq) wbY©‡qi Rb¨ 03
[Note: 01 mark will be deducted if unit is not written or wrong
b¤^i|
unit is written.]
[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv
n‡e|]

imvqb Chem
18 10
4 gm CuSO4 bgybv‡K cvwb‡Z `ªexf‚Z K‡i 350 cc 4 gm CuSO4 is dissolved in water to prepare 350 cc solution. 20 cm3
`ªeY ˆZix Kiv nj| GB `ªe‡Yi 20 cm3 wb‡q Zv‡Z from the solution is taken & mixed with excess KI. Then 15cc of
AwZwi³ KI †hvM K‡i gy³ I2 †K Na2 S2 O3 `ªeY Øviv 0.06 M Na2 S2 O3 solution is needed for the reduction of released I2 .
weRvwiZ Ki‡Z 0.06 M Na2 S2 O3 `ªe‡Yi 15 cc jv‡M| Determine the percentage of cupric salt in that sample.
bgybvwU‡Z wKDwcÖK je‡Yi kZKiv cwigvY wbY©q
Ki|
2 CuSO4 ≡ I2 ≡ 2Na2 S2 O3 2 CuSO4 ≡ I2 ≡ 2Na2 S2 O3
m(Na2 S2 O3 ) = 0.06 × 15 × 10−3 × 158 m(Na2 S2 O3 ) = 0.06 × 15 × 10−3 × 158 = 0.1422 gm
= 0.1422 gm 158 g Na2 S2 O3 ≡ 159.5 gm CuSO4
158 g Na2 S2 O3 ≡ 159.5 gm CuSO4 ∴ 0.1422 g Na2 S2 O3 ≡ 0.14355 gm CuSO4
∴ 0.1422 g Na2 S2 O3 ≡ 0.14355 gm CuSO4 0.14355×350
∴ In 350 cc CuSO4 = gm
0.14355×350 20
∴ 350 cc G CuSO4 = gm = 2.512125 gm.
20
= 2.512125 gm. 2.512125
% of CuSO4 = × 100% = 62.8%
2.512125 4
% of CuSO4 = 4
× 100% = 62.8% Marks distribution :
b¤^i eÈb: For determining m(Na2 S2 O3 ) = 0.1422 gm; 02 marks.
m(Na2 S2 O3 ) = 0.1422 gm wbY©‡qi Rb¨ 02 b¤^i| For determining 0.1422 g Na2 S2 O3 ≡
0.1422 g Na2 S2 O3 ≡ 0.14355 gm CuSO4 0.14355 gm CuSO4 ; 02 marks.
wbY©‡qi Rb¨ 02 b¤^i| For determining the amount of CuSO4 = 2.512125 gm ; 03 marks.
CuSO4 Gi cwigvY 2.512125 gm wbY©‡qi Rb¨ 03 For determining % of CuSO4 = 62.8% ; 03 marks.
b¤^i| [Note: 01 mark will be deducted if unit is not written or wrong unit is
% of CuSO4 = 62.8% wbY©‡qi Rb¨ 03 b¤^i| written.]
[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i
KZ©b Kiv n‡e|]