Eng.

Subject final (2023)

Chemistry, Written, Set-C (Live)

imvqb Chem
01 10
(a) NO− + 2−
3 , NH4 Ges SO4 Avqb¸‡jvi R¨vwgwZK KvVv‡gv (a) Draw the geometric structure of the following ions and
A¼b I Avqb¸‡jvi bvgKiY Ki| naming them. NO− +
3 , NH4 and SO4
2−

(b) Zzu‡Zi †Kjv‡mi MVbwPÎ AvuK| (b) Draw the structure of the blue vitriol crystal.
(a) (a)

NO−
3 (bvB‡UªU Avqb) NO−
3 (Nitrate ion)

NH4+ (A¨v‡gvwbqvg Avqb) NH4+ (Ammonium ion)

SO2−
4 (mvj‡dU Avqb) SO2−
4 (Sulfate ion)

(b) (b)

b¤^i eÈb : Mark Distribution:

(a) Avqb¸‡jvi R¨vwgwZK KvVv‡gv A¼b I Avqb¸‡jvi bvgKiY (a) For writing, the geometric structure of the ions and
mwVKfv‡e ‡jLvi Rb¨; (03 × 02) = 06 b¤^i| naming them ; (03× 02) = 06 marks.
(b) Zzu‡Zi †Kjv‡mi MVbwPÎ mwVKfv‡e AvuKvi Rb¨ 04 (b) For drawing the structure of the blue vitriol crystal 04
b¤^i| marks.

imvqb Chem
02 10
CO2 (g) + H2 (g) ⇌ CO(g) + H2 O(g) GB wewµqvi K C = For the reaction CO2 (g) + H2 (g) ⇌ CO(g) + H2 O(g),
0.137| cªv_wgK Ae¯’vq wewµqv cv‡Î 5mol CO2 , 6mol H2 , K C = 0.137. 5mol CO2 , 6mol H2 , 1 mol CO and
1 mol CO Ges 1 mol H2 O Dcw¯’Z Av‡Q| mvg¨ve¯’vq 1 mol H2 O are present in the container at initial condition.
cª‡Z¨‡Ki NbgvÎv wbY©q Ki| [wewµqv cv‡Îi AvqZb = 2L] Find the concentration of each one at equilibrium. [Volume
of reaction container = 2L]
[CO][H2 O] 1×1 [CO][H2 O] 1×1
QC = [CO2 ][H2 ]
= = 0.0333 < K C QC = [CO2 ][H2 ]
= = 0.0333 < K C
5×6 5×6
∴ wewµqvwU m¤§yLw`‡K AMªmi n‡e| ∴ The reaction will move forward.
 Reaction: CO2 + H2 ⇌ CO + H2 O Reaction: CO2 + H2 ⇌ CO + H2 O
At starting: 5 6 1 1 At starting: 5 6 1 1
At equilibrium: (5– x) (6– x) (1 + x) (1 + x) At equilibrium: (5– x) (6– x) (1 + x) (1 + x)
1+x 1+x 1+x 1+x
[CO][H2 O] ( )( ) (1+x)2 [CO][H2 O] ( )( ) (1+x)2
2 2 2 2
∴ KC = [CO2 ][H2 ]
= 5−x 6−x ⇒ 0.137 = (5−x)(6−x)
∴ KC = [CO2 ][H2 ]
= 5−x 6−x ⇒ 0.137 = (5−x)(6−x)
( )( ) ( )( )
2 2 2 2

⇒ 0.137 (30 − 5x − 6x + x 2 ) = 1 + 2x + x 2 ⇒ 0.137 (30 − 5x − 6x + x 2 ) = 1 + 2x + x 2

⇒ 0.863x 2 + 3.507x − 3.11 = 0 ∴ x = 0.7488 A_ev ⇒ 0.863x 2 + 3.507x − 3.11 = 0 ∴ x = 0.7488 or,
−4.8125 (AMªnY‡hvM¨) −4.8125 (unacceptable)
∴ mvg¨ve¯’vq NbgvÎvmg~nt ∴ Concentration at equilibrium:
5−x 5−0.7488 5−x 5−0.7488
[CO2 ] = = = 2.1256 molL−1 (Ans. ) [CO2 ] =
2
= 2
= 2.1256 molL−1 (Ans. )
2 2
6−x 6 − 0.7488 6−x 6−0.7488
[H2 ] = ( )= = 2.6256 molL−1 (Ans. )
[H2 ] = ( 2 )= 2
= 2.6256 molL−1 (Ans. )
2 2 1+x 1+0.7488
1+x 1 + 0.7488 [CO] = ( 2 )= 2
= 0.8744 molL−1 (Ans. )
[CO] = ( )= = 0.8744 molL−1 (Ans. )
2 2 1+x 1 + 0.7488
1+x 1 + 0.7488 [H2 O] = ( )= = 0.8744 molL−1 (Ans. )
[H2 O] = ( )= = 0.8744 molL−1 (Ans. ) 2 2
2 2
Mark Distribution:
b¤^i eÈb : For writing, the reaction will move forward ; 02 marks.
wewµqvwU m¤§yLw`‡K AMªmi n‡e ; ‡jLvi Rb¨ 02 b¤^i| For determining, x = 0.7488 ; 04 marks.
x = 0.7488 ; wbY©‡qi Rb¨ 04 b¤^i| For determining, the concentration of each one at
mvg¨ve¯’vq cª‡Z¨‡Ki NbgvÎv wbY©‡qi Rb¨ (01×04) = 04 equilibrium ; (01×04) = 04 marks.
b¤^i|

imvqb Chem
03 10
cªgvY Ae¯’vq Pt|Sn2+ , Sn4+ ZworØv‡ii RviY wefe At STP, oxidation potential of the electrode Pt|Sn2+ , Sn4+
−0.15 Volt| Sn4+ I Sn2+ `ªe‡Yi NbgvÎvi AbycvZ KZ n‡j is −0.15 Volt. At 298K temperature, what will be the ratio
298𝐾 ZvcgvÎvq ZworØviwUi RviY wefe −0.1 𝑉𝑜𝑙𝑡 n‡e? of concentration Sn4+ and Sn2+ solution if oxidation
potential has to be −0.1V?
o o
bvb©‡÷i mgxKiY †_‡K cvB- ESn2+/Sn4+ = ESn2+ /Sn4+ − We get from Nernst's equation- ESn2+/Sn4+ = ESn 2+ /Sn4+ −

RT [Sn4+ ] RT [Sn4+ ]
ln ln 2+
nF [Sn2+ ] nF [Sn ]
RT [Sn4+ ] RT [Sn4+ ]
2+ /Sn4+ − ESn2+ /Sn4+ ; Sn
o 2+ o 2+
⇒ ln = ESn → ⇒ nF ln [Sn2+] = ESn2+ /Sn4+ − ESn2+ /Sn4+ ; Sn →
nF [Sn2+ ]
4+
Sn + 2e Sn4+ + 2e
o
cªkœvbymv‡i, E o Sn2+/Sn4+ = −0.15 Volt ; R = According to the question, ESn2+ /Sn4+ = −0.15 Volt ; R =

8.314 J𝐾 −1 𝑚𝑜𝑙 −1 ; 298 K ; ESn2+/Sn4+ = −0.1 Volt 8.314 J𝐾 −1 𝑚𝑜𝑙 −1 ; T = 298 K ; ESn2+/Sn4+ = −0.1 Volt
0.059 [Sn4+ ] 0.059 [Sn4+ ] o
∴ log [Sn2+ ]
= E o Sn2+/Sn4+ − ESn2+/Sn4+ ∴ log = ESn2+ /Sn4+ − ESn2+ /Sn4+
2 2 [Sn2+ ]
[Sn4+ ] −0.15−(−0.1) −0.15+0.1 −0.05 [Sn4+ ] −0.15−(−0.1) −0.15+0.1 −0.05
∴ log [Sn2+] = 0.03
= 0.03
= 0.03
= −1.67 ∴ ∴ log [Sn2+] = = = = −1.67 ∴
0.03 0.03 0.03
[Sn4+ ] [Sn4+ ]
[Sn2+ ]
= 0.02 = 0.02
[Sn2+ ]

b¤^i eÈb: Mark Distribution:

o RT [Sn4+ ] o
ESn2+ /Sn4+ = ESn2+ /Sn4+ − ln 2+ ;m~Î †jLvi Rb¨ 03 For writing formula, ESn2+/Sn4+ = ESn2+ /Sn4+ −
nF [Sn ]
b¤^i| RT [Sn4+ ]
nF
ln [Sn2+ ]
;03 marks.
m~‡Î gvb emv‡bvi Rb¨ 04 b¤^i|
[Sn4+ ]
For putting values correctly in the formula 04 marks.
[Sn2+ ]
= 0.02 ;wbY©‡qi Rb¨ 03 b¤^i|
[Sn4+ ]
For determining, [Sn2+ ]
= 0.02 ;03 marks.

imvqb Chem
04 10
wbw`©ó AvqZ‡bi weï× 𝑂2 e¨vwcZ n‡Z 80 𝑠𝑒𝑐 mgq jv‡M For diffusing pure O2 of a definite volume, time required is
Ges GKB Ae¯’vq mgvb AvqZ‡bi 20% 𝑂3 wgwkªZ 𝑂2 e¨vwcZ 80 sec and under same condition equal volume of O2
n‡Z 85 𝑠𝑒𝑐 mgq jv‡M| 𝑂3 Gi AvYweK fi wbY©q Ki| mixed with 20% O3 takes 85 sec time to diffuse. Determine
the molecular mass of O3.
rO2 M r o2 M
rmix
= √ Mmix ⇒ Mmix = 36.125 [†h‡nZy, G‡¶‡Î, VO2 = rmix
= √ Mmix ⇒ Mmix = 36.125 [In this case, VO2 =
O2 o2
rO2 tmix rO2 tmix
Vmix ; †m‡nZy, = ] Vmix ; ∴ r = tO 2
]
rmix tO 2 mix
20 80 20
⇒ O3 Gi AvYweK fi × 100 + O2 Gi AvYweK fi × 100 = ⇒ Molecular mass of O3  + Molecular mass of O2 
100
80
36.125 = 36.125
20 80 100
⇒ MO 3 × 100
+ 32 × 100
= 36.125 ⇒ MO3 = 20 80
⇒ MO3 × 100 + 32 × 100 = 36.125 ⇒ MO3 =
52.625 (Ans. ) 52.625 (Ans. )

b¤^i eÈb: Mark Distribution:

Mmix = 36.125 ; wbY©‡qi Rb¨ 04 b¤^i| For determining, Mmix = 36.125 ; 04 marks.
For determining, MO3 = 52.625 ; 06 marks.
MO3 = 52.625 ; wbY©‡qi Rb¨ 06 b¤^i|

imvqb Chem
05 10
wb‡Pi wewµqvmg~n m¤ú~Y© Kit Complete the following reactions:
Fe Fe
(a) HC ≡ CH → (a) HC ≡ CH →
400C 400C
2% KMnO4 2% KMnO4
(b) H2 C = CH2 → (b) H2 C = CH2 →
KOH KOH
(c) MgI + H2 O → (c) MgI + H2 O →

H2 SO4 (conc.) H2SO4 (conc.)

(d) + HNO3 → (d) + HNO3 →
100C 100C

MnO2 MnO2
(e) → (e) →
65%H2 SO4 ,45°C 65% H2 SO4 ,45o C

(a) (a)
(b) H2 C − CH2 (b) H2 C − CH2
| | | |
OH OH OH OH

(c) + Mg (OH)I (c) + Mg (OH)I

 NO
2 NO
2

(d) + H2 O (d) + H2 O
NO
2 NO
2
CHO CHO
(e) (e)

b¤^i eÈb: Mark Distribution:

wewµqvmg~n m¤ú~Y© Kivi Rb¨ (02×05) = 10 b¤^i| For completing the reactions ; (02×05) = 10 marks.

imvqb
06
GKwU †Wªb †_‡K 1000 mL cvwb msMªn K‡i Zvi 𝐶𝑂𝐷
wbY©‡qi Rb¨ 𝐷𝑂 cwigvc Ki‡Z wM‡q †`Lv †Mj, 50 𝑚𝐿
bgybv cvwbi Rb¨ 0.025 M Na2 S2 O3 `ªe‡Yi 10 𝑚𝐿
†j‡M‡Q| Gici H bgybv cvwb‡Z H2 SO4 Ges K 2 Cr2 O7 ‡hvM
Kivi 2-3 N›Uv ci 𝐷𝑂 wbY©q Ki‡Z wM‡q †`Lv †Mj Gi 50 𝑚𝐿
cvwbi Rb¨ 0.015 N Na2 S2 O3 `ªe‡Yi 3.5 mL ‡j‡M‡Q| H
bgybv cvwbi 𝐶𝑂𝐷 wbY©q Ki|
Chem
10
To calculate the COD of 1000 mL water collected from a
drain, it was found during the calculation of DO that for 50
mL of sample water 10 mL of 0.025 M Na2 S2 O3 was
needed. Adding H2 SO4 and K 2 Cr2 O7 into the sample water
and after 2-3 hours it was found during the calculation of
DO that for 50 mL water 3.5 mL of 0.015 N Na2 S2 O3 was
needed. Determine the COD of that sample water.

0.025 M Na2 S2 O3 ≡ 0.025 N Na2 S2 O3 0.025 M Na2 S2 O3 ≡ 0.025 N Na2 S2 O3

GLb, Avgiv Rvwb, 1 ml 1 N Na2 S2 O3 ≡ 8 mg `ªexf~Z Now, we know that, 1 ml 1 N Na2 S2 O3 ≡ 8 mg
Aw·‡Rb dissolved oxygen
∴ 10 ml 0.025N Na2 S2 O3 ≡ 8 × 10 × 0.025 mg `ªexf~Z ∴ 10 ml 0.025N Na2 S2 O3 ≡ 8 × 10 × 0.025 mg
Aw·‡Rb dissolved oxygen
myZivs, H2 SO4 Ges K 2 Cr2 O7 ‡hvM Kivi c~‡e© 50 𝑚𝐿 Therefore,before adding H2 SO4 and K 2 Cr2 O7 the DO of
cvwbi DO = 2 mg 50 mL water= 2 mg
Avevi, Again,
1 mL 1 N Na2 S2 O3 ≡ 8 mg `ªexf~Z Aw·‡Rb 1 mL 1 N Na2 S2 O3 ≡ 8 mg dissolved oxygen
∴ 3.5 mL 0.015 N Na2 S2 O3 ≡ 8 × 3.5 × 0.015 mg
∴ 3.5 mL 0.015 N Na2 S2 O3 ≡ 8 × 3.5 × 0.015 mg `ªexf~Z
dissolved oxygen
Aw·‡Rb
Therefore, after adding H2 SO4 and K 2 Cr2 O7 the DO of
myZivs, H2 SO4 Ges K 2 Cr2 O7 ‡hvM Kivi ci 50 𝑚𝐿 cvwbi
50 mL water= 0.42 mg
DO = 0.42 mg
So, lost oxygen from 50 mL water = (2 − 0.42)mg =
myZivs, 50 mL cvwb n‡Z nviv‡bv Aw·R‡b
1.58 mg
= (2 − 0.42)mg = 1.58 mg
That is the COD of 50 mL sample water = 1.58 mg
A_©vr, 50 mL bgybv cvwbi COD = 1.58 mg
∴ That is the COD of 1000 mL sample water =
1.58×1000
∴ 1000 mL bgybv cvwbi COD = mg = 31.6 mg 1.58×1000
50 mg = 31.6 mg
50
myZivs, bgybv cvwbi COD n‡”Q 31.6 ppm (Ans: )
Therfore, the COD of the supplied sample water is
31.6 ppm (Ans: )
b¤^i eÈb:
H2 SO4 Ges K 2 Cr2 O7 †hvM Kivi c~‡e© 50 ml cvwbi DO = Mark Distribution:
2 mg ;wbY©‡qi Rb¨ 02 b¤^i|
For determining, before adding H2 SO4 and K 2 Cr2 O7 the
H2 SO4 Ges K 2 Cr2 O7 †hvM Kivi ci 50 ml cvwbi DO = DO of 50 mL water = 2 mg ;02 marks.
0.42 mg ;wbY©‡qi Rb¨ 02 b¤^i|
50 ml bgybv cvwbi COD = 1.58 mg ;wbY©‡qi Rb¨ 02
b¤^i|
bgybv cvwbi COD = 31.6 ppm ;wbY©‡qi Rb¨ 04 b¤^i|
[we:`ª: GKK bv wjL‡j A_ev fzj GKK wjL‡j 01 b¤^i KZ©b Kiv
n‡e| m~Î bv wj‡L mivmwi gvb emv‡jI m~‡Îi Rb¨ eivÏK…Z
b¤^i cv‡e|]
For determining, after adding H2 SO4 and K 2 Cr2 O7 the
DO of 50 ml water = 0.42 mg ;02 marks.
For determining, COD of 50 ml water = 1.58 mg ;02
marks.
For determining,
COD of the supplied water specimen = 31.6 ppm ;04
marks.
[N:B: 01 mark will be deducted if unit is not written or
wrong unit is written. Direct input of values without writing
formula is also acceptable.]

imvqb
07
MnO2 I HCl Gi wewµqvq Cl2 Drcbœ nq| 37°C ZvcgvÎv I
2.5 atm Pv‡c 4.0425 dm3 Cl2 Drcbœ Ki‡Z MnO2 Gi mv‡_
35 % (W ∕ W) Ges 1.125 Av‡cw¶K ¸iæZ¡ wewkó 𝐻𝐶𝑙
`ªe‡Yi KZ AvqZb wewµqv Kiv‡bvi cª‡qvRb n‡e?
Chem
10
MnO2 and HCl reacts to produce Cl2 . At temperature 37°C
and pressure 2.5 atm what volume of HCl solution of
specific gravity 1.125 is added to MnO2 of concentration
35 % (W ∕ W) to produce 4.0425 dm3 Cl2?

MnO2 + 4 HCl → MnCl2 + 2H2 O + Cl2; 37°C ZvcgvÎv I MnO2 + 4 HCl → MnCl2 + 2H2 O + Cl2; at temperature of
2.5 atm Pv‡c 4.0425 dm3 Cl2; cªgvY ZvcgvÎv I Pv‡c n‡e = 37°C and pressure 2.5 atm 4.0425 dm3 Cl2; it will be at
2.5×4.0425 273 2.5×4.0425
310
× 1 dm3 = 8.9 dm3 standard temperature and presure =
310
×
273
wewµqv n‡Z †`Lv hvq, 22.4 Litre (S. T. P. ‡Z) Cl2 M¨vm dm3 = 8.9 dm3
1
Drcbœ nq (4 × 36.5)g HCl n‡Z From the reaction it is seen that, 22.4 Litre (S. T. P.) Cl2
∴ 8.9 Litre (S. T. P) ‡Z 𝐶𝑙2 M¨vm Drcbœ nq gas is produced from (4 × 36.5)g HCl
4×36.5×8.9
g HCl = 58g HCl n‡Z ∴ 8.9 Litre (S. T. P) Cl2 gas is produced from
22.4
4×36.5×8.9
GLb, 35% (𝑤/𝑤) 𝐻𝐶𝑙 `ªeY A_©vr, 22.4
g HCl = 58g HCl
100
35 𝑔 𝐻𝐶𝑙 _v‡K 100 𝑔 `ªe‡Y ev, mL `ªe‡Y Now, 35% (w/w) HCl solution that is,
1.125
100
100×58
∴ 58 g HCl _v‡K 1.125×35 mL `ªe‡Y = 147.302 ml `ªe‡Y| 35 g HCl is present in 100 g solution or, in mL
1.125

myZivs, 147.302 mL HCl `ªeY cª‡qvRb n‡e (Ans.) solution

100×58
∴ 58 g HCl is present in 1.125×35 mL = 147.302 ml
b¤^i eÈb: solution.
Therefore, 147.302 mL HCl solution will be needed (Ans.)
cªgvY ZvcgvÎv I Pv‡c n‡e 8.9 dm3 ; wbY©‡qi Rb¨ 03
b¤^i| Mark Distribution:
8.9 Litre (S. T. P) ‡Z 𝐶𝑙2 M¨vm Drcbœ nq = 58g HCl n‡Z ; For determining, at standard temperature and pressure
wbY©‡qi Rb¨ 03 b¤^i| 8.9 dm3 ; 03 marks.
For determining, 8.9 Litre (S. T. P) Cl2 gas is produced
147.302 mL HCl `ªeY cª‡qvRb n‡e ; wbY©‡qi Rb¨ 04 from 58g HCl ; 03 marks.
b¤^i| For determining, 147.302 mL HCl solution will be needed
; 04 marks.
[we:`ª: GKK bv wjL‡j A_ev fzj GKK wjL‡j 01 b¤^i KZ©b Kiv
[N.B: 01 mark will be deducted if unit is not written or
n‡e|]
wrong unit is written.]
imvqb Chem
08 10

C cv‡Î (A + B) wgkÖ `ªeY †hvM Kiv n‡j cÖvß bZzb If (A + B) mixed solution is added to container C,
wgkÖ‡Yi pOH wbY©q Ki| determine pOH of the newly obtained mixture.
(A + B) wgkÖ `ªe‡Y, In (A + B) mixture solution,
nNaOH = 0.02 mol nNaOH = 0.02 mol
nH2 SO4 = 9 × 10−3 mol nH2 SO4 = 9 × 10−3 mol
H2 SO4 + 2NaOH → Na2 SO4 + 2H2 O H2 SO4 + 2NaOH → Na2 SO4 + 2H2 O
nNaOH −3 nNaOH
2
= 0.01 > 9 × 10 2
= 0.01 > 9 × 10−3
∴ cÖkg‡bi ci NaOH Aewkó _vK‡e = 0.02 − 2 × 9 × ∴ after neutralization, remaining NaOH = 0.02 −
10−3 = 2 × 10−3 mol 2 × 9 × 10−3 = 2 × 10−3 mol
bZzb wgkÖ‡Yi pH = − log(1.85 × 10−5 ) + pH of newly obtained mixture = − log(1.85 × 10−5 ) +
300×0.1×10−3 +2×10−3 300×0.1×10−3 +2×10−3
log 200×0.1×10−3 −2×10−3 = 4.73 + 0.25 = 4.98 log 200×0.1×10−3 −2×10−3 = 4.73 + 0.25 = 4.98
∴ pOH = 14 − 4.98 = 9.02 ∴ pOH = 14 − 4.98 = 9.02
b¤^i eÈbt Marks distribution :
cÖkg‡bi ci NaOH Aewkó _vK‡e = 2 × 10−3 mol; wbY©q For determining after neutralization, remaining NaOH =
Kivi Rb¨ 02 b¤^i| 2 × 10−3 mol ; 02 marks.
300×0.1×10−3 +2×10−3 For determining pH = − log(1.85 × 10−5 ) +
pH = − log(1.85 × 10−5 ) + log
200×0.1×10−3 −2×10−3 300×0.1×10−3 +2×10−3
log 200×0.1×10−3 −2×10−3 ; 03 marks.
wbY©q Kivi Rb¨ 03 b¤^i|
pH = 4.98 ; wbY©q Kivi Rb¨ 03 b¤^i| For determining pH = 4.98; 03 marks.
pOH = 9.02 ; wbY©q Kivi Rb¨ 02 b¤^i| For determining pOH = 9.02; 02 marks.

imvqb Chem
09 10
25o C ZvcgvÎvq N2 O4 Gi we‡qvRb wewµqv: N2 O4 (g) ⇌ At 25o C temperature, decomposition reaction of N2 O4:
2NO2 (g) ; mvg¨ve¯’vq N2 O4 I NO2 Gi AvswkK Pvc N2 O4 (g) ⇌ 2NO2 (g) ; at equilibrium, if the partial
h_vµ‡g 0.61 atm I 0.39 atm n‡j wewµqv cv‡Îi AvqZb pressure of N2 O4 and NO2 are 0.61 atm and 0.39 atm
wbY©q Ki| respectively, determine the volume of the reaction
container.
N2 O4 (g) ⇌ 2NO2 (g) N2 O4 (g) ⇌ 2NO2 (g)
t = 0: 1 0 t = 0: 1 0
t = t: 1−α 2α t = t: 1−α 2α
0.392 0.392
Kp = 0.61
= 0.25 Kp = 0.61
= 0.25
P = 0.61 + 0.39 = 1 atm P = 0.61 + 0.39 = 1 atm
4α2 p 4α2 4α2 p 4α2
K p = 1−α2 = 0.25 ⇒ 1−α2 = 0.25 K p = 1−α2 = 0.25 ⇒ 1−α2 = 0.25
∴ 4.25α2 = 0.25 ∴ 4.25α2 = 0.25
∴ α = 0.24 mol ∴ α = 0.24 mol
 4α2 K 4α2 K
K c = V(1−α) = (RT)p∆n K c = V(1−α) = (RT)p∆n
4×0.242 0.25 4×0.242 0.25
∴ = (0.0821×298)1 ∴ = (0.0821×298)1
V(1−0.24) V(1−0.24)
∴ V = 29.67 L ∴ V = 29.67 L
b¤^i eÈbt Marks distribution :
K p = 0.25 ; wbY©q Kivi Rb¨ 01 b¤^i| For determining, K p = 0.25; 01 mark.
4α2 p 4α2 p
K p = 1−α2 ; wbY©q Kivi Rb¨ 01 b¤^i| For determining, K p = 1−α2; 01 mark.
gvb emv‡bvi Rb¨ 01 b¤^i| For putting values; 01 mark.
α = 0.24 mol ; wbY©q Kivi Rb¨ 02 b¤^i| For determining, α = 0.24 mol; 02 marks.
4α2 K 4α2 Kp
K c = V(1−α) = (RT)p∆n; wbY©q Kivi Rb¨ 01 b¤^i| For determining, K c = V(1−α) = (RT)∆n; 01 mark.

gvb emv‡bvi Rb¨ 01 b¤^i| For putting values; 01 mark.

V = 29.67 L; wbY©q Kivi Rb¨ 03 b¤^i|
[we.`«t GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv
n‡e| m~Î bv wj‡L mivmwi mwVK gvb emv‡jI m~‡Îi Rb¨
eivÏK…Z b¤^i c«`vb Kiv n‡e|]
For determining, V = 29.67 L; 03 marks.
[Note: 01 mark will be deducted if unit is not written or
wrong unit is written. The mark allocated for the formula
will be provided even if the correct value is put directly
without writing the formula.]

imvqb Chem
10 10
500mL AvqZ‡bi 2M Ni(NO3 )2 `ªe‡Yi ga¨w`‡q 3500mA 3500mA electricity is passed through Ni electrode for 4
we`y¨r 4 NÈv a‡i Ni ZworØv‡ii gva¨‡g Pvjbv Kiv nj| Zwor hours through 2M Ni(NO3 )2 solution having 500mL
we‡køl‡Yi c~‡e© A¨v‡bvW I K¨v‡_v‡Wi fi h_vµ‡g 40g I volume. If the mass of the anode and cathode before
80g n‡j Zworwe‡køl‡Yi ci- electrolysis are 40g and 80g respectively, then after
(a) A¨v‡bvW Ges K¨v‡_v‡Wi fi KZ n‡e? electrolysis-
(b) `ªe‡Yi cwiewZ©Z NbgvÎv KZ n‡e? (a) How much will be the mass of anode and cathode ?
(b) How much will be the changed concentration of
solution ?
Mit 58.7×3.5×4×3600 Mit 58.7×3.5×4×3600
(a) W = = = 15.33g (a) W = = = 15.33g
nF 2×96500 nF 2×96500
∴ Zworwe‡køl‡Yi ci A¨v‡bv‡Wi fi = 40 − 15.33 = ∴ Mass of anode after electrolysis = 40 − 15.33 =
24.67 g 24.67 g
K¨v‡_v‡W fi = 80 + 15.33 = 95.33 g Mass of cathode = 80 + 15.33 = 95.33 g
(b) GLv‡b, Ni(NO3 )2 Gi `ªe‡Y Ni ZworØvi e¨envi Kiv (b) Here, Ni electrode was used in Ni(NO3 )2 solution.
n‡q‡Q| By decaying of Ni from anode, it comes to the solution as
A¨v‡bvW †_‡K Ni ÿqcÖvß n‡q Ni2+ wnmv‡e `ªe‡Y Ni2+ , where Ni2+ ion of the solution will be deposited as
Avm‡e †hLv‡b `ªe‡Yi Ni2+ , Ni(s) AvKv‡i K¨v‡_vW Rgv Ni(s) in the cathode. As a result, the concentration of the
n‡e d‡j `ªe‡Yi NbgvÎv c~‡e©i gZB _vK‡e| solution will remain the same as before.
A_©vr, S ′ = 2M (Ans. ) That means, S ′ = 2M (Ans. )
Marks distribution :
b¤^i eÈbt
(a)
(a)
Mit
Mit For writing, W = ; 01 mark.
W= nF
; ‡jLvi Rb¨ 01 b¤^i| nF
For putting values 01 mark.
gvb emv‡bvi Rb¨ 01 b¤^i|
For determining, W = 15.33g ; 01 mark.
W = 15.33g ; wbY©q Kivi Rb¨ 01 b¤^i|
For determining, Mass of electrode = 24.67 g ; 02
A¨v‡bv‡Wi fi = 24.67 g; wbY©q Kivi Rb¨ 02 b¤^i|
marks.
K¨v‡_v‡W fi = 95.33 g; wbY©q Kivi Rb¨ 02 b¤^i|
(b)
Ni(NO3 )2 Gi `ªe‡Y Ni ZworØvi e¨envi Kiv n‡q‡Q|
A¨v‡bvW †_‡K Ni ÿqcÖvß n‡q Ni2+ wnmv‡e `ªe‡Y
Avm‡e †hLv‡b `ªe‡Yi Ni2+ , Ni(s) AvKv‡i K¨v‡_vW Rgv
n‡e d‡j `ªe‡Yi NbgvÎv c~‡e©i gZB _vK‡e ‡jL‡j 02 b¤^i|
S ′ = 2M; wbY©q Kivi Rb¨ 01 b¤^i|
[we.`«t GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv
n‡e| m~Î bv wj‡L mivmwi mwVK gvb emv‡jI m~‡Îi Rb¨
eivÏK…Z b¤^i c«`vb Kiv n‡e|]
For determining, Mass of cathode = 95.33 g ; 02 marks.
(b)
For writing Ni electrode was used in Ni(NO3 )2 solution.
By decaying of Ni from anode, it comes to the solution as
Ni2+ , where Ni2+ ion of the solution will be deposited as
Ni(s) in the cathode. As a result, the concentration of the
solution will remain the same as before ; 02 marks.
For determining, S ′ = 2M; 01 mark.
[Note: 01 mark will be deducted if unit is not written or
wrong unit is written. The mark allocated for the formula
will be provided even if the correct value is put directly
without writing the formula.]

imvqb Chem
11 10
Cn H2n+2 O(n = 4) Gi m¤¢ve¨ mKj MvVwbK mgvYy¸‡jv Write down all the possible structural isomers of
wjL Ges Av‡jvK mwµq mgvYywU wPwýZ Ki| Cn H2n+2 O(n = 4) and identify the optical isomers.
n = 4 n‡j †hŠMwU C4 H10 O| Gi MvVwbK mgvYymg~n: If n = 4 , the compound is C4 H10 O. Its structural
A¨vj‡Kvnj: isomers:
(i) CH3 − CH2 − CH2 − CH2 − OH or, Alcohol:
OH (i) CH3 − CH2 − CH2 − CH2 − OH or,
|
OH
(ii) CH3 − CH2 − CH − CH3 or, ; hv Av‡jvK |
(ii) CH3 − CH2 − CH − CH3 or, ;Which is
mwµq KviY KvBivj Kve©b Dcw¯’Z|
CH3 optically active as chiral Carbon is present.
| CH3
(iii) CH3 − CH − CH2 − OH or, |
CH3 (iii) CH3 − CH − CH2 − OH or,
| CH3
(iv) CH3 − C − OH or, |
|
CH3 (iv) CH3 − C − OH or,
|
B_vi: CH3

(v) CH3 − CH2 − O − CH2 − CH3 or, Ether:

(v) CH3 − CH2 − O − CH2 − CH3 or,
(vi) CH3 − CH2 − CH2 − O − CH3 or,
CH3 (vi) CH3 − CH2 − CH2 − O − CH3 or,
| CH3
(vii) CH3 − CH − O − CH3 or, |
(vii) CH3 − CH − O − CH3 or,
b¤^i eÈbt
†hŠMwU wPwýZKi‡Y 01 b¤^i| Marks distribution :
7wU MvVwbK mgvYy †jL‡j (1×7) = 07 b¤^i| For identifying the compound ; 01 mark.
For writing 7 structural isomers; (1×7) = 07 marks.
Av‡jvK mwµq mgvYywU wPwýZKi‡Y 02 b¤^i|
For identifying the optical isomers; 02 marks.

imvqb Chem
12 10
25o C ZvcgvÎvq Ag 2 CrO4 Gi `ªve¨Zvi ¸Ydj 9 × 10−12 n‡j At 25o C temperature, if the solubility product of
Ag 2 CrO4 is 9 × 10−12, how many times will be the
0.1M AgNO3 `ªe‡Y Ag 2 CrO4 Gi `ªve¨Zvi Zzjbvq weï× solubility of Ag 2 CrO4 in pure water in comparison to its
cvwb‡Z Dnvi `ªve¨Zv KZ¸Y n‡e? wbY©q Ki| solubility in 0.1M AgNO3 solution at the same
temperature? Determine.
Ag 2 CrO4 (s) ⇌ 2Ag + (aq) + CrO2−
4 (aq) Ag 2 CrO4 (s) ⇌ 2Ag + (aq) + CrO2− 4 (aq)
awi, weï× cvwb‡Z Ag 2 CrO4 Gi `ªve¨Zv S molL−1 Let, the solubility of Ag 2 CrO4 in pure water is S molL−1
∴ 4S 3 = 9 × 10−12 ∴ 4S 3 = 9 × 10−12
∴ S = 1.31 × 10−4 M ∴ S = 1.31 × 10−4 M
0.1M AgNO3 `ªe‡Y Ag 2 CrO4 Gi `ªve¨Zv S1 molL−1 n‡j If the solubility of Ag 2 CrO4 in 0.1M AgNO3 solution is
(2S1 + 0.1)2 × S1 = 9 × 10−12 S1 molL−1 , (2S1 + 0.1)2 × S1 = 9 × 10−12
∴ 0.01 S1 = 9 × 10−12 ∴ 0.01 S1 = 9 × 10−12
∴ S1 = 9 × 10−10 molL−1 ∴ S1 = 9 × 10−10 molL−1
∴ 0.1M AgNO3 `ªe‡Y Ag 2 CrO4 Gi `ªve¨Zvi Zzjbvq weï× 1.31×10−4
∴ the solubility of Ag 2 CrO4 in pure water is 9×10−10
or
1.31×10−4 5
cvwb‡Z Gi `ªve¨Zv ev, 1.46 × 10 ¸Y n‡e| 5
1.46 × 10 times than in 0.1M AgNO3 solution.
9×10−10
b¤^i eÈbt Marks distribution :
S = 1.31 × 10−4 M ; wbY©q Kivi Rb¨ 03 b¤^i| For determining S = 1.31 × 10−4 M ; 03 marks.
S1 = 9 × 10−10 molL−1 ; wbY©q Kivi Rb¨ 03 b¤^i| For determining, S1 = 9 × 10−10 molL−1 ; 03 marks.
‘0.1M AgNO3 `ªe‡Y Ag 2 CrO4 Gi `ªve¨Zvi Zzjbvq weï× For determining, ‘the solubility of Ag 2 CrO4 in pure
cvwb‡Z Gi `ªve¨Zv 1.46 × 105 ¸Y n‡e’; wbY©q Kivi Rb¨ water is 1.46 × 105 times than in 0.1M AgNO3 solution’;
04 b¤^i| 04 marks.
[Note: 01 mark will be deducted if unit is not written or
[we.`«t GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv
wrong unit is written. The mark allocated for the formula
n‡e| m~Î bv wj‡L mivmwi mwVK gvb emv‡jI m~‡Îi Rb¨
will be provided even if the correct value is put directly
eivÏK…Z b¤^i c«`vb Kiv n‡e]
without writing the formula.]

imvqb Chem
13 10
∆λ = λmax − λmin , (z = 1) ∆λ = λmax − λmin , (z = 1)
wb‡Pi wmwiR¸‡jv‡K Zv‡`i ∆λ Gi gv‡bi µgvbymv‡i mvRvI: Arrange the following series according to its value of ∆λ:
evgvi wmwiR, eªv‡KU wmwiR, dzbW wmwiR Balmer series, Brackett series, Pfund series
1 1 1 1 1 1
evgvi wmwi‡Ri, λ = R H × (22 − 32 ) For Balmer series, λ = R H × (22 − 32 )
max max
7.2 7.2
∴ λmax = ∴ λmax = RH
RH
1 1 1 1 1 1
= R H × (22 − ∞2 ) λmin
= R H × (22 − ∞2 )
λmin
4 4
λmin = λmin = R
RH H
3.2 3.2
∆λ1 = ∆λ1 = RH
RH
1 1 1 1 1 1
eªv‡KU wmwi‡Ri, λ = R H × (42 − 52 ) For Brackett series, λ = R H × (42 − 52 )
max max
44.44 44.44
∴ λmax = ∴ λmax = RH
RH
1 1 1 1 1 1
= R H × (42 − ∞2 ) λmin
= R H × (42 − ∞2 )
λmin
16 16
∴ λmin = R ∴ λmin = R
H H
28.44 28.44
∆λ2 = ∆λ2 =
RH RH
1 1 1 1 1 1
dzbW wmwi‡Ri, = RH × ( − ) For Pfund series, , = RH × ( − )
λmax 52 62 λmax 52 62
 81.82 81.82
∴ λmax = RH
∴ λmax = RH
1 1 1 1 1 1
= RH × ( − ) = RH × ( − )
λmin 52 ∞2 λmin 52 ∞2
25 25
∴ λmin = R ∴ λmin = R
H H
56.82 56.82
∆λ3 = RH
∆λ3 = RH
∴ ∆λ3 > ∆λ2 > ∆λ1 ∴ ∆λ3 > ∆λ2 > ∆λ1
∴ dzbW wmwiR > eªv‡KU wmwiR > evgvi wmwiR ∴ Pfund series > Brackett series > Balmer series
b¤^i eÈbt Marks distribution :
7.2 7.2
λmax = R ; wbY©q Kivi Rb¨ 01 b¤^i| For determining, λmax = R ; 01 mark.
H H
4 4
λmin = R ; wbY©q Kivi Rb¨ 01 b¤^i| For determining, λmin = R ; 01 mark.
H H
3.2 3.2
∆λ1 = R ; wbY©q Kivi Rb¨ 01 b¤^i| For determining, ∆λ1 = R ; 01 mark.
H H
44.44 44.44
λmax = R ; wbY©q Kivi Rb¨ 01 b¤^i| For determining, λmax = R ; 01 mark.
H H
16 16
λmin = ; wbY©q Kivi Rb¨ 01 b¤^i| For determining, λmin = R ; 01 mark.
RH H
28.44 28.44
∆λ2 = R ; wbY©q Kivi Rb¨ 01 b¤^i| For determining, ∆λ2 = ; 01 mark.
H
RH
81.82 81.82
λmax = R ; wbY©q Kivi Rb¨ 01 b¤^i| For determining, λmax = R ; 01 mark.
H H
25 25
λmin = R ; wbY©q Kivi Rb¨ 01 b¤^i| For determining, λmin = R ; 01 mark.
H H
56.82 56.82
∆λ3 = R ; wbY©q Kivi Rb¨ 01 b¤^i| For determining, ∆λ3 = ; 01 mark.
RH
H

dzbW wmwiR> eªv‡KU wmwiR > evgvi wmwiR; wbY©q For determining, Pfund series > Brackett series > Balmer
Kivi Rb¨ 01 b¤^i| series; 01 mark.

imvqb
14
A = [Cu(NH3 )4 ]SO4 GKwU †hŠM|
(a) A †hŠ‡Mi RwUj Avq‡bi R¨vwgwZK AvK…wZ I Cu2+ Gi
msKiY Ae¯’v D‡jøL Ki|
(b) †hŠMwU‡Z Dcw¯’Z eÜbmg~‡ni cÖK…wZ I Zv‡`i
msL¨v D‡jøL Ki|
(a) mgZjxq eM©vKvi, sp2 d |
(b) [Cu(NH3 )4 ]2+ + SO2−
4 (b) [Cu(NH3 )4 ]2+ + SO2−4
AvqwbK eÜb msL¨v = 1 wU (K¨vUvqb msL¨v = A¨vbvqb
msL¨v = 1)
mg‡hvRx eÜb msL¨v = 4 × 3 + 2 = 14 wU|
mwbœ‡ek mg‡hvRx eÜb msL¨v = 4 + 2 = 6 wU|
Chem
10
A = [Cu(NH3 )4 ]SO4 is a compound.
(a) Mention the geometric shape of complex ion of the
compound A and the hybridization state of Cu2+.
(b) Mention the nature of bonds present in the compound
and their number.
(a) Square planar, sp2 d
No. Of ionic bonds = 1 (no. of cation =no. of anion=1)
no. of covalent bonds = 4 × 3 + 2 = 14
no. Of coordinate covalent bonds = 4 + 2 = 6

Marks distribution :
b¤^i eÈbt (a) For writing square planar, sp2 d; 04 marks.
(a) mgZjxq eM©vKvi, sp2 d ‡jL‡j 04 b¤^i| (b) For determining, nature of bonds and their number;
(b) cÖK…wZ I msL¨v; wbY©q Kivi Rb¨ (2×3) = 06 b¤^i| (2×3) = 06 marks.

imvqb Chem
15 10
(a) B‡jKUªb Avmw³i µgvbymv‡i mvRvI: O, S, Se, Te (a) Arrange according to the order of electron affinity :
(b) Zwor FYvZ¥KZvi µgvbymv‡i mvRvI: Cl, S, F, O O, S, Se, Te
(c) AiweUvj¸‡jv‡K AveiYx cÖfv‡ei µgvbymv‡i mvRvI: (b) Arrange according to the order of electronegativity :
s, p, d, f Cl, S, F, O
(d) Mjbv‡¼i µgvbymv‡i mvRvI: Na, K, Rb, Cs (c) Arrange the orbitals according to the order of
(e) AvqwbKiY wef‡ei gv‡bi µgvbymv‡i mvRvI: Al, Mg, P, S shielding effect : s, p, d, f
(d) Arrange according to the order of melting point :
Na, K, Rb, Cs
(e) Arrange according to the order of ionization
potential : Al, Mg, P, S
(a) S > Se > Te > O (a) S > Se > Te > O
(b) F > O > Cl > S (b) F > O > Cl > S
(c) s > p > d > f (c) s > p > d > f
(d) Na > K > Rb > Cs (d) Na > K > Rb > Cs
(e) P > S > Mg > Al (e) P > S > Mg > Al
b¤^i eÈbt Marks distribution :
5wUi Rb¨ (2×5) = 10 b¤^i| For five; (2×5) = 10 marks.

imvqb Chem
16 10
GKwU †U÷wUD‡e mvj‡dU jeY wb‡q K‡qK †duvUv In a test tube, when some drops of Potassium
cUvwkqvg †d‡ivmvqvbvBW `ªeY †hvM Kiv n‡j jvj‡P Ferrocyanide solution are added to Sulphate salt, reddish
ev`vwg Aa:‡ÿc Drcbœ nq| jeYwU‡Z Dcw¯’Z K¨vUvqb brown precipitate is produced. Identify the cation present
wPwýZ Ki Ges †gŠjwUi †hvR¨Zv I me©‡kl B‡jKUª‡bi Rb¨ in the salt and show the the application of Pauli’s
cvDwji eR©b bxwZi cÖ‡qvM †`LvI| exclusion Principle for the Valency and last electron of
the element.
K¨vUvqb Cu2+ Cation Cu2+
2CuSO4 + K 4 [Fe(CN)6 ] → Cu2 [Fe(CN)6 ] + 2K 2 SO4 2CuSO4 + K 4 [Fe(CN)6 ] → Cu2 [Fe(CN)6 ] + 2K 2 SO4
লালচে বাদামি reddish brown
2 2 6 2
Cu(29): 1s 2s 2p 3s 3p 3d 6 10
4s 1 Cu(29): 1s 2 2s2 2p6 3s 2 3p6 3d10 4s1
1 1
†hvR¨Zv B‡jKUª‡bi Rb¨: n = 4, l = 0, m = 0, s = + 2 For Valence electron : n = 4, l = 0, m = 0, s = + 2
1
me©‡kl B‡jKUª‡bi Rb¨: n = 3, l = 2, m = +2/−2, s = For the last electron: n = 3, l = 2, m = +2/−2, s = − 2
1
−2 Here, the value of the four quantum numbers of the two
GLv‡b, B‡jKUªb؇qi †Kvqv›Uvg msL¨v PviwUi gvb GK electrons are not the same. That means, Pauli’s exclusion
bq| A_©vr, cvDwji eR©b bxwZ AYym„Z n‡q‡Q| principle is followed.
Marks distribution :
b¤^i eÈbt
For determining, Cation Cu2+; 01 mark.
K¨vUvqb Cu2+; wbY©q Kivi Rb¨ 01 b¤^i|
For determining, 2CuSO4 + K 4 [Fe(CN)6 ] →
2CuSO4 + K 4 [Fe(CN)6 ] → Cu2 [Fe(CN)6 ] + 2K 2 SO4 ;
লালচে বাদামি Cu2 [Fe(CN)6 ] + 2K 2 SO4; 02 marks.
reddish brown
wbY©q Kivi Rb¨ 02 b¤^i|
For determining, Cu(29): 1s 2 2s2 2p6 3s 2 3p6 3d10 4s1;
Cu(29): 1s 2 2s2 2p6 3s 2 3p6 3d10 4s1 ; wbY©q Kivi Rb¨ 01 mark.
01 b¤^i| For Valence electron ; 02 marks.
†hvR¨Zv B‡jKUª‡bi Rb¨ 02 b¤^i| For the last electron ; 02 marks.
me©‡kl B‡jKUª‡bi Rb¨ 02 b¤^i| For writing the value of the four quantum numbers of the
B‡jKUªb؇qi †Kvqv›Uvg msL¨v PviwUi gvb GK bq| two electrons are not the same. That means, Pauli’s
A_©vr, cvDwji eR©b bxwZ Abym…Z n‡q‡Q †jLvi Rb¨ 02 exclusion principle is followed; 02 marks.
b¤^i|

imvqb Chem
17 10
GKwU †mZz wbg©v‡Yi Rb¨ A I B †Kv¤úvwbi h_vµ‡g 3g I For building a bridge, 3g and 2g sample steel from two
2g K‡i bgybv w÷j `ywU c„_K weKv‡i wb‡q companies A and B respectively are taken in two separate
100mL H2 SO4 †hvM Kiv n‡jv| cÖvß `ªeYØq‡K beakers and 100mL H2 SO4 is added.
UªvB‡Uªkb Ki‡Z h_vµ‡g 15 mL 0.4 M K 2 Cr2 O7 Ges 15 mL 0.4 M K 2 Cr2 O7 and 20mL 0.3M KMnO4
20mL 0.3M KMnO4 `ªeY cÖ‡qvRb nq| †mZz wbg©v‡Yi solutions respectively are required in order to titrate the
†Kvb †Kv¤úvwbi w÷j e¨envi jvfRbK n‡e? two obtained solutions. Using steel from which company
is profitable for building the bridge ?
1mol K 2 Cr2 O7 = 6 mol Fe 1mol K 2 Cr2 O7 = 6 mol Fe
6×55.85×15×0.4 6×55.85×15×0.4
∴ 15mL 0.4 M K 2 Cr2 O7 = 1000
g Fe = ∴ 15mL 0.4 M K 2 Cr2 O7 = 1000
g Fe =
2.0106 g Fe 2.0106 g Fe
2.0106 2.0106
∴ †jvnvi weï×Zv, x = × 100% = 67.02% ∴purity of iron, x = × 100% = 67.02%
3 3
1 mol KMnO4 = 5 mol Fe 1 mol KMnO4 = 5 mol Fe
5×55.85×20×0.3 5×55.85×20×0.3
∴ 20mL 0.3 M KMnO4 = 1000
g Fe = 1.675 g ∴ 20mL 0.3M KMnO4 = 1000
g Fe = 1.675 g
1.675 1.675
∴ †jvnvi weï×Zv, y = 2
× 100% = 83.775% ∴ purity of iron, y = 2
× 100% = 83.775%
∵ y > x ∴ B †Kv¤úvwbi w÷j e¨envi jvfRbK| ∵ y > x ∴ using steel from B company is profitable.
b¤^i eÈbt Marks distribution :
15mL 0.4 M K 2 Cr2 O7 = 2.0106 g Fe wbY©q Kivi Rb¨ For determining, 15mL 0.4 M K 2 Cr2 O7 = 2.0106 g Fe ;
02 b¤^i| 02 marks.
x = 67.02% ; wbY©q Kivi Rb¨ 02 b¤^i| For determining, x = 67.02%; 02 marks.
20mL 0.3 M KMnO4 = 1.675 g ; wbY©q Kivi Rb¨ 02 For determining, 20mL 0.3 M KMnO4 = 1.675 g; 02
b¤^i| marks.
y = 83.775% ; wbY©q Kivi Rb¨ 02 b¤^i| For determining, y = 83.775% ; 02 marks.
For writing, using steel from B company is profitable; 02
B †Kv¤úvwbi w÷j e¨envi jvfRbK; ‡jL‡j 02 b¤^i|
marks.
[we.`«t GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv
[Note: 01 mark will be deducted if unit is not written or
n‡e|]
wrong unit is written.]

imvqb
18
`ywU wfbœ ˆRe †hŠM A I B Gi DfqB Av‡qv‡Wvdg©
wewµqvq CHI3 I CH3 COONa Drcbœ K‡i| A †K weRvwiZ
Ki‡j B Drcbœ nq| Avevi, A †hŠMwU jNy KOH Gi
Chem
10
Two different organic compounds A and B both produces
CHI3 and CH3 COONa by iodoform reaction. B is
produced from the reduction of A. Again, compound A
produces compound C with chloroform (CHCl3 ) in
Dcw¯’wZ‡Z †K¬v‡ivdg© (CHCl3 ) mnKv‡i C †hŠM Drcbœ
K‡i| A, B I C Dchy³ wewµqvmn kbv³ Ki Ges B †hŠM †_‡K
A †hŠ‡Mi cÖ¯‘wZ wewµqvmn †`LvI|
†h‡nZz, CHI3 I CH3 COONa Drcbœ nq Zvn‡j Dfq ˆRe
†hŠM wZb Kve©b wewkó n‡e|
G‡ÿ‡Î, wZb Kve©b wewkó †hŠMØq CH3 − CO − CH3 I
CH3 − CH − CH3 DfqB Av‡qv‡Wvdg© wewµqv †`q|
| |
OH
CH3 − CO − CH3 †K weRvwiZ Ki‡j CH3 − CH − CH3
|
OH
Drcbœ nq|
presence of dilute KOH. Identify A, B and C with
suitable reactions and show the preparation of compound
A from compound B with reactions.
Since, CHI3 and CH3 COONa are produced then both the
organic compounds will have three Carbons.
In this case, the two compounds having three Carbons
CH3 − CO − CH3 and CH3 − CH − CH3 both gives
OH
iodoform reactions.
CH3 − CH − CH3 is produced from the reduction of
|
OH

myZivs, CH3 − CO − CH3 .

A n‡jv CH3 − CO − CH3 Therefore,
B n‡jv CH3 − CH(OH) − CH3 A is CH3 − CO − CH3
60o C B is CH3 − CH(OH) − CH3
CH3 COCH3 + 3I2 + 4NaOH → CHI3 + CH3 COONa + 60o C
CH3 COCH3 + 3I2 + 4NaOH → CHI3 + CH3 COONa +
3NaI + 3H2 O
3NaI + 3H2 O
CH3 − CH − CH3 + 4I2 + 6NaOH → CHI3 +
| CH3 − CH − CH3 + 4I2 + 6NaOH → CHI3 +
OH |
CH3 COONa + 5NaI + 5H2 O OH
CH3 COONa + 5NaI + 5H2 O
LiAlH4
LiAlH4 CH3 − CO − CH3 + [H] → CH3 − CH − CH3
CH3 − CO − CH3 + [H] → CH3 − CH − CH3 |
| OH
OH CH3
dilute \ /OH
লঘু CH3
\ /OH CH3 − COCH3 + CHCl3 → C
CH3 − COCH3 + CHCl3 → C KOH CCl3 / \CH3
KOH CCl / \CH3
3 CH3
CH3 \ /OH
\ /OH Therefore, compound C is C
myZivs, C †hŠMwU C CCl3 / \CH3
CCl3 / \CH3
300o C
CH3 − CH − CH3 → CH3 − CO − CH3 300o C
| Cu CH3 − CH − CH3 → CH3 − CO − CH3
OH (A) | Cu
(B) OH (A)
(B)
b¤^i eÈbt
Marks distribution :
Dchy³ wewµqvmn A, B, C kbv³ Kivi Rb¨ (2×3) = 06 b¤^i|
For identifying A, B, C with suitable reaction ; (2×3) = 06
B †_‡K A †hŠMwUi cÖ¯‘wZ wewµqvi gva¨‡g ‡`Lv‡bvi
marks.
Rb¨ 04 b¤^i|
For showing the preparation of A from B with the help of
reaction ; 04 marks.