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#GK Complete Chemistry Notes English
#GK Complete Chemistry Notes English
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SSC GK
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PARMAR'S GK BATCH
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Chemistry
Atom and It’s Structure PD
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Lecture :- 2
as
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PARMAR'S GK BATCH
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Chemistry
Metal and Non-metal PD
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Lecture :- 3
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DF
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- What are Acids and Bases?
Ed
Acids: Sour substance, Corrosive in nature
Types:
-> Has source
1. Organic acids: from nature
2. Mineral acids: eg: HCl, H24
SO , HNO3
DF
↓
Corrosive
Bases: Bitter substances
rP
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as
-
- -
6-8% acetic acid and
Used as Preservatives
M
, Tomato
~
ed
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-
)
I
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Purple dye
natural indicator ↓
Neutral
Belongs to Thallophyta
Blue to Red in Acid
DF
Red to Blue in Base
Phenolphthalein
rP
-
Acid: Colourless
! A
Base: Pink smell
Methyl Orange
te
- Acid: Red
Base: Yellow
as
*
M
↓
when washed
in
however changes
to yellow again
Due to Soap when dried
ed
(Base)
M A S H ↓
re
r
i to
↑ Metal carbonate + Acid -> Salt + H2O + CO2
Ed
· ->
Quick lime
-
Ca(OH)2 + CO2- CaCO3 + H2O - -
DF
ppt Chalk
Turns lime water Marble
milky
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-> How do acids and bases react with each other?
A + B -> S + H2-
O Neutralisation reaction
te
↓
as
I
Base + Acid -> Salt + Water
at
-
Acidic + Base ->Salt + Water
r
-> What happens to an acid or base in a water solution?
i to
HCl H + Cl
+ -
/ - >
Ed
H2O -> H3
O Hydronium ion
NaOH Na + OH -Hydroxide
+
↑ ->
DF
-
37
/ Less H3O -> Less acidic
- rP
Acid Why?
as Highly exothermic
I
HO
. . . . . .
te
as
Water
I
Those bases which dissolve in water are called as Alkali -> Corrosive
M
1.6 H3O I
OH
-
Milk of Magnesia
↓ ↑ * -> Sodium
at
0 Hydroxide
re
r
i to
M Our body works in a pH of: 7-7.8
↑
pH in our digestive system: 1.6
pH change as a cause of Tooth Decay: 5.5 ↓
Ed
~
-
Use of pH by plants for self defence
Acid Rain: 5.6H
: Saliva pH: slightly acidic (6.4)
Uses it as self-defence
↑
Blood pH: slightly alkaline (7.4) -
DF
Nettle leaves (Herbaceous plant) -> Formic acid ->Methanoic acid
. Dock Plant neutralises Nettle leaves sting (basic in nature) ↓
Planets: thick clouds of H SO Venus Present in Ant sting
out
-
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Oil of Vitriol
te
Salts
pH of salts
as
14
A + B - Salt + Water (Basic)
in
strong
ed
Sodium Hydroxide
electrolysis
re
*
NaCl (aq) + H2O NaOH + Cl + H -> Chlor-alkali process
↓ 1
Brine cathode anode cathode
r
Bleaching Powder
i to
- used for making Bleaching
-
Ca(OH)2 + Cl2-> CaOCl2 powder
↓ ↓ ↓ Oxidising agent
Ed
Lime water Calcium Hypochlorite to make drinking water germ
free
Uses:
-
DF
&
Cotton and linen: Textile industry and bleaching
Paper factories: wood pulp bleaching
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Baking Soda
-
NaCl + H22
O + CO + NH -> NH4Cl + NaHCO3
3
↓
te
- Baking Soda (common name)
Sodium Hydrogen Carbonate
as
-
Uses
--
1. Baking powder: Baking soda + edible acid (tartaric acid)
2. Soda Acid fire extinguisher
M
3. Antacids
Heat/Water
-
NaHCO3 + H+-> CO24
in
Washing Soda
ed
A
-
·
2 NaHCO3 -> Na23
CO + H2O + CO2
-
Na25
CO + 10 H 2O -> Na 23
CO . 10 H2O
at
↓
Water of crystallisation
re
Uses of Washing Soda
r
-
i to
2. Glass, soap and paper factories
3. To manufacture Sodium compounds ->Borax
->
4. As a Cleansing agent for domestic purpose Na2472
B O . 10 H O
Ed
↓
Used in Toothpaste/mouthwash
DF
Plaster of Paris
Gypsum: CaSO4. 2H O -> CaSO4. 1/2 H2O
2
.
↓
-
rP
Plaster of Paris
373-273 -> 100 C
-
Blue vitriol: CuSO4. 5H O
It
2
-
White “ : ZnSO4. 7H O
2
·
Epsom salt: MgSO↳ .7H O 2
-
2
CH COOH
* 3
-
Ethanoic acid: Acetic acid
ed
W
Glauber salt: Na24
SO .10H O 2
-
Acid found in Spinach: Oxalic acid
at
-
Another folic acid: Pteroylglutamic acid
re
-
Citric acid: Oranges
r
&
Muriatic acid another name for Hydrochloric acid
↓
i to
used in chlorides, fertilizers and dyes,
in electroplating and in the
Ed
photographic, textile and rubber
industries
DF
M
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I
Litmus paper changes to blue color when put in soap water
I pH of water: 7 te
I
Double salt
-
Formula: CaMg(CO ) 32
M
in
ed
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CARBON AND IT’S COMPOUND
C PD
F
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Carbon
r
- -
Atmosphere: 0.036%
i to
↑
+
↑
Earth crust: 0.02% -> C
I Atomic no: 6 -> 2, 4
4
↳ C4
Ed
-
+1
- e sharing
.
L
Alkali metals: Li, Na, K
I Halogen: 7 1
+1 Covalent Bond
F
C PD
Bonding in Carbon: The Covalent Bond
e
H*1
-
*H =-
O O O O =
~
Strength: weak Nitrogen:
r N
: N
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-
Low Melting Point/Boiling Point
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Allotropes of Carbon
Graphite: 1C 3C> -Slippery
->
I
Diamond: 1C -> 4C -Hardest substance known
iAn
-
Buckmister Fullerene: C 60
↓
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- Catenation: unique ability to form bonds with other carbon atom- Large molecule
rPeA
↓
- -
C-C-C-C-C
Due to small size of C atom
ane: C-C single bond Saturated compounds
r
/
ene: C=C
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/
- yne: C=C
-
> Unsaturated compounds
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· +
2
I
I
Alkene: C Hzu
n
W
Alkyne: CnH2n -2
F
Saturated and Unsaturated Carbon Compounds
C PD
H I -H
H- ~H
H C-C H -
C=C
H-H
-
H - H
↓ ↓
ane ene
↓ r
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H-C=C-H
C H2n
n +
1
↳ yne
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Nomenclature
1C: Meth
:
2C: Eth I 23
4C: But
↳ continuation of Parent chain
↑
/
5C: Pent
6C: Hexa
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d
7C: Hepta
/ 8C: Octa
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Chains, Branches, and Rings
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Molecular formula same
-
-C
-
C-C-C-C C-C
- C
-
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Structure - Different
-C-CI
C C -> cyclical -> C
n Hzu
↳ ~
C-C
DF
Isomers: compounds with identical molecular formula but different structural formula
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-
-Difference in CH atoms 2
Homogenous Series CH3OH, CH32
-
>
, CH OH, CH3CH CH OH
2 I
H -1H H ↓
H C-C-C H Same chemical properties
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Nomenclature of Carbon Compounds
-
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W
v
CH4: Methane
-
v
CH Cl: Chloro Methane
~
: 3
F
W
CH3CH OH: Propanol
-
2
W
CH3COOH: Ethanoic acid
C PD
-
W
HCOOH: Methanoic acid
-
-
> - -
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↑
Primary: CH32
- -
CH OH, CH5CHiCH2CHIOH
·
Secondary: CH CH2CH CH2CH
;
-
OH
CH
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-
- !?
Tertiary: CH3CH CH CH:CHs
OH
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d
Aromatic Compounds
-
I kI - Benzene
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-
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C=C 2π
-
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1. Combustion:
-
CH32
CH OH + O2- CO2+ H O + Heat and light
2
Ed
Exothermic
-
Saturated: burns with clear blue flame
-
Unsaturated: burns with yellow sooty flame
LPG: Propane + Butane
F
I
-
CNG: Methane
C PD
2. Oxidation
-
Alkaline KMNO4
CH CH OH -> CH3COOH
K Cr O
31 22
H
Ethanol Ethanoic acid
r
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3. Addition Reaction -> Hydrogenation
-
-
Unsaturated Hydrocarbon: HI
H-H
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R -- R H 11
C=C
2
- R-C-C-R
R- R Ni/Pd II
R-R
↓ -Unhealthy
↓
Vegetable oil saturated
healthier
↓ ↓Animal fats
unsaturated fatty acids
iAn
4. Substitution Reaction
eM
CHn2
+ Cl - CH3Cl + HCl [sunlight]
aRt
I 2
H-C-H
1 I
H Cl
Some important Carbon Compounds- Ethanol and Ethanoic Acid
r
i to
I
Ethanol ->Good solvent; used in Cough syrup
I Can be made from Sugarcane juice -> Molasses Fermentation
-> Ethanol
Tincture of Iodine
Ed
Conc. H SO4
CH CH OH -
32 CH2=CH2
2
443k
↓
H H Ethene
I I
H-C-C OH-
- W
F
H H
C PD
Properties of Ethanol
Reactions of Sodium
W 2CH32
-CH OH + 2Na - >
CH32
CH ONa + H2
r
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Properties of Ethanoic Acid
in Vinegar: 5-8%
↓
↓ -
RMas
Commonly known as Acetic acid
Also known as Glacial Acetic Acid as Melting Point is 290 K
↓
Freezes during winters
iAn
1. Esterification Reaction
d
I
Acid + Alcohol reaction COOR group -> Ester
*
CH25-
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i to
W
CHs COOC H CH3COONa + C22
H OH
↓
Saponification rkn
↓
Ed
For making soaps
I
Sodium salts of long
chain of carboxylic acids
F
C PD
Detergent: Sodium
- salt of long chain Sulphonic acid
2CH3COOH + Na23
CO -> 2CH3COONa + H2O + CO2
I
r
SS te
&
Alkylebenzene widely used in production of phenol: Cumene
RMas
-
Strong reducing agent used to reduce aldehydes, ketones, esters, carboxylic acid chlorides,
carboxylic acids and even carboxylate salts to alcohols: Lithium aluminium hydride (LiAlH4)
-
Two double carbon- carbon bonds are known as dienes
-
Isopentane also called 2-methylbutane and is branched structure with formula C5H12
iAn
↓
CH
13
eM
CH-CH-CH-CH
d
3 2 23
Nitromethane formula: CH NO
!
H
O
aRt
H-C-N
E
rPeA
O
.
H
I
Sedimentation not used to purify organic compounds
r
I
Alkanes were earlier known as Paraffin
i to
- Paradichlorobenzane is used as fumigant insecticide to contra cloth moths and chemical
formula is: C642
H Cl
Ed
I Root is used to represent the no. of carbon atoms in the parent chain
F
Simplest form of Sugar
C PD
-
Cereals: Maltose
-
Largest compound of natural gas: Methane (seen in Paddy field, they are Marsh gas)
↓
Also seen in where there are Termite
r
SS te
I Butane gas: C"10
H
! Alkane: C H
RMas
n 2n +
2
=2x4+2
-
Three carbon molecules broken down from six-carbon molecules of glucose during the first
step in the process of nutrition in all organisms is called: Pyruvate
Cytoplasm
Glucose ->Pyruvate
iAn
- Dicholorodifluromethane: CCl22
F
eM
d
aRt
rPeA
r
i to
SSC GK
Ed
PARMAR'S GK BATCH
F
Chemistry
Periodic Table PD
te r
Lecture :- 6
as