EN ISO 11114-1

October 1997

+ AC
April 1998

ICS 23.020.30; 23.060.40

Descriptors: Gas cylinders, valves, materials, compatibility, testing.

English version

Transportable gas cylinders

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Compatibility of cylinder and valve materials with gas contents
Part 1: Metallic materials
(ISO 11114-1 : 1997, including Corrigendum AC : 1998)

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Bouteilles à gaz transportables –
Compatibilité des matériaux des
bouteilles et des robinets avec les
contenus gazeux – Partie 1:
Matériaux métalliques
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(ISO 11114-1 : 1997, Corrigendum
AC : 1998 inclus)
Ortsbewegliche Gasflaschen –
Verträglichkeit von Werkstoffen für
Gasflaschen und Ventile mit den in
Berührung kommenden Gasen –
Teil 1: Metallische Werkstoffe
(ISO 11114-1 : 1997, einschließlich
Berichtigung AC : 1998)

This European Standard was approved by CEN on 1997-09-18 and Corrigendum

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AC on 1998-04-02.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations
which stipulate the conditions for giving this European Standard the status of a
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national standard without any alteration.

Up-to-date lists and bibliographical references concerning such national
standards may be obtained on application to the Central Secretariat or to any
CEN member.
The European Standards exist in three official versions (English, French, German).
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A version in any other language made by translation under the responsibility of a

CEN member into its own language and notified to the Central Secretariat has the
same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, the Czech
Republic, Denmark, Finland, France, Germany, Greece, Iceland, Ireland, Italy,
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Luxembourg, the Netherlands, Norway, Portugal, Spain, Sweden, Switzerland,

and the United Kingdom.

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European Committee for Standardization
Comité Européen de Normalisation
Europäisches Komitee für Normung

Central Secretariat: rue de Stassart 36, B-1050 Brussels

© 1997. CEN – All rights of exploitation in any form and by any means Ref. No. EN ISO 11114-1 : 1997 + AC : 1998 E
reserved worldwide for CEN national members.
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Annex ZZ (informative) Corresponding International and European Standards ........ 43
for which equivalents are not given in the text
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EN ISO 11114-1 : 1997 + AC : 1998

The text of the draft standard was submitted to the Formal Vote and was approved by CEN as
EN ISO 11114-1 on 1997-09-18.
This European Standard has been submitted for reference into the RID and/or in the technical
annexes of the ADR. Therefore in this context the standards listed in the normative references
and covering basic requirements of the RID/ADR not addressed within the present standard are
normative only when the standards themselves are referred to in the RID and/or the technical
annexes of the ADR.

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NOTE: In this standard the term ‘cylinder’ refers to transportable pressure receptacles,
which also include tubes and pressure drums.

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: 1996
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: 1996

: 1995
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: 1996
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EN 10088-1 Stainless steels – Part 1: List of stainless steels

: 1997

: 1997
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ISO 10156 : 1996 Gases and gas mixtures – Determination of fire potential and
oxidizing ability for the selection of cylinder valve outlets

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ISO 10156 or EN 720-2).
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4.3.4 Reference is made in this standard to stainless steels by their commonly used AISI
identification numbers, e.g. 304. The equivalent grades in EN 10088-1 are as follows:
304 1.4301
304L 1.4306 – 1.4307
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316 1.4401
316L 1.4404
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NOTE: For 34 Cr Mo 4 Q and T steels and equivalent hydrogen partial pressures above
5 MPa (50 bar), the maximum ultimate tensile strength (UTS) of the steel should be
950 MPa. Some standards specify testing methods to select appropriate steels with
appropriate maximum UTS for hydrogen cylinders. Equivalent partial pressure for
hydrogen sulphide and methyl mercaptan is reduced to 0,25 MPa (2,5 bar) at a

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maximum UTS of 950 MPa.
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generally
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Risk of formation of toxic metal carbonyls.

Highly sensitive to any traces of moisture
(> 5 ppmV at 20 MPa (200 bar)), in the
presence of CO2 (> 5 ppmV). Industrial
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grades of carbon monoxide normally con-

tain traces of CO2. This can result in risk of
stress corrosion, in the case of QTS, CS
and NS cylinders if used at the normal
service stress levels.
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and CS.

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i.e.
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-
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(continued)
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not susceptible to hydrogen

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not
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susceptible to

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not
susceptible to hydrogen
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Annex ZZ (informative)
Corresponding International and European Standards for which equivalents are not
given in the text

EN 849 : 1996 ISO 10297 : ...1), Gas cylinder valves – Specifications and type testing
The other European publications have no equivalent international publication.

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1
) In preparation