AM I N E S

/
aammionnesdpnepminon
wei.fi
Physical E chemical Properties

Diazonium salts
AMINES Classification
-

go 20 30

RNNL Ri Rin R
NH
-

R
-
←

PREPARATION
RI t
HN.tk Rnhz 1- ZR

Rz N t ZR RzNht I -
R

t
④ 2-0
Ryn

R -
CR -

Nhz
Bra
Rnnz (only to
amines
Kon )
Bromamide
Hoffamine synthesis

R -
I -

ee Nami
Rnnz
NaOH
D

Curtius Reaction
 ROOM
Nah
)
RNNL
nisoy
Schmidt
Reaction

WAVY
Rconnz RChzNhz
ti ALMY RN hchz
Rnc

RN Oz with
RNhz
Sn Ince
MINK
lining
Electrolytic cuz
weakly fog N°2
fog
- -

Acidic realm

physical PROPERTIES
I
-

• lower aliphatic amines :

Gases

• it z° aliphatic amines : Intermolecular

H -

bonding
•
Boiling point
Primary 7 Secondary >
Tertiary
 CHEMICAL PROPERTIES
• Amines are basic

in
gaseous state 3072075

if its
methyl gp
'
in
aqueous state
I > to 730
other
GP
zo > 3075

• Aniline : less basic than aliphatic

amines I ammonia due to
'

resonance .

2 .
Reaction with nnoz

"N"
R -

Nha ROM t Nz T
L°ame°ne
Nhl NANKIN U nzce

O C
'
-

HN "
Rz NH Rz No fellow)2° amine

(R3NnJN0i
MN 02
Rz N 3. amine
2 Reaction
.

Carbylamine
R
R Chaz
+
-
NHL + KOH -
NC

( i) pungent
smell

3 .

Electrophilic Ar . Substitution
ghz
Bru BI - Br

water Q
Br
WAC
1- NHL pnw Ac yn
Ac< 0
① a Bra a
Lot water hi!
Br
Nh WAC
,
t Br
acti
highly
-
-

voting Gp
-

o -

p directing
Difficult to Frieda
monosubstitue No Reaction
craft
 conc
gone ghost
'
I
NNZ Hzsoy i

503M 503-0
It zwitteee
④ Ion

NML NHL NHL

in a large
cone ¥ Lot
no,
H
Nose
HN Oz -1

517 477 21
hrsoy .
.
.

R cuz
- N 02

Tn ) nilnz
Nuuk HNOZ Snlncl

Rchz NHON Rom NML

i -
Nikolic Acid
i -

Pseudonitrol
30 -

No Rxn
Benzene Diazonium Chloride
Previous Yrs ofs