Marks booster challenge #3

The moles of methane required to produce 81 g of water after complete

combustion is____ × 10-2 mol. [Nearest integer]
If compound A reacts with B following first order kinetics with
rate constant 2.011 × 10–3 s –1 . The time taken by A (in seconds)
to reduce from 7 g to 2 g will be __________. (Nearest
Integer)
[log 5 = 0.698, log 7 = 0.845, log 2 = 0.301]
A system does 200 J of work and at the same time absorbs 150 J of
heat. The magnitude of the change in internal energy is ______J.
(Nearest integer)
The limiting molar conductivities of NaI, NaNO3 and AgNO3 are
12.7, 12.0 and 13.3 S m2 mol–1, respectively (all at 25°C). The
limiting molar conductivity of Agl at this temperature is ____
mS m2 mol–1.
If the radius of the 3rd Bohr’s orbit of hydrogen atom is r3 and
the radius of 4th Bohr’s orbit is r4. Then :

D
The resistivity of a 0.8 M solution of an electrolyte
is 5 × 10-3 Ω cm. Its molar conductivity is
____________________ 104 Ω-1 cm2 mol-1.
(Nearest integer)
For the reaction R → P, the concentration of a reactant
changes from 0.03 M to 0.02 M in 25 minutes. The average
rate in seconds is

A 4 x 10–4 M sec–1

B 4 x 10–4 M min–1

C 6.66 x 10–6 M sec–1

D 6.66 x 10–6 M min–1

The unit of ebullioscopic constant is

A K kg mol-1 or K(molality)-1

B mol kg-1 K-1 or K-1(molality)

C kg mol-1 K-1 or K-1(molality)-1

D K mol kg-1 or K(molality)

For conversion of compounds A → B, the rate constant of
the reaction was found to be 4.6 × 10– 5 L mol–1 s–1. The
order of the reaction is________.
Total vapour pressure of mixture of 1 mol X (POx = 150 torr)
and 2 mol Y (POy = 300 torr) is 240 torr. In this case:

A there is a negative deviation from Raoult’s law

B there is a positive deviation from Raoult’s law

C there is no deviation from Raoult’s law

D can not be decided

The number of atomic orbitals from the following having 5
radial nodes is ________.
7s, 7p, 6s, 8p, 8d
For the zero order reaction A → B + C; initial concentration
of A is 0.1 M. If [A] = 0.08 M after 10 minutes, then its
half-life and completion time are respectively :

A 10 min; 20 min

B 2 x 10-3 min; 4 x 10-3 min

C 25 min, 50 min

D 250 min, 500 min

At room temperature, a dilute solution of urea is
prepared by dissolving 0.60 g of urea in 360 g of water. If
the vapour pressure of pure water at this temperature is
35 mm Hg, lowering of vapour pressure will be: (molar
mass of urea = 60 g mol-1)

A 0.027 mmHg

B 0.028 mmHg

C 0.017 mmHg

D 0.031 mmHg
A 5% solution of cane sugar (molar mass 342 is
isotonic with 1% of a solution of an unknown
solute. The molar mass of unknown solute in
g/mol is

A 34.2

B 136.2

C 171.2

D 68.4
For a given chemical reaction A → B at 300 K the free energy change
is -49.4 kJ mol-1 and the enthalpy of reaction is 51.4 kJ mol-1. The
entropy change of the reaction is _____ J K-1 mol-1.
For the first order reaction A → B, the half life is 30 min. The time
taken for 75% completion of the reaction is______ min.
(Nearest integer)
Given :
log 2 = 0.3010
log 3 = 0.4771
log 5 = 0.6989
Which transition in the hydrogen spectrum would have the
same wavelength as the Balmer type transition from n = 4
to n = 2 of He+ spectrum

A n = 2 to n = 1

B n = 3 to n = 4

C n = 1 to n = 2

D n = 1 to n = 3
One mole of an ideal gas is expanded isothermally and
reversibly to half of its initial pressure. ΔS for the process in
J K-1 mol-1 is [ln 2 = 0.693 and R = 8.314 J/(mol K)]

A 6.76

B 10.76

C 5.76

D 8.03
The half-life period for a reaction at initial concentration
of 0.5 and 1.0 moles L–1 are 200 sec and 100 sec
respectively. The order of the reaction is

A 0

B 1

C 2

D 3
At constant volume, 4 mol of an ideal gas when heated from 300 K to
500 K changes its internal energy by 5000 J. The molar heat capacity
at constant volume is —------.
When 5 moles of He gas expand isothermally and reversibly
at 300 K from 10 litre to 20 litre, the magnitude of the
maximum work obtained is ______ J . [nearest integer]
(Given : R = 8.3 J K-1 mol-1 and log 2 = 0.3010)
Q- Match List - I with List-II.

List - I (Parameter) List - II (Unit)

(a) Cell constant (i) S cm2 mol-1

(b) Molar conductivity (ii) Dimensionless

(c) Conductivity (iii) m-1

(d) Degree of dissociation of electrolyte (iv) Ω-1 m-1

Choose the most appropriate answer from the options given below

A (a) - (iii), b - (i), (c) - (ii), (d) - (iv)

B (a) - (i), b - (iv), (c) - (iii), (d) - (ii)

C (a) - (ii), b - (i), (c) - (iii), (d) - (iv)

D (a) - (iii), b - (i), (c) - (iv), (d) - (ii)

Calculate the emf of following cell at 298 K:
Mg(s) | Mg2+ (0.1 M) || Cu2+ (0.01 M)|Cu(s)
[Given Eocell = +2.71 V, 1 F = 96500 C mol-1]
The volume of hydrogen liberated at STP by treating 2.4 g of
magnesium with excess of hydrochloric acid is _____ x 10-2 L
Given: Molar volume of gas is 22.4 L at STP.
Molar mass of magnesium is 24 g mol-1