PRODUCT DESCRIPTION

BIOBROM (DBNPA)
Safety Handbook
Year Edition Remarks Approved by
6/2011 1
6/2016 2 Approved edition R.L
 CONTENTS

INTRODUCTION ....................................................................................................................... 5
ICL-IP SUSTAINABILITY POLICY...............................................................................................6
GLOSSARY OF COMMONLY USED ABBREVIATIONS ...........................................................8

1.. PRODUCT DESCRIPTION

1.1. PRODUCT DESCRIPTION ....................................................................................13

1.2.IDENTIFICATION..................................................................................................13
1.3. PHYSICAL PROPERTIES.......................................................................................14

2..PACKAGING

2.1. PLASTIC SACKS.....................................................................................................18

2.2. PLASTIC PAILS......................................................................................................19
2.3. BIG BAGS..............................................................................................................20
2.4. PLASTIC JERRICANS.............................................................................................21
2.5. INTERMEDIATE BULK CONTAINER (IBC) ..........................................................22
2.6. L-RING DRUMS....................................................................................................23
2.7. MARKING AND LABELING..................................................................................24

3..TRANSPORTATION

3.1. PACKAGING AND TRANSPORTATION...............................................................31

3.2. DRIVER’S LOADING CHECK LIST.........................................................................36
3.3. DRIVER’S ROAD REMINDERS..............................................................................38

DBNPA SAFETY HANDBOOK 3

4.. USER GUIDE

4.1. GENERAL SITE RECOMMENDATIONS................................................................41

4.2. PROCESS SAFETY MANAGEMENT REGULATIONS............................................45
4.3. HAZARDOUS EXPOSURE LIMITS........................................................................46
4.4. PROTECTIVE CLOTHING......................................................................................46
4.5. RESPIRATORY PROTECTION PROGRAM............................................................47

5.. EMERGENCY RESPONSE

5.1. FACILITY EMERGENCY ACTION PLANNING......................................................51

5.2. TRANSPORT EMERGENCY RESPONSE...............................................................52
5.3. HAZARD IDENTIFICATION...................................................................................53
5.4. CLASSIFICATION OF THE SUBSTANCE...............................................................54
5.6. FIRE FIGHTING.....................................................................................................60
5.7. SPILLS OR LEAKS.................................................................................................61
5.8. EMERGENCY REPAIRS.........................................................................................62
5.9. EXPOSURE TO DBNPA.........................................................................................63

6.. OPERATORS GUIDE

6.1. OPERATOR HEALTH MONITORING...................................................................67

6.2. OPERATOR/DRIVER SAFETY TRAINING.............................................................69

APPENDIX

A.. TYPICAL QUALITY SPECIFICATIONS............................................................................73

B..REFERENCES..................................................................................................................74

4 EDITION 2, 2016
INTRODUCTION

This Safety Handbook has been compiled by ICL Industrial Products (ICL-IP) Ltd. as a
part of its continuing commitment to the principles of Product Stewardship, and is
intended to provide a guide to the safe handling and use of DBNPA products.

DBNPA is effective in the control of bacteria, algae, slime and fungi in industrial water
systems. DBNPA can be safely used by untrained persons following the few basic
precautions which are clearly indicated on each receptacle.

Whether you are a manufacturer, transporter, distributor or end user, we hope that
the information contained in this Safety Handbook will prove useful in your handling
of these products. Information is also provided to assist regulatory and transportation
authorities in determining if DBNPA is being handled or transported properly, and to
assist medical personnel in case of accident involving this product.

DBNPA is not a substance to be used casually. It is a hazardous chemical which can

be used safely if its properties are understood and the necessary safety precautions
are observed. Safety is the personal responsibility of everyone working with DBNPA.
Managers and supervisors should be well versed in the safe handling practices
required and enforce their implementation. Operators should be well trained in the
use of safety equipment and safety procedures.

Note: The relevant Safety Data Sheet should be consulted before undertaking any
activities involving DBNPA.

The handling of DBNPA is strictly regulated by international agreements and

government regulations. As new information is continuously becoming available,
anyone handling this substance must keep up-to-date on relevant practices and
regulations.

ICL-IP emphasizes the need for safe handling of DBNPA, the integrity of the containers
and the prominent display of instructions and warnings.

For further information about DBNPA, please contact your local ICL-IP office. website:
www.icl-industrial.com

We also welcome your comments and input on the content and presentation of this
Safety Handbook.

DBNPA SAFETY HANDBOOK 5

Although the information and recommendations set forth herein (hereinafter
“Information”) are presented in good faith and believed to be correct as of the date
here-of, ICL Industrial Products makes no representations as to the completeness or
accuracy thereof. Information is supplied upon the condition that the person receiving
it will make their own determination as to its safety and suitability for their purposes
prior to use.

In no event will ICL Industrial Products be responsible for damages of any nature
whatsoever resulting from the use or reliance upon the Information.

In the event of a discrepancy between the contents of the safety handbook and the
updated SDS, then the SDS will prevail (see ICL-IP website for latest version www.icl-ip.
com)

NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESSED OR IMPLIED OF

MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE,
ARE MADE HEREUNDER WITH RESPECT TO INFORMATION OR THE PRODUCT TO
WHICH THE INFORMATION REFERS.

ICL-IP SUSTAINABILITY POLICY

The managers and employees at ICL-IP are committed to sustaining economic growth
without harming our planet or exhausting its resources while improving the quality of
life for its current and future inhabitants.

ICL-IP practices Sustainable Development in the knowledge that it makes good

business sense and will incorporate sustainability considerations in all operations
and business decisions in alignment with a commitment to the global Sustainable
Development effort.

This will be achieved by:

• Maintaining a balance between economic, environmental and social needs of
present and future generations
• Developing a companywide culture of Sustainable Development
• Complying with all national and international regulatory requirements including
emergency regulatory requirements in cooperation with local emergency
authorities
• Implementation of enforcement and risk management plans

6 EDITION 2, 2016
• Adoption of Responsible Care and Product Stewardship principles
• Certification of all production facilities to ISO 14001/ OHSAS 18001/ ICL internal
“Green Facility” certification
• Transparency and voluntary reporting according to the GRI (Global Reporting
Initiative) model
• Focusing R&D on design and development of sustainable products and solutions
• Use of best available and economical technologies (BAT) to ensure conformance
to legal requirements and beyond
• Minimizing the corporate environmental footprint including ongoing reduction of
greenhouse gas emissions
• Commitment to safety by striving for zero accidents and ensuring a good
working environment for employees and contractors
• Encouraging downstream users, transporters and suppliers, to adopt good
practices for safe handling of chemicals and to minimize emissions during use
and disposal of products and packages
• Promoting programs in support of the community and social involvement
• Upholding the principles of human rights both in and outside the workplace
• Adoption of a Code of Ethics
• Corporate governance according to principles and rules that ensure
accountability, fairness, and transparency in relationships between management,
the Board, shareholders and other stakeholders
• Educating and training all managers and employees to be fully aware of the
Sustainability Policy and to be committed to its implementation
• Supplying resources needed for implementation of this policy

DBNPA SAFETY HANDBOOK 7

GLOSSARY OF COMMONLY USED ABBREVIATIONS

ACC American Chemistry Council (US), formerly Chemical

Manufacturers Association
ACEP Approved Continuous Examination Program (CSC)
ACGIH American Conference of Governmental Industrial Hygienists
ADR European Agreement concerning the International Carriage
of Dangerous Goods by Road
BPD Biocidal Products Directive (BPD 98/8/EC)
CAS Chemical Abstract Service
CEFIC European Council of Chemical manufacturers Federations
CERCLA Comprehensive Environmental Response, Compensation
& Liability Act (US)
CFR Code of Federal Regulations (US)
CHEMTREC Chemical Transportation Emergency Center (US)
COMAH Control of Industrial Major Accident Hazards Regulations (UK)
COSHH Control of Substances Hazardous to Health Regulations (UK)
CSC International Convention for Safe Containers (IMO)
CWA Clean Water Act (US)
DBNPA 2,2-dibromo-3-nitrilopropionamide
DOT Department of Transportation (US)
EmS Emergency Schedule (IMO)
EPA Environmental Protection Agency (US)
FIFRA Federal Insecticide Fungicide and Rodenticide Act
GHS Globally Harmonized System
HSE Health and Safety Executive (UK)
IATA International Air Transport Association
IDLH Immediately Dangerous to Life and Health
IMDG International Maritime Dangerous Goods code
IMO International Maritime Organization
ISO International Standards Organization
MAK Maximum Concentration at the Workplace (Germany)
MFAG Medical First Aid Guide (IMO)
SDS Safety Data Sheet
NFPA National Fire Protection Association (US)
NIOSH National Institute of Occupational Safety & Health (US)
NOS Not Otherwise Specified
NTP National Toxicology Program (US)
OSHA Occupational Safety and Health Administration (US)
OES Occupational Exposure Standard (UK)
PEL Permissible Exposure Limit (OSHA) (US)

8 EDITION 2, 2016
RCRA Resources Conservation and Recovery Act (US)
REL Recommended Exposure Level (NIOSH) (US)
RID Regulations concerning the International Carriage
of Dangerous Goods by Rail (Europe)
RQ Reportable Quantity
SARA Superfund Amendments and Reauthorization Act (US)
SCBA Self Contained Breathing Apparatus
STEL Short Term Exposure Limit
TEFC Totally Enclosed Fan Cooled Electric Motor
TLV Threshold Limit Value (ACGIH) (US)
TSCA Toxic Substances Control Act (US)
TWA Time Weighted Average
UL Underwriters Laboratories (US)
UN United Nations

DBNPA SAFETY HANDBOOK 9

1.. PRODUCT DESCRIPTION

1.1. PRODUCT DESCRIPTION .......................................................................... 13

1.2.IDENTIFICATION........................................................................................ 13

1.3. PHYSICAL PROPERTIES............................................................................. 14

 PRODUCT DESCRIPTION

1.1 PRODUCT DESCRIPTION

2,2-Dibromo-3-nitrilopropionamide can be supplied as a powder, a granulate or as a

Solution formulation.

DBNPA Technical 100%, powder

DBNPA Granulate

DBNPA Solution in a non regulated solvent* and water

* Solvent DPG - Dipropylene glycol

Solvent PEG - Polyethylene glycol

1.2 IDENTIFICATION

UN Number – Technical grade 2811

Toxic solid, Organic n.o.s.
(2,2-Dibromo-3-nitrilopropionamide)

UN Number – Granulate 3077

Environmentally hazardous substance, solid, n.o.s.
(2,2-Dibromo-3-nitrilopropionamide)

UN Number Solution formulations - Generally not regulated

Regulated by DOT for bulk shipments only (UN No. 3082)

CAS Number
2,2-dibromo-3-nitrilopropionamide 10222-01-2

Formula
2,2-dibromo-3-nitrilopropionamide, C3H2Br2N2O

Br O
N C C C NH2
Br

DBNPA SAFETY HANDBOOK 13

Synonyms
DBNPA, 2,2-dibromo-3-nitrilopropionamide, 2,2-dibromo-2-cyanoacetamide

Trade names
Biobrom C-103, Biobrom C-103 L, Biobrom C-103 LP,
Biobrom C-100 G, Biobrom AS

Chemical Family Halogenated cyanoacetamide

Appearance
Color: white to off - white powder or granulate, or clear to amber liquid
Odor: mild antiseptic

1.3 PHYSICAL PROPERTIES

Characteristic 100% Powder 20% Solution

Boiling Point Decomposes Not applicable
Melting Point 123 to 125 °C -20 to -25 °C
Flash Point None 159 to 165 °C
Auto ignition temperature Not Available Not Available
Vapor pressure Not applicable 2266.5 Pa (20 °C)
Decomposition Temperature 190 °C Not applicable
Molecular Weight 241.84 Not applicable
Density 2.375 g/ml 1.16 to 1.21 g/ml
Flammable limits in air Will not support combustion

Solubility in water 17 ± 0.05 g/l at 25.7°C

Solubility of DBNPA in other solvents g/100g at 25°C

Acetone 35
Ethanol 25
Dimethyl formamide 120
Polyethylene glycol 120

Dust Flammability
DBNPA is not classified as a flammable substance for transportation. The dust is
weakly explosive (KST value 92, class I). It is not sensitive to ignition by static electricity
(Minimum Ignition Energy > 500 mJ).

14 EDITION 2, 2016
 PRODUCT DESCRIPTION

2..PACKAGING

2.1. PLASTIC SACKS........................................................................................... 18

2.2. PLASTIC PAILS............................................................................................ 19

2.3. BIG BAGS.................................................................................................... 20

2.4. PLASTIC JERRICANS................................................................................... 21

2.5. INTERMEDIATE BULK CONTAINER (IBC)................................................. 22

2.6. L-RING DRUMS.......................................................................................... 23

2.7. MARKING AND LABELING........................................................................ 24

 PACKAGING

STANDARD DBNPA PACKAGING

DBNPA is packaged in convenient forms for practical use.

Solid – powder or granulate

• 25 Kg Valve Woven P.E.Bags for DBNPA powder
• 20 Kg Plastic pails for DBNPA granulate
• 227 Kg Big bags for DBNPA granulate

Solution formulations
• 20 Liter Jerricans
• 240-300 Kg Plastic drums for DBNPA solution
• 1000-1500 Liter IBC’s

All DBNPA Solution packaging is supplied with a vent. DBNPA is shipped in freight
containers. When opening a container at its destination, cautiously open the doors
completely and allow the container to be aired for 15 minutes before entering and
before any unloading operations are started.

Palletized drums, bags or pails should be stacked no more than three pallets high.
Palletized big bags should be stacked no more than two pallets high.

Exceeding this limit may damage the packaging.

Drums should be shipped and stored upright. They should be supported so that there
is no danger of a drum being moved accidentally or falling.

DBNPA pails should not be used for any other purpose other than the original DBNPA
filling. The receptacles should be kept tightly closed except when in use.

The Shelf Life of DBNPA is 3 years

This DBNPA substance should never be stored in a home or office building. It should
only be stored in a well ventilated warehouse, in an area that is adequately marked
and locked.

Drums should be issued “First-in, First-out”, and should be inspected for external
damage every three months. After any unusual incident in the warehouse which could
damage the drums or the bags, they should be inspected.

If there are any signs of spills or leakages, take appropriate action as indicated in
section 5, emergency response.

Receptacles with signs of external damage should never be sent to a customer. The
supplier should be consulted for instructions on disposal of damaged drums, or bags.

DBNPA SAFETY HANDBOOK 17

2.1 PLASTIC SACKS

Net Weight 20 / 25 Kg
Material LDPE
UN code UN 5H3/Y25/S
Dimensions (cm) 13 X 58 X 38

PALLET DETAILS
Dimensions (cm) 100 X 120 X 96
No of units per pallet 42
Gross weight of pallet 1078

CONTAINER DETAILS
Quantities per container according to shipping destination

20 foot containers

Destination Number of Total number Net weight Gross weight

pallets of sacks (Kg) (Kg)
Europe 20 840 21,000 21,568
Japan 20 840 21,000 21,568
USA - Warehouse 18 756 18,900 19,411
USA - Direct 17 714 17,850 18,333
India 19 798 19,950 20,490
Korea 17 714 17,850 18,333

Height 960 mm

1200 mm
1000 mm

18 EDITION 2, 2016
 PACKAGING

2.2 PLASTIC PAILS

Net Weight 20 Kg
Material LDPE
Dimensions 31 Dia. X 36 cm

PALLET DETAILS
Dimensions (cm) 100 X 120 X 90
No of units per pallet 24
Gross weight of pallet 534

CONTAINER DETAILS
Quantities per 20 foot container according to shipping destination

Destination Number of Total number Net weight Gross weight

pallets of pails (Kg) (Kg)
All 20 480 9600 11060

Height 900 mm

1000 mm 1200 mm

DBNPA SAFETY HANDBOOK 19

2.3 BIG BAGS

Net Weight (Kg) 227

Material Polypropylene and liner
UN code UN13H4/Y
Dimensions 89 X 89 X 40 cm

PALLET AND CONTAINER DETAILS

Size (Kg) 227

Dimensions (cm) W100 X L120 X H95
No of units per pallet 3
Net weight of pallet (Kg) 681
No. of pallets per container (20 ft) 20
Net weight per container (Kg) 13,620

Height 950 mm

1200 mm
1000 mm

20 EDITION 2, 2016
 PACKAGING

2.4 PLASTIC JERRICANS

20 Liter
Net Weight 20 Kg
Material HDPE
UN code UN 3H1/X1.9/250
Dimensions (cm) 29 x 26 x 39

PALLET DETAILS
Dimensions (cm) 100 X 120
No of units per pallet 16
Gross weight of pallet 357

DBNPA SAFETY HANDBOOK 21

2.5 INTERMEDIATE BULK CONTAINER (IBC)

1000 Liter
Net Weight 1000-1500 Kg
Material HDPE
UN code UN 31HA1/Y/
Typical Dimensions (cm) 100 X 120 X 116

22 EDITION 2, 2016
 PACKAGING

2.6 L-RING DRUMS

220 Liter
Net Weight 240-300 Kg
Material HDPE
UN code UN 1H1
Dimensions (cm) 58 Diameter X 94

PALLET DETALS
Dimensions (cm) 100 X 120
No of units per pallet 4
Net weight of pallet 1040 Kg

DBNPA SAFETY HANDBOOK 23

2.7 MARKING AND LABELING

Labels
Labels are used for marking packages.

The labels relate to:

Hazard risk marking
Consumer product identification
Consumer use information
Medical treatment guides.

Placards
Placards are used for marking transport containers and provide:
1. Product identification
2. Hazard risk marking.

Diamond Shaped Labels and Placards

Diamond shaped labels and placards are internationally recognized danger
identification for hazardous substances.

For DBNPA solid products:

Toxic Symbol: Skull and crossbones
Black printing on a white background

The hazard class number “6” shall appear in the lower corner of the danger label and
placard.

For DBNPA granulate:

Environmentally hazardous symbol: Seven vertical stripes in upper half
Black printing on a white background.
The hazard class number “9” underlined shall appear in the lower corner of the danger
label and placard.

Sizes:
Label size: 100 mm x 100 mm, except for small packages only able to bear smaller
labels.
Placard size: Not less than, 250 mm x 250 mm
DBNPA PACKAGING 23

24 EDITION 2, 2016
 PACKAGING

Orange Panel
The orange panel with the UN number and the Hazard (Kemler) identification number,
is required by the ADR/RID Regulations. Some countries, such as the UK and Israel,
require the UN number and the Hazchem emergency action code.

The hazard (Kemler) identification number of solid DBNPA is 60 indicating that the
substance is toxic.

The hazard (Kemler) identification number of granulated DBNPA is 90 indicating that

the substance is environmentally hazardous.

The Hazchem Emergency Action Code for DBNPA is

• 2X for solid
• 2Z for granulate

DBNPA SAFETY HANDBOOK 25

26 EDITION 2, 2016
 PACKAGING

DBNPA SAFETY HANDBOOK 27

 TRANSPORTATION

3..TRANSPORTATION

3.1. PACKAGING AND TRANSPORTATION..................................................... 31

3.2. DRIVERS' LOADING CHECKLIST................................................................ 36

3.3 . DRIVERS' ROAD REMINDERS.................................................................... 38

 TRANSPORTATION

This chemical, 2,2-Dibromo-3-nitrilopropionamide, does not appear specifically by

name in the lists of hazardous materials. It has been assigned to one of the “not
otherwise specified” entries in accordance with its dangerous properties. All conditions
of this entry must be met for shipping, transportation and related handling functions.

The following is a summary of the main regulations and requirements regarding the
transportation of DBNPA products according to international regulations.

3.1 PACKAGING AND TRANSPORTATION

United Nations (Orange Book)

There has been considerable harmonization between the Orange Book and the
various international regulations. These model regulations have been adopted in
the various regulations, agreements and codes specified in this section. Many of the
sections are numbered in the same way and much of the text is identical.

IMDG Code
DBNPA technical (solid)DBNPA technical (granulate) DBNPA
solution
(liquid)
Shipping Toxic solid, Organic UN no. 3077 Environmentally Not
name n.o.s. UN no. hazardous substance, solid, regulated for
2811(2,2-Dibromo-3- N.O.S., (2,2-Dibromo-3- transportation
nitrilopropionamide) nitrilopropionamide)
Hazards 6.1: Poisons 9: Miscellaneous Dangerous
Class Substances and Articles.
Packing II:- medium danger III: Substances presenting
group low danger
Marking Marine Pollutant Marine Pollutant
EmS F-A, S-A F-A, S-F
Hazards 6.1: Toxic substances 9: Miscellaneous Dangerous
Class Substances and articles
Packaging Packing instruction P002, Packing instruction P002, IBC
IBC 08 08
Stowage Stowage Category B Stowage Category A
Segregation “Separate from” No specific segregation
explosives. “Away specified
from” substances
liable to spontaneous
combustion, oxidizers
and infectious
substances

DBNPA SAFETY HANDBOOK 31

The technical name, 2,2-Dibromo-3-nitrilopropionamide, should be shown in
parentheses immediately following the proper shipping name as shown above.

Stowage Category A:
• Cargo ships or passenger ships carrying less than 25 passengers: on deck or
under deck
• Other passenger ships: on deck or under deck

Stowage Category B:
• Cargo ships or passenger ships carrying less than 25 passengers: on deck or
under deck
• Other passenger ships: on deck only

Part 6 - Freight Containers

• Require approval in accordance with the International Convention for Safe
Containers. (CSC)
• Safety Approval Plate permanently affixed to each approved container.

Part 7.3 - Special precautions in the event of an incident involving

dangerous goods
The emergency procedures for ships carrying dangerous goods are contained in the
supplement. For DBNPA products, the EmS schedules are given in the above table.
The Medical First Aid Guide (MFAG) is also contained in the supplement and is for use
in accidents involving dangerous goods.

32 EDITION 2, 2016
 TRANSPORTATION

DOT Regulations
Table of Hazardous Materials 49 CFR 172.101

DBNPA technical DBNPA technical DBNPA solution

(solid) (granulate) (liquid)
Shipping Toxic solid, Environmentally for bulk shipments
Name Organic N.O.S. hazardous only Environmentally
(2,2-dibromo-3- substance, Hazardous
nitrilopropionamide) solid, N.O.S., Substance,
(2,2-Dibromo-3- liquid, N.O.S.
nitrilopropionamide) (2,2-dibromo-3-nitrilo
propionamide)
UN number 2811 3077 3082
Hazard Class 6.1 Toxic 9: Miscellaneous 9: Miscellaneous
Dangerous Hazardous Material
Substances and
Articles.
Guide number 154 171 171
(Emergency
Response
Guidebook,
1996)
Packaging II III III
group
Vessel Category B Category A Category A
Stowage
Ships: Cargo: on deck Cargo or passenger Cargo or passenger
or under deck, vessel: on deck or vessel: on deck or
passenger: on deck under deck under deck
only
Aircraft: cargo: 100 Kg/pKg No limit No limit
passenger:
25 Kg/pKg

DBNPA SAFETY HANDBOOK 33

ADR
European Agreement Concerning the International Carriage of Dangerous Goods by
Road

According to: Table A - Dangerous Goods list DBNPA are classified as:

DBNPA Solid
Toxic solid, organic, N.O.S, T2 (Toxic substance without subsidiary risk, solid)
Packaging instructions P002 and IBC 08 apply.
Flexible IBCs shall be sift-proof and water resistant or shall be fitted with a sift-proof
and water resistant liner (B4).

Special provisions for carriage:

Loading, unloading and handling
CV13 Special provisions for spills in a vehicle or container.
CV28 Precautions with respect to foodstuffs.
S9, S19 Provisions for stopping near public places and supervision of loads above
5,000 Kg.
Hazard identification number for labeling transport units.
Hazard Identification Number, No. 60.

DBNPA Granulate
Environmentally hazardous substance, Solid, N.O.S, M7 (pollutant to the aquatic
environment, solid)
Packaging instructions P002 and IBC 08 apply.
Flexible IBCs shall be sift-proof and water resistant or shall be fitted with a sift-proof
and
water resistant liner (B3).

Special provisions for carriage:

Loading, unloading and handling
CV13 Special provisions for spills in a vehicle or container.
Hazard identification number for labeling transport units.
Hazard Identification Number, No. 90.

DBNPA Solution
Not regulated for transportation

RID (Europe)
Regulations concerning the International Carriage of Dangerous Goods by Rail
These regulations are similar to the ADR agreement.

34 EDITION 2, 2016
 TRANSPORTATION

IATA Regulations
Dangerous Goods Regulations, 51st Edition, January 2010

Shipping name

Solid: Toxic solid, Organic N.O.S. UN no. 2811

(2,2-dibromo-3-nitrilopropionamide)

Granulate: Environmentally hazardous substance, solid, N.O.S. UN no. 3077

(2,2-dibromo-3-nitrilopropionamide)

Stowage Solid Granulate Solution

Cargo Aircraft Only Packaging instruction Packaging instruction Not
615 911 regulated for
100 Kg/package 400 Kg/package transportation
Passenger and Combination Packaging instruction
Cargo Aircraft Packaging 613 911
25 Kg/package 400 Kg/package
single packaging not
permitted
Limited Quantity Y613 Y911
1 Kg/package 30 Kg/package

Local Regulations

United Kingdom and Israel

Regulations apply to the transport of 200 Kg or more of a toxic substance of packing
group II.

The Hazchem Emergency Action Codes for DBNPA:

Description UN Number Hazchem EAC Code

DBNPA Solid 2811 2X
DBNPA Granulate 3077 2Y

DBNPA SAFETY HANDBOOK 35

3.2 DRIVER’S LOADING CHECKLIST
The following is a suggested checklist for DBNPA solid, based on European Agreement
concerning the Carriage of Dangerous Goods by Road (ADR) regulations and good
practice. The shipper should also ensure that all local regulations are complied with.

❏ Container is marked clearly at both sides and at each end with the UN No. (2811),
Hazard Identification Number 60 and Hazard Placard no. 6, Toxic Solid. Vehicles need
only be placarded if the container placards are not visible

❏ Vehicle is equipped with at least two portable dry powder fire extinguishers or equivalent,
of at least two and twelve Kg capacity, unused and checked within the past year.

❏ Approved portable lamps are available to each member of the crew

Vehicle has the following emergency equipment:

❏ Eye rinsing liquid
❏ Wheel blocks
❏ Two self-standing warning signs
❏ Suitable warning vests, protective gloves, eye protection and an emergency escape mask
for each member of the crew
❏ A shovel, drain seal and plastic container for collection of material.

❏ Vehicle has a certificate of approval for dangerous goods. The validity of the approval
shall expire not later than one year after inspection date.

❏ Driver and assistant driver have valid licenses to operate dangerous goods vehicles,
issued or renewed within the past five years, together with a valid training certificate
and means of identification.

❏ Hazardous transport unit does not consist of more than one trailer

❏ The vehicle is not carrying any materials incompatible with DBNPA at the same time
(Explosives, substances liable to spontaneous combustion, organic peroxides and
oxidizing substances, and infectious substances)
❏ DBNPA will be kept apart from food stuffs and animal feed.

Shipping papers include:

❏ Shipping name: Toxic solid, Organic n.o.s. UN no. 2811 (2,2 Dibromo-3-
nitrilopropionamide)
❏ Container/vehicle packing certificate
❏ Quantity being shipped, including number and description of packages.
❏ The name and address of the consignor and consignee

36 EDITION 2, 2016
 TRANSPORTATION

❏ All papers concerning the transport of the dangerous goods are kept in a holder on the
inside of the door on the driver’s side of the vehicle

❏ Driver has approved route to destination with specified stops.

No alternative routes will be used or unauthorized stops made.

❏ Vehicle has a full fuel tank before loading DBNPA

❏ Containers have been fastened with all the twist lock corner fittings.

DBNPA SAFETY HANDBOOK 37

3.3 DRIVER’S ROAD REMINDERS
The driver and assistant driver of any vehicle transporting DBNPA should comply
With the following requirements:

Supervision of vehicles (ADR regulation section 8.4)

Parking the hazardous goods transport unit should be under one of the following
conditions:
• Supervised parking lot, attendant aware of the nature of the load, and how to
contact the driver.
• Vehicle parking lot where unit is not likely to suffer damage.
• Open space separated from public highway and public dwellings, where public
does not normally pass.

Miscellaneous requirements (ADR regulation section 8.3)

• No passengers are allowed.
• The crew shall know how to use fire-fighting appliances.
• A driver or driver’s assistant may not open a package containing DBNPA.
• Portable lighting apparatus shall be spark proof.
• No smoking is permitted during handling operations in the vicinity of the vehicle
and inside the vehicle.
• The engine is to be shut-off during all handling operations unless required to
drive pumps, hoist, etc.
• Parking brakes are to be applied whenever parked. Trailers without braking
devices shall be restrained from moving by applying wheel chocks.
• If the vehicle is parked on a road at night or with poor visibility, warning signs are
to be placed 10 meters ahead of and behind the vehicle.

38 EDITION 2, 2016
 TRANSPORTATION

4.. USER GUIDE

4.1. GENERAL SITE RECOMMENDATIONS...................................................... 41

4.2. PROCESS SAFETY MANAGEMENT REGULATIONS.................................. 45

4.3. OCCUPATIONAL EXPOSURE LIMITS........................................................ 46

4.4. PROTECTIVE CLOTHING............................................................................ 46

4.5. RESPIRATORY PROTECTION PROGRAM.................................................. 47

 USER GUIDE

4.1 GENERAL SITE RECOMMENDATIONS

As DBNPA is a toxic or environmentally hazardous material, storage areas should be

carefully designated and supervised. Local regulations must be complied with.

This is a guide is to be used for the selection and supervision of a DBNPA storage area.

The storage areas can be supplier distribution warehouses, third party distribution
houses or user storage areas.

The storage area should be located at least 100 meters, and preferable 200 meters,
from any school, hospital or concentration of 10 or more private dwellings, and at
least 25 meters from the nearest occupied building, or public road.

The amount of DBNPA stored at the user site should be kept to a minimum.

Worksite should be enclosed with a low curb or wall, called a dike, to contain any
spilled material and prevent the dispersal of fire fighting water.
Within the diked area, there should be no sewer connection. However, a sump should
be provided for collecting and pumping away any collected fire fighting water.

Arrangement of the storage area should take into consideration the potential
evolution of large quantities of toxic fumes which would be hazardous to the
surrounding areas.

Provide adequate ventilation to extract fumes from indoor storage areas in the event
of a fire.

DBNPA pallets should not be stored closer than 1.2 meters (4 feet) from a wall or
ceiling.

DBNPA should never be stored in a basement

Buildings should be at least 10 meters apart to allow strengthened approach roads for
emergency vehicles on two sides of the installation.

Building construction should be fire resistant and provisions made for potential fire
fighting activities, according to relevant local and national codes, and in consultation
with the local fire brigade. The fire fighting installation should include provision for
an adequate supply of water. Fire extinguishers and hydrants should be distributed
around the area.

DBNPA SAFETY HANDBOOK 41

Electrical installation:
Junction boxes and light fittings should be dust tight. Cast iron (epoxy-base coated) or
a non-metallic material is suitable.

Use TEFC (Totally Enclosed Fan Cooled) motors of cast iron or steel construction with
epoxy-base coating.

Floors should be of impervious construction, preferably concrete.

Safety and Security

Any area where DBNPA is used or stored should be enclosed so that unauthorized
persons and animals are prevented from entering the area.

Adequate lighting should be provided to allow sufficient night surveillance.

Surveillance should be provided 24 hours a day.

Provide clearly marked personnel escape routes without obstructions including

adequately sized doors and windows.

Provide special remote eating and changing areas with adequate supplies of clean
water for washing and showers. Provide a smoking area remote from the operating
area.

A telephone should be provided which is freely available and readily accessible for the
reporting of accidents or emergency situations.

A windsock should be clearly visible from all points on the site and replaced as
required for indicating wind velocity and direction.

Emergency equipment cabinets should be installed not more than 30 meters or ten
seconds walking distance from any location in the storage area.

Non freeze safety showers and eyewash fountains should be provided, clearly marked,
well lighted and with unobstructed access. They should be located close to the DBNPA
storage area and not more than 30 meters or 10 seconds walking distance from any
location in the storage area. Provide an alternative supply of clean water.

Handling DBNPA
All management and operating personnel involved in the use or handling of DBNPA
should undergo safety training, in addition to the specific task training. Only
experienced well-trained operators should be allowed to receive and unload DBNPA
receptacles.

42 EDITION 2, 2016
 USER GUIDE

The management should ensure that emergency response plans have been made and
coordinated with the local emergency response authorities.

Precautions should be taken from the moment the shipment of DBNPA arrives at the
site gate.

Ensure that road and rail vehicles cannot be moved during a transfer operation.

DBNPA is shipped in freight containers. When opening a container at its destination,

cautiously open the doors completely and allow the container to be aired for 15
minutes before entering and before any of the unloading operations are started.

The drums should not be handled roughly.

No open flame heating is allowed. Keep the DBNPA receptacles away from heating coils.

Operators that could be exposed to DBNPA dust should wear goggles and a dust filter.

When dry, DBNPA powder is non-corrosive. Protective measures should be taken

when there is the possibility of dusting conditions or the decomposition of DBNPA.

Receptacles should be kept dry and tightly closed.

Use only clean and dry utensils for handling DBNPA.

Make sure that the equipment for handling DBNPA is clean and dry before starting
a process including DBNPA. Clean the equipment of all trace materials after process
completion.

Do not start a batch process involving DBNPA unless the process can be completed.

Prevent contact of DBNPA with chemicals such as oxidizers, reducing agents or bases.

Filters of dust collecting systems which are contaminated with DBNPA have to be
disposed of in an approved manner at an approved disposal facility. Consult with the
local authorities for information on these regulations and facilities.

Work with DBNPA should be carried out with a high standard of housekeeping and
personal hygiene.

Provide up to one or two drums of 10% sodium carbonate solution for dealing with
DBNPA spills.

Provide clean, dry, empty receptacles or overpacks for dealing with spills or damaged
DBNPA drums.

DBNPA SAFETY HANDBOOK 43

Sample Checklist for a DBNPA Handling Facility

Yes No
Toxic hazard signs displayed (for DBNPA solid)
Storage away from schools, hospitals or private dwellings
Minimum amount is being stored
Area surrounded by curb or dike
Sewer connections with quick closure
Sump to prevent contamination of sewers and water courses
Adequate ventilation in storage buildings
Clear space 1.2 m. from walls and ceiling
Nearest building - 10 meter gap
Reinforced road for emergency vehicles
Fire resistant building construction
Fire fighting hydrants
Fire fighting extinguishers
Dust and vapor tight electrical fittings
TEFC electric motors
Impervious floor
Area enclosed and secure – no unauthorized entry
Adequate lighting
24 hour surveillance
Clearly marked escape routes
Remote eating, changing and smoking areas
Emergency telephone
Wind sock
Emergency equipment cabinets, showers and eye-wash
Prevent vehicles from moving during handling operations
No open flame heating
Personal protection equipment used when unloading or handling
Good housekeeping and personal hygiene
Provide neutralizing agent
Availability of overpacks for collecting spills

44 EDITION 2, 2016
 USER GUIDE

4.2 PROCESS SAFETY MANAGEMENT REGULATIONS

USA
• Facilities handling HIGHLY HAZARDOUS CHEMICALS over a threshold quantity
(29CFR1910.119): For DBNPA there is no threshold quantity.

The management is required to prepare EMERGENCY ACTION PLANS to minimize the

consequences of a hazardous release of this toxic material. This written emergency
action plan describes the measures taken to prevent any release and the activities of
the workers and community services in the event of a release.
Workers, including contractor workers, are to be given adequate training and
refresher courses to implement this emergency action plan. Compliance audits
are to be made before starting up a facility and after changes have been made in a
facility or its operation procedures. Deficiencies and the corrections made are to be
documented to assure that the facility can be put into safe operation.
Changes may have to be reflected in emergency action plans.
A compliance audit is to be repeated every three years.
All incidents, which result in a release of hazardous materials or could have resulted
in the release, are to be investigated. The results of the investigation and corrective
actions recommended and taken are to be documented.

• Toxic Chemical Release Reporting (40 CFR 372)

DBNPA is not listed

• CERCLA (40 CFR 302)

DBNPA is not listed

Europe & UK - Directive 96/82/EG (SEVESO guidelines) COMAH (UK), BRZO (NL)
The purpose of this directive is to prevent and limit the consequences of major
accidents involving a dangerous substance. DBNPA is not listed in these regulations,
but does fall under the category of toxic for DBNPA solid (lower tier 50 tons, top tier
200 tons) substances, whose inventory is cumulative, with respect to other substances
in the same category.

Granular DBNPA, which is environmentally hazardous, has a lower tier of 100 tons and
an upper tier of 200 tons. Therefore specific safety reports and emergency plans may
have to be prepared and accidents involving DBNPA may have to be reported under
these regulations.

DBNPA SAFETY HANDBOOK 45

4.3 HAZARDOUS EXPOSURE LIMITS

Exposure limit values go under different names in the various standards, countries,
time periods and populations.

Generally, the exposure limit is specified as TWA, Time Weighted Average, for an eight
or a ten hour workday and a STEL, Short Term Exposure Limit for fifteen minute, five
minute periods or a ceiling value not to be exceeded.

Some of the limits are called TLV, Threshold Limit Values (ACGIH), REL, Recommended
Exposure Limit (NIOSH) or OES, Occupational Exposure Standard (UK - HSE - COSHH).

There is also an ERPG, Emergency Response Planning Guideline value for planning
exposure limits for the civilian population that includes children, the elderly and
disabled persons.

The United States (ACGIH, OSHA, and NIOSH) and United Kingdom authorities have
not determined occupational exposure limits for DBNPA.

The manufacturer’s recommended exposure limit is 0.25 mg/m3

4.4 PROTECTIVE CLOTHING

The protective clothing required for workers, under routine operating conditions,
should be sufficient to allow the worker to escape the operating area, if there should
be a release of hazardous material.

Dust masks, goggles, gauntlets and full body covering clothing should be worn when
handling DBNPA, or when there is a possibility of dusty conditions.

Contaminated work clothes should be placed in closed containers until laundering.

The clothes should be laundered under supervision, by the employer and not
laundered at home.

46 EDITION 2, 2016
 USER GUIDE

4.5 RESPIRATORY PROTECTION PROGRAM

Under routine operating conditions, when working with DBNPA, a gas mask is not
necessary, but a dust filter should be used.

However, should DBNPA begin to decompose, a full face gas mask with a new, unused
chlorine/bromine canister should be used to escape the area.

The face piece should be full face made of neoprene or other non-natural or non-butyl
rubber elastomer. Eyeglasses cannot be worn with regular face pieces. Special face
pieces or face piece adapter kits can be supplied for use with special eyeglass frames.

Color coding of gas mask filters differ under different regulations.

U.S. Code of Federal Regulations 29 CFR 1910.134, Chlorine, Color coded: White, with
a yellow stripe.

European Standard, EN 141,

Inorganic gases, Type B, Color coded: Grey.

It should be emphasized that the filter life is limited, even at low vapor concentrations
(no more than 20 minutes continuous use). While wearing a gas mask, the operator
should immediately leave the area on detecting any smell, taste or irritation of the
eyes A self contained breathing apparatus should be worn to reenter an area where
DBNPA is decomposing and when the oxygen content, is less than 19.5%, or if odor is
detected while wearing a gas mask.

The self-contained breathing apparatus should be stored in a clean sanitary cupboard,

conveniently located. Whenever possible, respirators should be individually assigned
for hygenic purposes and to assure a good fit. After each use, they should be
inspected, cleaned and disinfected. It should also be cleaned and disinfected each
month, even if the respirator has not been used. A record should be kept of the
inspection date, and what was found at the time. The breathing air cylinders of the
self-contained breathing apparatus, should be tested and maintained in accordance
with the local pressure vessel regulations.

A new operator should be trained in respirator use, and fitting the face piece before
starting his assignment. A record should be kept of the training and fitting dates.

Contact lenses must not be worn with a respirator.

Canisters should not be used after expiration date.

DBNPA SAFETY HANDBOOK 47

Respirator Regulations
A respirator protection program is required in the U.S., and is recommended for other
locations:

• Written standard procedures governing the selection and use of respirators shall
be established.
• Written procedures shall be prepared, covering safe use of respirators in
dangerous atmospheres that might be encountered in normal operations or in
emergencies.
• Training shall provide an opportunity to handle the respirator, have it fitted
properly, test its face-piece-to-face seal, and wear it in normal air and a test
atmosphere
• A record shall be kept of inspection dates and findings, for respirators
maintained for emergency use.
• There shall be an annual inspection and evaluation to determine the
effectiveness of the respiratory program including respirator condition and
correct gas mask, face-piece fitting.

48 EDITION 2, 2016
5.. EMERGENCY RESPONSE

5.1. FACILITY EMERGENCY ACTION PLANNING...................................... 51

5.2. TRANSPORT EMERGENCY RESPONSE............................................... 52

5.3. HAZARD IDENTIFICATION................................................................... 53

5.4. CLASSIFICATION OF THE SUBSTANCE.............................................. 54

5.5. FIRE FIGHTING..................................................................................... 60

5.6. SPILLS OR LEAKS................................................................................. 61

5.7. EMERGENCY RECEPTACLES................................................................ 62

5.8. EXPOSURE TO DBNPA........................................................................ 63

 EMERGENCY RESPONSE

5.1 FACILITY EMERGENCY ACTION PLANNING

USA - OSHA (29 CFR 1910.119n and 29 CFR 1910.120q)

Emergency Action plans must be established and submitted to state and local
authorities for any facility where Threshold Quantities (TQ) of hazardous substances
are handled.

Reportable Quantities (RQ) - U.S.A.

DBNPA is classified as a hazardous substance due to its characteristic of reactivity with
water. It generates toxic gases, vapors or fumes in a quantity sufficient to present a
danger to human health or to the environment 40 CFR 261.23 (a) (4).

The disposal of DBNPA is regulated by the US federal RCRA regulations as a hazardous

waste, number D003. 40 CFR 261.23 (b).

Any release, leak or spill of 100 pounds (45.4 Kg) or more must be immediately
reported to the: National Response Center, phone: 800-424-8802.
New Jersey Toxic Catastrophic Prevention Act, Not Listed.

A Facility Emergency Coordinator is to be appointed to the local Emergency Planning

Committee.

The plan has to be reviewed and audited every three years. When there is a release
of a hazardous material, the Emergency Planning Committee is to be advised of the
following information (a transportation related release may be notified to the 911
emergency operator):
• That the released material, DBNPA is a toxic material.
• The quantity released, the time of the release and its duration.
• The media into which the release occurred.
• An indication of the health risks and sources for medical advice.
• Precautions to be taken by the local community, preferably as established in a
previously prepared emergency plan.
• Names and phone numbers for receiving further information on the material.

The Emergency Planning Committee is to be given the following follow-up information:

• Actions that were taken to contain the release.
• Any acute or chronic health problems that were the result of the release.
• Medical advice that was given to the exposed individuals.

DBNPA SAFETY HANDBOOK 51

EUROPE & UK: (EC Directive 82/501 with the latest amendments)
The European Economic Community has issued regulations on Major Accident
Hazards, Directive 82/501/EEC.
Storage sites for 50 tons or more of DBNPA (100 tons for granulate) must prepare
a written policy for identifying the major accident hazards at their sites and what
steps have been taken to prevent and limit the consequences of major accidents. In
addition, a safety management system, a training program, planning for emergencies
and reporting of major accidents or near misses are to be implemented at these sites.
Process sites for 200 tons or more of DBNPA must prepare a safety report, emergency
plans, and provide information to the public, in accordance with the schedules
contained in the directive.

5.2 TRANSPORT EMERGENCY RESPONSE

The driver of a vehicle involved in an accident while transporting a hazardous material
should immediately leave the vehicle, taking with him the shipping papers, and take
reasonable measures to extinguish any small fires.

The driver should call for help, and furnish the following information about the
hazardous material involved:

• UN number: 2811
• Hazard Class Placard.
• Hazardous response markings (e.g. EAC Code, NFPA diamond numbers).
• Quantity of hazardous material involved.
• Emergency contact phone number.

The first responder is generally the local fire department, which should act to:
• Protect persons, property and environment.
• Contain the release from a safe distance.
• Do not get involved in stopping the release.
• Ensure that a qualified responder has been called.

The Qualified responder, Hazardous Waste Operations & Emergency Response

(HAZWOPER), is called by the shipper of the hazardous material or by the first
responder if the shipper has not acted.
The Hazardous Materials Technician is qualified to stop the release.
Hazardous Materials Specialist provides support to responders with information
on the hazardous materials, but he is not authorized to become actively involved in
response action.

52 EDITION 2, 2016
 EMERGENCY RESPONSE

The shipper, the first responder or the qualified responder calls the Hazardous
Material Specialist when additional information or procedures are required.
Emergency Response Telephone Number should be clearly identified as “EMERGENCY
CONTACT” on labels and shipping papers.

• USA: CHEMTREC 1-800-424-9300

National Response Center 1-800-424-8802
ICL-IP AMERICA 1-304-675-1150
• UK: National Chemical Emergency Center “CARECHEM 24” 44-1865-407333
• EUROPE: ICL-IP Terneuzen B.V. 31-1156-89000
• ICL-IP, Israel 972-8-6544475/6
• ICL JAPAN: 81-3-6801-8430
• CHINA: 86-21-2315-7500
NRCC: 86-532-83889090

5.3 HAZARD IDENTIFICATION

ADR Hazard Identification Number

Toxic Solid n.o.s. UN 2811
Hazard identification number No. 60
EAC Emergency Action Code (EAC)
The UK CDG Road - Carriage of Dangerous Goods Regulations require the display of
this code number in the UK.
The EAC - Emergency Action Code for DBNPA is:
2 Use fine water spray.
X Prevent material from entering drains and watercourses.
Wear chemical protective clothing including gloves and breathing apparatus.
Contain and gather spilled material.

DBNPA SAFETY HANDBOOK 53

NFPA Hazard Identification: DBNPA
Health hazard: 3 Serious
Materials that under emergency conditions can cause serious or permanent injury.
Areas should be entered only when wearing self-contained breathing apparatus and
special protective clothing.

Flammability hazard 0
DBNPA does not burn.

Reactivity Hazard 1
Materials that in themselves are normally stable, but that can become unstable at
elevated temperatures and pressures.

Decomposition of DBNPA
If exposed to a temperature of 190˚C or more, decomposition will take place with the
generation of heat and toxic gases such as bromine, hydrogen bromide, CNBr, C2H5Br,
CH3Br and nitrogen oxides.
DBNPA is not combustible.
Check that the free bromine level does not increase over 3 ppm.

5.4 CLASSIFICATION OF THE SUBSTANCE

Regulation (EC) No 1272/2008 aligns the European Union system of classification,

labelling and packaging (CLP) of chemical substances and mixtures to the Globally
Harmonised System (GHS). DBNPA is classified in accordance to Annex I of this
Regulation as follows:

POWDER
Classification in accordance with Regulation (EC) No 1272/2008 [CLP/GHS]
Acute Tox. 2, H330, Fatal if inhaled
Acute Tox. 4, H302 Harmful if swallowed
Skin Irrit. 2, H315 Causes skin irritation
Skin Sens. 1, H317 May cause an allergic skin reaction
Eye Damage 1, H318 Causes serious eye damage
Aquatic Acute 1, H400 - Very toxic to aquatic life
Aquatic Chronic 3, H412 Harmful to aquatic life with long lasting effects

Additional OSHA/ WHMIS 2015 hazards

Combustible dust

54 EDITION 2, 2016
 EMERGENCY RESPONSE

Label elements
Labelling in accordance with CLP Regulation EC (No) 1272/2008

Symbol(s)

Signal Word DANGER

Hazard statements
H330 Fatal if inhaled
H302 Harmful if swallowed
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H318 Causes serious eye damage
H410 Very toxic to aquatic life with long lasting effects

Precautionary statements
P260 Do not breathe dust/fume/gas/mist/vapors/spray
P280 Wear protective gloves/protective clothing/eye protection/face
protection
P284 Wear respiratory protection
P302 + P352 IF ON SKIN: Wash with plenty of soap and water
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable
for breathing
P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you
feel unwell
P330 Rinse mouth
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue
rinsing
P310 Immediately call a POISON CENTER or doctor/physician

DBNPA SAFETY HANDBOOK 55

GRANULAR
GHS classification
Acute Tox. 4, H302 Harmful if swallowed
Skin Irrit. 2, H315 Causes skin irritation
Skin Sens. 1, H317 May cause an allergic skin reaction
Eye Damage 1, H318 Causes serious eye damage
Aquatic Acute 1, H400 - Very toxic to aquatic life
Aquatic Chronic 3, H412 Harmful to aquatic life with long lasting effects

Additional OSHA/ WHMIS 2015 hazards

Combustible dust

Labels and other form of warning

Symbol(s)

Signal Word DANGER

Hazard statements
H302 Harmful if swallowed
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H318 Causes serious eye damage
H410 Very toxic to aquatic life with long lasting effects

Precautionary statements
P261 Avoid breathing dust/fume/gas/mist/vapors/spray
P280 Wear protective gloves/protective clothing/eye protection/face
protection
P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you
feel unwell
P330 Rinse mouth
P302 + P352 IF ON SKIN: Wash with plenty of soap and water

56 EDITION 2, 2016
 EMERGENCY RESPONSE

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue
rinsing
P310 Immediately call a POISON CENTER or doctor/physician
P264 Wash hands thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P272 Contaminated work clothing should not be allowed out of the
workplace
P273 Avoid release to the environment
P391 Collect spillage
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention
P362 + P364 Take off all contaminated clothing and wash it before reuse
P501 Dispose of contents/container in accordance with national and
international regulations

Hazard statements
H302 Harmful if swallowed
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H318 Causes serious eye damage
H410 Very toxic to aquatic life with long lasting effects

Additional OSHA/ WHMIS 2015

hazards
May form combustible dust concentrations in air

Precautionary statements
P261 Avoid breathing dust/fume/gas/mist/vapors/spray
P280 Wear protective gloves/protective clothing/eye protection/face
protection
P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you
feel unwell
P330 Rinse mouth
P302 + P352 IF ON SKIN: Wash with plenty of soap and water
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue
rinsing
P310 Immediately call a POISON CENTER or doctor/physician
P264 Wash hands thoroughly after handling
P270 Do not eat, drink or smoke when using this product

DBNPA SAFETY HANDBOOK 57

P272 Contaminated work clothing should not be allowed out of the
workplace
P273 Avoid release to the environment
P391 Collect spillage
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention
P362 + P364 Take off all contaminated clothing and wash it before reuse
P501 Dispose of contents/container in accordance with national and
international Regulations

SOLUTION
GHS classification
Acute Tox. 4 H302 Harmful if swallowed
Eye Damage 1, H318 Causes serious eye damage
Skin Sens. 1, H317 May cause an allergic skin reaction

Signal Word DANGER

Hazard statements
H302 Harmful if swallowed
H318 Causes serious eye damage
H317 May cause an allergic skin reaction

Precautionary statements
P261 Avoid breathing fume/gas/mist/vapors/spray
P280 Wear protective gloves/protective clothing/eye protection/face
protection
P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if
you feel unwell
P330 Rinse mouth
P302 + P352 IF ON SKIN: Wash with plenty of soap and water
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER or doctor/physic

58 EDITION 2, 2016
 EMERGENCY RESPONSE

Classification:
Acute Toxicity 3 Eye Damage 1 Aquatic Acute 1
M factor = 1

GHS05 GHS06 GHS09

Signal word: Danger

Hazard pictograms

H&P statements as will appear in MSDS and label:

H331: Toxic if inhaled.
H302: Harmful if swallowed.
H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H318: Causes serious eye damage.
H400: Very toxic to aquatic life.
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P280: Wear protective gloves/protective clothing/eye protection/face
protection.
P301+P330+ P331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a
position comfortable for breathing
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or a doctor/physician

DBNPA SAFETY HANDBOOK 59

5.5 FIRE-FIGHTING
It is very important that DBNPA receptacles should not remain in a fire zone, as the
heat will lead to decomposition and to production of toxic vapors. If possible, the
DBNPA receptacles should be physically removed from the fire zone. Sometimes, it is
possible to move the fire source away from the DBNPA receptacles. The closed DBNPA
receptacles, involved in the fire should be cooled by the most practical means. Direct
contact with water should be avoided unless copious amounts of water can be used.

A fire in an area containing DBNPA should be extinguished with the most appropriate
means available. If the DBNPA is itself involved in the fire, use copious amounts
of water to extinguish the fire and cool the DBNPA to prevent and arrest its
decomposition due to heat.

If there is a DBNPA spill at the same time that there is a fire, the safety procedure for
spills has to be immediately implemented:
1. Evacuation of a zone, 50 m around the spill zone.
2. Self-contained breathing apparatus for the fire-fighters.
3. Wearing of impervious and chemical resistant, clothing. This clothing may not be
suitable for fire-fighting.
4. Protect water sources from being contaminated by spilled DBNPA.
5. Have all non-essential personnel leave the area immediately.

After the fire, all DBNPA containers should be carefully inspected for leaks or any
physical damage. The DBNPA supplier should be immediately informed of any unusual
conditions, which have been noticed.

On the road
If a vehicle carrying DBNPA catches fire and no DBNPA leak is detectable, the driver
should move the vehicle to an open area, remove shipping and other emergency
response documents (MSDS) from the vehicle and make reasonable efforts to
extinguish any small fires. He should then:
• Notify the local police and the fire department.
• Warn other drivers and pedestrians of the danger.
• Notify the nearest DBNPA handling facility.
• Stay at a safe distance until the incident has been declared resolved by the
responder in charge on the scene.
If the driver cannot reasonably extinguish the fire and/or a DBNPA leak is evident,
“Spills or Leaks” procedure (Section 5.7) should be followed immediately.

60 EDITION 2, 2016
 EMERGENCY RESPONSE

5.6 SPILLS OR LEAKS

DBNPA has been shipped for many years with very few accidents. This is due to the
care taken in packaging and handling this material.

Only trained, suitably protected personnel should respond to a DBNPA emergency.

See section 4.5 of this handbook for the personnel protective equipment
recommended for emergency response personnel. If there should be an uncontrolled
DBNPA spill or leak, immediately call the fire department, giving them the maximum
information. The competent authorities should be informed of the spill in accordance
with local regulations. Twenty-four hour telephone advice is available in most
countries for DBNPA road transport emergencies, as noted in section 5.2 above.

If there is a DBNPA spill, it should be immediately contained and gathered into

covered, clean, dry containers. Prevent the spilled DBNPA from penetrating a water
source or sewer system. Dust masks, goggles, gloves and full body covering clothing
should be worn if there is no decomposing of the DBNPA.

The area of decomposing DBNPA should only be entered with self-contained

breathing apparatus with a full-face mask, impervious fully-encapsulated and
chemically inert clothing, should be worn.

After collecting as much as possible into containers, the remaining traces of DBNPA
should be flushed to drain with copious amounts of water. A safer practice would be
to spread dry Sodium carbonate solution over the traces of DBNPA and then flush
to drain with copious amounts of water. Protect the DBNPA from contamination by
materials which can cause decomposition. Do not discard DBNPA spill material in the
conventional manner. Consult with the local authorities for disposal of DBNPA spill
material in an authorized disposal facility.

If a small amount of DBNPA begins to decompose for any reason, the immediate
area of 20 meters (60 feet) should be isolated. If a large amount of DBNPA begins
to decompose, a distance of 50 meters (150 feet) around the area, should be
immediately evacuated.

Further evacuation decisions should be based on the size of the spill, wind intensity,
height of the release above the ground, and the relative health level of the people
in the area. All non-essential personnel should be kept out of the area. Used, empty
receptacles can be rinsed with copious amounts of water and disposed of in the
conventional manner.

DBNPA SAFETY HANDBOOK 61

5.7 EMERGENCY REPAIRS
Empty, clean, dry, covered receptacles (overpacks) should be available for leaking
DBNPA drums and for collecting spilled DBNPA or contaminated absorbent materials.
It is difficult to define the protective clothing required for the protection of rescue, fire
and emergency repair teams, who have to enter a DBNPA spill area, because of the
variety of conditions which can be encountered.

The following points are indicative of the precautions to be taken under various levels
of exposure. Dust masks, goggles, gloves and full body covering clothing should be
worn when handling a DBNPA spill which is not decomposing. If the DBNPA spill
material is decomposing, enter the spill area, only with a self-contained breathing
apparatus. This equipment is for limited time depending on the cylinder size and
pressure. One apparatus should be provided for each emergency worker who will be
expected to enter the danger zone. Two spare cylinders should be provided for each
apparatus. This should be sufficient equipment for the initial response.

Encapsulated, chemically inert and impervious clothing will prevent DBNPA from
causing chemical burns. Not all protective clothing is suitable for fire-fighting.

62 EDITION 2, 2016
 EMERGENCY RESPONSE

5.8 EXPOSURE TO DBNPA

When a person who has been exposed to DBNPA is sent to a hospital, information
should be pinned to the person’s clothing stating that he was exposed to DBNPA. If
possible, the MSDS should be sent with the patient.

Acute exposure:
Ocular Corrosive
Dermal Irritant
Sensitization: May cause skin sensitization
Inhalation: In severe cases pulmonary oedema may develop Irritant to upper
respiratory tract
Ingestion: Corrosive by ingestion.
Abdominal pain, nausea, vomiting and diarrhea

First Aid
Eye contact: Holding the eyelids apart, flush eyes promptly with copious flowing
water for at least 20 minutes. Get medical attention immediately.
Skin contact: Remove contaminated clothing. Wash skin thoroughly with mild soap
and plenty of water for at least 15 minutes. Wash clothing before re-
use. Get medical attention if irritation persists.
Inhalation: In case of dust inhalation or breathing fumes released from heated
material, remove person to fresh air. Keep him quiet and warm.
Apply artificial respiration if necessary and get medical attention
immediately.
Ingestion: If swallowed, wash mouth thoroughly with plenty of water and give
water to drink. Get medical attention immediately.

NOTE: Never give an unconscious person anything to drink!.

Notes to the physician: Corrosive to eyes

In case of ingestion DO NOT induce vomiting. No specific antidote.

Treat symptomatically and supportively.

DBNPA SAFETY HANDBOOK 63

6.. OPERATORS GUIDE

6.1. OPERATOR HEALTH MONITORING................................................... 67

6.2. OPERATOR/DRIVER SAFETY TRAINING............................................. 69

 OPERATORS GUIDE

6.1 OPERATOR HEALTH MONITORING

Workers regularly exposed to DBNPA should be given routine medical check-ups.

This applies to personnel of operations where DBNPA is used, stored, filled, or

unloaded.
(US Code of Federal Regulations, 29 CFR 1910.120 (f))

There are no regulations or standards indicating a medical test, which would show an
overexposure to DBNPA.

It is recommended that complete medical records be kept for each person working in
a facility where there is potential exposure to DBNPA vapors.

A sample medical record is provided on the following page.

DBNPA SAFETY HANDBOOK 67

MEDICAL RECORD FOR EMPLOYEE EXPOSED

Name: Date of birth:

Address:
Occupation: Date start employment:

Previous history of following disorders Yes / No

(Provide details if necessary)

Skin diseases
Lung diseases
Liver diseases
Kidney diseases
Psychiatric
Neurologic

MEDICAL EXAMINATIONS
Date Test Remarks

SICK LEAVE
From To Reasons

68 EDITION 2, 2016
 OPERATORS GUIDE

6.2 OPERATOR / DRIVER SAFETY TRAINING

The installation management should be aware of the potential dangers of DBNPA.

Management personnel should undergo training in DBNPA specific safety inspections
and safety auditing.

Workers involved with DBNPA must have special safety training regarding the
precautions to observe in accordance with local regulations. This applies to personnel
of operations where DBNPA is used, stored, filled or unloaded.

The safety training for handling DBNPA has to include both theoretical classroom
courses and practical hands-on and observation exercises, appropriate to the level of
likely exposure of the individual worker to DBNPA.

Records should be kept of each person’s participation in initial training and refresher
courses.

The theoretical classroom training should be at least one day.

Some of the subjects to be covered should be:
• The main types of hazards
• Packaging details
• Labelling and marking to indicate hazards
• Precautions during loading and unloading
• Environmental protection
• First-aid
• Fire-fighting
• Selection and use of personal protection equipment
• Respiratory protection
• Emergency procedures

Refresher training courses should be taken regularly, at least every two or three years,
and should include new technical and substance-related developments.
The refresher course should be for at least one full day.

DBNPA SAFETY HANDBOOK 69

EMPLOYEE SAFETY TRAINING RECORD

Name: Date of birth:

Address:
Occupation: Date start employment:
Education:

Period Institute name Place Certificate

High School
Technical School
University
Post Graduate
Other

“Company organized” courses:

Course Name Institute name Period Certificate

70 EDITION 2, 2016
APPENDIX

A.. TYPICAL SPECIFICATIONS................................................................... 73

B..REFERENCES......................................................................................... 74
APPENDIX A:

Typical Quality Specifications

DPNPA Technical grade

Appearance White to off- white powder
Assay (as DBNPA) % 98 min
Loss on drying % 0.5 max

DBNPA Granulate
Appearance White to off- white granules
Assay (as DBNPA) % 98 min
Loss on drying % 0.5 max

DBNPA Solution 20% in solvent DPG

Appearance clear, yellow solution
Assay (as DBNPA) % 20.0 - 23.0
Specific gravity 20/20 1.16 - 1.21
Viscosity cP at 200c 45

DBNPA Solution 20% in solvent PEG

Appearance clear solution
Assay (as DBNPA) % 20.0 min
Turbidity, NTU 3.0 max
pH at 25 deg C 2.0 - 6.7
Specific gravity 1.216 - 1.300

DBNPA SAFETY HANDBOOK 73

APPENDIX B:

REFERENCES

1. ICL-IP
DBNPA PRODUCT DATA SHEET
(www.icl-ip.com)
2. ICL Industrial Products
MATERIAL SAFETY DATA SHEET for DBNPA
(www.icl-ip.com)
3. UNITED NATIONS TRANSPORT OF DANGEROUS GOODS (ORANGE BOOK)
Fifteenth Revised Edition, 2007
4. INTERNATIONAL MARITIME DANGEROUS GOODS (IMDG) CODE, 2008 Edition
(www.imo.org)
5. EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF
DANGEROUS GOODS BY ROAD (ADR), 2009 Edition (Restructured)
(www.unece.org/trans/danger/danger.htm)
6. US CODE OF FEDERAL REGUALTIONS (Issued annually)
TITLE 29 - Occupational Safety and Health Administration (OSHA), 2008
TITLE 49 - Department of Transportation (DOT), 2008
(www.access.gpo.gov/nara/cfr/index.html)
7. International Air Transportation Association
DANGEROUS GOODS REGULATIONS 42nd Edition, January 2010
(www.iata.org)
8. AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL
HYGIENISTS (ACGIH)
THRESHOLD LIMIT VALUES, 2009
(www.acgih.org)
9. US DEPARTMENT OF TRANSPORTATION
EMERGENCY RESPONSE GUIDE BOOK 2008
(http://www.phmsa.dot.gov/hazmat/library/erg)
10. National Institute for Occupational Safety and Health (NIOSH)
POCKET GUIDE TO CHEMICAL HAZARDS, 2005 Edition
(http://www.cdc.gov/niosh/npg/)
11. Z. E. Jolles, 1966
BROMINE AND ITS COMPOUNDS

Note: The internet websites are given for reference only, as their contents are continually changing.

74 EDITION 2, 2016
Head Office
ICL-IP

July 2016
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www.icl-ip.com