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Doha-Qatar

CLASS XI REVISION TEST- INTRODUCTION TO ORGANIC CHEMISTRY

Class 11 - Chemistry
Time Allowed: 30 minutes Maximum Marks: 15

Section A
1. The IUPAC name of the following compound is: [1]
CH
3 OH

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H3 C − CH − CH − CH2 − COOH

a) 4, 4-Dimethyl-3-hydroxybutanoic acid b) 4-Methyl-3-hydroxypentanoic acid

c) 2-Methyl-3-hydroxypentan-5-oic acid d) 3-Hydroxy-4-methylpentanoic acid

2. Covalent bond can undergo fission in two different ways. The correct representation involving heterolytic fission [1]
of CH3-Br is

a) b)

c) d)

3. Write the state of hybridisation of carbon in the compound, HC ≡ N and shape of the molecule. [1]

a) sp3 hybridised carbon, tetrahedral b) sp3 hybridised carbon, trigonal pyramidal

c) sp3 hybridised carbon, trigonal planar d) sp hybridised carbon, linear

4. Propanal and propanone are [1]

a) Position isomers b) Functional group isomers

c) Chain isomers d) Steroisomers

5. Assertion (A): In ethyl cation positively charged carbon atom has a completely filled p-orbital. [1]
Reason (R): Hyperconjugation is a permanent effect.

a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.

c) A is true but R is false. d) A is false but R is true.

6. Assertion (A): Pent-1-ene and pent-2-ene are position isomers. [1]
Reason (R): Position isomers differ in the position of a functional group or a substituent.

a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.

c) A is true but R is false. d) A is false but R is true.

Section B
[2]
+ + +

7. Explain why (C H 3 )3 C is more stable than C H

3 C H2 and C H is the least stable cation.
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 8. Name the compounds: [2]

9. Draw all its possible chain isomers of C5H12and write their IUPAC names. [2]
Section C
10. Draw the resonance structures for the following compounds. Show the electron shift using curved arrow [3]
notation.
i. C6H5OH
ii. C6H5NO2

iii. CH3CH=CHCHO

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