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Effect of curing methods on the properties of plain and blended cement concretes
A.S. Al-Gahtani *
Department of Civil Engineering, King Fahd University of Petroleum and Minerals, Dhahran, Saudi Arabia
a r t i c l e i n f o a b s t r a c t
Article history: This paper reports result of a study conducted to investigate the effect of curing methods on the proper-
Received 15 June 2009 ties of plain and blended cement concretes. The concrete specimens were prepared with Type I, silica
Received in revised form 13 August 2009 fume, and fly ash cement concretes. They were cured either by covering with wet burlap or by applying
Accepted 14 August 2009
two types of curing compounds, namely water-based and acrylic-based. The effect of curing methods on
Available online 14 November 2009
the properties of plain and blended cement concretes was assessed by measuring plastic and drying
shrinkage, compressive strength, and pulse velocity. Results indicated that the strength development
Keywords:
in the concrete specimens cured by covering with wet burlap was more than that in the specimens cured
Curing
Plain and blended cement concretes
by applying water – and acrylic-based curing compounds. Concrete specimens cured by applying curing
Plastic and drying shrinkage compounds exhibited higher efficiency in decreasing plastic and drying shrinkage strain than specimens
Compressive strength cured by covering with wet burlap. The performance of acrylic-based curing compound was better than
Pulse velocity that of water-based curing compound. The data developed in this study indicate that curing compounds
Curing efficiency index could be utilized in situations where curing with water is difficult. Among the two curing compounds
investigated, acrylic-based curing compound performed better than the water-based curing compound.
Ó 2009 Elsevier Ltd. All rights reserved.
1. Introduction gested that the permeability of the surface concrete may increase
five to ten folds if concrete is insufficiently cured. High wind and
The objective of curing is to keep concrete saturated or as nearly temperature increases the drying of concrete skin. Therefore, the
wet to assist the hydration of cement. The rate and degree of recommendations of ACI Committee 305 regarding minimizing
hydration, and the resulting strength of concrete and other proper- the rate of water evaporation, such as lowering concreting temper-
ties, depend on the curing process that follows placing and consol- ature, increasing the humidity by water spraying, and erecting
idation of the plastic concrete. Hydration of cement continues for wind barriers, should be adopted. The protection of concrete
years at a decreasing rate as long as the mixture contains water against corrosion of steel, which is mainly due to the ingress of
and the temperature conditions are favorable. Once the water is chloride ions, is greatly decreased with an increase in the period
lost, hydration ceases. of curing [2].
Curing of concrete is very essential for its strength gain and Curing becomes even more important if it contains supplemen-
durability. Proper curing becomes very difficult under hot weather tary cementing materials, such as fly ash, ground granulated blast
conditions as low humidity and high ambient temperature greatly furnace slag, or silica fume, and it is subjected to hot and dry envi-
assist in the evaporation of the mix-water. Concrete is generally ronments immediately after placement and consolidation. How-
cured by water ponding. However, membrane-forming curing ever concretes moist cured for only two days exhibited
compounds are also utilized for this purpose. Curing compounds significant improvement in strength and other characteristics, as
are utilized in situations where curing by water ponding is not compared with concrete without any curing [3].
practical. However, with increasing scarcity of water, there is pres- Concrete is mostly cured by covering it with wet burlap. In
sure on the construction industry to decrease its water consump- some cases it is also done by coating the freshly cast surface with
tion. This problem is more acute in countries where natural a curing compound. The curing compound acts as a barrier coating
sources of water are scarce and it has to be obtained from other and does not allow the mix water to evaporate from the concrete in
sources, such as desalination of the seawater. case of dry conditions prevailing on the surface of concrete. In
In general, curing ensures that the mix water is available for ce- some cases a curing compound is applied after initial water curing
ment hydration. According to Powers [1] a minimum of 80% for a certain period of time.
humidity is required for hydration of cement. Moreover, he sug- The most effective method of curing is to keep the exposed con-
crete surfaces continuously moist by ponding or spraying with
* Fax: +966 38602565.
water. In this method, the concrete is kept fully saturated during
E-mail address: agahtani@kfupm.edu.sa the period, the ideal condition for strength development and
0950-0618/$ - see front matter Ó 2009 Elsevier Ltd. All rights reserved.
doi:10.1016/j.conbuildmat.2009.08.036
A.S. Al-Gahtani / Construction and Building Materials 24 (2010) 308–314 309
hydration of cement. Another curing method is to cover the surface 2. Methodology of research
with an impermeable sheet, such as polyethylene. Owing to
2.1. Materials
restrictions encountered in the field, curing by water-retaining
techniques, which also includes the application of curing mem- As stated earlier, the concrete specimens were prepared with plain, very fine fly
branes, are also used. When applied onto a concrete surface, curing ash (VFFA), silica fume, and fly ash cements. The VFFA cement concrete specimens
compounds leave a moisture retentive membrane, either upon were prepared with 10% VFFA while silica fume cement concrete specimens con-
tained 7% silica fume. Fly ash constituted 30% of the cementitious material in the
evaporation of their volatile component (solvent-based com-
fly ash cement concrete specimens.
pounds) or through their reaction with the alkaline concrete sur- ASTM C150 Type I cement was utilized in the preparation of both plain and
face (water-based curing compounds). blended cement concrete specimens. Table 1 shows the chemical composition of
Wang et al. [4] evaluated the performance of membrane curing Type I cement and the pozzolanic materials used in the preparation of concrete
and the experimental results showed that the effectiveness of specimens.
The concrete mixtures were proportioned on a weight basis. The following
membrane curing was dependent markedly on the time of its
parameters were kept constant in all the mixtures:
application. Among curing compounds studied, chlorinated rubber
was found to be the most effective one, followed by the solvent- (1) Cementitious material content: 370 kg/m3.
based curing compound, and the least effective was water-based (2) Coarse/fine aggregate ratio: 1.64.
type. (3) Effective water to cementitious materials ratio: 0.45.
Austin and Robins [5] indicated that wet burlap curing was the
Crushed limestone was used as coarse aggregates in all the concrete mixtures. It
most effective and air curing was the least effective between 7 and
was washed to remove dust and other fines. The maximum size of the coarse aggre-
28 days in hot climate. Moist cured blast furnace slag cement con- gates was 12.5 mm and its grading corresponded to ASTM C 33 size # 7. Dune sand
crete exhibited a greater increase in the pulse velocity than simi- with a fineness modulus of 1.3, absorption of 0.57%, and specific gravity of 2.57 was
larly cured plain cement concrete mixes. Wang and Black [6] used as fine aggregate.
evaluated the performance of curing membranes. It was reported
that the Curing Efficiency Index (CEI) correlated well with the 2.2. Specimen preparation
capability of the curing membranes in retaining moisture within
concrete. The concrete constituents were mixed in an electrically operated revolving
drum type concrete mixer. The ingredients were initially mixed in dry condition
Tests conducted by Grafe and Grube [7] on the influence of
and then water was added. Table 2 lists the sizes of specimens that were utilized
curing on the gas permeability of concrete prepared with differ- to evaluate the performance of curing methods. The molds were filled in two layers
ent types of cement indicated that concrete containing GGBFS and vibrated until the consolidation of concrete, indicated by the formation of a thin
and PFA had greater permeability than Portland cement concrete, sheen of mortar on the surface.
when curing was poor (1 day curing). However, they concluded
that with prolonged sealed curing, mixes prepared with cement 2.3. Exposure
replacement materials may become more impervious than analo-
gous concretes (same water–cement ratio and same cement con- The concrete specimens were cured by one of the following methods:
tent) containing only Portland cement. Data developed by
(i) By covering with wet burlap.
Rasheeduzzafar et al. [2] indicated that the protection provided
(ii) By applying one of the following curing compounds:
by concrete against corrosion of steel by migration of chlorides – acrylic-based;
into the concrete is greatly dependent upon the duration of – water-based.
curing.
It has generally been accepted that curing is more important for The concrete specimens for normal curing were covered with plastic sheet and
allowed to harden under laboratory conditions for 24 h. Thereafter, they were
concrete with mineral admixtures than for normal concrete [8]. demoulded and an epoxy coating was applied on the molded surfaces. They were
Water curing has more effect on the permeability than on the then cured for 7 days by covering with wet burlap. The epoxy coating was applied
strength of concrete. Dinku and Reinhardt [9] have shown that to represent conditions similar to those for the specimens cured by the application
the gas permeability is sensitive to changes in curing duration, of the curing compounds in the field.
In the second group of concrete specimens, curing compound was applied when
water/cement ratio, age of testing and moisture history of con-
the bleeding water, if any, had evaporated from the surface. The application rate
crete; according to their research, it is possible to predict the gas was similar to that recommended by the supplier. After 24 h of casting, the speci-
permeability from the capillary sorptivity measurements. Martys
and Ferraris [10] have shown that the sorptivity coefficient is
essential to predict the service-life of concrete as a structural mate-
rial and to improve its performance. Table 1
According to Khan and Ayers [11], the minimum length of cur- Chemical composition of Type I cement and supplementary cementing materials.
ing should be optimized in terms of several properties, such as Constituent Type I Very fine fly ash Silica Fly
strength, permeability and the movement of aggressive gases (wt.%) cement (VFFA) fume ash
and/or liquids from the environment. Their results show that the SiO2 20.52 53.5 93.7 52.8
minimum lengths of curing for, Portland cement, fly ash and the Al2O3 5.64 34.3 0.16 34.3
silica fume cement concrete mixtures were 3, 3.75 and 6.5 days, Fe2O3 3.8 3.6 0.12 3.6
CaO 64.35 4.4 0.65 4.4
respectively. In general, it has been shown that concretes prepared
Mgo 2.11 1 0.39 1.1
with mineral admixtures are more sensitive to water curing than SO3 2.1 – 0.23 0.1
concretes prepared with ordinary Portland cement. Loss on ignition 0.7 – 5.14 0.8
Though few studies have been conducted earlier to evaluate ef- K2O 0.36 0.8 0.02 0.5
fect of curing methods on the properties of concrete, data are Na2O 0.19 – 0.02 0.4
Na2O equiv 0.43 – –
sparse on the effect of curing compounds on the properties, espe- MnO2 – – 0.1
cially shrinkage and denseness, of plain and blended cement con- TiO2 – 1.7 – 1.6
cretes. This study was conducted to evaluate the effect of curing C3S 56.7 – – –
methods on the properties of plain and blended cement concretes C2S 16.05 – – –
C3A 8.25 – – –
with the aim of specifying type of curing compound for areas with
C4AF 11.56 – – –
water scarcity.
310 A.S. Al-Gahtani / Construction and Building Materials 24 (2010) 308–314
-6
Plastic shrinkage strain, mm/mm x10
500
300
400 250
200
300
150
200
100
100
50
0 0
0 200 400 600 800 1000 1200 1400 1600 0 200 400 600 800 1000 1200 1400 1600
Time, Minutes Time, Minutes
Fig. 1. Plastic shrinkage strain in the plain cement concrete specimens. Fig. 2. Plastic shrinkage strain in the VFFA cement concrete specimens.
A.S. Al-Gahtani / Construction and Building Materials 24 (2010) 308–314 311
400 600
Air Water-compound Acrylic-compound
-6
-6
Drying shrinkage strain, mm/mm x10
Plastic shrinkage strain, mm/mm x10
500
300
400
200 300
200
100 7days-burlap
100 Water-compound
Acrylic-compound
0 0
0 200 400 600 800 1000 1200 1400 1600 0 20 40 60 80 100 120
Time. Minutes Time, days
Fig. 3. Plastic shrinkage strain in the silica fume cement concrete specimens. Fig. 6. Drying shrinkage strain in the VFFA cement concrete specimens.
pound was less than that in the specimens cured by covering with
500 wet burlap or by the application of the water-based curing com-
-6
450 pound. The maximum drying shrinkage strain in the concrete spec-
Plastic shrinkage strain, mm/mm x10
400
imens cured by covering with wet burlap for 7 days or applying
water-based or acrylic-based curing compound was 540, 501,
350
and 47010 6 mm/mm, respectively.
300 The drying shrinkage strain in the silica fume cement concrete
250 specimens is shown in Fig. 7. An increase in the drying shrinkage
200 strain was noted in all the concrete specimens. The maximum dry-
ing shrinkage strain in the concrete specimens cured by covering
150
Air with wet burlap for 7 days or applying water-based or acrylic-
100
Water-compound based curing compounds was 508, 469, and 45510 6 mm/mm,
50 Acrylic-compound respectively.
0 The drying shrinkage strain in the fly ash cement concrete spec-
0 200 400 600 800 1000 1200 1400 1600 imens is shown in Fig. 8. The maximum drying shrinkage strain in
Time, Minutes
the concrete specimens cured by covering with wet burlap for
Fig. 4. Plastic shrinkage strain in the fly ash cement concrete specimens. 7 days or applying water-based or acrylic-based curing compounds
was 451, 439, and 42810 6 mm/mm, respectively.
300
tion of water-based curing compound exhibited higher drying
shrinkage strain than those cured by covering with wet burlap
200
for 7 days or by applying acrylic-based curing compound. Maxi-
mum drying shrinkage strain in the concrete specimens cured by 7days-burlap
100
covering with wet burlap for 7 days or applying water-based or ac- Water-compound
rylic-based curing compounds was 491, 526, and 47510 6 mm/ Acrylic-compound
mm, respectively. 0
0 20 40 60 80 100
Fig. 6 shows the drying shrinkage strain in the VFFA cement
Time. days
concrete specimens. The drying shrinkage strain in the concrete
specimens cured by the application of acrylic-based curing com- Fig. 7. Drying shrinkage strain in the silica fume cement concrete specimens.
312 A.S. Al-Gahtani / Construction and Building Materials 24 (2010) 308–314
500 40
-6
35
Drying shrinkage strain, mm/mm x10
400
200
20
wet burlap
7days-burlap
100 15 acrylic-compound
Water-compound
water-compound
Acrylic-compound
10
0 0 20 40 60 80 100
0 20 40 60 80 100
Age, days
Time, days
Fig. 11. Compressive strength development in the silica fume cement concrete
Fig. 8. Drying shrinkage strain in the fly ash cement concrete specimens.
specimens.
35
the compressive strength of concrete specimens cured by covering
with wet burlap for 7 days or applying acrylic-based, or water-
based curing compound was 34.2, 30.9, and 29.4 MPa, respectively.
30 Fig. 11 shows the compressive strength development in the sil-
Compressive strength, MPa
40
35
35
Compressive strength, MPa
30
Compressive strength, MPa
30
25
25
20
20
wet burlap wet burlap
15 acrylic-compound 15 acrylic-compound
water-compound water-compound
10 10
0 10 20 30 40 50 60 70 80 90 100 0 20 40 60 80 100
Age, days Age, days
Fig. 10. Compressive strength development in the VFFA cement concrete Fig. 12. Compressive strength development in the fly ash cement concrete
specimens. specimens.
A.S. Al-Gahtani / Construction and Building Materials 24 (2010) 308–314 313
4.650
4.1
4.600
Pulse Velocity, Km/s
4.400
3.8
4.350
3.7 4.300
4.250
3.6
4.200
14 28 90
Age,days 14 28 90
Age, days
Fig. 13. Pulse velocity in the plain cement concrete specimens.
Fig. 15. Pulse velocity in the silica fume cement concrete specimens.
specimens cured by covering with wet burlap for 7 days was more
than that of concrete specimens cured by applying a curing com-
pound. Further, the pulse velocity in the concrete specimens cured wet burlap acrylic-compound water-compound
by applying the acrylic-based curing compound was more than 4.600