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Pictograms:
Hazard statements
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H412 Harmful to aquatic life with long lasting effects.
Precautionary statements
P280 Wear protective gloves and eye/face protection.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor.
P501 Dispose of contents/container to an appropriate recycling or disposal facility.
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3.2. Mixtures
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Hazardous components
CAS No Chemical name Quantity
EC No Index No REACH No
Classification (Regulation (EC) No 1272/2008)
85590-00-7 10-methacryloyloxydecyl dihydrogen phosphate 5 - < 10 %
Skin Irrit. 2, Eye Irrit. 2, STOT SE 3; H315 H319 H335
72869-86-4 7,7,9-(resp. 7,9,9-)Trimethyl-4,13-dioxo-3,14-dioxa-5,12-diaza-hexadecane-1,16-diol 5 - < 10 %
dimethacrylate (mixture of isomers)
276-957-5 01-2120751202-68
Skin Sens. 1B, Aquatic Chronic 2; H317 H411
41637-38-1 ethoxylated bisphenol A dimethacrylate 1-<5%
609-946-4 01-2119980659-17
Aquatic Chronic 4; H413
Aliphatic epoxy diacrylate 1-<5%
01-2119980027-36
Acute Tox. 4, Eye Dam. 1, Skin Sens. 1B, Aquatic Chronic 4; H302 H318 H317 H413
868-77-9 2-hydroxyethyl methacrylate 1-<5%
212-782-2 607-124-00-X 01-2119490169-29
Skin Irrit. 2, Eye Irrit. 2, Skin Sens. 1; H315 H319 H317
109-16-0 Triethylene glycol dimethacrylate 1-<5%
203-652-6 01-2119969287-21
Skin Sens. 1B; H317
Aliphatic epoxy acrylate <1%
Skin Irrit. 2, Skin Sens. 1A, Aquatic Chronic 3; H315 H317 H412
21245-02-3 2-Ethylhexyl 4-(dimethylamino)benzoate <1%
244-289-3 01-2120766649-35
Repr. 1B; H360
2867-47-2 2-dimethylaminoethyl methacrylate <1%
220-688-8 607-132-00-3
Acute Tox. 4, Acute Tox. 4, Skin Corr. 1C, Eye Irrit. 2, Skin Sens. 1; H312 H302 H314 H319 H317
72829-09-5 1,12-Dodecane Dimethacrylate < 0.1 %
276-900-4 01-2120756306-53
Skin Sens. 1B, Aquatic Acute 1, Aquatic Chronic 1; H317 H400 H410
80-62-6 methyl methacrylate; methyl 2-methylprop-2-enoate; methyl 2-methylpropenoate < 0.1 %
201-297-1 607-035-00-6 01-2119452498-28
Flam. Liq. 2, Skin Irrit. 2, Skin Sens. 1, STOT SE 3; H225 H315 H317 H335
Full text of H and EUH statements: see section 16.
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DNEL/DMEL values
CAS No Substance
DNEL type Exposure route Effect Value
72869-86-4 7,7,9-(resp. 7,9,9-)Trimethyl-4,13-dioxo-3,14-dioxa-5,12-diaza-hexadecane-1,16-diol dimethacrylate (mixture of
isomers)
Worker DNEL, long-term inhalation systemic 3,3 mg/m³
Worker DNEL, long-term dermal systemic 1,3 mg/kg bw/day
41637-38-1 ethoxylated bisphenol A dimethacrylate
Worker DNEL, long-term inhalation systemic 3,52 mg/m³
Worker DNEL, long-term dermal systemic 2 mg/kg bw/day
868-77-9 2-hydroxyethyl methacrylate
Worker DNEL, long-term inhalation systemic 4,9 mg/m³
Worker DNEL, long-term dermal systemic 1,3 mg/kg bw/day
109-16-0 Triethylene glycol dimethacrylate
Worker DNEL, long-term inhalation systemic 48,5 mg/m³
Worker DNEL, long-term dermal systemic 13,9 mg/kg bw/day
13463-67-7 titanium dioxide
Worker DNEL, long-term inhalation local 10 mg/m³
80-62-6 methyl methacrylate; methyl 2-methylprop-2-enoate; methyl 2-methylpropenoate
Worker DNEL, long-term inhalation systemic 208 mg/m³
Worker DNEL, long-term dermal systemic 13,7 mg/kg bw/day
Worker DNEL, acute dermal local 1,5 mg/cm²
128-37-0 2,6-Di-tert-butyl-4-methylphenol
Worker DNEL, long-term inhalation systemic 3,5 mg/m³
Worker DNEL, long-term dermal systemic 0,5 mg/kg bw/day
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PNEC values
CAS No Substance
Environmental compartment Value
72869-86-4 7,7,9-(resp. 7,9,9-)Trimethyl-4,13-dioxo-3,14-dioxa-5,12-diaza-hexadecane-1,16-diol dimethacrylate (mixture of
isomers)
Freshwater 0,01 mg/l
Marine water 0,001 mg/l
Freshwater sediment 4,56 mg/kg
Marine sediment 0,456 mg/kg
Micro-organisms in sewage treatment plants (STP) 3,61 mg/l
Soil 0,91 mg/kg
868-77-9 2-hydroxyethyl methacrylate
Freshwater 0,482 mg/l
Freshwater sediment 3,79 mg/kg
Micro-organisms in sewage treatment plants (STP) 10 mg/l
Soil 0,476 mg/kg
109-16-0 Triethylene glycol dimethacrylate
Freshwater 0,164 mg/l
Marine water 0,0164 mg/l
Freshwater sediment 1,85 mg/kg
Marine sediment 0,185 mg/kg
Micro-organisms in sewage treatment plants (STP) 10 mg/l
Soil 0,274 mg/kg
13463-67-7 titanium dioxide
Freshwater 0,127 mg/l
Freshwater (intermittent releases) 0,61 mg/l
Marine water 1 mg/l
Freshwater sediment 1000 mg/kg
Marine sediment 100 mg/kg
Micro-organisms in sewage treatment plants (STP) 100 mg/l
Soil 100 mg/kg
80-62-6 methyl methacrylate; methyl 2-methylprop-2-enoate; methyl 2-methylpropenoate
Freshwater 0,94 mg/l
Marine water 0,094 mg/l
Freshwater sediment 10,2 mg/kg
Marine sediment 10,2 mg/kg
Micro-organisms in sewage treatment plants (STP) 10 mg/l
Soil 1,48 mg/kg
128-37-0 2,6-Di-tert-butyl-4-methylphenol
Freshwater 0,000199 mg/l
Freshwater (intermittent releases) 0,00199 mg/l
Marine water 0,000199 mg/l
Freshwater sediment 0,0996 mg/kg
Marine sediment 0,00996 mg/kg
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Explosive properties
The product is not: Explosive.
Oxidizing properties
The product is not: oxidising.
Other safety characteristics
Evaporation rate: not determined
Solid content: not determined
10.1. Reactivity
No hazardous reaction when handled and stored according to provisions.
10.2. Chemical stability
The product is stable under storage at normal ambient temperatures.
10.3. Possibility of hazardous reactions
No known hazardous reactions.
10.4. Conditions to avoid
none
10.5. Incompatible materials
No information available.
10.6. Hazardous decomposition products
No known hazardous decomposition products.
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15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulatory information
Restrictions on use (REACH, annex XVII):
Entry 75
Information according to 2012/18/EU Not subject to 2012/18/EU (SEVESO III)
(SEVESO III):
National regulatory information
Employment restrictions: Observe restrictions to employment for juveniles according to the 'juvenile
work protection guideline' (94/33/EC).
Water hazard class (D): 2 - obviously hazardous to water
Skin resorption/Sensitization: Causes allergic hypersensitivity reactions.
15.2. Chemical safety assessment
Chemical safety assessments for substances in this mixture were not carried out.
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(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's
safety data sheet.)