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ELECTRICITY
Electricity | Prof. Dr.-Ing. Joachim Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 2
Electricity is Pure Exergy (1/2)
Electricity | Prof. Dr.-Ing. Joachim Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 3 Sources: EUROSTAT (2022); Exergy Economics (n. d.)
Electricity is Pure Exergy (2/2)
Electricity | Prof. Dr.-Ing. Joachim Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 4 Sources: EUROSTAT (2022); Exergy Economics (n. d.)
Main Technologies of Electricity Generation
Nuclear-plant
Offshore-wind Hydro-plant
Coal-plant
Combined cycle
Onshore-wind Solar-plant plant
Electricity | Prof. Dr.-Ing. Joachim Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 5 Image sources: Kernenergie (n. d.), NDR (n. d.), Voith (2016)
Converting Primary Energy into Mechanical and
Electrical Energy
Known from lecture “Energy”
Nuclear fission/
Combustion Absorption
heat transfer
Thermal internal energy of Thermal internal energy of Inner and kinetic energy
the combustion gas the "heat carrier" of the atmosphere
Internal
Potential energy of Wind power
combustion
water plant
engine
Electrical energy
Electricity | Prof. Dr.-Ing. Joachim Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 6 Source: Baehr & Kabelac (2012)
Electricity Generation
▪ Electricity, the flow of electrical power, is a secondary energy source generated by the
conversion of primary sources of energy like fossil fuels, nuclear, wind or solar.
▪ Utility-scale generation of electricity is done by rotating electric generators, by
photovoltaic systems or electrochemistry.
Electricity | Prof. Dr.-Ing. Joachim Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 7
Definition of Terms for Energy Conversion
▪ A power plant has the task of converting primary energy into rotational or electrical
energy.
Heat losses
Own consumption
Heat extraction
𝐸𝑙𝑒𝑐𝑡𝑟𝑖𝑐𝑎𝑙 𝑜𝑢𝑡𝑝𝑢𝑡
Efficiency = 𝐻𝑒𝑎𝑡 𝑖𝑛𝑝𝑢𝑡 (𝑓𝑢𝑒𝑙 𝑝𝑜𝑤𝑒𝑟) (gross or net) (Point in time)
Electricity | Prof. Dr.-Ing. Joachim Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 8
Currently Achievable Conversion Efficiencies
Technical Conversion
Input energy Output energy Conversion
process efficiency
Fuel cell Chemical energy Electrical energy Direct 60 %
Combustion Chemical energy Heat Direct 97 %
Steam power plant Chemical energy Electrical energy Indirect 47 %
Nuclear power plant Nuclear energy Electrical energy Indirect 36 %
Gas power plant Chemical energy Electrical energy Indirect 39 %
Combined cycle plant
Chemical energy Electrical energy Indirect 60 %
(gas/steam turbines)
Battery Chemical energy Electrical energy Direct 50 %
▪ In general, forms of energy with a high proportion of exergy, i.e. mechanical and electrical
energy, can also be converted into other forms of energy with a high degree of efficiency.
▪ A high degree of conversion efficiency is not synonymous with high economic efficiency, which
always depends on the degree of technological development, fuel cost and even the
consideration of external effects.
Electricity | Prof. Dr.-Ing. Joachim Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 9 Source: Zahoransky (2015)
Structure
Electricity | Prof. Dr.-Ing. Joachim Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 10
An Analogy Between Water and Electrical Circuit
Pump Converter/
(Pressure is Pressure “consumer“
increased) decreases (Turbine)
Converter/
Voltage source “consumer“
(Voltage is increased) Voltage drops (Electrical
resistance)
Electricity | Prof. Dr.-Ing. Joachim Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 11
What is Electricity?
Electricity | Prof. Dr.-Ing. Joachim Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 12 Sources: BET (2005), Mortimer & Müller (2014)
Key Terms
Electric charge Q in Coulomb [C]
▪ Basic property of the building blocks of matter, distinction between electron (-) and proton (+)
▪ A neutral atom becomes a positive/negaitve ion by addition/elimination of an electron
▪ Ions and electrons are carriers of electric charge
Electricity | Prof. Dr.-Ing. Joachim Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 13 Image source: Sengpiel (2015)
Overview of Properties and Units
Formula
Property Symbol Unit Unit abbreviation
(examples)
Charge Q Coulomb C
Time T Second s
Electricity | Prof. Dr.-Ing. Joachim Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 14
Fundamentals of Electric Flow
▪ Electricity requires the presence of electric charges (both positive and negative). Between positive
and negative charge carriers there is a force effect according to Coulomb's law.
▪ Identical charges repel each other, while opposite charges attract each other. Electrons and protons
serve as charge carriers. If there is a surplus of one of the charge carriers in an object, it is
considered negatively or positively "charged".
▪ The "technical current direction" is defined as the flow direction from positive to negative pole -
opposite to the "physical flow direction" of the charge carriers in metallic conductors from anode to
cathode.
+I - - - +I
- -
-
Electricity | Prof. Dr.-Ing. Joachim Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 15 Source: Kories (2013)
Electromagnetic Fields
Magnetic field
to the conductor.
▪ Since both fields occur together in moving charges, one
speaks of an electromagnetic field. Electromagnetic field
▪ If the direction of the movement of the charges in a
conductor changes back and forth, the direction of the
fields rotates accordingly.
▪ The convention for the direction of the field lines is
– For the magnetic field: "Right-Hand-Rule”
– For the electric field: from higher to lower potential
Radial field
lines
Concentric field
lines
Conductor
Electricity | Prof. Dr.-Ing. Joachim Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 16 Source: DL2KHP (2017)
Inverter and Rectifier
Inverter Rectifier
▪ Basically “chopping off” the direct current and ▪ Rectification of the AC voltage by a bridge
periodic change of polarity by an H-bridge circuit of diodes.
circuit.
▪ Subsequent smoothing of the pulsed direct
▪ Due to very high frequencies of the power current by filters.
electronics, any oscillation form can be
simulated very accurately (mostly sinusoidal
oscillation).
▪ Problem: Harmonic oscillations caused by fast
switching on and off, which have to be
reduced by filters.
Electricity | Prof. Dr.-Ing. Joachim Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 17 Sources: elektronik-kompendium (2018); SMA (2018)
Voltage Levels – Basic Principle of Electrical Power
Transmission
I
U P Electric consumer
Electricity | Prof. Dr.-Ing. Joachim Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 18
Stand-Alone and Interconnected Systems
System 1
~
~ ~
To system 2 To system n
Electricity | Prof. Dr.-Ing. Joachim Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 19 Source: BET(2005)
Technical Structure of a Power Supply System
Corresponds to:
Transmission grid
Extra high voltage grid High way
Neighbour
380/220 kV ~ grid
200…1.600 MW
Electricity | Prof. Dr.-Ing. Joachim Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 20 Source: Own representation according to BMWI (n. d.)
German Extra-High Voltage Grid (220 and 380 kV) and
the Control Areas of the Four TSOs
Electricity | Prof. Dr.-Ing. Joachim Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 21 Sources: Federal Government (2017); VDE(2018)
Grid Map of the Interconnected Network of Continental
Europe (2018)
Electricity | Prof. Dr.-Ing. Joachim Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 22 Source: ENTSO-E (2018a)
Value Chain of Electricity
Extraction of Grids,
primary Generation transmission & Trading Sale
energy distribution
▪ Power grid: Connection of (spatially separated) generators and consumers via lines
and cables
▪ Fundamental challenges in the network operation:
− Electricity must be generated at the same time as it is consumed
− Fluctuating demand and generation
− Ensuring security of supply and frequency stability
→ Natural monopoly, no competition possible
Electricity | Prof. Dr.-Ing. Joachim Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 23 Sources: Leuscher (2014); Schmidt (2014)
Structure
Electricity | Prof. Dr.-Ing. Joachim Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 24
Interactions Between Charges and Fields
Electricity | Prof. Dr.-Ing. Joachim Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 25 Sources and image sources: Geusschool (2011), Honina (2008)
Basic Principle of Power Generation
Electricity | Prof. Dr.-Ing. Joachim Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 26 Source and image source: EEE (n. d.)
Structure
Electricity | Prof. Dr.-Ing. Joachim Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 27
Fundamentals of Electrochemistry
▪ Electrochemistry describes:
– The relationship between electrical and chemical processes
– The processes at the boundary surface between an electron conductor (electrode) and an ion
conductor (electrolyte)
Electricity | Prof. Dr.-Ing. Joachim Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 28 Source: chemie.de (2016a), Siesler (2010)
Fuel Cell
▪ Fuel cells generate electricity and heat from hydrogen and oxygen ("cold combustion").
▪ A fuel cell consists of two electrodes, the anode (negative pole) and the cathode
(positive pole). They are separated by the electrolyte with a solid, ion-permeable
membrane. Each of the electrodes is coated with a catalyst, e.g. nickel or platinum.
▪ After hydrogen comes into contact with the anode, it splits into electrons and protons.
Electric Current
▪ The free electrons: Usable electric current on
the external circuit.
▪ The Protons: Reach cathode by passing through Oxygen
Electricity | Prof. Dr.-Ing. Joachim Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 29 Source: erdgas.info (2017); Image source: elektronik-kompendium (2008)
Different Types of Fuel Cells
▪ Depending on the electrolyte used, there are different types of fuel cells.
▪ The electrolyte can be either liquid, plastic or ceramic.
▪ The operating characteristics and efficiency of the fuel cells depend on the electrolyte.
Abbreviations: Molten Carbonate; Phosphoric Acid; Proton Exchange Membrane; Solid Oxide; Fuel Cell
Electricity | Prof. Dr.-Ing. Joachim Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 30 Source: Universität Leipzig (2013)
Energy Conversion in a Fuel Cell
▪ The conventional conversion of the chemical energy of a fuel into electricity is currently based on the
use of thermal engines.
▪ The fuel cell, which directly converts chemical energy stored in the fuel into electrical energy, is in
competition with the thermomechanical energy conversion which has been used up to now.
Heat engine
Fuel Cell
▪ 2nd Law of Thermodynamics: the efficiency of energy conversion is highest when it is done in a
reversible way. In the case of the combustion path, irreversibility is caused by the uncontrolled
exchange of electrons between the reaction partners during combustion. The electron exchange can
be carried out in a controlled way when the combustion chamber is replaced by an electrolysis cell.
▪ Disadvantage: hydrogen is not a primary energy carrier, so that an additional process step is
necessary: the production of hydrogen is required. Thus, the potential of hydrogen conversion has
so far been seen in the storage of energy. This disadvantage, together with the problem of hydrogen
storage and the high investment costs, has meant that fuel cells have not yet been able to establish
themselves on a larger scale compared to other electricity generators.
Electricity | Prof. Dr.-Ing. Joachim Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 31 Sources: erdgas.info (2017), Strauss (2016)
"the other way around" – Hydrogen Electrolysis
Storage of H2: LP HP
▪ Gaseous hydrogen in pressure vessels
▪ Liquid hydrogen in vacuum insulated containers
HP El
▪ Deposition of hydrogen in hybrid metals or carbon LP El
HP = high pressure
LP = low pressure
nanotubes
Development El = electrolysis
Existing electrolysis technologies: High pressure electrolysis:
▪ Alkaline electrolysis (AEL) ▪ System simplification: elimination of troublesome,
maintenance-intensive compressors and buffer tanks
▪ Polymer electrolyte membrane electrolysis (PEMEL) ▪ Higher system efficiency
Electricity | Prof. Dr.-Ing. Joachim Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 33 Source: Sterner & Stadler (2019)
References – Literature
▪ Baehr & Kabelac (2012): Baehr, H. D., und Kabelac, S.; „Thermodynamik: Grundlagen und technische Anwendungen ; mit zahlreichen
Tabellen sowie 74 Beispielen“. 16., neu bearb. und erw. Aufl. Springer-Lehrbuch. Berlin, 2016
▪ BET (2005): Technische Grundlagen der Stromversorgung – Physik, Historie und Kraftwerke. BNetzA-Schulung 1x1 der Energiewirtschaft.
Bonn 23. August 2005.
▪ chemie.de (2016a): Elektrochemie. http://www.chemie.de/lexikon/Elektrochemie.html
▪ chemie.de (2016b): Elektromotorische Kraft. http://www.chemie.de/lexikon/Elektromotorische_Kraft.html
▪ chemie.de (2016c): Elektrochemische Spannungsreihe. http://www.chemie.de/lexikon/Elektrochemische_Spannungsreihe.html
▪ chemgapedia.de (2017): Spannungsreihe.
http://www.chemgapedia.de/vsengine/media/vsc/de/ch/11/aac/vorlesung/kap_11/kap11_2/grafik/spannungsreihe.gif
▪ DL2KHP (2017): Elektromagnetische Wellen. http://www.dl2khp.de/elektromagnetische-wellen.html
▪ EEE (n. d.): EEE Interview Tips. 16 Common Interview Questions & Answers on Generators - Part-1.
https://eeeinterviewtips.blogspot.com/2011/07/question-answer-in-generator-part-1.html
▪ elektroauto-news.net (n. d.): Lithium-Ionen-Akku. http://www.elektroauto-news.net/wiki/elektroauto-batterien-akkus
▪ erdgas.info (2017): Funktionsprinzip Brennstoffzelle. https://www.erdgas.info/neue-heizung/heizungstechnik/brennstoffzelle/funktionsprinzip-
brennstoffzelle/
▪ EUROSTAT (2020): Electricity price statistics. https://ec.europa.eu/eurostat/statistics-explained/index.php?title=Electricity_price_statistics
▪ Exergy Economics (n. d.): What is Exergy? https://exergyeconomics.wordpress.com/exergy-economics-101/what-is-exergy/
▪ Geuschool (2011): Kraft auf den stromdurchflossenen Leiter. http://physik.geusschool.de/elek/os/mfeld/buch1/p2.htm
▪ Kowal (2017): Skript der Vorlesung „Grundlagen Batterietechnik“ an der TU Berlin.
▪ Kories (2013): Taschenbuch der Elektrotechnik: Grundlagen und Elektrotechnik. Verlag Harri Deutsch.
▪ Mortimer & Müller (2014): Chemie. Georg Thieme Verlag.
▪ Siesler (2010): Naturwissenschaftliche Grundlagen für Maschinenbauer und Wirtschaftsingenieure. https://www.uni-due.de/pc-
sa/lehre/Vorlesung_NWGIWI_131-140-s-w.pdf
▪ Strauss (2016): Kraftwerkstechnik zur Nutzung fossiler, nuklearer und regenerativer Energiequellen. 7. Auflage. Springer Verlag. Berlin.
▪ stromschnell (2016): https://www.stromschnell.de/technik/batterien-in-elektroautos-aktueller-stand-und-perspektiven_5123204_5093776.html
▪ Universität Leipzig (2013): Bruckner, T.: Vorlesung Energiemanagement „Power Plants“.
▪ Zahoransky (2015): Energietechnik – Systeme zur Energieumwandlung. 7., überarbeitete und erweiterte Auflage. Springer Verlag,
Wiesbaden 2015.
Electricity | Prof. Dr.-Ing. Joachim Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 34
References – Image Sources
Electricity | Prof. Dr.-Ing. Joachim Müller-Kirchenbauer | Sustainable Energy and Resources – Technologies and Systems
Page 35