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CONCRETE RHEOLOGY
IR. DR. RAHIZUWAN BIN HAMID, P.ENG
Concrete
Stone or
Gravel Water
Sand
Cement
3
PORTLAND CEMENT
Concrete Basics
Concrete Cement
Concrete Basics
Flour Cake
Cement is to concrete
… as flour is to cake!
USES OF PORTLAND CEMENT CONCRETE
• Buildings
• Bridges
• Pavements
• Concrete block buildings
OTHER USES OF CEMENTITIOUS MATERIALS
• Rotary Kiln
• Ransome (1886), Edison (1909)
• Lime (CaO)
- Limestone, shale
• Silica (SiO2)
-Clay, sand, shale
• Alumina (Al2O3)
- Clay, fly ash, shale
• Iron (Fe2O3)
- Clay, iron ore
PORTLAND CEMENT PRODUCTION
C = CaO H = H2 O
S = SiO2 S = SO3
A = Al2O3 F = Fe2O3
CLINKER: ARTIFICIAL MINERAL CONTAINING:
• Hydraulic
• Fineness
• 90% finer than 45m
• Setting Time
• Controlled
• False Set
• Flash Set
PORTLAND CEMENT PROPERTIES
• Soundness
• MgO or Hard-Burned Lime
• Specific Gravity: 3.15
• Heat of Hydration - Exothermic Reaction
• C3S & C3A
• LOI
• SO3
HOW ARE PORTLAND CEMENTS DIFFERENT?
FOUR MAIN COMPOUNDS
24
The oxides interact with each other in the rotary kiln to form a series of
complex compounds.
2CaO·SiO2+H2O
3CaO·2SiO2·3H2O+Ca(OH)2
Dicalcium silicate hydrates slowly and is
responsible for strength increase in concrete
at later ages. The heat of hydration is
liberated slowly.
More dicalcium silicate is formed when the
raw materials contain less lime.
Hydration Mechanism
4CaO·Al2O3·Fe2O3+H2O
3CaO·Al2O3·6H2O+CaO·Fe2O3·H2O
The addition of iron or iron ore to the raw materials
lowers the percentage of tricalcium aluminate. The iron
reacts with the tricalcium aluminate, forming the tetra
calcium aluminoferrite.
This compound does not add significantly to the
properties of concrete, but does cause the charge in the
cement kiln to liquefy at lower temperature (lowers the
point of fusion), thus reducing the energy required in
cement manufacture.
Development of Microstructure
Anhydrous cement
Water
Development of Microstructure
C-S-H
Ettringite
CH
Development of Microstructure
C-S-H
Ettringite
CH
Development of Microstructure
C-S-H
Ettringite
CH
Development of Microstructure
C-S-H
Ettringite
CH
Development of Microstructure
C-S-H
CH
Monosulfate
Hydration of Cement Compounds
100
C3A
80
60 C4AF
40 C2S
20
0
0 20 40 60 80 100
Time (days)
70 10,000
40 6,000
C2S
30
4,000
20
C3A+CSH2 2,000
10
C4AF+CSH2
0 0
0 20 40 60 80 100
Time (days)
Compressive Strength development in pastes of pure cement compounds
(Mindess et al, 2003)
37
•Cementitious
•Pozzolans
•Nominally Inert
CEMENTITIOUS MATERIALS
• Aggregate size:
• Grading of Aggregate:
• Surface texture of aggregate
• Shape of aggregate
• Cement type and source
• Pozzolans
• Air Entraining & Chemical Admixtures
• Setting Time
THE WATER - CEMENT RATIO LAW
Duff A. Abrams
May 1918
Same cement content
W/CM RATIO
55
WWater 350
W =
CM W
50
45
kg
300
CementitiousMaterial 40
Fc', MPa
kg
35 250
30 kg
25
20
15
10
0.2 0.3 0.4 0.5 0.6
5 5 5 5 5
w/cm ratio
WATER IN CONCRETE
• Increased water:
• reduced strength
• increased shrinkage and creep
• increases permeability
• reduced abrasion resistance
• reduced Freeze-Thaw resistance
INFLUENCE OF AGGREGATES
• STRENGTH
Aggregate shape
Aggregate size
Aggregate texture
INFLUENCE OF AGGREGATES
• DURABILITY
Weathering
Impurities
CONCRETE MATERIALS
• Congestion
• Shrinkage
• Mass Concrete
CONCRETE CONSTRUCTION
• Strength
• fc' (required 28 day compressive strength)
• fcr' (actual average 28-day strength of mixture)
• fc (compressive strength of concrete)
• fcr' is based on field records and laboratory results
• variations in materials
• variations in mixing times and methods
• variations in transportation time and methods
• variations in the preparation of test cylinders
STRENGTH (7 DAY)
• Workability: Ease with which a concrete can be handled and placed into forms.
• Slump
• Kelly Ball
• Penetration
• Flow Cone
QUALITY CONCRETE
• Consistency
• Workability
• Uniformity
• Finishability
• Low Bleeding
CONCRETE - WORKABILITY
• Setting Time
• Cement: different cements have different setting times
• alkalis, sugars, salts, organics
• Water: Impurities
• -sodium carbonate (Na+) rapid set
• -bicarbonate can accelerate or retard set
• Aggregate: None
CONCRETE - FRESH PROPERTIES
• Strength Gain
• Normal strength concrete 7-day fc is 60-70% of the 28-day for Type I
• 3-day fc is about 50% of the 7 day.
• Type III may have 3-day fc of 60-70% of the 28-day
• Moist cured concrete gains faster than air dried
• Steam curing is fastest, but......
CONCRETE STRENGTH
• Sulfate Resistance is the concrete’s susceptibility to chemical attack from external sulfate
ions.
• ground water or soil are SO4 sources
• concrete with low C3A cement and pozzolans, low permeability, or protecting it from
intrusion.
CONCRETE - DURABILITY
• Abrasion Resistance
• essential in floors, pavements and hydraulic structures.
• compressive strength is an important consideration,
• choice of aggregate. (limestone is not good, gravel is very good)
• steel trowelling and moist curing surface is best
ADMIXTURES
• DEFINITION:
Admixtures are any ingredients in concrete other than:
• Water
Aggregates
Cementitious Materials
Fiber Reinforcement
• Added to the batch
before or during mixing
WHY USE ADMIXTURES?
TO MODIFY FRESH CONCRETE PROPERTIES
• Dispersing Agents
• Water Reducers, Superplasticizers
• Accelerators
• Retarders
ASTM C 494 CHEMICAL ADMIXTURES
(AASHTO M 194)
• Type A - Water-reducing admixtures
• Type B - Retarding admixtures
• Type C - Accelerating admixtures
• Type D - Water-reducing and retarding
• Type E - Water-reducing and accelerating
• Type F - High range water reducing
• Type G - HRWR and retarding
WATER REDUCERS
• DEFINITION: Water Reducers are used for the
purpose of reducing the quantity of mixing water
required to produce a concrete of given consistency.
ACCELERATORS
• DEFINITION: Accelerating admixtures are added to
concrete for the purpose of shortening set time and
accelerating early strength development.
RETARDERS
• DEFINITION: Retarding, and Water-reducing and
retarding admixtures are used to offset acceleration
and unwanted effects of high temperature and keep
concrete workable during placement and
consolidation.
SHRINKAGE REDUCING
ADMIXTURES
• DEFINITION: Shrinkage Reducing Admixtures are used to
minimize drying shrinkage cracking in concrete .
CORROSION INHIBITORS
• Depends on:
• Type & Brand
• Amount of Cement
• Water Content
• Temperature
• Aggregate Shape
• Proportions
• Mixing Time
• Consistency of the
Mix
• Sequencing