CHEMIIT

ORGANIC CHEMISTRY
Q1] The major product of the following reaction is

Q2] The major product of the following reaction is

Q3] The major product in the following conversion is

Q4] The correct options for the products A and B of the following reactions are

Q5]
Consider the above reaction, the major product P is

Q6] The major product of the following reaction is

Q7] The major product “X” formed in the following reaction is

Q8] The major product of the following reaction is

Q9] The major product of the following reaction is

Q10] In the following reaction sequence the major products A and B are
Q11] In the following reaction A is

Q12] The major product of the following reaction is

Q13] The test performed on compound X and their inferences are :

Q14] The major product of the following reaction is

Q15] The major product of the following reaction is

Q16] Compound(s) which will liberate carbon dioxide with sodium bicarbonate solution
is/are

a] A and B b] C only c] B and C d] B only

Q17] An organic compound [A], molecular formula C10H20O2 was hydrolysed with dilute
sulphuric acid to give a carboxylic acid [B] and an alcohol [C]. oxidation of [C] with CrO 3 –
H2SO4 produced [B]. which of the following structures are not possible for [A]?
Q18] An organic compound [A], (molecular formula C6H12O2 was hydrolysed with dil. H2SO4
to give a carboxylic acid [B] and an alcohol [C]. “C” gives white turbidity immediately. when
treated with anhydrous ZnCl2 and conc. HCl. The organic compound (A) is

Q19] [P] on treatment with Br2/FeBr3 in CCl4 produced a single isomer C8H7O2 Br while
heating [P] with sodalime gave toluene. The compound [P] is

Q20] What is the product of following reaction ?

Q21] The major product obtained in the following reaction is

Q22] In the following compounds, the decreasing order of basic strength will be :-
A] C2H5NH2 > NH3 > (C2H5)2NH B] (C2H5)2NH > NH3 > C2H5NH2
C] (C2H5)2NH > C2H5NH2 >NH3 D] NH3 > C2H5NH2 > (C2H5)2NH
Q23] Which of the following amines can be prepared by Gabriel phthalimide reaction?
A] n-butylamine B] triethylamine C] t-butylamine D] neo-pentylamine
Q24] The major product formed in the reaction given below will be

Q25] The major product of the following reaction is

Q26] The major product of the following reaction is

Q27] The major product obtained in the following reaction is

Q28] coupling to benzene diazonium chloride with 1-naphthol in alkaline medium will give

Q29] Aniline dissolved in dil. HCl is reacted with sodium nitrate at 0 oC. This solution was
added dropwise to a solution containing equimolar mixture of aniline and phenol in dil. HCl.
The structure of the major product is
Q30] The major product Z obtained in the following reaction scheme is

Q31] Identify A in the given chemical reaction.

Q32] Mjaor product P of above reaction is

Q33] The major product obtained from E2 – elimination of 3-bromo-2-fluoropentane is

Q34] The major product [R] in the following sequence of reactions is

Q35] The major product (Y) in the following reaction is

Q36] Which one of the following compound(s) is/are aromatic in nature ?

Q37] Among the following, the aromatic compounds are

Choose the correct answer from the following options.

A] only (A) and (B) B] only (B) and (C) C] (B), (C) and (D) D] (A), (B) and (C)
Q38] The major product of the following reaction is
Q39] Which of the following compounds will form the precipitate with aq. AgNO 3 solution
most readily?

Q40] The increasing order of the boiling points of the major products A, B and C of the
following reactions will be

A] II < III < I B] III < I < II C] I < II < III D] I <III < II
Q41] The decreasing order of reactivity towards dehydrohalogenation (E1) reaction of the
following compounds is :

a] B > A > D > C b] B > D > A > C c] D > B > C > A d]B>D>C>A

Q42]
The given reaction can occur in the presence of
a] bromine water b] Br2 in CS2, 273 K c] Br2/FeBr3 d] Br2 in CHCl3, 273 K
Choose the correct answer from the options given below
a] B and D only b] A and C only c] B, C and D only d] A, B and D only
Q43] Match LIST – 1 With LIST – 2
Q44] The major product of the following reaction is

Q45]
Consider the above reaction, and choose the correct statement
a] The reaction is not possible in acidic medium.
b] Both compounds A and B are formed equally.
c] Compound A will be the major product.
d] compound B will be the major product.
Q46] Which one of the following phenols does not give colour when condensed with
phthalic anhydride in presence of conc. H2SO4 ?

Q47] What is ‘X’ in the given reaction ?

Q48] The major product of the following reaction is
𝐿𝑖𝐴𝑙𝐻4
CH3CH = CHCO2CH3 →
A] CH3CH = CHCH2OH B] CH3CH2CH2CH2OH
C] CH3CH2CH2CO2CH3 D] CH3CH2CH2CHO
Q49] Iodoform can be prepared from all except
a] ethyl methyl ketone b] isopropyl alcohol
c] 3-methyl-2-butanone d] isobutyl alcohol
Q50] In the following reaction sequence, structure of A and B, respectively will be

Q51] The correct order of heat of combustion for following alkadienes is

a] B < C < A b] A < B < C c] A < C < B d] C < B < A

Q52] Consider the following reactions,
A is
a] CH ≡ CH b] CH3C ≡ CCH3 c] CH3 – C ≡ CH d] CH2 = CH2
Q53] In the following sequence of reactions the P is

Q54] Identify A and B in the chemical reaction.

Q55] Among the following compounds, which one has the shortest C – Cl bond ?

Q56] Two compound s A and B with same molecular formula (C3H6O) undergo Grignard’s
reaction with methyl magnesium bromide to give product C and D. Products C and D show
following chemical tests.

Q57] The major products of the following reaction are

Q58] The structure of product C, formed by the following sequence of reactions is

Q59] Consider the above chemical reaction, identify the

product “X”
Q60] The increasing order of pKb for the following compounds will be :

a] B < C < A b] C < A < B c] A < B < C d] B < A < C

ANSWERKEY
1] D 2] A 3] D 4] B 5] C 6] C 7] B
8] C 9] B 10] D 11] C 12] D 13] B 14] A
15] D 16] C 17] A,C 18] B 19] B 20] D 21] B
22] C 23] A 24] 25] C 26] C 27] D 28] C
29] A 30] C 31] B 32] D 33] B 34] C 35] A
36] A,D 37] B 38] B 39] B 40] A 41] C 42] C
43] C 44] D 45] C 46] B 47] C 48] A 49] D
50] D 51] B 52] C 53] A 54] B 55] B 56] A
57] D 58] A 59] C 60] D