Diesel exhaust fluid

Diesel exhaust fluid (DEF; also known as AUS 32 and marketed

as AdBlue[3]) is a liquid used to reduce the amount of air pollution
created by a diesel engine. Specifically, DEF is an aqueous urea
solution made with 32.5% urea and 67.5% deionized water. DEF is
consumed in a selective catalytic reduction (SCR) that lowers the
concentration of nitrogen oxides (NOx) in the diesel exhaust
emissions from a diesel engine.[4]

Other names
A 1.5-liter and a 10-liter AdBlue
In the international standard defining DEF (ISO 22241), it is container
referred to as AUS 32 (aqueous urea solution 32%).[5] DEF is also
sold as AdBlue, a registered trademark of the German Association
of the Automotive Industry.

Several brands of SCR systems use DEF: BlueHDI is used by PSA

Group vehicles including Peugeot, Citroën, and DS Automobiles
brands; BlueTec by Daimler AG; and FLENDS (Final Low
Emission New Diesel System) by UD Trucks.

Background Hino truck and its SCR next to the

Diesel engines are typically operated with a lean burn air-to-fuel diesel particulate filter (DPF) with
ratio (over-stoichiometric ratio) to ensure the full combustion of soot regeneration process by the late fuel
and to prevent them from exhausting unburnt fuel. The excess air injection to control exhaust
temperature to burn off soot[1][2]
leads to the generation of NOx, which are harmful pollutants, from
nitrogen in the atmosphere. SCR is used to reduce the amount of
NOx released into the atmosphere. DEF from a separate tank is
injected into the exhaust pipeline, and the exhaust heat decomposes
it to ammonia. Within the SCR catalyst, the NOx are reduced by the
ammonia into water and nitrogen, which are both nonpolluting. The
water and nitrogen are then released into the atmosphere through
the exhaust.[6]
Passenger car using an AdBlue
SCR was applied to automobiles by Nissan Diesel Corporation, and pump
the first practical product "Nissan Diesel Quon" was introduced in
2004. With the cooperation of the oil and chemical industry, a
1,300-station infrastructure to supply DEF was prepared by September 2005 in Japan.[7]

In 2007, the United States Environmental Protection Agency (EPA) enacted requirements to significantly
reduce harmful exhaust emissions. To achieve this standard, Cummins and other diesel engine
manufacturers developed an aftertreatment system that includes the use of a diesel particulate filter (DPF).
As the DPF does not function with low-sulfur diesel fuel, diesel engines that conform to 2007 EPA
emissions standards require ultra-low-sulfur diesel (ULSD) fuel to prevent damage to the DPF. After a brief
transition period, ULSD fuel became common at fuel pumps in the United States and Canada.

The 2007 EPA regulations were meant to be an interim solution to allow manufacturers time to prepare for
the more stringent 2010 EPA regulations, which reduced NOx levels even further.[8] In 2008, the concerns
about compliance shifted to the infrastructure for DEF distribution.[9]

The injection rate of DEF into the exhaust depends on the specific after-treatment system, but is typically 2–
6% of diesel consumption volume. This low dosing rate ensures long fluid refill intervals and minimizes the
tank's size and intrusion into vehicle packaging space. An electronic control unit adjusts the addition of fluid
in accordance with parameters such as NOx level in the exhaust gas (before catalytic converter, after
catalytic converter, and possibly between catalytic converters if there is more than one), current ammonia
filling level,[10] engine operating temperature and speed.

Chemistry
DEF is a 32.5% solution of urea, (NH2 )2 CO. When it is injected into the hot exhaust gas stream, the water
evaporates and the urea thermally decomposes[11] to form ammonia (NH3 ) and isocyanic acid (HNCO):

(NH2)2CO → NH3 + HNCO

The isocyanic acid reacts with the water vapor and hydrolyses to carbon dioxide and ammonia:

HNCO + H2O → CO2 + NH3

Overall, thus far:

(NH2)2CO + H2O → 2 NH3 + CO2

Ammonia, in the presence of oxygen and a catalyst, reduces two different nitrogen oxides:[12]

4 NO + 4 NH3 + O2 → 4 N2 + 6 H2O ("standard SCR") and

6 NO2 + 8 NH3 → 7 N2 + 12 H2O ("NO2 SCR selective catalytic reduction")
NO + NO2 + 2 NH3 → 2 N2 + 3 H2O ("fast SCR")

The overall reduction of NOx by urea is then:

2 (NH2)2CO + 4 NO + O2 → 4 N2 + 4 H2O + 2 CO2 and

4 (NH2)2CO + 6 NO2 → 7 N2 + 8 H2O + 4 CO2 and
(NH2)2CO + NO + NO2 → 2 N2 + 2 H2O + CO2

The ratio between NO2 and NO determines which reactions take place and how fast. The highest
conversion rates are achieved if equal amounts of NO2 and NO are present, especially at temperatures
between 200°C and 350°C. If there is more NO than NO2 , fast SCR and standard SCR take place
sequentially. If there is more NO2 than NO, fast SCR and NO2 SCR take place sequentially, however, NO2
SCR is slower than standard SCR, and ammonium nitrate can form and temporarily deactivate the catalytic
converter.[13]

Operation in winter time

DEF freezes at −11 °C (12 °F).[14][15][16] For the SCR exhaust cleaning system to function at low
temperatures, a sufficient amount of the frozen DEF must be melted in as short time as possible, preferably
on the order of minutes. For example, 2010 EPA emissions requirements require full DEF coolant flow
within 70 minutes.[17][18]

In Europe, Regulation (EC) No 692/2008[19] specified in Annex XVI point 10 that DEF from a frozen tank
at a core temperature of −15 °C (5 °F) must become available within 20 minutes when starting the engine at
−15 °C (5 °F).

Typically, the frozen DEF is melted by heat from the engine, e.g. engine coolant passing through the DEF
tank, governed by a thermostatic coolant control valve. This method may take significant time before the
SCR exhaust cleaning system is fully operational, often up to an hour.[4]

Another method to thaw DEF (and thus allow for full SCR operation) is to integrate an electric heater into
the DEF tank. This heater must be sized, positioned, and powered adequately to rapidly melt sufficient
frozen DEF. It should preferably be self regulating not to overheat if (part of) the heater is outside of the
liquid. It should also preferably be self regulating to eliminate any complicated sensor and temperature
regulating systems. Furthermore, the heater should not exceed 50–60 °C (122–140 °F), as DEF begins to
decompose at around 60 °C (140 °F). PTC heaters are often used to achieve this.

Safety and storage

The urea solution is clear, non-toxic and safe to handle.[20] Since urea has corrosive impact on metals like
aluminium, DEF is stored and transported in special containers.[21][22] These containers are typically made
of stainless steel.[22] Vehicles' selective catalytic reduction (SCR) systems and DEF dispensers are designed
in a manner that there is no corrosive impact of urea on them.[21] It is recommended that DEF be stored in a
cool, dry, and well-ventilated area that is out of direct sunlight. Bulk volumes of DEF are compatible for
storage within polyethylene containers (HDPE, XLPE), fiberglass reinforced plastic (FRP), and steel tanks.
DEF is also often handled in intermediate bulk containers for storage and shipping.

DEF is offered to consumers in a variety of quantities ranging from containers for single or repeated small
usage, up to bulk carriers for consumers requiring a large amount of DEF. As of 2013, many truck stops
have added DEF pumps. These are usually adjacent to fuel pumps so the driver can fill both tanks without
moving the truck.

In Europe, increasing numbers of fuel stations offer AdBlue pumps, not only for large commercial vehicles
but also for passenger cars.
At airports, where DEF can sometimes be required for diesel ground service vehicles, its labelling and
storage must be carefully managed to avoid accidentally servicing jet aircraft with DEF instead of fuel
system icing inhibitor, a mistake that has been blamed for multiple in-flight engine failure and grounding
incidents. [23][24][25]

Supply shortage

South Korea
As of December 2021, a shortage of DEF in South Korea was continuing and brought havoc to its
economy. As most of the urea used is supplied by China, imports have slowed since China introduced
mandatory inspections of urea exports in September. [26] Nearly 97% of South Korea's urea imports came
from China between January and September. In 2015, South Korea had made it mandatory for diesel cars to
use urea solutions to control emissions, a move that now impacts 40% of registered vehicles. Diesel vehicles
made since 2015 were required to be fitted with SCR systems.[27] The South Korean government started
rationing urea solution, and banned its resale as panic buying by drivers exacerbated an acute shortage that
could cause transport and industry to grind to a halt.[28] A KC-330 Cygnus was sent to import Diesel
exhaust fluid from Australia to ease a supply shortage of the key material used in diesel vehicles.[29]

Australia
In early December 2021, the Australian National Road Transport Association also raised concerns about a
shortage of DEF in the country due to the shortage of urea in China.[30] China capped exports to protect its
domestic supplies and rising DEF prices. By mid-December there was approximately 7 weeks’ supply of
AdBlue left in Australia.[31] On 14 December, an Australian company stated that it would build a new
plant.[32]

References
1. "Hino Standardized SCR Unit" (https://archive.today/20140805130141/http://www.hinoscr.co
m/scrtechnology/story_6.php?PHPSESSID=da323bebe58c10762bbb47df09a4bd91). Hino
Motors. Archived from the original (http://www.hinoscr.com/scrtechnology/story_6.php?PHPS
ESSID=da323bebe58c10762bbb47df09a4bd91) on 5 August 2014. Retrieved 30 July 2014.
2. "The DPR Future" (http://www.hino.com/download/86/file/Hino_DPR.pdf) (PDF). Hino
Motors. Retrieved 30 July 2014.
3. "What is the function of AdBlue?" (https://eurol.com/en/what-is-the-function-of-adblue/). Eurol
lubricants. 18 May 2020. Retrieved 16 November 2021.
4. "What is DEF?" (https://web.archive.org/web/20210323193733if_/http://www.cumminsfiltratio
n.com/pdfs/product_lit/americas_brochures/MB10033.pdf) (PDF). Cummins Filtration.
Archived from the original (http://www.cumminsfiltration.com/pdfs/product_lit/americas_broch
ures/MB10033.pdf) (PDF) on 23 March 2021.
5. "ISO 22241-4:2019 Diesel engines — NOx reduction agent AUS 32" (https://www.iso.org/sta
ndard/66411.html). ISO (International Organization for Standardization). 1 July 2019.
6. "How it works" (https://web.archive.org/web/20171121125421/http://h2blu.ca/about-def/how-i
t-works/). H2Blu. Archived from the original (http://h2blu.ca/about-def/how-it-works) on 21
November 2017. Retrieved 9 July 2012.
 尿素
7. " CSRシステム（ ）
FLENDS " (https://www.jsae.or.jp/autotech/11-3.php) [CSR System
"FLENDS"]. Society of Automotive Engineers of Japan (in Japanese). Retrieved
28 November 2021.
8. Mark Quasius (1 May 2013). "2010 EPA Emissions Standards And Diesel Exhaust Fluid" (htt
ps://familyrvingmag.com/2013/05/01/2010-epa-emissions-standards-and-diesel-exhaust-flui
d/). FamilyRVing. Retrieved 3 December 2021.
9. Brian Straight (28 May 2008). "DEF infrastructure in good shape" (https://www.fleetowner.co
m/emissions-efficiency/article/21669331/def-infrastructure-in-good-shape). Fleet Owner.
Retrieved 3 December 2021.
10. "Exhaust-gas treatment with double-injection technology" (https://www.bosch-mobility-solutio
ns.com/en/solutions/exhaust-gas-treatment/exhaust-gas-treatment-with-double-injection-tech
nology/). Bosch. Retrieved 8 May 2022.
11. Kuternowski, Filip; Staszak, Maciej; Staszak, Katarzyna (July 2020). "Modeling of Urea
Decomposition in Selective Catalytic Reduction (SCR) for Systems of Diesel Exhaust Gases
Aftertreatment by Finite Volume Method" (https://doi.org/10.3390%2Fcatal10070749).
Catalysts. 10 (7): 749. doi:10.3390/catal10070749 (https://doi.org/10.3390%2Fcatal1007074
9).
12. EP 2551009 (https://worldwide.espacenet.com/textdoc?DB=EPODOC&IDX=EP2551009),
Harris, Thomas M.; Ayyappan, Ponnaiyan & Dou, Danan, "Diesel exhaust fluid formulation
having a high ammonium content and a low freezing point", published 2013-01-30, assigned
to Deere & Co.
13. Koebel, Manfred; Madia, Giuseppe; Elsener, Martin (2002). "Selective catalytic reduction of
NO and NO2 at low temperatures". Catalysis Today. 73 (3–4): 239–247. doi:10.1016/S0920-
5861(02)00006-8 (https://doi.org/10.1016%2FS0920-5861%2802%2900006-8).
14. "Does AdBlue freeze" (https://carsneedcare.com/does-adblue-freeze/). carsneedcare. May
2023.
15. "AdBlue What diesel vehicle owners need to know" (https://www.rix.co.uk/blog/2018/12/adbl
ue-what-diesel-vehicle-owners-need-to-know/). www.rix.co.uk. Retrieved 20 November
2019.
16. Panayi, Adam (2017). "Frequently Asked Questions" (http://www.discoverdef.com/def-overvi
ew/faq/). discoverdef.com. Retrieved 29 December 2017.
17. "DEF Equipment Delivery & Storage" (https://www.cummins.com/engines/def-equipment-del
ivery-and-storage). Cummins Inc. 2017. Retrieved 29 December 2017.
18. "The 5 Facts and Fiction of Diesel Exhaust Fluid" (https://web.archive.org/web/20171229171
846/http://govictoryblue.com/the-5-facts-and-fiction-of-diesel-exhaust-fluid/). Victory Blue -
Diesel Exhaust Fluid. 2016. Archived from the original (http://govictoryblue.com/the-5-facts-a
nd-fiction-of-diesel-exhaust-fluid/) on 29 December 2017. Retrieved 29 December 2017.
19. Regulation (EU) No 692/2008 of 18 July 2008 implementing and amending Regulation (EC)
No 715/2007 of the European Parliament and of the Council on type-approval of motor
vehicles with respect to emissions from light passenger and commercial vehicles (Euro 5
and Euro 6) and on access to vehicle repair and maintenance information (https://eur-lex.eur
opa.eu/legal-content/EN/TXT/?uri=CELEX:32008R0692)
20. "3. Hazard Identification" (https://adbtrasemisa.com/wp-content/uploads/2015/09/MSDS_Ad
Blue_english.pdf) (PDF). Urea Solution 32,5% Material Safety Sheet. Fertiberia. 21 August
2008. p. 2. "3.1– For Human Health … The product has a low toxicity and it is not considered
that it could be harmful to health. … 3.1.5. – Long-term effects: … Urea is a substance that
appears in the body as a result of proteins during metabolism, it is eliminated with the urine."
21. "Urea tanks on diesel trucks -- that's the law in the United States starting in 2010" (https://ww
w.eurekalert.org/pub_releases/2008-11/i-uto111008.php). EurekAlert operated by AAAS. 10
November 2008. Retrieved 22 July 2020.
22. "Urea – Krampitz storage tanks" (https://web.archive.org/web/20200723125808/https://www.
krampitz.de/en/urea-krampitz-storage-tanks/). 5 October 2016. Archived from the original (htt
ps://krampitz.de/en/urea-krampitz-storage-tanks/) on 23 July 2020. Retrieved 22 July 2020.
23. Epstein, Curt (24 August 2018). "Close Call for Falcon with DEF-contaminated Fuel" (https://
www.ainonline.com/aviation-news/business-aviation/2018-08-24/close-call-falcon-def-conta
minated-fuel). AIN Online. Retrieved 8 July 2021.
24. Thurber, Matt (27 May 2019). "DEF Contamination Downs Two Citations" (https://www.ainonl
ine.com/aviation-news/business-aviation/2019-05-27/def-contamination-downs-two-citation
s). AIN Online. Retrieved 8 July 2021.
25. "NBAA Encourages More DEF Training to Avoid Fuel Contamination" (https://nbaa.org/aircra
ft-operations/safety/hangar-ground-safety/fuel-contamination/nbaa-encourages-more-def-trai
ning-to-avoid-fuel-contamination/). National Business Aviation Association. 17 August 2020.
Retrieved 8 July 2021.
26. Kyung-min, Lee (9 November 2021). "No immediate end in sight for diesel exhaust fluid
shortage in Korea" (https://www.koreatimes.co.kr/www/nation/2021/11/281_318484.html).
The Korea Times. ISSN 0712-1733 (https://www.worldcat.org/issn/0712-1733). Archived (htt
ps://web.archive.org/web/20211109075843/https://www.koreatimes.co.kr/www/nation/2021/1
1/281_318484.html) from the original on 9 November 2021. Retrieved 6 January 2022.
27. Cha, Sangmi; Yang, Heekyong (9 October 2021). "Urea shortage threatens South Korea's
transport, energy industries" (https://www.reuters.com/business/energy/urea-shortage-threate
ns-south-koreas-transport-energy-industries-2021-11-09/). Reuters. Retrieved 6 December
2021.
28. Yang, Heekyong (11 October 2021). "S.Korea rations urea amid shortage, drivers panic buy"
(https://www.reuters.com/world/asia-pacific/skorea-rations-urea-supply-amid-shortage-leadin
g-drivers-panic-buy-2021-11-11/). Reuters. Retrieved 17 November 2021.
29. "Sales of DEF restricted in amounts, vendors" (https://koreajoongangdaily.joins.com/2021/1
1/11/business/economy/Urea-Urea-solutoin-DEF/20211111173002614.html). Korea
JoongAng Daily. 11 November 2021. Retrieved 17 October 2023.
30. Sparkes, David (3 December 2021). "Diesel crisis threatens to grind Australia to a halt,
transport industry warns" (https://www.abc.net.au/news/2021-12-03/diesel-crisis-adblue-shor
tage-supply-china/100673482). ABC News. Archived (https://web.archive.org/web/20220103
195729/https://www.abc.net.au/news/2021-12-03/diesel-crisis-adblue-shortage-supply-chin
a/100673482) from the original on 3 January 2022. Retrieved 6 January 2022.
31. Belot, Henry (13 December 2021). "Australia to get more of crucial trucking chemical after
China cracks down on world market" (https://www.abc.net.au/news/2021-12-13/australia-app
roaches-nations-for-adblue-supplies/100695094). ABC News. Australian Broadcasting
Corporation. Retrieved 13 December 2021.
32. Macdonald-Smith, Angela; Evans, Simon (14 December 2021). "AdBlue crisis fires up $2.6b
South Australian urea venture" (https://www.afr.com/companies/energy/adblue-crisis-fires-up
-2-6b-sa-urea-venture-20211214-p59hg9). The Australian Financial Review. Retrieved
15 December 2021.

External links
ISO 22241-1:2019 Diesel engines — NOx reduction agent AUS 32 — Part 1: Quality
requirements (https://www.iso.org/standard/66408.html)
Adblue consumption by vehicle type (https://www.carblue.co.uk/vehicle-guide/)

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