Professional Documents
Culture Documents
JEE Advanced - Paper 2 - (07!03!2024) - Facilty
JEE Advanced - Paper 2 - (07!03!2024) - Facilty
Single Correct
(Section-I)
1. A cosmic body A moves towards star with velocity v (when far from the star) and aiming parameter L and arm of velocity
0
vector v relative to the centre of the star as shown in figure. Find the minimum distance (take 10 m as unit) by which this
0
8
[M = 10 kg,
20
]
, ,
(A) 2 unit (B) 3 unit (C) 4 unit (D) 5 unit
Ans. (B)
Sol.
2. Two billiard balls of the same size and mass are in contact on a billiard table. A third ball of same size and mass strikes
them symmetrically and remains at rest after the impact. The coefficient of restitution between the balls is:
Ans. (C)
vsep v
Sol. e
vopp vcos
m v 2m vcos
1
sin
2
1
3. 540 g of ice at 0 °C is mixed with 540 g of water at 80°C. The final temperature of the mixture is
(A) 0°C (B) 53°C (C) 80°C (D) less than 0°C
Ans. (A)
Sol. 540 x 80 = 540 x 80 x 1
T = 0°
4. A reel rolls without slipping on the horizontal surface as shown in figure. If point A on the string has a velocity V to the
A
Ans. (A)
Sol. w r Vcom VA
Vcom w R
VA
w
r R
2
One or More than One Correct
(Section-II)
5. A bimetallic strip is formed out of two identical strips one of copper and the other of brass. The coefficients of linear
expansion of the two metals are On heating, the temperature of the strip goes up by and the strip bends
to form an arc of radius of curvature R. Then R is
(A) Proportional to (B) inversely proportional to
k 2k
B
2T T1
Sol. I2
2R
T T
I1 1
R
T2 T1
I1 I2
2R
3
from above T2 TB 1.4 T
2T T
I2 1
T1 T2R
D 1.
6T
T1 T
I1 1KTS
I1 I2R
T2 T1 5
I1 I2
2R
7. fromrise
The above TB in
of aT2liquid 1.4aTcapillary tube depends on
1 T T 1.6 T
D
(A) the material (B) the length
1KTS
I1 I2
(C) the outer radius5 (D) the inner radius of the tube
Ans. (A, B, C)
8. P-V diagram of a cyclic process ABCA is as shown in figure. Choose the correct statement (s):
Ans. (A, B, D)
Sol. W AC O
W BC V2 V1 P1
1
W AB P1 V2 V1 P2 P1 V2 V1
2
1
W ABC P2 P1 V2 V1 ve
2
P2V2 P1V1
T2 T1
For process A B, P = KV
PV = nRT
kV2 = nRT
4
2kVdv. = nRdT,
dU = dQ – dW
nCVdT = dQ – pdv
dQ = nCVdT + pdv
2kVdV
dQ = C V kVdV
R
2C V
V1
Q AB
R
V2
1 kVdV
w hich is ve
For process C A
dv = nCVdT
VdP
nC V
nR
P2
C
U V V dP ,w hich is positive
P1 R ve
For process B C
dQ nC V dT pdV
pdV
nC V PdV
nR
C
Q B C V 1 PdV
R
ve
Ans. (A, B, D)
Sol. (A) Velocity = length/time
(B) momentum = mass x velocity
(C) Force depends upon mass, length time
Change in m om entum
(D) Force =
Change in tim e
10. In figure P1 and P2 are the pressures in broad and narrow tubes as shown. Select the correct option/s.
5
11. An ideal gas is taken through the cyclic process shown in P – V diagram.
P0 V0
(A) In this cyclic process, work done by the Ideal gas is
2
P0 V0
(B) Heat released by the gas is
2
P0 V0
(C) Heat absorbed by the gas is
2
(D) Change in internal energy of the gas in process CA is zero
Ans. (B, D)
Sol. Area of PV graph
1 PV
2Po Po 2Vo Vo o o
2 2
W BC W CA ,W AB O
W BC is ve & W CA is ve
w ork done by gas Po Vo /2
U Q W U O , for cyclic process
Q W Po Vo /2 heat is released
12. Two spherical black- bodies A and B of radii rA and rB, (where rB = 2rA ) emit radiations with peak intensities at
wavelengths 400 nm and 800 nm respectively. If their temperature are TA and TB in Kelvin scale, their emissive powers
are EA and EB and power emitted are PA and PB respectively, then
TA PA EA EA
(A) 2 (B) 4 (C) 8 (D) 4
TB PB EB EB
Ans. (A, B)
TA 8
Sol. PA ATA4 ,
TB 4
PA 4ATB4
PA T
4 , A 2
PB TB
6
Numerical Value
(Section-III)
13. Two wires A and B are of same materials. Their lengths are in the ratio 1 : 2 and diameters are in the ratio 2 : 1 when
stretched by force FA and FB respectively they get equal increase in their lengths. Then the ratio FA/FB will be 8 : m. Find
‘m’
Ans. (1)
AY A /4 Y
Sol. FA ;FB
2
FA :FB 8 :1
1
14. A smooth chain PQ of mass M rests against a th circular and smooth surface of radius r. If released, its velocity to
4
ngr
comeover the horizontal part of the surface is 2gr . Find the value of n
Ans. (4)
2
M 1
2r/4 Rd R 1 cos g 2 m v
2
Sol.
0
4gr
v 2gr
15. A siren placed at a railway station is emitting sound of frequency 5 kHz. A passenger sitting in a moving train A records a
frequency 5.5 kHz while the train approaches the siren. During his return journey in a different train B he records a
11
frequency of 6 kHz while approaching the same siren. The ratio of velocity of train A to train B is . Find k.
k
Ans. (22)
C VA 5.5 V
Sol. 5.5 f 1 A
C f C
C VB
6 f
C
6 VB
1
f C
VA 5.5 f 5.5 5 0.5 1 11
VB 6f 65 1 2 11
16. A thermally insulated vessel contains some water at 0oC. The vessel is connected to a vacuum pump to pump out water
vapour. This results in some water getting frozen. It is given Latent heat of vaporization of water at 0°C =21 × 10 5 J/kg and
latent heat of freezing of water = 3.36 × 105 J/kg. The maximum percentage amount of water that will be solidified in this
manner will be
(A) 86.2 % (B) 33.6 % (C) 21 % (D) 24.36 %
7
Ans. (A)
Sol. Let m will be mass of water evaporated, x is frozen water
m L v xLf
x 21 105 6.25
m 3.36 10 5
100
x 1
Ratio 86.2%
xm 1
M
x
17. The cylinder initially contains a volume V of ideal fluid of density . The small orifice at the end of the cylinder has cross-
sectional area A. If you exert a constant force on the plunger. Then work must you do to empty the cylinder in time t is
V x
W . Find x + y + z.
2A y t z
Ans. (7)
v
Sol. volum e flow rate
t
2
1 v
K.E. m
2 At
1 vv2
K.E.
2 A 2t2
x 3,y 2,z 2
18. A transverse wave on a string has an amplitude of 0.2 m and a frequency of 175 Hz. Consider a particle of the string at
x 0 . It begins with a displacement y 0, at t 0, according to equation y A sin Kx t . How much time passes
between the first two instants when this particle has a displacement of y 0.1m ?
(A) 1.9 ms (B) 3.8 ms (C) 2.4 ms (D) 0.5 ms
Ans. (C)
Sol. y A sin kx w t ,for x 0
y A sin w t
y A sin w t A 0.2
0.1 0.2 sinw tor 0.1 0.2 sinw t
1 1
sinw t or sinw t
2 2
5
wt or w t ,2
6 6 6 6
5
2
t 6 6 , t 6 6
w w
2 1 3 2 1
t t
3 w w 3 w
8
2 2
/ 2 175 ,t /2 175
3 3
t 1.9m /s
9
Chemistry
Single Correct
(Section-I)
20. The mole fraction of a solute in a solution is 0.1 . At 298 K , molarity of this solution is the same as its molality. Density
3 M W solute
of this solution at 298 K is 2.0 g cm . The ratio of the molecular weights of the solute and solvent, , is
M W solvent
(A) 1:9 (B) 9:1 (C) 6:1 (D) 0.9:1
Ans. (B)
0.1 1000
Sol. Molality m
0.9 M W solvent
0.1 2 1000
Molarity M
0.9 M W solvent 0.1 M W solute
Equating (i) & (ii)
0.1 1000 0.1 2 1000
0.9 M W solvent 0.9 M W solvent 0.1 M W solute
M W solute
So, 9 :1
M W solvent
˙ ˙
(C) H C C H 2C CH CH 3 CH 2 (D)
Ans. (B)
Sol. Due to percentage S-character (electronegativity) anion of sp hybridized carbon is most stable.
Due to lower bond energy of allylic H as compared to benzylic H , allyl radical is more stable than benzyl radical.
Ans. (C)
Sol. The second ionization energy implies the removal of electron from O ,F ,N and C species. Their configurations are
O :(1 s)2 (2 s)2 (2p)3 F : (1 s)2 (2 s)2 (2p)4
N :(1 s)2 (2 s)2 (2p)2 C : (1 s)2 (2 s)2 (2p)1
10
The species O will have maximum value due to the stable half-filled electronic configuration. The species C will have
minimum value as the removal of electron leads to the inert-gas configuration.
11
One or More than One Correct
(Section-II)
23. 0.5 g of fuming H 2SO 4 oleum is diluted with water. This solution is completely neutralised by 26.7m l of
0.4 N N aO H . The correct statement is/are
(A) Mass of SO 3 is 0.104 g
(B) % of free SO 3 20.7
(C) Normality of H 2SO 4 for neutralization is 0.2 N
(D) Weight of H 2SO 4 is 0.104 g
Ans. (A, B)
Ans. (A, C)
Sol.
12
Achiral 4
24 2
x y 2 4 6
Hence, (a) and (c) are correct.
Ans. (A, D)
Sol. According to van der Waal's equation (for one mole of gas)
a
P 2 V b RT
V
a
The pressure exerted by gas molecules on each other.
V2
27. Which of the following statements is/are correct regarding catalytic hydrogenation?
(A) It is an exothermic reaction
(B) It is syn addition
(C) Reactive intermediate is carbocation
(D) Reactive intermediate is free radical
Ans. (A, B)
Ans. (C)
14
Numerical Value
(Section-III)
Ans. (0)
32. The compressibility factor for nitrogen at 223 K and 800 atm is 1.95 and at 373 K and 200 atm, is 1.10 . A certain
mass of nitrogen occupies a volume of 1.0dm 3 at 223 K and 800 atm . Calculate the volume occupied by the same
quantity of nitrogen at 373 K and 200 atm .
Ans. (3.77)
V1 Z1T1 P2
Sol.
V2 Z2T2 P1
1 1.95 223 200
V2 1.10 373 800
V2 3.77 litres
33. How many optically active stereoisomers are possible for butane-2, 3-diol?
Ans. (2)
Sol. There are three stereoisomers out of which only two are optically active.
K Violet/Lilac
Na Yellow
Be Crimson red
Ca Brick red
Sr Apple green
Mg No colour
Rb Red violet
Cs Blue
Li Crimson red
Ans. (7)
15
35. According to Bohr theory, the electronic energy of a hydrogen atom in the nth Bohr atom is given by
19
21.76 10
En J . Calculate the longest wavelength of light that will be needed to remove an electron from the
n2
third Bohr orbit of the H e ion (If the wavelength is x 107 (in meter) and x is an integer. Report ' x ')
(take h 6.625 1034 Jsec)
Ans. (2.05)
36. Find out the number of compounds which are more acidic than benzoic acid among the following.
Ans. (4)
Sol. Acidic strength can be attributed to the stability of the conjugate base. Electron donating species destabilise the
conjugate base, whereas electron withdrawing group stabilises it.
16
Formic acid and oxalic acid are stronger acids than benzoic acid. Thus, a total of 4 acids are stronger than benzoic acid
among the given compounds.
The compounds are
17
Math
Single Correct
(Section-I)
37. If xn cos n isin n then x1x2x3 is equal to -
2 2
(A) -1 (B) 1 (C) 0 (D)
Ans. (A)
x
1n
Sol. xn cos n isin n 1 e 2
2 2
x1x2x3
1 1
1 1 2 n
e2 e2 e 2 e 2 2
1 2 n
2
cos 2 3 .. isin 2 3 .. 1
2 2 2 2 2 2
/2
as 2 3
2 2 2 1 1/2
38.
If two events A and B are such that P A 0.3,P B 0.4 and P AB 0.5 then P B ∣ A B equals –
1 1 1 1
(A) (B) (C) (D)
2 3 4 5
Ans. (C)
P B A B
Sol.
we have P B ∣ A B P A B
P B A B B
P A P B P A B
P AB P A P AB
P A P B P AB P A P B P AB
0.7 0.5 0.2 1
0.7 0.6 0.5 0.8 4
etanx ex
39. Evaluate: lim
x0 tanx x
(A) 1 (B) 2 (C) 3 (D) 4
Ans. (1)
etanx ex exxe tanx x ex
Sol. lim lim
x0 tanx x x0 tanx x
ex etanxx 1
lim
x0 tanx x
ex ey 1 ey 1
lim w here y tanx x and lim 1
x0y0 y y 0 y
e0 1 [as x 0,tanx x 0 ]
1 1 1
18
x2 y2
40. If asec,btan and asec,btan are the ends of a focal chord of 2
2 1, then tan tan equal to –
a b 2 2
2e 1 1 2e 1 e e1
(A) (B) (C) (D)
2e 1 1 2e 1 e e1
Ans. (C)
Sol. Equation of chord connecting the points asec,btan and asec,btan is
x y
cos sin cos
a 2 b 2 2
If it passes through (ae, 0 ); we have, ecos cos
2 2
cos 1 tan tan
e 2
2 2
1 tan tan
cos
2 2 2
1 e
tan tan
2 2 1 e
1 e
Similarly if (i) passes through ae,0 ,tan tan
2 2 1 e
19
One or More than One Correct
(Section-II)
n i j
41. Find the value of the expression
i 1 j 1 k 1
1
n n 1 n n 1n 2
2n 1 3 .
12 6
42. If f0 f 1 f2 0 & function f x is twice differentiable in 0,2 and continuous in 0,2 . Then which of the
following is/are definitely true :
(A) f c 0;c 0,2
(B) f c 0 ; for at least two c 0,2
(C) f c 0 ; for exactly one c 0,2
f c2 0
1 c2 2
f x 0 where 1 c2 2 … (2)
f x 0 in 0,2
f x 0
2m 2m
2
43. The bisectors of angle between the straight lines, y b x a and y b x a are
1 m 1 m '2
(A) y bm m x a1 m m 0
y b tan2 x a
xa yb xa yb
and
cos2 sin2 cos2 sin2
20
44. If the length of the projection of the line segment with points 1,0,1 and 1,2,2 to the plane x 3y 5z 6 is d ,
d
then find the value of where represent greatest integer function.
2
(A) 7 (B) 5 (C) 3 (D) 1
Ans. (D)
121
(2)2 (2)2 (3)2 1
595
474
35
d /2 1
45. The number 71995 when divided by 100 leaves the remainder
(A) 41 (B) 42 (C) 43 (D) 44
Ans. (C)
Sol. 71995 7(49)993
7(50 1)997
7 997 C 0 50997 997 C 150996 9999
976 50 1
10k 7 997 50 1
100k 7 990 50 7 50 1
100k1 2450 7
100k1 2400 43
100k2 43
46. Let C 1 be the circle of radius 1 with center at the origin. Let C 2 be the circle of radius r with center at the point
A 4,1 , where 1 r 3 . Two distinct common tangents PQ and ST of C 1 and C 2 are drawn. The tangent PQ
touches C 1 at P and C 2 at Q . The tangent ST touches C 1 at S and C 2 at T . Mid points of the line segments PQ and
ST are joined to form a line which meets the X -axis at a point B . If AB 5 , then the value of r2 is
(A) 1 (B) 2 (C) 3 (D) 4
Ans. (B)
21
Sol.
47. Find the condition on a, b, c and d such that equations 2ax3 bx2 cx d 0 and 2x2 3bx 4c 0 have a
common root
9
(A) (4ab cd)2
2
ac 4d2 b2 ac
9
(B) (4cd ab)2 ad 4c2 b2 ac
2
9
(C) (4bc ad)2 bd 4c2 b2 ac
2
9
(D) (4ad bc)2 bc 4a2 b2 ac
2
Ans. (C)
Sol. Let ' ' be a common root of the given equations,
then 2a3 b2 c d 0 …(1)
and 2a2 3 b 4c 0 …(2)
Multiply (2) by and then subtract (1) from it, to get
2 b2 3c d 0 …(3)
Now (2) and (3) are quadratic having a common root , so
2 1 bd 4c2 4bc ad
,2
,
3bd 12c2 8bc 2ad 6ac 6b2 2b2 2ac 3ac 3b2
Eliminating from these two equations, we get
9
(4bc ad)2
2
bd 4c2 b2 ac , which is the required condition.
m an
48. If the length of the focal chord of the parabola y2 4ax whose distance from the vertex is p is then total
p
number of divisors of m n is :
(A) 2 (B) 3 (c) 4 (D) 5
Ans. (B)
Sol. y2 4ax
22
Let points of focal chord be
A at21 ,2at1 & B at1,2aa1
1 2 1
tt
AB : t1 t2 y 2x 2at1t2
2att
p 1 2
t1 t2
2
22
2a
2 t1 2 t2 2
also let length be c
c2 length 2 a2 t21 t22 4a2 t1 t2
2 2
a2 t t2
2
t t
1 2
2
4
c length a t21 t22 2
4a2
p2
t t22 2
2
1
4a2 4a3
p2
c /a c
4a3
c
p2
m 4
n3
2
m n 9
no of divisors 3
1,3,9
23
Numerical Value
(Section-III)
49. If the roots of the equation, x3 P2 Q x 19 0 are each one more than the roots of the equation
x3 Ax2 Bx C 0 , where A,B,C,P & Q are constants then the value of A B C is equal to :
Ans. (18)
Sol. x3 Px2 Q x 19 0 =
x3 Ax2 Bx C 0
A
c
1 1 1 19
1
19
C B 1 A 19
A B C 18
50. the equation (sinx cosx)1sin2x 2 , when 0 x has root , K is.
K
Ans. (4)
Sol. We know, a2 b2 asin bcos a2 b2 and 1 sin 1.
sinx cosx admits the maximum value as 2 and 1 sin2x admits the maximum value as 2 .
Also ( 2)2 2 .
the equation could hold only when, sinx cosx 2 and 1 sin2x 2
Now, sinx cosx 2
cos x 1
4
x 2n ,n I ...(i)
4
and 1 sin2x 2
sin2x 1 sin
2
2x m (1)m ,m I
2
m
x (1)m ...(ii)
2 4
K4
The value of x in 0, satisfying equations (i) and (ii) is x (when n 0 & m 0 )
4
n
1 1 1 1
51. If b is the harmonic mean between a and c , there , n is.
b a b c a c
Ans. (1)
24
2ac
Sol. b
ac
1 1
ba bc
1 1
2ac 2ac
a c
ac ac
1 a c
a c
ac a2 ac c2
1 1
a c
a c a c a c
a c 1 1
c a a c
ac 1 1
ac a c
n=1
1 1
52. If two roots are equal, find the roots of 4x3 20x2 23x 6 0 . If roots are find
( = )
Ans. (10)
Sol. Let roots be , and
20
2 5
4
23 23 6
2 2 & 2
4 4 4
from equation (i)
23 23
2 2 5 2 2 10 42 122 40 23 0
4 4
23
1/2,
6
1
when
2
1 3
2 5 1
4 2
23 23 23 23 3 1
when 2 5 2x 6
6 36 6 2 2
1 1
Hence roots of equation , ,6
2 2
1 1
226
10
53. Equation of the chord of the hyperbola 25x2 16y2 400 which is bisected at the point 6,2 is- 75x- 16y = k, k is.
Ans. (418)
x2 y2
Sol. 1
16 25
T S1
25
6x 2y 36 4
1 1
16 25 16 25
150x 32y 900 64
75x 16y 418
54. Find the total number of 4 letter words formed using four letters from the word "PARALLELOPIPED'.
Ans. (2780)
Sol. Given letters are PPP, LLL, AA, EE, R, O, I, D.
Cases No. of ways of selection No. of ways of arrangements Total
All distinct 8
C4 8
C 4 4! 1680
2 alike, 2 distinct 4
C 1 7C 2 4
C 1 7C 2
4! 1008
2!
2 alike, 2 other 4
C2 4! 36
4
C2
alike 2!2!
3 alike, 1 distinct 2
C 1 7C 1 2
C 1 7C 1
4! 56
3!
Total 2780
26