1 0 B B

0C C11 627 7806 68F FA0 60E E41 1BB EB 993

6 6
C1 116 278 8068 8FA A06 0E4 41B BBE EB9 9938 873
2 0 0 9 A
11 1627 780 68F FA0 060E E41 1BB BEB B99 387 73A DE
62 80 68 A 60 4 BB EB 99 38 3A DE 0C
62 780 68 FA 060 E4 1BB EB 99 38 73A DE 0C 11
F 0 1 7 6

Q.7
Q.6
Q.5
Q.4
Q.3
Q.2
Q.1
N.B
27 7806 68F A0 60E E41 BB EB 993 387 3AD DE 0C1 116 278
80 8F A0 60 41 BB EB 99 87 3A E 0C 16 27 06
80 68F A0 60 E41 BB EB 99 387 3A DE 0C 116 27 806 8F
6 A 6 E B E 9 38 3 D 0 1 2 80 8 A

F-6095
68 8FA 060 0E4 41B BE B99 938 73A ADE E0C C11 1627 780 68F FA0 060E
B B 7 6
8F FA0 060E E41 1BB EB 993 387 3A DE 0C1 116 6278 806 8FA A06 60E 41B
6 B

i)
A0 0 41 B EB 99 87 3A DE 0C 16 27 06 8F 0 0E 41 B

v)

x)
ii)

vi)
iv)

ix)
iii)
A0 60 E41 BB EB 99 387 3A DE 0C 116 27 806 8F A0 60E 41 BB EB

vii)
E 3 3 D 0 1 8 8 A 6 4 B E 9

viii)
06 60E4 41B BBE EB9 9938 873 AD E0 C11 162 2780 068 FA 060 0E4 1BB BEB B99 938
0E 1B B B 93 73 AD E0 C1 62 78 68 FA 06 E4 1B E 9 38 73
41 B EB 993 87 A E C1 16 78 06 FA 06 0E 1B BE B9 93 73 AD

[Time: Three Hours]

BB EB 99 87 3A DE 0C 16 27 06 8F 0 0E 41 B B 93 87 AD E0
EB 99 387 3A DE 0C 116 27 806 8F A0 60E 41 BB EB 993 873 3AD E0 C1

chloride.
99 387 3A DE 0C 116 27 806 8F A0 60E 41 BB EB 993 873 AD E0 C1 16
38 3A D 0C 11 27 80 8F A0 60 41 BB EB 99 87 A E C 16 27
Total No. of Printed Pages:2

73 D E0 1 62 80 68 A 60 E4 B E 99 38 3A DE 0C 11 27 80
AD E0 C1 16 78 68 FA 06 E4 1B BE B9 38 73 D 0 11 62 80 68
E0 C1 162 278 068 FA 060 0E4 1B BE B9 938 73A AD E0C C11 627 780 68F FA0
C1 16 78 068 FA 06 E4 1B BE B9 938 73 D E0 11 62 80 68 A 60
16 278 06 FA 06 0E 1B BE B9 93 73 AD E0 C1 62 780 68 FA 060 E4
27 06 8F 0 0E 41 B B 93 87 AD E C1 16 78 68 FA 06 E 1B
80 8F A0 60 41 BB EB 99 87 3A E 0C 16 27 06 F 06 0E 41 B
68 A 60 E4 B E 99 38 3A DE 0C 11 27 80 8F A0 0E 41 BB EB

Explain Salt effect

FA 06 E4 1B BE B9 38 73 D 0 11 62 80 68 A 60 4 BB EB 99
06 0E4 1B BE B9 938 73 AD E0 C11 62 780 68 FA 060 E4 1BB EB 99 38
0E 1B B B 93 73 AD E0 C1 62 78 68 FA 06 E4 1B E 9 38 73
41 B EB 993 87 A E C1 16 78 06 FA 06 0E 1B BE B9 93 73 AD
BB EB 99 87 3A DE 0C 16 27 06 8F 0 0E 41 B B 93 87 AD E0
EB 99 387 3A DE 0C 116 27 806 8F A0 60E 41 BB EB 993 873 3AD E0 C1
99 387 3A DE 0C 116 27 806 8F A0 60E 41 BB EB 993 873 AD E0 C1 16

Give the concept of fugacity.

Answer the following questions in brief.
38 3A D 0C 11 27 80 8F A0 60 41 BB EB 99 87 A E C 16 27
73 D E0 1 62 80 68 A 60 E4 B E 99 38 3A DE 0C 11 27 80

a) Derive Debye-Huckel limiting law.

AD E0 C1 16 78 68 FA 06 E4 1B BE B9 38 73 D 0 11 62 80 68

a) Derive Fermi-Dirac distribution law.

E0 C1 162 278 068 FA 060 0E4 1B BE B9 938 73A AD E0C C11 627 780 68F FA0

Write a note on solubility product.

Explain Debye-Falkenhagen effect
C1 16 78 068 FA 06 E4 1B BE B9 938 73 D E0 11 62 80 68 A 60
i. Q.No.1 is compulsory.

16 278 06 FA 06 0E 1B BE B9 93 73 AD E0 C1 62 780 68 FA 060 E4

1
27 06 8F 0 0E 41 B B 93 87 AD E C1 16 78 68 FA 06 E 1B

b) Discuss the translational partition function.

80 8F A0 60 41 BB EB 99 87 3A E 0C 16 27 06 F 06 0E 41 B
Write a note on partial molar properties.
68 A 60 E4 B E 99 38 3A DE 0C 11 27 80 8F A0 0E 41 BB EB
Chemistry

b) Derive Laplace equation and Kelvin equation

a) Discuss dissociation of weak acids and bases.

b) Explain the binding of oxygen by myoglobin.
FA 06 E4 1B BE B9 38 73 D 0 11 62 80 68 A 60 4 BB EB 99

Write the validity test of Onsager equation’

06 0E4 1B BE B9 938 73 AD E0 C11 62 780 68 FA 060 E4 1BB EB 99 38

b) Give any two methods to determine the fugacity

0E 1B B B 93 73 AD E0 C1 62 78 68 FA 06 E4 1B E 9 38 73

Write different types of surface active agents.

a) Define CMC. Discuss the factors affecting CMC.

41 B EB 993 87 A E C1 16 78 06 FA 06 0E 1B BE B9 93 73 AD
BB EB 99 87 3A DE 0C 16 27 06 8F 0 0E 41 B B 93 87 AD E0
EB 99 387 3A DE 0C 116 27 806 8F A0 60E 41 BB EB 993 873 3AD E0 C1

a) Give the thermodynamic formulation of rate equation.

99 387 3A DE 0C 116 27 806 8F A0 60E 41 BB EB 993 873 AD E0 C1 16
Examination Oct/Nov 2019

a) Discuss Lindemann’s theory for unimolecular reaction.

iii. Figure to the right indicate full marks.

38 3A D 0C 11 27 80 8F A0 60 41 BB EB 99 87 A E C 16 27
Physical Chemistry - CHE 104
SUBJECT CODE NO:- F-6095

73 D E0 1 62 80 68 A 60 E4 B E 99 38 3A DE 0C 11 27 80
Calculate ionic strength of 0.25 M Aluminum nitrate.

AD E0 C1 16 78 68 FA 06 E4 1B BE B9 38 73 D 0 11 62 80 68

873ADE0C116278068FA060E41BBEB993
E0 C1 162 278 068 FA 060 0E4 1B BE B9 938 73A AD E0C C11 627 780 68F FA0

b) Explain relaxation method to study kinetics of fast reactions.

C1 16 78 068 FA 06 E4 1B BE B9 938 73 D E0 11 62 80 68 A 60
ii. Attempt any five questions from Q.No.2 to 8.

16 278 06 FA 06 0E 1B BE B9 93 73 AD E0 C1 62 780 68 FA 060 E4

27 06 8F 0 0E 41 B B 93 87 AD E C1 16 78 68 FA 06 E 1B
iv. Use of non-programmable calculator is allowed.

80 8F A0 60 41 BB EB 99 87 3A E 0C 16 27 06 F 06 0E 41 B
water is 0.97 gm cm-3 and surface tension is 72.25 dynes cm-1.
FACULTY OF SCIENCE AND TECHNOLOGY

68 A 60 E4 B E 99 38 3A DE 0C 11 27 80 8F A0 0E 41 BB EB
M.Sc (CBCGS) (Sem -I) Examination Oct/Nov 2019

FA 06 E4 1B BE B9 38 73 D 0 11 62 80 68 A 60 4 BB EB 99
Please check whether you have got the right question paper.

06 0E4 1B BE B9 938 73 AD E0 C11 62 780 68 FA 060 E4 1BB EB 99 38

0E 1B B B 93 73 AD E0 C1 62 78 68 FA 06 E4 1B E 9 38 73
41 B EB 993 87 A E C1 16 78 06 FA 06 0E 1B BE B9 93 73 AD
Show graphically the effect of ionic strength on rate constant when

BB EB 99 87 3A DE 0C 16 27 06 8F 0 0E 41 B B 93 87 AD E0
EB 99 387 3A DE 0C 116 27 806 8F A0 60E 41 BB EB 993 873 3AD E0 C1
99 387 3A DE 0C 116 27 806 8F A0 60E 41 BB EB 993 873 AD E0 C1 16
38 3A D 0C 11 27 80 8F A0 60 41 BB EB 99 87 A E C 16 2
73 D E0 1 62 80 68 A 60 E4 B E 99 38 3A DE 0C 11 27
AD E0 C1 16 78 68 FA 06 E4 1B BE B9 38 73 D 0 11 62
E0 C1 162 278 068 FA 060 0E4 1B BE B9 938 73A AD E0C C11 627 780
C1 16 78 068 FA 06 E4 1B BE B9 938 73 D E0 11 62 80
16 278 06 FA 06 0E 1B BE B9 93 73 AD E0 C1 62 780 6
27 06 8F 0 0E 41 B B 93 87 AD E C1 16 78 68
80 8F A0 60 41 BB EB 99 87 3A E 0C 16 27 06 F
68 A 60 E4 B E 99 38 3A DE 0C 11 27 80 8F
FA 06 E4 1B BE B9 38 73 D 0 11 62 80 68 A
06 0E4 1B BE B9 938 73 AD E0 C11 62 780 68 FA
Calculate the height to which water will rise in a capillary of radius 0.025 cm if density of

0E 1B B B 93 73 AD E0 C1 62 78 68 FA 06
41 B EB 993 87 A E C1 16 78 06 FA 06
BB EB 99 87 3A DE 0C 16 27 06 8F 0 0
[Max. Marks: 80]

06
06
06
06
b) Calculate the activity coefficients of Ba++ and Cl- ions in 0.025 M solution of Barium 06
06
06
06
06
06
06
06
20

2019
F-6095

EB 99 387 3A DE 0C 116 27 806 8F A0 60E

99 387 3A DE 0C 116 27 806 8F A0 60E
38 3A D 0C 11 27 80 8F A0 60 41
73 D E0 1 62 80 68 A 60 E4
AD E0 C1 16 78 68 FA 06 E4 1B
E C 1 27 0 F 0 0E 1
 1 0 B B
0C C11 627 7806 68F FA0 60E E41 1BB EB 993
6 6
C1 116 278 8068 8FA A06 0E4 41B BBE EB9 9938 873
2 0 0 9 A
11 1627 780 68F FA0 060E E41 1BB BEB B99 387 73A DE
62 80 68 A 60 4 BB EB 99 38 3A DE 0C
62 780 68 FA 060 E4 1BB EB 99 38 73A DE 0C 11
F 0 1 7 6

Q.8
27 7806 68F A0 60E E41 BB EB 993 387 3AD DE 0C1 116 278
80 8F A0 60 41 BB EB 99 87 3A E 0C 16 27 06
80 68F A0 60 E41 BB EB 99 387 3A DE 0C 116 27 806 8F
6 A 6 E B E 9 38 3 D 0 1 2 80 8 A

F-6095
68 8FA 060 0E4 41B BE B99 938 73A ADE E0C C11 1627 780 68F FA0 060E
B B 7 6
8F FA0 060E E41 1BB EB 993 387 3A DE 0C1 116 6278 806 8FA A06 60E 41B
6 B
A0 0 41 B EB 99 87 3A DE 0C 16 27 06 8F 0 0E 41 B
A0 60 E41 BB EB 99 387 3A DE 0C 116 27 806 8F A0 60E 41 BB EB
E 3 3 D 0 1 8 8 A 6 4 B E 9
06 60E4 41B BBE EB9 9938 873 AD E0 C11 162 2780 068 FA 060 0E4 1BB BEB B99 938
0E 1B B B 93 73 AD E0 C1 62 78 68 FA 06 E4 1B E 9 38 73
41 B EB 993 87 A E C1 16 78 06 FA 06 0E 1B BE B9 93 73 AD
BB EB 99 87 3A DE 0C 16 27 06 8F 0 0E 41 B B 93 87 AD E0
EB 99 387 3A DE 0C 116 27 806 8F A0 60E 41 BB EB 993 873 3AD E0 C1
99 387 3A DE 0C 116 27 806 8F A0 60E 41 BB EB 993 873 AD E0 C1 16
38 3A D 0C 11 27 80 8F A0 60 41 BB EB 99 87 A E C 16 27
73 D E0 1 62 80 68 A 60 E4 B E 99 38 3A DE 0C 11 27 80
AD E0 C1 16 78 68 FA 06 E4 1B BE B9 38 73 D 0 11 62 80 68
E0 C1 162 278 068 FA 060 0E4 1B BE B9 938 73A AD E0C C11 627 780 68F FA0
C1 16 78 068 FA 06 E4 1B BE B9 938 73 D E0 11 62 80 68 A 60
16 278 06 FA 06 0E 1B BE B9 93 73 AD E0 C1 62 780 68 FA 060 E4
27 06 8F 0 0E 41 B B 93 87 AD E C1 16 78 68 FA 06 E 1B
80 8F A0 60 41 BB EB 99 87 3A E 0C 16 27 06 F 06 0E 41 B
68 A 60 E4 B E 99 38 3A DE 0C 11 27 80 8F A0 0E 41 BB EB
FA 06 E4 1B BE B9 38 73 D 0 11 62 80 68 A 60 4 BB EB 99
06 0E4 1B BE B9 938 73 AD E0 C11 62 780 68 FA 060 E4 1BB EB 99 38
0E 1B B B 93 73 AD E0 C1 62 78 68 FA 06 E4 1B E 9 38 73
41 B EB 993 87 A E C1 16 78 06 FA 06 0E 1B BE B9 93 73 AD
BB EB 99 87 3A DE 0C 16 27 06 8F 0 0E 41 B B 93 87 AD E0
EB 99 387 3A DE 0C 116 27 806 8F A0 60E 41 BB EB 993 873 3AD E0 C1
99 387 3A DE 0C 116 27 806 8F A0 60E 41 BB EB 993 873 AD E0 C1 16
38 3A D 0C 11 27 80 8F A0 60 41 BB EB 99 87 A E C 16 27
73 D E0 1 62 80 68 A 60 E4 B E 99 38 3A DE 0C 11 27 80
AD E0 C1 16 78 68 FA 06 E4 1B BE B9 38 73 D 0 11 62 80 68
E0 C1 162 278 068 FA 060 0E4 1B BE B9 938 73A AD E0C C11 627 780 68F FA0
C1 16 78 068 FA 06 E4 1B BE B9 938 73 D E0 11 62 80 68 A 60
16 278 06 FA 06 0E 1B BE B9 93 73 AD E0 C1 62 780 68 FA 060 E4

2
27 06 8F 0 0E 41 B B 93 87 AD E C1 16 78 68 FA 06 E 1B
80 8F A0 60 41 BB EB 99 87 3A E 0C 16 27 06 F 06 0E 41 B
68 A 60 E4 B E 99 38 3A DE 0C 11 27 80 8F A0 0E 41 BB EB
FA 06 E4 1B BE B9 38 73 D 0 11 62 80 68 A 60 4 BB EB 99
06 0E4 1B BE B9 938 73 AD E0 C11 62 780 68 FA 060 E4 1BB EB 99 38
0E 1B B B 93 73 AD E0 C1 62 78 68 FA 06 E4 1B E 9 38 73
41 B EB 993 87 A E C1 16 78 06 FA 06 0E 1B BE B9 93 73 AD
BB EB 99 87 3A DE 0C 16 27 06 8F 0 0E 41 B B 93 87 AD E0
EB 99 387 3A DE 0C 116 27 806 8F A0 60E 41 BB EB 993 873 3AD E0 C1
99 387 3A DE 0C 116 27 806 8F A0 60E 41 BB EB 993 873 AD E0 C1 16
Examination Oct/Nov 2019

38 3A D 0C 11 27 80 8F A0 60 41 BB EB 99 87 A E C 16 27
73 D E0 1 62 80 68 A 60 E4 B E 99 38 3A DE 0C 11 27 80
AD E0 C1 16 78 68 FA 06 E4 1B BE B9 38 73 D 0 11 62 80 68

873ADE0C116278068FA060E41BBEB993
E0 C1 162 278 068 FA 060 0E4 1B BE B9 938 73A AD E0C C11 627 780 68F FA0
C1 16 78 068 FA 06 E4 1B BE B9 938 73 D E0 11 62 80 68 A 60
a) State and explain Debye-Huckel theory of strong electrolytes.

16 278 06 FA 06 0E 1B BE B9 93 73 AD E0 C1 62 780 68 FA 060 E4

27 06 8F 0 0E 41 B B 93 87 AD E C1 16 78 68 FA 06 E 1B
80 8F A0 60 41 BB EB 99 87 3A E 0C 16 27 06 F 06 0E 41 B
68 A 60 E4 B E 99 38 3A DE 0C 11 27 80 8F A0 0E 41 BB EB
FA 06 E4 1B BE B9 38 73 D 0 11 62 80 68 A 60 4 BB EB 99
06 0E4 1B BE B9 938 73 AD E0 C11 62 780 68 FA 060 E4 1BB EB 99 38
0E 1B B B 93 73 AD E0 C1 62 78 68 FA 06 E4 1B E 9 38 73
41 B EB 993 87 A E C1 16 78 06 FA 06 0E 1B BE B9 93 73 AD
b) Explain thermodynamics of micellisation in terms of mass action model.

BB EB 99 87 3A DE 0C 16 27 06 8F 0 0E 41 B B 93 87 AD E0
EB 99 387 3A DE 0C 116 27 806 8F A0 60E 41 BB EB 993 873 3AD E0 C1
99 387 3A DE 0C 116 27 806 8F A0 60E 41 BB EB 993 873 AD E0 C1 16
38 3A D 0C 11 27 80 8F A0 60 41 BB EB 99 87 A E C 16 2
73 D E0 1 62 80 68 A 60 E4 B E 99 38 3A DE 0C 11 27
AD E0 C1 16 78 68 FA 06 E4 1B BE B9 38 73 D 0 11 62
E0 C1 162 278 068 FA 060 0E4 1B BE B9 938 73A AD E0C C11 627 780
C1 16 78 068 FA 06 E4 1B BE B9 938 73 D E0 11 62 80
16 278 06 FA 06 0E 1B BE B9 93 73 AD E0 C1 62 780 6
27 06 8F 0 0E 41 B B 93 87 AD E C1 16 78 68
80 8F A0 60 41 BB EB 99 87 3A E 0C 16 27 06 F
68 A 60 E4 B E 99 38 3A DE 0C 11 27 80 8F
FA 06 E4 1B BE B9 38 73 D 0 11 62 80 68 A
06 0E4 1B BE B9 938 73 AD E0 C11 62 780 68 FA
0E 1B B B 93 73 AD E0 C1 62 78 68 FA 06
41 B EB 993 87 A E C1 16 78 06 FA 06
BB EB 99 87 3A DE 0C 16 27 06 8F 0 0
06
06

2019
F-6095

EB 99 387 3A DE 0C 116 27 806 8F A0 60E

99 387 3A DE 0C 116 27 806 8F A0 60E
38 3A D 0C 11 27 80 8F A0 60 41
73 D E0 1 62 80 68 A 60 E4
AD E0 C1 16 78 68 FA 06 E4 1B
E C 1 27 0 F 0 0E 1