Cat 1

Sec: Incoming.Jr.IIT_*CO.
SC Date: 05-07-20
Time: 3HRS Max. Marks: 186
05-07-20_ Incoming.Jr.IIT _*CO SUPER CHAINA_Jee-Adv_CAT-1_SYLLABUS

PHYSICS: PRESENT WEEK (80%): Spring problems, the problems involving
constraints like multiple pulley & multiple contact problems
PREVIOUS WEEK (20%):Newton’s Laws Of Motion: Cause of motion,
cause for the change of motion, Newton's first law, qualitative definition
of force, inertia and mass, types of inertia,Newton's second law, quantitative
definition of force, definition of unit force, dimensional formula and SI units of
force, Newton's third law, action and reaction, Internal and external forces in
case of system of objects, Discussion on cancellation of action and reaction
forces, Inertial and non inertial frames of reference and pseudo force,
Problems on simple application of NLM - Atwood machine, Lift problems,
spring balance, weighing machine etc.
CUMULATIVE(25%): Optics- Lenses and combination or lenses
CHEMISTRY: PRESENT WEEK (80%):Chemical Kinetics: Rates of chemical
reactions; Order, Molecularity and Rate constant, Zero and First
Order Reactions, First order Kinetic, examples of 1st order Kinetics
Types of problems based on first order kinetics, second order kinetics
,nth order kinetics
PREVIOUS WEEK (20%):Collision number, mean free path, collision
frequency
Gaseous State-II: Non ideality of gases; vander Waal's equaiton of
state, Compressibility factor; liquifaction of gases & Critical state
CUMULATIVE(25%): 1) IUPAC 2) VBT Bond angles comparision
3) Hardness of water, Volume strength of H2O2
MATHEMATICS: PRESENT WEEK (80%):Determinants: Introduction of Determinants
& its Properties, Properties of Determinants, Expressing a Determinant as a
product of two Determinants, Cramer's Rule
(Avoid use of Differentiation, Integration, and Solving Linear
Equation)
PREVIOUS WEEK (20%):method of differences / Vn method, AM-GM-HM
Inequalities, Triangular Inequality, Cauchy-Schwartz Inequality,Problems
based on inequalities(Inequalities prescribed in the IIT JEE Syllabus only)
CUMULATIVE(25%): Quadratic Equations
Narayana IIT Academy 05-07-20_Incoming.Jr.IIT_*CO SC_JEE-Adv_CAT-1_Q’P
Time: 3 Hrs IMPORTANT INSTRUCTIONS Max Marks: 186
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 6) Questions with Single Correct Choice 3 -1 6 18
Questions with Multiple Correct
Sec – II(Q.N : 7 – 14) 4 -2 8 32
Choice (Partial Marking +1)
Questions with ComprehensionType
Sec – III(Q.N : 15 – 18) 3 0 4 12
(2 Comprehension-2+2=4Q)
Total 18 62
CHEMISTRY:
Sec – II(Q.N : 25 – 32) 4 -2 8 32
Sec – III(Q.N : 33 – 36) 3 0 4 12
Total 18 62
MATHS:
Sec – II(Q.N : 43 – 50) 4 -2 8 32
Sec – III(Q.N : 51 – 54) 3 0 4 12
Total 18 62
PHYSICS Max.Marks: 62
SECTION-I
(Single Correct Answer Type)
This section contains 6 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) out of which
ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
1. Light ray incident on a prism of angle A  600 and refractive index   2 . The angle
of incidence at which the emergent ray grazes the surface is given by
 3 1 
1 1  3
  3  2 
A) sin 1   B) sin   C) sin 1
  D) sin 1  
 2   2   2   3
2. Figure shows the graph of angle of deviation (  )versus angle of incidence ( i ) for
light ray striking a prism. The prism angle is
A) 300 B) 450 C) 600 D) 750
3. Two blocks ‘A’and ‘B’ each of mass ‘m’ are placed on a smooth horizontal surface.
Two horizontal forces F and 2F are applied on the blocks ‘A’and ‘B’ respectively as
shown in figure. The block A does not slide on block B. Then the normal reaction
acting between the two blocks is . (Surface below A and B is smooth)
F
A) F B) F/2 C) D) 3F
3
g
4. A balloon of mass m is found to accelerate up at the rate of . The amount of water
6
g
that should be put inside the balloon so that it may accelerate down at the rate of .
6
Assume buoyancy force remains same.
m 2m 3m 4m
A) B) C) D)
5 5 5 5
5. A bead of mass m is attached to one end of a spring of natural length R and spring
constant K 
 
3  1 mg
. The other end of the spring is fixed at a point A on a
R
smooth vertical ring of radius R as shown in the figure. The normal reaction at B just
after it is released to move is
3 3mg
A) mg / 2 B) 3mg C) 3 3mg D)
2
6. IF block B moves towards right with acceleration b, find the net acceleration of block
A.
a) bi  4b j B) bi  b j C) bi  2b j D) None of these

SECTION-II
(Multiple Correct Answer Type)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong cases.
7. A painter of mass 100kg is raising himself and the crate on which he stands as shown.
When be pulls the rope, the force exerted by him on the crate’s floor is 375 N. If the
mass of the crate is 50 kg then__
A) Acceleration of the system (painter+crate) is 5ms 2 is upward direction
B) Acceleration of the system (painter+crate) is 1ms 2 is upward direction
C) Tension in the rope is 1250 N
D) Tension in the rope is 1125 N
8. In the arrangement, shown below pulleys are massless and frictionless and threads are
in-extensible, block of mass m1 may remain at rest if
4 1 1 m 1 1 1 1 2 3
A)   B) 1  m2  m3 C)   D)  
m1 m2 m3 2 m1 m2 m3 m1 m2 m3
9. Ring A can slide on a smooth horizontal rod and block B can move vertically. Both
are attached by an inextensible string. At a certain instant velocity of ring is v1 and of
block is v2 . At that instant ring is at a horizontal distance b from pulley as shown.
Then
A) v2  v1 cos 
B) a2  a1 cos , where a2 and a1 represent the accelerations of block and ring
respectively at that instant
C) v1  v2 cos 
v1v2 3
D) a1  a2 cos  sin  where a1 & a2 represents accelerations of ring and block
a
respectively.
10. A point source of light S is placed on the axis of a thin lens of focal length 20 cm as
shown. A screen is placed normal to the axis of lens at a distance 'x' from it. Treat all
rays as paraxial.
A) As 'x' is increased from zero, intensity continuously decreases

B) As 'x' is increased from zero, intensity first increases then decreases
C) Intensity at centre of screen for x = 90 cm and x = 110 cm is same
D) radius of bright circle obtained on screen is equal to 1 cm for x = 200 cm
11. A luminous point object is placed at O, whose image is formed at I as shown in the
figure. AB is the optical axis. Which of the following statements are correct? (Assume
paraxial rays only)
A) If a lens is used to obtain image, the lens must be converging

B) If a mirror is used to obtain image, the mirror must be a convex mirror having pole
at the point of intersection of lines OI and AB
C) Position of principal focus of mirror cannot be found
D) I is real image
12. The convex surface of a thin concavo–convex lens of glass of refractive index 1.5 has
a radius of curvature of 20 cm. The concave surface has a radius of curvature of 60
cm. The convex side is silvered and placed on a horizontal surface as shown in the
figure.
A) The focal length of the combination has the magnitude 7.5cm

B) The combination behaves like a concave mirror
C) A small object is placed on the principal axis of the combination, at a distance of
30 cm in front of the mirror. The magnification of the image is 3/4.
D) None of the above three options is correct
13. Seven pulleys are connected with the help of three light strings as shown in the figure.
Consider P3 , P4 , P5 as light pulleys and pulleys P6 and P7 have masses m each. For
this arrangement, mark the correct statement(s)
A) Tension in the string connecting P1 , P2 and P3 is zero
B) Tension in the string connecting P1 , P2 and P3 is mg / 3
C) Tensions in all the three strings are same and equal to zero
D) Acceleration of P6 is g downwards and that of P7 is g upwards
14. Two masses m1 and m2 are connected by light inextensible string passing over a
smooth pulley moves vertically upwards with an acceleration equals to g then,
(Assume, m2 >m1)
4m1m2 g
A) Tension in the string is
m1  m2
2m1m2 g
B) Tension in the string is
m1  m2
 3m  m2 
C) The acceleration of mass m1 with respect to ground is  1 g
 m1  m2 
 m  m1 
D) The acceleration of mass m1 with respect to ground is 2  2 g
 1
m  m2
SECTION-III
(Paragraph Type)
This section contains 2 groups of question. Each group has 2 multiple choice questions based on a paragraph.
Each question has 4 choice (A), (B),(C) AND (D) for its answer, out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
Paragraph For Questions 15 and 16:
In the system shown in the figure, m1  m2 . System is held at rest by thread BC. Now
thread BC is burnt. Answer the following
15. Before burning the thread, what are the tensions in spring and thread BC, respectively?
A) m1 g , m2 g B) m1 g , m1 g  m2 g C) m2 g , m1 g D) m1 g , m1 g  m2 g
16. Just after burning the thread, what is the acceleration of m2 ?
 m  m1   m  m2   m  m2 
A)  2 g B)  1 g C) zero D)  1 g
 m 2   1
m  m2   m2 
Paragraph For Questions 17 and 18:

In the shown arrangement, both pulleys and the string are massless and all the surfaces
are frictionless.
Given:( m1 = 1Kg, m2 = 2Kg and m3 = 3Kg)

17. Find the tension in the string.
120 240 130 80
A) N B) N C) N D) N
7 7 7 7
18. The acceleration of m1 is
40 2 30 2 20 2 17 g
A) ms B) ms D) ms D) ms 2
7 7 7 7
CHEMISTRY Max.Marks: 62
SECTION-I
19. Under the same reaction conditions initial concentration of 1.386 mol dm 3 of a
substance becomes half in 40 s and 20 s through first order and zero order kinetics
k 
respectively. Ratio  1  of the rate constants for first order k1  and zero order k0 
 k0 
of the reaction is
A) 0.5mol 1dm 3 B) 1.0mol dm 3 C) 1.5mol dm 3 D) 2.0mol 1dm 3
20. The reaction between NO and Br2 takes place in two steps
k1
I) NO  Br2 NOBr2 II) NOBr2  NO 
k
 2 NOBr
3
k2
If k1  k2  k3 , then the rate law of the overall reaction, 2 NO  Br2  2 NOBr can be
given by
A) rate  k  NO  Br2  B) rate  k  NO  Br2 

2 1
C) rate  k  NOBr  NO  D) rate  k  NO Br2 

2
21. A substance ‘A’ decomposes in solution by following the first order kinetics .Flask I
contains 1 L of 1 M of solution of ‘A’ and flask II contains 100 ml of 0.6 M solution
of ‘A’. After 8 hrs the concentration of ‘A’ in flask I become 0.25 M. What will be the
time for concentration of ‘A’ in flask II to become 0.3 M?
A) 2.0 hrs B) 8.0 hrs C) 4.0 hrs D) 6.0 hrs
22. In dilute aqueous H 2 SO4 , the complex diaquadioxalate ferrate(II) ion

2
 Fe  H 2O 2  C2O4 2  is oxidized by MnO4 . For this reaction, the ratio of rate of change
of [ H  ] to the rate of change of [ MnO4 ] is
A) 4 B) 6 C) 8 D) 10
23. Fraction of molecules ( ) are related with velocity according to reaction
3 9
 1   v 2  3v  1  v  3
4 4
Then find most probable speed?
A) 0 B) 1 C) 2 D) 3
24. Density of hydrogen gas at 27 0 C is 0.25 g / lt .If van der Waals gas constant ‘b’ for H 2
is 0.5 lt / mol ,then compressibility factor of H 2 is
A) 1.8 B) 1.412 C) 1.23 D) 1.067
SECTION-II
25.
Cl  g   CHCl3  g  
k2
 HCl  g   CCl3  g 
CCl3  g   Cl  g  
k3
 CCl4  g 
k1  4.8  103 ; k1  1.2  103 ; k2  1.3  10 2 ; k3  2.1 10 2
A) Order of reaction is 3/2
B) Magnitude of overall rate of constant is 2.6  10 2
C) If conc. of CHCl3 is increased four times rate of reaction increases by a factor of two
D) If conc. of Cl2 is increased four times rate of reaction increases by a factor of two
26. For the first order reaction 2 N 2O5 ( g ) 

 4 NO2 ( g )  O2 ( g )
A) The concentration of reactant decreases exponentially with time
B) The t1/ 2 of reaction decreases with increasing temperature.
C) Half life period is independent on initial concentration
D) The reaction processes to 99.6% completion in 8t1/ 2 duration.

27. Among the following second order reaction is/are
A) KClO3  6 FeSO4  3H 2 SO4  KCl  3Fe2  SO4 3  3H 2O
B) CHCl3  Cl2  CCl4  HCl

C) C2 H 4  H 2  C2 H 6

D) CH 3COOC2 H 5  H 2O 
H
CH 3COOH  C2 H 5OH
28. Isotherms of carbon dioxide at various temperatures given below
Incorrect statement among the following is

A) At T1K , vapour pressure of liquid carbon dioxide is P1
B) ED represents super cooled vapour, AB represents super heated liquid and these
two are metastable
C) Curve BCD possible practically
 P 
D) P  Pc  V  is zero
lt
 TC
B
29. One way of writing the equation of state PV = RT[A + + .......]. Which is true for
V
constant A & B in equation, if van der Waal’s equation of a state is expressed in
the above form
b
A) Expression for B is a –
RT
a
B) Expression for B is b –
RT
C) Unit of B is cm3 and it is temperature dependent

D) Constant A must be 1
30. 500 ml 22.4 V H 2O2 solution and 500 ml 44.8 V H 2O2 solution mixed together. Which
is/are correct statement about final H 2O2 solution of density equal to 1.182 g/mL
A) Volume strength is 33.6 V B) Molarity is 3M
C) % w/v of H 2O2 is 10.2 D) Mole fraction of H 2O2 is 0.0476
31. In which of the following molecules, different bond lengths possible
A) PCl5 B) SF4 C) IF7 D) SO42
32. 100 ml of hard water sample is titrated against standard soap solution, when 20 ml of
soap solution is added; lathes formed, but if you repeat the literation after boiling now
lather observed when 15 ml of soap solution added. Correct statement(s) among the
following is/are
A) Temporary hardness of water sample is 50ppm
B) Permanent hardness of water sample is 150 ppm
C) Concentration of bi carbonate ion in the sample is 61 ppm
D) If hardness is only due to calcium ions then concentration of calcium ions is 40
ppm
SECTION-III
(Paragraph Type)
Paragraph for Questions 33 and 34:
X and Y are two volatile liquids with molar weights of 10 g mol 1 and 40 g mol 1
respectively. Two cotton plugs, one soaked in X and the other soaked in Y, are
simultaneously placed at the ends of a tube of length L = 24 cm, as shown in the
figure. The tube is filled with an inert gas at 1 atmosphere pressure and a temperature
of 300 K. Vapours of X and Y react to form a product which is first observed at a
distance d cm from the plug soaked in X. Take X and Y to have equal molecular
diameters and assume ideal behaviour for the inert gas and the two vapours.
33. The value of d in cm (shown in the figure), as estimated from Graham’s law, is
A) 8 B) 12 C) 16 D) 20
34. The experimental value of d is found to be smaller than the estimate obtained using
Graham’s law. This is due to
A) Larger mean free path for X as compared to that of Y.
B) Larger mean free path for Y as compared to that of X.
C) Increased collision frequency of Y with the inert gas as compared to that of X with
the inert gas.
D) Increased collision frequency of X with the inert gas as compared to that of Y with
the inert gas.

Titration process may be used to find out the rate of first order kinetics. During the
process reaction mixture is titrated against a suitable reagent of standard concentration
and the used volume of the reagent observed at different time. The following
observation are given for a particular first order reaction.
AB+C
Time t 
Volume of reagent V2 V3
Reagent reacts with all A, B and C which have ‘n’ factors in the ratio of 1 : 2 : 3 with
the reagent.
35. Which of the following relation is correct?
A) Initial volume of reagent = V3/3 B) Initial volume of reagent = V3/5
C) Initial volume of reagent = V2/3 D) Initial volume of reagent = V2/5
36. Rate constant ‘k’ for above reaction is –
1 4V3 1 4V3
A) k  ln B) k  ln
t 5 V2  V3  t 5V3  V2
1 4V3 1 V3
C) k  ln D) k  ln
t 5 V3  V2  t 2 V3  V2 
MATHEMATICS Max.Marks: 62
SECTION-I
37. If ax12  by12  cz12  ax22  by22  cz22  ax32  by32  cz32  d ,
ax2 x3  by2 y3  cz2 z3  ax3 x1  by3 y1  cz3 z1  ax1 x2  by1 y2  cz1 z2  f .
x1 y1 z1
Then x2 y2 z2 
x3 y3 z3
d  2 f   d  2 f  
1/2 1/ 2
A)  d  f    B)  d  f   
 abc   abc 
d  2 f   d  2 f  
1/2 1/2
C)  d  f    D)  d  f   
 abc   abc 
38. If a,b,c are the roots of the equation x 3  3 x 2  3 x  7  0 , then the value of
2bc  a 2 c2 b2
c2 2ac  b 2 a2 is
b 2
a 2
2ab  c 2
A) 9 B) 27 C) 81 D) 0
ap a p
39. If bc  qr  ca  rp  ab  pq  1 then 3 bq b q is
cr c r
A) 0 B) 1 C) 2 D) 3
40. If a 2  b 2  c 2  1 then the value of the determinant
a 2   b 2  c 2  cos  ba 1  cos   ca 1  cos  

ab 1  cos   b 2   c 2  a 2  cos  cb 1  cos   is f   ,then the correct option is
ac 1  cos   bc 1  cos   c 2   a 2  b 2  cos 
   
A) f    4 B) f    C) f    D f    1
1 3
4 3 4 6 8 2
a2 1 ab ac
41. If a, b, c are real then the value of determinant ab b2  1 bc  1 if:
ac bc c2  1
A) a  b  c  0 B) a  b  c  1 C) a  b  c  1 D) a  b  c  0
 4 1  4 1   1
1    3   ....   2n  1  
4
42. The value of  4  4  4

is equal to
 4 1  4 1   1
 2    4   .....   2n   
4
 4  4  4
1 1 1 n
A) B) C) D)
4n  2n  1 8n  4n  1 4  2n  n  1 8n  4n  1
2 2 2 2
SECTION-II
a  p a  q a  r 
2 2 2
43. The value of determinant  b  p   b  q   b  r  is not equal to

2 2 2
c  p c  q c  r 
2 2 2
1  ap  1  aq  1  ar  1  ap  1  aq  1  ar 
2 2 2 2 2 2
A) 1  bp  1  bq  1  br  B) 1  bp  1  bq  1  br 
2 2 2 2 2 2
1  cp  1  cq  1  cr  1  cp  1  cq  1  cr 
2 2 2 2 2 2
1  ap  1  aq  1  ar  1  ap  1  aq  1  ar 
3 3 3 3 3 3
C) 1  bp  1  bq  1  br  D) 1  bp  1  bq  1  br 
3 3 3 3 3 3
1  cp  1  cq  1  cr  1  cp  1  cq  1  cr 
3 3 3 3 3 3
a2   b  c
2
a2 bc
b2   c  a 
2
44. The determinant b 2 ca is divisible by:
c2   a  b 
2
c2 ab
A) a  b  c B)  a  b  b  c  c  a 
C) a 2  b 2  c2 D)  a  b  b  c  c  a 
1/ z 1/ z   x  y / z2
45. If     y  z  / x 2 1/ x 1/ x then
y  y  z / x z 2
 x  2 y  z  / xz  y  x  y  / xz 2
A)  is independent of z B)  is independent of x
C)  depends on z D)  depends on x
1 1 1 1
46. For a positive integer n, let a  n   1     .... . Then
2 3 4  2  1n
A) a(100)  100 B) a(100) > 100 C) a(200)  100 D) a(200) > 100
47. Let S be the set of all non-zero real numbers  such that the quadratic equation
x 2  x    0 has two distinct real roots x1 and x 2 satisfying the inequality x1  x 2  1 .
Which of the following intervals is(are) a subset(s) of S ?
 1 1   1   1   1 1
A)   ,   B)   ,0 C)  0,  D)  , 
 2 5  5   5  5 2
48. Let p, q be integers and let ,  be the roots of the equation x 2  x  1  0 , where    .
For n = 0, 1, 2, …, let a n  pn  qn . (Fact : If a and b are rational numbers and
a  b 5  0 then a = 0 = b.
A) a12  a11  a10 B) p + 2q = 12 C) a12  a11  a10 D) p + 2q = 12

n
k
49. Let a k  and Sn   a k , then
 k  1  k 4/3   k  1
4/3 4/3
k 1
17 17
A) S26  B) S26  C) S999  50 D) S999  50
4 4
a b a  b
50. The determinant b c b  c  0 , if
a  b b  c 0
A) a, b, c are in A.P. B) a, b, c are in G.P.
C) a, b, c are in H.P. D)  x    is a factor of ax 2  2bx  c

SECTION-III
(Paragraph Type)
Let Vr denotes the sum of the first r terms of an arithmetic progression whose first term
is r and the common difference is (2r – 1). Let Tr  Vr 1  Vr  2 and Q r  Tr 1  Tr for
r = 1, 2,…
51. The sum V1  V2  ....  Vn is
n  n  1  3n 2  n  1 n  n  1  3n 2  n  2 
1 1
A) B)
12 12
n  2n 2  n  1  2n 3  2n  3
1 1
C) D)
12 3
52. Which one of the following is a correct statement ?
A) Q1 , Q 2 , Q3 ,.... are in AP with common difference 5
B) Q1 , Q 2 , Q3 ,.... are in AP with common difference 6
C) Q1 , Q 2 , Q3 ,.... are in AP with common difference 11
D) Q1  Q 2  Q3  ....
The value of the determinant of a square matrix will not be changed, by applying
elementary row (column) operations on it.
1  sin 2  cos 2  4sin 4
53. The number of values of  satisfying the equation sin  2
1  cos 2
4sin 4  0 for
sin 
2
cos 
2
1  4sin 4

0   is
2
A) 0 B) 1 C) 2 D) 4
1 a a2
54. The parameter on which the value of the determinant cos  p  d  x cos px cos  p  d  x
sin  p  d  x sin px sin  p  d  x
does not depend is
A) a B) p C) d D) x
Sec:Incoming.Jr.IIT _*COSC CAT-1 Date: 05-07-20
Time: 3HRS 2016-P2 Max.Marks:186
KEY SHEET
PHYSICS
1 A 2 B 3 D 4 B 5 D
6 A 7 AD 8 AB 9 CD 10 BCD
11 AD 12 AB 13 AC 14 AC 15 B
16 D 17 A 18 D
CHEMISRTY
19 A 20 A 21 C 22 C 23 C
24 D 25 ABD 26 ABCD 27 A 28 C
29 BD 30 ABCD 31 ABC 32 ABCD 33 C
34 D 35 B 36 C
MATHS
37 A 38 D 39 A 40 B 41 D
42 B 43 ACD 44 ACD 45 AB 46 AD
47 AD 48 AB 49 BC 50 BD 51 B
52 B 53 C 54 B
Narayana IIT Academy 05-07-20_Incoming.Jr.IIT_*CO SC_JEE-Adv_CAT-1_Key & Sol’s
SOLUTIONS
PHYSICS
5. Extension in the spring is
x  AB  R  2 R cos300  R   3 1 R 
 
3  1 mg
Spring force: F  kx 
R
  
3  1 R  2mg
6.
Acceleration of A in horizontal direction = the acceleration of B= b rightwards

Acceleration of A in vertical direction = the acceleration of A with respect to b in upwards direction
= a  4b
Hence, net acceleration of A  bi  4b j
1 1 1 1 1 1 1 1 1 1
10.           v  100cm
v u f v  25  20 v 20 25 100
From O to I intensity increases and then decreases at x = 90 cm and 110 cm intensity is same.
(D) Radius at x = 200 cm is equal to radius of lens .
11. Inverted image is real
12. Pe  2 Pl  Pm
The combination behaves like a mirror positive power is converging.
13. First of all draw FBD of P3 . Let tensions, in three strings be T1 , T2 and T3 , respectively.
2T1  T1  0  a  T1  0
Now draw FBD of P4 and P5 .
2T1  T2  0  T2  0
2T2  T3  0  T2  T3  0
So forces acting on P6 and P7 will be that of gravity and they be in free fall. Hence, acceleration of
each of them will be g downwards.
15&16.Before burning BC, the Free-Body diagrams are shown in the figure.
T2  T1  m2 g
kx  T2  m1 g
Where x is extension in the spring. Just after burning, T1 will become zero, but T2 will remain
same.
T2  m2 g  m2 a
a 1
 m  m2  g
m2
As T2 remains same, acceleration of block A will still remain zero.
17&18.Free-body diagrams
Constraint relation:
x1  x2  x3
a1  a2  a3
Equation of motion:
T  N  m1a1
N  m2 a1
m2 g  T  m2 a2
m2 g  T  m3a3
Using above equations, we can calculate the values.
CHEMISTRY
0.693 1
19. K1  sec
40
1.386
K0 
2  20
K1
 0.5M 1
K0
r  K 3  NOBr2   NO  -----------(1)
1 1
20.
K1  NOBr2   NOBr  K1 NO Br -----------(2)
  2   2 
K 2  NO  Br2  K2
Put (2) in (1)
K
r  K 3  1  NO  Br2  NO 
K2
r  K  NO   Br2 
2 1
21. for first order reaction t1/2 independent on initial conc.

Flask-I 1M   0.25M
2t1/2  8h  t1/2  4h
2
22. MnO4   Fe  H 2O 2  C2O4 2   8H  
 Mn 2  Fe3  4CO2  6 H 2O
d  n1  3
23.   2V  3
dv 4
dn1 3
At C p ,  0 v  3 v  2
nv 2
25. Second state is slow step
r  K 2 Cl CHCl3  ------------(1)
From equation (1)
1
K1 Cl 
2
 K 2 1
  Cl    1  Cl2  2 --------- (2)
K 1 Cl2   K 1 
Put (2) in (1)
1
 K  2 1
r  K 2  1  CHCl3  Cl2  2
1
 K 1 
1
 K CHCl3  Cl2  2
1
1
 4.8 103  2
K  1.3  102  3 
 1.2 10 
 2.6  102
32. 100ml hard water 
 20ml soap
106 ml hard water  20  104 ml soap
1ml soap  103 gCaCO3
2  105 ml soap  200gCaCO3
Total hardness  200 ppm
Permanent hardness  150 ppm
Temporary hardness  50 ppm
HCO3  2  0.5  61  61 ppm
lx My
33. 
ly Mx
d 40
 2
24  d 10
d  48  2d  d  16cm
1
34. Z11   2 n 2
2
1 8 RT
  2 n 2
2 M
Lesser the M, greater the Z11
A   B C
t 0 a 0 0
35.
t t ax x x
t  0 a a
Let us consides that normality of reagent is N
NV3
NV3  2  a  3  a  5a  a 
5
Initially
a NV2 V3
N  V1  a  V1   
N SN S
36. At time t
NV2   a  x   x  2  x  3
 a  4x
NV3
 4 x  NV2  a  NV2 
5
N  v2  v3 
N  v2  v1 
x
45
1  a  1 NV3 1
K  in    in 
t ax t 5  
NV3  N  v2  v3 
5  5 
1  4V3 
 in  
t  5V3  V2 
MATHS
37.
38.
39. Conceptual
40. f    cos 2 
We get 1  a  b  c  1
2 2 2
41.
a bc0
1  2 1  1
42. k4    k  k   k 2  k  
4  2  2
 1  1
  2k  1   2k  1    2k  1   2k  1  
2 2

 2  2
   
  2k   2k    2k   2k  
k 1 2 1 2 1
 2  2 
1 1
2k  1   2 k  1 
2

1
  1
2  2
1

8n  4n  1
2
2k   2k  4n 2  2n 
2
k 1
2 2
43. Conceptual
44. Use C2  C2  C1  2C3 then C1  C1  C2 take a 2  b 2  c2 common from first
column.
45.
1 1 1 1 1
46. We have a  n   1      ....  n
2 3 4 5 2 1
1 1 1 1 1 1 1 1  1 1 
 1              ....    ....   n 1  ....  n 
 2 3  4 5 6 7  8 15  2 2 1 
1 1 1 1 1 1 1 1  1 1 
 1         ....       ....    ....   n 1  ...  n 1 
2 2 4 4 4 8 8 8 2 2 
2 4 8 2n 1
 1     ....  n 1  1  1  ....  1  n
2 4 8 2
Thus, a(100) < 100
1 1 1 1 1 1 1  1 1  1
Also a  n   1             ...   n 1  ...  n  n
2 3 4 5 6 7 8  2 1 2  2
1 1 1 1 1 1  1 1  1
 1          ...    ....   n  ...  n   n
2 4 4 8 8 8 2 2  2
1 2 4 2n 1 1 1 1 1 1 1
 1     ...  n  n  1      ....    n
2 4 8 2 2 
2 2 
2 2 2
n times
n 1  1  n
 1  n  1  n 
2 2  2  2
 1  200
Thus, a  200   1  200    100,
 2  2
i.e. a  200   100
47. ax 2  x    0 has distinct real roots
 D  0  1  4 2  0
 1 1
    , 
 2 2
Also x1  x 2  1
  x1  x 2   1   x1  x 2   4x1x 2  1
2 2
1 1 1
  4  1  2  5 or  2 
 2
 5
 1   1 
    ,   ,
 5  5 
Combining (i) and (ii)
 1 1   1 1
S   ,  , 
 2 5   5 2
 1 1   1 1
 Subsets of S can be   ,   and  , 
 2 5  5 2
48. ,  are roots of x 2  x  1  0
  2    1  0, 2    1  0
  2    1and 2    1
Also a n  p n  qn
 a0  p  q
a1  p  p
a 2  p 2  q 2  p    1  q    1
  p   q    p  q   a 1  a 0
a 3  p 3  q3  p    1  q   1
  p 2  q2    p  q   a 2  a1
Proceeding in the same manner, we get

a12  a11  a10
a 4  a 3  a 2  a 2  a 2  2a 2  a1
 2a1  2a 0  a1  3a1  2a 0  3  p  q   2  p  q 
  1 5   1  5 
 3  p    q     2  p  q 
  2   2  
7 3
  p  q    p  q  5  28
2 2
pq4
 p  2q  12
k k
49. 
 k  1 k   k  1  k  1    k  1 k  1    k  1
4/3 4/3 4/3 4/3 2/3 4/3
 k  1 2/3
  k  1
2/3
 k  1  k  1

 k  1   k  1
2 2
4
 2/3
  k  1
2/3

1 n
 Sn    k  1   k  1
4 k 1
2/3
2/3 1
  n  1  n 2/3  1
4
2/3
  
 S999 
1
4
 2/3 2/3 1
1000    999   1  100  100  1  50
4

S26 
1
4
 2/3 2/3 1
 27    26   1   9  9  1 
4
17
4

50. Conceptual
 2r   r  1 2r  1     2r 3  r 2  r 
r 1
51. Vr 
2 2
n
1 n 3 n 3 n 
  Vr  2 r   r   r 
r 1 2  r 1 r 1 r 1 
1   n  n  1  n  n  1 2n  1 n  n  1 
2
 2     
2  2  6 2 

n  n  1  3n 2  n  2 
1

12
52. Tr  3r 2  2r  1
 Tr 1  3  r  1  2  r  1  1
2
 Q r  Tr 1  Tr  3  2r  1  2 1
 Q r  6r  5
 Q r 1  6  r  1  5
Common difference = Q r 1  Q r  6
53. Conceptual
54. Conceptual

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Sec: Incoming.Jr.IIT_*CO.

05-07-20_ Incoming.Jr.IIT _*CO SUPER CHAINA_Jee-Adv_CAT-1_SYLLABUS

A) 300 B) 450 C) 600 D) 750

acting between the two blocks is . (Surface below A and B is smooth)

a) bi  4b j B) bi  b j C) bi  2b j D) None of these

A) Acceleration of the system (painter+crate) is 5ms 2 is upward direction

B) Acceleration of the system (painter+crate) is 1ms 2 is upward direction

C) Tension in the rope is 1250 N

D) Tension in the rope is 1125 N

A) As 'x' is increased from zero, intensity continuously decreases

A) If a lens is used to obtain image, the lens must be converging

A) The focal length of the combination has the magnitude 7.5cm

A) Tension in the string connecting P1 , P2 and P3 is zero

B) Tension in the string connecting P1 , P2 and P3 is mg / 3

D) Acceleration of P6 is g downwards and that of P7 is g upwards

16. Just after burning the thread, what is the acceleration of m2 ?

Paragraph For Questions 17 and 18:

Given:( m1 = 1Kg, m2 = 2Kg and m3 = 3Kg)

A) 0.5mol 1dm 3 B) 1.0mol dm 3 C) 1.5mol dm 3 D) 2.0mol 1dm 3

A) rate  k  NO  Br2  B) rate  k  NO  Br2 

C) rate  k  NOBr  NO  D) rate  k  NO Br2 

A) 2.0 hrs B) 8.0 hrs C) 4.0 hrs D) 6.0 hrs

22. In dilute aqueous H 2 SO4 , the complex diaquadioxalate ferrate(II) ion

of [ H  ] to the rate of change of [ MnO4 ] is

k1  4.8  103 ; k1  1.2  103 ; k2  1.3  10 2 ; k3  2.1 10 2

A) Order of reaction is 3/2

B) Magnitude of overall rate of constant is 2.6  10 2

26. For the first order reaction 2 N 2O5 ( g ) 

A) The concentration of reactant decreases exponentially with time

B) The t1/ 2 of reaction decreases with increasing temperature.

C) Half life period is independent on initial concentration

D) The reaction processes to 99.6% completion in 8t1/ 2 duration.

B) CHCl3  Cl2  CCl4  HCl

28. Isotherms of carbon dioxide at various temperatures given below

Incorrect statement among the following is

C) Unit of B is cm3 and it is temperature dependent

A) Larger mean free path for X as compared to that of Y.

B) Larger mean free path for Y as compared to that of X.

Paragraph for Questions 35 and 36:

35. Which of the following relation is correct?

A) Initial volume of reagent = V3/3 B) Initial volume of reagent = V3/5

C) Initial volume of reagent = V2/3 D) Initial volume of reagent = V2/5

36. Rate constant ‘k’ for above reaction is –

ax2 x3  by2 y3  cz2 z3  ax3 x1  by3 y1  cz3 z1  ax1 x2  by1 y2  cz1 z2  f .

40. If a 2  b 2  c 2  1 then the value of the determinant

a 2   b 2  c 2  cos  ba 1  cos   ca 1  cos  

42. The value of  4  4  4

43. The value of determinant  b  p   b  q   b  r  is not equal to

Which of the following intervals is(are) a subset(s) of S ?

A) a12  a11  a10 B) p + 2q = 12 C) a12  a11  a10 D) p + 2q = 12

A) a, b, c are in A.P. B) a, b, c are in G.P.

C) a, b, c are in H.P. D)  x    is a factor of ax 2  2bx  c

Paragraph for Questions 53 and 54:

29 BD 30 ABCD 31 ABC 32 ABCD 33 C

Acceleration of A in horizontal direction = the acceleration of B= b rightwards

21. for first order reaction t1/2 independent on initial conc.

Proceeding in the same manner, we get

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