®

NORTH-WEST UNIVERSITY
YUNI BESITI YA BOKeNE-BOPHIRIMA
NOOR DWES·UNIVERSITEIT

Sakrekenaars/Calculators: Ja/Yes

Antwoordskrifte/
Answer scripts:
D
Benodigdhede vir hierdie vraestel/Requirements for this paper:
Multikeusekaarte (AS}/
Multi-choice cards (AS): D
Ander hulpmiddels/Other resources:

Presensiestrokies (lnvulvraestel)/
Attendance slips (Fill-in paper) : 0 Multikeusekaarte (A4)/
Multi-choice cards (A4): D
Rofwerkpapier/
Scrap paper: D Grafiekpapier/
Graph paper: D
Tipe Assessering/ Eksamen 1e geleentheid Kwalifikasie/ BSc
Type of Assessment: Exam 1st opportunity Qualification:
Vraestel/Paper 1
Modulekode/ CHEM311 Tydsduur/ 3 uur
Module code: Duration: 3 hour
Module beskrywing/ Analitiese Metodes Ill Maks/ 100
Module description: Max:
Eksaminator(e)/ Dr JHL Jordaan Datum/ 09/06/2017
Examiner(s): Date:
Dr A Falch Tyd/ 9:00
Time:
Moderator(s): Prof HCM Vosloo

lnhandiging van antwoordskrifte/Submission of answer scripts: Gewoon/Ordinary

Naam van student/ Universiteitsnommer/

Student name: University number:

Eksamenvoorskrifte I Examination instructions

1. Studente mag in die eerste ha~uur van 'n sessie tot die lokaal toegelaat 1. Students are allowed into the venue in the first half hour of a session, but no
word, maar geen ekstra tyd word toegestaan nie. extra time is granted.
2. Geen student word toegelaat om die lokaal te verlaat binne die eerste 2. No student is allowed to leave the venue before ha~ an hour Of the
halfwr van 'n eksamensessie nie. examination session has elapsed.
3. Studente bring sakke na lokaal op eie risiko, en moet dit voor in die lokaal 3. Students bring bags to the venue at own risk, and must put them in front Of
nee rs it. the room.
4. Studente mag nie seWone/elektroniese toestelle by hulle h~ en/Of hanteer 4. Students may not have cell phones/electronic devices with them and/or
nie. handle them.
5. Geen verversings word in 'n eksamenlokaal toegelaat nie. 5. No refreshments are allowed in the examination venue.
6. Studente mag nie die lokaal ver1aat om te gaan rook nie. 6. Students may not leave the room for a smoke break.
7. Skryf op beide kante van die bladsye. 7. Write on both sides of each page.
8. Skryf slegs in swart Of blou ink. 8. Write in black or blue ink only.
9. Geen bladsye mag uit die antwoordskrif verwyder word nie. 9. No pages may be removed from the answer scripts.
10. Studente mag nie ontoelaatbare materiaal by hulle M tydens 'n sessie nie, 10. Students may not have unauthorised material with them during a session,
bv. notas en/Of objekte wat notas bevat nie. e.g. notes and/or objects that contain notes.
11 . Geen items mag tydens die sessie geleen word nie. 11 . No items may be borrowed during the session.
12. Studente mag nie 'n ander student probeer help Of probeer om hulp te kry 12. Students may not attempt to assist another student, or attempt to obtain
nie. assistance.
13. Studente meet hul antwoordskrifte aan toesighouers oomandig voordat 13. Students must hand in their answer scrips to invigilators before they leave
hulle die lokaal verlaat. the venue.
14. Die presensiestrokie op die agterblad, wat ook as onderneming geld, meet 14. The attendance slip on the back cover that also serves as an undertaking,
voltooi en ingegee word. must be completed and handed in.

CHEM311 1/22
 Vraag 1 Question 1
Waarom sal minder absorpsiebande op 'n IR- Why will fewer absorption bands be observed on an
spektrum waargeneem word? IR-spectrum? [4]

Vraag 2 Question 2
Wat is die voordele van 'n FT-IR-spektrometer What is the advantages of an FT-IR spectrometer
teenoor 'n dispersiewe instrument? compaired to a dispersive instrument? [4]

CHEM311 2122
 Vraag 3 Question 3

3.1 Hoe sal u die spektrum meet van 'n 3. 1 How will you measure the spectrum of a
3.1 .1 lae kookpunt vloeistof met FT-IR? 3. 1. 1 low boiling point liquid with FT-IR? [1]

3.1 .2 oplossing met FT-IR? 3.1.2 solution with FT-IR? [1]

3.2 Hoekom het die oplossingtegniek in 3.1 .2 'n 3.2 Why does the solution technique in 3.1.2
beperkte toepassing? have a limited application? [1]

3.3 Waarom is water en alkohole nie geskikte 3.3 Why are water and alcohols not suitable
oplosmiddels vir FT-IR nie? solvents for FT-IR? [2]

Vraag 4 Question 4

'n ATR-eksperiment met 'n monster het 'n An A TR experiment with a sample has a
brekingsindeks van 1.03 by 'n golfgetal van 2000 refractive index of 1.03 at a wave number of 2000
cm-1· Die AgCI ATR-kristal beskik oar 'n cm·1. The AgCI A TR crystal has a refractive index
brekingsindeks van 2.00 by die golfgetal. of 2.00 at this wave number. Calculate the
Bereken die penetrasiediepte indien die penetration depth if the angle of incidence is 4S1.
invalshoek 45° is. [4]

CHEM311 3/22
 Vraag 5 Question 5

Skets met byskrifte 'n elektronsproei- Sketch with captions an electron spray ionization
ionisasiebron in massaspektrometrie. source in mass spectrometry. [5]

Vraag 6 Question 6

Gee die voor- en nadele van 'n El-bron van 'n Give the advantages and disadvatages of an El
massaspektrometer. source of a mass spectrometer. [6]

CHEM311 4/22
 Vraag 7 Question 7

Hoe kan u die effek van termiese ontbinding in 'n How can you minimize the effect of thermal
massaspektrometer El-bron verminder? decomposition in a mass spectrometer El
source? [2]

Vraag 8 Question 8

Bereken die resolusie nodig om die MS Calculate the resolution needed to resolve the MS
ioonpieke vir C3 H7 N3 + (M+ = 85.0641) en ion peaks for C3H7N/ (~ = 85.0641) en CsH90+
C5H90+ (M+ = 85.0653) te kan onderskei. (M+ = 85.0653). [2]

CHEM311 5122
 Vraag 9 Question 9

Bespreek magneetveldsluiting in KMR. Discuss locking of the magnetic field in NMR.

[6]

Vraag 10 Question 10

Verduidelik die verskil in die manier waarop Explain the difference in the way a continuous
kontinue golf- en 'n FT-KMR eksperiment wave and a FT-NMR experiment is performed.
uitgevoer word. [3]

CHEM311 6/22
 Vraag 11 Question 11

Verduidelik waarom die resonanssein van Explain why the resonance signal of benzene is
benseen by 7-8 ppm waargeneem word. observed at 7-8 ppm. [4]

Vraag 12 Question 12

Hoe sal u te werk gaan om gebruikte KMR- How will you go about cleaning used NMR
buise skoon te maak? tubes? [3]

CHEM311 7/22
 Vraag 13 Question 13

Lei die struktuur van die verbinding met Deduce the structure of the compound with
molekulere formule C9 H11 N02 van die gegewe molecular formula C9H 11 N0 2 from the given
spektra af. Toon alle afleidings en toekennings spectra. Show all deductions and assignments that
wat u maak. you make. [20]

CHEM311 8122
 Vraag 14 Question 14

Gee die drie algemene metodes om die Give the three general methods for improving the
resolusie in partisiechromatografie te verbeter. resolution in partition chromatography. [3]

Vraag 15 Question 15

Gee die voor- en nadele van 'n brekingsindeks- Give the advantages and disadvantages of a
detektor wat in HPLC gebruik word. refractive index detector used in HPLC. [5]

CHEM311 10/22
 Vraag 16 Question 16

In 'n omgekeerde fase kolom, is gevind dat 'n
opgeloste stof 'n retensietyd van 31 .3 min het en dat
'n nie teruggehoude spesie 0.48 min vir eluering
benodig wanneer die mobiele fase 30% (per
volume) metanol en 70% water was. Bereken (a) k
en (b) 'n water-metanol samestelling wat die waarde
van k tot 'n waarde van 5 sal bring.
In a reversed-phase column, a solute was found
to have a retention time of 31.3 min, and an
unretained species required 0. 48 min for elution
when the mobile phase was 30% (by volume)
methanol and 70% water. Calculate (a) k and (b)
a water-methanol composition that should bring
k to a value of 5. [6]

Gegee Given

Oplosmiddel Polariteitsindeks Solvent Polarity index

Meta noI 5.1 Methanol 5.1

Water 10.2 Water 10.2

CHEM311 11/22
 Vraag 17
2 2
'n 0.6025 g monster was opgelos en die Ca +
en Ba2+-ione teenwoordig was as BaC204•H20
en CaC 20 4•H20 gepresipiteer. Die oksalate was
dan met 'n TG- apparaat verhit om 'n residu te
lewer wat 0.5713 g in die gebied van 320 tot
400°C (BaC2 0 4 en CaC 2 04) en 0.4673 g in die
gebied van 580 tot 620°C (BaC03 en CaC03)
geweeg het. Bereken die persentasie Ca en Ba
in die monster.
CHEM311
Question 17
A 0. 6025 g sample was dissolved, and the Ca +
and Ba2+ ions present were precipitated as
BaC20 4•H20 and CaC204•H20. The oxalates were
then heated in a TG apparatus leaving a residue
that weighed 0.5713 gin the range of 320 to 400"C
(BaC20 4 and CaC20 4) and 0.4673 g in the range of
580 to 620"C (BaC03 and CaC03). Calculate the
percentage Ca and Ba in the sample. [7]
12/22
 Vraag 18 Question 18

Beskryf hoe u te werk sal gaan om 'n DSC Describe how you will go about performing a
eksperiment uit te voer. DSC experiment. (6)

Vraag 19 Question 19

Verduidelik hoe u te werk sal gaan om · die Explain how you will go about calibrating the
temperatuuras van 'n TGA-instrument te temperature axis of a TGA instrument. (5)

kalibreer.

TOTAAUTOTAL: 100

CHEM311 13/22