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Material Safety Data Sheet

DOC NO.: 1/3


Version:A/2 Last update:2014-03-03

COSPHAGUAR 14S

1. IDENTIFICATION OF THE PRODUCT AND OF THE COMPANY


1.1 INCI Name: Guar Hydroxypropyltrimonium Chloride
1.2 CAS No: 65497-29-2
1.3 Chemical Classification: Quaternary Guar gum
1.4 Dangerous Goods Classification: Not assessed.
1.5 Company Details:
Manufacture/Supplier:
Address: March 2014

1.6 The date of taking effect:


2. COMPOSITION/INFORMATION ON INGREDIENTS
2.1 Chemical characterization: Compound
2.2 Physical Form: Powder
2.3 Color: Little yellow
2.4 Use: Cosmetics additive
2.5 Hazardous Ingredients:
Chemical Name CAS No %(w/w) Classification
Guar,2-hydroxy 3- 65497-29-2 85-90 N; R50/53
(trimethylamino) propyl ether
chloride
3. HAZARDS IDENTIFICATION
3.1 Hazard Classification: Dangerous for the environment.
3.2 Hazard Information: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
3.3 Possible Health Effects:
Acute
Eyes: May cause eye injury which may persist for several days
Skin: No significant irritation expected from a single exposure.
Inhalation: Some individuals may develop a respiratory allergenic response.
Ingestion: Practically non-toxic.
Chronic
Skin: Repeated or prolonged exposure may cause irritation.
Inhalation: Inhaling long will injure breath system.
Ingestion: Repeated ingestion or swallowing large amounts may injure internally.
3.4 Additional risk and advice: Risk of dust explosion.
4. FIRST AID MEASURES
4.1 Eyes: Rinse with plenty of water. Remove contact lenses. Protect unharmed eye. Keep eye wide
open while rinsing. If eye irritation persists, consult a specialist.
4.2 Skin: Remove contaminated clothing. Wash the skin immediately with soap and water.
4.3 Inhalation: Remove to fresh air. Keep patient warm and at rest. Rinse nose and mouth with water.
4.4 Ingestion: Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth
to an unconscious person. If symptoms persist, call a physician.
4.5 Comments: Treat according to person’s condition and specifics of exposure.
4.6 Note to physicians: Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Ignition temperature: 199 °C.
5.2 Flash point: Not applicable.
5.3 Extinguishing Media: Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment.
5.4 Special Fire Fighting Firefighters should be equipped with self-contained breathing apparatus to protect against
Procedures: potentially toxic and irritating fumes.
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COSPHAGUAR 14S

5.5 Specific hazards during fire Do not allow run-off from fire fighting to enter drains or water courses. Risks of ignition
fighting: followed by flame propagation or secondary explosions shall be prevented by avoiding
accumulation of dust, e.g. on floors and ledges.
5.6 Further information: Collect contaminated fire extinguishing water separately. This must not be discharged into
drains. Fire residues and contaminated fire extinguishing water must be disposed of in
accordance with local regulations.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal Precaution: Avoid eye contact. Avoid dust formation. Ensure adequate ventilation.
6.2 Environmental Do not flush into surface water or sanitary sewer system. If the product contaminates rivers
Precautions: and lakes or drains inform respective authorities.
6.3 Spill and Leak Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable,
Procedures: closed containers for disposal.
7. HANDLING AND STORAGE
7.1 Handling: This product may present a dust explosion hazard. It is recommended that all dust control
equipment and material transport system involved in handling of this product contain
explosion relief vents or explosion suppression system or an oxygen deficient environment.
In electrically bonded and grounded. Keep away from heat/sparks/open flames/hot surfaces.
No smoking. No sparking tools should be used. Dispose of rinse water in accordance with
local and national regulations.
7.2 Storage Conditions: Store in dry area .Store in closed containers at room temperature.
7.3 Unsuitable Packaging None established.
Materials:
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 Industrial Hygiene
Standards
Components Value Exposure Limits
Dust TWA (Time Weighted 4 mg/m3
Average)
8.2 Engineering Controls: Provide appropriate exhaust ventilation at places where dust is formed.
8.3 Personal Protective
Respiratory protection: Half mask with a particle filter P2 (EN 143).
Eye protection: Wear safety glasses with side shields. Protect against dust and particulates.
Hand protection: For prolonged or repeated contact use protective gloves. Protective gloves complying with
EN 374.
Clothing Requirements: Protective suit. Choose body protection according to the amount and concentration of the
dangerous substance at the work place.
Change/Removal Of Remove contaminated clothing and launder before reuse.
Clothing:
Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Wash hands before
breaks and at the end of workday.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Physical Form: Powder
9.2 Color: Little yellow
9.3 Odor: Negligible
9.4 pH(1%): 9.0-11.0
9.5 Solubility in water: Soluble in water
9.6 Oxidizing properties: Not applicable
9.7 Pile up specific gravity: 0.63(25℃)
9.8 Loss on Drying(105℃/2h): ≤12.0%
The above information is not intended for use in preparing product specifications. Contact Tinci before writing specifications.
10. STABILITY AND REACTIVITY
10.1 Stability: Stable.
10.2 Stability Detail: Conditions to be avoided: dusting conditions, extreme heats, open flames, sparks.
Materials/Chemicals to be avoided: strong oxidizing agents
11. TOXICOLOGICAL INFORMATION
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Version:A/2 Last update:2014-03-03

COSPHAGUAR 14S

11.1 Possible Health Effects: Product dust may be irritating to eyes, skin and respiratory system.
11.2 Carcinogenic Effects: None.
11.3 Other Health Hazard Guar gum: May cause allergic respiratory reaction.
Information:
12. ECOLOGICAL INFORMATION
12.1 Ecotoxicity effects: An environmental hazard cannot be excluded in the event of unprofessional handling or
disposal. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
12.2 Biodegradability: Not readily biodegradable.
13. DISPOSAL CONSIDERATIONS
13.1 Product Disposal: The product should not be allowed to enter drains, water courses or the soil. Do not
contaminate ponds, waterways or ditches with chemical or used container.
Hazardous waste
13.2 Packaging Disposal: Empty remaining contents. Dispose of as unused product.
14. TRANSPORT INFORMATION
14.1 Road and Rail Transport: Environmentally hazardous substance, solid, n.o.s.
14.2 Sea Transport(IMDG): Environmentally hazardous substance, solid, n.o.s.
14.3 Air Transport(ICAO): Environmentally hazardous substance, solid, n.o.s.
15. REGULATORY INFORMATION
15.1 Labelling according to EC Directives1999/45/EC
Symbol(s):

N, Dangerous for the environment.


R-phrase(s): R50/53, Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
S-phrase(s): S57, Use appropriate container to avoid environmental contamination.
S60, This material and its container must be disposed of as hazardous waste.
15.2 CH INV: n (Negative listing)
The formulation contains substances listed on the Swiss Inventory
DSL: q (quantity restricted)
This product contains the following components listed on the Canadian NDSL list. All other
components are on the Canadian DSL list.
AICS: n (Negative listing)
Not in compliance with the inventory
ENCS: n (Negative listing)
Not in compliance with the inventory
KECI: y (positive listing)
On the inventory, or in compliance with the inventory
IECSC: y (positive listing)
On the inventory, or in compliance with the inventory
PICCS: n (Negative listing)
Not in compliance with the inventory
TSCA: y (positive listing)
On TSCA Inventory
16. OTHER INFORMATION

This information is offered in good faith as typical values and not as a product specification. No warranty, expressed or implied, is
hereby made. The recommended industrial hygiene and safe handling procedures are believed to generally applicable. However,
each user should review these recommendations in the specific context of the intended use and determine whether they are
appropriate.

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