Professional Documents
Culture Documents
Eldridge 1967 Water Vapor Absorption of Visible and Near Infrared
Eldridge 1967 Water Vapor Absorption of Visible and Near Infrared
Infrared Radiation
Ralph G. Eldridge
Water vapor error function absorption coefficientsfor visible and near ir radiation have been recalculated
from experimental transmission data. The error function absorption coefficients and the resulting
transmissions as a function of precipitable water vapor are tabulated for wavelengths from 0.2 , to 1.3 ,u.
Comparisons are made between computed and measured spectral transmittances.
--
T = 1 - erf[(13/2)(7W)'/], (1)
where T is the transmittance through a 1-km path, w is 0.5
0.2 04 0.6 0.8 1.0 i.2 1.4
the water vapor content, and f is the error function ab- WAVELENGTH (MICRONS)
sorption coefficient. The water vapor content is ex-
pressed in terms of the depth of precipitable water vapor Fig. 2. Transmissions resulting from Rayleigh scattering, ozone
in centimeters in the optical path. and water vapor absorption, and the best estimate transmission
through 1 cm of precipitable water vapor. inferred (Fig. 1).
The resulting error function absorption coefficients ozoneabsorption. - - - Rayleighscattering. -
are tabulated in Table I. These coefficients are used to - - best
estimate.
compute spectral transmissions (see Table II) as a func-
tion of the precipitable water vapor in an optical path
of 1 km.
Table I. Water Vapor Error Function Absorption Coefficient
Computed Spectral Transmissions as a Function of Wavelength (Microns)
Spectral attenuation through realistic atmospheres re- X (,u) ,(cm '/,) X( 0(cm-l
sults from scattering by aerosols and absorption by 0.20 0.000 0.70 0.024
atmospheric gases. In the spectral region from 0. 5 -A 0.25 0.000 0.75 0.050
to 1. 3-bt wavelength, the major gaseous absorber (at 0.30 0.000 0.80 0.056
sea level) is water vapor; there is no significant carbon 0.35 0.003 0.85 0.018
dioxide or ozone absorption. Therefore, the propi- 0.40 0.009 0.90 0.016
tiousness of the revised water vapor error function ab- 0.45 0.016 0.95 0.19
sorption coefficients may be indicated by employing 0.50 0.022 1.0 0.028
them in computations of spectral transmissions and 0.55 0.022 1.1 0.13
comparing the results with the experimental trans- 0.60 0.020 1.2 0.14
missions of Taylor and Yates.6 0.65 0.020 1.3 0.19
In order to compute
Precipitable Wavelength ()
water vapor
(cm) 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65
0.01 1.000 1.000 1.000 1.000 0.999 0.998 0.998 0.998 0.998 0.998
0.02 + + 1.000 0.999 0.998 0.997 0.997 0.997 0.997
0.05 I l 0.999 0.998 0.996 0.995 0.995 0.996 0.996
100.0 1.000 1.000 1.000 0.971 0.911 0.841 0.783 0.783 0.803 0.803
0.01 0.998 0.995 0.994 0.998 0.998 0.981 0.997 0.987 0.986 0.981
0.02 0.997 0.993 0.992 0.997 0.998 0.974 0.996 0.982 0.981 0.973
0.05 0.995 0.989 0.987 0.996 0.996 0.958 0.994 0.972 0.970 0.957
0.1 0.992 0.984 0.982 0.994 0.995 0.941 0.991 0.960 0.957 0.939
0.2 0.989 0.978 0.975 0.992 0.993 0.917 0.987 0.943 0.939 0.914
0.5 0.983 0.964 0.960 0.987 0.989 0.869 0.980 0.911 0.904 0.864
1.0 0.976 0.950 0.944 0.982 0.984 0.816 0.972 0.874 0.865 0.810
2.0 0.966 0.929 0.920 0.974 0.977 0.742 0.960 0.823 0.811 0.733
5.0 0.946 0.888 0.874 0.960 0.964 0.603 0.937 0.724 0.705 0.589
10.0 0.924 0.843 0.824 0.943 0.949 0.461 0.911 0.617 0.592 0.445
20.0 0.892 0.779 0.753 0.919 0.928 0.298 0.875 0.478 0.449 0.281
50.0 0.832 0.656 0.618 0.873 0.887 0.100 0.805 0.263 0.231 0.088
100.0 0.764 0.530 0.479 0.822 0.841 0.020 0.727 0.114 0.090 0.016
2
in nature, the resulting computed spectral transmissions longer than 0.4 A. Curcio et al.1 indicate that the
should encompass the measured spectral transmissions. spectral region below 0.54 A is free of observable ab-
The meteorological/optical parameters observed by sorption structure down to 0.35 u, except for a few weak
Taylor and Yates6 during their transmission measure- absorption bands. Their statement may be considered
ments are presented in metric units in Table III. The as a justification for the apparent absorption between
three continental and the three maritime model aerosol 0.4 A and 0.54 A, but a more reasonable assumption
distributions are shown in Fig. 3. Because the resolu- might be that the apparent absorption in this spectral
tion of the computed spectral transmissions is con- region is somewhat overestimated. Without confirm-
siderably less than that of the measured spectral trans- ing or negating evidence,the best estimate transmission
missions, the latter must be degraded to approximately still appears reasonable at this time.
the resolution of the computations. The solid, heavy
curves of Fig. 4 represent the degraded spectral trans-
mission depicted by the solid, light curves. These6 Table IlIl. Meteorological/Optical Parameters
latter curves have been copied from Taylor and Yates. Pre-
The data points with the dashed curves represent com- cipi-
Trans-
puted transmissions for continental or maritime hazes mission Temper- Humid- table
as indicated, and these can be compared with the ex- designa- Path ature ity Visibility water
perimental transmissions. tion (km) (0 C) (%) (km) (cm)
Therefore, the experimental window transmissions are Fig. 4. Comparison of computed and measured spectral trans-
100%. It is interesting to note that Taylor and Yates missions. measured transmission. - degraded resolu-
indicate an uncertainty of measurements of about 3% tion. - - - - continental haze. - - X - - maritime haze.