Clapeyron Equation

(Eqn. 5.6-6)

VAPOR-LIQUID EQUILIBRIUM

Clausisus-Clapeyron Equation
(Eqns. 5.6-7, 5.6-9, 5.6-10)

∆𝐻 is constant
(Eqns. 5.6-12, 5.6-13)

∆𝐻 varies with
Temperature,
∆𝐻 expression
(Eqns. 5.6-14-5.6-15)

∆𝐻 varies with
Temperature,
∆𝐶 is constant
(Eqns. 5.6-16-5.6-17)
Antoine equation
(Eqn. 5.6-18)
SOLID-LIQUID EQUILIBRIUM

Clapeyron Equation
(Eqns. 5.6-19, 5.6-20, 5.6-21)

∆𝐻 is constant
(Eqns. 5.6-22, 5.6-23)
 SOLID-LIQUID EQUILIBRIUM-cont.

∆𝐻 varies with
Temperature,
∆𝐻 expression
(Eqns. 5.6-24-5.6-25)

∆𝐻 varies with
Temperature,
∆𝐶 is constant
(Eqns. 5.6-26-5.6-27)
SOLID-VAPOR EQUILIBRIUM

Clapeyron Equation
(Eqns. 5.6-28, 5.6-29, 5.6-30)

∆𝐻 is constant
(Eqns. 5.6-31, 5.6-32, 5.6-33)

C = Integration constant,

Tt = Triple point temperature, Pt = Triple point pressure