Experiment 1:

Data : Part II: Titration with Acetic Acid

Sample No. First Reading Final Reading V(acetic acid) (ml)
1 2.4 3.6 1.2
2 3.6 5.4 1.8
3 5.4 7.1 1.7
4 7.1 9.79 2.69
5 9.79 13.2 3.41
6 13.2 16.2 3
7 16.2 19.92 3.72
8 19.92 25 5.08
9 11.28 17.4 6.12
10 0.00 4.22 4.22
11 4.22 11.8 7.58

Calculations : Sample # V H2O (ml) Vbu Ac (ml) V CH3COOH (ml)

Density H2O (g/ml) 1.00 1 0.25 4.75 1.20
Density butyl acetate (g/ml) 0.88 2 0.50 4.50 1.80
Density CH3COOH(g/ml) 1.05 3 1.00 4.00 1.70
4 1.50 3.50 2.69
5 2.00 3.00 3.41
6 2.50 2.50 3.00
7 3.00 2.00 3.72
8 3.50 1.50 5.08
9 4.00 1.00 6.12
10 4.50 0.50 4.22
11 4.75 0.25 7.58

For the tie Lines :

Sample # Vbu Ac (ml) V H2O (ml) V CH3COOH (ml)
1 7 11 2
2 7 9 4

For the aqueous layer: Density of aqueous layer=

V NaOH (ml)
Sample # V aqueous mass For 2 ml
1 13 13.26 14.4
2 12.3 12.5 18.3

For the organic layer: Density of organic layer=

V NaOH (ml)
Sample # V organic mass For 5 ml
1 6.2 5.70 17
2 7.5 6.9 26.4
 Part III: Separate the two layers Part III(B):
sample 1:
Volume of organic layer (ml) 6.2
Volume of aqueous layer(ml) 13

sample 2:
Volume of organic layer (ml) 7.5
Volume of aqueous layer(ml) 12.3

M H2O (g) Mbu Ac (g) MCH3COOH(g) Total mass % H2O % Bu Ac % CH3COOH

0.25 4.18 1.26 5.69 4.39 73.46 22.14
0.50 3.96 1.89 6.35 7.87 62.36 29.76
1.00 3.52 1.79 6.31 15.86 55.83 28.31
1.50 3.08 2.82 7.40 20.26 41.60 38.15
2.00 2.64 3.58 8.22 24.33 32.11 43.56
2.50 2.20 3.15 7.85 31.85 28.03 40.13
3.00 1.76 3.91 8.67 34.62 20.31 45.07
3.50 1.32 5.33 10.15 34.47 13.00 52.53
4.00 0.88 6.43 11.31 35.38 7.78 56.84
4.50 0.44 4.43 9.37 48.02 4.70 47.28
4.75 0.22 7.96 12.93 36.74 1.70 61.56

M H2O (g) Mbu Ac (g) MCH3COOH(g) Total mass % H2O % Bu Ac % CH3COOH

11 6.16 2.1 19.26 57.11 10.79 10.90
9 6.16 4.2 19.36 46.49 31.82 21.69

1.02 g/ml
V NaOH (ml)
For the whole layer V CH3COOH m:CH3COOH %CH3COOH
93.6 2.52 2.65 19.98
112.5 3.0 3.2 25.4

0.92 g/ml
V NaOH (ml)
For the whole layer V CH3COOH m:CH3COOH %CH3COOH
21.08 0.57 0.60 10.46
39.6 1.07 1.12 16.24
 Titration with NaOH (0.5M)
sample 1:
aqueous VNaOH (ml) 14.4
Organic VNaOH (ml) 17

sample 2:
aqueous VNaOH (ml) 18.3
Organic VNaOH (ml) 26.4

1 ml Acetic acid
VNaOH (ml) 37.1