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Physics
Section A 4 3
(1) rad/s (2) rad/s
5 4
Q. 1. The magnitude of vectors A , B and C are 8
(3) 3 rad/s (4) 1 rad/s
respectively 12, 5 and 13 units
and A+B = C , 3
then the angle between A and is :
π π Q. 6. A pendulum of mass m and length is
(1) 0 (2) π (3) (4) suspended from the ceiling of a trolley
2 4
Q. 2. A wave is represented by y = a sin (At – Bx + C) which has a constant acceleration a in the
where A, B, C are constants and t is in horizontal direction as shown in figure.
seconds and x is in metre. The Dimensions Work done by the tension is (In the frame of
of A, B, C are : trolley) :
(1) [T –1], [L], [M0L0T0]
(2) [T –1], [L–1], [M0L0T0]
m a
(3) [T], [L], [M]
(4) [T –1], [L–1], [M–1]
Q. 3. The Ratio of SI unit to CGS unit of Planck’s
Constant is—
(1) 107 (2) 10–5 (3) 103 (4) 105
Q. 4. In a legend the hero-kid kicked a toy pig so mg
that it is projected with a speed greater than (1) [cos(tan –1 ( a / g ) − 1]
tan θ
that of its cry. If the weight of the toy pig is
assumed to be 5 kg and the time of contact mg
(2) [sin(tan –1 ( a / g ) − 1]
0.01 s, the force with which the hero-kid tan θ
kicked him was (Speed of cry = 330 m/s) : mg
(1) 5 × 10–2 N (2) 2 × 105 N (3) [sin(tan −1 ( a / g ) − 1]
cos θ
5
(3) 1.65 × 10 N (4) 1.65 × 103 N mg
Q. 5. A racing car is travelling along a track at a (4) [cos(tan –1 ( a / g ) − 1]
cos θ
constant speed of 40 m/s. A T.V. camera man
Q. 7. Figure shows a small wheel fixed coaxially
is recording the event from a distance of
on a bigger one of double the radius. The
30 m directly away from the track as shown
system rotates about the common axis. The
in figure. In order to keep the car under view strings supporting A and B do not slip on the
in the position shown, the angular speed wheels. If x and y be the distances travelled
with which the camera should be rotated, is : by A and B in the same time interval, then :
Track
car
40 m/s
30 m
A
30° B
(1) x = 2y (2) x = y
TV Camera
(3) y = 2x (4) None of these
MOCK TEST PAPER-2 25
Q. 8. The velocities of a particle in SHM at positions achromatic combination with a crown glass
x1 and x2 are v1 and v2, respectively, its time prism of refracting angle 4° :
period will be (1) 2° (2) 4° (3) 5° (4) 6°
(1) 2π
(v 2
1 − v22 )
(2) 2π
(x 2
1 )
+ x 22
Q. 14. In young's double slit experiment
d
= 10 −4
(x 2
2 − x12 ) (v 2
2 −v )2
1
D
(d = distance between slits, D = distance
(x 2
1 − x 22 ) (x 2
1 +x )2
2
of screen from the slits). At a point P on
the screen resulting intensity is equal to
(3) 2π (4) 2π
(v 2
2 − v12 ) (v 2
2 +v )2
1 the intensity due to individual slit l0. Then
the distance of point P from the central
Q. 9. One cubic plate, having 15 cm side, floats
maximum is (λ = 6000 Å)
on water surface. If surface tension of water
is 60 dyne/cm. To lift this plate from water, (1) 2 mm (2) 1 mm
Find the extra force required against weight. (3) 0.5 mm (4) 4 mm
(1) 3600 dyne (2) 1800 dyne Q. 15. The mobility of electrons in a semiconductor
(3) 900 dyne (4) 7200 dyne chip of length 10 cm is observed to be 1000
Q. 10. The number density fo electrons in Copper cm2/Vs. When a potential difference of 2v is
applied across it. What is the drift speed of
is 8.5 × 1028 m–3. Find the current flowing
electrons.
through copper wire of length 0.2 m, are a
of cross section 1 mm2, when connected to a (1) 1 cm/s (2) 5 cm/s
battery of 4V. Given that electron mobility = (3) 2 m/s (4) 1000 m/s
4.5 × 10–6 m2v–1s–1. Q. 16. The energy levels of a certain atom for first,
(1) 1.3 A (2) 1.22 A second and third levels are E, 4E/3 and 2E,
(3) 2.11 A (4) 1.12 A respectively. A photon of wavelength λ is
emitted for a transition 3 → 1. What will be the
Q. 11. Two coherent sources of different intensities
wavelength of emission for transition 2 → 1 ?
send waves which interfere. The ratio
of maximum intensity to the minimum λ 4λ 3λ
(1) (2) (3) (4) 3λ
intensity is 25. The intensities of the sources 3 3 4
are in the ratio : Q. 17. The graph of ln R
versus ln A (R = radius
R 0
(1) 25 : 1 (2) 5 : 1 of a nucleus and A = its mass number) is :
(3) 9 : 4 (4) 625 : 1 (1) a straight line (2) a parabola
Q. 12. A spherical surface of radius R separates two (3) an ellipse (4) none of these
medium of refractive indices m1 and m2, as
Q. 18. A square coil ABCD with its plane vertical
shown in figure. Where should an object be
is released from rest in a horizontal
placed in the medium 1 so that a real image
is formed in medium 2 at the same distance ? uniform magnetic field B of length 2L. The
acceleration of the coil is :
A C
µ1 µ2
L
O P I
B D
B
× × × ×
x x
2L × × × ×
µ − µ1 µ 2 + µ1
(1) 2 R (2) R
µ 2 + µ 1 µ 2 − µ 1 × × × ×
(1) less than g for all the time till the loop
µ + µ1 µ2 crosses the magnetic field completely
(3) 2 R (4) R
µ 2 µ 2 + µ 1 (2) less than g when it enters the field and
greater than g when it comes out of the
Q. 13. The dispersive powers of flint glass and field
crown glass are 0.053 and 0.034, respectively (3) g all the time
and their mean refractive indices are 1.68 (4) less than g when it enters and comes
and 1.53 for white light. Calculate the angle out of the field but equal to g when it is
of the flint glass prism required to form an within the field
26
Q.19. We have three identical perfectly black Q. 26. A copper ball of density 8.6 g/cm3, 1 cm
plates. The temperatures of first and third in diameter is immersed in oil of density
plate is T and 3T. What is the temperature of 0.8 g/cm3. The charge in mC on the ball, if it
second plate if system is in equilibrium ? remains just suspended in an electric field
of intensity 3600 V/m acting in upward
(1) 411/4 T (2) 511/4 T direction is..... mC.
(3) 21/4 T (4) 371/4 T Q. 27. In a YDSE experiment two slits S1 and S2
Q. 20. If a baseball player can throw a ball at have separation of d = 2 mm. The distance
of the screen is D = 8/5 m. Source S starts
maximum distance = d over a ground, the
moving from a very large distance towards
maximum vertical height to which he can
S2 perpendicular to S1S2 as shown in figure.
throw it, will be (Ball has same initial speed
The wavelength of monochromatic light is
in each case) :
d 500 nm. The number of maximas observed
(1) (2) d (3) 2d (4) on the screen at point P as the source moves
2 4
towards S2 is 3995 + n. The value of n is.....
Section B
Q. 21. A ball falls from a height of 1 m on a ground S1
d
and it loses half its kinetic energy when it S P
S2 D
hits the ground. What would be the total
distance covered by the ball after sufficiently
long time ?
Q. 22. Consider a gravity-free hall in which an Q. 28. A leaky parallel plate capacitor is filled
experimenter of mass 50 kg is resting on a
completely with a material having dielectric
5 kg pillow, 8 ft above the floor of the hall.
constant K = 5 and electric conductivity
He pushes the pillow down so that it starts
falling at a speed of 8 ft/s. The pillow makes s = 7.4 × 10–12 W–1 m–1. If the charge on the
a perfectly elastic collision with the floor, plate at the instant t = 0 is q = 8.85 mC, then
rebounds and reaches the experimenter’s the leakage current at the instant t = 12 s
head. The time elapsed in the process is......s is………× 10–1 µA.
Q. 23. A battery of EMF 10V sets up a current of Q. 29. Potential difference between the points
1A when connected across a resistor of 8Ω.
A and B in the circuit shown is 16 V, then
If the resistor is shunted by another 8Ω
resistor, what would be the current in the potential difference across 2Ω resistor is
circuit ? (in A) .….V. volt. (VA > VB)
Q. 24. A liquid flows out drop by drop from a vessel
9V 1Ω 3V
through a vertical tube with an internal 4Ω 1Ω 3Ω
diameter of 2 mm, then the total number of A B
drops that flows out during 10 grams of the
liquid flow out..... [Assume that the diameter 2Ω
of the neck of a drop at the moment it breaks
away is equal to the internal diameter of Q. 30. The half-value thickness of an absorber is
tube and surface tension is 0.02 N/m]. defined as the thickness that will reduce
Q. 25. A cylinder of area 300 cm2 and length 10 cm exponentially the intensity of a beam of
made of material of specific gravity 0.8 is particles by a factor of 2. The half-value
floated in water with its axis vertical. It is then thickness in (mm) for lead assuming X-ray
pushed downward, so as to be just immersed. beam of wavelength 20 pm, m = 50 cm–1
The work done by the agent who pushes the for X-rays in lead at wavelength l = 20 pm,
cylinder into the water is.....J. is..... mm
MOCK TEST PAPER-2 27
Chemistry
CH3 OH 2 OΘ
(4) CH O
3
(1)
Me Me
Q. 41. H OH –
OH + HO H
II (2)
Et Et
B
Me Me
OH – (3)
H Cl HO H
I
Et Et
A
The reaction involved in steps I and II are : (4)
(1) Both SN1 (2) Both SN2
(3) I SN1, II SN2 (4) I SN2, II SN1
MOCK TEST PAPER-2 29
Q. 46. Total number of possible stereoisomers of Consider the above reaction, the compound
dimethyl cyclopentane is ‘A’ is :
(1) 10 (2) 5 (3) 6 (4) 4 O
Q. 47. Given below are two statements : one is
labelled as Assertion (A) and the other is (1) Cl
labelled as Reason (R)
Assertion (A) : Aniline on nitration yields Cl CH3
ortho, meta & para nitro derivatives of
O
aniline.
Reason (R) : Nitrating mixture is a strong Cl
(2) Cl
acidic mixture.
In the light of the above statements, choose
the correct answer from the options given H 3C
below
O
(1) Both A and R are true and R is the correct
explanation of A.
Cl
(2) Both A and R are true but R is NOT the (3)
correct explanation of A.
Cl
(3) A is true but R is false.
(4) A is false but R is true. CH3
OH (1) I /NaHCO O
2 3
Q. 48.
(2) Pyridine,
O H
Find out major product for the above (4)
reaction Cl
O CH2Cl
(1)
O Q. 50. Glycosidic linkage between C-1 of α-glucose
I and C-2 of β-fructose is found in
CO2H (1) maltose (2) sucrose
(2) (3) lactose (4) amylose
I
Section B
(3) O Q. 51. A drop of solution (volume 0.05 mL) contains
O 3.0 × 10–6 mole of H+. If the rate constant
of disappearance of H+ is 1.0 × 107 mole
L–1s–1. It would take for H+ in drop to
(4) O
disappear in..... × 10–9s
O Q. 52. The amount of C-14 isotope in a piece of wood
is found to be 1/16th of its amount present in a
C fresh piece of wood. The age of wood, half-life
NH3 period of C-14 is 5770 years, is.....years
Q. 49. ‘A’ (C8H6Cl2O) C8H8CNH2
Q. 53. The overall formation constant for the
reaction of 6 mol of CN– with Cobalt(II) is
Br2 NaOH 1 × 1019. The formation constant for the
reaction of 6 mol of CN– with Cobalt(III)
CH3 is ..... × 1063. Given that,
Co(CN)–3 6 + e
–1
Co(CN)6–4
Cl
E°Rp = 0.83 V
Co+3 + e–1 Co+2
H 2N E°Rp = 1.82 V
30
Mathematics
Q. 72. If the line y – 3x + 3 = 0 cuts the parabola Q. 79. The number of positive integers satisfying
y2 = x + 2 at A and B, then PA. PB is equal to the inequality n + 1Cn – 2 – n + 1Cn – 1≤ 100 is
(where co-ordinates of P are ( 3 , 0)) (1) Nine (2) Eight (3) Five (4) Ten
(1)
4 ( 3 +2 ) (2)
(
4 2− 3 ) Q. 80. If the orthocentre of the triangle formed by
(1, 3) (4, –5) and (a, b) is (2, 4), Then the value
3 3
of 33b + 22a is
(3) 2 3 (4)
2 ( 3 +2 ) (1) 0 (2) 1 (3) 1 (4) 3
3 11 11
Q. 73. The tangent and the normal at a point P
x2 y2 Section B
on an ellipse 2 + 2 = 1 meet its major
a b
1
axis at T and T’ such that TT’ = a, then
e2 cos2 θ + cos θ (where e is eccentricity of
=
Q. 81. Given fn ( x )
n
( )
sin n x + cosn x for n = 1,
are co-prime and s is semiperimeter of ∆ABC, Q. 90. Let |z| = |z – 3| = |z – 4i|, then the
then the value of (p – q) is..... value|2z| is.....
34
Physics
So, the applied force should by greater than
1. (3) The Vectors A , B and C can be represented
calculated value, so correct option will be (2)
as shown in figure.
i.e., 2 × 105 N.
Car 40 m/s v
5. (4)
C
13 B
5 30 m
12 θ
A
T.V. camera
π
Clearly angle between A and B is . We have
2 x d x
d
2. (2) y = asin (At – Bx + C) tan q = ;
30 dt
[tan θ] = dt 30
Angle has no dimensions so d dθ 1 dx
( tan θ ) ⋅ =
Dimensions of At = [M0L0T0] dθ dt 30 dt
⇒ A = [T–1] dθ 1
sec2 q
= × 40
Dimensions of Bx = [M L T ]0 0 0 dt 30
dθ 4
⇒ B = [L–1] ⇒ =
dt 3 sec 2 θ
Dimensions of C = [M0L0T0] At the given instant, q = 30°
dθ 4
Energy ⇒ = cos2 30°
3. (1) h= dt 3
c 2
4 4
λ = × 3 = × 3 = 1 rad s-1
3 3
Where c is speed of light 2 4
h = Planks Constant or the angular speed with which camera
l = Wave length should be rotated = 1 rad/s
M1 L2 T –2 6. (4)
h= = M1 L2 T-1
æ LT –1 ö÷
çç ÷
çç L ÷÷
⇒ è ø
⇒ h = kg m2s–1
⇒ = (103 g) (102 cm)2 s–1
⇒ h = 107 g cm2 s–1
Hence, the required ratio will be 107 T sinq = ma
T cosq = mg...(1)
4. (2) Given : m = 5 kg, v > 330 m/s, Dt = 0.01 s
a
F. Dt = Dp = mDv = 5 kg × 330 m/s \ tanq =
g
Dp = 1650 kg m/s dW = – T sinq.ldq
tan –1 ( a / g )
F=
∆
=
1650
= 1650 × 100
W = ∫0 −T sin θ.ldθ
∆ 0.01
= Tl [ cos θ]0
tan –1 ( a / g )
5
= 1.65 × 10 N
SOLUTIONS MOCK TEST PAPER-2 35
v22 − v12
⇒ w2 = x x
x12 − x 22
m1 = Refractive index of object medium
v22 − v12
2 m2 = Refractive index of image medium
2π
⇒ = x 2 − x 2 R = Radius of curvature
T 1 2 µ2 µ µ − µ1
– 1 = 2
x12 − x 22 v u R
T2
⇒ = µ2 m1 µ 2 − µ1
2 π2 v22 − v12 – =
x -x R
x12 − x 22 µ1 + µ 2 m - m1
⇒ T = 2π = 2
v22 − v12 x R
µ + µ2
9. (1) F = T × l ⇒ x= 1 R
= 60 dyne/cm × 15 cm × 4 µ 2 − µ1
13. (1) Given
= 3600 dyne Flint glass Crown glass
10. (2) I = nAend = nAemE wf = 0.053 wc = 0.034
mf = 1.68 mc = 1.53
V
= nAem = (8.5 × 1028) × (10–2)2 × Af = ? Ac = 4°
L
4 For no dispersion
(1.6 × 10–19) × (4.5 × 10–6) ×
0.2 wf df – wc dc = 0
⇒ = 1.22 A or w f Af (mf – 1) – wc Ac(mc – 1) = 0
ω c A c ( µ c − 1)
Af =
( ) ,I ( ) ( )
2 2
11. (3) Imax = I1 + I 2 min = I1 − I 2 ωf µf −1
I + I2
2 0.034 × 4° ( 1.53 − 1 )
I =
\ max = 1 = 25 0.053 × ( 1.68 − 1 )
Imin I1 − I 2
0.034 × 4 × 0.53
I1 + I 2 =
=5 0.053 × 0.68
I1 − I 2 ⇒ Af = 2°
36
= 2 m/s 1
\ v' = v
2
ch 1 1
16. (4) E= or E∝ or lE = constant \ e=
λ λ 2
4E 1 + e2
Given E1 = E, E2 =
, E3 = 2E
3 Now d = h 2
1 − e
E3 – E1= 2E – E = E
wavelength of the emitted photon is 1 + (1 / 2 )2
= 1 2
4E E 1 – (1 / 2 )
\ E2 – E1 = –E=
3 3
1 + 12 3
2
E = = = 3.00
lE = l’ 1– 1 1
3 2 2
R
17. (1) Graph between log and loge A is always
R0
v 2 = 8 ft/s
a straight line.
m1v1 = m2v2
R = R0 A1/3
R ⇒ 50 v1 = 5 × 8
= A1/3
R0 ⇒ v1 = 0.8 ft/s
R 1 Now dp – 2 × (df) = dM
loge = logeA
R0 3 ⇒ v2t – 2 × 8 = v1 × t
18. (4) When the coil is within the field there is no 16 16
change in magnetic flux passing through ⇒ t= = s
it. Thus, no current will be induced and v2 − v1 7.2
the acceleration will be g. But according to = 2.22 s
SOLUTIONS MOCK TEST PAPER-2 37
E 10 4
23. [1.67] I1 = 1 = = ⇒ r = 2Ω × 3.14 × (0.5 × 10 −2 )3 (7.8) × 10 3 × 10
R+r 8+r q= 3
E 10 3600
I2 = = = 1.67 A 4
[8×8/8+8]+2 6 × 3.14 × 7.8 × 0.125 × 10 −2
q = 3
24. [780] If m is mass of single drop then as it drops 3600
mg = 2 prT q = 3.4 × 10–5 C
If number of drops in M = 10 grams is N = 34 × 10–6 C
then, = 34.00 mC
M Mg Mg 27. [5.00]
N= = = ≈ 779.86 ≈ 780
m mg 2 πrT 2
S1 P – S 2 P = d
2D
25. [0.06] Weight of cylinder
= 300 × 10–4 × 10 × 10–2 × 800 g 2 × 10 −3 × 2 × 0 −3
=
8
= 2.4 g 2×
5
Let x is the length of cylinder inside water.
Then 5
= λ
2.4 g = 300 × 10–4 × x × 1000 g 2
x = 0.08 m (λ =500 nm )
When completely immersed buoyant force So, when S is at ∞ there is 1st minima and
Fb = 300 × 10–4 × 0.1 × 1000 g when S is at S2 there is last minima because
Fb = 3 gN d/l=4000
Therefore to immerse the cylinder inside So the number of minimas will be 4001 and
water external agent has to push it by number of maximas will be 4000 = 3995 + 5
0.02 m. against average upward thrust. i.e., n = 5
Increase in upward thrust 28. [2.00] As in case of discharging of a capacitor
= 3 g – 2.4 g = 0.6 g N. through a resistance
Since this increase takes place gradually, q = q0e–t/CR
so we take average upward thrust against
which work done = 0.3 g N dq q0 − t / CR
=i –= e
\ Work done = 0.3 g × 0.02 dt CR
= 0.3 × 10 × 0.02 ε kA d ε k
Here, CR = 0 ρ = 0 [as r = 1/s]
= 0.06 J d A σ
−12
26. [34.00] qE i.e., CR = 8.846 × 10 × 5 = 6
4 3 7.4 × 10 −12
πR × ρoil × g
3 −6
So, i = 8.85 × 10 e −12 / 6
6
8.85 ´10-6
=
6 ´7.39
é As e = 2.718, e 2 = 7.39 ù
ëê úû
4 3
πR × ρCu × g
3 = 0.20 = 2 × 10–1µA
For equilibrium 29. [6.00]
4Ω 6V 1Ω 3V 1Ω 3Ω
4 3 4
qE+ πR × ρoil × g = πR 3 × ρCu × g A B
3 3
9 0
4 3 +
πR (ρCu − ρoil ) g E eg = 1 2
q = 3 1 1
+
E 1 2
38
3 mx = ln2
= 9÷
2 n 2
x =
= 6.00 V µ
Potential difference across 2W = 6.00 V
0.693
=
50
30. [139] I = I0e–mx
= 0.01386 cm
I0
= I0 e − µx = 138.6 mm 139 mm
2
Chemistry
31. Option (2) is correct. Mn+3
[PtCl4]2– has square planar geometry and dsp2
hybridisation. CN– strong field ligand, causes the pairing
BrF5 has sp3 d2 hybridisation and square of electron so low spin complex will be
bipyramidal geometry formed. Thus, all the given complexes are
PCl5 has sp3d hybridisation and triginal low spin complex.
bipyramidal geometry
[CO(NH3)6]3+ has d2sp3 hybridisation & 34. (3) Na3PO4 + 3AgNO3 → Ag3PO4 ↓ + 3NaNO3
octahedral geometry. yellow
32. Option (3) is correct. Yellow precipitate is soluble in dilute nitric
acid as well as in ammonium hydroxide.
6 −1
Co+3 a=
3d 4s 1
−1
NO2– being a strong field ligand is able to 2
pair up the pairing of electrons, so low spin = 0.8
complex will form.
The percentage association of solute A in water
Mn (25)
is 80%.
3d 4s
SOLUTIONS MOCK TEST PAPER-2 39
∧ m 2 =2 ∧ m1
reduction
37. (2) (A) R–CN R–CH2NH2
1° Amine
CH3
CH3MgBr |
(B) R–CN H 2O
R–C= N–MgBr
41. (4)
H 2O Br
R – C– CH 3 + NH3 +Mg Me Me Me
|| OH
O OH –
H OH +OH H H cl
Methyl ketone SN 1 (II)
Et Et Et
Retention Inversion
hydrolysis OH –
SN 2 (I)
(C) R–NC R–NH–CH3 product product
Me
2° Amine
HNO2 HO H
(D) R–NH2 R–OH
Et
Alcohol Inversion product
+
N2 Cl
– OH OH Step 1 is a SN2 reaction, since as inverted
Total no. of 1
Molecular orbital configuration B.O = ( N b − N a ) Magnetic properties
electrons 2
(s1s)2 (s*1s)2 (s2s)2 (s*2s)2 (s2pz)2 1
O+2 15 (10 − 5) = 2.5 Paramagnetic
(p2px2 = p2py2) (p*2px1 = p*2py0) 2
(s1s)2 (s*1s)2 (s2s)2 (s*2s)2 (s2pz)2 1
O2 16 (10 − 6 ) = 2 Paramagnetic
(p2px2 = p2py2) (p*2px1 = p*2py1) 2
(s1s)2 (s*1s)2 (s2s)2 (s*2s)2 (s2pz)2 1
O−2 17 (10 − 7 ) = 1.5 Paramagnetic
(p2px2 = p2py2) (p*2px1 = p*2py1) 2
(s1s)2 (s*1s)2 (s2s)2 (s*2s)2 (s2pz)2 1
O2− 18 (10 − 8 ) = 1 Diamagnetic
2 (p2px2 = p2py2) (p*2px1 = p*2py1) 2
According to this, the correct order of bond strength is : O22 − < O2− < O2 < O+2
43. (2) Cl2(g) → 2Cl(g) 242.3 kJ mol–1 47. (1) Nitration of aniline involves acidic medium.
I2(g) → 2I(g) 151 kJ mol–1 So protonation of aniline takes place
I2(s) → I2(g) 62.76 kJ mol–1 forming anilium ion which being meta
directing forms mainly m-nitro aniline.
2I(g)+2Cl (g) → 2ICl(g) 2×(–242.3 kJ mol–1)
Hence, direct nitration of aniline forms the
The required equation will be following products.
I2(s)+Cl2(g) → 2ICl(g) Nitrating mixture is a strong acidic mixture
ΔH = 242.3+151+62.76 – (2×242.3) = –28.54 because electron-withdrawing is the
−28.54 NO2 group.
∆H = = −14.27 kJ/mol NH2 NH2 NH2 NH2
2 NO2
HNO3/H2SO4
44. (4) Expansion of octet is not possible for second + +
period elements e.q. NO etc,. in option (1), NO2
(2) if positive charge delocalised expansion NO2
of octet of atom is required which is not 2% 47% 51%
O-Nitro aniline M-Nitro aniline P-Nitro aniline
possible where as in option (3) explanation
of octet of oxygen is required which also +
not possible. NH2 NH3
O H+
Strong
(Strong deactivated)
Br NaBH4 Acidic sol.
O
46. (3) The structure possible for stereoisomer of I
O
dimethyl cyclopentane are I+ OH
–
H H
CH3 CH3 O
CH3
CH3 Pyridine
CH3 CH3
H I –
H O
Trans cis
H H O
CH3 CH3 −Ι
−
H 3C H 3C O
cis
H H Trans
\ Thus there are 5 stereoisomers possible. O
SOLUTIONS MOCK TEST PAPER-2 41
49. (3) 53. [8.23] [Co (CN)6]4– → [Co(CN)6]3–+ e–, E°RP= 0.83 V
O O Co3+ + e– → Co2+ E°RP = 1.82 V
Cl C NH2 [Co (CN)6]4– + Co3+ Co2+ + [Co (CN)6]3–
NH3
0.059. [Co3 + ] [Co (CN )6 ]4 −
HCl Ecell = E°cell + log 10
Cl 1 [Co2 + ] [Co (CN )6 ]3 −
Cl
CH3 CH3 0.59 [Co3 + ] [Co (CN )6 ]4 − [CN − ]6
= E°cell + log 10
1 [Co2 + ] [Co (CN )6 ]3 − [CN − ]6
Br2 NaOH
22.4 × 10 −3
Mass of N2 gas evolved = × 28 60. [2].
22.4
= 0.028 g H+
0.028 × 100
%of nitrogen in the compound =
0.2 2, 7-Dimethylocta-2, 6-diene
1, 2, 3, 3-tectro
The percentage of nitrogen in the compound is methyl cyclohex-1-ene
= 14%
Mathematics
61. (4) 3x − 4 y + 12 8 x + 6 y + 11
=
( 3 )2 + ( 4 )2 64 + 36
0
y
=
3α − 4β + 12
P(α,β) ∴ =1
x 5
−4
⇒ 3α-4β+7=0 (ii)
∴ P(α,β) also lies on 2x+14y-13=0
L2 : 8x + 6y+11=0
∴2 α+14 β – 13=0 (iii)
Given: L1 : 3x-4y+12=0
L2 : 8x+6y+11=0 on solving equation (ii) and (iii), we get
Equation of angle bisector of L1 and L2 −23 53
containing origin α= and β =
25 50
SOLUTIONS MOCK TEST PAPER-2 43
−23 53 dy π
∴ 100( α + β) = 100 + = 14 ⇒ =
25 50 dx 6
π
62. (2) A (a ( ⇒ =
y x+c
6
The curve passes through (0, 1) ⇒ c = 1
( (
( ( a+b
2
F E
a+c
2 ∴ =
y
π
x +1 ⇒
y −1 π
= = sin −1
1
6 x 6 2
y −1 1
(b (B C(c ( ⇒ sin =
x 2
D
( (
b+c
2
67. (2) Given: y = a loge|x| + bx2 + x
⇒ 16 – 7 =
144
+
a (T8 )1 30 15
= =
25 25 (T8 )2 16 8
144 a
⇒ 9 =+ 3
25 25 1
78. (2) T4 = nC3(ax)n–3
⇒ 9 × 25 = 144 + a x
⇒ a = 225 – 144 = 81 5
= nC3 an–3 xn–6 = (given)
2
∴ ⇒ a = 81 \ n–6=0
α
2× ⇒ n=6
2b 2 25 5
Latus Rectum of hyperbola = = ⇒ T4 = 6C3a6–3 =
a 12 2
5 3
2 × 81 5 27
1
3 1
⇒ × = ⇒ a = =
25 12 8 2
10
1
⇒ a=
75. (3) Let roots be a and b then from equation 2
– x2 – bx + a = 0 1
⇒ a= , n=6
We have ab = – a < 0 2
⇒ Both the roots are in opposite sign and (n + 1)
a+b=–b<0 79. (1) C(n – 2) – (n + 1)C(n – 1)≤ 100
⇒Both roots are in opposite sign and ( n + 1) !
greater root in magnitude is negative. ⇒
(n − 2 )!(n + 1 − n + 2 )!
5
−100
( n + 1) !
–
76. (2) N=
3 ( n − 1) ! ( n + 1 − n + 1) ! ≤ 100
⇒ log10 N = – 100 (log10 5 – log10 3) ( n + 1) ! ( n + 1) !
⇒ – ≤ 100
= – 100 (1 – 0.3010 – 0.4771) ( n − 2 ) !3! ( n − 1) !2!
= – 100 (0.2219)
1 1
= – 22.19 −
⇒ (n + 1)! ≤ 100
= – 23 + 0.81 3! ( n − 2 ) ! 2! ( n − 1 ) !
So, characteristic = – 23
( n − 1 ) !− 3 ( n − 2 ) !
⇒ Number of ciphers after decimal is 22 ⇒ (n + 1)! ≤ 100
6 ( n − 1 ) ! ( n − 2 ) !
77. (1) Sum of n terms of A.P with first terms a
and common difference d is given by ⇒
( n + 1) n(n − 1)! ( n − 1)( n − 2 ) !− 3 ( n − 2 ) ! ≤ 100
n 6 ( n − 1) ! ( n − 2 ) !
Sn = [a + (n – 1) d]
2 ( n + 1) n (n − 1)! ( n − 2 ) ! ( n − 1 − 3 )
⇒ ≤ 100
n 6 ( n − 1) ! ( n − 2 ) !
2 a1 + ( n − 1 ) d1
sn1 2 2n
\
sn2
=
n
=
n+1
( n + 1) n ( n − 4 )
2b1 + ( n − 1 ) d2 ⇒ ≤ 100
2 6
⇒ n(n + 1)(n – 4) ≤ 600
a1 +
( n − 1) d Put n = 1, 2, 3, 4, 5, 6, 7, 8, 9, ……
2
1 2n
⇒ = …(i) For n = 5, 600 ≥ 5 × 6 × 1 holds good
b1 +
( n − 1) d2
n+1
For n = 8, 600 ≥ 8 × 9 × 4 = 288
2 holds good
n −1 For n = 9, 600 ≥ 9 × 10 × 5 = 450
For T8, we know =7 holds good
2
46
\ a2 + b2 = 5.00 (0, 4)
87. [7.00] 4 must be obtained on atleast one dice. z
x = number of dice on which 4 is obtained
required probability and the rest of the Real
A
number same from 1, 2, 3 (3, 0)
Now, P(x = 1) + P(x = 2) + P(x = 3) + P(x = 4)
5
4
C1 × 3 × 3 × 3 4 C 2 × 3 2 4 C 3 .3 1 ⇒ |z| =
= + + + 4 2
64 64 64 6 ⇒ |2z| = 5.00
175 25 × 7
= =
1296 1296