Professional Documents
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Questions Quizrr
Q1
A tuning fork A of unknown frequency produces 5beats/s with a fork of known frequency 340 HZ. When fork A filed, the
(1) 342 Hz
(2) 335 Hz
(3) 338 Hz
(4) 345 Hz
Q2
The trajectory a projectile in a vertical plane is y = αx − βx , where α and β are constants and x \& y are respectively the
2
horizontal and vertical distance of the projectile from the point of projection. The angle of projection θ and the maximum
(1) tan −1
α,
α
4β
(2) tan −1 α
β,
2β
2
β
(3) tan −1
(
α
),
α
(4) tan −1
α,
4α
Q3
A cord is wound round the circumference of wheel of radius r. The axis of the wheel is horizontal and the moment of
inertia about it is I. A weight mg is attached to the cord at the end. The weight falls from rest. After falling through a
(2) 2gh
2mgh
(3) I +2mr
2
2mgh
(4) I +mr
2
Q4
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Find the peak current and resonant frequency of the following circuit (as shown in figure)
Q5
(1) →b = 2a
→ + c→
(2) →b = a
→ − c→
(3) →b = a
→ + 2c→
(4) →b = a → ⋅ c→)c→
→ − 2(a
Q6
A radioactive sample is undergoing α decay. At any time t , its activity is A and another time t the activity is
1 2
A
5
. What is
1n(t2 +t1 )
(2) 2
t1 −t2
(3) 1n5
(4)
1n5
t2 −t1
Q7
(1) a circle
(2) a parabola
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(3) an ellipse
(4) a helix
Q8
A scooter accelerates from rest for time t at constant rate a and then retards at constant rate a for time t and comes to
1 1 2 2
t1
rest. The correct value of t2
will be:
a1 +a2
(1) a2
a2
(2) a1
a1 +a2
(3) a1
a1
(4) a2
Q9
(1)
(2)
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(3)
(4)
Q10
An inclined plane making an angle of 30 with horizontal is placed in a uniform horizontal electric field 200
∘ N
C
as shown in
the figure. A body of mass 1 kg and charge 5mC is allowed to slide down from rest at a height of 1 m. If the coefficient of
frication is 0.2, find the time taken by the body to reach the bottom.
√3
2 ∘ 1 ∘
[g = 9.8m/s , sin 30 = ; cos 30 = ]
2 2
(1) 2.3 s
(2) 0.46 s
(3) 1.3 s
(4) 0.92 s
Q11
If ' C and 'V' represent capacity and voltage respectively then what are the dimensions of λ where C/V
′
= λ?
(1) [M −2
L
−4
I
3
T
7
]
(2) [M −2
L
−3
I
2
T
6
]
(3) [M −1
L
−3
I
−2
T
−7
]
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(4) [M −3
L
−4
I
3
T
7
]
Q12
Given below are two statements: One is labeled as Assertion A and the other is labeled as Reason R. Assertion A : For a
simple microscope, the angular size of the object equals the angular size of the image. Reason R : Magnification is
achieved as the small object can be kept much closer to the eye than 25 cm and hence it subtends a large angle. In the light
of the above statements, choose the most appropriate answer from the options given below:
(1) Both A and R are true but R is NOT the correct explanationof A
(2) Both A and R are true and R is the correct explanation of A
Q13
The recoil speed of a hydrogen atom after it emits a photon in going from n = 5 state to n = 1 state will be:
(1) 4.17 m/s
(2) 4.34 m/s
(3) 219 m/s
(4) 3.25 m/s
Q14
Two masses A and B, each of mass M are fixed together by a massless springs. A force acts on the mass B as shown in
figure. If the mass A starts moving away from mass B with acceleration 'a', than the acceleration of mass B will be:
F+Ma
(1) M
F−Ma
(2) M
(3)
M a−F
(4) MF
F +M a
Q15
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A wire of 1Ω has a length of 1 m. It is stretched till its length increases by 25%. The percentage change in a resistance to
the nearest integer is:
(1) 25%
(2) 12.5%
(3) 76%
(4) 56%
Q16
Statement (II) :- It takes precisely one second to move between the two extreme positions.
In the light of the above statements, choose the correct answer from the options give below.
Q17
An aeroplane, with its wings spread 10 m, is flying at a speed of 180 km/h in a horizontal direction. The total intensity of
wings will be
(1) 88.37mV
(2) 62.50mV
(3) 54.125mV
(4) 108.25mV
Q18
The length of metallic wire is l when tension in it is T . It is l when the tension is T . The original length of the wire will
1 1 2 2
be :
(1)
l1 +l2
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(2) T1 l1 −T2 l2
T2 −T1
(3)
T2 l1 +T1 l2
T1 +T2
(4)
T2 l1 −T1 l2
T2 −T1
Q19
The internal energy (U), pressure (P) and volume (V) of an ideal gas are related as U = 3PV + 4. The gas is :
Q20
Statement - I : An electric dipole is placed at the centre of a hollow sphere. The flux of electric
field through the sphere is zero but the electric field is not zero anywhere in the sphere.
Statement - II : If R is the radius of a solid metallic sphere and Q be the total charge on it.
The electric field at any point on the spherical surface of radius r(< R) is zero but theelectric
flux passing through this closed spherical surface of radius r is not zero.
In the light of the above statements. Choose the correct answerfrom the option given below :
Option :
Q21
If thehighest frequency modulating a carrier is 5kHz, then the number of AM broadcast stations accommodated in a 90kHz
bandwidth are
Q22
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Q
1 mole of rigid diatomic gas performs a work of 5
when heat Q is supplied to it. The molar heat capacity of the gas during
Q23
A particle excutes S.H.M with amplitude 'a' and time period T . The displacement of the particle when its speed is half of
√xa
maximum speed is 2
. The value of x is
Q24
Two stream of photons, possessing energies equal to twice and ten times the work function of metal are incident on the
metal surface successively. The value of ratio of maximum velocities of the photoelectrons emitted in the two respective
Q25
A point source of light S, placed at a distance 60 cm infront of the centre of plane mirror of width 50 cm, hangs vertically
on a wall. A man walks infront of the mirror along a line parallel to the mirror at a distance 1.2 m from it (see in the
figure). The distance between the extreme points where he can see the image of the light source in the mirror is cm
Q26
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The zener diode has a V z = 30 V . The current passing through the diode for the following ciruit is ____ mA
Q27
In the reported figure of earth, the value of acceleration due to gravity is same at point A and C but it is smaller than that of
its value at point B (surface of the earth). The value of OA : AB will be x : y. The value of x is
Q28
27 similar drops of mercury are maintained at 10 V each. All these spherical drops combine into a single big drop. The
potential energy of the bigger drop is ____ times that of a smaller drop.
Q29
2
The volume V of a given mass of monatomic gas changes with temperature T according to the relation V = KT . The 3
work done when temperature changes by 90 K will be xR. The value of X is ____ [R =universal gas constant]
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Q30
Time period of a simple pendulum is T . The time taken to complete oscillations starting from mean position is . The
5 α
T
8 β
value of α is
Q31
(1) aldehyde
(2) halogens
(3) ether
(4) amine
Q32
(1)
(2)
(3)
(4)
Q33
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The nature of charge on resulting colloidal particles when FeCl is added to excess of hot water is:
3
(1) positive
(2) neutral
(3) sometimes positive and sometimes negative
(4) negative
Q34
Q35
In
molecule, the hybridization of carbon 1,2,3 and 4 respectively are:
(1) sp 2 2
, sp, sp , sp
3
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(2) sp 2 2 2
, sp , sp , sp
3
(3) sp 2 3 2
, sp , sp , sp
3
(4) sp 3 3
, sp, sp , sp
3
Q36
Q37
(1) N 2 O, BaO
(3) B 2 O3 , CaO
(4) B 2 O3 , SiO2
Q38
Calgon is used for water treatment. Which of the following statement is NOT true about calgon?
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Q39
Ceric ammonium nitrate and CHCl 3/ alc. KOH are used for the identification of functional groups present in _____ and
_____ respectively.
Q40
Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R.
Assertion A: In TII , isomorphous to CsI , the metal is present in +1 oxidation state.
3 3
Q41
Q42
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(1)
(2)
(3)
(4)
Q43
Q44
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(1)
(2)
(3)
(4)
Q45
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Q46
Q47
(1) Proton H +
(2) Deuterium 2
1
H
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(3) Protium 1
1
H
(4) Tritium 3
1
H
Q48
A. Phenyl methanamine
B. N, N-Dimethylaniline
C. N-Methyl aniline
D. Benzenamine
Q49
Considering the above reaction, the major product among the following is:
(1)
(2)
(3)
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(4)
Q50
Seliwanoff test and Xanthoproteic test are used for the identification of ____ and ____ respectively
Q51
The NaNO weighed out to make 50 mL of an aqueous solution containing 70.0mgNa per mL is ____g. (Rounded off to
3
+
Q52
Q53
[Given : The values of standard enthalpy of formation of SF 6 ( g), S(g) and F(g) are -1100,275 and 80 kJ mol −1
respectively.]
Q54
Q55
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Questions Quizrr
A ball weighing 10 g is moving with a velocity of 90 ms . If the uncertainty in its velocity is 5%, then the uncertainty in
−1
Q56
In mildly alkaline medium, thiosulphate ion is oxidized by MnO to "A". The oxidation state of sulphur in "A" is
−
Q57
When 12.2 g of benzoic acid is dissolved in 100 g of water, the freezing point of solution was found to be
∘
−0.93 C (Kf (H2 O) = 1.86 K kg mol
−1
) . The number (n) of benzoic acid molecules associated (assuming 100%
association ) is
Q58
If the activation energy of a reaction is 80.9 kJ mol , the fraction of molecules at 700 K, having enough energy to react
−1
[Use R = 8.31JK
−1
mol
−1
]
Q59
The pH of ammonium phosphate solution, if pk of phosphoric acid and pk of ammonium hydroxide are 5.23 and 4.75
a b
respectively, is
Q60
Q61
Let L be a line obtained from the intersection of two planes x + 2y + z = 6 and y + 2z = 4. If point P (α, β, γ) is the foot
(1) 142
(2) 68
(3) 136
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(4) 102
Q62
2
n +6n+10
The sum of the series ∑ is equal to :
∞
n=1 (2n+1)!
(1)
41 19 −1
e + e − 10
8 8
(2) − 41
8
e +
19
8
e
−1
− 10
(3) 41
8
e −
19
8
e
−1
− 10
(4) 41
8
e +
19
8
e
−1
+ 10
Q63
xf (a)−af (x)
Let f (x) be a differentiable function at x = a with f ′
(a) = 2 and f (a) = 4. Then lim x→a
x−a
equals :
(1) 2a + 4
(2) 2a − 4
(3) 4 − 2a
(4) a + 4
Q64
Let A(1, 4) and B(1, −5) be two points. Let P be a point on the circle (x − 1) 2
+ (y − 1)
2
= 1 such that (P A) 2
+ (P B)
2
(1) a parabola
(2) a straight line
(3) a hyperbola
(4) an ellipse
Q65
If the locus of the mid-point of the line segment from the point (3,2) to a point on the circle, x 2
+ y
2
= 1 is a circle of the
(1) 1
(2)
1
(3) 1
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(4)
1
Q66
2
xy +y
Let slope of the tangent line to a curve at any point P(x, y) be given by x
. If the curve intersects the line x + 2y = 4 at
x = −2, then the value of y, for which the point (3, y) lies on the curve, is :
(1) −
18
11
(2) − 18
19
(3) − 4
(4) 18
35
Q67
Let A be the area of the region bounded by the curves y = sin x, y = cos x and y -axis in the first quadrant. Also, let A
1 2
be the area of the region bounded by the curves y = sin x, y = cos x, x -axis and x = π
2
in the first quadrant. Then,
(1) A 1 = A2 and A 1 + A2 = √ 2
(2) A 1 : A2 = 1 : 2 and A 1 + A2 = 1
(4) A 1 : A2 = 1 : √ 2 and A 1 + A2 = 1
Q68
2 2 3 3 4 4
a +b a +b a +b
If 0 < a, b < 1, and tan −1
a + tan
−1
b =
π
4
, then the value of (a + b) − ( 2
) + (
3
) − (
4
) +. . is :
(1) log e
2
(2) log e
(
e
2
)
(3) e
(4) e 2
− 1
Q69
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Q70
x + 2y − 3z = a
2x + 6y − 11z = b
x − 2y + 7z = c
Q71
A seven digit number is formed using digit 3,3,4,4,4,5,5 . The probability, that number so formed is divisible by 2, is :
(1)
6
(2) 4
(3)
3
(4)
1
Q72
→ →
If vectors a 1 = x^
i − ^ ^
j + k and a 2 = ^
i + y^ ^
j + zk are collinear, then a possible unit vector parallel to the vector
x^
i + y^ ^
j + zk is :
(1) 1
(−^ ^
j + k)
√2
(2)
1
(^
i − ^
j)
√2
(3)
1
(^
i − ^ ^
j + k)
√3
(4)
1
^
(^
i + ^
j − k)
√3
Q73
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x log t
For x > 0, if f (x) = ∫ then f (e) + f ( is equal to :
e 1
dt, )
1 (1+t) e
(1)
1
(2) -1
(3) 1
(4) 0
Q74
πx
⎧
⎪ 2 sin(− ), if x < −1
⎪
⎪ 2
(1) 3
(2) -1
(3) -3
(4) 1
Q75
(1) 10 5
(2) 10
C5
(3) 5 5
(4) 5!
Q76
(1) 11
(2) 6x
(3) 12
(4) 6
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Q77
2
x −x−2
Let f (x) = sin −1
x and g(x) = 2
2x −x−6
. If g(2) = lim x→2 g(x), then the
2
, ∞)
Q78
If the mirror image of the point (1,3,5) with respect to the plane 4x − 5y + 2z = 8 is (α, β, γ), then 5(α + β + γ) equals:
(1) 47
(2) 39
(3) 43
(4) 41
Q79
(1) 2e
x
(e −1)
− 1
(2) e
x
(e −1)
(3) 2e
x
e
− 1
(4) e
x
e
− 1
Q80
The triangle of maximum area that can be inscribed in a given circle of radius 'r' is:
(1) A right angle triangle having two of its sides of length 2r and r.
Q81
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The total number of 4 -digit numbers whose greatest common divisor with 18 is 3 , is
Q82
Let α and β be two real numbers such that α + β = 1 and αβ = −1. Let P n = (α)
n n
+ (β) , Pn−1 = 11 and P n+1 = 29
Q83
18 18
Let X be eighteen observation such that ∑ and ∑ where α
2
1, X2 , … … … .X18 (Xi − α) = 36 (Xi − β) = 90,
i=1 i=1
and β are distinct real numbers. If the standard deviation of these observations is 1, then the value of |α − β| is
Q84
m−1 n−1
1 1 x +x
In I m,n = ∫
0
x
m−1
(1 − x)
n−1
dx, for m, n ≥ 1 and ∫ 0 (1+x)
m+n
dx = αIm,n , α ∈ R, then α equals
Q85
Q86
1 0 0 1 0 0
⎡ ⎤ ⎡ ⎤
If the matrix A = ⎢ 0 2 0 ⎥ satisfies the equation A 20
+ αA
19
+ βA = ⎢ 0 4 0⎥ for some real numbers α and
⎣ ⎦ ⎣ ⎦
3 0 −1 0 0 1
β, then β− α is equal to
Q87
Q88
Let the normals at all the points on a given curve pass through a fixed point (a, b). If the curve passes through (3,-3) and
(4, −2√2), and given that a − 2√2 b = 3, then (a 2
+ b
2
+ ab) is equal to
Q89
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Let z be those complex number which satisfy |z + 5| ≤ 4 and z(1 + i) + z̄ (1 − i) ≥ −10, i = √−1 If the maximum
value of |z + 1| is α + β√2, then the value of (α + β) is
2
Q90
Let a be an integer such that all the real roots of the polynomial 2x 5
+ 5x
4
+ 10x
3
+ 10x
2
+ 10x + 10 lie in the interval
(a, a + 1) Then, ∣ a| is equal to
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Answer Key
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Q73 (1) Q74 (2) Q75 (1) Q76 (3)
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Solutions Quizrr
Q1 (2)
Given
Before Filed :
Q2 (1)
Given :
y = αx − βx 2 …. (1)
for maximum height, we should find out maximum value of y from equation (1) so, for maximum value of y
dy
dx
= 0 ⇒ α − 2βx = 0
α
x = 2β …(2)
()α
Now, put value of x from equation (2) in quation (1) y = α 2β −β
( )α2
4β 2
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Solutions Quizrr
⇒
()()α2
2β
−
α2
4β
⇒ 4β
α2
α2
So, H max = 4β …. (3)
u 2sin 2 θ
As we know maximum height H max = 2g
…(4)
u 2 × 2sin θcos θ
and range (R) = 2x = g
( )( )
α2
4β
2g
sin 2 θ
× 2sin θcos θ
()
2 2β
α
= g
Q3 (4)
(
2mgh = MR 2 + I ω 2 )
2mgh
ω2 =
I + MR 2
Q4 (4)
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Solutions Quizrr
∴ XL = ω × L
(
⇒ (100) 100 × 10 − 3 ⇒ 10 )
1 1
XL = ω × c ⇒
100 × 100 × 10 − 6
10 6
⇒ ⇒ 100
10 4
1
Resonance frequency ω =
√LC
1 1
ω= ⇒
√ 100 × 10 − 3 × 100 × 10 − 6 √10 − 5
∴ ω = 2πF
1 1
F = 2π ×
√10 − 5
1
⇒ 2π √10 5
100
⇒ 2π √10
⇒ 50 Hz
Q5 (4)
→
We see from the diagram that because of the law of reflection, the component of the unit vector →
a along b changes sign on reflection
→ →
while the component parallel to the mirror remain unchanges. →
a = a 11 + a ⊥
→
→ → →
and a ⊥ = c ( a ⋅ c )
→
→ →
we see that the reflected unit vector is b = a 11 − a ⊥ ⇒ →
a − 2(→
a⋅→
c )→
c
Q6 (1)
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Solutions Quizrr
A = A 0e − αt 1 ...(1)
A
5
A 0e − αt 2 ...(2)
5 = e − λ ( t1 − t2 )
ln ( 5 )
( )
ln(5) = t 2 − t 1 λ ⇒ λ = t − t
2 1
1 t2 − t1
avg. life = λ ⇒ ln ( 5 )
Q7 (3)
v 2 + ω 2x 2 = ω 2A 2
v2 ω 2X 2 ω 2X 2
divide whole equation by ω 2 A 2 + =
ω2 A2 ω2 A2 ω2 A2
v2 x2
+ =1
( ωA ) 2 ( A )2
above equation is similar as standard equation of ellipes, so graph between velocity and displacement will be ellipes.
Q8 (2)
For 1 st interval
v0
a1 = t
1
v 0 = a 1t 1 …. . (1)
For 2 nd interval
v0
a2 = t
2
v 0 = a 2t 2 …. . (2)
from (1)&(2)
a 1t 1 = a 2t2
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t1 a2
t2
= a
1
Q9 (1)
Inputs
Q10 (3)
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Solutions Quizrr
(
F = 1 × 10 × sin30 − 0.2 1 × 10 × cos30 ∘ + 200 × 5 × 10 − 3sin30 ∘ )
− 200 × 5 × 10 − 3cos30 ∘
F = 2.3 N
F 2.3
a = m ⇒ 1 ⇒ 2.3 m / sec 2
25 2×2
t=
√ √ 9
⇒ 2.3
⇒ 1.3sec
Q11 (1)
w q
∴ v = q and c = v
c
dimension of v
q
⇒
v2
q q3
⇒ × q2 ⇒
w2 w2
I3 T3
⇒
M2 L4 T − 4 [
⇒ M − 2 L − 4 T 7I 3 ]
Q12 (2)
Both obtain same angle, since image can be at a distance greater than 25 cm, object can be moved closer to eye.
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Q13 (1)
ΔE ( 13.6 − 0.54 ) eV
momentum (P) = C =
3 × 10 8
( 13.06 ) × 1.6 × 10 − 19
mv =
3 × 10 8
( 13.06 ) × 1.6 × 10 − 19
v= ⇒ 4.17 m / sec
3 × 10 8 × 1.67 × 10 − 27
Q14 (2)
F − F s = Ma ′
F
a′ = M − 9
F − ma
M
Q15 (4)
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⇒ R 2 = 1.5625R
% increase → 56.235%
Q16 (3)
Above statement is correct because time taken by particle performing SHM between two
extreme position is T / 2.
Here, T = 2 sec.
So, time = 2 / 2 = 1sec
Q17 (4)
∑ = B ⊥ vℓ
Bv
sin60 ∘ = B
√3 Bv
2
= B
√3
BV = 2 B
√3
E = 2 Bℓv
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√3 5
= 2 × 2.5 × 10 − 4 × 10 × 180 × 18
√3
= 2 × 2.5 × 5 × 10 − 2 = 10.825 × 10 − 2 = 108.25mV
Q18 (4)
( )
F
A
From young's modulus relation y =
( )
ΔI
I
T1 (
y ℓ1 − ℓ )
A
= ℓ
we can write for 2 nd case
T2 (
y ℓ2 − ℓ )
A
= ℓ
T1 ℓ1 − ℓ
T2
= ℓ −ℓ
2
T 1ℓ 2 − T 1ℓ = T 2ℓ 1 − T 2ℓ
T 2l 1 − T 1l 2
T2 − T1
=ℓ
Q19 (1)
U = 3PV + 4
f f
2
PV = 3PV + 4 ∴ u = 2 nRT
8
f = 6 + PV ∴ PV = nRT
Q20 (1)
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Statement − 1 → Correct
Statement − 2 → Incorrect
Q21 (9)
Band width
No. of station = 2 × Highest Band width
90
⇒ 2×5
⇒9
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Q22 (25)
ΔQ = ΔU + ΔW …. . (1)
Q
Q = nC vΔT + 5
Q 5
Q − 5 = 1 × 2 R × ΔT
25
Q = 8 RΔT ……(2) ∴ Q = ncΔT
25 xR
c= 8R given C = 8
x = 25
Q23 (3)
Q24 (1)
E 1 = 2ϕ r k1 = ϕ
E 2 = 10ϕ r k 2 = 9ϕ
∴V∝
v1
√k ( 1
k = 2 mv 2 )
1 1 x
v2 =
√ 9 ⇒ 3 = y
x=1
Q25 (150)
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F. O. V. = 2 × 75 ⇒ 150 cm
Q26 (9)
90 − 30
I= 4
= 15 mA
30
I I = 5 KΩ = 6 mA
I 2 = 15 mA − 6 mA = 9 mA
Q27 (4)
GM GMr
=
R3
( ) 3R
2
2
4R
OA = 9 = r
4R 5R
AB = R − 9 = 9
OA : AB
4R 5R
9 : 9 ⇒ 4: 5 = x: y
(x = 4)
Q28 (243)
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kq 2
For self energy of sphere (conducting) U = 2r
kq 2
For small drop → U i = 2r ……. (1)
After combine small drops volume remains same as bigger drop
4 4
3
∴ 3 πr × n = 3 πR 3
1
R = (n) 3 r ………. (2)
k ( nq ) 2
For large drop → U f = 2 × 3R ………. (3)
From equation (1),(2),(3)
Uf
Ui
= (n) 5 / 3
⇒ (27) 5 / 3
$\Rightarrow 2
Q29 (60)
Given: V = kT 2 / 3
V 3 / 2 = (k) 3 / 2T
TV − 3 / 2 = const. ...(1)
and TV γ − 1 = const ...(2)
From (1)&(2)
3
−2 = γ−1
1
γ= − 2
nRΔT
Work done (w) = γ − 1
1 × R × 90
W= 1 | W | = 60R x = 60
− 2 −1
Q30 (7)
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For given
()
5
8
oscillation, we can write it as →
( )
1
2
1
+ 8
T
And we know for half oscillations time → 2
π 7π
For final point → π + 6 ⇒ 6
7T α
Time → 12 → given → β Tα = 7p
Q31 (1)
Q32 (3)
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Q33 (1)
If FeCl 3 is added to excess of hot water, a positively charged sol of hydrated ferric oxide is formed due to adsorption of Fe 3 + ions.
Q34 (3)
(a)
(b)
Ether
(c) 2CH 3 − CH 2Cl + 2Na (Wurtz reaction) C 2H 5 − C 2H 5 + 2NaCl
(d) 2C 6H 5Cl + 2Na Ether C 6H 5 − C 6H 5 + 2NaCl
(Fitting reaction)
Q35 (1)
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CH 2 = C = CH sp 2 − CH sp 3
sp
sp 2
Q36 (4)
Q37 (4)
B 2O 3 and SiO 2 both are oxides of non-metal and hence are acidic in nature.
Q38 (1)
( )
Na 6 PO 3 or Na 6P 6O 18
6
Order of abundance of element in earth crust is
Q39 (1)
Alcohol give positive test with ceric ammonium nitrate and primary amines gives carbyl amine test with CHCl 3, KOH.
Q40 (3)
−
TℓI 3 is Tℓ + I 3
−
CSI 3 is Cs + I 3
Thallium shows Tℓ + state due to inert pair effect.
Q41 (1)
Q42 (1)
Q43 (2)
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Sì − FeCO 3
Calamine − ZnCO 3
Q44 (2)
Q45 (2)
Q46 (1)
Ne 2O BO = 0
N2 BO = 3
F2 BO = 1
O2 BO = 2
Q47 (4)
Tritium isotope of hydrogen is radioactive and emits low energy β − particles. It is because of high n / p ratio of tritium which makes
nucleus unstable.
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Q48 (4)
Q49 (3)
Q50 (1)
Seliwanoff test and Xanthaproteic test are used for identification of 'Ketoses' and proteins respectively.
Q51 (13)
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Na + = 70mg / mL
W Nat in 50 mL solution = 70 × 50mg
= 3500mg
= 3.5gm
3.5
Moles of Na + in 50ml solution = 23
Moles of NaNO 3 = moles of Na +
3.5
= mol
23
3.5
Mass of NaNO 3 = × 85 = 12.934
23
≃ 13gm Ans.
Q52 (3)
[Co(ox)2Br (NH3 )] 2 −
Q53 (309)
SF 6( g) ⟶ S(g) + 6 F( g)
∘ ∘ ∘ ∘
[
ΔH reaction = 6 × E S − F = ΔH f [S(g)] + 6 × ΔH f [F(g)] − ΔH f SF 6( g) ]
6 × E s − F = 275 + 6 × 80 − ( − 1100)
= 275 + 480 + 1100
6 × E s − F = 1855
1855
Es − F = 6 = 309.1667
≃ 309 kJ / molAns.
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Q54 (147)
| |
Zn(s) Zn + 2(0.1M) Ag + (0.01M) ∣ Ag(s)
0.059
{ }Zn 2 +
( Ag )
+ 2
E = E 0 − n log(Q)
E = 1.56 −
0.059
2
log
[ ]
( 0.01 ) 2
0.1
[ ]
0.059
E = 1.56 − 2
log (10) 3
Q55 (1)
m = 10g = 10 − 2Kg
v = 90 m / sec
5
Δv = v × 5% = 90 × 100 = 4.5 m / sec
h
m ⋅ Δv ⋅ Δx ≥ 4π
6.63 × 3 × 10 − 34
10 − 2 × 4.5 × Δx ≥ 22
4× 7
6.63 × 7 × 2 × 10 − 34
Δx ≥
9 × 4 × 22 × 10 − 2
− 33
Δx ≥ 1.17 × 10 = x × 10 − 33
x = 1.17 ≃ 1
Q56 (6)
2− − Alkaliue
S 2O 3 + MnO 4 Melium A
−2
A → SO 4
∴ Oxidation no. of 'S' = + 6 Ans.
Q57 (2)
n PhCOOH → (PhCOOH) n
1
N = X = i{ As α = 1}
ΔT f = i × k f × m
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1 12.2 × 1000
0.93 = n × 1.86 × 122 × 100
n=2
Q58 (14)
E a = 80.9 kJ / mol
Q59 (7)
√
+ ×
a ka × kb
1
{
pH = pk a + 2 pk w − pk a − pk b }
1
pH = 5.23 + 2 {14 − 5.23 − 4.75}
1
pH = 5.23 + 2 (4.02) = 7.24 = 7( Nearest integer )
Q60 (1)
Assuming FCC
No of lactice sites = 6 face centre +8 corner = 14
No. of octahedral voids = 13
13
Ratio = 14 = 0.92857 = 1 (Nearest integer)
Q61 (4)
| |
î ĵ k̂
Dr's of line 1 2 1 = 3î − 2ĵ + k̂
0 1 2
Dr / s : − (3, − 2, 1)
x+2 y−4 z
Points on the line (-2,4,0) Equation of the line 3 = − 2 = 1 = λ
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Solutions Quizrr
Dr's of PQ; 3λ − 5, − 2λ + 2. λ − 1
Dr's of y lines are (3,-2,1) Since PQ ⊥ line 3(3λ − 5) − 2( − 2λ + 2) + 1(λ − 1) = 0
10
λ= 7
( 16 8 10
P 7 , 7, 7 )
21(α + β + γ) = 21 7 ()
34
= 102
Q62 (3)
∞ n 2 + 6n + 10
∑ n = 1 ( 2n + 1 ) !
Put 2n + 1 = r, where r = 3, 5, 7, …
r−1
⇒n= 2
n 2 − 6n + 10
=
( ) r−1
2
2
+ 3r − 3 + 10
=
r 2 + 10r + 29
( 2n + 1 ) ! r! 4r !
Now ∑ r − 3 , 5 , 7
r ( r − 1 ) + 11r + 29
4r !
1
( 1 11
= 4 ∑r = 3 , 5 , 7 , … … ( r − 2 ) ! + ( r − 1 ) ! + r !
29
)
= 4
1
{( 1!
1 1
+ 3 ! + 5 ! + …. ⋅
1
) ( 1 1 1
) ( 1
+ 11 2 ! + 4 ! + 6 ! + … + 29 3 ! + 5 ! + 7 ! + …. .
1 1
)}
{ ( ) ( )} )
1
1 e+ e −2 1
1 e− e e− e −2
= 4 2
+ 11 2
+ 29 2
1
{ 1
= 8 e − e + 11e + e − 22 + 29e − e − 58
11 29
}
1
{
= 8 41e − e − 80
19
}
Q63 (3)
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By L-H rule
f ( a ) − af ′ ( x )
L = lim x → a 1
∴ L = 4 − 2a
Q64 (2)
|
3π
PA 2 + PB 2 max . = 47 − 18sinθ| min . ⇒ θ = 2
∴ P, A, B lie on a line x = 1
Q65 (2)
∴ P ≡ (2h − 3, 2k − 2) → on circle
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( )
∴ h− 2
3 2
+ (k − 1) 2 = 4
1
1
⇒ radius = 2
Q66 (2)
dy xy 2 + y
dx
= x
xdy − ydx
⇒ = xdx
y2
⇒ −d y () x
=d 2
() x2
−x x2
⇒ y = 2 +C
Curve intersect the line x + 2y = 4 at x = − 2 So, − 2 + 2y = 4 ⇒ y = 3
2
So the curve passes through (-2,3) ⇒ 3 = 2 + C
−4
⇒C= 3
−x x2 4
∴ curve is y = 2 − 3
−3 9 4
It also passes through (3, y) y = 2 − 3
−3 19
⇒ y = 6
18
⇒ y = − 19
Q67 (4)
π/2 π/2
A 1 + A 2 = ∫ 0 cosx ⋅ dx = sinx| 0 =1
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Q68 (1)
( )
tan − 1 1 − ab
a+b π
= 4 ⇒ a + b = 1 − ab ⇒ (1 + a)(1 + b) = 2
Now, (a + b) −
( )( )
a2 + b2
2
+
a3 + b3
3
…∞
( a2
= a− 2 + 3… + b− 2 + 3…
a3
)( ) b2 b3
Q69 (1)
Q70 (2)
| |
1 2 −3
D= 2 6 − 11
1 −2 7
= 20 − 2(25) − 3( − 10)
= 20 − 50 + 30 = 0
| |
a 2 −3
D1 = b 6 − 11
c −2 7
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| |
1 a −3
D2 = 2 b − 11
1 c 7
| |
1 2 a
D3 = 2 6 b
1 −2 c
= 6c + 2b − 2(2c − b) − 10a
= − 10a + 4b + 2c
= − 2(5a − 2b − c)
for infinite solution
D = D1 = D2 = D3 = 0
⇒ 5a = 2b + c
Q71 (3)
7!
n(s) = 2 ! 3 ! 2 !
6!
n(E) = 2 ! 2 ! 2 !
n(E) 6! 2!3!2!
P(E) = n ( S ) = 7 ! × 2 ! 2 ! 2 !
1 3
7
×3= 7
Q72 (3)
x 1 1
1
= − y = z = λ( let )
( 1 1
λî − λ ĵ + λ k̂ )
Unit vector parallel to xî + yĵ + zk̂ = ±
√
2
λ2 +
λ2
( î − ĵ + k̂ )
For λ = 1, it is ±
√3
Q73 (1)
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1 / e ℓnt 1 dz
I2 = ∫1 1+t
dt put t = z , dt = − 2
z
e
= ∫1 −
ℓnz
1+
1
z
×
( )
−
dz
z2
e ℓnz
= ∫ 1 z ( z + 1 ) dz
e ℓnt
{
= ∫ 1 t dt lnt = u, t dt
1
}
|
1
1 u2 1
= du = ∫ 0 udu = 2 = 2
0
Q74 (2)
If f is continuous at x = − 1, then f − 1 − = f( − 1) ( )
⇒ 2 = |a − 1 + b|
⇒ | a + b − 1 | = 2……(i)
similarly
( )
f 1 − = f(1)
⇒ |a + b + 1| = 0
⇒a+b= −1
Q75 (1)
g(f(x)) = f(x)
⇒ g(x) = x, when x is even
5 elements in A can be mapped to any 10
So, 10 5 × 1 = 10 5
Q76 (3)
y + z = 5 ...(1)
1 1 5
y
+ z = 6
y+z 5
⇒ yz = 6
5 5
⇒ yz = 6
⇒ yz = 6
Also (y − z) 2 = (y + z) 2 − 4yz
⇒ (y − z) 2 = (y + z) 2 − 4yz
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⇒ (y − z) 2 = 25 − 4(6) = 1
⇒y−z=1
from (1) and (2), y = 3 and z = 2
Q77 (1)
(x−2) (x+1) 3
g(2) = lim x → 2 ( 2x + 3 ) ( x − 2 ) = 7
⇒ (3x + 4)(x + 2) ≥ 0
x ∈ ( − ∞, − 2] ∪ ( 4
− 3, ∞ ]
Q78 (1)
∴α=1+4 5 () 2
= 5
13
β=3−5 5 ()2
=1= 5
5
γ=5+2 5 ()
2
= 5
29
Thus, 5(α + β + γ) = 5 5 + 5 + 5 ( 13 5 29
) = 47
Q79 (1)
x
Given, f(x) = ∫ 0 e tf(t)dt + e x ...(1)
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Q80 (4)
Triangle of maximum area that can be inscribed in a circle is an equilateral triangle. Let ΔABC be inscribed in circle,
r
Now, in ΔOBD OD = rcos60 ∘ = 2
3r
Height = AD = 2
r
32
Again in ΔABD Now sin60 ∘ = AB
⇒ AB = √3r
Q81 (1000)
Since, required number has G.C.D with 18 as 3. It must be odd multiple of ' 3 ′ but not a multiple of '9'.
(i) Now, 4 -digit number which are odd multiple of ' 3 ' are,
Q82 (324)
Given, α + β = 1, αβ = − 1
∴ Quadratic equation with roots α, β is x 2 − x − 1 = 0 ⇒ α 2 = α + 1
Multiplying both sides by α n − 1 α n + 1 = α n + α n − 1 ...(1)
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Similarly, β n + 1 = β n + β n − 1 ...(2)
(
Adding (1)&(2) α n + 1 + β n + 1 = α n + β n + α n − 1 + β n − 1 ) ( )
⇒ Pn + 1 = Pn + Pn − 1
Q83 (4)
18
Given, ∑ i = 1 X i − α = 36( )
⇒ ∑ x i − 18α = 36
⇒ ∑ x i − 18(α + 2) ...(1)
Also, ∑ 18
i = 1 Xi − β (
2 = 90
)
2
⇒ ∑ xi + 18β 2 − 2β ∑ x i = 90
2
⇒ ∑ xi + 18β 2 + 2β × 18(α + 2) = 90 (using equation (1))
2
⇒ ∑ xi = 90 − 18β 2 + 36β(α + 2)
σ 2 = 1 ⇒ 18 ∑ x i −
1 2
( ) ∑ xi 2
18
=1 ( ∵ σ = 1, given )
1
(
⇒ 18 90 − 18β 2 + 36αβ + 72β − ) ( 18 ( α + 2 )
18 ) 2
=1
⇒ 5 − β 2 + 2αβ + 4β − (α + 2) 2 = 1
⇒ 5 − β 2 + 2αβ + 4β − α 2 − 4 − 4α = 1
⇒ α 2 − β 2 + 2αβ + 4β − 4α = 0
⇒ (α − β)(α − β + 4) = 0
⇒α−β= −4
∴ |α − β| = 4 (α ≠ β)
Q84 (1)
1
I m , n = ∫ 0 x m − 1 ⋅ (1 − x) n − 1dx
1 −1
Put x = y + 1 ⇒ dx = dy
( y + 1 )2
y
1 − x = y+1
yn − 1 yn − 1
∴ I m , n = ∫ 0∞ ( − 1)dy = ∫ ∞
0 dy ...(i)
( y + 1 )m + n ( y + 1 )m + n
1
Similarly I m , n = ∫ 0 x n − 1 ⋅ (1 − x) m − 1dx
∞ ym − 1
⇒ Im , n = ∫0 dy ..(ii)
( y + 1 )m + n
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Q85 (3)
x2 y2 31
E : 9 + 4 = 1 C : x2 + y2 = 4
equation of tangent to ellipse is y = mx ± √9m 2 + 4
equation of tangent to circle is
31 31
y = mx ±
√ 4
m2 + 4 ⋯ (ii)
31 31
Comparing equation (i) \& (ii) 9m 2 + 4 = 4 m 2 + 4
⇒ 36m 2 + 16 = 31m 2 + 31
⇒ 5m 2 = 15
⇒ m2 = 3
Q86 (4)
[ ][ ] [ ]
1 0 0 1 0 0 1 0 0
A2 = 0 2 0 0 2 0 = 0 4 0
3 0 −1 3 0 −1 0 0 1
[ ][ ] [ ]
1 0 0 1 0 0 1 0 0
A3 = 0 4 0 0 2 0 = 0 8 0
0 0 1 3 0 −1 3 0 −1
[ ][ ] [ ]
1 0 0 1 0 0 1 0 0
A4 = 0 4 0 0 4 0 = 0 16 0
0 0 1 0 0 1 0 0 1
.
.
.
.
.
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[ ] [ ]
1 0 0 1 0 0
A 19 = 0 2 19 0 , A 20 = 0 2 20 0
3 0 −1 0 0 1
[ ]
1+α+β 0 0
L.H.S = A 20 + αA 19 + βA = 0 2 20 + α2 19 + 2β 0
3α + 3β 0 1−α−β
[ ]
1 0 0
R.H.S = 0 4 0 ⇒ α + β = 0 and 2 20 + α2 19 + 2β = 4
0 0 1
(
⇒ 2 20 + α 2 19 − 2 = 4 )
4 − 2 20
⇒α= = −2
2 19 − 2
⇒β=2
∴β−α=4
Q87 (10)
Given, 4x 2 − 9x + 5 = 0
⇒ (x − 1)(4x − 5) = 0
5
⇒ A. M = 4 , G. M = 1 (QA. M > G. M)
Again, for the series
− 16, 8, − 4, 2……
p th term t p = − 16 ( ) −1 p−1
2
q th term t p = − 16
tp + tq
( ) −1 q−1
2
5
NoW, A. M = = 4 &G. M =
2 √tptq = 1
( )
⇒ 16 2 − 2
1 p+q−2
=1
⇒ ( − 2) 8 = ( − 2) ( p + q − 2 )
⇒ p + q = 10
Q88 (9)
1 dy 1 dx
Let the equation of normal is Y − y = − m (X − x), where, m = dx As it passes through (a, b) b − y = − m (a − x) = − dy (a − x)
⇒ (b − y)dy = (x − a)dx
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y2 x2
by − 2 = 2 − ax + c
It passes through (3,-3)&(4, − 2√2)
9 9
∴ − 3b − 2 = 2 − 3a + c
⇒ − 6b − 9 = 9 − 6a + 2c
⇒ 6a − 6b − 2c = 18
⇒ 3a − 3b − c = 9
Also − 2√2b − 4 = 8 − 4a + c
4a − 2√2 b − c = 12
Also a − 2√2 b = 3 ...(iv) (given)
Q89 (48)
Given, | z + 5 | ≤ 4
⇒ (x + 5) 2 + y 2 ≤ 16 …(1)
Also, z(1 + i) + zˉ (1 − i) ≥ − 10.
⇒ x − y ≥ − 5 ...(2)
From (1) and (2) Locus of z is the shaded region in the diagram.
| z + 1 | represents distance of ′z ′ from Q( − 1, 0) Clearly ' p ′ is the required position of ' z ′ when | z + 1 | is maximum.
∴ P ≡ ( − 5 − 2√2, − 2√2)
|
∴ (PQ) 2 max = 32 + 16√2
⇒ α = 32
⇒ β = 16
Thus, α + β = 48
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Q90 (2)
(
⇒ f ′(x) = 10 x 4 + 2x 3 + 3x 2 + 2x + 1 )
( ( ) )
= 10 x 2 +
1
x2
+2 x+ x
1
+3
= 10
(( ) ( ) )
x+ x
1 2
+2 x+ x
1
+1
= 10 (( ) )
x+ x
1
+1
2
> 0; ∀x ∈ R
∴ f(x) is strictly increasing function. Since it is an odd degree polynomial it will have exactly one real root. Now, by observation
f( − 1) = 3 > 0
f( − 2) = − 64 + 80 − 80 + 40 − 20 + 10
= − 34 < 0
⇒ f(x) has at least one root in (-2,-1) ≡ (a, a + 1)
⇒a= −2
⇒ |a| = 2
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