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M m m 37. Two ice skaters A and B approach each other at right
(a) u (b) u angles. Skater A has a mass 30 kg and velocity 1 m/s and
M M m skater B has a mass 20 kg and velocity 2 m/s. They meet
2m M and cling together. Their final velocity of the couple is
(c) (d) v (a) 2 m/s (b) 1.5 m/s
M m M m
36. A particle of mass m moving with speed v towards east (c) 1 m/s (d) 2.5 m/s
strikes another particle of same mass moving with same
speed v towards north. After striking, the two particles ****
fuse together. With what speed this new particle of mass
2m will move in north-east direction?
v
(a) v (b)
2
v
(c) (d) v 2
2
CHEMISTRY
1. One the Pauling’s electronegativity scale, which 10. The maximum number of molecules is present in
element is next to F. (a) 15 L of H2 gas at STP (b) 5 L of N2 gas at STP
(a) Cl (b) O (c) Br (d) Ne (c) 0.5 g of H2 gas (d) 10 g of O2 gas
2. A molal solution is one that contains one mole of a 11. The volume occupied by one molecule of water
solute in (density 1g cm–3) is
(a) 1000 g of the solvent (a) 18 cm3 (b) 22400 cm3
(b) 1000 mL of the solution 23
(c) 6.023 10 cm 3
(d) 3.0 10 23 cm3
(c) One litre of the solvent 12. How many atoms are contained in a mole of acetic
(d) 1000 g of the solution acid?
3. The number of atoms present in a poly atomic (a) 8 6.02 10 23 atom/mol
molecule is called
(a) atomicity (b) molecularity (b) 4 6.02 10 23 atom/mol
(c) poison’s ratio (d) none of these (c) 6 6.02 10 23 atom/mol
4. Which sample contains the largest number of atoms? (d) None of the above
(a) 1 mg of C4H10 (b) 1 mg of N2 13. Equal volumes of 0.1 M AgNO3 and 0.2 M NaCl are
(c) 1 mg of Na (b) 1 mL of water mixed. The concentration of NO 3 ions in the
5. One mole of P4 molecules contain:
mixture will be
(a) 1 molecule of P (b) 4 molecules of P
(a) 0.1 M (b) 0.05 M (c) 0.2 M (d) 0.15 M
1 14. The molality of 15% (mass/vol.) solution of H2SO4
(c) 6.022 1023 atoms of P
4 of density 1.1 g/cm3 is approximately
(d) 24.088 10 23 atoms of P (a) 1.2 (b) 1.4 (c) 1.8 (d) 1.6
6. The total number of protons, electrons and neutrons 15. Number of electrons in 1.8 mL of H2O is
in 12 g of 126 C is (a) 6.02 10 23 (b) 3.011 10 23
(c) 6.6022 10 23 (d) 60.22 10 23
(a) 1.084 10 25 (b) 6.022 10 23
16. The least number of molecules are contained in
(c) 6.022 10 22 (d) 18 (a) 2 g hydrogen (b) 8 g oxygen
7. The chloride of a metal contains 71% chlorine by (c) 4 g nitrogen (d) 16 g CO2
mass and the vapour density of it is 50. The atomic 17. 11.2 litre of a gas at STP weighs 14 g. The gas could
mass of the metal will be not be
(a) 29 (b) 58 (c) 35.5 (d) 71 (a) N2 (b) CO (c) B2H6 (d) N2O
8. An element A (atomic mass = 75) and B (atomic
18. The volume of 1.204 10 24 molecules of water at
mass = 25) combine to form a compound. The
4o C and 100o C and 1 atm are respectively.
compound contains 75% A by mass. The formula of
(a) 36 mL, 22400 mL (b) 36 mL, 44800 mL
the compound will be
(c) 18 mL, 44800 mL (d) 36 mL, 61247 mL
(a) A2B (b) A3B (c) AB3 (d) AB
19. 1024 molecules of solute are dissolved in 1025
9. When 100 g of ethylene polymerizes to polyethylene
molecules of solvent, the mole fraction of solute in
according to the equation.
solution are
n(CH 2 CH 2 ) ( CH 2 CH 2 ) n . (a) 0.09 (b) 0.08 (c) 0.07 (d) 0.9
The mass of polyethylene produced will be 20. Mole fraction of solute present in an aqueous
n solution having molality equal to 2
(a) g (b) 100 g (a) 0.9653 (b) 0.347 (c) 0.653 (d) 0.0347
2
21. Non-directional orbital is
100
(c) g (d) 100 ng (a) 3s (b) 4f (c) 4d (d) 4p
n
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22. Which d-orbital has different shape from rest of all (d) different with 1, 0 and 2 lone pairs of electrons
d-orbitals? respectively
(a) d x2 y 2 (b) d z 2 (c) d x2 y (d) d xz (e) d yz 33. The hybridization of atomic orbitals of nitrogen in
23. A p-orbital can accommodate:
NO 2 , NO 3 and NH 4 are
(a) 4 electrons (a) sp, sp3 and sp2 respectively
(b) 6 electrons (b) sp, sp2 and sp3 respectively
(c) 2 electrons with parallel spins (c) sp2, sp and sp3 respectively
(d) 2 electrons with opposite spins (d) sp2, sp3 and sp respectively
24. The orbital angular momentum of an electron in 2s- 34. The correct order of radii is
orbital is (a) N < Be < B (b) F– < O2– < N3–
h h h (c) Na < Li < K (d) Fe3+ < Fe2+ < Fe4+
(a) (b) Zero (c) (d) 2 35. Which are true statements among the following?
4 2 2 1) PH5 and BiCl5 do not exist
25. The orbital diagram in which Aufbau Principle is 2) p d bonds are present in SO2
violated is
3) Electrons travel with speed of light
4) SeF4 and CH4 has same shape
5) I 3 has bent geometry
(a) 1, 3 (b) 1, 2, 5 (c) 1, 3, 5 (d) 1, 2, 4
36. In which molecule sulphur atom is not sp3-
26. Which of the following has the maximum number of hybridized?
unpaired electrons?
(a) SO 24 (b) SF4 (c) SF2 (d) None
(a) Mg2+ (b) Ti3+ (c) V3+ (d) Fe2+ 2
27. The electron identified by quantum numbers n and l, 37. Which has sp -hybrization?
(i) n =4, l = 1 (ii) n = 4, l = 0 (iii) n = 3, l = 2 (a) CO2 (b) SO2 (c) N2O (d) CO
(iv) n = 3, l = 1 can be placed in order of increasing 38. Which bond is more polar?
energy from the lowest to highest. (a) Cl – Cl (b) N – F (c) C – F (d) O – F
(a) (iv) < (ii) < (iii) < (i) (b) (ii) < (iv) < (i) < (iii) 39. The structure of IF5 can be best demonstrated as
(c) (i) < (iii) < (ii) < (iv) (d) (iii) < (i) < (iv) < (ii)
28. If the nitrogen atom had electronic configuration 1s7,
it would have energy lower than that of the normal
ground state configuration 1s2 2s2 2p3, because the
electrons would be closer to the nucleus. Yet 1s7 is
not observed because it violates:
(a) Heisenberg’s uncertainty principle
(b) Hund’s rule
(c) Pauli’s exclusion principle
(d) Bohr postulate of stationary orbits
40. Which species does not exist?
29. d z 2 -orbital has
(a) (SnCl6)2– (b) (GeCl6)2–
(a) a lobe along z-axis and a ring along xy-plane (c) (CCl6) 2–
(d) (SiCl6)2–
(b) a lobe along z-axis and a lobe along xy-plane
41. In the formation of N 2 from N2, the electron is lost
(c) a lobe along z-axis and a ring along yz-plane
(d) a lobe and a ring along z-axis from:
30. An element, ‘E’ has the following isotopic (a) A -orbital (b) A -orbital
(c) A * -orbital (d) A * -orbital
composition: 200 A 90% ; 199 A 8% ; 202 A 2% .
42. Among the following compounds the one that is
The average atomic mass of the naturally occurring
polar and has the central atom with sp2-hybridization
element is
(a) H2CO3 (b) SiF4
(a) 201 amu (b) 202 amu (c) 198 amu (d) 200 amu
(c) BF3 (d) HClO2
31. The magnetic moment order is correctly given in
43. How many -bonds and -bonds are there in the
(a) Fe 2 Fe3 Mn 4 Cr 3 molecule of tetracyanoethylene?
(b) Cr 3 Mn 4 Fe 2 Fe3
(c) Cr 3 Mn 4 Fe3 Fe 2
(d) Fe 2 Cr 3 Fe3 Mn 4
32. Molecular shape of SF4, CF4 and XeF4 are (a) Nine - and nine (b) Five - and nine
(a) the same with 2, 0 and 1 lone pair of electrons (c) Nine - and seven (d) Five - and eight
respectively 44. The correct increasing bond angles order is
(b) the same with 1, 1 and 1 lone pair of electrons (a) BF3 < NF3 < PF3 < ClF3
respectively (b) ClF3 < PF3 < NF3 < BF3
(c) different with 0, 1 and 2 lone pairs of electrons (c) BF3 = NF3 < PF3 < ClF3
respectively (d) BF3 > NF3 > PF3 > ClF3
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45. The incorrect statement among the following is 51. The bond between carbon atom (1) and carbon atom
(a) the first ionisation potential of Al is less than the (2) in compoud,
first ionization potential of Mg N C CH CH 2 , involves the hybrid orbitals
(b) the second ionisation potential of Mg is greater (a) sp and sp2 (b) sp2 and sp3
than the second ionisation potential of Na (c) sp and sp 3
(d) sp and sp
(c) the first ionisation potential of Na is less than the
52. The hybridisation of carbon atoms in C C single
first ionisation potential of Mg
(d) the third ionisation potential of Mg is greater bond of HC C CH CH 2 is
than the third ionisation potential of Al (a) sp 3 sp 3 (b) sp 2 sp 3
46. Which one species has the longest bond length?
(c) sp sp 2 (d) sp 3 sp
(a) NO (b) O 2
53. The IP1, IP2, IP3, IP4 and IP5 of an element are 7.1,
(c) O 2 (d) N 2 14.3, 34.5, 46.8, 162.2 eV respectively. The element
47. The ionisation energy will be maximum for the is likely to be
process: (a) Na (b) Si
(a) Ba Ba 2 (b) Be Be 2 (c) F (d) Ca
54. Which has the lowest anion to cation size ratio?
(c) Cs Cs (d) Li Li (a) LiF (b) NaF
o
48. If the ionic radii of K+ and F– are about 1.34 A (c) CsI (d) CsF
each, then the expected values of atomic radii of K 55. The nodal plane in the -bond of ethene is located
and F should be respectively. in
o o (a) the molecular plane
(a) 1.34 and 1.34 A (b) 2.31 and 0.64 A (b) a plane parallel to the molecular plane
o o (c) a plane perpendicular to the molecular plane
(c) 0.64 and 2.31 A (d) 2.31 and 1.34 A which bisects the carbon-carbon -bond at right
49. Which molecule is T-shaped? angle
(a) BeF2 (b) BCl3 (d) a plane perpendicular to the molecular plane
(c) NH3 (d) ClF3 which contains the carbon-carbon -bond
50. Oxygen is divalent, but sulphur exhibits variable 56. The electronegativity of N, O, F, Cl and H are 3.0,
valency of 2, 4 and 6, because 3.5, 4.0, 3.2 and 2.1 respectively. The strongest bond
(a) sulphur is less electronegative than oxygen is
(b) sulphur is bigger atom than oxygen (a) H – N (b) H – O
(c) ionisation potential of sulphur is more than (c) H – F (d) H – Cl
oxygen
(d) of the presence of d-orbitals in sulphur
***
MATHEMATICS
1. 1 5.
2.
6.
3.
7.
4. 8.
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9. 22.
23.
10. 24.
25.
11.
26.
27.
28.
12.
29.
30.
13.
31.
14.
32.
33.
15.
34.
16.
35.
17. 36.
18. 37.
19. 38.
39.
20.
40.
21.
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41. 55.
42.
56.
43.
57.
44.
58.
45.
59.
46. 60.
47. 61.
62.
63.
48.
64.
49.
65.
50.
66.
67.
51.
68.
52.
69.
53.
70.
71.
54.
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72. 86.
73.
87.
74.
88.
75.
76. 89.
90.
77.
91.
78.
92.
79.
93.
94.
80.
95.
81.
96.
82.
97.
83.
98.
84.
99.
100.
85.
***
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ANSWER KEY
PHYSICS
01. (C) 02. (B) 03. (A) 04. (C) 05. (D) 06. (B) 07. (A) 08. (D) 09. (C) 10. (D) 11. (A) 12. (B) 13. (B) 14. (B)
15. (C) 16. (B) 17. (C) 18. (B) 19. (C) 20. (B) 21. (B) 22. (C) 23. (B) 24. (A) 25. (A) 26. (C) 27. (D) 28. (C)
29. (C) 30. (C) 31. (D) 32. (B) 33. (C) 34. (D) 35. (A) 36. (C) 37. (C)
CHEMISTRY
01. (B) 02. (A) 03. (A) 04. (D) 05. (D) 06. (A) 07. (A) 08. (D) 09. (B) 10. (A) 11. (D) 12. (A) 13. (B) 14. (D)
15. (A) 16. (C) 17. (D) 18. (D) 19. (A) 20. (D) 21. (A) 22. (B) 23. (D) 24. (B) 25. (B) 26. (D) 27. (A) 28. (C)
29. (A) 30. (D) 31. (B) 32. (D) 33. (B) 34. (B) 35. (B) 36. (B) 37. (B) 38. (C) 39. (C) 40. (C) 41. (A) 42. (A)
43. (A) 44. (B) 45. (B) 46. (B) 47. (B) 48. (B) 49. (D) 50. (D) 51. (A) 52. (C) 53. (B) 54. (D) 55. (A) 56. (C)
MATHEMATICS
01. (B) 02. (D) 03. (D) 04. (B) 05. (A) 06. (B) 07. (D) 08. (A) 09. (A) 10. (A) 11. (B) 12. (B) 13. (B) 14. (B)
15. (A) 16. (B) 17. (B) 18. (D) 19. (D) 20. (B) 21. (A) 22. (B) 23. (B) 24. (B) 25. (A) 26. (B) 27. (C) 28. (D)
29. (B) 30. (B) 31. (A) 32. (D) 33. (A) 34. (C) 35. (C) 36. (C) 37. (A) 38. (C) 39. (B) 40. (C) 41. (B) 42. (A)
43. (A) 44. (C) 45. (A) 46. (A) 47. (B) 48. (C) 49. (D) 50. (B) 51. (C) 52. (B) 53. (A) 54. (B) 55. (B) 56. (C)
57. (A) 58. (B) 59. (B) 60. (C) 61. (A) 62. (D) 63. (B) 64. (B) 65. (D) 66. (D) 67. (A) 68. (D) 69. (B) 70. (A)
71. (C) 72. (B) 73. (D) 74. (C) 75. (B) 76. (D) 77. (A) 78. (D) 79. (A) 80. (A) 81. (A) 82. (C) 83. (D) 84. (C)
85. (A) 86. (B) 87. (A) 88. (A) 89. (A) 90. (A) 91. (A) 92. (D) 93. (B) 94. (A) 95. (A) 96. (B) 97. (B) 98. (D)
99. (C) 100. (A)
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