JEE

LAKSHYA JEE 2025

CHEMISTRY
DPP: 5
SOLUTIONS

Q1 If liquids A and B form an ideal solution, the (B) ΔHmix = 0

(A) Enthalpy of mixing is zero (C) ΔVmix = 0

(B) Entropy of mixing is zero (D) ΔHmix = ΔVmix ≠ 0

(C) Free energy of mixing is zero

Q7 Which pair from the following will not form an
(D) Free energy as well as the entropy of mixing
ideal solution
are each zero
(A) CCl4 + SiCl4

Q2 The mixture that forms maximum boiling (B) H2 O + C4 H9 OH

azeotrope is: (C) C2 H5 Br + C2 H5 I
(A) Water + Nitric Acid (D) C6 H14 + C7 H16

(B) Ethanol + Water

Q8 Which of the following form is an ideal solution?
(C) Acetone + Carbon disulphide
(A) Ethyl Bromide + Ethyl iodide
(D) Heptane + Octane
(B) Ethyl alcohol + Water
Q3 An azeotropic mixture of two liquids has boiling (C) Chloroform + Benzene
point lower than either of them, when it (D) HCl+ Water
(A) Shows a negative deviation from Raoult's
Q9 The azeotropic mixture of water (b. pt. ∘
100 C )
law
and HCl (b.pt. ∘
85 C ) boils at ∘
108.5 C . When
(B) Shows no deviation from Raoult's law
this mixture is distilled it is possible to obtain
(C) Shows positive deviation from Raoult's law
(A) Pure HCl
(D) Is saturated
(B) Pure water
Q4 A non-ideal solution was prepared by mixing (C) Pure water as well as HCl
30 mL chloroform and 50 mL acetone. The (D) Neither HCl nor H2 O in their pure states
volume of mixture will be
Q10 An aqueous solution of methanol in water has
(A) > 80 mL
vapour pressure
(B) < 80 mL
(A) Less than that of water
(C) = 80 mL
(B) More than that of water
(D) ≥ 80 mL
(C) Equal to that of water
Q5 Azeotropic mixture of HCl and water has (D) Equal to that of methanol
(A) 48% HCl
Q11 Which of the following is true when components
(B) 22.2% HCl
forming an ideal solution are mixed?
(C) 36% HCl
(A) ΔHmix = ΔVmix = 0
(D) 20.2% HCl
(B) ΔHmix < ΔVmix

Q6 Which one of the following is not correct for an (C) ΔHmix = ΔVmix = 1

ideal solution? (D) ΔHmix > ΔVmix

(A) It must obey Raoult's law

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Q12 Azeotropic mixture are

(A) Constant temperature boiling mixture
(B) Those which boils at different temperatures
(C) Mixture of two solids
(D) None of the above

Q13 An ideal solution is that which:

(A) Obeys Raoult's law
(B) Shows positive deviation from Raoult's law
(C) Shows negative deviation from Raoult's law
(D) Has no connection with Raoult's law

Q14 Positive deviation from Raoult's law is shown by

which of the following mixtures?
(A) Benzene and toluene
(B) CHCl3 and Acetone
(C) Ethanol and Water
(D) HCl and Water

Q15 When two liquids A and B are mixed then

their boiling points becomes greater than both
of them.
What is the nature of this solution?
(A) Ideal solution
(B) Normal solution
(C) Negative deviation from ideal solution
(D) Positive deviation from ideal solution

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Answer Key
Q1 (A) Q9 (D)

Q2 (A) Q10 (B)

Q3 (C) Q11 (A)

Q4 (B) Q12 (A)

Q5 (D) Q13 (A)

Q6 (D) Q14 (C)

Q7 (B) Q15 (C)

Q8 (A)

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