lOMoARcPSD|26086987

CHEM - ctto

Biological Science (AMA Computer University)

Scan to open on Studocu

Studocu is not sponsored or endorsed by any college or university

Downloaded by Marnie Muaña Seroy (mmuanaseroy@gmail.com)
 lOMoARcPSD|26086987

A T V
The ____ of a substance is the amount of energy required to raise the temperature of 1 gram
of the substance by 1 degree Celsius.
Specific heat
Calculate ΔG⁰ for a reaction where ΔH⁰ is equal to 36.2 kJ and ΔS ⁰ is equal to 123 J/K at 298
K.
-0.45 kJ
Which of the following is true regarding the concentration of products, for a chemical reaction
that is already at equilibrium, assuming no disruptions to the equilibrium?
The concentrations of products will not change because the forward and reverse rates are
equal.
Freezing and condensation are examples of exothermic process.
True
In exothermic reaction, heat is liberated into the surroundings.
True
Melting and vaporization are examples of exothermic process.
False
A common name for methanol (CH3OH) is wood alcohol. The normal boiling point of methanol
is 64.7 o C and the molar enthalpy of vaporization if 71.8 kJ/mol. The value of ΔS when 2.15
mol of CH3OH (l) vaporizes at 64.7 o C is ___ J/K.
457
Which of the following is true for a chemical reaction at equilibrium?
The rates of the forward and reverse reactions are equal
What kind of thermodynamic system is coffee held in a cup?
Open system
Predict the entropy change (ΔS) if a liquid substance crystallizes into a solid.
ΔS < 0
A system suffers an increase in internal energy of 80 J and at the same time has 50 J of work
done on it. What is the heat change of the system?
+30 J
Calculate the number of kJ necessary to raise the temperature of 80 grams of aluminum from
45 to 65 degrees Celsius. Molar heat capacity of aluminum is 24 J/mole.K.
1.44 KJ
Total change in energy is equal to the sum of the heat and work transferred between the
systems and surroundings.
First Law of Thermodynamics
In thermodynamics, an ___process, also called a constant-volume process.
Isochoric
The increased in internal energy of the system is 80 J and has 70 J of work done on it. What is
the heat change of the system?
+10 J

A T V
Downloaded by Marnie Muaña Seroy (mmuanaseroy@gmail.com)
 lOMoARcPSD|26086987

A T V
The lower the concentration of the weak acid decreases the pH of the buffer solution.
False
The equation that relates enthalpy, temperature and entropy is
Gibbs Free Energy
The equilibrium constant for the reaction is 10. What will be the value of ΔG?
-5744 J
If ΔG is 1, the system is at equilibrium.
False
An equilibrium that strongly favors products has __________
a value of K >> 1.
A photochemical reaction is one of the examples of non-spontaneous reaction.
True
A chemical equilibrium may be established by starting a reaction with __________
All the above
___ is the state at which the concentration ratio of products to reactants is observed to be
constant.
Equilibrium
In thermodynamics, an ___process is a type of thermodynamic process in which the pressure
P of a system remains constant.
Isobaric
____ constant tells how far the reaction has proceeded once the equilibrium is reached.
Equilibrium
Chemical equilibrium is described as a dynamic process because there is a movement in which
the forward and reverse reactions occur at the same rate to reach a point where the amounts
or concentrations of the reactants and products are unchanging with time.
True
Predict the entropy change (ΔS) if the temperature of crystal is increased.
ΔS will decrease
A reversible reaction has ΔG negative for forward reaction. What will be the sign for the
backward reaction?
Negative
The standard enthalpy of formation for a simple substance in its most stable state must be
non-zero
False
Which one of the following thermodynamic quantities is not a state function?
Work
Twenty grams of ammonium nitrate( NH4NO3 ) is dissolve in 125 grams of water in a coffee
cup calorimeter and the temperature drops from 295 oC to 285 o C. Find the value of q for the
calorimeter.

A T V
Downloaded by Marnie Muaña Seroy (mmuanaseroy@gmail.com)
 lOMoARcPSD|26086987

A T V
(hint: treat heat capacity of water as the heat capacity of calorimeter and its contents)
-5430 J
___ states that regardless of the multiple stages or steps of a reaction, the total enthalpy
change for the reaction is the sum of all changes
Hess's Law
In thermodynamics, an ___process is a type of thermodynamic process in which the
temperature T of a system remains constant.
Isothermal
Which phase of matter has the greatest motion and least orderly arrangement?
Gas
If 100 J are required to change the temperature of 10 g of substance B by 5.68 degrees
Celsius, what is the specific heat of substance B?
1.76 J/g. C
If ΔG is positive, the reaction is spontaneous in the reverse direction.
True
Determine the change in the standard entropy, ΔS⁰, for the synthesis of carbon dioxide from
graphite and oxygen:

C(s) + O2(g) → CO2(g)

Standard Entropy in J/mol.K for: C= 5.740 O2 = 205.14 CO2=213.74

2.86 J/mol.K
The standard free energy is found to be zero. What is its equilibrium constant?
1
If the reaction quotient Q has a smaller value than the related equilibrium constant, K,
__________
The reaction is not at equilibrium, and will make more products at the expense of reactants.
Non-spontaneous processes are those that do not take place by themselves or is a type of
reaction which cannot occur without the input of work from an external source.
True
If 25 J are required to change the temperature of 5.0 g of substance A by 2.0 degrees Celsius,
what is the specific heat of substance A?
2.5 J/g. C
The higher the number of types of molecules, the higher is the degree of disorder
True
Reactions in which the products can react to form back the reactants are said to be ___.
Reversible
Spontaneous processes are those that can proceed with any outside intervention.
False

A T V
Downloaded by Marnie Muaña Seroy (mmuanaseroy@gmail.com)
 lOMoARcPSD|26086987

A T V
What happens to the internal energy of the system if work is done on the system?
Internal energy will increase
The equilibrium constant for the formation of hydrogen iodide from hydrogen and iodine is at a
certain temperature.

H2(g) + I2(s) ⇌ 2 HI(g) K = 45

Which of the following is true regarding this equilibrium?

I. The reaction is product favored.

II. The reaction is reactant favored.

III. Equilibrium lies to the right.

IV. Equilibrium lies to the left.

I and III
The ___ is a unit of energy defined as the amount of heat needed to raise the temperature of
1 cm³ of water by one degree Celsius.
Calorie
Calculate the enthalpy (ΔH) for the process in which 45.0 grams of water is converted from
liquid at 10° C to vapor at 30° C.
126Kj
An isometric process, is a thermodynamic process during which the volume of the closed
system undergoing such a process remains constant.
True
What happens to the internal energy of the system if work is done by the system?
Internal energy will decrease

A T V
Downloaded by Marnie Muaña Seroy (mmuanaseroy@gmail.com)
 lOMoARcPSD|26086987

A T V

A T V
Downloaded by Marnie Muaña Seroy (mmuanaseroy@gmail.com)