Notes Chemistry 1 501 566

Heat of Reaction Page: 501
Big Ideas Details Unit: Thermochemistry (Heat)

Sample Problem:
Q: Calculate the energy produced by the reaction:
Ca + FeO → CaO + Fe
A: First we look up our heats of formation. We need to remember to change the

sign of any compounds that we are breaking apart (reactants), and keep the sign
the same for compounds that we are creating (products):
Ca + FeO → CaO + Fe
kJ
0 mol 272 mol
kJ 634.92 mol
kJ kJ
0 mol
sign changed
because we’re
“taking apart”
FeO
To find the heat of reaction, we simply add up all of the heat of formation
numbers for each compound in the reaction:
(272 mol
kJ )  (634.92 kJ )  361 kJ
mol mol
Because the coëfficients are all one, that means we can cancel moles to give:
(272kJ)  (634.92kJ)  361kJ
The last step is to change the sign of the answer. Our calculation tells us that
the enthalpy change for the reaction is −361 kJ. That means the products have
361 kJ less enthalpy than the reactants did. That energy was released as heat,
which means the heat was produced by the reaction.
We always represent heat as a positive quantity in chemical reactions. If heat is

produced, it is a product so it goes on the right. This gives us:
Ca + FeO → CaO + Fe + 361 kJ
Use this space for summary and/or additional notes:
Chemistry 1 Mr. Bigler

If we had gotten a positive number for the heat of reaction, that would mean
that the products have more enthalpy content than the reactants, which means
we would have had to add heat in order to make the reaction happen. In this
case, heat would be a reactant and would go on the left.
For example, in the reaction:
N2 + O2 → 2 NO
We see that N2 and O2 are elements with an enthalpy of formation of zero, and
kJ . Because the coëfficient for NO
NO has an enthalpy of formation of +90.2 mol
is 2, this means the enthalpy of reaction is +180.4 kJ. (Using heat of reaction
with stoichiometry will be explained on the following pages.) The products have
more enthalpy than the reactants, which means we have to add energy to make
the reaction happen. This means heat is a reactant, so it goes on the left:
N2 + O2 + 180.4 kJ → 2 NO

Heat of Reaction and Stoichiometry

Heat of reaction works just like the coëfficients in a stoichiometry problem.
Because heats of reaction are expressed in molkJ , we need to multiply each
substance’s heat of formation by its coëfficient in order to calculate its contribution

to the heat of reaction.
Sample Problem:
Q: Calculate the heat produced by the reaction:
3 Ca + 2 AlCl3 → 3 CaCl2 + 2 Al
A: Again we look up our heats of formation. However, now, we need to both

remember to use positive vs. negative numbers correctly and multiply each heat
of formation by its coëfficient in the chemical equation:
3 Ca + 2 AlCl3 → 3 CaCl2 + 2 Al
kJ )
3(0 mol 2(704 mol
kJ ) 3(795.8 mol
kJ ) kJ )
2(0 mol
0 kJ 1 408kJ 2 387.4 kJ 0 kJ
As before, to find the heat of reaction, we add the heats of formation:
(1 408kJ)  (2 387.4 kJ)  979kJ
The result tells us that the reaction produces 979 kJ of heat when the number of
moles of each reactant and product are the same as the coëfficients. (This is
sometimes described as “979 kJ per mole of reaction”.) We can write the
equation as follows:
3 Ca + 2 AlCl3 → 3 CaCl2 + 2 Al + 979 kJ
Again, notice that we changed the sign of the heat when we wrote it in the
reaction because heat is produced, which means (positive) heat is a product of
the reaction.
In this reaction, suppose we had used 4.5 mol of Ca (and excess AlCl3). To find
the heat produced, we would calculate it as if the 979 kJ were the coëfficient for
heat in the chemical equation.
Using our stoichiometry “input/output machine”, 3 mol of Ca produces 979 kJ of

heat. This means that to get from 3 to 979, we have to divide by 3 and multiply
by 979. This gives:
4.5mol Ca 979 kJ
  1 469 kJ of heat produced
1 3mol Ca

Homework Problems
Using enthalpy of formation (H of ) data in “Table BB. Thermodynamic Data” in your
Chemistry Reference Tables, on page 559, calculate the heat of reaction for each of
the following chemical reactions and write out the reaction with the heat in the
correct place.
1. Pb + FeSO4 → PbSO4 + Fe
Answer: H o  9 kJ Pb + FeSO4 + 9 kJ → PbSO4 + Fe
2. 2 C2H2 + 5 O2 → 4 CO2 + 2 H2O
Answer: H o  2 511kJ 2 C2H2 + 5 O2 → 4 CO2 + 2 H2O + 2 511 kJ
3. C6H12O6 + 6 O2 → 6 CO2 + 6 H2O
Answer: H o  2 537kJ C6H12O6 + 6 O2 → 6 CO2 + 6 H2O + 2 537 kJ

Bond Energies Page: 505
Bond Energies
Unit: Thermochemistry (Heat)
MA Curriculum Frameworks (2016): HS-PS1-4
MA Curriculum Frameworks (2006): N/A
Mastery Objective(s): (Students will be able to…)
 Identify the bonds in molecular compounds and look up their bond energies.
 Calculate the heat produced or consumed by a reaction based on bond energy
calculations.
Success Criteria:
 Bond energies have the correct sign and the correct units based on where
they appear in the chemical equation.
 Heat of reaction calculated from bond energies agrees with heat of reaction
calculated from heat of formation data.
Tier 2 Vocabulary: bond
Language Objectives:
 Explain how heat of reaction is calculated using bond energies.
Notes:
Ionic compounds form crystals that have straightforward ratios of cations to anions,
which means it is practical to publish a table of the heats of formation of common
ionic compounds and to calculate the heat of reaction from heat of formation data.
Molecular compounds, however, can form long chains, and there are thousands
upon thousands of common molecular compounds.
For most molecular compounds, instead of attempting to publish an exhaustive list

of heat of formation data, it is much simpler to publish a table of the energy it takes
to dissociate the individual bonds in molecular compounds. This way, it is possible
to estimate the heat of reaction by simply adding up the energies for breaking or
forming the individual bonds in a compound.
These bond energies are shown in “Table AA. Bond Dissociation Energies & Bond
Lengths” in your Chemistry Reference Tables on page 558. Note that the table is
“bond dissociation energies.” This means that the numbers represent the amount
of energy needed to dissociate (break) the bonds listed. If it takes energy (a positive
number) to break a bond, that means energy is released (a negative number) when
the bond is formed. This means we can use bond energies to calculate the enthalpy
of formation of a compound, but we need to remember that the bond energies are
negative when bonds are formed.

Here are bond dissociation energies for some bonds commonly found in organic
compounds. A more extensive list can be found in “Table AA. Bond Dissociation
Energies & Bond Lengths” on page 558 of your Chemistry Reference Tables.
Bond C−C C=C C≡C C−H C−O C=O O=O O−H
Bond Dissociation
346 602 835 411 358 799 494 459
Energy* ( mol
kJ )
Sample problem:
Use bond dissociation energy data to predict the energy of reaction for the
combustion of methane:
CH4 + 2 O2 → CO2 + 2 H2O
This actually means:
H
O
H C H + 2 O O → O C O + 2 H H
H
break break form
form 2 O−H
4 C−H + 2 1 O=O → 2 C=O + 2
bonds
bonds bond bonds
4(411 kJ) + 2(494 kJ) → 2(−799 kJ) + 4(−459 kJ)
1 644 kJ + 988 kJ + −1 598 kJ + −1 836 kJ
Note that numbers on the left are positive, because we are dissociating (breaking)
those bonds, and numbers on the right are negative because we are forming those
bonds.
As with heat of reaction calculations, we add the energies for each of the individual
molecules:
1 644 kJ + 988 kJ + (−1 598 kJ) + (−1 836 kJ) = −802 kJ
*
These are bond dissociation energies are for homolytic dissociation (i.e., the electrons are
equally split between the two atoms). Heterolytic bond dissociation energies (where the
electrons split unequally) are always higher.

We can now write the reaction as:
CH4 + 2 O2 → CO2 + 2 H2O + 802 kJ
This agrees with the heat of reaction that we would calculate from enthalpy of
formation data:
Compound H f  molkJ 
CH4 (g) −74.8
O2 (g) 0
CO2 (g) −393.5
H2O (g) −241.8
CH4 + 2 O2 → CO2 + 2 H2O

74.8 mol
kJ kJ )
2(0 mol 393.5 mol
kJ 2(241.8 mol
kJ )
+74.8 kJ 0 kJ 393.5kJ 483.6 kJ

74.8 kJ + 0 + (−393.5 kJ) + (−483.6 kJ) = −802.3 kJ
Note that adding the bond dissociation energies for a compound does not give the
compound’s enthalpy of formation. As an example, recall that the heat of formation
kJ of heat energy to break an O=O double bond.
of O2 is zero, but it takes 494 mol

Limitations of Using Bond Energy to Calculate Heat of Reaction
The above example with methane is one of the few instances where bond energies
and heats of formation give the same values. This is often not the case. For
example, if you calculate the heat of reaction for the combustion of acetylene:
2 H C C H + 5 O2 → 4 CO2 + 2 H2O + heat
you would get −2 511 kJ using heat of formation data, but −4 914 kJ using bond
energies.
Enthalpies of formation are well-defined and precise, meaning that different people
could measure them and expect to get the same answer. Average bond enthalpies,
however, can vary widely depending on which molecules were used to gather the
data. (In fact, the numbers may vary significantly from one published table to
another.)
For example, there are many different molecules with C–H bonds. The bond energy
of a C–H bond in CH4 is very different from the bond energy of a C–H bond in
acetylene.
The bond energies found in the bond energy tables for the bonds involved in the
combustion of methane are based on:
Bond C−H C=O O=O O−H

Energy  mol
kJ
 411 799 494 459
Based on CH4 CO2 O2 H2O
Needless to say, the basis for each of these bond energies is exactly the same as the
bonds broken or formed in the combustion of methane. It is therefore not
surprising that using bond energies gives the same result. However, it takes much
more energy to break the C−H bond in acetylene, which is part of the reason that
using bond energies does not give the correct answer for acetylene.
Because average bond enthalpies are much less accurate than enthalpies of
formation, calculating heat of reaction from bond energies should only be used for a
quick estimation, or as a last resort when heat of formation data are not available.

Homework Problem
1. Propane (C3H8) has the following structure:
H H H
H C C C H
H H H
Using the bond energy data from this chapter or on page 558 of your
Chemistry reference tables, compute the heat of reaction for the complete
combustion of propane:
C3H8 + 5 O2 → 3 CO2 + 4 H2O + heat
Answer: −2 016 kJ (Note: calculating from H of values gives 2 044 kJ)

Summary: Thermochemistry (Heat) Page: 510
Summary: Thermochemistry (Heat)

Unit: Thermochemistry (Heat)
List the main ideas of this chapter in phrase form:
Write an introductory sentence that categorizes these main ideas.
Turn the main ideas into sentences, using your own words. You may combine
multiple main ideas into one sentence.
Add transition words to make your writing clearer and rewrite your summary below.

Introduction: Kinetics & Equilibrium Page: 511
Big Ideas Details Unit: Kinetics & Equilibrium
Introduction: Kinetics & Equilibrium

Unit: Kinetics & Equilibrium
Topics covered in this chapter:
Collision Theory ........................................................................................... 513
Rate of Reaction (Kinetics) .......................................................................... 516
Equilibrium .................................................................................................. 520
Le Châtelier’s Principle ................................................................................ 527

Introduction: Kinetics & Equilibrium Page: 512
Standards addressed in this chapter:
Massachusetts Curriculum Frameworks & Science Practices (2016):
HS-PS1-4 Develop a model to illustrate the energy transferred during an
exothermic or endothermic chemical reaction based on the bond energy
difference between bonds broken (absorption of energy) and bonds formed
(release of energy).
HS-PS1-5 Construct an explanation based on kinetic molecular theory for why
varying conditions influence the rate of a chemical reaction or a dissolving
process. Design and test ways to slow down or accelerate rates of processes
(chemical reactions or dissolving) by altering various conditions.
HS-PS1-6 Design ways to control the extent of a reaction at equilibrium (relative
amount of products to reactants) by altering various conditions using Le
Châtelier’s principle. Make arguments based on kinetic molecular theory to
account for how altering conditions would affect the forward and reverse
rates of the reaction until a new equilibrium is established.
Massachusetts Curriculum Frameworks (2006):

7.5 Identify the factors that affect the rate of a chemical reaction (temperature,
mixing, concentration, particle size, surface area, catalyst).
7.6 Predict the shift in equilibrium when a system is subjected to a stress (Le
Châtelier’s principle) and identify the factors that can cause a shift in
equilibrium (concentration, pressure, volume, temperature).

Collision Theory Page: 513
Collision Theory
MA Curriculum Frameworks (2016): HS-PS1-4, HS-PS1-5
MA Curriculum Frameworks (2006): 7.5
 Use collision theory to explain activation energy and when a reaction does or
does not occur.
Success Criteria:
 Explanations refer to Kinetic Molecular Theory (KMT).
 Explanations account for the role of activation energy.
Tier 2 Vocabulary: collision
 Explain the process of reactants colliding with enough energy to react and
form products.
Notes:
Recall that Kinetic Molecular Theory (KMT) states:
 Gases are made of very large numbers of molecules.
 Molecules are constantly moving (obeying Newton’s laws of motion), and
their speeds are constant.
 Molecules are very far apart compared with their diameter.
 Molecules collide with each other and walls of container in elastic collisions.
 Molecules behaving according to KMT are not reacting or exerting any other
forces (attractive or repulsive) on each other.

When we studied KMT earlier this year, we mentioned that the last bullet point did
not mean that reactions did not occur, but that they were covered by collision
theory, not KMT.
Collision theory states that:

 Molecules can be modeled as rigid spheres.
 Molecules move according to KMT.
 When molecules collide, kinetic energy (proportional to temperature) is
transferred.
 If the molecules collide with enough energy to break existing chemical bonds,
and if they are oriented in a way that allows the new bonds to form, a
reaction occurs.
 If a reaction does not occur, the reactants “bounce” off each other as
described by KMT.
For example, consider the reaction: NO3 + CO → NO2 + CO2
effective collision: a collision with enough energy that it leads to formation of

products
ineffective collision: a collision that does not have enough energy to lead to
formation of products.
mechanism: the details of which molecules collide and in what order and
orientation in order for the reaction to take place.

The progress of the reaction vs. energy can be graphed in a “reaction coördinate”
diagram:
reaction coördinate diagram: a graph that shows energy vs. progress of a chemical
reaction.
enthalpy of reaction (ΔHrxn): the difference between the enthalpy of the products
and the enthalpy of the reactants. The enthalpy change is the overall heat
produced or consumed by the chemical reaction.
activation energy (ΔEa): minimum kinetic energy needed for a collision to produce
the transition state (and therefore proceed to form products).
transition state (or activated complex): the configuration of all molecules at the
instant an effective collision happens. In the transition state, all of the energy
needed by the reaction has been converted to enthalpy.

Rate of Reaction (Kinetics) Page: 516
Rate of Reaction (Kinetics)

 List and explain factors that affect the rate of a chemical reaction.
Success Criteria:
 Descriptions convey how each factor affects the rate of reaction.
Tier 2 Vocabulary: intermediate
 Explain what it means for a reaction to happen faster vs. slower, and how
each factor affects the reaction rate.
Labs, Activities & Demonstrations:

 Drop of food coloring in hot vs. cold water.
Notes:
reactants: the compounds consumed in the chemical reaction; compounds that
react.
products: the compounds created by the chemical reaction; compounds that are
produced.
intermediates: compounds that are produced in one step of a multi-step reaction

and consumed by a later step.

reaction rate (k): the rate at which products are formed in a chemical reaction,
mol M mol
usually expressed in units of: Ls or s (where M = molarity = L )
The reaction rate is related to the activation energy. A reaction with higher
activation energy will happen more slowly, because fewer of the collisions will
have enough energy to enable the molecules to react. Conversely, a reaction
with lower activation energy will happen more quickly.
RT
RT Ea
The equation for rate of reaction is: ln(k)   or ke
Ea
Quantitative rate calculations are studied in AP® Chemistry. In this course, you
need to understand how the equation shows that a higher temperature will
speed up the reaction (larger value of k), and a higher activation energy will
slow down the reaction (smaller value of k).
rate-limiting step (or rate-determining step): the step that determines the overall
rate of the reaction. In a multi-step reaction, the rate-limiting step is the
slowest step.
For example, in the multi-step reaction:
A B C D
 A → B will happen faster than B can get used up, so B will accumulate and the
first reaction will not affect the overall rate.
 C → D will happen fast, which means as soon as C is produced, it will react to
produce D.
Therefore, the rate of B → C, which happens slowly, is what determines the
overall rate of the reaction A → D.
catalyst: a substance that speeds up a reaction by lowering the activation energy of

(and therefore speeding up) the rate-limiting (slowest) step.

Factors that Affect Reaction Rates
 concentration of reactants: higher concentration means more frequent
collisions = faster rate. (Only applies to molecules involved in the rate-
determining step.) For gases, higher pressure = higher concentration.
 surface area of reactants: more surface area means higher probability of a
collision = faster rate.
 temperature: higher temperature = faster because faster-moving molecules
collide more often, and because faster-moving molecules have more kinetic
energy to overcome the activation energy.
 nature of the reactants: weak bonds are easier to break than strong bonds.
Reactions involving dissolved ions are very fast, because bonds are already
broken.
 catalysts: catalysts speed up reactions in any of several ways:
o bring molecules into the correct orientation for an effective collision
(equivalent to increasing the concentration and/or surface area)
o assist in breaking of bonds in the reactant(s) and/or formation of bonds in
the products (equivalent to changing the nature of the reactants and/or
lowering the activation energy)
Catalysts are not reactants; they are not consumed by the reaction.

Homework Problems
Consider the following decomposition reaction:
2 N2O5 → 2 N2 + 5 O2
This reaction happens in three steps:
1. 2 N2O5 + 2 H2O → 4 HNO3 fast
2. 2 HNO3 → N2 + 3 O2 + H2 slow
3. 2 H2 + O2 → 2 H2O very fast
Answer the following questions:

1. Which compounds are intermediates in this reaction?
2. If you wanted to speed up the overall reaction, which of the three steps
would you try to speed up? Explain why, and give an example of how you
might do this.

Equilibrium Page: 520
Equilibrium
 List and explain factors that affect the equilibrium of a chemical reaction.
 Write equilibrium expressions from chemical equations and chemical
equations from equilibrium expressions.
Success Criteria:
 Equilibrium expressions have products on top and reactants on the bottom.
 Equilibrium expressions have coëfficients shown as exponents.
Tier 2 Vocabulary: forward, backward, expression
 Explain how different factors affect the equilibrium of a chemical reaction.
Notes:
reversible reaction: a reaction that proceeds in both forward and backward
directions. Usually written with double half-arrows:
N2 (g)  3H2 (g) 2NH3 (g)
dynamic chemical equilibrium: reaction is happening in both directions, but the

changes balance each other, so the concentrations of reactants & products
remain constant. At equilibrium:
rateforward reaction = ratereverse reaction or k f  kr
concentration: the amount of a compound dissolved in a given amount of solution,

usually expressed in mol
L
(moles of the compound per liter of solution).
A shorthand way to write the concentration of a compound is to place the

chemical formula in square brackets. For example, [NH3] means “the
concentration of NH3 in mol
L
”.

Arrows Used in Chemical Equations
Arrow Meaning
A + B react to produce C + D
Either there is little or no reverse
A B C D
reaction, or no information is given
about equilibrium.
A + B are in equilibrium with C + D
A B C D No information is given about whether
products or reactants are favored.
Products are favored. (I.e., the
A B C D
concentrations of products are higher
than the concentrations of reactants.)
Reactants are favored. (I.e., the
A B C D
concentrations of reactants are higher
than the concentrations of products.)
A and B are different resonance
A B structures of the same compound.
This is different from a chemical
reaction that is at equilibrium.

equilibrium expression: a mathematical expression relating the concentrations of
the products and reactants at equilibrium. For the reaction:
N2  3H2 2NH3
the equilibrium expression is:
[NH3 ]2
K eq 
[N2 ][H2 ]3
where [NH3] means the molarity of NH3 (the concentration in mol ).

L
The equilibrium expression comes from collision theory. In order for N2 and H2
to react, one N2 and 3 H2 molecules need to find each other. The probability of
this 4-way collision is related to the product of the concentrations of each of the
molecules involved, i.e., [N2] [H2] [H2] [H2] or [N2] [H2]3. Notice that the
coëfficients in the equation became exponents in the equilibrium expression.
The reverse reaction requires 2 NH3 molecules to collide; the probability of this
collision is the product of the concentrations, [NH3] [NH3] or [NH3]2. Again, the
coëfficient “2” became the exponent.
For the equilibrium expression, we write the concentrations of products on the

top and reactants on the bottom. (The reason for this comes from the rate laws
for the forward and reverse reactions. Rate laws are beyond the scope of this
course, but are studied in AP Chemistry.) However, for our purposes, it also
means that an equilibrium constant greater than 1 means we have more
products, and an equilibrium constant less than 1 means we have more
reactants.
equilibrium constant (Keq): when we plug the concentrations (in mol ) for each of the
L
products and reactions into the equilibrium expression, we get a value for Keq.
If Keq > 1 then there are more products than reactants, and we say that the
“equilibrium lies to the right”.
If Keq < 1 then there are more reactants than products, and we say that
“equilibrium lies to the left”.
If Keq = 1 then there are equal amounts of reactants and products, and we say
that the reactants and products are equally favored.
Keq depends on temperature, but is constant for a given reaction at a given

temperature.

Equilibrium Constant vs. Free Energy
In the section on Thermodynamics, starting on page 489, we saw that the extent of
the reaction (how much reaction occurs) depends on the change in Gibbs free
energy of the reaction.
The equilibrium constant is related to the Gibbs free energy by the equation:
G
G  RT ln(Keq ) or Keq  e RT
While the calculations are beyond the scope of this course, you should understand
that a higher value of ΔG corresponds with a higher value of the equilibrium
constant Keq:
Sample Problems:
Q: Write the equilibrium expression for the chemical reaction 2H2  Cl2 2HCl
A: Products go on the top and reactants go on the bottom.
Coëfficients become exponents.
[HCl]2
K eq 
[H2 ]2 [Cl2 ]
[CO2 ]4 [H2O]2
Q: Write the chemical equation for the equilibrium expression: K eq 
[C2H2 ]2 [O2 ]5
A: The denominator becomes the reactants (on the left), and the numerator
becomes the products (on the right). Exponents become coëfficients:
2 C2H2  5O2 4 CO2  2H2O

Q: Calculate the value of the equilibrium constant for the reaction
2 NOBr 2 NO  Br2 if the concentration of NOBr is 3.00 M, the concentration
of NO is 0.750 M, and the concentration of Br2 is 0.200 M
A: The equilibrium expression is:
[NO]2 [Br2 ]
K eq 
[NOBr]2
Plugging in the concentrations, we get:
(0.750)2 (0.200)
Keq   0.0125
3.002
Note that the units for equilibrium constants are tricky, because each
concentration is in mol
L
. This means that if a concentration is squared, the units
2
become (mol
L
)2  mol2 . This means that every equilibrium constant has its own
L
units, depending on the number of molecules that take part in the forward and
reverse reactions.
From the equilibrium expression, the units of the equilibrium constant for this
expression happens to be:
( mol )2 ( mo l
)
L L
 mol
L
( mol
L
)2
Working with the units for the equilibrium constant is beyond the scope of this
course.

Homework Problems
Write the expression for the equilibrium constants for each of the following
reactions.
1. Xe  3F2 2 XeF6
2. CH4  2H2S CS2  4 H2
3. 3 CO2  4 H2O C3H8  5 O2
4. Write the chemical equation for the equilibrium system given by the
expression:
[H2O]2 [O2 ]
K eq 
[H2O2 ]2
expression:
[NH3 ]2
K eq 
[N2 ][H2 ]3
expression:
[HCl]4 [O2 ]
K eq 
[H2O]2 [Cl2 ]2

7. A reaction vessel contains 0.150 M CH4, 0.233 M H2O, 0.259 M H2, and
0.513 M CO. If the equilibrium reaction is CH4  H2O CO  3H2 , write the
equilibrium expression and calculate the value of Keq.
Answer: Keq = 0.255
8. A 10 L flask contains 0.128 mol of CO, 0.155 mol of H2 and 0.0244 mol of
CH3OH. If the equilibrium reaction is CH3OH CO  2H2 , write the
equilibrium expression and calculate the value of Keq.
(Note: you will need to divide each number of moles by 10 L to get the
concentrations in mol
L
.)
Answer: Keq = 0.001 26

Le Châtelier’s Principle Page: 527
Le Châtelier’s Principle
 Use Le Châtelier’s Principle to predict a shift in equilibrium in response to a
change.
Success Criteria:
 Prediction correctly describes the shift in equilibrium when the concentration
of one chemical species is changed.
Tier 2 Vocabulary: stress
 Explain how a change provokes a response.
Notes:
If a reaction is at equilibrium, the reaction will resist any change with a
corresponding change that shifts the reaction back to its equilibrium. Because Keq is
a constant, after the equilibrium shifts, the value of Keq will be the same as it was
before the change.
In plain English, if you change something, the equilibrium will shift to partly undo
the change. This principle is called Le Châtelier’s Principle, named after the French
chemist Henry Louis Le Châtelier who first proposed the idea.
For example, consider the reaction:

N2 (g) + 3 H2 (g) ⇋ 2 NH3 (g) + 92.1 kJ
[NH3 ]2
For this reaction, Keq   835 at 25 °C.
[N2 ][H2 ]3
Suppose we started with [N2] = 0.05 M, [H2] = 0.3 M, and [NH3] = 1.06 M.
If we add more [H2], the reaction would use more H2, and make more NH3. If we
kept adding H2 until [H2] = 0.4 M, we would have [N2] = 0.026 M, and [NH3] = 1.18 M.
As you can see, adding more H2 caused the reaction to use up more N2 and make
more NH3.

Le Châtelier’s Principle tells us that we don’t have to perform the equilibrium
calculation to qualitatively predict what will happen. We can just look at the
equation:
N2 (g) + 3 H2 (g) ⇋ 2 NH3 (g) + 92.1 kJ
if we add more H2, the equilibrium will shift to use more of it up. This means the
equilibrium will shift to the right, also using up more N2 and making more NH3.
On the other hand, if we added NH3, the equilibrium would instead shift to the left
to use up some of the NH3, and make more N2 and H2.
Action Equilibrium shift

Add N2 or H2 to the right
Remove N2 or H2 to the left
Add NH3 to the left
Remove NH3 to the right
Increase the temperature
to the left
(add heat)
Note that the value of Keq is different at different temperatures. Adding reactants or
products doesn’t change the value of Keq, but changing the temperature does. Le
Châtelier tells us that adding heat must shift the equilibrium to the left. The
equilibrium shift occurs because increasing the temperature results in a lower value
of Keq for this equation.
Quantitative equilibrium calculations and the relationship between the equilibrium

constant and thermodynamics are studied in more depth in AP® Chemistry.

Homework Problems
Consider the chemical equation:
6H2 (g)  P4 (g) 4 PH3 (g)  53.5kJ
1. Indicate which direction the equilibrium would shift as a result of each of the
following:
a. Adding P4 c. Removing H2
b. Removing PH3 d. Decreasing the temperature
2. Write the equilibrium expression for the above reaction.
3. The value of Keq for this reaction is 4.44 at 25 °C. If the reaction is at
equilibrium at 25 °C, the concentration of H2 is 1.00 M and the concentration
of P4 is 0.025 M, what is the concentration of PH3?
Answer: [PH3] = 0.58 M
4. If the reaction is cooled to 4 °C, the value of the equilibrium constant

increases to 4.77. Is this consistent with the prediction made by Le
Châtelier’s Principle in question #1d above? Explain.

Summary: Kinetics & Equilibrium Page: 530
Summary: Kinetics & Equilibrium


Introduction: Acids & Bases Page: 531
Big Ideas Details Unit: Acids & Bases
Introduction: Acids & Bases

Unit: Acids & Bases
Topics covered in this chapter:
Acids & Bases ............................................................................................... 532
pH & Indicators ............................................................................................ 537
pKa & Buffers ............................................................................................... 544
Standards addressed in this chapter:

Massachusetts Curriculum Frameworks & Science Practices (2016):
HS-PS1-9(MA) Relate the strength of an aqueous acidic or basic solution to the
extent of an acid or base reacting with water as measured by the hydronium
ion concentration (pH) of the solution. Make arguments about the relative
strengths of two acids or bases with similar structure and composition.
Massachusetts Curriculum Frameworks (2006):
8.1 Define the Arrhenius theory of acids and bases in terms of the presence of
hydronium and hydroxide ions in water and the Brønsted-Lowry theory of
acids and bases in terms of proton donors and acceptors.
8.2 Relate hydrogen ion concentrations to the pH scale and to acidic, basic, and
neutral solutions. Compare and contrast the strengths of various common
acids and bases (e.g., vinegar, baking soda, soap, citrus juice).
8.3 Explain how a buffer works.

Acids & Bases Page: 532
Acids & Bases

Unit: Acids & Bases
MA Curriculum Frameworks (2016): HS-PS1-9(MA)
 Define acids and bases based on both the Arrhenius and Brønsted-Lowry
theories and give examples.
 Classify acids and bases as strong or weak.
 Identify conjugate acid and base pairs.
Success Criteria:
 Prediction correctly describes the shift in equilibrium when the concentration
of one chemical species is changed.
Tier 2 Vocabulary: stress
 Explain how a change provokes a response.
Notes:
Acids are one of the first substances that come to mind when we think of chemistry.
Acids are the dangerous chemicals that mad scientists in movies throw at people,
and the chemicals that impressively dissolve metals and other substances right
before your eyes.
Acids have held this sort of fascination for centuries. The American chemist Ira
Remsen wrote the following wonderful anecdote of his first encounter with them:
While reading a text book of chemistry, I came upon the statement, “nitric acid
acts upon copper.” I was getting tired of reading such absurd stuff and I
determined to see what this meant. Copper was more or less familiar to me,
for copper cents were then in use. I had seen a bottle marked “nitric acid” on a
table in the doctor’s office where I was then “doing time!” I did not know its
peculiarities, but I was getting on and likely to learn. The spirit of adventure
was upon me. Having nitric acid and copper, I had only to learn what the words
“act upon” meant. Then the statement “nitric acid acts upon copper,” would
be something more than mere words.

All was still. In the interest of knowledge I was even willing to sacrifice one of
the few copper cents then in my possession. I put one of them on the table;
opened the bottle marked “nitric acid;” poured some of the liquid on the
copper; and prepared to make an observation. But what was this wonderful
thing which I beheld? The cent was already changed, and it was no small
change either. A greenish blue liquid foamed and fumed over the cent and
over the table. The air in the neighborhood of the performance became
colored dark red. A great cloud arose: This was disagreeable and suffocating—
how should I stop this?
I tried to get rid of the objectionable mess by picking it up and throwing it out
the window, which I had meanwhile opened. I learned another fact—nitric acid
not only acts upon copper but it acts upon fingers. The pain led to another
unpremeditated experiment. I drew my fingers across my trousers and another
fact was discovered. Nitric acid acts upon trousers.
Taking everything into consideration, that was the most impressive

experiment, and, relatively, probably the most costly experiment I have ever
performed. I tell of it even now with interest. It was a revelation to me. It
resulted in a desire on my part to learn more about that remarkable kind of
action. Plainly the only way to learn about it was to see its results, to
experiment, to work in a laboratory.
However, not all acids are this dangerous, especially when they are more dilute. We
eat and drink vinegar (dilute acetic acid), orange juice (which contains citric acid),
and Coca-Cola (which contains phosphoric acid).
acid: a substance that can produce H3O+ ions in water, release H+ ions* in solution,
and/or accept electrons from another substance.
base: the “opposite” of an acid; a substance that can produce OH− ions in water,
accept H+ ions in solution and/or donate electrons to another substance.
* + +
Note that an H ion is a proton. Chemists often use the term “proton” in place of “H ion”
for convenience. Thus an acid is a compound that releases protons in water. These
+
protons are just the H ions—there’s no nuclear weirdness going on!

Some Properties of Acids & Bases
Acids
 taste sour  produce H3O+ ions in water
 react with some metals (i.e., the (Arrhenius definition)
ones above hydrogen on the  release H+ ions
activity series) (Brønsted-Lowry definition)
 dissolve plants  accept electrons
(Lewis definition)
Bases
 taste bitter  produce OH− ions in water
 feel “slippery” (like soap) (Arrhenius definition)
 dissolve people (skin)  accept H+ ions
(Brønsted-Lowry definition)
 give electrons
(Lewis definition)
dissociation: to dissolve by splitting into positive and negative ions

Acids & bases dissociate in water.
Strong acids & bases dissociate completely; weak acids & bases only dissociate
partially.
For example:
HCl → H+ + Cl−
NaOH → Na+ + OH−
neutralization: a reaction in which an acid and a base react to produce a salt (a type
of ionic compound) plus water. For example:
HNO3 + KOH → KNO3 + H2O
(acid) + (base) → (salt) + (water)

strong acid: an acid that dissociates completely in water and produces H+ ions,
which then convert H2O molecules to H3O+ ions. Strong acids include HCl, HBr,
HI, H2SO4, HNO3, and HClO4.
weak acid: an acid that only partially dissociates in water. HF is an example of a

weak acid:
HF H+ + F−
strong base: a base that dissociates completely in water and produces OH− ions.
Strong bases include all of the group 1 hydroxides (LiOH, NaOH, KOH, etc.), plus
the group 2 hydroxides Ca(OH)2, Sr(OH)2, and Ba(OH)2.
weak base: a base that only partially dissociates in water. NH3 is an example of a
weak base:
NH3 + H2O NH4+ + OH−
conjugates: the acid & base forms of a compound. The acid form has an extra H+
that can dissociate. The base form is the same compound without the H+.
conjugate base: the base formed by removing H+ from an acid. For example, the
conjugate base of HCl is Cl−.
conjugate acid: the acid formed by adding H+ to a base. For example, the conjugate
acid of NH3 is NH4+.
polyprotic: an acid that can lose more than one H+. For example, H2SO4 can lose
one H+ to dissociate into H+ and HSO4−. HSO4− can then lose a second H+ to
dissociate into H+ and SO42−.
Remember that an H+ ion is just a proton. A polyprotic acid is just an acid with
more than one proton that it can lose by dissociation.
amphoteric: a substance that “can go either way”—i.e., it has both a conjugate acid
and a conjugate base. For example, the HSO4− ion is amphoteric:
H2SO4 HSO4− SO42−

Homework Problems
Give the conjugate base for each of the following acids:
1. HCl 5. HSO4−
2. H2S 6. H2SO3
3. HCO3− 7. NH3
4. H2PO4− 8. HS−
Give the conjugate acid for each of the following bases:

9. HSO4− 14. PO43−
10. SO32− 15. CH3NH2
11. ClO4− 16. F−
12. H2PO4−
13. SO42−

pH & Indicators Page: 537
pH & Indicators
Unit: Acids & Bases
MA Curriculum Frameworks (2016): HS-PS1-9(MA)
 Calculate pH from [H+] and pOH from [OH−].
 Identify acids and bases from their pKa values.
 Select an appropriate indicator for a desired pH range.
Success Criteria:
 pH and pOH are calculated correctly.
 Acids and bases are correctly identified from their pKa values.
 Indicator changes color in a pH range that includes the pH of the given acid or
base.
Tier 2 Vocabulary: acid, base, indicator
 Explain why higher [H+] results in a lower pH.
Notes:
In water, a very small amount of H2O dissociates into H+ and OH− ions:
H2O H+ + OH−
The amount of dissociation of any compound in a solvent is a constant that is

determined by the attractions of the ions for each other vs. the attraction between
the ions and the solvent.
In water at 25 °C, the product of the concentrations of H+ and OH− ions (in mol )
L
is
−14
1.0 × 10 . This number is called the “water dissociation constant” Kw*. In other
words, in water at 25 °C:
Kw = [H+] [OH−] = 1.0 × 10−14
* [H ][OH ]
Kw is actually the equilibrium constant for the dissociation reaction. K eq  .
[H2O]
However, because H2O is a pure liquid, the concentration of H2O in pure H2O is constant—
it’s just the density divided by the molar mass, which works out to 55.6 M. Therefore, we
leave [H2O] out of the equilibrium expression.

Recall that acids create H (or H3O ) in water, and bases create OH− in water. In the
+ +
dissociation equation:
H2O H+ + OH−
Le Châtelier’s principle predicts that if we add acid, [H+] increases. This shifts the
equilibrium to the left, which means [OH−] decreases, and it is still true that
[H+] [OH−] = 1.0 × 10−14 = Kw.
Similarly, if we add base, [OH−] increases and [H+] decreases and

[H+] [OH−] = 1.0 × 10−14 = Kw.
If we have exactly the same amount of acid and base, then [H+] = [OH−] and both are
equal to the square root of 1 × 10−14, which is 1 × 10−7 M. A solution with the same
amount of acid and base is said to be neutral.
Working with concentrations in scientific notation that vary over 14 powers of ten is
unwieldy, so we define a function “p” which means “take the logarithm of the
quantity and multiply the result by −1.” (See the “Logarithms” topic starting on
page 102 for a brief description of the logarithm mathematical function.)
Therefore, the quantity “pH” would be −log [H+].
pH: a measure of the strength of an acidic or basic solution. Equal to −log [H+].
Examples:
if [H+] = 0.001 M, then pH = −log (0.001) = 3
if [H+] = 0.000 000 01 M (= 1 × 10−8 M) then pH = −log (1 × 10−8) = 8
pOH: another measure of the strength of an acidic or basic solution. Equal to

−log [OH−]. Much less commonly used that pH.
Examples:
if [OH−] = 0.001 M, then pOH = −log (0.001) = 3
if [OH−] = 0.000 000 01 M (= 1 × 10−8 M) then pOH = −log (1 × 10−8) = 8
pH & pOH Equations

pH = −log[H+] pOH = −log[OH−]
[H+] = 10−pH [OH−] = 10−pOH
Because the (multiplication) product of [H+][OH−] = 1 × 10−14, this means that:

pH + pOH = 14

Note that the higher the concentration of H ions (higher value of [H+]), the lower
+
the pH.
Low pH = acidic = more H+ = less OH−
High pH = basic = less H+ = more OH−
[H+] [OH−] pH pOH Acidic/Basic?

1 M (= 1 × 100 M) 1 × 10−14 M 0 14 very acidic
0.1 M (= 1 × 10−1 M) 1 × 10−13 M 1 13
0.01 M (= 1 × 10−2 M) 1 × 10−12 M 2 12
1 × 10−3 M 1 × 10−11 M 3 11
1 × 10−4 M 1 × 10−10 M 4 10
1 × 10−5 M 1 × 10−9 M 5 9 slightly acidic
−6
1 × 10 M 1 × 10−8 M 6 8
1 × 10−7 M 1 × 10−7 M 7 7 neutral
1 × 10−8 M 1 × 10−6 M 8 6
1 × 10−9 M 1 × 10−5 M 9 5 slightly basic
1 × 10−10 M 1 × 10−4 M 10 4
1 × 10−11 M 1 × 10−3 M 11 3
1 × 10−12 M 0.01 M (= 1 × 10−2 M) 12 2
−13
1 × 10 M 0.1 M (= 1 × 10−1 M) 13 1
1 × 10−14 M 1 M (= 1 × 100 M) 14 0 very basic
Sample Problems:
Q: What is the pH of a solution with [H+] = 2.5 x 10−4 M?
A: −log(2.5 x 10−4) = 3.60
Q: What is the concentration of H+ ions in a solution with a pH of 11.4?
A: 10−11.4 = 3.98 x 10−12 M

An aqueous solution is neutral when the concentration of H and OH− are equal.
+
This occurs in water at pH 7.00 at a temperature of 25 °C. However, remember that

temperature affects equilibrium; as the temperature increases, more H+ and OH−
dissociate. This means [H+] and [OH−] both increase with higher temperatures,
which means Kw increases. When that happens, [H+] and [OH−] are still equal in a
neutral solution, but both are larger, and because [H+] and [OH−] are larger, the pH
and pOH are both lower.
pH of a
Temp. (°C) Kw neutral
solution
0 0.114 × 10−14 7.47
10 0.293 × 10−14 7.27
20 0.681 × 10−14 7.08
25 1.008 × 10−14 7.00
−14
30 1.471 × 10 6.92
40 2.916 × 10−14 6.77
50 5.476 × 10−14 6.63
100 51.3 × 10−14 6.14
In other words, despite what your previous teachers may have taught you, a pH of 7
is only neutral at 25 °C. In fact, in warm-blooded animals with body temperatures
around 37 °C, a neutral pH would be approximately 6.8.
This also means that pH + pOH = 14 is only correct at 25 °C.

Indicators
indicator: a substance that changes color in a specific range of pH values. Indicators
are used as a visual way to measure pH.
The following table lists some common indicators.
pH range where
Name of color color
color change
Indicator in acid in base
occurs
bromophenol blue yellow purple 3.0–4.6
methyl red red yellow 4.4–6.2
litmus red blue 5.5–8.2
bromothymol blue yellow blue 6.0–7.6
phenol red yellow red 6.8–8.4
phenolphthalein clear pink 8.2–10.0
There are many others, and multiple indicators can be used in order to have
different color changes over a broader pH range.
In fact, some clever chemists have developed a “universal indicator,” which is

typically composed of water, propanol, phenolphthalein, sodium hydroxide, methyl
red, bromothymol blue, and thymol blue. This mixture indicates pH over a range
from 3 to 11, in ROYGBIV (rainbow) order:
pH range Description Color

<3 Strong acid red
3–6 Weak acid orange or yellow
7 Neutral green
8–11 Weak base blue
indigo (dark blue)
> 11 Strong base
or violet (purple)

Homework Problems
For each of the following solutions, calculate the information indicated. Choose pH
indicators from the “Common Acid-Base Indicators” table in your reference packets.
1. [H+] = 2.5 × 10−4 M

a. pH =
b. Is the solution acidic, basic, or neutral?
c. Which pH indicator would be best for this solution?
2. [H+] = 4.59 × 10−7 M

a. pH =
3. pH = 9.1
a. [H+] =

4. pH = 5.5
a. [H+] =
5. [OH−] = 7.9 × 10−7 M

a. [H+] =
b. pH =
c. Is the solution acidic, basic, or neutral?
d. Which pH indicator would be best for this solution?

pKa & Buffers Page: 544
pKa & Buffers

Unit: Acids & Bases
MA Curriculum Frameworks (2016): N/A
 Calculate pH from [H+] and pOH from [OH−].
 Identify acids and bases from their pKa values.
 Select an appropriate indicator for a desired pH range.
Success Criteria:
 pH and pOH are calculated correctly.
 Acids and bases are correctly identified from their pKa values.
 Indicator changes color in a pH range that includes the pH of the given acid or
base.
Tier 2 Vocabulary: acid, base, indicator
 Explain why higher [H+] results in a lower pH.
Notes:
Acid-base chemistry is largely equilibrium chemistry in which the solvent, usually
H2O, plays a significant role.
As stated earlier, water dissociates into H+ and OH− ions. Acids and bases change
the concentrations of H+ and OH− ions in solution, which can have significant effects
on the behavior of the solution.
acid dissociation constant (Ka): is the equilibrium constant for the dissociation of an
acid. For the “generic” acid HA:
[H ][A  ]
Ka 
[HA]
The greater the Ka value, the stronger the acid. (Remember your negative
exponents! E.g., 10−5 is greater than 10−7.)

pK a = −log K a (analogous to pH). The lower (or more negative) the pK a, the
stronger the acid.
When exactly 50 % of the acid HA is neutralized, [HA] = [A−], and the above
formula reduces to K a = [H+]. This means that pH = pK a when the acid is half-
neutralized.
base dissociation constant (Kb): is the equilibrium constant for the dissociation of a
base. For the “generic” base B:
[HB ][OH ]
Kb 
[B]
We can use the concept of pKa to add to our definitions of strong acids and bases:
strong acid: an acid with a pKa lower than that of H3O+ (1.0). Strong acids include
HCl, HBr, HI, H2SO4 and HNO3.
Strong acids dissociate completely into H+ and the corresponding anion. The
dissociated H+ converts H2O molecules to H3O+ ions.
weak acid: an acid with a pKa higher than that of H3O+ (1.0), but less than 7.0 (the
pH of a neutral solution at 25 °C).
strong base: a base whose conjugate acid is weaker than H2O (i.e., whose conjugate
acid has a pKa higher than 14). Hydroxides are strong bases because they
release OH−. However, note that aqueous Mg(OH)2 acts more like a weak base
because the limited solubility of Mg(OH)2 results in a concentration of OH− that
is similar to that produced by a weak base.
Strong bases either release OH− ions directly into solution, or form OH− ions by
pulling H+ off of H2O molecules.
weak base: a base whose conjugate acid has a pKa higher than 7.0 but less than 14.

Buffers
buffer: a weak acid or base that prevents the pH of a solution from changing
drastically until it neutralizes the buffer.
For example, if you have a fish tank, you want to keep the pH from getting too low,
you could add NaHCO3. The reaction:
H+ + HCO3− H2CO3
occurs around pH 6.4. As acid accumulates in your fish tank, it will react with the
HCO3− ions, and the pH will remain above 6.4 until all of the HCO3− ions have been
converted to H2CO3.
Buffers can work in either direction—to absorb acid or base. If you use a
combination of two buffers (one above and one below your desired pH), you can
keep the pH within a narrow range.
In fact, water acts as a buffer, but over a very wide pH range. The pH of an aqueous
solution is limited, because stronger acids just convert more H2O to H3O+, and
stronger bases just convert more H2O to OH−. The presence of water effectively
keeps the pH between 1 and 14. In fact, the reason your biology teacher taught you
that the pH range goes from 1−14 is because acid-base reactions in biology all
happen in aqueous environments.

Homework Problems
1. Rank the following acids from strongest to weakest, based on their pKa
values. Refer to of your Chemistry Reference Tables.
Based on pKa values in “Table P. pKa Values for Common Acids” on page 553 of
your Chemistry Reference Tables, rank the following ten compounds in order, from
the strongest acid to the strongest base.
HF, HCN, HCl, HPO42−, HNO3, H2O, CH3COOH, NH4+, H2SO4, H2CO3
1. 5. 8.
2. 6. 9.
3. 7. 10.
4.
11. The wastes from fish in a fish tank produce acids, which cause the pH of the
water in the tank to decrease over time. Which acid-base pair from the
table of pKa Values for Common Acids would be most effective at keeping
the pH from dropping below 7.0. Explain.

Summary: Acids & Bases Page: 548
Summary: Acids & Bases

Unit: Acids & Bases

Chemistry 1 Chemistry Reference Tables Page: 549
Appendix: Chemistry Reference Tables

Table A. Standard Temperature and Pressure ..........................................................................................................549
Table B. Selected Units .............................................................................................................................................549
Table C. Selected Prefixes .........................................................................................................................................549
Table D. Physical Constants for Water ......................................................................................................................550
Table E. Vapor Pressure and Density of Water .........................................................................................................550
Figure F. Phase Diagram for Water ...........................................................................................................................550
Table G. Solubility Guidelines ...................................................................................................................................551
Table H. Ksp Values for Some Insoluble Salts at 25 °C ...............................................................................................551
Figure I. Solubilities of Selected Compounds ............................................................................................................551
Table J. Number Prefixes ..........................................................................................................................................552
Table K. Polyatomic Ions ...........................................................................................................................................552
Table L. Flame Test Colors ........................................................................................................................................552
Table M. Aqueous Ion Colors ....................................................................................................................................552
Table N. Colors of Assorted Compounds ..................................................................................................................552
Table O. Common Acids ............................................................................................................................................553
Table P. pKa Values for Common Acids .....................................................................................................................553
Table Q. Common Bases ...........................................................................................................................................553
Table R. Common Acid-Base Indicators ....................................................................................................................553
Figure Z. Bonding Triangle ........................................................................................................................................553
Table S. Symbols Used in Nuclear Chemistry ............................................................................................................554
Table U. Selected Radioisotopes...............................................................................................................................554
Table U. Constants Used in Nuclear Chemistry ........................................................................................................554
Figure V. Neutron/Proton Stability Band ..................................................................................................................554
Table W. Activity Series ............................................................................................................................................555
Table X. Std. Reduction Potentials ............................................................................................................................555
Table Z. Selected Properties of the Elements ...........................................................................................................556
Table AA. Bond Dissociation Energies & Bond Lengths ............................................................................................558
Table BB. Thermodynamic Data ...............................................................................................................................559
Table DD. Selected Formulas and Equations ............................................................................................................561
Periodic Table of the Elements ..................................................................................................................................563
Table A. Standard Temperature and Pressure Table B. Selected Units

Name Values Name Symbol Quantity
“Standard” Pressure 1 atm 760 torr 101.3 kPa meter (SI) m
length
Standard Temperature 0 °C 32°F 273.15K centimeter cm
atm = atmosphere kilogram (SI) kg
mass
Torr = millimeter of mercury (mm Hg) gram g
kPa = kilopascal Pascal (SI derived) Pa
°C = degree Celsius atmosphere atm
pressure
°F = degree Fahrenheit mm of mercury mm Hg
K= kelvin Torr Torr
Kelvin (SI) K
temperature
Table C. Selected Prefixes degree Celsius °C
Factor Number of Units Prefix Symbol amt of substance (SI) mol mole
6
10 1,000,000 mega- M Joule (SI derived) J
3 energy
10 1,000 kilo- k kilocalorie kcal
−1
10 0.1 deci- d second (SI) s time
−2
10 0.01 centi- c liter L, ℓ volume
−3
10 0.001 milli- m part per million ppm concentration
−6
10 0.000 001 micro- molarity M, mol
concentration

Table D. Physical Constants for Water
Freezing Point @ 1 atm 0 °C = 273.15 K
Boiling Point @ 1 atm 100 °C = 373.15 K
Heat of Fusion 333.6 J/g
Heat of Vaporization 2270 J/g
Specific Heat Capacity (Cp) 4.184 J/g∙°C
Freezing Point Depression Constant (Kf) 0.52 °C/m
Boiling Point Elevation Constant (Kb) 1.86 °C/m
Table E. Vapor Pressure and

Figure F. Phase Diagram for Water
Density of Water
Temp Pvap density
3
(°C) (kPa) (g/cm )
0.01 0.61173 0.99978
1 0.65716 0.99985
4 0.81359 0.99995
5 0.87260 0.99994
10 1.2281 0.99969
15 1.7056 0.99909
20 2.3388 0.99819
25 3.1691 0.99702
30 4.2455 0.99561
35 5.6267 0.99399
40 7.3814 0.99217
45 9.5898 0.99017
50 12.344 0.98799
55 15.752 0.98565
60 19.932 0.98316
65 25.022 0.98053
70 31.176 0.97775
75 38.563 0.97484
80 47.373 0.97179
85 57.815 0.96991
90 70.117 0.96533
95 84.529 0.96192
100 101.32 0.95475
105 120.79 0.95475
Table G. Solubility Guidelines
Ions That Form Ions That Form INSOLUBLE
EXCEPT with EXCEPT with
SOLUBLE Compounds Compounds
+ + 2–
Group I ions (Li , Na , etc.) carbonate (CO3 )
+ 2–
ammonium (NH4 ) chromate (CrO4 ) Group I ions,
– 3– +
nitrate (NO3 ) phosphate (PO4 ) ammonium (NH4 )
– 2–
hydrogen carbonate (HCO3 ) sulfite (SO3 )
–
chlorate (ClO3 ) 2– Group I ions,
– sulfide (S ) +
perchlorate (ClO4 ) Group II ions, NH4
– – + –
acetate (C2H3O2 or CH3COO ) Ag hydroxide (OH ) Group I ions,
– – – + + 2+ 2+ 2– + 2+ 2+ +
halides (Cl , Br , I ) Ag , Cu , Pb , Hg2 oxide (O ) NH4 , Ba , Sr , Tl
2– 2+ 2+ 2+ + 2+
sulfates (SO4 ) Ca , Sr , Ba , Ag , Pb
Table H. Ksp Values for Some

Figure I. Solubilities of Selected Compounds
Insoluble Salts at 25 °C
Compound Ksp
−5
MgCO3 1.0 × 10
−5
PbCl2 1.7 × 10
−6
BaF2 2.0 × 10
−6
CuCl 1.0 × 10
−8
PbI2 1.6 × 10
−8
AgOH 1.0 × 10
−9
BaCO3 8.1 × 10
−9
CaCO3 3.8 × 10
−10
SrCO3 9.4 × 10
−10
AgCl 1.8 × 10
−10
BaSO4 1.1 × 10
−11
CaF2 3.9 × 10
−11
Mg(OH)2 1.0 × 10
−12
Ag2CrO4 9.0 × 10
−12
CuI 5.0 × 10
−13
AgBr 3.3 × 10
−13
PbSO4 2.5 × 10
−13
PbCO3 1.6 × 10
−14
Mn(OH)2 4.0 × 10
−14
PbCrO4 1.8 × 10
−14
Fe(OH)2 1.6 × 10
−16
AgI 1.5 × 10
−18
Zn(OH)2 7.9 × 10
−18
FeS 4.0 × 10
−18
HgCl 2.0 × 10
−23
ZnS 1.0 × 10
−28
PbS 8.4 × 10
−29
CdS 3.6 × 10
−34
Al(OH)3 1.6 × 10
−36
CuS 8.7 × 10
−36
Fe(OH)3 1.3 × 10
−50
Ag2S 2.0 × 10
−53
HgS 3.0 × 10
Table J. Number Prefixes
Number Inorganic Organic Number Inorganic Organic
1 mono- meth- 6 hexa- hex-
2 di- eth- 7 hepta- hept-
3 tri- prop- 8 octa- oct-
4 tetra- but- 9 nona- non-
5 penta- pent- 10 deca- dec-
Table K. Polyatomic Ions

ion formula ion formula ion formula ion formula
2+ + − 2−
americyl AmO2 ammonium NH4 cyanate OCN dichromate Cr2O7
2+ + − 2−
carbonyl CO hydronium H3O thiocyanate SCN imide NH
2+ + − 2−
thiocarbonyl CS iodyl IO2 selenocyanate SeCN molybdate MoO4
2+ + − 2−
chromyl CrO2 nitrosyl NO tellurocyanate TeCN peroxide O2
2+ + − 2−
neptunyl NpO2 thionitrosyl NS hydroxide OH oxalate C2O4
2+ + − 2−
plutoryl PuO2 phosphoryl PO iodate IO3 phthalate C8H4O4
2+ + − 2−
selinyl SeO thiophosphoryl PS methanolate CH3O selenate SeO4
2+ + − 2−
selenoyl SeO2 phospho PO2 methanethiolate CH3S disulfide S2
2+ − − 2−
thionyl / sulfinyl SO acetate CH3COO ethanolate C2H5O sulfate SO4
2+ − − 2−
sulfonyl / sulfuryl SO2 amide NH2 permanganate MnO4 thiosulfate S2O3
2+ − − 2−
uranyl UO hydroxylamide NHOH nitrate NO3 dithionate S2O4
2+ − − 2−
vanadyl VO azide N3 superoxide O2 silicate SiO3
2+ − 2− 3−
mercury (II) Hg hydrazide N2H3 tetraborate B4O7 borate BO3
2+ − 2− 3−
mercury (I) Hg2 bromate BrO3 carbide C2 arsenate AsO4
− 2− 3−
chlorate ClO3 carbonate CO2 phosphate PO4
− 2− 4−
cyanide CN chromate CrO4 orthosilicate SiO4
Table L. Flame Test Colors

Element Color Element Color Element Color
Ba yellow-green K pink Pb blue
Ca orange-red Li fuchsia Sb pale green
Cu blue-green Mg bright white Sr red
Fe gold Na yellow Zn blue-green
Table M. Aqueous Ion Colors

Ion Color Ion Color
+ 2+
Cu green V violet
2+ 3+
Cu blue V blue-green
2+ 2−
Fe yellow-green CrO4 yellow
3+ 2−
Fe orange-red Cr2O7 orange
3+ 2+
Cr violet [Cr(NO3)3] to green [CrCl3] Cu(NH3)4 dark blue
2+ 2+
Ni green FeSCN red-brown (wine-red to dark orange)
2+ 2+
Mn pink Co pink
7+ − 2−
Mn purple (e.g., the MnO4 ion) CoCl4 blue
3+ 2+ 4+ 3+
Pb blue-green (Pb and Pb are clear) Ti(H2O)6 purple
Table N. Colors of Assorted Compounds

Compound Color Compound Color
F2 pale yellow gas NO colorless gas
Cl2 green-yellow gas NO2 brown gas
Br2 red-brown liquid metallic sulfides of transition metals
I2 dark metallic solid; dark violet vapor sulfides tend to be black
S8 yellow odorous solid metallic oxides of colored transition metals
PbI2 bright yellow precipitate oxides tend to be colored
Fe2O3 reddish-brown (rust)
Table O. Common Acids Table P. pKa Values for Common Acids
Formula Name Acid pKa Conj. Base
−
HCl (aq) hydrochloric acid H2O 15.7 OH
2− 3−
HNO3 (aq) nitric acid HPO4 12.6 PO4
− 2−
H2SO4 (aq) sulfuric acid HCO3 10.2 CO3
+
H3PO4 (aq) phosphoric acid NH4 9.2 NH3
−
H2CO3 (aq) carbonic acid HCN 9.1 CN
− 2−
HC2H3O2 (aq) ethanoic acid H2PO4 7.2 HPO4
or CH3COOH (aq) (acetic acid) H2S 7.0 HS
−
−
H2CO3 6.4 HCO3
−
Table Q. Common Bases CH3COOH 4.8 CH3COO
−
Formula Name HCOOH 3.7 HCOO
−
NaOH (aq) sodium hydroxide HNO2 3.3 NO2
−
KOH (aq) potassium hydroxide HF 3.2 F
Ca(OH)2 (aq) calcium hydroxide C6H8O7 −
3.1 C6H7O7
NH3 (aq) aqueous ammonia (citric acid)
−
H3PO4 2.2 H2PO4
− 2−
Table R. Common Acid-Base Indicators HSO4 2.0 SO4
−
pH Range of HNO3 −1.4 NO3
Indicator Color Change +
Color Change H3O −1.7 H2O
−
bromophenol blue 3.0 – 4.6 yellow−purple HCl −7.0 Cl
−
methyl orange 3.2 – 4.4 red−yellow HBr −9.0 Br
−
bromocresol green 3.8 – 5.4 yellow−blue HI −10 I
−
methyl red 4.4 – 6.2 red−yellow HClO4 −10 ClO4
−
litmus 5.5 – 8.2 red−blue H2SO4 −12 HSO4
bromothymol blue 6.0 – 7.6 yellow−blue
phenol red 6.8 – 8.4 yellow−red Any acid with a pKa value less than 1 is a strong
thymol blue 8.0 – 9.6 yellow−blue acid; any base whose conjugate acid has a pKa
phenolphthalein 8.2 – 10 clear−pink value greater than 14 is a strong base.
Figure S. Bonding Triangle
EN  average electroneg ativity EN  electroneg ativity difference

Table T. Symbols Used in Nuclear Chemistry Table U. Selected Radioisotopes

Decay
Name Notation Symbol Nuclide Half-Life
Mode
alpha particle
4
2 He or 24 α
3
H 12.26 y β−
beta particle (electron) 0
-1 e
or -1 
0 β
− 14
C 5730 y β−
gamma radiation 0
0
γ
16
N 7.2 s β−
neutron 1
0n n
19
Ne 17.2 s β+
proton 1
1H
or 11 p p
24
Na 15 h β−
positron 0
1 e
or 1 
0 β
+ 27
Mg 9.5 min β−
32
P 14.3 d β−
Table V. Constants Used in Nuclear Chemistry
36
Cl 3.01 × 10 y
5
β−
Constant Value
37
K 1.23 s β+
mass of an electron (me) 0.00055 amu
40
K 1.26 × 10 y
9
β+
mass of a proton (mp) 1.00728 amu
42
K 12.4 h β−
mass of a neutron (mn) 1.00867 amu
37
Ca 0.175 s β−
51
Becquerel (Bq) 1 disintegration/second Cr 27.7 d α
Curie (Ci)
10
3.7 x 10 Bq
53
Fe 8.51 min β−
59
Fe 46.3 d β−
Figure W. Neutron/Proton Stability Band
60
Co 5.26 y β−
85
Kr 10.76 y β−
87
Rb 4.8 × 10 y
10
β−
90
Sr 28.1 y β−
99
Tc 2.13 x 10 y
5
β−
131
I 8.07 d β−
137
Cs 30.23 y β−
153
Sm 1.93 d β−
198
Au 2.69 d β−
222
Rn 3.82 d α
220
Fr 27.5 s α
226
Ra 1600 y α
232 10
Th 1.4 x 10 y α
233 5
U 1.62 x 10 y α
235 8
U 7.1 x 10 y α
238 9
U 4.51 x 10 y α
239 4
Pu 2.44 x 10 y α
241
Am 432 y α
Table X. Activity Series Table Y. Std. Reduction Potentials
Non- 0
Metals Half-Reaction E (V)
metals
+ −
Cs F2 Li + e  Li(s) −3.040
+ −
Rb Cl2 Cs + e  Cs(s) −3.026
+ −
Reacts with cold H2O K Br2 Rb + e  Rb(s) −2.98
+ −
and acids, replacing Na I2 K + e  K(s) −2.931
2+ −
hydrogen. Reacts with Li Ba + 2 e  Ba(s) −2.912
2+ −
O2, forming oxides. Ba Sr + 2 e  Sr(s) −2.899
2+ −
Sr Ca + 2 e  Ca(s) −2.868
+ −
Ca Na + e  Na(s) −2.71
2+ −
Mg Mg + 2 e  Mg(s) −2.372
2+ −
Be Be + 2 e  Be(s) −1.85
Reacts with steam (not 3+ −
Al Al + 3 e  Al(s) −1.66
cold H2O) and acids, 2+ −
Mn Mn + 2 e  Mn(s) −1.029
replacing hydrogen. −
Zn 2 H2O + 2 e 
Reacts with O2, − −0.828
Cr H2(g) + 2 OH
forming oxides. 2+ −
Fe Zn + 2 e  Zn(s) −0.762
3+ −
Cd Cr + 3 e  Cr(s) −0.74
2+ −
Does not react with H2O. Co Fe + 2 e  Fe(s) −0.44
3+ − 2+
Reacts with acids, Ni Cr + e  Cr −0.42
2+ −
replacing hydrogen. Sn Cd + 2 e  Cd(s) −0.40
2+ −
Reacts with O2, Pb Co + 2 e  Co(s) −0.28
2+ −
forming oxides. H2 Ni + 2 e  Ni(s) −0.25
2+ −
Sb Sn + 2 e  Sn(s) −0.13
Reacts with O2, forming 2+ −
Bi Pb + 2 e  Pb(s) −0.13
oxides. + −
Cu 2 H + 2 e  H2(g) 0.000
+ −
Ag S(s) + 2 H + 2 e  H2S(g) +0.14
Fairly unreactive, 4+ − 2+
Hg Sn + 2 e  Sn +0.15
forming oxides only 2+ − +
Au Cu + e  Cu +0.159
indirectly. 2+ −
Pt Cu + 2 e  Cu(s) +0.340
+ −
Arrows indicate direction from LEAST to MOST Cu + e  Cu(s) +0.520
− −
active elements. An element can replace any I2(s) + 2 e  2 I +0.54
3+ − 2+
element below itself on the activity series. Fe + e  Fe +0.77
+ −
Ag + e  Ag(s) +0.800
2+ −
Note that the order of elements in the activity Hg2 + 2 e  2 Hg(l) +0.80
2+ −
series is similar to, though not quite identical Hg + 2 e  Hg(l) +0.85
with, the order of elements/ions in the table of 2+ − 2+
2 Hg + 2 e  Hg2 +0.91
Std. Reduction Potentials (Table Y).
− −
Br2(l) + 2 e  2 Br +1.07
2+ −
Pt + 2 e  Pt(s) +1.188
+ −
O2(g) + 4 H + 4 e  2 H2O +1.23
− −
Cl2(g) + 2 e  2 Cl +1.36
3+ −
Au + 3 e  Au(s) +1.52
3+ − 2+
Co + e  Co +1.82
− −
F2(g) + 2 e  2 F +2.87
o
E values at 1 M concentration and 1 atm.
Table Z. Selected Properties of the Elements
st
atomic specific electro- 1 ioniza-
melting boiling common
atomic atomic element mass heat density neg- tion
point point oxidation
# symbol name (IUPAC capacity (g/mL) ativity potential
°C °C states
2005) (J/g∙K) (Pauling) (kJ/mol)
89 Ac actinium 227 1050 3200 — 10.1 1.1 499 +3
13 Al aluminum 26.98 660 2467 0.9 2.7 1.61 578 +3
95 Am americium 243 994 2607 0.11 13.7 1.3 578 +3,4,5,6
51 Sb antimony 121.8 631 1950 0.21 6.69 2.05 834 +3,5
18 Ar argon 39.95 −189.2 −185.7 0.52 0.00178 1521 0
33 As arsenic 74.92 817 617 0.33 5.73 2.18 947 ±3,+5
85 At astatine 210 302 337 — — 2.2 917
56 Ba barium 137.3 725 1640 0.204 3.5 0.89 503 +2
97 Bk berkelium 247 986 — — 14 1.3 601 +3,4
4 Be beryllium 9.012 1278 2970 1.82 1.85 1.57 899 +2
83 Bi bismuth 209.0 271 1560 0.12 9.75 2.02 703 +3,5
107 Bh bohrium 272 — — — — — — —
5 B boron 10.81 2079 2550 1.02 2.34 2.04 801 +3
35 Br bromine 79.90 −7.2 58.8 0.473 3.12 2.96 1140 ±1,+5
48 Cd cadmium 112.4 320.9 765 0.23 8.65 1.69 868 +2
20 Ca calcium 40.08 839 1484 0.63 1.55 1 590 +2
98 Cf californium 251 — — — — 1.3 608 +3
6 C carbon 12.01 3367 4827 0.71 2.25 2.55 1086 ±4
58 Ce cerium 140.1 798 3257 0.19 6.66 1.12 534 +3,4
55 Cs cesium 132.9 28.4 669 0.24 1.87 0.79 376 +1
17 Cl chlorine 35.45 −101 −34.6 0.48 0.00321 3.16 1251 −1
24 Cr chromium 52.00 1857 2672 0.45 7.19 1.66 653 +3,2,6
27 Co cobalt 58.93 1495 2870 0.42 8.9 1.88 760 +2,3
112 Cn copernicum 285 — — — — — — —
29 Cu copper 63.55 1083 2567 0.38 8.96 1.9 745 +2,1
96 Cm curium 247 1340 — — 13.5 1.3 581 +3
110 Ds darmstadtium 281 — — — — — — —
105 Db dubnium 268 — — — — — — —
66 Dy dysprosium 162.5 1412 2567 0.17 8.55 1.22 573 +3
99 Es einsteinium 252 — — — — 1.3 619 +3
68 Er erbium 167.3 1529 2868 0.17 9.07 1.24 589 +3
63 Eu europium 152.0 822 1529 0.18 5.24 547 +3,2
100 Fm fermium 257 — — — — 1.3 627 +3
114 Fl flerovium 289 — — — — — — —
9 F fluorine 19.00 −219.8 −188.1 0.82 0.0017 3.98 1681 −1
87 Fr francium 223 27 677 0.7 380 +1
64 Gd gadolinium 157.3 1313 3273 0.23 7.9 1.2 593 +3
31 Ga gallium 69.72 29.8 2403 0.37 5.9 1.81 579 +3
32 Ge germanium 72.63 947.4 2830 0.32 5.32 2.01 762 +4,2
79 Au gold 197.0 1064 3080 0.128 19.3 2.54 890 +3,1
72 Hf hafnium 178.5 2227 4600 0.14 13.3 1.3 659 +4
108 Hs hassium 270 — — — — — — —
2 He helium 4.003 −272.2 −268.9 5.193 0.000179 2372 0
67 Ho holmium 164.9 1474 2700 0.16 8.8 1.23 581 +3
1 H hydrogen 1.008 −259.1 −252.9 14.304 0.0000699 2.2 1312 ±1
49 In indium 114.8 156.6 2080 0.23 7.31 1.78 558 +3
53 I iodine 126.9 113.5 184 0.214 4.93 2.66 1008 −1,+5,7
77 Ir iridium 192.2 2410 4130 0.13 22.4 2.2 878 +4,3,6
26 Fe iron 55.85 1535 2750 0.44 7.86 1.83 762 +3,2
36 Kr krypton 83.80 −157 −152 0.248 0.00374 3 1351 0
57 La lanthanum 138.9 920 3454 0.19 6.15 1.1 538 +3
103 Lr lawrencium 262 — — — — — — +3
82 Pb lead 207.2 327.5 1740 0.13 11.4 2.33 716 +2,4
3 Li lithium 6.968 180.5 1342 3.6 0.543 0.98 520 +1
116 Lv livermorium 293 — — — — — — —
71 Lu lutetium 175.0 1663 3402 0.15 9.84 1.27 524 +3
12 Mg magnesium 24.31 649 1090 1.02 1.74 1.31 738 +2
25 Mn manganese 54.94 1244 1962 0.48 7.43 1.55 717 +2,3,4,6,7
st
atomic specific electro- 1 ioniza-
melting boiling common
atomic atomic element mass heat density neg- tion
point point oxidation
# symbol name (IUPAC capacity (g/mL) ativity potential
°C °C states
2005) (J/g∙K) (Pauling) (kJ/mol)
109 Mt meitnerium 276 — — — — — — —
101 Md mendelevium 258 — — — — 1.3 635 +3,2
80 Hg mercury 200.6 −38.9 357 0.139 13.5 2 1007 +2,1
42 Mo molybdenum 95.95 2617 4612 0.25 10.2 2.16 684 +6,3,5
115 Mc moscovium 288 — — — — — — —
60 Nd neodymium 144.2 1016 3127 0.19 7 1.14 533 +3
10 Ne neon 20.18 −248 −248.7 0.904 0.0009 — 2081 0
93 Np neptunium 237 640 3900 0.12 20.2 1.36 605 +5,3,4,6
28 Ni nickel 58.69 1453 2730 0.44 8.9 1.91 737 +2,3
113 Nh nihonium 284 — — — — — — —
41 Nb niobium 92.91 2468 4742 0.26 8.57 1.6 652 +5,3
7 N nitrogen 14.01 −209.9 −195.8 1.04 0.00125 3.04 1402 −3
102 No nobelium 259 — — — — 1.3 642 +2,3
118 Og oganesson 294 — — — — — — —
76 Os osmium 190.2 3045 5030 0.13 22.6 2.2 839 +4,6,8
8 O oxygen 16.00 −218.4 −183 0.92 0.00143 3.44 1314 −2
46 Pd palladium 106.4 1554 3140 0.24 12 2.2 804 +2,4
15 P phosphorus 30.97 44.1 280 0.77 1.82 2.19 1012 −3
78 Pt platinum 195.1 1772 3827 0.13 21.4 2.28 868 +4,2
94 Pu plutonium 244 641 3232 0.13 19.8 1.28 585 +4,3,5,6
84 Po polonium 209 254 962 0.12 9.32 2 812 +4,2
19 K potassium 39.10 63.25 760 0.75 0.86 0.82 419 +1
59 Pr praseodymium 140.9 931 3017 0.19 6.77 1.13 527 +3,4
61 Pm promethium 145 1042 3000 0.18 7.26 — 535 +3
91 Pa protactinium 231.0 1570 4000 0.12 15.4 1.5 568 +5,4
88 Ra radium 226 700 1140 0.12 5 0.9 509 +2
86 Rn radon 222 −71 −61.8 0.09 0.00973 — 1037 0
75 Re rhenium 186.2 3180 5600 0.13 21 1.9 760 +7,4,6
45 Rh rhodium 102.9 1966 3727 0.242 12.4 2.28 720 +3,4,6
111 Rg roentgentium 280 — — — — — — —
37 Rb rubidium 85.47 38.9 686 0.363 1.53 0.82 403 +1
44 Ru ruthenium 101.1 2310 3900 0.238 12.4 2.2 710 +4,3,6,8
104 Rf rutherfordium 267 — — — — — — —
62 Sm samarium 150.4 1074 1794 0.2 7.52 1.17 545 +3,2
21 Sc scandium 44.96 1541 2832 0.6 2.99 1.36 633 +3
106 Sg seaborgium 271 — — — — — — —
34 Se selenium 78.97 217 685 0.32 4.79 2.55 941 +4,−2,+6
14 Si silicon 28.09 1410 2355 0.71 2.33 1.9 787 ±4
47 Ag silver 107.9 962 2212 0.235 10.5 1.93 731 +1
11 Na sodium 22.99 97.8 883 1.23 0.971 0.93 496 +1
38 Sr strontium 87.62 769 1384 0.3 2.54 0.95 549 +2
16 S sulfur 32.07 112.8 444.7 0.71 2.07 2.58 1000 −2
73 Ta tantalum 180.9 2996 5425 0.14 16.6 1.5 761 +5
43 Tc technetium 98 2172 4877 0.21 11.5 1.9 702 +7,4,6
52 Te tellurium 127.6 449.5 989.8 0.2 6.24 2.1 869 +4,6,−2
117 Ts tennessine 292 — — — — — — —
65 Tb terbium 158.9 1365 3230 0.18 8.23 — 569 +3,4
81 Tl thallium 204.4 303 1457 0.13 11.9 1.62 589 +1,3
90 Th thorium 232.0 1750 4790 0.12 11.7 1.3 587 +4
69 Tm thulium 168.9 1545 1950 0.16 9.32 1.25 597 +3,2
50 Sn tin 118.7 232 2270 0.227 7.31 1.96 709 +4,2
22 Ti titanium 47.87 1660 3287 0.52 4.54 1.54 659 +4,3,2
74 W tungsten 183.8 3410 5660 0.13 19.3 2.36 770 +6,4
92 U uranium 238.0 1132 3818 0.12 19 1.38 598 +6,3,4,5
23 V vanadium 50.94 1890 3380 0.49 6.11 1.63 651 +5,2,3,4
54 Xe xenon 131.3 −111.8 −107.1 0.158 0.00589 2.6 1170 0
70 Yb ytterbium 173.1 819 1196 0.15 6.97 — 603 +3,2
39 Y yttrium 88.91 1523 3337 0.3 4.47 1.22 600 +3
30 Zn zinc 65.38 419.6 906 0.39 7.13 1.65 906 +2
40 Zr zirconium 91.22 1852 4377 0.27 6.51 1.33 640 +4
Table AA. Bond Dissociation Energies & Bond Lengths
Values given are homolytic bond dissociation energies, meaning that the electrons are divided equally between the
two atoms.
Hydrogen Compounds Group IVA Compounds Group VA Compounds

D r D r D r
Bond Bond Bond
(kJ/mol) (pm) (kJ/mol) (pm) (kJ/mol) (pm)
H−H 432 74 C−C 346 154 N−N 167 145
H−B 389 119 C=C 602 134 N=N 418 125
H−C 411 109 C≡C 835 120 N≡N 942 110
H − Si 318 148 C − Si 318 185 N−O 201 140
H − Ge 288 153 C − Ge 238 195 N=O 607 121
H − Sn 251 170 C − Sn 192 216 N−F 283 136
H−N 386 101 C − Pb 130 230 N − Cl 313 175
H−P 322 144 C−N 305 147 P−P 201 221
H − As 247 152 C=N 615 129 P−O 335 163
H−O 459 96 C≡N 887 116 P=O 544 150
H−S 363 134 C−P 264 184 P=S 335 186
H − Se 276 146 C−O 358 143 P−F 490 154
H − Te 238 170 C=O 799 120 P − Cl 326 203
H−F 565 92 C≡O 1072 113 P − Br 264 ?
H − Cl 428 127 C−B 356 ? P−I 184 ?
H − Br 362 141 C−S 272 182 As − As 146 243
H−I 295 161 C=S 573 160 As − O 301 178
C−F 485 135 As − F 484 171
C − Cl 327 177 As − Cl 322 216
Group VIIA Compounds C − Br 285 194 As − Br 458 233
D r C−I 213 214 As − I 200 254
Bond
(kJ/mol) (pm) Si − Si 222 233 Sb − Sb 121 ?
F−F 155 142 Si − N 355 ? Sb − F 440 ?
Cl − Cl 240 199 Si − O 452 163 Sb − Cl(5) 248 ?
Br − Br 190 228 Si − S 293 200 Sb − Cl(3) 315 232
I−I 148 267 Si − F 565 160
At − At 116 ? Si − Cl 381 202
I−O 201 ? Si − Br 310 215 Group VIA Compounds
I−F 273 191 Si − I 234 243 D r
Bond
I − Cl 208 232 Ge − Ge 188 241 (kJ/mol) (pm)
I − Br 175 ? Ge − N 257 ? O−O 142 148
Ge − F 470 168 O=O 494 121
Ge − Cl 349 210 O−F 190 142
Group IIIA Compounds Ge − Br 276 230 S=O 522 143
D r Ge − I 212 ? S − S(8) 226 205
Bond
(kJ/mol) (pm) Sn − F 414 ? S=S 425 149
B−B 293 ? Sn − Cl 323 233 S−F 284 156
B−O 536 ? Sn − Br 273 250 S − Cl 255 207
B−F 613 ? Sn − I 205 270 Se − Se 172 ?
B − Cl 456 175 Pb − F 331 ? Se = Se 272 215
B − Br 377 ? Pb − Cl 243 242
Pb − Br 201 ?
Pb − I 142 279
Table BB. Thermodynamic Data

Standard enthalpy of formation (H f ) & standard entropy ( S ) for selected compounds. Note that standard
enthalpy values are in kilojoules per mole, whereas entropy values are in joules per mole∙Kelvin.
  
ΔH f S ΔH f S ΔH f S
Subst. State kJ
Subst. State kJ
Subst. State kJ
( mol ) ( molJK ) ( mol ) ( molJK ) ( mol ) ( molJK )
Ag s 0 42.6 Cr2O3 g −1139.7 81.2 MnO2 s −520.0 53.0
+
Ag aq 105.79 72.7 Cu s 0 33.2 N2 g 0 191.5
+
AgCl s −127.01 96.2 Cu aq +71.7 40.6 NH3 g −45.94 192.3
+2 +
AgBr s −100.4 107.1 Cu aq +64.8 −99.6 NH4 aq −133.26 113.4
−
AgNO3 s −124.4 140.9 CuO s −157.3 42.6 NO2 aq −104.6 123.0
−
Al s 0 28.3 Cu2O s −168.6 93.1 NO3 aq −206.85 146.4
+3
Al aq −538.4 −321.7 Cu(OH)2 s −450 108 N2H4 ℓ +50.6 121.2
AlCl3 s −704 110.7 CuS s −53.1 66.5 NH4Cl s −314.4 94.6
Al2O3 s −1675.7 50.9 Cu2S s −79.5 120.9 NH4NO3 s −365.6 151.1
Al(OH)3 s −1277 CuSO4 s −771.4 107.6 NO g +90.2 210.7
−
Ba s 0 62.8 F aq −335.35 −13.8 NO2 g +33.2 240.0
BaCl2 s −858.6 123.7 F2 g 0 202.7 N2O g +82 220
BaCO3 s −1216.3 112.1 Fe s 0 27.3 N2O4 g +9.2 304.2
Ba(NO3)2 s −992 214 Fe(OH)3 s −823.0 106.7 Na s 0 51.2
+
BaO s −553.5 70.4 FeO s −272 61 Na aq −240.34 59.0
Ba(OH)2 s −998.2 112 Fe2O3 s −824.2 87.4 Na2CO3 s −1131 136
BaSO4 s −1473.2 132.2 Fe3O4 s −1118.4 146.4 NaHCO3 s −948 102
Be s 0 10 FeSO4 s −929 121 NaCl s −411.2 72.1
BeO s −599 14 H2 g 0 130.6 NaF s −573.6 51.5
+
Br2 ℓ 0 152.2 H aq 0 0.0 NaNO3 s −467 116
Br− aq −121 82 HBr g −36.29 198.6 NaOH s 425.6 64.5
−
C s 0 5.7 HCO3 aq −689.93 91.2 Ni s 0 29.9
CCl4 ℓ −135.4 216.4 HCl g −92.31 186.8 NiCl2 s −316 107
CHCl3 ℓ −134.5 201.7 HF g −273.30 173.7 NiO s −239.7 38.0
−
CH4 g −74.8 186.2 HI g 26.50 206.5 OH aq −230.015 −10.8
C2H2 g +226.7 200.8 HNO3 aq −174.1 155.6 O2 g 0 205.0
−2
C2H4 g +52.3 219.5 HPO4 aq −1299.0 −33.5 P4 s 0 164.4
−
C2H6 g −84.7 229.5 HSO4 aq −886.9 131.8 PCl3 g −287.0 311.7
C3H8 g −103.8 269.9 H2O ℓ −285.830 69.9 PCl5 g −374.9 364.5
CH3OH ℓ −238.7 126.8 H2O g −241.826 188.7 PH3 g +5 210
− −3
C2H5OH ℓ −277.7 160.7 H2PO4 aq −1302.6 90.4 PO4 aq −1277.4 −222
C6H12O6 s −1275 212 H2S g −20.6 205.7 Pb s 0 64.8
+2
CO g −110.53 197.6 Hg ℓ 0 76.0 Pb aq 0.92 10.5
+2
CO2 g −393.51 213.6 Hg aq 170.21 −32.2 PbBr2 s −278.7 161.5
−2
CO3 aq −675.23 −56.9 HgO cr −90.79 70.3 PbCl2 s −359.4 136.0
−
Ca s 0 41.4 I aq −56.78 111.3 PbO s −219.0 66.5
+2
Ca aq −543.0 −53.1 I2 s 0 116.1 PbO2 s −277.4 68.6
CaCl2 s −795.8 104.6 K s 0 64.2 PbS s −100 91
+
CaCO3 s −1206.9 92.9 K aq −252.14 102.5 PbSO4 s −920 149
CaO s −634.92 39.8 KBr s −393.8 95.9 S s 0 31.8
Ca(OH)2 s −986.1 83.4 KCl s −436.7 82.6 SO2 g −296.81 248.1
Ca3(PO4)2 s −4126 241 KClO3 s −397.7 143.1 SO3 g −395.7 256.7
−2
CaSO4 s −1434.1 106.7 KClO4 s −432.8 151.0 SO4 aq −909.34 20.1
Cd s 0 51.8 KNO3 s −494.6 133.0 S - 2 aq
+2
Cd aq −75.92 −73.2 Mg s 0 32.7 Si s 0 18.8
+2
CdCl2 s −391.5 115.3 Mg aq −467.0 −138.1 SiO2 s −910.7 41.8
CdO s −258.35 54.8 MgCl2 s −641.3 89.6 Sn s 0 51.6
+2
Cd(OH)2 s −561 96 MgCO3 s −1095.8 65.7 Sn aq −8.9 −17.4
CdS s −162 65 MgO s −601.60 26.9 SnO2 s −577.63 52.3
CdSO4 s −935 123 Mg(OH)2 s −924.5 63.2 Zn s 0 41.6
+2
Cl2 g 0 223.0 MgSO4 s −1284.9 91.6 Zn aq −153.39 −112.1
−
Cl aq −167.080 56.5 Mn s 0 32.0 ZnI2 s −208.0 161.1
− +2
ClO4 aq −128.10 182.0 Mn aq −220.8 −73.6 ZnO s −350.46 43.6
Cr s 0 23.8 MnO s −385.2 59.7 ZnS s −206.0 57.7
Table CC. Some Common & Equivalent Units and Approximate Conversions
Some Common & Equivalent Units

Length 1 in. (inch) = 2.54 cm
12 in. = 1 ft. (foot)
3 ft. = 1 yd. (yard)
5,280 ft. = 1 mi. (mile) = 1,760 yd
Mass 1 lb. (pound) = 16 oz. ~ 454 g

1 ton = 2000 lb.
1 tonne = 1000 kg
Volume 1 pinch = ≤ 1 8 teaspoon

3 teaspoons = 1 tablespoon (Tbsp)
2 tablespoons = 1 ounce
8 oz. (ounces) = 1 cup
2 cups = 1 pint
2 pints = 1 quart
4 quarts = 1 gallon
Some APPROXIMATE Conversions

Length 1 cm ~ width of a small paper clip
6 in. ~ length of a (US) dollar bill
1 ft. ~ 30 cm
1m ~ 1 yd.
1 mi. ~ 1.6 km
0.6 km ~ 1 mi.
1
Volume 1 pinch ~ ≤ 8 teaspoon
1 mL ~ 10 drops
1 teaspoon (tsp) ~ 5 mL ~ 60 drops
1 tablespoon (Tbsp) = 3 tsp ~ 15 mL
2 Tbsp. = 1 fl. oz. ~ 30 mL
1 C (cup) = 8 fl. oz. ~ 250 mL
1 qt. (quart) ~ 1L
Mass 1 small paper clip ~ 1 gram (g)

1 nickel (5¢ coin) ~ 5g
1 oz. ~ 30 g
1 pound (lb.) = 16 oz. ~ 0.5 kg
1 ton = 2000 lb. ~ 1 tonne
Speed 60 mi./h ~ 100 km/h ~ 30 m/s
Density air ~ 1 g/L

fresh water ~ 1 g/mL ~ 8.3 lb./gal.
3 3
~ 1 tonne/m ~ 1 ton/yd.
Table DD. Selected Formulas and Equations

M
Density D D = density M = mass V = volume
V
1 mol = [molar mass] g (molar mass = formula weight = gram formula mass)
Mole Conversions 1 mol = 22.4 L of gas at 0 °C and 1 atm
23
1 mol = 6.022 × 10 molecules, atoms, or particles
measured value - accepted value
Percent Error % error  *100%
accepted value
Percent mass of part
% composition  *100%
Composition mass of whole
moles of solute (moles of solute)(dissociation factor)
molarity (M)  normality (N) 
liter of solution liter of solution
moles of solute
Concentration molality (m) 
kg of solvent
moles of A grams of solute
mole fraction ( A )  parts per million (ppm)   1,000,000
total moles grams of solvent
P1 V1 PV P = pressure n = moles
 2 2
Gases T1 T2 V = volume (L) T = temperature (K)
atm  8.31 LkPa  62.4 Ltorr
R  0.0821 Lmol
PV = nRT K molK molK
1 atm = 101.3 kPa = 760 torr = 760 mm Hg = 29.92 in. Hg = 1.013 bar = 14.7 psi
Pressure PA = χAPT PA= partial pressure of A χA = mole fraction of A
PT = PA + P B + PC + … PT = total pressure
+ −
NA = normality of H3O NB = normality of OH
Titration NAVA = NBVB
VA = volume of acid VB = volume of base
Tf = freezing point depression
Tb = boiling point elevation (°C)
Tf = imKf (°C)
Kf = freezing point depression constant (H2O = 0.52 °C/m)
Colligative
Kb = boiling point elevation constant (H2O = 1.86 °C/m)
Properties Tb = imKb
i = van’t Hoff factor (dissociation factor) π = osmotic pressure
m = molality M = molarity (mol/L) N = normality (mol/L)
π = iM RT = N RT
R = ideal gas const. T = temperature (K)
+
pH = −log[H3O ] [H3O ][A  ]
Ka 
pOH = −log[OH ]
− [HA]
pKa = −log(Ka)
pH  pKa  log
base
Acid-Base
pH + pOH = 14
Kb 

[H B][OH ] 
pKb = −log(Kb)
acid 
−14
Kw= Ka∙Kb = 1 × 10 [B]
Δn Kp = gas press. Kc = molar conc. Δn = change in
Equilibrium Kp = Kc(RT)
equil. const. equil. const. # moles
q = m Cp T q = heat T = change in temperature
Heat q = m Hf m = mass Hf = heat of fusion
q = m Hv Cp = specific heat capacity Hv = heat of vaporization
ΔG° = ΔH° − TΔS° G° = standard free energy S° = standard entropy
Thermodynamics
ΔG° = −RT ln K H° = standard enthalpy T = temperature (K)
q=
charge
q I = current (amperes) t = time (seconds)
I (Coulomb
Electrochemistry t
s)
F = Faraday’s constant = 96,000 Coulomb per mole electrons
ΔG° = −nFE° n = moles of electrons E° = standard reduction potential
K = °C + 273.15 K = Kelvin
Temperature
°C= (°F−32) * 5/9 °C = degrees Celsius °F = degrees Fahrenheit
t
A = amount left t = total elapsed time t
Radioactive Decay A  Ao  12 ½ number of half-lives = 
  Ao = original amount τ½ = half-life ½
Periodic Table of the Elements
Chemistry 1
1 18
IA VIII A
Period
1 ±1 atomic # → 29 +2,1 ← ions commonly formed 2
H 2 atomic symbol → Cu 13 14 15 16 17 He
1 1s
hydro gen II A English element name → co pper III A IV A VA VI A VII A helium
1.008 63.55 ← atomic mass (rounded) 4.003

3 +1 4 +2 5 +3 6 −4 7 −3 8 −2 9 −1 10
2 2s Li Be 2p B C N O F Ne
lithium beryllium bo ro n carbo n nitro gen o xygen fluo rine neo n
6.968 9.012 Gases Liquids Metalloids 10.81 12.01 14.01 16.00 19.00 20.18
11 +1 12 +2 13 +3 14 −4 15 −3 16 −2 17 −1 18
Na Mg 3 4 5 6 7 8 9 10 11 12 Al Si P S Cl Ar
3 3s 3p
so dium magnesium III B IV B VB VI B VII B VIII B VIII B VIII B IB II B aluminum silico n pho spho rus sulfur chlo rine argo n
22.99 24.31 26.98 28.09 30.97 32.07 35.45 39.95
19 +1 20 +2 21 +3 22 +4,3,2 23 +5,2,3,4 24 +3,2,6 25 +2,3,4,6,7 26 +3,2 27 +2,3 28 +2,3 29 +2,1 30 +2 31 +3 32 +4,2 33 −3 34 −2 35 −1 36
4 4s K Ca 3d Sc Ti V Cr Mn Fe Co Ni Cu Zn 4p Ga Ge As Se Br Kr
po tassium calcium scandium titanium vanadium chro mium manganese iro n co balt nickel co pper zinc gallium germanium arsenic selenium bro mine krypto n
39.10 40.08 44.96 47.87 50.94 52.00 54.94 55.85 58.93 58.69 63.55 65.38 69.72 72.63 74.92 78.97 79.90 83.80
37 +1 38 +2 39 +3 40 +4 41 +5,3 42 +6,3,5 43 +7,4,6 44 +4,3,6,8 45 +3,4,6 46 +2,4 47 +1 48 +2 49 +3 50 +4,2 51 +3,5 52 −2 53 −1 54
5 5s Rb Sr 4d Y Zr Nb Mo Tc Ru Rh Pd Ag Cd 5p In Sn Sb Te I Xe
rubidium stro ntium yttrium zirco nium nio bium mo lybdenum technetium ruthenium rho dium palladium silver cadmium indium tin antimo ny tellurium io dine xeno n
85.47 87.62 88.91 91.22 92.91 95.95 98 101.1 102.9 106.4 107.9 112.4 114.8 118.7 121.8 127.6 126.9 131.3
55 +1 56 +2 71 +3 72 +4 73 +5 74 +6,4 75 +7,4,6 76 +4,6,8 77 +4,3,6 78 +4,2 79 +3,1 80 +2,1 81 +1,3 82 +2,4 83 +3,5 84 +4,2 85 86
6 6s Cs Ba † 5d Lu Hf Ta W Re Os Ir Pt Au Hg 6p Tl Pb Bi Po At Rn
cesium barium lutetium hafnium tantalum tungsten rhenium o smium iridium platinum go ld mercury thallium lead bismuth po lo nium astatine rado n
132.9 137.3 175.0 178.5 180.9 183.8 186.2 190.2 192.2 195.1 197.0 200.6 204.4 207.2 209.0 209 210 222
87 +1 88 +2 ## +3 ## ## ## ## ## ## ## ## ## ## ## ## ## ## ##
7 7s Fr Ra ‡ 6d Lr Rf Db Sg Bh Hs Mt Ds Rg Cn 7p Nh Fl Mc Lv Ts Og
francium radium lawrencium rutherfo rdium dubnium seabo rgium bo hrium hassium meitnerium darmstadtium ro entgentium co pernicum niho nium flero vium mo sco vium livermo rium tennessine o ganesso n
223 226 262 267 268 271 272 270 276 281 280 285 284 289 288 293 292 294
57 +3 58 +3,4 59 +3,4 60 +3 61 +3 62 +3,2 63 +3,2 64 +3 65 +3,4 66 +3 67 +3 68 +3 69 +3,2 70 +3,2
lanthanides † 4f La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb
(rare earth metals) lanthanum cerium praseo dymium neo dymium pro methium samarium euro pium gado linium terbium dyspro sium ho lmium erbium thulium ytterbium
138.9 140.1 140.9 144.2 145 150.4 152.0 157.3 158.9 162.5 164.9 167.3 168.9 173.1
89 +3 90 +4 91 +5,4 92 +6,3,4,5 93 +5,3,4,6 94 +4,3,5,6 95 +3,4,5,6 96 +3 97 +3,4 98 +3 99 +3 100 +3 101 +3,2 102 +2,3
actinides ‡ 5f Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No
actinium tho rium pro tactinium uranium neptunium pluto nium americium curium berkelium califo rnium einsteinium fermium mendelevium no belium
227 232.0 231.0 238.0 237 244 243 247 247 251 252 257 258 259
Page 563
Chemistry 1 Index Page 564
Index
acceleration, 61 calorimetry, 478, 479 dipole moment, 340, 343, 495
accuracy, 36, 38, 72 catalyst, 514, 519 direction, 36, 37, 474
acid, 7, 124, 174, 297, 438, 536, cell, 396, 442, 443 dissolve, 7, 28, 46, 112, 264, 345,
537, 540, 543, 548, 555, 563 charge, 75, 85, 129, 163, 164, 165, 372, 373, 374, 375, 377, 378,
air, 137, 138, 148, 225, 255, 395, 168, 169, 177, 180, 181, 190, 380, 384, 387, 388, 392, 393,
416, 491, 562 193, 214, 247, 259, 266, 273, 394, 395, 404, 416, 438, 520,
alkali, 263 274, 279, 282, 283, 284, 286, 536
alkali metal, 263 289, 290, 291, 294, 311, 314, distance, 23, 176, 192, 195
alkaline, 263 332, 337, 338, 343, 412, 434, double displacement, 402, 408
alkaline earth metal, 263 436, 437, 438, 563 double replacement, 408, 411, 412,
alpha decay, 193 chemical bond, 112, 279, 307, 335, 413
alpha particle, 193, 195, 208 342, 428, 500 effusion, 155, 157
Amonton, 128 chemical equilibrium, 522 electrolysis, 417
amphoteric, 537 chemical formula, 112, 148, 174, electrolytic cell, 442, 443
amplitude, 223 278, 281, 286, 287, 290, 300, electromagnet, 206
assumptions, 140 306, 356, 359, 360, 366, 367, electron, 162, 163, 166, 167, 168,
atom, 74, 75, 112, 123, 162, 163, 392, 419 170, 171, 193, 194, 197, 199,
164, 166, 167, 168, 169, 170, chemical reaction, 7, 17, 18, 30, 43, 213, 214, 215, 219, 221, 223,
173, 174, 183, 199, 200, 201, 125, 130, 163, 167, 229, 244, 224, 228, 230, 231, 234, 238,
204, 214, 221, 223, 224, 230, 246, 352, 381, 402, 403, 407, 239, 240, 244, 245, 246, 247,
233, 238, 244, 246, 247, 257, 408, 411, 419, 427, 428, 435, 248, 249, 254, 263, 265, 266,
265, 266, 267, 269, 272, 273, 446, 447, 452, 453, 456, 496, 267, 306, 307, 308, 309, 311,
274, 279, 280, 281, 286, 287, 497, 502, 514, 517, 518, 519, 313, 314, 318, 319, 320, 324,
300, 301, 307, 308, 309, 310, 523 435, 556
311, 313, 314, 317, 318, 319, chemical symbol, 165 electron capture, 194
320, 323, 324, 332, 335, 337, circuit, 208 electronegativity, 254, 269, 270,
338, 339, 351, 353, 412, 419, collision 280, 281, 306, 330, 331, 332,
420, 434, 435, 436 elastic, 135 333, 334, 335, 343
atomic mass, 157, 163, 164, 183, color, 178 electrostatic, 7, 108, 224
184, 256, 257, 258, 259, 351, combination, 10, 19, 74, 145, 174, element, 9, 111, 112, 114, 123, 163,
352, 353, 360 223, 402, 497, 548 164, 165, 167, 173, 183, 213,
atomic number, 164, 165, 196, 237, combined gas law, 139, 140 228, 229, 231, 234, 238, 240,
254, 258, 259 combustion, 402, 408, 411, 435, 248, 254, 255, 256, 257, 260,
atomic radius, 272 508, 510, 511 265, 266, 269, 270, 274, 281,
band of stability, 192, 193, 194 composition, 7, 162, 166, 174, 190, 287, 289, 290, 291, 333, 343,
base, 7, 73, 74, 75, 413, 438, 536, 359, 402 359, 360, 407, 412, 421, 422,
537, 540, 543, 548, 555, 563 compound, 76, 96, 98, 99, 111, 112, 435, 436, 437, 500, 557
basic, 84, 168, 389, 533, 540, 541 114, 133, 148, 164, 167, 174, empirical formula, 350, 359, 360,
beta decay 257, 281, 282, 283, 284, 287, 361, 362
beta minus, 193 289, 290, 291, 297, 299, 307, energy, 135, 170, 176, 195, 199,
beta plus, 194 314, 342, 343, 351, 353, 359, 200, 206, 207, 208, 219, 473,
beta particle, 195 360, 361, 362, 365, 366, 380, 474, 475, 477, 484, 493
binding energy, 199, 200 382, 392, 397, 407, 408, 412, kinetic, 473, 474, 493
Bohr model, 219 435, 436, 437, 447, 448, 498, enthalpy, 7, 375, 491, 494, 495,
boiling, 7, 108, 110, 111, 113, 119, 499, 500, 502, 503, 507, 509, 497, 498, 499, 500, 507, 509,
122, 129, 151, 205, 262, 263, 523, 537, 539 517, 561, 563
264, 330, 343, 372, 392, 393, concentration, 46, 85, 99, 100, 372, entropy, 7, 375, 472, 491, 494, 496,
394, 563 378, 387, 394, 396, 397, 514, 497, 561, 563
boiling point, 7, 108, 111, 113, 122, 520, 524, 541, 542, 551, 557 equilibrium, 18, 85, 493, 514, 522,
129, 151, 262, 263, 264, 330, conjugate, 537 523, 524, 529, 530, 540, 542
343, 372, 392, 393, 394, 563 Cornell Notes, 9 expand, 477, 483
boiling point elevation, 392, 394, current, 206 fermion, 180
563 debye, 340 fission, 190, 204, 205
bonding, 17, 278, 279, 306, 307, decomposition, 402, 407, 435 fluid, 116, 129, 404
323, 324 density, 7, 45, 85, 86, 87, 88, 90, 97, force, 176, 181, 192, 193, 199, 219
boson, 180 98, 100, 108, 111, 113, 262, 330,
buffer, 533, 548 552, 563
burning, 111, 113, 433 dipole, 340, 343, 344, 345, 374,
calorimeter, 30, 31, 43 377, 495
formula, 14, 30, 39, 61, 86, 112, kinetic molecular theory, 108, 128 osmotic pressure, 397, 563
124, 136, 145, 148, 156, 157, kinetics, 7, 18 oxidation, 7, 433, 434, 435, 436,
174, 230, 281, 283, 284, 286, limiting reactant, 456, 457, 458, 437, 438, 441, 442
287, 288, 290, 291, 294, 300, 459 oxidation number, 7, 433, 436, 437
314, 333, 340, 343, 351, 356, limiting reagent, 456 oxidation state, 436
359, 360, 361, 362, 366, 367, liquid, 33, 34, 100, 108, 109, 110, particle, 108, 163, 168, 171, 214,
392, 397, 437, 554, 563 114, 115, 116, 117, 118, 119, 215, 223, 229, 443, 495, 514,
free energy, 7, 496, 563 120, 121, 122, 129, 130, 135, 556
Gibbs free energy, 496, 497 151, 206, 264, 279, 343, 345, percent error, 39, 72
fuse, 206 378, 381, 393, 395, 404, 473, percent yield, 7, 446, 464, 465
fusion, 115, 116, 117, 190, 206, 483, 484, 485, 554 period, 74, 76, 229, 231, 260, 270
484, 485, 563 mass defect, 199, 200 periodic law, 258
galvanic cell, 442 mass number, 164, 165, 183, 184, periodic table, 17, 112, 213, 231,
gamma ray, 195, 207, 208 196 234, 237, 238, 240, 244, 245,
gas, 4, 7, 89, 90, 101, 108, 109, 110, matter, 4, 16, 17, 23, 84, 87, 108, 247, 248, 254, 257, 258, 259,
115, 116, 118, 120, 122, 124, 109, 112, 114, 120, 123, 128, 260, 263, 264, 270, 351, 353
125, 128, 129, 130, 131, 132, 173, 309, 351, 423, 428, 438 periodic trend, 7
133, 134, 135, 136, 137, 138, melt, 117, 206, 264 phase change, 483
139, 140, 141, 144, 145, 146, metal, 13, 45, 90, 168, 208, 280, physical, 7, 18, 74, 84, 108, 109,
148, 150, 152, 155, 156, 167, 289, 309, 333, 342, 343, 344, 111, 112, 113, 120, 123, 173,
240, 244, 247, 266, 267, 343, 407, 412, 416, 434, 437, 442, 230, 257, 258, 260, 330, 392,
351, 356, 378, 381, 394, 395, 443, 453 417, 495
397, 404, 477, 483, 484, 486, metathesis, 408 plasma, 206, 483
495, 500, 554, 563 metric system, 74, 77, 145 positive charge, 163, 168, 169, 208,
gas constant, 89, 90, 133, 145, 156, mixture, 108, 111, 112, 113, 114, 266, 273, 274, 282, 284, 289,
397, 563 156, 395 332, 337
gravity, 176 molecule, 120, 122, 123, 151, 157, power, 81, 195, 202, 207
half-life, 201, 202, 208 164, 167, 256, 260, 299, 300, precision, 36, 38, 40, 44, 48, 52, 72,
heat, 7, 13, 18, 30, 31, 33, 34, 43, 309, 313, 317, 318, 319, 320, 491, 502, 507, 515
85, 90, 129, 131, 168, 200, 205, 332, 337, 338, 339, 340, 342, pressure, 134, 137, 138, 139, 141,
206, 262, 266, 343, 375, 403, 343, 353, 359, 380, 394, 404, 146, 205, 477
404, 408, 416, 417, 473, 474, 419, 420, 422, 447, 495, 499 propagation, 204
475, 476, 477, 478, 479, 483, momentum, 135, 473 proton, 163, 171, 199, 204, 214,
484, 485, 486, 487, 492, 493, negative charge, 163, 168, 229, 215, 533, 556
495, 497, 499, 500, 502, 503, 274, 282, 283, 284, 289, 311, quantum, 18, 166, 170, 171, 219,
505, 507, 508, 509, 510, 511, 332, 337, 338 221, 223, 224, 228, 238
517, 530, 563 neutralization, 536 quantum mechanics, 18
heat capacity, 343, 563 neutralize, 208 quantum number, 170, 171, 224
heat of fusion, 484, 485, 563 neutrino, 180 quark, 176, 181, 192, 193, 194
heat of vaporization, 484, 486, 563 neutron, 163, 171, 199, 204, 215, radiation, 74, 75, 195, 207, 556
heating curve, 485, 486 556 radioactive, 190, 196, 201, 205,
hydrocarbon, 362, 408, 411 noble gas, 240, 244, 247, 264, 266, 207, 208
hydrogen bond, 330, 343, 344, 345, 267, 270 radioactive decay, 191, 192, 193,
374 nonmetal, 280, 289, 333, 342, 344 194, 195, 196, 197, 201
hydroxide, 124, 278, 288, 383, 533, non-metal, 261, 262, 280 reactant, 30, 31, 407, 447, 452, 456,
553, 554, 555 non-metal, 280 457, 458, 459, 505, 520
ideal gas law, 146 non-metal, 307 reaction, 7, 31, 43, 62, 123, 124,
inorganic, 18 non-metal, 309 173, 204, 205, 206, 352, 380,
intermolecular force, 342, 343, 375, non-metal, 407 381, 403, 404, 407, 408, 411,
377, 382 non-metal, 412 412, 413, 416, 419, 420, 427,
ion, 164, 165, 166, 214, 247, 264, nonpolar bond, 334 428, 433, 434, 435, 438, 441,
266, 267, 270, 274, 279, 280, nuclear, 123, 124, 125, 162, 190, 442, 443, 447, 452, 453, 456,
283, 286, 287, 288, 289, 290, 196, 199, 205, 206, 207, 214, 457, 459, 464, 465, 496, 500,
291, 293, 294, 297, 311, 314, 259, 273, 495 502, 503, 505, 507, 508, 509,
343, 344, 345, 374, 377, 380, nucleus, 162, 163, 164, 166, 168, 510, 511, 515, 516,517, 518,
381, 382, 407, 413, 416, 427, 169, 170, 171, 199, 204, 214, 519, 520, 522, 523, 524, 529,
436, 437, 500, 533, 537, 554 221, 223, 230, 231, 266, 272, 536, 548
isotope, 183, 184, 190, 196, 208 273, 274, 319 reagent, 456
Kelvin, 140, 146 orbital, 166, 224, 230, 232, 234, redox, 435, 438, 441
kinetic energy, 97, 130, 131, 145, 238, 239, 248, 249, 323, 324 reduction, 7, 433, 434, 435, 438,
151, 155, 157, 378, 473, 474, organic, 18, 281, 508 441, 442, 563
493, 495, 517, 520 osmosis, 396, 397
relative error, 38, 39, 42, 43, 45, 46, specific heat capacity, 13, 30, 43, units, 14, 17, 43, 55, 57, 72, 73, 74,
62 90, 476, 477, 478, 485, 486, 563 75, 76, 84, 85, 89, 90, 91, 93, 96,
salt, 100, 112, 114, 393, 394, 443, spectrum, 217 97, 109, 111, 115, 140, 145, 146,
536 speed, 193, 194, 199, 204 156, 157, 353, 356, 477, 498,
scientific notation, 49, 52, 72, 78, standard model, 178 502, 507
80, 81, 82, 83 stoichiometry, 7, 18, 356, 372, 446, valence, 246, 247, 248, 249, 257,
significant figures, 14, 47, 48, 49, 447, 448, 449, 452, 453, 456, 260, 262, 263, 264, 270, 278,
52, 53, 54, 57, 72, 84, 94, 96, 99, 458, 464, 465, 502, 505 280, 306, 307, 313, 314
109 strong force, 176, 181, 192 valent, 247, 257, 266, 267, 280,
single displacement, 402, 407 surroundings, 484, 492, 493 308, 309, 311, 324, 437
single replacement, 407, 411, 412, synthesis, 402, 407, 435 vapor, 7, 115, 120, 122, 151, 392,
416, 435 system, 9, 11, 13, 16, 19, 27, 33, 36, 395, 404, 554
solid, 72, 108, 109, 110, 113, 114, 38, 47, 55, 59, 64, 73, 80, 84, 91, velocity, 195
115, 116, 118, 120, 121, 129, 96, 109, 111, 115, 473, 483, 484, VSEPR, 306, 317, 318, 319, 320,
130, 135, 166, 215, 264, 279, 491, 492, 493, 502, 507 321, 324, 325
343, 365, 380, 393, 404, 428, temperature, 134, 137, 138, 139, water, 17, 28, 30, 31, 43, 45, 74, 99,
442, 473, 483, 484, 485, 554 140, 141, 146, 208, 473, 474, 112, 113, 114, 117, 119, 124,
solubility, 373, 380, 383, 384 477, 478, 479, 480, 485, 486, 138, 151, 174, 205, 225, 255,
soluble, 263, 264, 342, 373, 382 487, 492, 493 263, 264, 297, 330, 339, 343,
solute, 342, 373, 374, 375, 377, theoretical yield, 464 345, 365, 366, 367, 377, 380,
378, 380, 382, 384, 387, 388, theory, 7, 11, 19, 22, 23, 130, 162, 381, 382, 384, 387, 388, 389,
389, 392, 393, 394, 395, 396, 166, 167, 168, 169, 174, 306, 392, 393, 394, 395, 396, 404,
397 317, 318, 397, 419, 515, 524, 412, 416, 417, 438, 442, 493,
solution, 11, 14, 46, 100, 112, 372, 533 533, 536, 537, 539, 540, 542,
373, 374, 375, 378, 380, 381, thermal equilibrium, 493 562
384, 387, 388, 389, 392, 393, thermal expansion, 473 wave, 171, 217, 223
394, 395, 397, 404, 420, 427, thermometer, 41, 57, 473, 493 wavelength, 171
442, 443, 453, 540, 541, 542, uncertainty, 38, 39, 40, 41, 42, 43, weak force, 176, 192, 193
548 44, 45, 46, 47, 48, 50, 52, 53, 57, weight, 57
solvent, 113, 342, 343, 373, 374, 58, 61, 62, 63, 66 wire, 206
375, 377, 378, 382, 384, 387, unit, 4, 39, 72, 73, 74, 76, 77, 82, work, 58, 59, 81, 193
392, 393, 394, 395, 396, 539 85, 88, 91, 92, 93, 94, 96, 97, 98, yield, 464, 465
specific heat, 13, 30, 43, 90, 343, 99, 145, 163, 190, 226, 340, 387,
563 452, 458

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Heat of Reaction Page: 501

Big Ideas Details Unit: Thermochemistry (Heat)

A: First we look up our heats of formation. We need to remember to change the

(272kJ)  (634.92kJ)  361kJ

We always represent heat as a positive quantity in chemical reactions. If heat is

Ca + FeO → CaO + Fe + 361 kJ

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Chemistry 1 Mr. Bigler

For example, in the reaction:

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Heat of Reaction and Stoichiometry

substance’s heat of formation by its coëfficient in order to calculate its contribution

A: Again we look up our heats of formation. However, now, we need to both

Using our stoichiometry “input/output machine”, 3 mol of Ca produces 979 kJ of

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Answer: H o  9 kJ Pb + FeSO4 + 9 kJ → PbSO4 + Fe

2. 2 C2H2 + 5 O2 → 4 CO2 + 2 H2O

Answer: H o  2 511kJ 2 C2H2 + 5 O2 → 4 CO2 + 2 H2O + 2 511 kJ

3. C6H12O6 + 6 O2 → 6 CO2 + 6 H2O

Answer: H o  2 537kJ C6H12O6 + 6 O2 → 6 CO2 + 6 H2O + 2 537 kJ

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For most molecular compounds, instead of attempting to publish an exhaustive list

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Bond C−C C=C C≡C C−H C−O C=O O=O O−H

CH4 + 2 O2 → CO2 + 2 H2O

This actually means:

1 644 kJ + 988 kJ + (−1 598 kJ) + (−1 836 kJ) = −802 kJ

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CH4 + 2 O2 → CO2 + 2 H2O

+74.8 kJ 0 kJ 393.5kJ 483.6 kJ

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Bond C−H C=O O=O O−H

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Answer: −2 016 kJ (Note: calculating from H of values gives 2 044 kJ)

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Summary: Thermochemistry (Heat)

Write an introductory sentence that categorizes these main ideas.

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Introduction: Kinetics & Equilibrium

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Massachusetts Curriculum Frameworks (2006):

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Collision theory states that:

For example, consider the reaction: NO3 + CO → NO2 + CO2

effective collision: a collision with enough energy that it leads to formation of

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Rate of Reaction (Kinetics)

Labs, Activities & Demonstrations: