SODA SOLVAY ww» Soda Ash Date ; 01.11.2016 Rev. SAFETY DATA SHEET Date : 15.09.2020 According to Page: 42 IRevisionNo 05 EU Regulation No (EC) 453/200 4. PRODUCT AND COMPANY IDENTIFICATION 1A. Identification of the substance/preparation Product Name Soda Ash Dense Chemical Name ‘Sodium carbonate, anhydrous: Grades/Trade Names Dense soda ash chemical grade soda ash Synonyms Soda salt, soda crystal, sodium carbonate Chemical Formula Na2CO3 Molecular Weight 105.99 GAS Number 497-18-8 REACH Registration Number : 01-2119485498-19-0003 one 263620000011 4.2, Relevant Identified Uses of the Substance and Uses Advised Against (ANNEX 1) Exposure Scenario Sector of Product Use SU) Category (PC) Manufeuring SUS Not applicable Girma Su No applicable meu Se opti Other indostial and SU0-20,2,Not protesionalses, 23,24 applicable Consuneruse st2l_ PCO No uses are advised against. Process category (PROC) PROC 1-4, 8a, 8b, 9, 22 PROC 26 82, 8b, 22, 23, Environmental Release Category (ERC) ERC 1 ERC 6a PROC 1-5, 8a, 8b, 9, 14, ISERC 2 PROC 1-4, 7, 8a, 8, 9, 10, 11, 13, 15, 17, 18, 19, 22,23, 26 Not applicable 4.3. _ Details of the Supplier of the SDS REACH Only Representat Sisecam Bulgaria EQOD (Ltd) 5 General Stoletov str. 9002 \Varna/Bulgaria Phone +359 52 608 963 Fax +: +359 52 608 964 E-mail : RDIMITROV@sisecam.com ERC 4, 5, 6a, 6b, 6d, 7, 8a, 8b, Bc, 8d, Be, Bf, 9a, 9b ERC 8a, 8b, 8c, 8d, Se, Bf, 92, 9b Article category ao) Not applicable Not applicable Not applicable Not applicable Not applicableSODA SOLVAY S&S ‘Soda Ash Date 201.11.2016 Rev. SAFETY DATA SHEET Date : 15.09.2020 According to Page: 2/12 [Revision No = 03 EU_Regulation No (EC) 4539/2010 Manufacturer 7 Sada Sanayii AS. Address Soda Sanayi A.S. Kazanli Bucagi Yani 33004 Mersin/Turkey Phone £490 324 241 6600 Fax +90 324.451 3440 E-mail of SDS Respons le : soda@sisecam.com 1.4, Emergency telephone number Emergency Tel. No +90 324 241 66 00 Opening Hours + Only available during office hours (07:00-17:00 CET) 2, HAZARDS IDENTIFICATION 2.4 Classification of the Substance Classification EU (67/548/EC) ‘Symbols Xi Irritant Phrases R36 Irritating to eyes. ‘$2 Keep out of reach of children. 22 Do not breathe dust. $26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 2.2. Classification EU (1272/2008/EC) Classification: Hazard Class and Category Code ~ Eye Imtant 2 Hazard Statement H319 Causes serious eye irritation Precautionary Statement: P 264 Wash thoroughly after handling 280 Wear protective gloves / protective clothing / eye protection / face protection P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P3374P313 If eye irritation persists: Get medical advice/attention Labelling Hazard Statement H319 Causes serious eye irritationSODA SOLVAY ww ‘Soda Ash Date TOT1.2016 Rev. SAFETY DATA SHEET Date : 15.09.2020 According to Page: 3/12 [Revision No 03 EU_ Regulation No (EC) 453/2010 Precautionary Statement P 264 Wash thoroughly after handling P280 Wear protective gloves / protective clothing / eye protection / face protection P205+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do, Continue rinsing, P337+P313 _ Ifeye irritation persists: Get medical advice/attention 2. 3.0ther Hazards ‘The substance does not contain any PBT or vPVB. 3. COMPOSITION OF/INFORMATION ON INGREDIENTS, Norm Sodium Carbonate, Na;COs (%) * $9.10 min ‘Sodium Carbonate, Na,COs (%) ** 99.30 min Sodium Chloride, NaCl (%) 0.20 max Iron, Fe (ppm) 15 max Insoluble Part (%) 0.01 max Sulphate SO (%) 0,027 max Copper, Cu (ppm) 41 max ‘Arsenic As (ppm) max Lead, Pb (ppm) 2max Mercury , Ha (ppm) 0.1 max Loss on Ignition (2%) 0,5 max “for the product of Light Soda Ash “for the product of Heavy Soda Ash 4, FIRST AID MEASURES 44. Inhalation = Remove the subject from dusty environment and let him blow his nose. ~ if symptoms persist, call a physician. 42, Eye contact ~ Rinse immediately with plenty of water, also under the eyelids, or atleast 15 minutes. ~ Consult with an ophthalmologist immediately in all cases.SODA SOLVAY \S Soda Ash Date 70712016 Rev. SAFETY DATA SHEET Date : 15.09.2020 According to Page: 4/12 RevisionNo : 03 EU_ Regulation No (EC) 453/2010 4.3. Skin contact ~ Remove and wash contaminated clothing before re-use. = Wash off with plenty of water. - If symptoms persist, call a physician. 4.4. Ingestion The following actions are recommended : = Call a physician immediately. If victim is conscious: = If swallowed, rinse mouth with water (only ifthe person is conscious). = Do NOT induce vomiting. If victim is unconscious but breathing: - Artificial respiration and/or oxygen may be necessary. = Never give anything by mouth to an unconscious person, 6 IRE-FIGHTING MEASURES. 5.1. Suitable extinguishing modia ~ Use extinguishing measures thal are appropriate to local circumstances and the surrounding environment 5.2, Extinguishing media which must not be used for safety reasons ~None 5.3. Special exposure hazards in a fire - Not combustible. 5.4. Special protective equipment for fire-fighters - No special precautions required. 6. ACCIDENTAL RELEASE MEASURES 6:1. Personal precautions Refer to protective measures listed in sections 7 and 8. 6.2. Environmental precautions ~ Do not flush into surface water or sanitary sewer system. “ifthe product contaminates rivers and lakes or drains inform respective authorities. 6.3. Methods tor cleaning up ~ Sweep up and shovel into suitable containers for disposal = Avoid dust formation = Keep in property labeled containers. = Keep in suitable, closed containers for disposal ~ Treat recovered material as described in the section "Disposal considerations”SODA SOLVAY w& ‘Soda Ash Date 701.11.2016 Rev. SAFETY DATA SHEET Date : 15.09.2020 According to Page: 6/12 IRevisionNo = 03 5 EU_Reguiation No (EC) 4535/2010 7. HANDLING AND STORAGE 7.4. Handling = Use only in well-ventilated areas. = Keep away from Incompatible products. 7.2. Storage ~Keep in a dry place, - Store in original container. - Keep container closed - Keep away from incompatible products. 7.3. Specific use(s) For further information, please contact: Supplier 7.4 Packaging material - Exterior Woven PP interior laminated - Kraft ~ Avoid dust formation. - Refer to protective measures listed in sections 7 and 8 8. EXPOSURE CONTROLS / PERSONAL PROTECTION DNEL Values In view of its physicochemical properties, the physiological role of its constituent ions, and its toxicological properties, exposure to NazCO, is considered to have no systemic effects. Sodium carbonate rapidly dissociates into Na" (sodium) and CO,” (carbonate), when in contact with any body fluid. Sodium is an essential metal, present in vertebrates in relatively high levels under physiological conditions, Carbonate is a component of the extracellular buffer in the blood and the interstitial fluid of vertebrates, ie. the bicarbonate buffer system. The uptake of sodium, via exposure to sodium caroonate via any route, is expected to be much less than the uptake of sodium via food (recommended daily dietary intake has been reported in the range of 3.1 to 6.0 9). Systemic effects Exposure to sodium carbonate is, therefore, not expected to result into systemic effects. This is supported by absence of any observed systemic effects in performed developmental toxicity studies, “Therefore, ne DNEL. ‘and DINE ang erm «yeame derivations are necessary. Local effects Itmay be thought that the substance could induce local effects upon contact with ports of entry at high concentration: dissolution of NagCO, may induce local pH changes, which may cause local effects uponSODA SOLVAY & ‘Soda Ash Date = 01.11.2076 Rev. SAFETY DATA SHEET Date : 15.09.2020 According to Page: 6/12 IRevisionNo : 03 EU_Reguiation No (EC) 453/2010 a fa single or repeated exposure, Available studies fo establish a DNELo~ for the various routes of exposure will be discussed hereafter. Oral route (Oral uptake of reasonable amounts of sodium carbonate will result in 2 neutralisation in the stomach due to the presence of gastric acid. Sodium carbonate is not classified for acute oral toxicity, due to its relatively low oral toxicity (LDso = 2600 mg/kg, rat). Therefore, itis not considered necessary to derive a DNELicca for oral exposure to sodium carbonate. Dermal route ‘Several derma irritation studies have been described, both with animals and human volunteers. Since no iritation has been observed when sodium carbonate was applied to intact skin, 2 DNELocs 's not considered necessary for dermal exposure. Inhalation Sodium carbonate was tested in a repeated dose rat inhalation study, showing local effects after 3.5 months at the only tested exposure of 70 mgim®. However, this study was considered unreliable. Acute toxicity studies showed local effects at the lowest tested concentration of 500 mgim” in guinea pigs. AS both studies suffer from clear short-comings, itis not considered possible to derive a DNELaaite lat ANG DINELing tom, cea directly from this data. They do inform though on the location and type of lesions ‘observed, and in that way support the view that the histopathological changes observed are the direct consequence of the alkaline nature of sodium carbonate, i.e. via generation of OH-cations upon contacting body fluids. In accordance with Chapter R.8 of REACH Guidance on information requirements and chemical safety ‘assessment, national Occupational Exposure Limit (OEL) can be used in piace of a DNEL if an evaluation of the scientific background for its setting has been performed. Currently, no OEL has been ‘set by any country authority. However, Occupational Exposure Limits have been derived for other well known substances which have also local effects based on their alkaline properties ‘Sodium hydroxide (NaOH) is a well known alkaline and corrosive substance and the OEL is 2 mg/m’ in most countries based on information from the Ariel database. Calcium hydroxide (CaOH2) is not Corrosive but is irtating to the skin and the OEL is 5 mg/m’ in most countries (information from the Ariel database), Sodium carbonate is even less alkaline because it is not irritating to the skin but it is only irritating to the eyes. Therefore the OEL of sodium carbonate should be higher than 5 mgim®. It is assumed that the estimated OEL of sodium carbonate is only a factor 2 higher than the OEL of calcium hydroxide and this results in an OEL of 10 mgim’ for sodium carbonate. A value of 10 mgim’is similar to the general dust limit of inert dust (inhalable fraction). Eye ‘Sodium carbonate is classified as an eye irritant. As eye irritation studies have been performed using Undiluted tect cubstance, no dose-reeponse data could be obtained to derive @ DNEL. Furthermore, no quantitative data on human eye irritation is available that could allow a DNEL to be set for eye exposure. PNEC ValuesSODA SOLVAY ‘Soda Ash Date [01.41.2076 Rev. SAFETY DATA SHEET Date : 15.09.2020 According to Page: 7/12 iRevisionNo 03 EU_Regulation No (EC) 453/2010 es Final pa” ‘Omgil HCO; 1.106) 16 (6.1) | 60361) (distilled water) 20 mg HCOs 272 32.26) 766 (81) | lo" percentile of 77 rivers) : 106 mg/l HCOs 9.7 (107) 102 (112) 1467 (167) | (mean value of 77 rivers) = 195 mgil HCO; 1719) ——~*| (75 @1) 2192 (056) [00 percentile of 7 river) | 8.1 Exposure Limit Values OSHA PEL SAEL Sodium Carbonate 10 mg/m3 Total Dust Nuisance Dust Smg/m3 (Respirable fraction) 15 mg/m3 (Total dust) Time Weighted Average for 8 hour workdays. No specific TLV-STEL (Short Term Exposure Level) has been set. Excursions in exposure level may exceed 3 times the TLV-TWA for no more than a total of 30 minutes during a workday and under no circumstances should they. exceed 5 times the TLV-TWA 8.2. Exposure controls ~ Ensure adequate ventilation ~ Provide adequate exhaust ventilation at places where dust is formed. ~ Refer to protective measures listed in sections 7 and 8 = Apply technical measures to comply with the occupational exposure limits 8.2.1. Exposure Controls 8.2.1.1.Respiratory protection = Use only respiratory protection that conforms to intemational/ national standards - In case of insufficient ventilation, wear suitable respiratory equipment - Use NIOSH approved respiratory protection. = Respirator with a dust fter 8.2.1.2. Hand protection —Take note of the information given by the producer conceming permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact) = Wear suitable gloves. = Suitable material: Neoprene, Natural Rubber. 8.2.1.3. Eye protection = Dust proof goggles. if dusty.SODA SOLVAY S&S ‘Soda Ash Date 7 07.11.2076 Rev. SAFETY DATA SHEET Date : 15.09.2020 According to Page: 8/12 IRevisionNo 03 EU_Regulation No (EC) 4539/2010 8.21.4, Skin and body protection Long sleeved clothing = Dust impervious protective suit ~ Rubber or plastic boots Rubber or plastic apron 5. Hygione measures - Use only in an area equipged with a safety shower. = When using do not eat, drink or smoke. = Handle in accordance with goad industrial hygiene and safety practice. 8.2.2. Environmental Exposure Controls ~ Dispose of rinse water in accordance with local and national regulations. 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1, General information ‘Appearance Granules, Powder Color White Odor Odorless 9.2. Important Health Safety and Environmental Information pH 114.4 Concentration: 4.016 gll Temperature: 25 °C (77 °F) Boiling pointirange Not applicable Flash point Not applicable Flammability Not applicable Explosive propertios Not applicable ‘Oxidizing properties + Not applicable Vapor pressure Not applicable Relative density / Density: 2.5 Partition coefficient Not applicable (noctanoliwator) Viscosity Not applicable Vapor density Not applicable Bulk density” 0.47 — 0.59 gfe? Bulk density “= 0.85 1.16 gicm? (Water) 71 gl Tomp: 0°C (32 °F) £215 gll Temp: 20°C (68 °F) for the product of Light Soda Ash ‘for tha product of Heavy Soda Ash 9.3 Other information Melting point/range 851°C ( 1,564°F) Decomposition tomperature : > 400 °C (752 °F)SODA SOLVAY & Soda Ash Date 701.171.2016 Rev. SAFETY DATA SHEET Date : 15.09.2020 ‘According to Page: 912 ~|Revision No: 03 EU_Regulation No (EC) 453/2010 Granulometry 95-100 % 250-400 pm 40. STABILITY AND REACTIVITY 10.1. Stability = Stable under recommended storage conditions 10.2. Conditions to avoid - Exposure to moisture, 10.3, Materials to avoid = Finely divided aluminum 40.4. Hazardous decomposition products = None 44. TOXICOLOGICAL INFORMATION 41.1 Toxicological data Acute oral toxicity = LDS0, rat, > 2,000 mg/kg Acute inhalation toxicity = C50, 2h, rat, 2.3 mg/l Acute dermal irritation/corrosion = LDS0, rabbit, 2,000 mg/kg Skin irritation = rabbit, No skin irritation Eye irritation - rabbit, Irritant effects 44.2 Chronic toxicity! Carcinogenic Designation: Chronic toxicity Inhalation, rat, Target Organs: Lungs, NOEL: 0.07 mg/l, observed effect Genetic toxicity in vitro Remarks: no observed effect Teratogenicity = Oral route (gavage), 10 days, Various species, NOAEL teratog. : 179 mg/kg, Did not show teratogenic effects in animal experiments Remarks = Imitating to eyes. 42. ECOLOGICAL INFORMATION 12.1, Ecotoxicity errects ‘Acute toxicity - Fishes, Lepomis macrochirus, LC50, 96 h, 300 magi! - Fishes, Gambusia affinis, LC50, 96 h, 740 mg/l ~ Crustaceans, Ceriodaphnia dubia, EC50, 48 h, 200 - 227 mg/lSODA SOLVAY & ‘Soda Ash ‘| Date 701.11.2046 Rev. SAFETY DATA SHEET | bate : 15.09.2020 According to Page: 10/12 IRevisionNo : 03 vas nega nee asa | Chronic toxicity Cprytoplankion, ECS0, biomass, 7 Days, 14 malt 12.2. Mobility -Air Remarks: not applicable = Water Remarks: Solubility = Water Remarks: Mobility - Soilsediments Remarks: not significant 42.3. Persistence and degrada! ‘Abiotic degradation = Water, Hydrolysis 7 Result: acibase equilibrium as a function of pty jopradation products: carbonic acc bicarbonate! carbonate Biodegradation “Remarks: The methods for determining biodegradability are not applicable 10 Inorganie substances. 42.4. Bioaccumulative potential = Not Applicable 42.5, Results of PBT assesstment ee adium earbonate is not considered fo be a PBT substance 42.6. Other adverse effects no data available 43, DISPOSAL CONSIDERATIONS 43.4 Waste treatment: Soda Ash is nota listed hazardous waste under 40 CFR 261 Heroes, state and local regulations for waste disposal ™2Y be more restrictive. Spilled product should te digposed of n accordance wit appicable federal ‘state and local environmental laws ang regulations. 43.2 Packaging treatment: To avoid treatments use dedicated containers where possible. Rinse the pty containers and treat the effluent in the same way St ‘waste, Consult current federal, state and Pret Squtations regarding the proper dieposal oF emptied containe!> 43.9 RORA Hazardous Waste: Not Listed 44, TRANSPORT INFORMATIONSODA SOLVAY ~ ‘Soda Ash Date 70741-2016 Rev. SAFETY DATA SHEET Date : 15.09.2020 According to Page: 1142 Revision No: 03 EU. Regulation No (EC) 453/2010 Mode Dor IMDG TATA UN Number Not a regulated Nota regulated Not a regulated hazardous material hazardous material hazardous material Other itis recommended that ERG guide #111 be used forall non DOT regulated material sTcc# (28-123-22 45. REGULATORY INFORMATION Labeling according to Directive 1272/2008/EC Name of dangerous products- sodium carbonate 15.2. Chemical Safety Assestment ‘A chemical safety assestment is prepared by the manufacturer 46. OTHER INFORMATION 16.1 Ratings: NFPA (NATIONAL FIRE PROTECTION ASSOCIATION) Health = 2 Fire =0 Instability = 0 Special = None HIS (HAZARDOUS MATERIAL INFORMATION SYSTEM) Health = 2 Fire = 0 Reactivity = 0 PPE = Supplied by User, dependent on local conditions 46.2 Other Information: To our actual knowledge, the information contained herein is accurate as of the date of this document. However, neither Soda Sanayii AS., nor any of its affilates makes any warranty, xpress or implied, or accepts any lablity in connection with this information or its use. This *Brmation ig for use by technically skilled persons at their own discretion and risk and does not Mate to the use of this product in combination with any other substance or any other process. This information gives typical properties only and is not to be used for specification purposes. Soda Sanayil AS, reserves the right to make additions, deletions or modifications to the information at any time without prior notification. TRADEMARKS: All trade name of products referenced herein are either trademarks or registered rademarks of Soda Senayii AS. unless otherwise identified ANNEX I:SODA SOLVAY we Soda Ash Date 701.11.2016 Rev. | SAFETY DATA SHEET Date : 15.09.2020 According Page: 1212 Revision No =03 EU_ Regulation No (EC) 453/2010 Identified uses Different qualities of sodium carbonate are produced based on the final use of the substance, Technical, food and pharmaceutical grades are placed on the market. ‘The highest volumes of sodium carbonate are used in the following industries: +” Glass industry; + Soap and detergent industry; Other industries like chemical industry, stee! industry, non ferrous metallurgy industry, etc. t ‘The glass industry is by far the largest single demand sector consuming more than half of the sodium carbonate producediimported. Sodium carbonate is used as an intermediate in the manufacturing of glass. The second largest industrial use is the formulation of cleaning products. Sodium carbonate '¢ for example used as a builder in detergent formulations. ih the chemical sector. sodium carbonate is used as intermediate, for example in the production of sodium tpolyphosphate, sodium silicate, sodium percarbonate, sodium chromate and sodium bicarbonate. In the steel industry sodium carbonate is used mainly as fluxing agent in the sleg formation, to remove the phosphorus from the steel. Sodium carbonate has also environmental applications in effluent and in acid waste neutralzation and is used 2s 9 source of alkalinity, inthe pully and paper sectors, nthe textles industry and for brine purfication. in the professional domain, sodium! Garoonate is mainly used in the cleaning industry and in some agricultural applications (co-formulant), It may be used directly in solutions of sodium carbonate for laundry, dishwashing, floor washing and for degreasing operations. ‘A lage number of consumer products ike washing powders, soans, cosmetics and scouring powders contain a varying proportion of sodium carbonate. The following exposure scenarios are distinguished: 0 -ES1_ Manufacturing of sodium carbonate ES2 Glass production ES3 Formulation ES4 Other industrial and professional uses ES5 Consumer use oooa In Section 1.2. the identified uses and exposure scenarios are described based on the use descriptors eveloped by the European Chemicals Agency (REACH Guidance on Information Requirements and Chemical Safety, Chapter R12).