SUNDAY, FEBRUARY 27, 2005

SUNDAY POSTER SESSION

Session 10

(10-21 P) Thermionic Detection of Water and Formic Acid with High Selectivity versus Hydrocarbons PAUL L PATTERSON, DETector Engineering & Technology (10-22 P) New On-line Monitoring System for Dissolved Gases in Electrical Insulating Fluids JOHN V HINSHAW, Serveron Corporation, Dan Morgan, Thomas Waters (10-23 P) Fast Resin-Screening and Method Development with PrePacked Process Development Columns THOMAS J HIGLEY, Tosoh Bioscience LLC (10-24 P) An Efficient Approach to Column Selection in HPLC Method Development GUANG QING LI, Varian, Inc., Dennis D Blevins (10-25 P) A New Phase for LC/MS Analysis of Drugs in High Organic Mobile Phases GUANG QING LI, Varian, Inc., Ritu Arora, Dennis D Blevins (10-26 P) Mercury Analysis of Any Sample Type: No Compressed Gases Required JASON P GRAY, AGS Scientific, Inc., Koji Tanida, Alvin Chua (10-27 P) Assessing New State-of-the-Art Silica-Based HPLC Columns: Improved Peak Shapes, Efficiencies and Low pH Stability DIANE M DIEHL, Waters Corporation, Kimvan Tran, Ziling Lu, Eric S Grumbach, Bonnie Alden, Pamela Iraneta, Jeffrey R Mazzeo (10-28 P) Evaluation of a New Purge and Trap On-line Interface for the Real Time Analysis of VOCs in Aqueous Streams MARK E KRIGBAUM, Teledyne Instruments - Tekmar (10-29 P) Portable, Fast GC/QitTof MS with Dual EI/PI Source JIANWEI LI, Syagen Technology, Inc., Matt Evans, Jack Syage (10-30 P) Collector/Concentrator of Bacteria and Virus for Biodetectors FRED TEPPER, Argonide Corporation, Leonid Kaledin (10-31 P) Identification of Chemical Unknowns in Micro Quantities MARTIN M SZCZESNIAK, Surface Optics Corporation, Michael Beecroft, Jamie Ferguson (10-32 P) Withdrawn (10-33 P) Withdrawn (10-34 P) Calibration Transfer between MEMS-Based Near-Infrared Spectrometers LARRY MCDERMOTT, Axsun Technologies, Richard A Crocombe, Matthew Smith (10-35 P) Qualification of an Electrodeionisation Module via Experimental Design and Ion-chromatographic Calibration Studies TELIS DIMITRAKOPOULOS, Millipore, Elodie Castillo, Daniel Darbouret, Emmanuel Feuillas, Celine Le Ninivin, Lynn Vanatta (10-36 P) Precision Study on Dip Rinse versus Shower Rinse on an Automated Titrator System TORE FOSSUM, Mettler-Toledo, Inc. (10-37 P) New pH Glass Electrode with Pb Free Glass TAKESHI KOBAYASHI, Horiba, Ltd. (10-38 P) Protecting our Water Sources from the Threat of Domestic Terrorism Using Online VOC Monitoring via Purge and Trap GC and GC/MS Systems AMOS LINENBERG, INFICON, Les H Volles, Nancy M Otto (10-39 P) Withdrawn (10-40 P) Remote Threat Detection Using Spectral Imaging Spectroscopy JAFOLLA C JAMES, Surface Optics Corporation, Michael Beecroft, Leif Hendricks (10-41 P) Minimizing Bleed and Stabilization Time in GC-MS with Thick Film Coated Fused Silica Capillary Columns JAAP DE ZEEUW, Varian, Inc., Peter Heijnsdijk (10-42 P) Fluidic Logic Valve for Liquid Chromatography ROBERT WESTERN, SGE International Pty. Ltd., Peter Dawes, Ern Dawes, Brett Barnett, Dan DiFeo (10-43 P) Possibilities to Use the Carbon Materials Obtained by Waste Oil Pyrogenation TONE LUMINITA, University "Politehnica" of Bucharest , Paraschiv Maria (10-44 P) A Multimode Source for Simultaneous Electrospray and Atmospheric Pressure Ionization PATRICK D PERKINS, Agilent Technologies, Inc., Steven M Fischer, Patricia H Cormia, Darrell L Gourley, Glen F Ingle, Wayne P Duncan, Douglas E McIntyre (10-45 P) Performance, and Applications of a Unique 3-D Optics Spectrophotometer with Far-UV Through NIR Measurement Capability SHANNON RICHARD, Shimadzu Instruments, Timothy Alt, John A Monti (10-46 P) Organic Elemental Analysis in Paper Industry by Flash Dynamic Combustion Method LILIANA KROTZ, Thermo Electron Corporation, Luigi Ragaglia, Guido Giazzi, Richard Hancock

Sunday posters will be on display from 2:00 PM to 7:30 PM with authors present from 5:30 PM to 7:30 PM. The posters will be located on the Exposition floor level South Hall A1

New Developments in Analytical Instrumentation and Software

(10-1 P) Infrared Spectrometry On-site MICHAEL S BRADLEY, Thermo Electron Corporation, Federico Izzia (10-2 P) Automating Lowry Protein and Other Assays Using a Personal Automated Pipetting System MICHAEL N SEVIGNY, Bio-Tek Instruments, Inc., Paul Held (10-3 P) Isotope Abundance Analysis Software for Improved Sample Identification with the Supersonic GC-MS and LC-EI-MS AVIV AMIRAV, Tel Aviv University, Tal Alon (10-4 P) Instrumental Features and Applications of Ion Attachment Mass Spectrometer YOSHIRO SHIOKAWA, ANELVA Technix Corporation, Harumi Maruyama, Masako Inoue, Megumi Nakamura, Yoshiki Hirano, Yasuyuki Taneda (10-5 P) Selective Extraction and Simultaneous Determination of Gold and Zinc by First-Derivative Sectrophotometry KAMEL BELHAMEL, University of Bejaia, Mohamed Benamor (10-6 P) Performance Results From a New UV-VIS Spectrophotometer, Out Performing Old-Style Technology DONALD F HARRINGTON, Hach Company (10-7 P) Time Dependence of Elemental Species in the Early LIBS Plasma RICHARD M HOSKINS, University of South Carolina, Scott R Goode (10-8 P) Measurements of Biofilm on Central Venous Catheters for Hemodialysis with FTIR ATR JIMMY BAK, Ris Na, Tanja Begovic, Sren Ladefoged (10-9 P) Advances in Instrument Qualification Tools for FTIR and Raman Spectroscopy MIKE C GARRY, Thermo Electron Corporation, Jim Willis (10-10 P) A Systematic Investigation of Chemical and Physical Interferences in Flame Atomic Emission Spectroscopy: An Experiment for the Undergraduate Laboratory CHRISTOPHER DOCKERY, University of South Carolina, Michael S Angel, Scott R Goode, Michael J Blew (10-11 P) A New Fused Silica Capillary Column for the Determination of Individual Components in Spark Ignition Fuels Following ASTM Method D6730-01. BARRY L BURGER, Restek Corporation, Valerie S Gamble, Don Rhoads (10-12 P) Characterization Injection Using Elemental Analyzer LILIANA KROTZ, Thermo Electron Corporation, Luigi Ragaglia, Guido Giazzi, Richard Hancock (10-13 P) Cadaver Caveats: Factors Affecting Forensic Identification Using Stable Isotopes FRANK L BAUER, Colorado College, Y Yasutomo, Nathan W Bower, JM Hoffman (10-14 P) Infrared Heating Device Combined with the Portable Gas Detector Array GDA2 for Monitoring Surfaces ANDREAS WALTE, Airsense Analytics, Wolf Muenchmeyer (10-15 P) Optical Bio-sniffer for Methyl Mercaptan Vapor KOHJI MITSUBAYASHI, Tokyo Medical and Dental University, Takeshi Minamide, Hirokazu Saito (10-16 P) Wearable Oxygen Sensor for Conjunctiva Transcutaneous Measurement KOHJI MITSUBAYASHI, Tokyo Medical and Dental University (10-17 P) Novel Gas Sensor Array (Electronic Nose) with Better Selectivity by Cyclic Parameter Variation of Each Sensor ANDREAS WALTE, Airsense Analytics, Wolf Muenchmeyer (10-18 P) Controlled Synthesis and Characterization of MonolayerProtected Gold Nanoparticle/ Dendrimer Nanocomposites B. DAVIS GARABATO, Western Kentucky University, Erin C Cutler, Young-Seok Shon (10-19 P) Scanning Calorimeter for Material Characterization PETER J RALBOVSKY, TIAX LLC, Simon Chippett, Adam Brady-Myerov (10-20 P) ICP/MS Analysis with New SEC Column of Protein Combined with Metal and Selenoamino Acids Present in Organism in Trace Amount KUNIKO IGARASHI, Shodex, Showa Denko K.K., Masuhiro Komuro, Masaru Yasuda, Kazunori Iwata, Yasumitsu Ogra, Kazuo T Suzuki

39

(10-47 P) New Mechanical Analysis Capabilities to Measure and Understand Materials Response to Impact or Specific Excitation Form are Brought to Classical Dynamic Mechanical Analyzers HUGUES BAURIER, 01db-METRAVIB (10-48 P) Lightweight Whole Air Sampling Apparatus for Collecting VOCs for Personal Monitoring in Industrial Hygiene Applications DAVID M SHELOW, Restek Corporation (10-49 P) FT and Dispersive Raman Spectroscopy Applied to the Analysis of Incoming Raw Materials and Final Products in the Nutraceuticals Industry MIKE P FULLER, Digilab, Wayne Jalenak (10-50 P) Analysis of Molecular Weight Distribution of Liposome and Drugs KUNIKO IGARASHI, Shodex, Showa Denko K.K., Yoshiji Okada, Ryuji Takahashi, Kazunori Iwata, Kuniaki Shimbo, Yosuke Iwata, Yoshihiro Hayakawa, Keiko Yamabe, Mitsuhiro Nishida (10-51 P) Analysis of Tree Rings by Ion Chromatography for Chemical Evidence of Volcanic Activity WALTER J BOWYER, Hobart and William Smith Colleges, Yim L Cheng, Caitlin C Graber, Caitlin C Graber (10-52 P) Performance of ODS Column Synthesized by High Temperature Gaseous Phase Silylation for HPLC SAKAMAKI HIROSHI, Chemicals Evaluation and Research Institute, Tajima Haruhiko (10-53 P) Novel Polymer-Coated C18 Stationary Phase for Improved Peak Shapes of Basic Compounds under Neutral Conditions TAKETOSHI KANDA, Shiseido Company, Kazuko Takezawa, Atsushi Kobayashi, Xiaomi Xin, Hiroshi Kutsuna (10-54 P) A New HPLC Method for Reversed-Phase Separations with Multi-Solvent, Multi-Column Selectivity, and Multi-Wavelength Spectrophotometric UV/VIS Detection MICHEL LAU, San Francisco State University, Eugene M Fujinari (10-55 P) Evaluation of Separation of Acidic Compounds for the Hydrophilic Interaction Chromatography (HILIC) NORIKAZU NAGAE, Nomura Chemical Co., Ltd., Toshiyuki Enami, Naoki Fujita (10-56 P) Comparison of Supercritical Fluid Extraction with Soxhlet Extraction in the Analysis of DDT in Soils WAKANA MIYAKAWA, Western Carolina University, Roger Bacon (10-57 P) Ultrasonic Autosampler for Reduction of Carryover in HighSensitivity Analysis OSAMU SHIROTA, Shiseido Company, Xiaomi Xin, Masashi Mita (10-58 P) Fakes, Forgeries, and Fourees: Some Numismatic Oddities Useful for Teaching Analytical Chemistry from a Forensic Perspective NATHAN W BOWER, Colorado College, Michael Epstein, John Sieber (10-59 P) Ruhel Word Converter Attach in Scanner, for PhD Students, Scientists, Its More than OCR RUHEL CHISTY, 2nd Mine New Company (10-60 P) The Recent Progress of Analytical Chemistry in Baosteel YINGYING CHEN, Baoshan Iron & Steel Co., Ltd. (10-61 P) Investigation Laser Ablation Processes Breakdown Induced Aerosols: Analysis of Morphology and Chemical Composition VALERY BULATOV, Technion, Yuheng Chen, Israel Schechter (10-62 P) Developments in Purge-and-Trap Automation LAURA CHAMBERS, OI Analytical, Michael L Duffy (10-63 P) Comparison of Advanced Vibrational Spectroscopic Techniques for Analysis of Spatially Heterogeneous Samples ERIC Y JIANG, Thermo Electron Corporation, Koichi Nishikida, Forrest J Weesener, Simon Nunn (10-64 P) Automated Characterization, Purification and Fraction Analysis PAUL M LEFEBVRE, Waters Corporation, Ronan Cleary, Warren Potts (10-65 P) Olfactory and Quality Study of a Natural Raw Material (benzoin gum) with an Electronic Nose JEAN-CHRISTOPHE MIFSUD, Alpha M.O.S., Sophie Venzal , Fernandez Xavier, Claire Delbecque, Ccilia Castel (10-66 P) Exploring the Public Literature for Solutions to Challenges in Analytical Chemistry FREDRIC WINER, CAS (10-67 P) Pharmaceutical Analysis: Common Problems, Uncommon Solutions YURY ZELECHONOK, SIELC Technologies, Vlad Orlovsky (10-68 P) Separation of Peptides and Proteins by Mixed Mode Chromatography-Faster and More Efficient? YURY ZELECHONOK, SIELC Technologies, Vlad Orlovsky (10-69 P) The Use of Parallel HPLC to Speed Up Chiral Column Screening HOLGER GUMM, Sepiatec GmbH, Ariane Bredebusch (10-70 P) Assembly of Microscale Mass Spectrometers GARETH HUGHES, Zyvex Corporation (10-71 P) Withdrawn

(10-72 P) Nitrogen, Carbon and Sulfur Analysis in ppm Level in Soils, Rocks and Sand by Combustion Method LUIGI RAGAGLIA, Thermo Electron Corporation, Liliana Krotz, Guido Giazzi, Richard Hancock (10-73 P) Detection of Thin Films on Polycarbonate Substrates SUSAN L BERETS, Harrick Scientific Products Inc., Milan Milosevic, Joseph Lucania, Jeff D'Agostino (10-74 P) Advancement of Capillary Coatings for Protein Separations XUEYING HUANG, Sepax Technologies, Inc. (10-75 P) New Stationary Phases for Separations of Nanoparticles and Nanotubes XUEYING HUANG, Sepax Technologies, Inc. (10-76 P) Low Level Sulfur in Fuel Determination Using Monochromatic WD XRF-ASTM D7039-04 BERRY BEUMER, XOS/Horiba

NEW PRODUCT FORUM

Advances in Process Analytical Chemistry
Sunday Afternoon, Room S220A John P Auses, Alcoa Technical Center, Presiding

Session 2

2:15 (2-1) SLS Micro Technology Introduces Nanotechnology to Gas Chromatography BERNHARD GREVESMUEHL, SLS Micro Technology GmbH 2:35 (2-2) LaserTrace O2: A New Generation Trace Oxygen Sensor Empowered by Catalytic Transformation and Cavity Ring-Down Spectroscopy YU CHEN, Tiger Optics, LLC, Wen-Bin Yan 2:55 (2-3) A Portable MidIR Spectroscopy with No Moving Parts, No Air Path PAUL A WILKS, Wilks Enterprise, Inc., Sandra Rintoul 3:15 (2-4) MARAN Ultra QuikFat - Rapid Fat and Moisture Determination via Low Resolution NMR and OneshotMARAN Ultra QuikFat - Rapid Fat and Moisture Determination via Low Resolution NMR and Oneshot Method RICK COMTOIS, Austin AI, LLC 3:35 (2-5) Direct In-Tank Density and Temperature Measurement Without Sampling DEANNE M EMORY, Miller & Weber, Inc.

NEW PRODUCT FORUM

Analysis of Materials
Sunday Afternoon, Room S220B Denise Wilkins, Bechtel Bettis, Inc., Presiding 2:15 (4-1) Recent Developments in Scanning Probe Microscopy MICHAEL SERRY, Veeco Instruments

Session 4

2:35 (4-2) The High Heat of Experimentation JEFF D'AGOSTINO, Harrick Scientific Products Inc., Joe Lucania, Susan L Berets 2:55 (4-3) Spec Info for Analytical Chemists CAROL COFFEY, John Wiley & Sons, Inc, Ryan Patricia 3:15 (4-4) A New Confocal Raman Fiber Optic Probe Brings New Opportunities for Raman Sampling SOPHIE MOREL, Jobin Yvon Horiba, Koen Janssens, Christopher Hadjur, Bernard Roussel, Fran Adar 3:35 (4-5) V-7000- Advances in UV-VIS Applications AMANDA L JENKINS, Jasco, Inc.

NEW PRODUCT FORUM

New Techniques for Environmental Applications
Sunday Afternoon, Room S220B Roy Backer, The Pittsburgh Conference, Presiding

Session 3

12:00 (3-1) Ultra-low Background Alpha Particle Counter Using Pulse Shape Analysis WILLIAM K WARBURTON, X-ray Instrumentation Associates 12:20 (3-2) Self Cleaning Portable Volumetric Moisture Meter KWAME OKYNE, COSA Instrument Corporation 12:40 (3-3) The ICS-3000 is a Full Featured Ion Chromatography System that Features the Latest Advances in Reagent Free Ion Chromatography, Electrochemical Detection and System Throughput RICHARD F JACK, Dionex Corporation, Mike Kinderman

40

1:00 (3-4) JOB ELDERS, C2V

New Gas Chromartograph for Nerve Gas Detection

SYMPOSIUM
University Monday Morning, Room S230H David R Walt, Tufts University, Presiding 8:30 Introductory Remarks - David R Walt

Session 30

1:20 (3-5) Versa-LIMSVersa-LIMS DALE JOSEPH, Versatile Technologies Group, Steve Rudeseal

Detection of Terrorist Weapons - arranged by David R Walt, Tufts

NEW PRODUCT FORUM

Physical Measurements and Particle Characterization
Sunday Afternoon, Room S220A Grace Ann Bello, PPG Industries, Inc., Presiding

Session 1

8:35 (30-1) An Electronic Nose from Arrays of Nanoparticle Based Chemiresistive Vapor Sensors NATHAN S LEWIS, Caltech 9:10 (30-2) Porous Si Photonic Crystals as Sensors for Chemical Agents, Viruses, and Bacteria MICHAEL J SAILOR, University of California at San Diego 9:45 (30-3) Detection of Chemical and Biological Threats via Amplified Visible-Light Diffraction JOSEPH HUPP, Northwestern University 10:20 Recess 10:35 (30-4) Japanese Detection and Identification System for Chemical and Biological Warfare Agents after the Tokyo Sarin Attack YASUO SETO, National Research Institute of Police Science 11:10 (30-5) Detection of Biological Threat Agents with a Portable Array-Based Detection System DAVID R WALT, Tufts University

12:00 (1-1) In-Process Particle Measurement Under In-situ Conditions in Original Dispersed Phases up to Cv 70 Vol. % LARRY R UNGER, Particle Sizing Systems 12:20 (1-2) High-Resolution Singe-Particle Sizing of Sub-micron Distributions Using Focused Light Scattering and Extinction PATRICK O'HAGAN, Particle Sizing Systems, David Nicoli, Kerry Hasapidis, Heather Helsing, Greg Pokrajac 12:40 (1-3) New Palm Abbe Digital Handheld Refractometer: Laboratory Precision in the Palm of Your Hand! MICHAEL RAINER, MISCO 1:00 (1-4) Intelligent Automation in Raman Microscopy FRAN ADAR, Jobin Yvon Horiba, Emmanuel Froigneux, Hans Juergen Reich, Bernard Roussel, Adrian Knowles, Andrew Whitley 1:20 (1-5) Density Measurement Utilizing New Technology: Digital Density Meters (Digital Thermohydrometers) DEANNE M EMORY, Miller & Weber, Inc.

SYMPOSIUM

Session 40

Informatics for Mass Spectrometry Data Mining - arranged by Kasi

V Somayajula, University of Pittsburgh and John Yates, The Scripps Research Institute Monday Morning, Room S210B Kasi V Somayajula, University of Pittsburgh, Presiding 8:30 Introductory Remarks - Kasi V Somayajula

MONDAY, FEBRUARY 28, 2005

SYMPOSIUM
Session 20

8:35 (40-1) Linking Proteome to Genome Using Genome Fingerprint Scanning MORGAN GIDDINGS, University of North Carolina at Chapel Hill, Atul C. Shah, Michael Wisz, Jainab Khatun, Mark Holmes, Dongmei Yang, Kristen Dang 9:10 (40-2) Shotgun Annotation and the Informatics of Top Down Tandem Mass Spectrometry NEIL L KELLEHER, University of Illinois at Urbana 9:45 (40-3) Informatics for Large Scale Proteomics JOHN YATES, The Scripps Research Institute, Rovshan Sadygov, David Tabb, Daniel Cociorva 10:20 Recess 10:35 (40-4) A Proteome-Scale Examination of MASCOT and SEQUEST Search Algorithms STEVEN GYGI, Harvard Medical School 11:10 (40-5) Biomarker Discovery: Mining the Proteome by LCMS and Pattern Recognition ANDREW EMILI, University of Toronto

Chromatography Forum of Delaware Valley Dal Nogare Award arranged by Mary Ellen P McNally, E. I. DuPont de Nemurs and Company Monday Morning, Room S210A Mary Ellen P McNally, E. I. DuPont de Nemurs and Company, Presiding 8:30 Introductory Remarks - Mary Ellen P McNally

8:35 Chromatographic Accomplishments of Stephen Dal Nogare Robert L Grob, Villanova University 8:45 Presentation of the 2005 Stephen Dal Nogare Award to Daniel W. Armstrong, Iowa State University by Mary Ellen P McNally, E.I. duPont de Nemours and Company 8:50 (20-1) State University Separation Sciences DANIEL W ARMSTRONG, Iowa

SYMPOSIUM

Session 50

Molecular Portrait of a Characterized Neuron: Direct Single Cell Microanalysis from RNAs to Proteins - arranged by Leonid L Moroz,
University of Florida and Jonathan V. Sweedler, University of Illinois Monday Morning, Room S230C Leonid L Moroz, University of Florida, Presiding 8:30 Introductory Remarks - Leonid L Moroz

9:30 (20-2) Microemulsion-Based Organogels and Polymeric Cryogels: Brief Characterization and Some Chemical Analysis and Separation Science Applications WILLIE L HINZE, Wake Forest University, Melissa M Stouffer, Julianne M Braun 10:00 (20-3) Better Understanding Through Chemical Snapshots: What Near-Infrared Multispectral Imaging Tells Us about Spectrochemical Analysis and Separations CHIEU D TRAN, Marquette University, Victor Grishko, Daniel Oliveira 10:30 Recess 10:45 (20-4) Single DNA Molecules as Probes of Chromatographic Surfaces EDWARD S YEUNG, Iowa State University, Hung-Wing Li, Hye-Young Park, Marc D Porter 11:15 (20-5) Study of Retention Mechanisms in Chiral and Conventional Chromatography GEORGE GUIOCHON, University of Tennessee at Knoxville

8:35 (50-1) Observing the Travels of Single mRNA Molecules ROBERT H SINGER, Albert Einstein College of Medicine, Yaron Shav-Tal, Xavier Darzacq, Shailesh M Shenoy 9:10 (50-2) Molecular Analysis of Neuronal Subregions JAMES EBERWINE, University of Pennsylvania 9:45 (50-3) Genomic Memory-Forming Network LEONID L MOROZ, University of Florida 10:20 Recess 10:35 (50-4) Single Neuron Proteomics and Metabolomics JONATHAN V SWEEDLER, University of Illinois at Urbana 11:10 (50-5) Neurons NORMAN J DOVICHI, University of Washington, Md. Abul Fazal

41

SYMPOSIUM

Session 60

10:35 (80-4) Highly Miniaturized Mass Spectrometry J MICHAEL RAMSEY, University of North Carolina at Chapel Hill 11:10 (80-5) Portable Micro Plasma Devices (MPDs) and Micro Flame Devices (MFDs) for Optical and Mass Spectrometric Detection VASSILI KARANASSIOS, University of Waterloo

Multifunctional Electrode Materials for Bioelectroanalytical Applications - arranged by Keith J Stevenson, University of Texas at Austin
Monday Morning, Room S220G Keith J Stevenson, University of Texas at Austin, Presiding 8:30 Introductory Remarks - Keith J Stevenson

ORAL SESSION
Analysis and Characterization of Pharmaceuticals and Impurities
Monday Morning, Room S230D Brian Bidlingmeyer, Agilent Technologies, Presiding

Session 90

8:35 (60-1) Sensor Arrays for Toxicity Screening and Other Biomedical Applications JAMES F RUSLING, University of Connecticut 9:10 (60-2) Biocompatible Glucose, pH, and Oxygen Sensors Based on Sol-Gel Chemistry MARK H SCHOENFISCH, University of North Carolina at Chapel Hill, Stephanie M Marxer, Jae Ho Shin 9:45 (60-3) Steady-State Detection of Cholesterol Contained in the Plasma Membrane of Single Cells JAMES D BURGESS, Case Western Reserve University 10:20 Recess 10:35 (60-4) Employing Quaternary Ammonium Salts to Form Bio-Compatible Nafion Membranes for Use to Immobilize Enzymes at Bioanodes SHELLEY D MINTEER, Saint Louis University, Becky Treu, Nick Akers, Christine M Moore 11:10 (60-5) Preparation of Bioelectrode Assemblies for Localized Sensing Using Direct Write Multiphoton Photolithography KEITH J STEVENSON, University of Texas at Austin, Jennifer Lyon, Ryan Hill, Jason B Shear

8:30 (90-1) Validation of a Method for Determination of Total Organic Carbon in Protein Manufacturing Cleaning Samples MOHAMMAD S LATIFI, Eli Lilly and Company, Inc., Brooks A Sunday, Brian M McInerny, Adam P Rauk, Joseph B Nguyen, James W Jessee 8:50 (90-2) How to Achieve an Improved Protocol for Water for Injection (WFI) and Cleaning Validation Samples Using UV Persulfate Total Organic Carbon (TOC) Analysis BRIAN T WALLACE, Teledyne Instruments Tekmar 9:10 (90-3) Low Level Analysis of Pharmaceuticals and Excipients for OVIs and Residual Solvents Using Dynamic Headspace GC/FID MARK E KRIGBAUM, Teledyne Instruments - Tekmar, Tom Hartlein 9:30 (90-4) Detecting Polymorphs and Low Amounts of Amorphous Material with Fast Scan DSC SVENJA GOTH, PerkinElmer Life and Analytical Science 9:50 (90-5) Thermally Stimulated Current (TSC) for the Investigation of Polymorphism in Pharmaceutical Materials PIERRE M LE PARLOUER, Thermal Consulting, Christine Mayoux, Ignatius Chan 10:10 Recess 10:25 (90-6) A New Preparative Column that Bridges the Gap from Analytical to Preparative HPLC FANG XIA, Waters Corporation, Jie Y Cavanaugh, Yuehong Xu, John O'Gara, Uwe D Neue, Diane M Diehl 10:45 (90-7) Ultra-Fast, High Resolution Stability-Indicating Method Development Using 1.7 Ultra-Fast, High Resolution StabilityIndicating Method Development Using 1.7 m Particulate Columns ERIC S GRUMBACH, Waters Corporation, Diane M Diehl, Jeffrey R Mazzeo 11:05 (90-8) A Versatile Polar-Embedded Reversed-Phase Column and Its Pharmaceutical Applications XIAODONG LIU, Dionex Corporation, Andrei Bordunov, Chris Pohl, Mark Tracy, Rosanne W Slingsby, Nebojsa Avdalovic 11:25 (90-9) Characterization of Polar-Modified Reversed-Phase Columns with HPLC Methods HUQUN LIU, Varian, Inc., Chris Lee, Guang Qing Li, Dennis D Blevins 11:45 (90-10) HPLC and SFC for the Analysis of Chiral Pharmaceuticals AMANDA L JENKINS, Jasco, Inc., William Hedgepeth, Richard A Larsen

SYMPOSIUM
arranged by Daniel Raftery, Purdue University Monday Morning, Room S230B Daniel Raftery, Purdue University, Presiding 8:30 Introductory Remarks - Daniel Raftery

Session 70

New Applications in Analytical Nuclear Magnetic Resonance -

8:35 (70-1) Analysis and Control of Guest-Host Interactions in Self-Assembled Macromolecular Solutions BRADLEY F CHMELKA, University of California at Santa Barbara 9:10 (70-2) Analysis of Pharmaceuticals Using Solid-State NMR Spectroscopy ERIC J MUNSON, University of Kansas 9:45 (70-3) YAN, Pfizer, Inc. 10:20 NMR in Structure Based Drug Discovery JIANGLI Recess

10:35 (70-4) Application of Tailored Stationary Phases in LC-MS and LC-NMR Analysis of Bioactive Compounds ALBERT KLAUS , Universitaet Tuebingen Institut fuer Organische Ch, Marc David Grynbaum, Petra Hentschel, Christoph Meyer, Karsten Putzbach, Siri Schauff, Karin Woellner 11:10 (70-5) Analysis of Combinatorial Libraries and Complex Mixtures Using Microcoil NMR Spectroscopy and Multivariate Statistics DANIEL RAFTERY, Purdue University, Nick Pan, Shuhui Liu, Peter Sandusky

ORAL SESSION
Atomic Spectroscopy: ICP Methods
Monday Morning, Room S220B I-Pin Ho, National Food Processors Association, Presiding

Session 100

SYMPOSIUM

Session 80

Paradigm Shift in Classical Chemical Analysis: Taking the Lab to the Sample - arranged by Vassili Karanassios, University of Waterloo
Monday Morning, Room S230F Vassili Karanassios, University of Waterloo, Presiding 8:30 Introductory Remarks - Vassili Karanassios

8:30 (100-1) Redesigning the Chamber of In-torch Vaporization (ITV) Sample Introduction for Inductively Coupled Plasma (ICP) Spectrometry Using Computational Fluid Dynamics (CFD) HAMID BADIEI, University of Waterloo, Vassili Karanassios, Gordon Stubley 8:50 (100-2) A Dual Source Inductively Coupled Plasma/ Electrospray Ionization Time-of-Flight Mass Spectrometer for Rapid Speciation and Metallomic Analysis DUANE A ROGERS, Indiana University, Steven J Ray, Gary M Hieftje 9:10 (100-3) Interference Removal in Cell Based ICP-MS: A Review of Current Theory and Practice PHIL N SHAW, Thermo Electron Corporation, Jonathan Batey, Philip Marriott, Simon M Nelms, Martin Nash, Bill Spence 9:30 (100-4) Study of the Temporal Evolution of Dual-Pulse Laser Induced Breakdown Spectroscopy (LIBS) Emissions CLEON M BARNETT, Florida A&M University

8:35 (80-1) Complementary Metal Oxide Semiconductor (CMOS)Based Chemical Sensors ANDREAS HIERLEMANN, ETH Zurich 9:10 (80-2) Integrating Microplasmas into Microanalytical Systems JEFFREY A HOPWOOD, Northeastern University 9:45 (80-3) The Impact of New Technologies on the Next Generation of Portable Spectroscopic Instrumentation M. BONNER DENTON, University of Arizona 10:20 Recess

42

9:50 (100-5) New Quantification Strategy Using Inductively Coupled Plasma Mass Spectrometry and the Method of Standard Additions STEVEN J CHRISTOPHER, National Institute of Standards and Technology, Colleen E Bryan, Russell D Day 10:10 Recess 10:25 (100-6) FACT Spectral Deconvolution: The Solution for Complex Spectral Overlaps in ICP-OES Applications MICHELLE E CREE, Varian, Inc., Christine M Rivera, Doug Shrader 10:45 (100-7) Source Optimisation for ICP-OES PAUL J NEAL, Thermo Electron Corporation, Adrian Holley 11:05 (100-8) Laser Ablation ICP-OES for Bulk Analysis of Steels and Refractory Geological Samples GEOFF TYLER, Jobin Yvon SAS, Isaac Brenner, Damon Green, Lawrence M Neufeld 11:25 (100-9) Routine Metals Speciation in Biomedical and Environmental Samples Using ICP-MS MARTIN NASH, Thermo Electron Corporation, Phil N Shaw 11:45 (100-10) Reduction or Elimination of Some Spectroscopic and Non-spectroscopic Interference Effects in ICP-MS Using In-torch Vaporization (ITV) for "Dry" Sample Introduction HAMID BADIEI, University of Waterloo, Vassili Karanassios

ORAL SESSION
Capillary Electrophoresis: UV/Fluorescence Detection
Monday Morning, Room S210E Elizabeth Harris, Mannkind Corporation, Inc., Presiding

Session 120

8:30 (120-1) Affinity Capillary Electrophoresis of Signal Transduction Proteins and Native Ligands with Laser-Induced Fluorescence Anisotropy Detection REBECCA J WHELAN, University of Michigan, Roger K Sunahara, Richard R Neubig, Robert T Kennedy 8:50 (120-2) Flow-Gated Interface for Hadamard Transform Capillary Electrophoresis with UV Detection LEYI GAO, University of Illinois at Chicago, Eric E Patterson, Scott A Shippy 9:10 (120-3) Separation of Redox Cofactors Flavin Adenine Dinucleotide and Reduced Nicotinamide Adenine Dinucleotide by Capillary Zone Electrophoresis with Laser Induced Fluorescence Detection PIYANKA G DE SILVA, University of Iowa, M Lei Geng, Semeena Ahmed 9:30 (120-4) Investigation of the Inner Mitochondrial Membrane Potential in Individual Organelles by Capillary Electrophoresis with Laser Induced Fluorescence Detection BOBBY G POE, University of Minnesota, Marian Navratil, Edgar A Arriaga 9:50 (120-5) Localization and Conversion of D-Aspartate in Aplysia Californica Neurons CORY SCANLAN, University of Illinois at Urbana, Jonathan V Sweedler, Hai Miao, Stanislav S Rubakhin 10:10 Recess 10:25 (120-6) Size Separation of Fluorescently Labeled Silica Nanoparticles in Capillary Zone Electrophoresis LU XI, University of Iowa, M Lei Geng 10:45 (120-7) SH2 Domain Protein Binding Studies by Affinity Capillary Electrophoresis with Laser-Induced Fluorescence Anisotropy Detection PEILIN YANG, University of Michigan, Rebecca J Whelan, Christin Carter-Su, Robert T Kennedy 11:05 (120-8) On-line Coupling of Solid Phase Microextraction and Capillary Isoelectric Focusing with Laser-Induced Fluorescence Whole Column Imaging Detection for Protein Analysis ZHEN LIU, University of Waterloo, Janusz B Pawliszyn 11:25 (120-9) Capillary Isoelectric Focusing with Liquid-core Waveguide Laser-induced Fluorescence Whole Column Imaging Detection for the Analysis of Proteins, Antibodies, Viruses and Cells ZHEN LIU, University of Waterloo, Janusz B Pawliszyn 11:45 (120-10) Highly Sensitive Protein Detection by SDS-Capillary Gel Electrophoresis Using a Lanthanide Fluorescence Dye KAZUKO MATSUMOTO, Waseda University, Yoshinori Yamaguchi, Takuya Nishioka, Kimikazu Hashino

ORAL SESSION

Session 110

Bioanalytical Sensors: Developments and Applications I

Monday Morning, Room S230G Peter Castle, Idaho National Engineering and Environmental Laboratory, Presiding 8:30 (110-1) High Throughput Oxygen Sensor for Monitoring Bacterial Pathogens JASON E KARASINSKI, State University of New York at Binghamton, Silvana Andreescu, Omowunmi A Sadik 8:50 (110-2) Multilayer Modified Cantilevers for Biosensors HAIFENG JI, Louisiana Tech University 9:10 (110-3) Development of a Quantitative Competitive NASBA Assay for the Detection of Escherichia coli WAN-YU LO, Cornell University, Antje J Baeumner 9:30 (110-4) A Quartz Crystal Microbalance Immunosensor for Detection of Salmonella Typhimurium Based on Simultaneous Measurements of Resonant Frequency and Resistance XIAO-LI SU, University of Arkansas, Yanbin Li 9:50 (110-5) Multiplexed Analysis of Viral Agents Using Nanoparticles JOSHUA E SMITH, University of Florida, Timothy J Drake, Kevin Turney, Weihong Tan 10:10 Recess 10:25 (110-6) An Ultrasensitive Fiber Optic Biosensor with Newly Designed Molecular Beacons for DNA Detection SHELLY J MECHERY, University of Florida, Chaoyong Yang, Weihong Tan 10:45 (110-7) Non-Resonant Multi-Photon Photoacoustic Spectroscopy for Subsurface Tumor Diagnostics NIRMALA CHANDRASEKHARAN, University of Maryland, Baltimore County, John B Kiser, Brian M Cullum 11:05 (110-8) Real-Time Detection of Nitric Oxide (NO) Released from Cells Using Microphysiometer Type Arrangement with Cells Adhered to Surface of Electrochemical NO Sensor WANSIK CHA, University of Michigan, Anjali Desai, Jeffrey S Warren, Mark E Meyerhoff 11:25 (110-9) Giant Magnetoresistive Sensors for Chip-Scale Detection of Multiple Biorecognition Events Using Surface Modification and Magnetic Labels RACHEL L MILLEN, Iowa State University, John Nordling, Heather A Bullen, Nikola Pekas, Toshikazu Kawaguchi, Mark Tondra, Marc D Porter 11:45 (110-10) Single Molecular Multi Analytes Sensors and Applications to Bioimaging HIROKAZU KOMATSU, Keio University, Takahiro Miki, Yukio Fujiwara, Daniel Citterio, Takeshi Kubuta, Yutaka Shindo, Yoshiichiro Kitamura, Masafumi Hagiwara, Kotaro Oka, Koji Suzuki

ORAL SESSION

Session 130

Food Science: GC/LC/LC-MS/Sample Preparation/Data Analysis and Manipulation

Monday Morning, Room S220C Fu-mei C Lin, Presiding 8:30 (130-1) Determination of Oxygenates and BTX in Beverage Grade CO2 JOHN N DRISCOLL, PId Analyzers, LLC 8:50 (130-2) FAME Analysis Using High Speed GC LEONARD M SIDISKY, Supelco, Inc., Katherine L Stenerson 9:10 (130-3) A Rapid Ion Chromatographic Determination of Phosphate and Citrate in Carbonated Beverages BRIAN DE BORBA, Dionex Corporation, Chris Pohl, Charanjit Saini, Brian Thompson, Jeffrey S Rohrer 9:30 (130-4) Fat: Getting a Handle BRIAN ROHRBACK, Infometrix, Inc., Scott Ramos, Fred Lewis 9:50 (130-5) HPLC Preparative Scaleup of Phospholipids RONALD E MAJORS, Agilent Technologies, Inc., Cliff Woodward, Bernard Permar 10:10 Recess 10:25 (130-6) Analysis of Ginkgolides and Bilobalide in Functional Food Products Using LC-APCI-MS LOWRI S DE JAGER, FDA, Gracia S Perfetti, Gregory W Diachenko

43

10:45 (130-7) Determination of Nutrients in Germinating and Fermented Soybeans with Mass Spectrometry Techniques HONGLAN SHI, University of Missouri-Rolla, Paul K Nam, Shubhen Kapila, Naga Mallika Surapaneni, Feng Liu, Keesoo Lee, Virgil Flanigan, Yinfa Ma 11:05 (130-8) Rapid Sample Preparation Method for Analysis of Acrylamide in Various Food Matrices KATERINA MASTOVSKA, USDA, Steven J Lehotay 11:25 (130-9) Determination of Low Molecular Mass Aldehyde by Automated Headspace Solid-Phase Microextraction with In-Fibre Derivatization QING WANG, University of Waterloo 11:45 (130-10) Determination of Sucralose Using Anion-Exchange Chromatography and Pulsed Amperometric Detection VALORAN P HANKO, Dionex Corporation, Jeffrey S Rohrer

11:25 (150-9) Peptide Electrophoresis by Two-Beam Fluorescence Cross Correlation Spectroscopy PAUL C BRISTER, Florida State University, Ying Xiao, Kenneth D Weston 11:45 (150-10) A Novel Approach to High Efficiency Multidimensional Electrophoresis of SDS-Denatured, Dye-labeled Proteins in a Disposable Poly(methyl methacrylate)-Based Microdevice HAMED SHADPOUR, Louisiana State University, Steven A Soper

ORAL SESSION

Session 160

Liquid Chromatography: Ion Chromatography and Column Technology

Monday Morning, Room S220D Alan Broske, Agilent Technologies, Presiding

ORAL SESSION
GC-MS of Polymers
Monday Morning, Room S210D James Berry, Berry Environmental, Presiding

Session 140

8:30 (160-1) A Portable Post Column Ion Chromatography Based Analyzer for Monitoring Haloacetic Acid Concentrations in Drinking Water GREG T ANDERSON, The University of Memphis, Paul S Simone, Gija Geme, Gary L Emmert 8:50 (160-2) Neomycin Determination Using Anion-Exchange Chromatography and Pulsed Amperometric Detection VALORAN P HANKO, Dionex Corporation, Jeffrey S Rohrer 9:10 (160-3) Capillary Ion Chromatography with On-line Electrolytic Eluent Generation and Suppressed Conductivity Detection YAN LIU, Dionex Corporation, Victor Barreto, Chris Pohl, Nebojsa Avdalovic 9:30 (160-4) Fast Ion Chromatography Using Short Columns CHARLES A LUCY, University of Alberta, Sarah Pelletier 9:50 (160-5) Reagent-Free Ion Chromatography with On-line Electrolytic Generation of Carbonate and Biocarbonate Eluents ZHONGQING LU, Dionex Corporation, Yan Liu, Chris Pohl, Nebojsa Avdalovic 10:10 Recess 10:25 (160-6) Suppressed Ion Chromatography Using a 1 MM Micro Column Format CHRIS POHL, Dionex Corporation, Kannan Srinivasan, Rong Lin, Sheetal Saini, Nebojsa Avdalovic 10:45 (160-7) Cation-Exchange Chromatography Employing Sulfonated Capillary-Channeled Polypropylene Fibers as Stationary Phase CHRISTINE STRAUT, Clemson University, Dwella M Nelson, S W Shalaby, Joel Corbett, R Kenneth Marcus 11:05 (160-8) Monolithic Carbon as a Novel Stationary Phase for Electrochemically Modulated Liquid Chromatography BETSY JEAN YAKES, Iowa State University, David W Keller, Lisa M Ponton, Chengdu Liang, Sheng Dai, George Guiochon, Marc D Porter 11:25 (160-9) Capillary-Channeled Polymeric Fibers as Stationary Phase in High Performance Liquid Chromatography Columns: Optimization of Fiber Packing Density RAYMAN D STANELLE, Clemson University, R Kenneth Marcus 11:45 (160-10) Advances in Monolithic Fiber Column Liquid Chromatography Technology JOSEPH B PAYNE, Filtrona Fibertec, Bennett C Ward, Jack C Ramsay

8:30 (140-1) Direct Solids Analysis by GC-MS Combined with a Thermal Sample Introduction System TERRY L RAMUS, Diablo Analytical, Inc., Chuichi Watanabe, Akihiko Hosaka 8:50 (140-2) Oxidative Pyrolysis-GC/MS of Combustible Materials THOMAS P WAMPLER, CDS Analytical, Inc., Leticia A Mancini, Charles P Zawodny 9:10 (140-3) Quantitative Analysis of Polymers in Cosmetics Using Pyrolysis GC/MS CHARLES P ZAWODNY, CDS Analytical, Inc., Thomas P Wampler, Leticia A Mancini 9:30 (140-4) Advances in Thermal Desorption with GC-MS for Enhanced Analysis of Volatiles and Semi-Volatiles in Plastics and Materials Emissions ELIZABETH WOOLFENDEN, Markes International Ltd 9:50 (140-5) Characterization of Polymers and Plastics by Pyrolysis-GC/MS INGER ERICSSON, Pyrol AB

ORAL SESSION
Lab-on-a-Chip I
Monday Morning, Room S220E Brian C Walsh, Bechel-Bettis, Presiding

Session 150

8:30 (150-1) Integration of an Immobilized PC 12 Cell Reactor with a Microchip-Based Flow Analysis System MICHELLE W LI, Saint Louis University, R. Scott Martin 8:50 (150-2) A Microfluidic Chip Coupled to Microdialysis for in vivo Monitoring of Primary Amine Neurotransmitters by Capillary Electrophoresis ZECHARIAH D SANDLIN, University of Michigan, Jonathan G Shackman, Robert T Kennedy 9:10 (150-3) Microchip-Based Resistance Vessel Mimics for the Detection of Deformation-Induced ATP from Erythrocytes ALEXANDER K PRICE, Saint Louis University, Dana M Spence, R. Scott Martin 9:30 (150-4) Design of Interfacial Selectivity of DNA Probes for Development of Quantitative Electrokinetic Biochips ULRICH J KRULL, University of Toronto, Xuezhu Liu, April Wong, Ying Lim, Paul Piunno, David Ercikson, Dongqing Li 9:50 (150-5) Highly Multiplexed DNA Sequencing from PMMA (Polymethylmethacrylate) Micro-devices Using Dual-Color Time-Resolved Near-IR Fluorescence LI (JULIE) ZHU, Louisiana State University, Steven A Soper 10:10 Recess 10:25 (150-6) Determination of Lead Based on Catalytic DNA in a Capillary Electrophoresis Microchip DONALD M CROPEK, US Army Engineer Research and Development Center, In-Hyoung Chang, Paul W Bohn, Jonathan V Sweedler, Yi Lu 10:45 (150-7) Metal-Polymer Nanocomposites for Integrated Microfluidic Separations and Surface Enhanced Raman Spectroscopic Detection R. MAGGIE CONNATSER, University of Tennessee at Knoxville, Michael J Sepaniak 11:05 (150-8) Electrokinetic Migration for the Concentration of Analytes and Labels in Immunoassays JILL UHLENKAMP, Iowa State University, Hye-Young Park, Jeremy D Driskell, Betsy Jean Yakes, Robert J Lipert, Marc D Porter

ORAL SESSION
Nanotechnology: New and Improved Techniques
Monday Morning, Room S220F Stephen Creager, Clemson University, Presiding

Session 170

8:30 (170-1) Recycling Size Exclusion Chromatography for the Analysis and Separation of Nanocrystalline Gold ALI M AL-SOMALI, Rice University 8:50 (170-2) Surfactant-Assisted Growth of Nanocrystalline Oxides: The Role of the Surface State CLAUDIA L BIANCHI, University of Milan, Giuseppe Cappelletti, Silvia Ardizzone 9:10 (170-3) Fabrication of Highly Ordered Poly(methyl methacrylate) Nanostructures with Anodic Alumina as Template GUOFANG CHEN, Louisiana State University, Steven A Soper, Robin L McCarley 9:30 (170-4) Flexible Nanotube-Based Fast Electrochromics SEUNG IL CHO, University of Maryland at College Park, Sang Bok Lee, SangHo Kim

44

9:50 (170-5) Spectroscopic and Mechanical Analysis of Syndiotactic Polypropylene and High Density Polyethylene Clay Nanocomposites VASILIS GREGORIOU, FORTH-ICEHT, Spyros Tzavalas, Stavos Bollas 10:10 Recess 10:25 (170-6) Real-Time Probing of Membrane Transport in Living Microbial Cells Using Single Nanoparticle Optics and Living Cell Imaging X, NANCY XU, Old Dominion University 10:45 (170-7) Coupled Raman Spectroscopic and Electrical Measurement of Diisocyanide Monolayers Sandwiched between Two Gold Electrodes ARCHANA JAISWAL, Miami University, Kusha G Tavakoli, Shouzhong Zou 11:05 (170-8) Raman Spectroscopy as a Quick Analytical Technique for Indicating Carbon Nanotube Growth on SiC JONATHAN M REYNOLDS, Fisk University, Weijie Lu , Warren E Collins, William C Mitchel 11:25 (170-9) Luminescent Bioconjugated Nanoparticles for Highly Sensitive Microarray Detection LIN WANG, University of Florida, Charles Lofton, Weihong Tan 11:45 (170-10) Formation of Bifurcating Surfactant Nanotube Networks and Knotted Structures that Work as Mechanical Tweezers TATSIANA LOBOVKINA, Chalmers University of Technology, Paul G Dommersnes, Jean-Francois Joanny, Patricia Bassereau, Mattias Karlsson, Owe Orwar

ORAL SESSION

Session 190

Surface Analysis and Microscopic Imaging Techniques: Materials Characterization

Monday Morning, Room S230E Richard Bormett, Renishaw, Inc., Presiding 8:30 (190-1) Layer-by-Layer Deposition of Silane-Based Copolymers ARUNA VELAMAKANNI, University of Rhode Island, Jaycoda S Major 8:50 (190-2) Characterization of Surfaces and Thin Films on Glasses by Radio Frequency Glow Discharge Optical Emission Spectrometry PATRICK CHAPON, Jobin Yvon SAS, Philippe Belenguer, Reha Ozalp 9:10 (190-3) Characterization of Hafnium Oxide Films on Silicon Using Photoelectron Spectroscopy HYLTON G MCWHINNEY, Prairie View A&M University, John F Conley, Thomas N Fogarty, Len Trombetta, Richard Wilkins, Monica Bibbs, Tony L Grady 9:30 (190-4) Infrared Imaging: From Pretty Pictures to Hard Information KOICHI NISHIKIDA, Thermo Electron Corporation, N S Nunn, William J McCarthy, Jonathan Tarr, Renee C Nesnidal 9:50 (190-5) Novel Interleaved Data Collection Method for Improved Chemical Imaging JOSEPH W SCHOPPELREI, Spectral Dimensions, Inc., Haber Ken, Eunah Lee, E. Neil Lewis 10:10 Recess 10:25 (190-6) Optical and Infrared Analysis of Forensic Evidence THOMAS J TAGUE, Bruker Optics, Inc. 10:45 (190-7) Application of Headspace Instrumentation for Sorption Studies and Characterization of Condensed Matrices MICHAEL MARKELOV, ACS Labs, Olga Bershevits 11:05 (190-8) Optimization of Experimental Constraints when Coupling Automated Polarized Light Microscopy with Raman Microscopy CARRIE A LENDON, Cargill Scientific Resources, Sean A Smith, John T McDonald, Douglas L Elmore, Chad L Leverette 11:25 (190-9) Extending Multicolor Fluorescence Microscopy with Hyperspectral Imaging JERILYN A TIMLIN, Sandia National Laboratories, Michael B Sinclair, David M Haaland 11:45 (190-10) Understanding and Correcting for the Effects of Instrumental Artifacts in Fluorescence Hyperspectral Images HOWLAND JONES, Sandia National Laboratories, Jerilyn A Timlin, David M Haaland

ORAL SESSION
Process Analytical Chemistry
Monday Morning, Room S210C John P Coates, Coates Consulting, Presiding

Session 180

8:30 (180-1) Ethernet Controlled Vision Based Particle Analyzers BRUNO C ALBANO, Canty Inc. 8:50 (180-2) An Automated and Simple Method for the Determination of Sulfur Compounds in Beverage Grade Carbon Dioxide ROBERT M HILLARD, GOW-MAC Instrument Company, Robert J Mathieu, Peter S Mathieu 9:10 (180-3) Streaming Gas Process Data to the Outside World: Applications of OPC (OLE for Process Control ) to FTIR Gas Analysis JAY P ROBERTS, Thermo Electron Corporation 9:30 (180-4) Advances in Surface Passivation Techniques Used for the Analysis of Sulfur Species in the Petrochemical and Refining Industries GARY A BARONE, Restek Corporation 9:50 (180-5) Continuous On-Site Monitoring of the Fermentation of Beer by Ion Mobility Spectrometry JOERG INGO BAUMBACH, ISAS Institute for Analytical Sciences, Wolfgang Vautz, Joachim Jung 10:10 Recess 10:25 (180-6) On-line Chemical Component Characterization and Concentration Measurement for Process Control Using Raman Spectroscopy HONGQI YUAN, Alberta Research Council, Theodore M Garver, George Sedgwick 10:45 (180-7) An EQCM Study on the Quantitative Determination of Palladium(II) Ions Using Carbon-Coated Quartz Crystals NATHAN A CARRINGTON, The University of Tennessee, David L Rodman, Ziling Xue 11:05 (180-8) Ultra Low Flow Reference Electrode Using Nanochannel Glass Array Junction TA-YUNG CHEN, Broadley-James Corporation, Frank Gao, Scott Broadley, Pamela Payne, Herbert Silverman 11:25 (180-9) Autarky Gas Chromatographic System Realized in MEMS Technology on a Credit Card-Sized Board UWE LEHMANN, SLS Micro Technology GmbH, Bernhard Grevesmuehl, Arne Koeninger, Andreas Behrends, Tobias Schmidt 11:45 (180-10) Determination of Boron in Protective Powder by ICP LI ZHU, Baoshan Iron & Steel Co., Ltd.

ORAL SESSION
Vibrational Spectroscopy: Monitoring of Materials and Processes I
Monday Morning, Room S230A Iona Black, Yale University, Presiding

Session 200

8:30 (200-1) Inspecting Metals for Contamination and Corrosion Using FTIR Reflectance Spectroscopy GEORGE L POWELL, Y-12 National Security Complex, Richard L Cox, Martin M Szczesniak, Michael Beecroft, Phillip Mattison 8:50 (200-2) Surface-Enhanced Raman Scattering of Ultrathin Cadmium SulfiIionic Layer Adsorption and Reaction (SILAR ) Technique LILI BAO, Oak Ridge National Laboratory, Shannon Mahurin, Sheng Dai 9:10 (200-3) Micro-lapping Depth Profile Analysis of Multilayer Polymer Films Using FTIR-Photoacoustic Spectroscopy and FTIR-ATR ANTHONY J WAGNER, Ames Lab, John McClelland 9:30 (200-4) Characterization of Organic Hydrogen Getters by Hydrogen Gas Titration, FT-MS, Dynamic MS, and UHV FTIR Gas Analysis NORMAN R SMYRL, Y-12 National Security Complex, Quirinus G Grindstaff, Kenneth D Nicklas, Dean Davis, George L Powell 9:50 (200-5) Monitoring of Sulfuric Acid Decomposition by Fourier Transform Infrared (FT-IR) Spectroscopy in the Sulfur Iodine Thermochemical Reaction for the Production of Hydrogen DION RIVERA, Sandia National Laboratories 10:10 Recess 10:25 (200-6) FTIR Validation Using EPA Method 301 and 320 for HCl and HF at a Municipal Solid Waste Incinerator PETER G ZEMEK, MIDAC

45

10:45 (200-7) An Integrated FTIR Micro Plate Reader for Analyzing Samples in 96 Well Plates STEPHEN R LOWRY, Thermo Electron Corporation, Sean Debnath, Dave Dalrymple 11:05 (200-8) Near-Field Raman Spectroscopy Using Optical Fiber and Silicon Cantilever DMITRY S BULGAREVICH, National Institute of Advanced Industrial Science and Technology (AIST), Masayuki Futamata 11:25 (200-9) A Unified Spectroscopic Methodology for the Determination of Isocyanate and Hydroxyl Number in the Polyurethane Industry MICHAEL KESTER, ABB, Inc., Paul Chabot, Marc Trygstad, Mike Simpson 11:45 (200-10) Scanning for Extinct Astrobiological Residues and Current Habitats (SEARCH) Using Integrated Computational Imaging ROBERT A LODDER, University of Kentucky, Clay Harris

(210-3 P) Newly Developed Double Capillary Column System for GC/MS HARUHIKO MIYAGAWA, Shimadzu Corporation, Hiroko Okuda, Manabu Shimomura, Keisuke Matsuda, Koki Tanaka, Charles R Lyle (210-4 P) New Performance Electronics Design for Faster Scanning GC/MSD MICHAEL SZELEWSKI, Agilent Technologies, Inc., Chinkai Meng, Philip L Wylie (210-5 P) Method for Delineation of Contaminated Areas Using Headspace-Gas Chromatography: A Case Study CANDACE M ROSE, Argonne National Laboratory, Jorge S Alvarado, Lorraine LaFreniere (210-6 P) New Carbopack X Adsorbent for 24-Hour Diffusive Sampling WILLIAM R BETZ, Supelco, Inc., Jamie L Brown, Leonard M Sidisky (210-7 P) Evaluation of a Variety of GC Stationary Phases for the Analysis of Volatile Organics by US EPA Method 8260 CHRISTOPHER M ENGLISH, Restek Corporation, Frank L Dorman, Gary B Stidsen (210-8 P) Application of a Recently Designed Robotic Liquid Autosampler, for the Analysis of Traces of Contaminants in Water by LVIGC-MS FAUSTO MUNARI, Thermo Electron Corporation, Stefano Pelagatti, Fausto Pigozzo (210-9 P) Low Background DNPH Glass Tubes for Trace Level Sampling of Carbonyl Compounds JAMIE DESORCIE, Supelco, Inc., Sterley B Cole, Toshiro Kaneko, William F Beaton, Leonard M Sidisky (210-10 P) New Portable SPME Passive Air Monitoring and Field Sampling Device ROBERT E SHIREY, Supelco, Inc., Leonard M Sidisky (210-11 P) A Tool for Selecting an Adsorbent for Thermal Desorption Applications JAMIE L BROWN, Supelco, Inc., William R Betz, Leonard M Sidisky, Mark V Robillard (210-12 P) Prevent Damage to Your Purge and Trap System by Prescreening with Static Headspace MARK E KRIGBAUM, Teledyne Instruments - Tekmar, Brian T Wallace (210-13 P) Determination of Oxyhalides with New Anion-Analysis Columns HIDEYUKI KONDO, Shodex, Showa Denko K.K., Hisashi Fujiki, Kuniaki Shimbo, Kuniko Igarashi (210-14 P) Recognition of Ceramic Glass Contaminants in Recycling Glass by FTIR Spectroscopy GIUSEPPE BONIFAZI, Universit di Roma La Sapienza, Silvia Serranti, Vincenzo Giancontieri (210-15 P) Polychlorinated Biphenyls in Argentina MARIANO GOTELLI, Center for Toxicological Research, Carlos Gotelli, Alfredo Lo Balbo, Luciano Signorini, Adrian Lopez

NEW PRODUCT FORUM

Advances in Technology for Biomedical Sciences
Monday Morning, Room S220A Robert W Baudaux, RWB Convention Mgt., Presiding

Session 201

8:30 (201-1) New Advancements in Protein Separation HY LIU, Sepax Technologies, Inc. 8:50 (201-2) Characteristics of the New Kromasil-Diol: Properties, Applications and Scale-Up KRISTINA HALLMAN, Eka Chemicals, Borje Persson, Mattias Bergqvist 9:10 (201-3) New Innovations in Miniature Diaphragm Isolation Valves KEN BURTT, Precision Dynamics, Inc., Steve Allen 9:30 (201-4) 3500 V Programmable Power Supply for Microfluidics Application EDWARD CHANG, Major Science Co., LTD 9:50 (201-5) Evaluation and Implementation of Charged Aerosol Detection (CAD) for HPLC DARWIN J ASA, ESA Inc.

NEW PRODUCT FORUM

Advances in Technology for Pharmaceutical Analyses
Monday Morning, Room S220A David S Cifrulak, The Pittsburgh Conference, Presiding

Session 202

10:25 (202-1) strata-X-CW Revolutionary SPE Sorbent for Simplified Cleanup and Sensitivity MICHAEL GARRIQUES, Phenomenex, Inc., Krishna Kallury, Shahana Huq 10:45 (202-2) CALLI 2002: New Automated Weighing and Liquid Handling System JIM SCHOOLS, Zinsser Analytic, Clifford A Olson 11:05 (202-3) CHIRALPAK IB: A New Immobilized Polysaccharide Chiral Stationary Phase RODGER W STRINGHAM, Chiral Technologies, Inc., Clint Amoss, Barbara Lord 11:25 (202-4) GeminiGemini C18: A New HPLC Column Technology that Delivers pH 1-12 Stability and High Performance MICHAEL D MCGINLEY, Phenomenex, Inc., Tivadar Farkas, Emmet Welch, Ismail Rustamov 11:45 (202-5) pH-Free Chromatography: Why You Dont Have to Adjust pH of the Mobile Phase YURY ZELECHONOK, Hichrom Ltd, Vlad Orlovsky, Tatiana Kochman

POSTER SESSION
Environmental: Analysis of Air and Water
Monday Morning

Session 220

(220-1 P) Determination of 14 Polycyclic Aromatic Hydrocarbons in Mainstream Smoke from U.S. Brand and Non-U.S. Brand Cigarettes YAN S DING, Centers for Disease Control and Prevention, Xizheng Yan, David Ashley, Clifford Watson, Gregory Polzin (220-2 P) Determination of Ions in Atmospheric Aerosols during the Lake Breeze in Chicago TINAMARIE FOSCO, Loyola University Chicago, Martina Schmeling (220-3 P) Direct Measurement of House Dust Mite Allergen AKI HONDA, Keio University, Koji Suzuki (220-4 P) Real Time Background Mercury Monitoring in Air Using Portable Zeeman Atomic Absorption Spectrometer NIKOLAY R MASHYANOV, Lumex Ltd., Joseph Siperstein, Vladimir V Ryzhov, Serguei E Sholupov, Akira Yasutake (220-5 P) Practical Guidelines for Cleaning Ambient Air Canisters DAVID M SHELOW, Restek Corporation (220-6 P) Objective Odor Measurement with Electronic Nose Module for Environmental Applications LOUIS VIVOLA, ALPHA M.O.S., Eric Chanie (220-7 P) A Portable GC for Indoor VOC Determinations QIONGYAN ZHONG, University of Michigan, Chunguang Jin, Edward T Zellers (220-8 P) Determination of Benalkomium Chlorides in Waters by Capillary Electrophoresis Coupled with Solid-Phase Extraction and Salting-Out Effect HSUEH-YING LIU, National Central University, Wang-Hsien Ding (220-9 P) Perchlorate in Drinking Water and Foods by LC/MS-MS MICHAEL SHELTON, West Coast Analytical Service (220-10 P) Determination of Fluorescent Whitening Agents in Household Detergents by Liquid Chromatography/Tandem Mass Spectrometry HSINCHANG CHEN, National Central University, Wang-Hsien Ding

POSTER SESSION

Session 210

Morning posters will be on display from 9:30 AM to 12:30 PM with authors present from 9:30 AM to 11:30 AM. The posters will be located on the Southeast corner of the Exposition floor (beginning Aisle 2900).

Environmental: Advances in Instrumentation and Techniques

Monday Morning (210-1 P) New Polymer-Based Ion Chromatography Columns for Cation Analysis EIJI KAGAWA, Shodex, Showa Denko K.K., Yoshiji Okada, Hideyuki Kondo, Kuniaki Shimbo, Kuniko Igarashi (210-2 P) Trace Level Analysis of Active Analytes by GC/MS on a New Column with Superior Inertness ROY R LAUTAMO, Agilent Technologies, Inc., Eberhardt Kuhn, Alan P Broske

46

(220-11 P) Comparison of Dynamic and Static Methods for Determination of Volatile Organic Compounds in Soil and Water JORGE S ALVARADO, Argonne National Laboratory, Candace M Rose, LaFreniere Lorraine (220-12 P) A Novel Automatic Luminous Bacteria-Based Early Warning Online Monitor for Water Toxicity Measurements LUCA SANFILIPPO, SYSTEA Srl, Pompeo Moscetta, Shimon Ulitzur, Nirit Ulitzur (220-13 P) Rapid Detection of E. coli O157: H7 in Finished Drinking Water Using a Paramagnetic Bead Based Immunoassay with Fluorescence Detection JIAN TU, University of Cincinnati, Agnese Jurkevica, H B Halsall, Carl J Seliskar, William R Heineman (220-14 P) New Reagent, Reagent Delivery System and Spectrophotometer Has Been Developed Providing Enhanced Stability, Greater Accuracy and Productivity for Analysis of Residual Chlorine DONALD F HARRINGTON, Hach Company (220-15 P) Atmospheric Pressure Chemical Ionization in the Detection of Rotenone Pollutant in River Waters: An MS/MS Approach by Means of a Suitable Internal Standard FABIO MAZZOTTI, Universit della Calabria/Dipartimento di Chimica, Leonardo Di Donna, Giovanni Sindona (220-16 P) Monitoring Biological Contamination (pyrogens and nucleases) in Water JULIEN BOLE, Millipore, Stephane Mabic, Ichiro Kano (220-17 P) Mimetizing the Atmospheric OH Radical-Mediated Photooxidation of Isoprene: Probing the Formation of Cloud Condensation Nuclei Polyols by Electrospray Ionization Mass and Tandem Mass Spectrometry MARCOS N EBERLIN, State University of Campinas UNICAMP (220-18 P) New Optical Design in Standard Reference Photometer (SRP) for the Absolute Measurement of Ozone WOO JIN-CHUN, KRISS, Hyun-Kil Bae (220-19 P) Miniaturised Portable Devices For Water Monitoring LEANNE MARLE, University of Hull, Gillian M Greenway (220-20 P) Use of Temperature Programming to Improve Resolution of Haloacetic Acids and Oxyhalides in Drinking Water by Suppressed Ion Chromatography BRETT PAULL, Dublin City University, Pavel N Nesterenko (220-21 P) Selection of Algal Species for Scavenging of Chromium Ions from Polluted Water Bodies DAVINDER P SINGH, Khalsa College for Women (220-22 P) Stability of Methoprene in Natural Waters and Analysis of Its Metabolites JOSEY GRABUSKI, National Laboratory for Environmental Testing, Ed Sverko, Erin Gilmer (220-23 P) Extracting Phenols and Napthols from Water Solutions YAKOV I KORENMAN, VoronezhTechnological Academy, Pavel T Sukhanov

(230-8 P) Systematic Approaches for Successful Implementation of a Field LC Method for Analysis of Multi-Components in Wood Treatment Facilities MANLI WU, Arch Chemicals, Inc., Susan Thomason, Edward Grabowski, Hongwei Xu, Peter Osborne (230-9 P) Determination of Arsenic in Pressure-Treated Wood Structures and Contaminated Environs by Flow Injection Pervaporation and Indirect Spectrophotometric Detection RICHMOND J AMPIAH-BONNEY, University of Massachusetts, Julian F Tyson (230-10 P) Optimized Reversed-Phase Packings for Preparative High Performance Liquid Chromatography RONALD E MAJORS, Agilent Technologies, Inc., Cliff Woodward, Alan P Broske, Maureen Joseph

POSTER SESSION
Environmental: Analysis of Organic Contaminants
Monday Morning

Session 240

(240-1 P) One-Line Switching Column Coupled with LC-TOF Mass Spectrometry for Multiresidue Pesticide Determination in DWTPs JOHANNE BEAUSSE, CAE Veolia Environnement, Sophie Men (240-2 P) A New, Unique Stationary Phase for the Rapid Analysis of Organochlorine Pesticides GREGORY FRANCE, Restek Corporation, Christopher M English, Gary B Stidsen (240-3 P) Optimization of Evaporation/Concentration Parameters Prior to Analysis for Pesticides by GC/XSD or GC/PFPD MICHAEL R HALVORSON, O. I. Analytical (240-4 P) Reducing Injection Port Breakdown for Organohalide Pesticide Analysis ROBERT H WOHLEB, VICI, Martin Okiro (240-5 P) Removal of Phthalate Esters from Contaminated Soil Using Ozone and Subcritical Water Extraction Techniques GASTON JC WU, National Taiwan Normal University (240-6 P) Trace Level Determination of PCBs in Water and Soil by GCECD Using Large Volume Splitless injection THOMAS PORZANO, Thermo Electron Corporation, Sonia Dall'Ara, Elisa Montanari, Giampiero Luciani, Paolo Magni, Flavio Bedini (240-7 P) Determination of PAHs in Aqueous Samples Using a Surfactant Immobilized Sorbent RACHEL T PHILPOTT, Appalachian State University, Qing Zhao, Eric D Conte (240-8 P) Withdrawn (240-9 P) Volatile Petroleum Hydrocarbons by Purge and Trap LAURA CHAMBERS, O. I. Analytical, Michael L Duffy (240-10 P) Spectroscopic Properties of Cyclophane-Anthracene and Cyclophane-Fluorenone THANDI BUTHELEZI, Western Kentucky University, Andrew Starosta (240-11 P) Investigation of Trichloroethylene Photooxidation Utilizing Photocatalyst-Coated Buoyant Microspheres and Simulated Solar Radiation SAM LOHSE, Idaho State University (240-12 P) Development of a Fluorimetric Method to Monitor Aging of Transformer Oil SUBBIAH DEEPA, Indian Institute of Technology, Madras, Ashok M Mishra, R Sarathi (240-13 P) Evaluation of Etched Chemically Modified Columns in Open Tubular Capillary Electrochromatography for the Separation of Phenoxyacid Herbicides KEVIN H BENNETT, Hood College, Jessica E Baer (240-14 P) New HPLC Columns for Fast, Efficient Separation of Aniline Derivatives GUANG QING LI, Varian, Inc., Dennis D Blevins (240-15 P) Withdrawn (240-16 P) Comparison of Spore Count to Microbial Volatile Organic Compounds in Mold Analysis DANIEL B CARDIN, Entech Instruments, Inc., Thomas X Robinson, Chris J Casteel

POSTER SESSION
Environmental: Analysis of Biological Matrices
Monday Morning (230-1 P) Withdrawn

Session 230

(230-2 P) Association Kinetics of Pyrene by Dissolved Humic Materials Using Fluorescence Spectroscopy HADI M MARWANI, Louisiana State University, Kristin A Fletcher, Mark Lowry, Aleeta M Powe, Robert L Cook, Isiah M Warner (230-3 P) The Pressurized Solvent Extraction and Analysis of PCB Cogeners from Minute Quantities of Avian Blood Samples Using Ion Trap GC-MS-MS ROLF SCHLAKE, Applied Separations, Christian Harrison, David G Kelly, Ron D Weir (230-4 P) Determination of Alkylphenols in Marine Species from Taiwan CHIN-YUAN CHENG, National Central University, Wang-Hsien Ding (230-5 P) The Study of Concentration of Some Elements in Medicinal Plants by Radioactivation Method on Cyclotron ABDUVOHID TILLAEV, Samarkand State University, Xurshida Tillaeva (230-6 P) Comparison of the Arsenic Uptake by Two Species of Hyperaccumulating Plants DAVID J BUTCHER, Western Carolina University, Patrick Baldwin, Alisha Pendergrass (230-7 P) Use of Tissue Samples from the Marine Environmental Specimen Bank for Analytical Research and Monitoring REBECCA S PUGH, National Institute of Standards and Technology, Michael Ellisor, Barbara Porter, Paul Becker, John Kucklick, Steven J Christopher, Stacy Vander Pol, Clay Davis , Heather Stapleton, Elizabeth Mackey, Stephen Wise

POSTER SESSION
Environmental: Analysis of Soils and Waste Materials
Monday Morning

Session 250

(250-1 P) Simultaneous Determination of Inorganic Anions and Organic Acids in Refinery Process and Waste Waters by Capillary Electrophoresis with Indirect UV Detection NICOLAS BORD, Universit Claude Bernard Lyon 1, Grard Cretier, Jean-Louis Rocca, Jean-Paul Souchez, Carole Bailly

47

(250-2 P) Accelerated Solvent Extraction of Polychlorinated Biphenyls from High Level Nuclear Waste S G METCALF, CH2MHill Hanford Group, Inc., Scott A Clauss, Jann M Frye, D R Hansen (250-3 P) Detection of Tetracycline Residues in Manure-Fertilized Soil and Wastewater Using ELISA and LC/MS Methods and Investigating the Factors that Affect Their Mobility in Soil PANKAJ KULSHRESTHA, State University of New York at Buffalo, Rossman Giese, Seamus O'Connor, Diana S Aga (250-4 P) Ammonia Concentrations Utilizing Acid Coated Denuters from Feedlots in Central Iowa KENWOOD D SCOGGIN, USDA Agricultural Research Service, Dick L Pfeiffer, Jerry L Hatfield (250-5 P) Matrix Challenges in the Analysis of Polychlorinated Biphenyls in the Hanford Tank Wastes RAMPUR S VISWANATH, CH2MHILL Hanford Group, Inc., Scott A Clauss, Duc M Nguyen (250-6 P) Rapid Analysis of Soil Samples for Organic Environmental Pollutants Using Gas Chromatography Time-of-Flight Mass Spectrometry LAWRENCE D CLARK, US Army Center for Health Promotion and Prevention (250-7 P) Solid Phase Microextraction-Gas Chromatographic-Mass Spectrometric (SPME-GC-MS) Determination of Nitrous Oxide Evolution by Denitrification in Soil and Sediments SADIE R DRESCHER, USDA Forest Service, Stacy D Brown (250-8 P) Monitoring of Insecticide and Heavy Metal Levels in Sediment Cores from Lake Abaya/South Ethiopia BERND W WENCLAWIAK, University of Siegen, Brigitta Schuett, Ulrike Koch, Thorsten Schmeck (250-9 P) Reversed-Phase HPLC Method for the Determination of Nitrosoglyphosate in Commercial and Environmental Samples WANLONG ZHOU, Wright State University, Roger K Gilpin (250-10 P) Rapid Enzymatic Nitrate Test Kits for Water, Soil and Plant Tissue Samples ELLEN R CAMPBELL, Nitrate Elimination Co, Inc, Michael J Broduer-Campbell, Troy P Kinnunen-Skidmore, Wilbur H Campbell

(260-12 P) Chemistry and HPLC Analysis of Phenylurea Herbicides KATIA M MAY, Restek Corporation, C. Vernon Bartlett, Rebecca E Wittrig (260-13 P) Sample Preparation and Confirmation Column for Phenoxyacid Herbicides by HPLC KRISTI J SELLERS, Restek Corporation, Nolan Lydia, Rebecca E Wittrig

POSTER SESSION
Gas Chromatography
Monday Morning

Session 270

(270-1 P) Evaluation of the Effects of Heating Profile and Modulation Period on a Resistively Heated Thermal Modulator for GC x GC CORY S FIX, University of Michigan, Mark Libardoni, Richard D Sacks (270-2 P) Withdrawn (270-3 P) Pesticides in Drinking Water-Beyond Dual Column Confirmation JAMES R SEEGER, US Army (270-4 P) Blood Alcohol Analysis Using an Automated Static Headspace Method VANESSA R KINTON, Gerstel Inc., Edward A Pfannkoch, Jacqueline Whitecavage (270-5 P) The Controller for Sulfur and Nitrogen Detection RANDALL L SHEARER, Ionics Instruments (270-6 P) Supported Capillary Membrane Sampling-Gas Chromatography on a Valve GARY L EMMERT, The University of Memphis, Michael A Brown, Paul S Simone, Greg T Anderson (270-7 P) Elucidation of Gas Chromatographic Sample Introduction Processes DAN DIFEO, SGE Incorporated, Peter Dawes, Robert Western (270-8 P) Increasing the Level of Testing Standards for Capillary Columns DAN DIFEO, SGE Incorporated, Peter Dawes (270-9 P) Quantitative Evaluation of Gas Chromatographic Capillary Column Bleed DAN DIFEO, SGE Incorporated, Peter Dawes, Robert Western (270-10 P) Enantioselective Gas Chromatographic Analysis of Cyclopropane Derivatives ASHRAF GHANEM, University of Geneva (270-11 P) Evaluation of a Software Tool for Selecting Method Parameters for Comprehensive Two-Dimensional Gas Chromatography MARK F MERRICK, LECO Corporation, Jon M Ruppel, Jonelle Shiel (270-12 P) A Model for Predicting the Carrier Gas Flow Rate in GC x GC Systems with Columns of Different Diameters TADEUSZ GRECKI, University of Waterloo, James Harynuk (270-13 P) A Model for Predicting the Carrier Gas Flow Rate in GC x GC Systems with Columns of Different Diameters JAMES HARYNUK, University of Waterloo, Tadeusz Grecki (270-14 P) Prediction of Gas Chromatographic Retention Indices Based on Component Structures ING.NORBERT REUTER, Varian, Inc., Rianne Heuker, Jaap De Zeeuw (270-15 P) Surface Derivatized Fibrous Stationary Phases in GC AKIRA ABE, Toyohashi University of Technology, Yoshihiro Saito, Tsutomu Takeichi, Kiyokatsu Jinno (270-16 P) Characteristic of Monolayer Stationary Phase for Capillary Gas Chromatography TSUNEAKI MAEDA, National Metrology Institute of Japan, Aya Murata, Norikazu Nagae, Tatsuro Nakagama, Katsumi Uchiyama (270-17 P) Temperature Programming and Selectivity Enhancement with Silicon Micro-Fabricated GC Columns SHAELAH M REIDY, University of Michigan, Gordon R Lambertus, Richard D Sacks (270-18 P) Development of Universal Calibration System for the Quantitative Analysis by Capillary GC/FID MAEDA TSUNEAKI, National Institute of Advanced Industrial Science and Technology (AIST), Watanabe Takuro, Matsumoto Nobuhiro, Kato Kenji (270-19 P) Outfitting the Gas Chromatograph for Multi-Detector Headspace Analysis FERENC A BENCSATH, U.S. FDA, Paul P Eilers (270-20 P) Ultra Fast GC Analysis of Essential Oils and Petroleum Fractions Using Automatic Nanovolumes Injection THOMAS PORZANO, Thermo Electron Corporation, Riccardo Facchetti, Andrea Cadoppi, Fausto Pigozzo, Flavio Bedini (270-21 P) Analysis of Accelerators in Cured Rubber Composites by Headspace-GC DONGHO CHANG, Kumho Tire, Bong Young Shon, Minhyun Han, Sung Hyo Chough

POSTER SESSION
Environmental: General Posters
Monday Morning

Session 260

(260-1 P) Subsurface Hydrolysis and Degradation of Aqueous Polyphosphates Determined by 31P NMR DAWN M WELLMAN, Pacific Northwest National Laboratory, Bruce K McNamara, Sarah D Burton, Jonathan P Icenhower (260-2 P) Routine Analysis of Low Levels of Arsenic Using a Unique Polymer-Based Method RENO CERRA, SGE International Pty. Ltd., Yaduvendra K Agrawal, Devraj Aiyar (260-3 P) Analytical Screening According to RoHS and ELV Directives Using Benchtop EDXRF DIRK WISSMANN, Spectro Analytical Instruments GmbH & Co. KG, Oliver Buettel (260-4 P) Advantage and Disadvantage Using Discrete vs. FIA/SFA Technology in Automated Monitoring of Ions in Water NINGLAN LIAO, O. I. Analytical, Michael L Duffy, Craig Marvin, William Lipps (260-5 P) Development of Standard Reference Materials for Environmental Iodine-129 Measurements STEPHEN E LONG, National Institute of Standards and Technology, John D Fassett, Larry L Lucas (260-6 P) Photon Ionization Time-of-Flight Mass Spectrometry for the Rapid Analysis of Aqueous Samples HARALD OSER, SRI International, Steven Young, Michael J Coggiola (260-7 P) Using a Discrete Analyzer for Nitrate Determination by Cadmium Reduction ANGELA D SERRA, STL, Inc. (260-8 P) Xerogel-Coated Electrodes in Room Temperature Ionic Liquids THOMAS L RIECHEL, Miami University, Christopher D Aluise (260-9 P) Quality of Runoff Roof Waters from an Urban Region (Gdansk, Poland) ZANETA POLKOWSKA, Gdansk University of Technology, Tadeusz Grecki, Jacek Namiesnik (260-10 P) Quantifying the Effects of CO2(g) on As(V) Adsorption in the Subsurface TANJA RADU, Auburn University, Jonathan LO Subacz, Mark O Barnett (260-11 P) Challenge to Lower Detection Limit by Discrete Analyzer to Meet EPA Regulated Requirements for Automated Wet Chemistry in Nutrient Analysis WILLIAM LIPPS, O. I. Analytical, Ninglan Liao

48

(270-22 P) Tandem Capillary Column Consisting of a Polar Column and a Nonpolar Column Using the Tandem Oven SEOKWON EOM, Seoul Metropolitan Government Institute of Enviro., Jae-Cheon You (270-23 P) Integrated Guard Columns: A Simple Solution for a Big Problem in Capillary GC JAAP DE ZEEUW, Varian, Inc., Peter Heijnsdijk (270-24 P) Improving Sensitivity and Separation Power by Using LVSLGCxGC-FID Technique for Pollutants' Detection at Low ppb Level DANIELA CAVAGNINO, Thermo Electron Corporation, Flavio Bedini, Giacinto Zilioli, Sorin Trestianu (270-25 P) A Study on Quantitative Analysis of Waxes (ethylene bis stearamide and metal stearates) in ABS Using Acylation KIM HEE YOUNG, Cheil Industries, Inc., Kim Youn-Sung (270-26 P) A Comparison of Liner Geometries and Their Effect on Gas Chromatographic Performance MICHAEL A GOSS, Restek Corporation, Brad R Rightnour (270-27 P) A Novel Approach to Ensuring a Leak-Free Injection Port MICHAEL A GOSS, Restek Corporation, Brad R Rightnour (270-28 P) Fast Separations with Standard Capillary Columns Using Accessory Heaters in Conventional GC Ovens STEPHEN J MACDONALD, Zip Scientific (270-29 P) A New Split/Splitless Injection Port Eliminates Analyte Breakdown and Sealing Problems BRAD R RIGHTNOUR, Restek Corporation, Michael A Goss, Paul Silvis, Christopher M English (270-30 P) Fast Gas Chromatography, Guidelines and Applications LEONARD M SIDISKY, Supelco, Inc., Katherine L Stenerson, Jamie Desorcie, Greg L Baney (270-31 P) Determination of ortho-Phthalaldehyde (OPA) in Salty Formulation by Gas Chromatograph PETER C ZHU, Johnson & Johnson

(280-12 P) A Novel Monomeric C18 Bonded Phase for Improved Resolution and Sensitivity in LC-MS/MS Analysis of Peptides RENO T NGUYEN, Grace Vydac, Cindy Lou Chepanoske, Nathan VerBerkmoes, Michael B Strader, Larry Gross, Ning Mu (280-13 P) High Throughput DNA Analysis of PCR Products and Plasmid DNA by Multiplexed Capillary Gel Electrophoresis with UV Absorbance Detection WEI WEI, CombiSep, Inc., Jeremy Kenseth, Ho-ming Pang (280-14 P) Multiplexed-CIEF with Absorption Detection for Protein Analysis KIT-SUM WONG, CombiSep, Inc., Ho-ming Pang (280-15 P) Improvement in Protein Identification Using Multiply Charged Ion by Nano Flow ESI MS MASAKI YOSHIE, Hitachi Science Systems Ltd., Shinji Yoshioka, Kimiyoshi Kohda, Shinya Ito (280-16 P) Monolithic Capillary Column LC-ESI MS/MS for Rapid Bacterial Identification YING ZHANG, University of Alberta, Zhihui Wen, Rui Chen, Xinlei Yu, Liang Li (280-17 P) Withdrawn (280-18 P) Comparison of Protein Separations Using Monolithic Columns and a Conventional Reversed-Phase Capillary Liquid Chromatography Column KRISTEL D ARRINGTON, Louisiana State University, Xiaodong Huang, Samuel J Washington, Isiah M Warner (280-19 P) Reversed-Phase Retention of Glycopeptides and Detection by Mass Spectrometry HILLEL K BRANDES, Supelco/Sigma-Aldrich, John Martin, David S Bell (280-20 P) Probing the Nature of Interactions of Nucleotides and Nucleosides: Utilization of Alkyl, Polar End-Capped and Polar Embedded Phases for RP-HPLC Based Screening KRISHNA KALLURY, Phenomenex, Inc., Scott Waite (280-21 P) High Resolution Separation of Proteins by Two-Dimensional HPLC Composed of IEC and RPC YOSHIO KATO, Tosoh Corporation (280-22 P) Performance of Cation-Exchange Columns Used in Proteomics MARY A SCHULTZE, University of Wisconsin at River Falls, Dwight R Stoll, Peter W Carr (280-23 P) 75m ID and Miniature Trap Columns with Integrated Design HANS-JUERGEN WIRTH, SGE International Pty. Ltd., Peter Dawes, Ern Dawes (280-24 P) A Novel Qualitative and Quantitative LC/MS Based Approach to Relative Protein Quantification and Biomarker Discovery TIMOTHY RILEY, Waters Corporation, Scott Geromanos, Keith Richardson, Phillip Young, Richard Denny, Kieran Neeson, Therese McKenna, Craig Doreschel, Marc Gorenstein, Guo-Zhong Li, Jeffrey Silva, James Langridge, Alistair Wallace (280-25 P) A Novel Wideport Ion Exchange Sorbent/Column for 1D or 2D Separations of Proteins and Nucleic Acids SCOTT WAITE, Phenomenex, Inc. (280-26 P) DNA Extraction Based on Photo-polymerized Monolithic Sol-gel in Capillaries JIAN WEN, University of Virginia, Christelle Guillo, Jerome P Ferrance, Michael G Roper, James P Landers (280-27 P) Modification of Poly(methyl methacrylate) Microchannels for Highly Efficient and Reproducible Electrophoretic Separations of DoubleStranded DNA YANG-WEI LIN, National Taiwan University

POSTER SESSION
Proteomics and Genomics
Monday Morning

Session 280

(280-1 P) Study of the Silanophilicity of Acid Stable Hyper-Crosslinked Stationary Phases LIANJIA MA, University of Minnesota (280-2 P) Accurate Mass Determination of Cloned Bile Salt Hydrolase Subunits from Bifidobacterium Species BYONG H LEE, McGill University, Geun Bae Kim (280-3 P) Improved Protein and Peptide Chromatography Using Lower Pore Size Phases as Alternative Chromatographic Media to Conventional Wide-Pore Phases RITU ARORA, Varian, Inc., Guang Q Li, Chris Lee, Dennis D Blevins (280-4 P) Features of a Dedicated Nano LC System JEAN-PIERRE CHERVET, LC Packings (280-5 P) Analysis of Protein Post-Translational Modifications Using Electrospray on a Hybrid Quadrupole Orthogonal Acceleration Time-ofFlight Mass Spectrometer KEITH COMPSON, Waters Corporation, Mark Ritchie, Christopher Jones, Therese McKenna, James Langridge (280-6 P) MALDI-TOF Profiling of Mycobacterium Tuberculosis: Temporal Changes in the Protein Profile JUSTIN M HETTICK, Niosh/Held/Asb, Janet P Simpson, Michael L Kashon, Paul D Siegel, David N Weissman (280-7 P) Nonenzymatic In Vivo Attachment of Phycoerythrobilin to ApoSubunits of R-phycoerythrin DRAGAN ISAILOVIC, Iowa State University, Gregory J Phillips, Edward S Yeung (280-8 P) Multi-protease PMF Analysis via Chemical Inkjet Printing (ChIP) JAMES J JERNEE, Shimadzu Biotech (280-9 P) Manipulating Selectivity in RP-HPLC of Proteins: Embedded Polar Functionality as a Lever KRISHNA KALLURY, Phenomenex, Inc., Scott Waite, Greg Scott, Ismail Rustamov (280-10 P) Analytical/Proteomic Approach to Evaluating the Effect of Alcohol Intake on Liver Protein Expression/Modification IVETA KLOUCKOVA, Indiana University, Petra Hrncirova, Randy J Arnold, Yehia Mechref, William J McBride, Milos V Novotny (280-11 P) Optimization of the Effective Separations for Peptides and Proteins Using High Durable Packing Materials for High Performance Liquid Chromatography NAOHIRO KURIYAMA, YMC Co., Ltd., Noriko Shoji, Masakatsu Omote, Masako Moriyama

SYMPOSIUM
University Monday Afternoon, Room S210A Richard L McCreery, Ohio State University, Presiding 1:30

Session 1940

Ralph N Adams Award - arranged by Richard L McCreery, Ohio State

Introductory Remarks - Richard L McCreery

1:35 Presentation of the 2005 Ralph N Adams Award to Edward S Yeung, Iowa State University, by Richard L McCreery, Ohio State University 1:40 (1940-1) Molecular Identification at the Single-Molecule Level for Disease Diagnosis EDWARD S YEUNG, Iowa State University, Ji-Young Lee, Hung-Wing Li 2:15 (1940-2) Recent Advances in Fourier Transform Ion Cyclotron Resonance Mass Spectrometry Instrumentation and Techniques ALAN G MARSHALL, Florida State University, Christopher Hendrickson, Mark R Emmett, Ryan P Rodgers, Greg T Blakney, Carol L Nilsson 2:50 (1940-3) Holding Biology up to the Light: Probing Single Molecules in Single Cells SUNNEY XIE, Harvard University 3:25 Recess

49

3:40 (1940-4) Single Cell Neurochemistry: How Complicated Is It? JONATHAN V SWEEDLER, University of Illinois 4:15 (1940-5) Unraveling the Neurochemistry of Disease States with bBoanalytical Methods R MARK WIGHTMAN, University of North Carolina at Chapel Hill, Michael A Johnson, Paul A Garris

2:45 (310-3) Amyloid Protein Structure Studied by Site-Directed Spin Labeling RALF LANGEN, University of Southern California, Martin Margittai, Mario J Isas, Ani Der-Sarkissian 3:20 Recess 3:35 (310-4) Membrane + Protein - Site-Directed Spin Labeling EPR: A Winning Combination YEON-KYUN SHIN, Iowa State University 4:10 (310-5) Application of EPR Spectroscopy for the Study of RNA and RNA-Ligand Interactions SNORRI T SIGURDSSON, University of Iceland

SYMPOSIUM

Session 840

Biomedical Chemical Micro- and Nanosensors: From Cytosol to Brain - arranged by Raoul Kopelman, University of Michigan
Monday Afternoon, Room S230C Raoul Kopelman, University of Michigan, Presiding 1:30 Introductory Remarks - Raoul Kopelman

SYMPOSIUM

Session 320

Getting Serious About Separations: Two-Dimensional Separations - Power for Complex Analyses - arranged by Stephen G
Weber, University of Pittsburgh Monday Afternoon, Room S220D Stephen G Weber, University of Pittsburgh, Presiding 1:30 Introductory Remarks - Stephen G Weber

1:35 (840-1) Monitoring Synaptic and Extrasynaptic Neurotransmission in the Brain ADRIAN C MICHAEL, University of Pittsburgh, Bridget M Willoughby, Laura M Borland 2:10 (840-2) University of Florida Bioconjugated Nanoparticles WEIHONG TAN,

2:45 (840-3) Dynamic Monitoring of Live Cells in a Microfluidic Environment ROBERT T KENNEDY, University of Michigan 3:20 Recess 3:35 (840-4) Some Aspects of Nanoelectrochemistry on Gold Nanoparticles and Their Derivatives ERKANG WANG, Changchun Institute of Applied Chemistry 4:10 (840-5) Optochemical Nanosensor PEBBLEs: Photonic Explorers for Bioanalysis and Bio-imaging of Localize Environments inside Live Cells RAOUL KOPELMAN, University of Michigan, Yong-Eun L Koo, Edwin J Park, Hao Xu, Martin A Philbert, Murphy Brasuel

1:35 (320-1) Effective Multidimensional Separations for Global Proteomics HALEEM J ISSAQ, SAIC Frederick, King C Chan, Timothy D Veenstra 2:10 (320-2) Multi-Dimensional HPLC Using Monolithic Silica Columns NOBUO TANAKA, Kyoto Institute of Technology 2:45 (320-3) Combined LC-LC and LC-CE for Separations of Complex Mixtures of Peptides and Proteins JAMES W JORGENSON, University of North Carolina at Chapel Hill 3:20 Recess 3:35 (320-4) Principles of Comprehensive 2-D Separations with Chemometric Data Analysis ROBERT E SYNOVEC, University of Washington 4:10 (320-5) Fast, Two-Dimensional High Performance Liquid Chromatography of Peptides PETER W CARR, University of Minnesota, Dwight R Stoll

SYMPOSIUM

Session 300

Bioterrorism: The Federal Response, Technologies and Research - arranged by Richard A Durst, Cornell University
Monday Afternoon, Room S230H Richard A Durst, Cornell University, Presiding 1:30 1:35 Security (300-1) Introductory Remarks - Richard A Durst TBA CHARLES MCQUEARY, Department of Homeland

SYMPOSIUM
arranged by Janusz B Pawliszyn, University of Waterloo Monday Afternoon, Room S230F Janusz B Pawliszyn, University of Waterloo, Presiding 1:30

Session 330

On-Site Analysis with Mobile GC and MS Instrumentation -

2:10 (300-2) Food Defense: FDA's Role in Protecting America's Food Supply ROBERT E BRACKETT, Food and Drug Administration 2:45 (300-3) The Laboratory Response Network J. MICHAEL MILLER, Centers for Disease Control and Prevention 3:20 3:35 (300-4) DARPA (DOD) Recess DARPA R&D to Defeat Bioterrorism AMY E ALVING,

Introductory Remarks - Janusz B Pawliszyn

2:05 (330-1) Chemical Mapping and Profiling of Aqueous Systems ROBERT T SHORT, University of South Florida 2:40 (330-2) Portable Fast GC with PFPD for Chemical Warfare Agent Analysis and Electrolyzer FID for Breath Analysis AVIV AMIRAV, Tel Aviv University 3:15 (330-3) GC/MS as Part of the German Analytical Task Force C for Chemical Accidents GERHARD MATZ, TUHH 3:50 Recess 4:25 (330-4) On-site Measurements and In-field Monitoring Using Gas Chromatographs, Ion Mobility Spectrometers, and Combinations of the Same GARY A EICEMAN, New Mexico State University 5:00 (330-5) In-situ Sampling/Sample Preparation Coupled to Portable GC for Rapid Air Investigations JANUSZ B PAWLISZYN, University of Waterloo

4:10 (300-5) Agricultural Biodefense Research HENRY S PARKER, USDA-ARS, Edward B Knipling

SYMPOSIUM

Session 310

Electron Spin Resonance Methodology for Structural and Dynamical Characterization of Proteins - arranged by Sunil Saxena,
University of Pittsburgh Monday Afternoon, Room S230B Sunil Saxena, University of Pittsburgh, Presiding 1:30 Introductory Remarks - Sunil Saxena

1:35 (310-1) FT-ESR Methods for Measuring Large Distances SUNIL K SAXENA, University of Pittsburgh, Marco Bonora, Pornsuwan Soraya, James Becker 2:10 (310-2) The Prion Protein Within Us: Using EPR Methods to Assess Structure and Evaluate Function of the PrP Copper Metalloprotein GLENN L MILLHAUSER, University of California at Santa Cruz, Colin S Burns, Eliah Aronoff-Spencer, Gary J Gerfen, Jack Peisach, William E Antholine, Giuseppe Legname, Stanley B Prusiner

50

SYMPOSIUM

Session 340

ORAL SESSION

Session 370

The Sixteenth James L Waters Annual Symposium Recognizing Pioneers in the Development of Scientific Instrumentation: Electrochemistry - arranged by Rita M Windisch, The Mercy Hospital of
Pittsburgh Monday Afternoon, Room S220G Adrian C Michael, University of Pittsburgh, Presiding Richard S Danchik, Presiding 1:30 Introductory Remarks - Rita M Windisch

Capillary Electrophoresis: Applications and MS/SEM/LED/Diode Array Detection

Monday Afternoon, Room S210E Mark Hayes, Arizona State University, Presiding 1:30 (370-1) Novel Polymeric Alkenoxy Sulfated Surfactant: Chiral Separation of Broad Range of Analytes SYED A RIZVI, Georgia State University, Shahab A Shamsi 1:50 (370-2) Ionic Liquids as Modifiers in the Separation of Charged Bases and Acids Using Capillary Electrophoresis CHARLOTTE E SILVERMAN, AstraZeneca Pharmaceuticals LP 2:10 (370-3) Evaluation of the Solution Structure of Lipase Enzymes Using Capillary Electrophoresis HENRIETTA MITCHELL, Georgia State University, Emelita D Breyer, Stuart Allison 2:30 (370-4) Capillary Electrochromatography-Electrospray Ionization Mass Spectrometry (CEC-ESI-MS) of Cationic Surfactants DEAN S NORTON, Georgia State University, Shahab A Shamsi 2:50 (370-5) Top-Down Multidimensional Separation Technologies Targeting Comprehensive Proteomics CHENG S LEE, University of Maryland at College Park, Yueju Wang, Jonathan W Cooper, Brian M Balgley, Paul A Rudnick, Don L DeVoe 3:10 Recess 3:25 (370-6) Polymeric Alkenoxy Amino Acid Surfactants: Synthesis, Characterization and Applications of Doubly Charged Anion Surfactants CHEERAPA BOONYAKONG, Georgia State University, Syed A Rizvi, Shahab A Shamsi 3:45 (370-7) Affinity Interactions Between Proteins and G-quartet DNA ADAM C CONNOR, Duke University, Linda B McGown 4:05 (370-8) Electrode Placement Optimization for Capillary Electrophoresis Using a Scanning Electrochemical Microscope DAVID M ROACH, Virginia Tech, Mark Anderson 4:25 (370-9) Use of Light-Emitting Diodes (LEDs) for Fluorescence Detection in Capillary Electrophoresis EBBING P DE JONG, University of Alberta, Charles A Lucy 4:45 (370-10) Capillary and Microchip Electrophoresis of Thiols after Fluorescence Labeling with Benzoxadiazoles TOBIAS REVERMANN, University of Twente, Sebastian Gtz, Uwe Karst

1:35 (340-1) The Rise of Voltammetry: From Polarography to the Scanning Electrochemical Microscopy ALLEN J BARD, University of Texas at Austin 2:10 (340-2) From the Science Fair to the Nasdaq PETER T KISSINGER, Bioanalytical Systems, Inc. 2:45 (340-3) The Historical and Emerging Role of Electrochemistry in Preventive Medicine Technical Solutions to Social Problems WAYNE R MATSON, ESA Inc. 3:20 Recess 3:35 (340-4) Serendipity: The Genesis of the Electrochemical Instrumentation Activity at Princeton Applied Research Corporation JUD B FLATO, JB Flato & Associates 4:10 (340-5) History of Clarks Membrane Polarographic Electrode and Initial Bioelectrode HARDY TROLANDER

ORAL SESSION
Monday Afternoon, Room S230G Cynthia Larive, University of California - Riverside, Presiding

Session 360

Bioanalytical Sensors: Developments and Applications II

1:30 (360-1) Immunosensor Based on Conducting Polymer Coated Magnetic Particles HAIRONG ZHANG, University of Michigan, Maxim Burgman, Hyoungsik Yim, Robert K Franklin, Mark E Meyerhoff 1:50 (360-2) A Novel Approach to Quantitative Measurements Using Giant Magnetoresistance Sensors JOHN NORDLING, Iowa State University, Rachel L Millen, Heather A Bullen, Nikola Pekas, Toshikazu Kawaguchi, Mark Tondra, Marc D Porter 2:10 (360-3) A Ratiometric Optical Fiber Sensor for the Measurement of Oxygen Inside Viable Cells and Tissues EDWIN J PARK, University of Michigan, Kendra R Reid, Robert T Kennedy, Raoul Kopelman 2:30 (360-4) Autonomous Multielectrode System for Monitoring Cell Growth and Cytotoxicity of Phenolic Estrogens on Lung Cancer Cells SILVANA ANDREESCU, State University of New York at Binghamton, Omowunmi A Sadik 2:50 (360-5) PCR Amplicon Analysis by Surface Plasmon-Based Biosensors DANFENG YAO, Max Planck Institute for Polymer Research, Wolfgang Knoll 3:10 Recess 3:25 (360-6) Crosslinked Lipid Nanosensors for Investigating Cellular Environments CRAIG A ASPINWALL, University of Arizona 3:45 (360-7) Photonic Crystal Ammonia Sensor Using the Berthelot Reaction KYLE W KIMBLE, University of Pittsburgh, Jeremy P Walker, Sanford A Asher 4:05 (360-8) Electrochemical Methods for the Determination of Sialic Acid SAYED A MARZOUK, United Arab Emirates University 4:25 (360-9) An Electrochemical Nucleic Acid Biosensor Based on Electrocatalytic Threading Intercalator NATALIA C TANSIL, Institute of Bioengineering and Nanotechnology, Zhiqiang Gao, Fang Xie 4:45 (360-10) Array Biosensor for Detection of Mycotoxins in Food MIRIAM M NGUNDI, Naval Research Laboratory, Lisa C Shriver-Lake, Kim E Sapsford, Joel P Golden, Frances S Ligler, Chris R Taitt

ORAL SESSION
Environmental: Advances in Instrumentation
Monday Afternoon, Room S210C Olujide T Akinbo, Butler University, Presiding

Session 380

1:30 (380-1) New Developments in ICP-OES to Meet the Demands of Routine Laboratories. ANDREW CLAVERING, Thermo Electron Corporation, Paul J Neal, Adrian Holley 1:50 (380-2) Expanding the Horizons of ICP-MS in Environmental Analysis PHIL N SHAW, Thermo Electron Corporation, Bill Spence 2:10 (380-3) Improved Sensitivity and Analysis Time for Semivolatile Organic Compounds Using GC-TOFMS: Can this Analysis Really be Performed in Less Than 10-Minutes? FRANK L DORMAN, Restek Corporation, Jack Cochran, Gary B Stidsen, Christopher M English, Michael S Wittrig 2:30 (380-4) Removing Carbonate Interference from the Sample for Hydroxide Eluent Ion Chromatography Using a Post Suppressor Device KANNAN SRINIVASAN, Dionex Corporation, Rong Lin, Sheetal Saini, Chris Pohl, Nebojsa Avdalovic, Rahmat S.M.Ullah, Purnendu K Dasgupta 2:50 (380-5) Fast and Sensitive Environmental Analysis Utilizing Microextraction in Packed Syringe (MEPS) On-line with GC-MS-MS MOHAMED ABDEL-REHIM, AstraZeneca, Aziza Elbeqqali, Lars Blomberg 3:10 Recess 3:25 (380-6) Simultaneous Dual-Column GC-ECD Analysis of Polychlorinated Biphenyls Using Two New Capillary Column Stationary Phases GARY B STIDSEN, Restek Corporation, Frank L Dorman, Christopher M English, Lydia Nolan, Jack Cochran 3:45 (380-7) New GC Method as a Replacement of IR Technique for the Analysis of Total Petroleum Hydrocarbons in Water and Soils ANDREA CADOPPI, Thermo Electron Corporation, Riccardo Facchetti, Thomas Porzano, Flavio Bedini

51

4:05 (380-8) On-line Monitoring of Glass Melter Slurry Using Laser Induced Breakdown Spectroscopy LAZARUS SOLOMON, Mississippi State University, Tracey Miller, John W Branch, Hongbo Zheng, Fang-Yu Yueh, Jagdish P Singh 4:25 (380-9) LC/Electrochemistry/MS: Analysis of Isocyanates as Ferrocenoyl Piperazide Derivatives BETTINA SEIWERT, Universiteit Twente, Hartmut Henneken, Uwe Karst 4:45 (380-10) Quantitative Elemental Analysis of Submicronic Atmospheric Particles by Computer-Controlled Scanning Electron Microscopy Combined with Energy Dispersive X-ray Spectrometry MARIE CHOL, Universit du Littoral Cte d'Opale, Karine Deboudt, Pascal Flament, Jnos Osn

2:50 (400-5) Nitrogen/Protein Determination in Meat Products by Flash Dynamic Combustion Method LUIGI RAGAGLIA, Thermo Electron Corporation, Liliana Krotz, Guido Giazzi, Richard Hancock 3:10 Recess 3:25 (400-6) Detection of Escherichia coli O157:H7 and Salmonella spp Using PCR and Fiber-Optic DNA Microarray SOOHYOUN AHN, Tufts University, David R Walt 3:45 (400-7) Long-Term Evaluation of a Gas Sensor Array (Electronic Nose) Used for Detection of Contamination in Recycled Beverage Containers WOLF MUENCHMEYER, Airsense Analytics, Andreas Walte 4:05 (400-8) Integral Identification of Multicomponent Liquids for Environmental, Food, Drug and Industrial Applications ANATOLY G SANIN, Aria Analytics Inc., Tatiana A Yakhno, Vladimir G Yakhno, Michael B Dowell 4:25 (400-9) Thermal and Hydrophobic Properties of Extruded Wheat Flour Components as Measured by Differential Scanning Calorimetry and Fluorescence Spectroscopy ALFRED ANDERSON, Kuwait University 4:45 (400-10) Withdrawn

ORAL SESSION
Environmental: Analysis of Contaminants in Water
Monday Afternoon, Room S210D John Stephens, PPG Industries, Inc., Presiding

Session 390

1:30 (390-1) Determination of Trace Disinfection Byproduct Anions and Bromide in Drinking Water Using a Hydroxide-Selective Column BRIAN DE BORBA, Dionex Corporation, Robert Joyce, Jeffrey S Rohrer, Chris Pohl, Charanjit Saini 1:50 (390-2) A Simple Method for Selectively Monitoring the Concentrations of Total Trihalomethanes and Total Haloacetic Concentrations in Drinking Water. GIJA GEME, The University of Memphis, Michael A Brown, Paul S Simone, Gary L Emmert, Kyoo Dong Jo 2:10 (390-3) A Simple, Inexpensive LED Spectrometer for Monitoring Disinfectants in Drinking Water LUCY J THURSTON, University of Memphis, James J Aschberger, Gary L Emmert 2:30 (390-4) Boost Productivity and Lower Analytical Costs with TOC/Nitrogen Monitoring by High Temperature Combustion (HTC) BRIAN T WALLACE, Teledyne Instruments - Tekmar 2:50 (390-5) A Fully Automated Membrane Sampling Method for Monitoring Trihalomethanes in Drinking Water Distribution Systems MICHAEL A BROWN, The University of Memphis, Gary L Emmert 3:10 Recess 3:25 (390-6) Nitrogen and Carbon Determination in Water by Elemental Analysis with Automatic Liquid Injection LILIANA KROTZ, Thermo Electron Corporation, Luigi Ragaglia, Guido Giazzi, Richard Hancock 3:45 (390-7) Cavity Ringdown Measurements of Carbon and Phosphorous Atoms Produced by Laser Induced Plasmas THUVAN N PIEHLER, U.S. Army Research Laboratory, Frank C De Lucia , Kevin L McNesby, Chase A Munson, Andrzej W Miziolek 4:05 (390-8) Experience of an Automatic On-line Measurement System Monitoring ppb-Level Volatiles in Water over the Last 10 Years ULRICH K GOKELER, Siemens 4:25 (390-9) Near Line Automated Analysis of Water Quality Parameters: Study Completed by Environmental Protection Agency Equipment Verification Program ROBERT V MENEGOTTO, Man-Tech Associates Inc., Tiffany Reid 4:45 (390-10) Direct Analysis Compounds in Water Matrix Using Splitless Injection Technique JAAP DE ZEEUW, Varian, Inc.

ORAL SESSION
Innovative Instrumentation in Gas Chromatography
Monday Afternoon, Room S220B Jean-Marie D Dimandja, Spelman College, Presiding

Session 420

1:30 (420-1) Stationary Phase Films for MicroAnalytical Measurements ULRICH BONNE, Honeywell Labs, Nancy Iwamoto, Nelson Lytle, Frank Nerenz, Robert Higashi, Cyrus Herring, Rob Synovec, Klein Johnson 1:50 (420-2) A New Detector for Gas Chromatography Based on Micro Plasma YVES GAMACHE, Contrle Analytique Inc 2:10 (420-3) New Combustion Techniques for Sulfur and Nitrogen Chemiluminescence Detection RANDALL L SHEARER, Ionics Instruments 2:30 (420-4) Development of New Element Recipes for the GCAED SCOTT J HEIN, Diablo Analytical, Inc., Terry L Ramus 2:50 (420-5) Fast Multi-element SimDis for Petroleum Analyses Using an Atomic Emission Detector JOACHIM GERSTEL, Joint Analytical Systems, David Grudoski 3:10 Recess 3:25 (420-6) Reducing GC Column Bleed with Single Molecular Network Polymers ROBERT H WOHLEB, VICI, Martin Okiro 3:45 (420-7) Comprehensive Two Dimensional Gas Chromatography as a Powerful Tool for Quantitative Analysis of Target Compounds in Real Life Samples: Instrumentation and Applications DANIELA CAVAGNINO, Thermo Electron Corporation, Flavio Bedini, Giacinto Zilioli, Sorin Trestianu 4:05 (420-8) Benefits of ISO 17025 Accreditation for Providers and Users of Calibration Gases Used In Environmental Testing DOUGLAS C KING, Airgas, Inc. 4:25 (420-9) Evaluation of Commercial Nonheated Gas Purifiers for Their Clearness, Efficiency, and Capacity HUAMIN CAI, VICI Valco Instruments Co., Inc., Sunsanee Sutippantupat, Stanley D Stearns 4:45 (420-10) Maintain Gas Stream Purity in Analytical Processes FRANK C KANDL, Airgas, Inc.

ORAL SESSION
Food Science: IR/UV-VIS/Atomic Spectroscopy/Sensors/Physical Measurement
Monday Afternoon, Room S220C Chin-I Shyr, Thermo Electron Corporation, Presiding 1:30 1:50 2:10 Safety (400-1) (400-2) Withdrawn Withdrawn

Session 400

ORAL SESSION
Lab-on-a-Chip II
Monday Afternoon, Room S220E Edward J Guthrie, Agilent Technologies, Inc., Presiding

Session 430

(400-3) FT-IR-Based Olfactory Sensing for Food Quality and SURANJAN PANIGRAHI, North Dakota State University

1:30 (430-1) UV Patterning of Oligonucleotide Microarrays in Microfluidic Devices CATHERINE N SITUMA, Louisiana State University, Steven A Soper 1:50 (430-2) One Dimensional (1-D) Biochip for Gene Profiling HONG WANG, University of Florida, Weihong Tan 2:10 (430-3) A Microfluidic System for Proteomic Sample Handling AARON T TIMPERMAN, West Virginia University

2:30 (400-4) Monitoring the Effects of Edible Oil Hydrogenation in a Lab-Scale High-Pressure Reactor GERALD J DEMENNA, Sacred Heart University, Nancy Gregorio

52

2:30 (430-4) A Microfluidic Gradient Generating Device for Studies of Concentration Dependent Ion Channel Effecters JOHAN PIHL, Chalmers University of Technology, Jon Sinclair, Mattias Karlsson, Eskil Sahlin, Jessica Olofsson, Owe Orwar 2:50 (430-5) Analysis of Inorganic Explosives Using Miniaturised Isotachophoresis (ITP) MATTHEW S BEARDAH, Defence Science and Technology Laboratory (DSTL) 3:10 Recess 3:25 (430-9) Eelectrokinetic Micro-Pump for Chip-Scale Flow Analysis ZILIN CHEN, University of Notre Dame, Ping Wang, Hsueh-Chia Chang 3:45 (430-7) On-line Photo-immobilization of Protein inside Microchannel HIZURU NAKAJIMA, Tokyo Metropolitan University, Satomi Ishino, Hironori Masuda, Takuya Shimosaka, Tatsuro Nakagama, Toshiyuki Hobo, Katsumi Uchiyama 4:05 (430-8) Electrokinetic Control of Hybrid Nano/Microfluidic Multilayer, Multicomponent Devices JAMIE M IANNACONE, University of Illinois at Urbana, Bruce R Flachsbart, Donald M Cannon, Robert L Vlach, Peter A Rauchfuss, Paul W Bohn, Mark A Shannon, Jonathan V Sweedler 4:25 (430-6) Multidimensional Microfluidcs-Based Comprehensive Proteome Profiling CHENG S LEE, University of Maryland at College Park, Jesse S Buch, Yan Li, Ying-Xin Wang, Jonathan W Cooper, Don L DeVoe 4:45 (430-10) Fabrication of PDMS Microchannels with One-step Printed Master in Common Laboratory HONG-YUAN CHEN, Nanjing University, Ning Bao, Qing Zhang, Jing-Juan Xu

ORAL SESSION
Nanotechnology: Applications
Monday Afternoon, Room S220F Herbert H Hill, Washington State University, Presiding

Session 440

1:30 (440-1) Synthesis and Utilization of Monodisperse Hollow Polymeric Particles in Photonic Crystals XIANGLING XU, University of Pittsburgh, Sanford A Asher 1:50 (440-2) Solvent Behavior in Hydrophobic Silica Nanotubes and Nanotube Membranes KARTHIK JAYARAMAN, University of Maryland at College Park, Kenji Okamoto, Sang Jun Son, Douglas English, Sang Bok Lee 2:10 (440-3) The Development of Biosensing Applications of Indium Tin Oxide (ITO) using FT-IR Spectroscopy CRISSY L RHODES, North Carolina State University, Scott H Brewer, Simon E Lappi, Wayne Jalenak, Stefan Franzen 2:30 (440-4) Voltage-Tunable Hydrogel Film Volumes in a Membrane-Based Molecular Filter ISHIKA S LOKUGE, University of Illinois at urbana, Paul W Bohn 2:50 (440-5) Fabrication and Application of Single-Nanochannel on Silicon Wafer BO HE, University of Maryland at College Park 3:10 Recess 3:25 (440-6) Nanoparticle Assay for Real-Time Monitoring of Signal Transduction Pathways in Single Living Cell PRAKASH D. NALLATHAMBY, Old Dominion University 3:45 (440-7) Study of Single Ligand-Receptor Interactions on Single Live Cell Using Single Nanoparticle Optics Assay PRAKASH D. NALLATHAMBY, Old Dominion University 4:05 (440-8) Developing Ratiometric Singlet Oxygen Ormosil (organically modified silicate) PEBBLE Nanoprobes and Its Applications in Monitoring PDT (Photo-Dynamic-Therapy) Process YOUFU CAO, University of Michigan, Yong-Eun L Koo, Raoul Kopelman 4:25 (440-9) Novel Continuous Free-Flow Electrophoresis Instrumentation for Large-Scale Separation of Monolayer Protected Nanoclusters RACHEL R PETERSON, Vanderbilt University, David E Cliffel 4:45 (440-10) QCM Detection of Glutathione Protected Nanoclusters Using Antibody Recognition AREN E GERDON, Vanderbilt University, David W Wright, David E Cliffel

ORAL SESSION
Mass Spectrometry/Instrumentation/High Throughput
Monday Afternoon, Room S230E Issac Brenner, Environmental Analytical Laboratory, Presiding

Session 990

1:30 (990-1) A New Distributed Plasma Ion Source WILLIAM C BLANCHARD, Blanchard & Co., Inc., Melanie J Crawford, Robert G Ewing 1:50 (990-2) Pu Isotope Analyses by Multi-Collector ICP-MS with On-line Electrochemically Modulated Separation MATTHEW J EVANS, Oak Ridge National Laboratory, Sea H Park, Debra A Bostick, Lee R Riciputi, Douglas C Duckworth 2:10 (990-3) Characterization of Novel ion Optic Components from Resistive Glass BRUCE N LAPRADE, BURLE Electro-Optics, Sharon Mrotek, William Dunn 2:30 (990-4) Electrochemically Modulated Separations Performed On-line with ICP Time-of-Flight Mass Spectrometry for Separation and Concentration of Plutonium SEA H PARK, Oak Ridge National Laboratory, Debra A Bostick, Douglas C Duckworth 2:50 (990-5) Investigation of Electrospray Ionization and Electrostatic Focusing Devices Using a Three-Dimensional Electrospray Current Density Profiler JOSEPH W THOMPSON, University of North Carolina at Chapel Hill, James W Jorgenson, John W Eschelbach, Richard T Wilburn 3:10 Recess 3:25 (990-6) In-situ Probing of the Biotic-Abiotic Boundary of Plants by Laser Desorption/ionization Time-of-Flight Mass Spectrometry CHANAN SLUSZNY, Iowa State University, Edward S Yeung, Basil J Nikolau 3:45 (990-7) High Throughput Nanospray Plate for Mass Spectrometry SAU LAN T STAATS, Phoenix S&T, Inc., Zhili Huang, James W Ashmead 4:05 (990-8) Selected Ion Flow Tube-Mass Spectrometry: RealTime Quantitative VOC Analysis DANIEL MILLIGAN, University of Canterbury, Murray J McEwan, Vaughan S Langford 4:25 (990-9) Pulsed Glow Discharge with High Flow Rate of Buffer Gas and Positive DC Bias Potential as Ion Source for TOFMS Elemental Analysis ALEXANDER A GANEEV, St. Petersburg State University, Michail A Kuzmenkov, Maxim N Slyadnev, Sergey V Potapov, Maxim V Voronov 4:45 (990-10) MALDITOF Mass Spectrometry as an Aid to Taxonomical Classification of Bacteria DIANE DARE, Manchester Metropolitan University, Helen Sutton, Carrina Keys, Haroun Shah, Mark McDowall, Martin Lunt

ORAL SESSION
Monday Afternoon, Room S230D Kim Williams, Colorado School of Mines, Presiding

Session 450

Polymer Characterization: Techniques and Applications

1:30 (450-1) Polymer Structure from Concentration Dependence of Polymer Solution Viscosity DAVID TROWBRIDGE, Cannon Instrument Company 1:50 (450-2) Structure Determination of the Amorphous Perfluorinated Homopolymer: Poly[perfluoro(4-vinyloxyl-1-butene)] KIYOSHI YAMAMOTO, Asahi Glass Co., Ltd. 2:10 (450-3) On-line and On-site Quality Control of Polymerisation Processes JOERG INGO BAUMBACH, ISAS - Institute for Analytical Sciences, Wolfgang Vautz, Ralf Guesthuisen 2:30 (450-4) Temperature-Dependent Photophysics of PyreneLabeled Oligomers Dissolved in a Room-Temperature Ionic Liquid (RTIL) WENDY E GARDINIER, University at Buffalo, Frank V Bright 2:50 (450-5) Automatic Continuous Online Monitoring of Polymerization Processes (ACOMP) JOHN A MCCONVILLE, Polymer Laboratories Inc., Wayne Reed, Stephen O'Donohue 3:10 Recess 3:25 (450-6) The Determination Of Creep Rupture In High-Density Polyethylene Fuze Subassemblies from Ma and the Predicted Shelf Life of Reworked Inventory JOHN W FASSINO, Naval Surface Warfare Center, Crane Division 3:45 (450-7) Separation and Characterization of Ultra High Molecular Weight Polymers Using Monolithic Columns DEAN LEE, Colorado School of Mines, Kim Williams, Frantisek Svec, Bernard Fields 4:05 (450-8) The Features of the Most Important Industrial Polymers Modified in Conditions of Elastic Deformation SEMEN S ZLOTSKY, Ufa State Petroleum Tech University, Guzel T Kagarmanova, Rinat M Akhmetkhanov

53

4:25 (450-9) A New and Practical Method for Characterization of Branched Macromolecules WEI GAO, Polytechnic University, Ankur S Kulshrestha, Wenchun Xie, Jun Hu, Richard A Gross 4:45 (450-10) Effects of Sample Concentration on Precise Characterization of Polymers with HPLC/LS Combination QINGYE ZHOU, Precision Detectors, Inc., Trevor Havard, Todd Bartlett, Tom Remsen

4:25 (470-9) Reactions of the Transient Intermediate Cr(CO)5(cyclohexane) Studied by Time-Resolved Infrared Spectroscopy RICHARD H SCHULTZ, Bar-Ilan University 4:45 (470-10) A Novel Spectral Shape Mapper for Chemical Imaging and Spectroscopic Analysis JOHN F TURNER, Cleveland State University, Anne O'Connor

ORAL SESSION

Session 460

NEW PRODUCT FORUM

Fuels, Polymers and Materials
Monday Afternoon, Room S220A John Baltrus, U.S. Department of Energy - NETL, Presiding

Session 475

Staged Electronic Data Deliverables (SEDD) and Electronic Data Management - arranged by Anand R Mudambi, U.S. EPA
Monday Afternoon, Room S210B Anand R Mudambi, U.S. EPA, Presiding 1:30 (460-1) MUDAMBI, US EPA SEDD: An Overview and Status Report ANAND R

1:30 (475-1) A Novel Technique for Measuring Water in Aldehydes and Ketones by Karl Fischer Titration KAZUHIKO OKUSA, JM Science, Naomi Kimura, John D MacFarlane 1:50 (475-2) Heracles Flash Electronic Nose LOUIS VIVOLA, Alpha Mos, Vincent Schmitt 2:10 (475-3) Separation of Nano-rods, Nanotubes and Nanoparticles H. Y. LIU, Sepax Technologies, Inc. 2:30 (475-4) Combining Confocal Raman and Atomic Force Microscopy in One Instrument for New Materials Research Possibilities HARALD FISCHER, WITec GmbH, Klaus Weishaupt, Matthias Kress 2:50 (475-5) Dual PlasmaDual Plasma Technology for Sulfur and Nitrogen Chemiluminescence Detection RANDALL L SHEARER, Ionics Instruments

1:50 (460-2) A Technical Overview of SEDD JOSEPH F SOLSKY, US Army Corps of Engineers 2:10 (460-3) A Focus on Stage 3 SEDD Files JOSEPH F SOLSKY, US Army Corps of Engineers 2:30 (460-4) SEDD and the Contract Laboratory Program ALFRED MAYO, CSC 2:50 (460-5) Creating SEDD Stage 3 Deliverables: A LIMS Vendors Perspective BUDDY WISON, Promium 3:10 Recess 3:25 (460-6) Performing Automated Data Review and Data Quality Assessment on SEDD Files SCOTT DENZER, Laboratory Data Consultants, Pamela Wehrmann 3:45 (460-7) Using SEDD Files with Web-Based Data Management Systems TODD PIERCE, Locus Technologies 4:05 (460-8) Stage 4 SEDD: A Challenge to the Analytical Community JOSEPH F SOLSKY, US Army Corps of Engineers 4:25 (460-9) Custom Database Application for Storage, Review, Management, and JOHN MORROW, Centers for Disease Control and Prevention, Robert Jones, Benjamin C Blount 4:45 (460-10) SEDD and Homeland Security JOHN NEBELSICK, US Army Corps of Engineers

POSTER SESSION

Session 480

Afternoon posters will be on display from 1:30 PM to 4:30 PM with authors present from 1:30 PM to 3:30 PM. The posters will be located on the Southeast corner of the Exposition floor (beginning Aisle 2900).

Atomic Spectroscopy: Environmental Applications

Monday Afternoon (480-1 P) Mercury Measurements: Overcoming Contamination and Interferences to Enable the Correct Measurements for Valued Judgments Using EPA 1631 PETER B STOCKWELL, P S Analytical Ltd., Warren T Corns, Derek W Bryce (480-2 P) Mercury Analysis in Solids, Liquids, and Gases on a Single Instrument JASON P GRAY, AGS Scientific, Inc., Koji Tanida, Alvin Chua (480-3 P) Determination of Inorganic Mercury by Flow Injection Cold Vapor Generation with Tin(II) Chloride Immobilized on an AnionExchanger with In-Atomizer Trapping by Electrothermal Atomic Absorption Spectrometry WIPHARAT CHUACHUAD, University of Massachusetts, Julian F Tyson (480-4 P) The Use of Atomic Fluorescence Spectrometry for Mercury Determination in the Petrochemical Industry WARREN T CORNS, P S Analytical Ltd. (480-5 P) Manganese Levels in Street Dust and Roadside Soil SHADUNG J MOJA, Tshwane University of Technology (480-6 P) Mercury Speciation in Flue Gas by Catalytic Converters MATTHEW A DEXTER, P S Analytical Ltd., Warren T Corns, Peter B Stockwell (480-7 P) Development and Application of a Flow Injection Hydride Generation Atomic Fluorescence Spectrometric (FI-HGAFS) Method for Determination of Total Arsenic in Hair Samples JON CLARK, Butler University, Olujide T Akinbo (480-8 P) Development of a Microwave Sample Preparation Method for Total Arsenic Determination in Edible Oils Using Flow Injection Hydride Generation Atomic Fluorescence Spectrometry (FI-HG-AFS) MEGAN BERGAUFF, Butler University, Olujide T Akinbo (480-9 P) Preconcentration and Speciation of Arsenic in Environmental Samples with Solid-Phase Extraction and FI-HGAAS KHALID H ALASSAF, University of Massachusetts, Marissa K Callahan, Julian F Tyson (480-10 P) Application of Factorial Design and Doehlert Matrix in Optimization Preconcentration Procedure for Cadmium Determination in Seawater by Flame Atomic Absorption Spectrometry ADRIANA C FERREIRA, SENAI-CETIND, Maria das Graas Korn, Srgio L Ferreira (480-11 P) Improving the Detection Limits of ICP-OES for Selenium by FI Sample Introduction Procedures PRINCESS HERNANDEZ, University of Massachusetts, Julian F Tyson, Peter C Uden, Dennis Yates

ORAL SESSION
Vibrational Spectroscopy: Monitoring of Materials and Processes II

Session 470

Monday Afternoon, Room S230A Mary A Kaiser, DuPont Corporate Center for Analytical Sciences, Presiding 1:30 (470-1) Application of Infrared Imaging for the Analysis of Polymer Defects JOHN WILSON, Digilab Europe Limited, Ellen V Miseo 1:50 (470-2) Sum Frequency Generation (SFG) Vibrational Spectroscopy Studies on Adhesion to Polymers CHERYL L LOCH, University of Michigan, Dongchan Ahn, Chunyan Chen, Zhan Chen 2:10 (470-3) Spectroscopic Studies on the Origin of Color Degradation in Polyfluorenes VASILIS GREGORIOU, FORTH-ICEHT, Christos Chochos, Georgia Kandilioti 2:30 (470-4) Infrared Imaging and Photoacoustic Spectroscopy for Analysis of Aged Wire Cladding KATHLEEN ALAM, Sandia National Laboratories, Dion Rivera 2:50 (470-5) Silane-Based Copolymers for Novel Sol-Gel Preparation SUNIL SONAWANE, University of Rhode Island, Jaycoda S Major 3:10 Recess 3:25 (470-6) NMR and IR Polymer Characterization: Practical Application and Analysis MARIE SCANDON, Bio-Rad Laboratories, Inc., Deborah Kernan 3:45 (470-7) Transfer of Gas Calibrations between FTIR Spectrometers RICHARD T MEYER, CIC Photonics, Inc., Jorge E Perez 4:05 (470-8) All Wave Number Miniature FT Spectrometer ALAN DOCTOR, City University of New York

54

(480-12 P) Atomic Absorption Detection of Tin and Tellurium Based on Hydride Technique ABDUMALIK Y KHUDAYBERDIEV, Samarkand Economy and Service Institute, Shahista A Ishniyazova (480-13 P) Withdrawn (480-14 P) A New Analytical System Based on Electrostatic Precipitation in a Furnace of Zeeman Spectrometer for Direct and Rapid Determination of Elements in Ambient Air and Exhaled Air NATALIJA B IVANENKO, Lumex Ltd., Alexander A Ganeev (480-15 P) Developing Standard Methods for Analysis for Arsenic, Selenium and Antominy PETER B STOCKWELL, P S Analytical Ltd. (480-16 P) Speciation of Arsenic in Cornish Soils DEREK W BRYCE, P S Analytical Ltd., Warren T Corns, Chris Hutton, Loveday Jenkin, Hylke J Glass

POSTER SESSION
Bioanalytical and Biomedical Analysis
Monday Afternoon

Session 500

(500-1 P) Scanning Electrochemical Microscopy Study of Molecular Transport through the Nuclear Pore Complex JIDONG GUO, University of Pittsburgh, Shigeru Amemiya (500-2 P) Determination of N-methyl Transfer from Drug to Lysine ILDIKO HOLLOSI, National Institute of Physical Education and Sport, Huba I Kalasz (500-3 P) Ultrafiltration of Bacteria and Virus Using Nano Alumina Fibers FRED TEPPER, Argonide Corporation, Leonid Kaledin (500-4 P) Withdrawn (500-5 P) Construction of DNA Aptamer Array on Nano-Well Electrode MAN BOCK GU, Gwangju Institute of Science and Technology, Yeon Seok Kim, Ho sup Jung, Hea Yeon Lee, Tomoji Kawaib (500-6 P) Photostability Study of Silica Nanoparticles JOSHUA K HERR, University of Florida, Chaoyong Yang, Weihong Tan (500-7 P) Analysis of Natural Flavonoids by Microchip-Micellar Electrokinetic Chromatography with Pulsed Amperometric Detection RICHARD W HOMPESCH, University of Colorado at Colorado Springs, Carlos D Garcia, David J Weiss, Jorge M Vivanco, Charles S Henry (500-8 P) Complete Scalability with a New Generation of Rigid Polymeric HPLC Particles JOHN A MCCONVILLE, Polymer Laboratories Inc., Linda L Lloyd, Keeley J Mapp, Adam J Croucher (500-9 P) mTHPC Encapsulated Nanoparticle Synthesis and in vitro Singlet Oxygen Production DE GAO, University of Michigan, Raoul Kopelman (500-10 P) Microsensors for Relevent Gases in Biomedical Research ZIAD TAHA, Innovative Instruments, Inc. (500-11 P) Investigation of Antivrous Action of Complex of Zn(II) with 2Amino-5-Phenyl-1,3,4-Tiadiazol SHAXNOZA KADIROVA, National University of Uzbekistan (500-12 P) Determination of Deracoxib in Feline Plasma Samples SHERRY COX, University of Tennessee, Jacob Roark, Adam Gassel, Karen Tobias (500-13 P) The Benefits of Ultra-Inert Stationary Phases for the ReversedPhase Analysis of Biomolecules KENNETH JONES, Advanced Chromatography Technologies, Carl L Zimmerman, Robert T Moody (500-14 P) Simultaneous Determination of Arg and Agmatine by Liquid Chromatography with Fluorescence Detection YANMING LIU, Institute for Drug Control (500-15 P) High Performance Affinity Columns for Antibody Purification SHAWN P WILLIAMS, Grace Vydac, Gonda Van Essche, Paul Garms, Ning Mu (500-16 P) Structures and Mechanical Properties of Self-Assembled Lipid Tubules Studied with Atomic Force Microscopy JIYU FANG, University of Central Florida, Nidhi Nahajan (500-17 P) Separation of Catecholamines and Dopamine-Derived DNA Adduct Using a Microfluidic Device with Electrochemical Detection ABDULILAH A DAWOUD, Iowa State University, Marc D Porter, Toshikazu Kawaguchi, Yuri Markushin, Ryszard Jankowiak

POSTER SESSION
Atomic Spectroscopy: General Posters
Monday Afternoon

Session 490

(490-1 P) Tungsten Coil Electrothermal Vaporization in Inductively Coupled Plasma Atomic Emission Spectrometry AMANDA DAVIS, Wake Forest University (490-2 P) Laser Ionization Time-of-Flight Mass Spectrometer with an Ion Guide JIAN HE, Los Alamos National Laboratory (490-3 P) Laser-Induced Breakdown Spectroscopy of Bulk Aqueous Solutions at Elevated Pressures MARION J LAWRENCE-SNYDER, University of South Carolina, Anna P Michel, Michael S Angel, Jonathan P Scaffidi (490-4 P) A Comparison of Methods to Determine the Temperature of Laser Induced Plasmas GALAN G MOORE, University of Florida, I B Gornushkin, Nicolo Omenetto, Benjamin W Smith, James D Winefordner (490-5 P) Developing Custom Programs for ICP Emission Spectrometry: Opening the Black Box JACQUES MOUTTE, Ecole Des Mines (490-6 P) A Method for the Determination of Trace Aluminum, Calcium, Magnesium, and Zinc Extractables Sourced from Irradiated Polypropylene Resin and Rubber Stopper Components in 0.9% Saline by Inductively Coupled Plasma - Atomic Emission Spectroscopy (ICP-AES) GREGORY W WHITE, Bracco Research USA, Julius P Zodda (490-7 P) Application of Atomic Vapor Resonance Ionization Imaging Detector NICHOLAS R TAYLOR, University of Florida, Benoit Lauly (490-8 P) In situ Elemental Analysis of Frog Eggs and Oocytes by LA-ICPMS ROBYN HANNIGAN, Arkansas State University, Khaled Machaca, Lu Sun (490-9 P) Determination and Speciation of Chromium in Human Urine Samples Using Selective Precipitation, Microwave Digestion and Graphite Furnace Atomic Absorption Spectrometry GASTON J. C. WU, National Taiwan Normal University, Jermiah Y. H. Shen, Jinn Rong Lu, Matt C. H. Chang (490-10 P) Separation and Quantitation of Arsenic Species in Food and Dietary Supplements by HPLC and ICP-MS SANG-HO NAM, FDA, John Cheng, Stephen G Capar (490-11 P) Redevelopment and Validation of an Air/Acetylene Flame Atomic Absorption Method for Low Level Quantitation of Iron in Insulin API MAHALAKSHMI V AMMACHATRAM, Eli Lilly and Company, Inc. (490-12 P) Using Spectrochemical Analysis to Solve an Ancient Numismatic Mystery CHRISTOPHER S EPSTEIN, Mount Saint Mary's College, Megan Daschbach, Michael Epstein, Nathan W Bower, David Hendin (490-13 P) When Radioactivity was Good: An Examination of the Radium Ore Revigator MICHAEL EPSTEIN, Mount Saint Mary's College, Danny Miles, Lee L Yu (490-14 P) Process Improvements in the Analysis of Plutonium Metal using an ICP-AES JOSEPH RODRIGUEZ, Los Alamos National Laboratory, David Gallimore, Randy Drake, Alex Martinez, Jeffrey Miller, Fran Martin (490-15 P) Evaluation of a Direct Injection Multi-Gas ICP Source for Elemental Analysis TAKAYUKI DOI, Tokyo Institute of Technology, Mizusawa Yoichi, Miyahara Hidekazu, Hotta Eiki, Okino Akitoshi (490-16 P) Study of Gas Flows in a Multi-Gas Inductively Coupled Plasma Source YOICHI MIZUSAWA, Tokyo Institute of Technology, Takayuki Doi, Hidekazu Miyahara, Eiki Hotta, Akitoshi Okino

POSTER SESSION
Drug Discovery
Monday Afternoon

Session 510

(510-1 P) How to Make the Best Better? Optimization of a High Throughput Purification Process XU ZHANG, ArQule, Inc., Bi Grace, Zhang Bailin, Marc Towle, Peter Tidswell, Wolfgang Goetzinger (510-2 P) Study on Sample Recovery in High Throughput Purification XU ZHANG, ArQule, Inc., Nicole Hosein, Wendy Picariello, Grace Bi, Aisha Siddiqua, Marc Towle, Wolfgang Goetzinger (510-3 P) From Analytical to Preparative HPLC: Workflow DANIEL ZIMMERLI, F. Hoffmann - La Roche Ltd., David Wechsler (510-4 P) Micro Parallel Liquid Chromatography (Micro Parallel Liquid Chromatography (PLC), a High-Throughput Variant of HPLC for Separation-Based Assays STEVE HOBBS, Nanostream, Paren Patel (510-5 P) Moisture and Trace Metal Impuritues in DNA Reagents and Their Effect on DNA Synthesis KALAKOTA S REDDY, Honeywell, Daniel J Todd

55

(510-6 P) Spectrophtometric Analysis as Sensor for Copper Ions Released from Styrene-Butadiene Rubber Formulations Containing Copper Sulphate Monohydrate FAHIMA M HELALY, National Research Centre (510-7 P) New Modified Bonded Macrocyclic Glycopeptide Chiral Stationary Phases with Enhanced Chiral Selectivity for Important Drugs and Drug Metabolites THOMAS E BEESLEY, Advanced Separation Technologies Inc. (Astec), J.T. Lee, Brian He (510-8 P) High Throughput Screening for Chiral Selectivity with a New Eight Column Parallel Screening System THOMAS E BEESLEY, Advanced Separation Technologies Inc. (Astec), Brian He, J.T. Lee, R.P.W. Scott (510-9 P) Chromatographic Analysis of Pegylated Protein Complexes with Evaporative Light Scattering Detection JEAN FREE, Alltech Associates, Inc. (510-10 P) Fast Screening of Zirconia Based Chiral Stationary Phases for Chiral Separations BINGWEN YAN, ZirChrom Separations, Inc., Clayton V McNeff, Peter W Carr, Thomas R Hoye (510-11 P) The Application of MS/MS Directed Purification to the Identification of Drug Metabolites in Biological Fluids ROBERT PLUMB, Waters Corporation, Warren Potts, Ronan Cleary, Paul M Lefebvre (510-12 P) The Application of Sub 2uM Porous Chromatographic Particles with Operating Pressures up to 15,000 PSI for Analysis of Pharmaceutical Compounds in Biological Fluids WARREN POTTS, Waters Corporation, Robert Plumb, Jose Castr-Perez, Kate Yu

POSTER SESSION
Pharmaceutical Analysis: LC Column Advances
Monday Afternoon

Session 530

(530-1 P) Evaluation of Reversed-Phase Sorbents for the On-line Desalting of Proteins by LC/MS PAUL RAINVILLE, Waters Corporation, Da Ren, Jeffrey R Mazzeo (530-2 P) LC/MS Analysis of Polar Compounds in High Organic Eluents RITU ARORA, Varian, Inc., Guang Q Li, Chris Lee, Dennis D Blevins (530-3 P) Novel Reversed-Phase Column for HPLC Separation of Relatively Highly Hydrophobic Substances with Subtle Structure Differences KATSUNORI TANIGUCHI, YMC Co., Ltd., Naohiro Kuriyama, Noriko Shoji, Masakatsu Omote (530-4 P) Pharmaceutical Metabolite Analysis Using 100% AqueousCompatible HPLC Stationary Phases CARMEN T SANTASANIA, Supelco/Sigma-Aldrich, Bei Chen, William Campbell, An Trinh, David S Bell (530-5 P) Novel C18 Reversed-Phase Columns for Small Pharmaceutical Compounds and Small Peptides DEREK W CHAN, Grace Vydac, Reno T Nguyen, Shawn P Williams (530-6 P) Enhanced Sensitivity and Quantitation by Obtaining Symmetrical Peak Shapes for Basic Pharmaceuticals MARK WOODRUFF, Thermo Electron Corporation, Charlotte Blythe, Harold Ritchie (530-7 P) A Highly Stable Cyano Phase for HPLC Analysis YIZHU GUO, Alltech Associates, Inc., Dennis McCreary, Raaidah Saari-Nordhaus (530-8 P) The Analysis of Compounds with Diverse Polarity Using Difunctionally Bonded C18 Column Technology under Typical Reverse Phase High-Performance Liquid Chromatography Conditions BRIAN P AXE, Eli Lilly and Company, Inc., Joseph A Turpin (530-9 P) Choosing an HPLC Stationary Phase to Optimize Selectivity for Polar versus Non-Polar Analytes WILLIAM E BARBER, Agilent Technologies, Inc., Maureen Joseph, Alan P Broske, Susan M Trzonkowski (530-10 P) Effect of Buffer Concentration on HPLC Retention of Charged Analytes YURY ZELECHONOK, SIELC Technologies, Tatiana Kochman (530-11 P) The Characteristics of New ODS Column for Polar Compound Analysis NISHI TOSHIAKI, TOSOH, Yamasaki Hiroyuki, Oguma Tukasa, Thomas J Higley, Nakatani Shigeru (530-12 P) Method Validation Characteristics of Gradient Capillary LC Analyses of Compounds of Pharmaceutical Interest: Are We There Yet? DAVID E HUGHES, Chromatographic Excellence, David Rakestraw, Ring-Ling Chien

POSTER SESSION
Monday Afternoon

Session 520

Pharmaceutical Analysis of Volatile Chemicals and Impurities

(520-1 P) Developing One Universal Method for Residual Solvents: How an Optimized Headspace Gas Chromatography Method Can Save Time and Money MARK E KRIGBAUM, Teledyne Instruments - Tekmar, Brian T Wallace (520-2 P) Develop and Validate the GC Method for the Determination of Residual Solvents in Beclomethasone 17, 21-Dipropionate Active Pharmaceutical Ingredient LIWEN YE, Dey, L.P., Jill Brians, Judson King, Muhammad Asif (520-3 P) Analysis of Residual Solvents in Pharmaceuticals Using Vacuum Fast Analysis by Static Headspace GC/MS JASON S COLE, Thermo Electron Corporation, Jessie Butler, Meredith Conoley, Eric Phillips, Trisa C Robarge (520-4 P) Headspace Analysis in Characterization of Pharmaceuticals OLGA BERSHEVITS, ACS Labs, Michael Markelov (520-5 P) Reduce Cleaning Validation Time and Costs by Implementing Total Organic Carbon Analysis BRIAN T WALLACE, Teledyne Instruments Tekmar (520-6 P) Novel Methods for HPLC Determination of Degradation Products in Topical Gels PETR SOLICH, Charles University - Prague, Ludmila Matysova, Lucie Novakova, Dagmar Solichova (520-7 P) Techniques for Reducing Run Times in Drug Substance Impurity Methods by Employing New LC Column and Instrument Technologies BRYAN CASTLE, Eli Lilly and Company, Inc., David P Myers, Matthew Earley (520-8 P) Evaluation of 1.7 Micron Particle Columns in a High Pressure Mode for Drug Substance Impurity Analysis DAVID P MYERS, Eli Lilly and Company, Inc., Bryan Castle, Timothy E Aldridge, Matthew Earley, David Linson, Linzhe Liu, Cynthia McCurry, Diane E Smith (520-9 P) Fast Analysis of Active Pharmaceutical Ingredients and Their Primary Degradants Using Nano-LC TODD D MALONEY, Pfizer, Inc., Gregory K Webster, Peter D Angus (520-10 P) Development of Methodology for the Analysis of 4Bromobenzenesulfonyl Chloride PAUL M MASON, Albany Molecular Research Inc. (520-11 P) Withdrawn (520-12 P) Analysis of Volatile Compounds of Dry Angelica Sinensis XUE-LI SU, Jingmen College

POSTER SESSION
Pharmaceutical Analysis: Novel Analytical Techniques
Monday Afternoon

Session 540

(540-1 P) Rapid Catalytic Formation of Nitroxides of Pharmaceutical Drug Molecules for HPLC Method Development LI LI, Merck & Co., Inc., Eric D Nelson (540-2 P) Oxidative Degradation Kinetics and Associated Effects of Oxygen Consumption Using AIBN and ACVA as Forced Degradation Model Systems RENEE C SZYMANIK, Merck & Co., Inc., Eric D Nelson, Martin G Teresk, Li Li, Randal A Seburg (540-3 P) On-line Electrochemistry/Mass Spectrometry for Studies of Clozapine Oxidation SUZE M VAN LEEUWEN, University of Twente, JeanMichel Kauffmann, Uwe Karst (540-4 P) Throughput Enhancement in 2-D Nano LC/MS/MS for the Analysis of Caenorhabditis elegans Proteome EMMANUEL VARESIO, LC Packings, Viviane Tschaeppaet (540-5 P) Applications of a Novel Flame Ionisation Detector for Liquid Chromatography ROGER M SMITH, Phlogiston Scientific Ltd, Joanne R Bone, Barry L Sharp (540-6 P) Multiplexed LC Separations and Fraction Collection with Nanospray and MALDI Ionization for Drug Metabolism Studies REMCO SWART, LC Packings, Mark van Gils (540-7 P) Water-Only HPLC Separations with Universal Flame Ionization Detection Using the Aquachrom Green Machine STEPHANIE J MARIN, Selerity Technologies, Brian A Jones, Jody Clark, Dale Felix, John Rizzo (540-8 P) Electronic Nose and Tongue: Innovative Tools to Speed Up Formulation Development VINCENT SCHMITT, Alpha M.O.S. America, Marielle Garnier

56

(540-9 P) A Simple Infrared Method for Characterizing the Polymorphic States of Tolfenamic Acid ROGER K GILPIN, Wright State University, Wanlong Zhou (540-10 P) Thermal Analysis and Calorimetry under Relative Humidity for the Investigations of Pharmaceutical Materials PIERRE M LE PARLOUER, Thermal Consulting, Jacques Cattiaux, Ignatius Chan (540-11 P) The Improvement of Solvent Flow Rate Accuracy for Normal Phase HPLC YOSHIAKI ASO, Shimadzu Corporation, Teruhisa Ueda, Masami Tomita (540-12 P) Application of Polymeric Surfactants for Enantioseparation and ESI-MS Detection of Chiral Benzodiazepines JINGGUO HOU, Georgia State University, Syed A Rizvi, Jack Zheng, Shahab A Shamsi (540-13 P) Monitoring Formation of Maillard Reaction Products (MRP) from Over- the-Counter Glucosamine Dietary Supplements by Capillary Electrophoresis PAULA F S, ANVISA, Xinfeng Zhang, Joel A Dain (540-14 P) Determination of Captopril in Pharmaceuticals by Capillary Electrophoresis MARIE POSPISILOVA, Charles University - Prague, Miroslav Polasek, Jiri Safra (540-15 P) Study of Binding Constants between a Drug Candidate and Various Cyclodextrins by Capillary Electrophoresis SEEMA TOMER, Novartis Pharmaceuticals, Qing Tang (540-16 P) Directing Molecular Crystal Growth with Self-Assembled Monolayers RUPA HIREMATH, Georgetown University (540-17 P) HPLC Analysis of Selected Herbal Formulations using Evaporative Light Scattering Detection ALISON MCHUGH, Polymer Laboratories, Ltd. (540-18 P) Spectrophotometric Determination of Magnesium in Pharmaceutical Preparations by Cost-Effective Sequential Injection Analysis ZERIET O TESFALDET, University of Pretoria (540-19 P) The Analysis of Aminoglycoside Antibiotics by LC-EC HENDRIK-JAN BROUWER, , Cees van Valkenburg, Nico Reinhoud (540-20 P) Orthogonal HPLC Method Development for the Determination of Polar Pharmaceuticals and Impurities XIANDE WANG, Johnson & Johnson PRD

POSTER SESSION
Toxicology/Clinical Chemistry
Monday Afternoon

Session 560

(560-1 P) Analysis of Biological Specimens Following Toxic Chemical Exposures STEVE C CORDERO, Uniformed Services University of Health Sciences, Thuy T Luong, Esta Tamanaha, Suzie Tsukerman (560-2 P) Withdrawn (560-3 P) Preparation of Bone Lead Reference Materials for Validating Kshell X-ray Fluorescence Spectrometry (KXRF): Cross-Validation with Analytical Atomic Spectrometric Techniques KATHERINE M HETTER, State University of New York at Albany, Patrick J Parsons, Andrew C Todd, Neeta Ginde (560-4 P) Simultaneous Determination of Amphetamines and Their Metabolites LIMING PENG, Phenomenex, Inc., Tivadar Farkas (560-5 P) Simultaneous Determination of Corticosteroids in Urine and Plasma LIMING PENG, Phenomenex, Inc. (560-6 P) Use of Saliva Enzymatic Alcohol Test Device for the Identification and Quantitation of Alcohol in Urine JOHN VASILIADES, Tox Labs, Kristin Colonna (560-7 P) Analysis of Benzodiazepines from Urine by Mixed-Mode Solid Phase Extraction and GC-MS MARK A WAKSMONSKI, Alltech Associates, Inc. (560-8 P) The Development of an Improved LC-MS/MS Analysis for the Opioids Fentanyl and Loperamide in Plasma JOHN C HODGIN, Alcott Chromatography, Inc. (560-9 P) Analysis of Ephedra Alkaloids by Capillary Gas Chromatography ROBERT T WIEDEMER, Alltech Associates, Inc. (560-10 P) Fast and Simple Separation of D- and L-Serine and Two Derivatives on Chiral Anion Exchangers STEFAN LAMOTTE, Bischoff Chromatography, Gerald Reindl, Rainer Brindle, Klaus D Bischoff (560-11 P) Use of FT-IR Spectroscopy to Diagnose Cancer In-situ and Invivo QINGBO LI, Peking University, Yizhuang Xu, Zhi Xu, Nengwei Zhang, Lixin Wang, Su Zhou, Limin Yang, Yuanfu Zhang, Jinguang Wu (560-12 P) Spectrophotometric Analysis of Cellular Uptake of Fluorescent Microprobes RICHARD J WILLIAMS, Morgan State University, Dwayne A Hill (560-13 P) Method of Iron, Zinc and Copper Content Determination in Condensed Moisture of Breathed Out Air, Sputum and Blood in Patient with Pulmonary Pathology FAZLITDIN S TADJIEV , Samarkand State Medical Institute, Abdurasul K Kurbanov (560-14 P) Quadrupole GC/MS Quantification of Fragrance Allergens JASON S COLE, Thermo Electron Corporation, Jessie Butler, Meredith Conoley, Eric Phillips, Robarge C Trisa (560-15 P) Determination of Formaldehyde, NOx, Mercury, and Other Undesirable Chemicals Evolving from Regular Construction Materials MICHAEL MARKELOV, ACS Labs, Olga Bershevits (560-16 P) Measurement of Uranium-DNA Adducts by Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES) JACOB T SHELLEY, Northern Arizona University, Adam Ashby, Diane Stearns (560-17 P) Fluorescence Detection of Enzymatic Activity within a Liposome Based Nano-Biosensor VICKY VAMVAKAKI, University of Crete, Nikos Chaniotakis

POSTER SESSION
Pharmaceutical Analysis: Sample Preparation
Monday Afternoon

Session 550

(550-1 P) New Weak Cation and Anion Exchange SPE Materials for Enhanced Sample Clean-Up DIANE M DIEHL, Waters Corporation, Ziling Lu, Jeffrey R Mazzeo (550-2 P) In-Valve Extraction Cartridge Designed for Microcolumn Liquid Chromatography MOTOHIRO IMAIZUMI, Toyohashi University of Technology, Yoshihiro Saito, Hiroo Wada, Kiyokatsu Jinno (550-3 P) Decreasing the Analysis Time of Pharmaceutical Solvents with SPME KATHERINE L STENERSON, Supelco, Inc., Robert E Shirey, Leonard M Sidisky (550-4 P) Withdrawn (550-5 P) Assay of Stability, Free and Total Concentration of Chlorhexidine in Saliva by Solid Phase Microextraction FLORIN MARCEL MUSTEATA, University of Waterloo, Janusz B Pawliszyn (550-6 P) The Extraction of the Silybin from Milk Thistle Seeds by Parallel Pressurized Solvent Extraction ROLF SCHLAKE, Applied Separations (550-7 P) Preparative HPLC: Factors and Parameters that Directly Affect Recovery of Collected Fractions JOAN M STEVENS, Gilson, Inc., Luke Roenneburg, Gary Scharrer, Alan Hamstra (550-8 P) Fast PCLC: A Widely Applicable Technique for LaboratoryScale Preparative Separations JOAN M STEVENS, Gilson, Inc., Gary Scharrer, Luke Roenneburg (550-9 P) Determining the Cloud Point, Solubility, Swelling and Crystallization Properties of Materials in Supercritical Carbon Dioxide KENNETH J JAMES, Supercritical Fluid Technologies, Inc., David Chesney, Jennifer Lefler (550-10 P) Quantification of Active Pharmaceutical Ingredients on Metal Surfaces Using mid-IR Grazing Angle Fiber Optics Probe - An In-situ Cleaning Verification Process NOEL TEELUCKSINGH, Novartis Pharmaceuticals, K. Bal Reddy (550-11 P) The Potential of Combining Solid Phase Optosensing and Multicommutation Principles for Routine Analyses of Pharmaceuticals JUAN F GARCIA-REYES, University of Jaen, Eulogio Llorent-Martnez, Pilar Ortega-Barrales, Antonio Molina-Daz

TUESDAY, MARCH 1, 2005

SYMPOSIUM
PPG Industries, Inc. Tuesday Morning, Room S210A Amit Ghosh, PPG Industries, Inc., Presiding 8:30 Introductory Remarks - Amit Ghosh Session 570

Pittsburgh Analytical Chemistry Award - arranged by Amit Ghosh,

8:35 Presentation of the 2005 Pittsburgh Analytical Chemistry Award to James W Jorgenson, University of North Carolina, by Janeth Pifer, The Society for Analytical Chemists of Pittsburgh 8:40 (570-1) Capillaries and Chemical Analysis JAMES W JORGENSON, University of North Carolina at Chapel Hill

57

9:15 (570-2) Analytical and Separation Chemistry of Metal Quantum Dots ROYCE W MURRAY, University of North Carolina at Chapel Hill 9:50 (570-3) Recent Advances in High-Sensitivity Glycoprotein Analysis MILOS V NOVOTNY, Indiana University, Yehia Mechref, Pilsoo Kang, Milan Madera 10:25 Recess 10:40 (570-4) Micro- and Nanofabricated Devices for Chemical Experimentation J MICHAEL RAMSEY, University of North Carolina at Chapel Hill 11:15 (570-5) Affinity Interactions in Capillary Electrophoresis ROBERT T KENNEDY, University of Michigan

9:45 (600-3) Coulter Counting Using Carbon Nanotubes LI SUN, Texas A&M University, Takashi Ito, Ronald Henriquez, Richard M Crooks 10:20 Recess 10:35 (600-4) Electrophoretic Trapping of Single Nanoparticles above the Opening of a Membrane Pore HENRY S WHITE, University of Utah, Ryan J White, Eric N Ervin, Sungwon Lee, Yanhui Zhang 11:10 (600-5) Application of Scanning Electrochemical Microscopy in the Investigation of Nanopores CYNTHIA G ZOSKI, Georgia State University

SYMPOSIUM
Aptamers: Novel Molecular Probes for Genomics and Proteomics - arranged by Weihong Tan, University of Florida
Tuesday Morning, Room S220E Weihong Tan, University of Florida, Presiding 8:30 Introductory Remarks - Weihong Tan

Session 610

SYMPOSIUM

Session 580

Advanced Carbon Materials for Chemical and Biological Sensing - arranged by Greg M Swain, Michigan State University
Tuesday Morning, Room S230G Greg M Swain, Michigan State University, Presiding 8:30 8:35 (580-1) Introductory Remarks - Greg M Swain TBA

8:35 (610-1) DNA Aptamers and DNA Enzymes with Fluorescence-Signaling Properties YINGFU LI, McMaster University 9:10 (610-2) CE-SELEX: In Vitro Evolution of DNA Aptamers Using Capillary Electrophoresis MICHAEL T BOWSER, University of Minnesota 9:45 (610-3) Directed Proteomics: "Selection" of Cellular proteins Using Genomic-Inspired DNA LINDA B MCGOWN, Rensselaer Polytechnic Institute, Adam C Connor, Lawrence W Dick 10:20 Recess 10:35 (610-4) Single-Stranded DNA Aptamers that Bind Differentiated but Not Parental Cells: Subtractive SELEX NINGSHENG SHAO, Beijing Institute of Basic Medical Sciences 11:10 (610-5) Clinical Diagnostics through Aptamer Arrays LARRY GOLD, SomaLogic, Inc.

9:10 (580-2) Tailor-Made Carbon Surfaces for Electrochemical Analysis Based on Covalent Bonding to Unusual Graphitic Substrates RICHARD L MCCREERY, Ohio State University, Franklin Anariba, Hong Tian 9:45 (580-3) Chemically Modified Diamond Thin Films as an Interface to Biology ROBERT J HAMERS, University of Wisconsin at Madison 10:20 Recess 10:35 (580-4) Detecting Biomolecules with Nanoscale Active Electronic Devices GEORGE GRUNER, University of California at Los Angeles 11:10 (580-5) Optically Transparent Diamond Electrodes for Chemical Analysis GREG M SWAIN, Michigan State University, Jerzy Zak, Jason Stotter, Yoshiyuki Show, Shannon M Haymond

SYMPOSIUM

Session 620

SYMPOSIUM
arranged by Akbar Montaser, The George Washington University Tuesday Morning, Room S220B Akbar Montaser, The George Washington University, Presiding 8:30 Introductory Remarks - Akbar Montaser

Session 590

Industrial Polymer Characterization - arranged by Andrea E Croslyn, GE Plastics and Jessica L. Jarman, GE Plastics
Tuesday Morning, Room S210E Andrea E Croslyn, GE Plastics, Presiding 8:30 Introductory Remarks - Andrea E Croslyn

Advances in Inductively Coupled Plasma Mass Spectrometry -

8:35 (590-1) Advances in Solution Introduction in ICP Spectrometry: Applications, Devices, and Fundamentals AKBAR MONTASER, The George Washington University 9:10 (590-2) Capabilities of ICP-MS to Vaporize Laser Generated Aerosols DETLEF GNTHER, ETH Zurich 9:45 (590-3) More Intense Ion Beams from the ICP DONALD DOUGLAS, University of British Columbia, Samir Al Moussalami, Chuanfan Ding 10:20 Recess 10:35 (590-4) Fundamental Characterization of the ICP/MS Interface for Improved Instrument Performance PAUL B FARNSWORTH, Brigham Young University, Jeffrey H Macedone, Andrew A Mills 11:10 (590-5) Multi-element Ion Detection Systems and a Double Focusing Focal Plane Mass Spectrometer for ICP-MS Applications MAHADEVA P SINHA, Jet Propulsion Laboratory, Mark Wadsworth

8:35 (620-1) Spectroscopic Imaging Techniques for Characterizing Industrial Polymers JACK L KOENIG, Case Western Reserve University 9:10 (620-2) Challenges in Polymer Characterization Using Mass Spectrometry CHARLES N MCEWEN, DuPont 9:45 (620-3) Practical Applications of Raman Spectroscopy for Process Analysis BRIAN J MARQUARDT, University of Washington, Brian Dable, David Veltkamp 10:20 Recess 10:35 (620-4) Polymer Rheology: Some Basics and Why It Is so Important Industrially GARTH L WILKES, Virginia Polytechnic Institute and State University 11:10 (620-5) Near Infrared Spectroscopy in the Polymer Industry: Applications from Raw Materials to Finished Molded Products JESSICA T JARMAN, GE Advanced Materials, Randy Bishop

SYMPOSIUM

Session 630

SYMPOSIUM
Georgia State University Tuesday Morning, Room S220F Cynthia G Zoski, Georgia State University, Presiding 8:30 Introductory Remarks - Cynthia G Zoski

Session 600

Single Molecule Detection and Spectroscopy: A 15-Year Perspective - arranged by Steven A Soper, Louisiana State University
Tuesday Morning, Room S230B Steven A Soper, Louisiana State University, Presiding 8:30 Introductory Remarks - Steven A Soper

Analytical Applications of Nanopores - arranged by Cynthia G Zoski,

8:35 (630-1) Learning to Count Molecules J MICHAEL RAMSEY, University of North Carolina at Chapel Hill 9:10 (630-2) Real-Time Dynamics of Single Native DNA and Protein Molecules in Solution EDWARD S YEUNG, Iowa State University, Hung-Wing Li, Seong Ho Kang, Seungah Lee, Yan He

8:35 (600-1) Biosensing with Nanotube Membranes CHARLES R MARTIN, University of Florida 9:10 (600-2) Molecular Sensing Using an On-Chip Artificial Pore LYDIA L SOHN, University of California at Berkeley

58

9:45 (630-3) Sorting Single Molecules in Laminar Flow RUDOLF H RIGLER, Karolinska Institutet 10:20 Recess 10:35 (630-4) Ultrasensitive Detection of GFP Fusion Proteins in Single Yeast Cells NORMAN J DOVICHI, University of Washington 11:10 (630-5) Efficient Single-Molecule Detection in Fluid Solution: RICHARD A KELLER, Los Alamos National Laboratory

ORAL SESSION
Tuesday Morning, Room S220D Charles J Belle, Stork Herron Testing Laboratories, Presiding

Session 660

Atomic Spectroscopy: Equipment/Method Improvements

8:30 (660-1) Ion Molecule Reactions to Overcome Spectral Overlaps in ICP-MS: Chemistry, Strategies and Unique Applications JOHN W OLESIK, The Ohio State University, Deanna R Jones, Greg Drozd 8:50 (660-2) A Microwave Induced Plasma Coupled to a Time-ofFlight Mass Analyzer for Rapid Elemental Speciation by Gas Chromatography STEVEN J RAY, Indiana University, Gary M Hieftje 9:10 (660-3) Optical Optimisation in the Use of Array Detectors for ICP-OES MICHAEL P WASSALL, Thermo Electron Corporation, Charles V Perkins 9:30 (660-4) Electrostatic Particle Sampler (EPS) for Elemental Analysis of Airborne Micro-size Particles by In-torch VaporizationInductively Coupled Plasma-Atomic Emission Spectrometry (ITV-ICP-AES) VASSILI KARANASSIOS, University of Waterloo, Greg Sprah, Cathy Zhao 9:50 (660-5) Standardized, Plug and Play ICP-OES Using Chemometric Modeling OLAF SCHULZ, Spectro Analytical Instruments GmbH & Co. KG, Dirk Ardelt 10:10 Recess 10:25 (660-6) Comparisons of Collinear and Orthogonal Femtosecond/Nanosecond Dual-Pulse LIBS JONATHAN P SCAFFIDI, University of South Carolina, William F Pearman, Jerry Chance Carter, Bill W Colston, Michael S Angel 10:45 (660-7) Microchip and Powerchip Lasers as Sources for Laser Induced Breakdown Spectroscopy K AMPONSAH-MANAGER, University of Florida, Cristina Lopez-Moreno, I B Gornushkin, Benjamin W Smith, Nicolo Omenetto, James D Winefordner 11:05 (660-8) Investigation of Statistics for Improving the Discriminating Power of Laser Induced Breakdown Spectroscopy (LIBS) CHASE A MUNSON, US Army Research Laboratory, Frank C DeLucia, Thuvan N Piehler, Kevin L McNesby, Andrzej W Miziolek 11:25 (660-9) Trace Aluminum Determination by Electrospray Laser-induced Breakdown Spectroscopy Coupled with Flow-injection Preconcentration System JER-SHING HUANG, Institute of Atomic and Molecular Science, King-Chuen Lin 11:45 (660-10) Analytical Approaches to Characterize Lead in Copper-based Alloys by Laser Induced Breakdown Spectroscopy SUHJEN J TSAI, Providence University, Shi-Yang Chen, Yao-Shen Zhong

WORKSHOP
Thomas J Wenzel, Bates College Tuesday Morning, Room S220C Thomas J Wenzel, Bates College, Presiding 8:30

Session 640

Problem-Based Learning in Analytical Chemistry - arranged by

Introductory Remarks - Thomas J Wenzel

8:40 (640-1) Why Use Cooperative and Problem-Based Learning? THOMAS J WENZEL, Bates College 8:55 (640-2) When Biology is Chemistry: A Case Study in Problem-Based Learning GEORGE S WILSON, University of Kansas, Nick Dickenson, William D Picking 9:10 (640-3) TBA 9:25 (640-4) Crime Solvers in the Analytical Lab ROBERT Q THOMPSON, Oberlin College 9:40 (640-5) Your Education as a Chemist Should Never Fail You GLENN D BOUTILIER, Procter & Gamble 9:55 10:10 Recess Panel/Participant Discussion

ORAL SESSION
Applications in Gas Chromatography
Tuesday Morning, Room S220G James Manner, PPG Industries - Retired, Presiding

Session 650

8:30 (650-1) Biomarkers for Characterization of Gram Negative and Gram Positive Bacteria by Coupling Pyrolysis Gas Chromatography to Ion Mobility Spectrometry SATENDRA PRASAD, New Mexico State University, Gary A Eiceman, Hartwig Schmidt 8:50 (650-2) Pyrolysis Gas Chromatography with MicroFabricated Differential Mobility Spectrometry: A Powerful Combination for a Fast and Sensitive Characterization of Bacteria HARTWIG SCHMIDT, New Mexico State University, Gary A Eiceman 9:10 (650-3) A Fully Automated Purge and Trap GC Analyzer for Monitoring Trihalomethanes in Drinking Water Distribution Systems MICHAEL A BROWN, The University of Memphis, Gary L Emmert 9:30 (650-4) Stability of Analytical Reference Materials and High Resolution Gas Chromatography for US EPA Method 551.1 KATIA M MAY, Restek Corporation, Gregory France, Andrew Stearns, John Lidgett 9:50 (650-5) Practical Approaches to Elimination or Compensation for Adverse Matrix Effects in Gas Chromatographic Analysis of Pesticides and Other Susceptible Analytes KATERINA MASTOVSKA, USDA, Steven J Lehotay, Tomas Cajka 10:10 Recess 10:25 (650-6) GCxGC-ECD of Organochlorine Pesticides JACK COCHRAN, LECO Corporation, Frank L Dorman 10:45 (650-7) Photoionization Differential Ion Mobility Spectrometer as a Gas Chromatographic Detector for Volatile Organic Compounds PRESHIOUS REARDEN, Ohio University, Peter B Harrington 11:05 (650-8) UltraFast (<3 minutes) Simulated Distillation of Petroleum Fractions According to ASTM FRANK P DI SANZO, ExxonMobil Research & Engineering, John Diehl, Riccardo Facchetti, Flavio Bedini 11:25 (650-9) Micro-fabricated Separation Columns for the Analysis of Organic Compounds in Atmospheric Vapor Samples GORDON R LAMBERTUS, University of Michigan, Shaelah M Reidy, Richard D Sacks 11:45 (650-10) Instrument and Material Considerations in the Analysis of Low Level NO and NO2 BRUCE TALBERT, Air Liquide, Malik Haouchine, Tracey Jacksier

ORAL SESSION

Session 670

Characterization of Pharmaceuticals by Spectroscopic and Imaging Techniques

Tuesday Morning, Room S230D Alice Riggin, Eli Lilly and Company, Presiding 8:30 (670-1) Identification of the Polymorphs of Sulfathiazole Using Terahertz Pulsed Spectroscopy PHILIP F TADAY, TeraView Limited, David A Newnham, Yaochun Shen, Clare J Strachan 8:50 (670-2) NIR: Practical Implementation in Pharmaceutical Analytical Development YONG WANG, Novartis Pharmaceuticals, Lakshman Parthiban, Michael Zheng, Rosario LoBrutto, Subash Patel, Bal Reddy, Richard Vivilecchia 9:10 (670-3) Particle Size Measurements by Automated Image Analysis MONIQUE DALLAIRE, ASM Member 9:30 (670-4) A Novel Silica Nanoparticles-Based Drug Delivery System Triggered by Antimicrobial Peptides LI CHEN, University of New Orleans, Zeev Rosenzweig 9:50 (670-5) Analysis of Residual Metals and Organometallics in Pharmaceuticals by High Performance Liquid Chromatography with Inductively Coupled Plasma Mass Spectrometry (HPLC-ICP-MS) MATTHEW A LORENZ, Pfizer, Inc., Daphne D Wang, Peter D Angus 10:10 Recess 10:25 (670-6) Recent Uses of Laser-Induced Breakdown Spectroscopy for the Direct Analysis of Solid and Non-solid Pharmaceutical Products LOUIS ST-ONGE, National Research Council of Canada (IMI), Martine Tourigny, Mohamad Sabsabi 10:45 (670-7) How Modern Optics Have Changed the Face of Pharmaceutical Powder X-ray Analysis BRIAN LITTEER, PANalytical, Inc.

59

11:05 (670-8) Near-IR and Raman Chemical Imaging Assesses Content Uniformity in Tablets MATTHEW P NELSON, ChemImage Corporation, Oksana Klueva, Patrick J Treado 11:25 (670-9) Withdrawn 11:45 (670-10) Spectral Informatics and Automated Sampling for High Throughput Raman Spectroscopy STEPHEN R LOWRY, Thermo Electron Corporation, Dave Dalyrmple, Garry L Ritter

ORAL SESSION
Fuel and Petrochemicals Analysis Methods and Instrumentation
Tuesday Morning, Room S230A Susan S Marine, Miami University Middletown, Presiding

Session 700

ORAL SESSION
Compliance Perspectives of LIMS
Tuesday Morning, Room S210B Douglas Perry, Indiana University School of Informatics, Presiding

Session 680

8:30 (700-1) Improved Analysis of Sulfur Compounds in Gasoline and Diesel Matrices Using the Pulsed Flame Photometric Detector (PFPD) LAURA CHAMBERS, O. I. Analytical, Michael L Duffy 8:50 (700-2) A New Miniaturized Gas Chromatography System for Online Analysis of Dissolved Gases in Electrical Insulating Fluids JOHN V HINSHAW, Serveron Corporation, Dan Morgan, Thomas Waters 9:10 (700-3) Multivariate Techniques in the Optimisation of Method for Direct Determination of Copper in Oil Condensate Using Graphite Furnace Atomic Absorption Spectrometry WALTER NEI L SANTOS, Universidade Federal da Bahia, Sergio Luis C Ferrreira, Marcelo S Fernandes, Fabio S Dias, Marcio V Rebouas 9:30 (700-4) Automated Measurement of Base Number by Potentiometric Titration ASTM D2896 TIFFANY REID, Man-Tech Associates Inc., Robert V Menegotto, Christopher Smith 9:50 (700-5) Development of a Test Method to Determine Swell and Expansion Potential in CCBs DAVID J HASSETT, UND Energy & Environmental Research Center, Erick J Zacher 10:10 Recess 10:25 (700-6) Evaluation of Oxidative Stabilities of Stabilized and Unstabilized Biogenic Oil Esters RACHADAPORN SEEMAMAHANNOP, University of Missouri-Rolla, Honglan Shi, Ranjith Kolli, Shubhen Kapila, Virgil Flanigan 10:45 (700-7) Methods for Selecting Gas Calibration Standards CHRISTOPHER E ROWLEY, Airgas, Inc., Daniel Bartel 11:05 (700-8) New and Novel Membrane Devices for Selective Removal or Addition of Water into Gases, Liquids and Solids JACK KERTZMAN, Kertzman Systems, Inc. 11:25 (700-9) A Comparative Study of Diesel Analysis by FTIR, FTNIR and FT-Raman Spectroscopy Using PLS and Artificial Neural Network Analysis JOEL C RUBIM, Universidade de Brasilia, Vianney O Santos, Flavia C Oliveira, Edgardo Garcia, Paulo A Z Suarez 11:45 (700-10) Fast Temperature Programming with Accessory Heaters for Conventional GC Ovens STEPHEN J MACDONALD, Zip Scientific

8:30 (680-1) Achieving and Maintaining Regulatory Compliance through Deployment of Enterprise LIMS EDWARD INGALLS, Thermo Electron Informatics & Services 8:50 (680-2) LIMS and the Content Regulatory Compliance Landscape CHRISTINE PASZKO, Accelerated Technology Laboratories, Inc., Manoucher Shahamat 9:10 (680-3) Establishment of Electronic Reporting Electronic Records-Proposed Rule CROMERRR and LIMS STEVE RAYBURN, Accelerated Technology Laboratories, Inc., Manoucher Shahamat 9:30 (680-4) Automatic Notification and its Role in Compliance Monitoring Requirements STEVE RAYBURN, Accelerated Technology Laboratories, Inc., Anson Ellstrom 9:50 (680-5) Publishing Analytical Instrument Data over Networks with AnIML PETER J LINSTROM, National Institute of Standards and Technology

ORAL SESSION
Electrochemistry: Neurochemical Applications
Tuesday Morning, Room S230C Paul A Garris, Illinois State University, Presiding

Session 690

8:30 (690-1) Miniaturized Wireless Device for Fast-Scan Cyclic Voltammetry, Single Unit Electrophysiology and Electrical Stimulation in Behaving Rats PAUL A GARRIS, Illinois State University, Robert Ensman, John Poehlman, Andrew Alexander, Paul Langley, Alfred Strickholm, Stefan G Sandberg, Rebec V George 8:50 (690-2) Analysis of Facilitation and Depression of Dopamine Neuronal Release JUSTIN M KITA, University of North Carolina at Chapel Hill, Paul E M Phillips, Paul A Garris, R. Mark Wightman 9:10 (690-3) Modified Electrodes for Mediated Electron Transport: Detection of Glucose and Glutamate ALICE C HARPER, Virginia Tech, Mark Anderson 9:30 (690-4) Improved Dopmaine Detection at Modified Carbon Fiber Microelectrodes ANDRE HERMANS, The University of North Carolina at Chapel Hill, R. Mark Wightman 9:50 (690-5) Diamond Microelectrodes for the In Vitro Measurement of Neurotransmitters JINWOO PARK, Michigan State University, James J Galligan, Greg D Fink, Greg M Swain 10:10 Recess 10:25 (690-6) Fluorescence Techniques in the Characterization of Dopaminergic Neurons MICHAEL A JOHNSON, University of North Carolina at Chapel Hill, R. Mark Wightman 10:45 (690-7) Voltammetry in the Brain for Investigating the Mechanism of Dopamine Release After Uptake Inhibition LAURA M BORLAND, University of Pittsburgh, Adrian C Michael 11:05 (690-8) Combined Iontophoresis and Voltammetry for Localized Modulation of in vivo Dopamine Release ANDREW T SEIPEL, University of North Carolina at Chapel Hill, R. Mark Wightman 11:25 (690-9) Catalyzed Oxidation of Catechols on Enzyme-Doped, Poly(vinylpyridine)-Based Os Films Applied to Carbon Fiber Microelectrodes JOSEPH J MITALA, University of Pittsburgh, Adrian C Michael 11:45 (690-10) Evaluation of Cholinergic Function by Capillary Electrophoresis Using Electrochemical Detection TATYANA V BARKHIMER, The University of Toledo, Jon Kirchhoff, Richard A Hudson , William S Messer

ORAL SESSION
Organics in the Environment
Tuesday Morning, Room S210C William Straub, Presiding

Session 710

8:30 (710-1) Spectroscopic Determination of Polybrominated Flame Retardants JOHN A MONTI, Shimadzu Instruments, Shannon Richard, Timothy Alt 8:50 (710-2) Comparison of HRGC/HRMS and HRGC/LRMS for Measuring Polybrominated Diphenyl Ethers in Environmental Samples ROGER K GILPIN, Wright State University, Joseph G Solch, Rukunda L Farai 9:10 (710-3) Characterization of Non-Volatile Organic Compounds in Oxidized Landfill Leachate by Fourier Transform Ion Cyclotron Resonance Mass Spectrometry DANIEL M OSBORNE, Florida State University, Tanner M Schaub, Alan G Marshall, William T Cooper, Ryan P Rodgers 9:30 (710-4) Rapid Total Petroleum Hydrocarbon (TPH) Analysis in Soil Using Fourier Transform Infrared Attenuated Total Reflection (FTIR/ATR) JOHN C CORBETT, Smiths Detection, David V Dewey, Mark L Norman 9:50 (710-5) Molecularly Imprinted Polymer Sensors for Organophosphorus Compounds and Its Application to the Determination of Organophosphorus Pesticides SUE Y BAE, U.S. Army, Michael W Ellzy, Amanda L Jenkins 10:10 Recess 10:25 (710-6) Objective Odor Measurement and Efficiency LOUIS VIVOLA, Alpha M.O.S. America, Vincent Schmitt, Eric Chanie

60

10:45 (710-7) Non-discriminating Pyrolysis - Two-Dimensional Gas Chromatography: Time-of-Flight Mass Spectrometry as the Tools for the Characterization of Urban Air Particulate Matter ZIBA PARSI, University of Waterloo, James Harynuk, Tadeusz Grecki, Ewa Dabek-Zlotorzynska 11:05 (710-8) Surface-Modified TiO2 Nanoparticles for the Selective Photodegradation of Nitroaromatic Compounds SARAH A SHEELEY, ERDC-CERL, Donald M Cropek 11:25 (710-9) Analysis of the Deposition of Military Smokes and Obscurants DONALD M CROPEK, ERDC-CERL, Jacob M Goran, Muneaki Nakamura, Anthony P Philipp 11:45 (710-10) Nanoparticle Mediated Photodehalogenation DELANA A NIVENS, Armstrong Atlantic State University, Will E Lynch , Joyce Chow, Nin Dingra

10:10

Recess

10:25 (730-6) Use of Neural Networks and Spectroscopic Methods in Forensic Analyses JOHN N DRISCOLL, PID Analyzers, LLC, Pat Hogan, Walter Johnson, Pol Perov, Raksmey Im, Rebecca Romasco 10:45 (730-7) Simplified Design of the Ion Mobility Spectrometer EUGENE V KRYLOV, New Mexico State University, Gary A Eiceman, John A Stone, Hartwig Schmidt 11:05 (730-8) Remote Analysis of Chromium(VI) using the Aquatic Remote Monitoring System STUART J CHALK, University of North Florida 11:25 (730-9) Fluorescence and Raman Modalities Combine to Accelerate Analysis of Biomaterials PATRICK J TREADO, ChemImage Corporation, Steven Vanni, John Maier, Julianne Wolfe, Matthew P Nelson, Rachel Roskovensky 11:45 (730-10) The Spectroscopy of High-Energy Materials Using Terahertz Pulsed Spectro Detection PHILIP F TADAY, TeraView Limited, William T Tribe, David A Newnham, Yaochun Shen, Mike Kemp

ORAL SESSION
Sample Preparation Systems and Processes
Tuesday Morning, Room S230F Frank L Dorman, Restek Corporation, Presiding

Session 720

ORAL SESSION

Session 740

8:30 (720-1) A New Neutralizer Method for Analysis of Trace Anions in Bases and Trace Cations in Acids KANNAN SRINIVASAN, Dionex Corporation, Rong Lin, Sheetal Saini, Nebojsa Avdalovic, Chris Pohl 8:50 (720-2) Techniques for Implementing High Throughput Screening (HTS) in Sample Preparation/Sample Handing Applications HALL T MARTIN, National Instruments 9:10 (720-3) Withdrawn 9:30 (720-4) NeSSI: Taking the Lab to the Sample DAVID M SIMKO, Swagelok Company, John J Wawrowski 9:50 (720-5) New Chromatographic Valves for Process and Laboratory Chromatographs YVES GAMACHE, Contrle Analytique Inc 10:10 Recess 10:25 (720-6) Direct Determination of Acrylamide in Foods Using Accelerated Solvent Extraction (ASE) and LC-MS RICHARD E CARLSON, Dionex Corporation, Eric S Francis, Bruce E Richter, Frank Hoefler 10:45 (720-7) Size Reduction Techniques: Pushing the Limits Using a New Design Approach to Planetary Ball Mills JUERGEN PANKRATZ, Retsch GmbH & Co. KG 11:05 (720-8) Monitoring Fermenter Exhaust Gas with Miniature Modular Systems - Enabling PAT DAVID M SIMKO, Swagelok Company 11:25 (720-9) New Sample Stream Selection System and Method YVES GAMACHE, Contrle Analytique Inc 11:45 (720-10) Comparison of Two Different Techniques in the Evaluation of Mercury Emissions from a Municipal Sludge Incinerator MEYER LALLOUZ, City of Montreal, Environmental Service

Surface Analysis and Microscopic Imaging Techniques: Nanotechnology

Tuesday Morning, Room S230E Jing-Fong Wei, Southern University, Presiding 8:30 (740-1) Synthesis, Patterning, and Applications of High Aspect Ratio Gold Nanorods Grown Directly on Surfaces FRANCIS P ZAMBORINI, University of Louisville, Zhongqing Wei, Aneta J Mieszawska 8:50 (740-2) Template Directed Formation of Nanosized Cavities in a Silicate Film and Their Applications MARYANNE M COLLINSON, Kansas State University 9:10 (740-3) Simultaneous Single-Molecule Optical and Electrical Recording of DNA/Protein Analytes Interacting with Nanopores in Membrane Bilayers DANIEL L BURDEN, Wheaton College, Emily L Chandler, Alyssa L Smith, Lisa M Burden, John J Kasianowicz 9:30 (740-4) High Resolution Mapping of Compositional Differences at Electrode Interfaces by Electric Force Microscopy GRANT A EDWARDS, Iowa State University, Jeremy D Driskell, Adam J Bergren, Robert J Lipert, Marc D Porter 9:50 (740-5) SERS Chemical Imaging Nanoprobe for Application to Biological Systems MIKELLA E HANKUS, University of Maryland, Baltimore County, Gibson Gregory, Nirmala Chandrasekharan, Brian M Cullum 10:10 Recess 10:25 (740-6) New Magnetic Labeling Technique with Giant Magneto Resistive Sensor for Bioassay TOSHIKAZU KAWAGUCHI, Iowa State University, Marc D Porter, Mark Tondra 10:45 (740-7) Chemical Force Microscopy with Carbon Nanotubes: Fly-fishing on the Nanoscale LAWRENCE A BOTTOMLEY, Georgia Institute of Technology, Mark A Poggi, Jabulani R Barber, Andrew W McFarland, Jonathan S Colton, Peter T Lillehei 11:05 (740-8) Measuring the Compression of Carbon Nanosprings JABULANI R BARBER, Georgia Institute of Technology, Mark A Poggi, Lawrence A Bottomley, Andrew W McFarland, Jonathan S Colton, Cattien V Nguyen 11:25 (740-9) Infrared Imaging of Surface Treated Carbon Fibers XIAOYU LUO, University of Tennessee at Knoxville, Wayne Jalenak, Roberto Benson 11:45 (740-10) A Study of TEM Sample Preparation Techniques for Carbon Nanotube Structures on SiC JOHN L RIGUEUR, Fisk University, John J Beckel, Weijie Lu Lu, Warren E Collins, William C Mitchel

ORAL SESSION

Session 730

Spectroscopic Methods for Use on Terroristic and Forensic Evidence

Tuesday Morning, Room S230H David N Rahni, Pace University, Presiding 8:30 (730-1) Raman Chemical Imaging Biothreat Detection System KATHRYN S KALASINSKY, Armed Forces Institute of Pathology, Robert Crawford, April Shea, Steven Vanni, Patrick J Treado, Matthew P Nelson, Julie Wolfe 8:50 (730-2) Discrimination of Dyed Nylon Fibers Using Raman Microspectroscopy for Forensic Analysis BRANDI L CLELLAND, University of South Carolina, Bryan Vasser, Michael S Angel, Stephen L Morgan, Edward G Bartick 9:10 (730-3) Adsorption of Nerve Agent Simulants within Polyhedral Oligomeric Silsesquioxane Films MELINDA K FERGUSONMCPHERSON, Virginia Tech, Emily R Low, John R Morris 9:30 (730-4) Integrated Microscopy as a First Response Against White Powder Bioterrorism GRETCHEN L SHEARER, The McCrone Group, Charles A Zona, John G Delly 9:50 (730-5) Optimization of Spectral Identification of AgentRelated Chemicals Using Statistical Factors JACK C DEMIRGIAN, Argonne National Laboratory, Francis D'Amico

ORAL SESSION
Water Analysis
Tuesday Morning, Room S210D Gary L Emmert, University of Memphis, Presiding

Session 750

8:30 (750-1) Determination of Lead(II) in Water by ColorimetricSolid Phase Extraction NEIL C DIAS, Iowa State University, James S Fritz, Marc D Porter 8:50 (750-2) Hollow Cathode Particle Beam-Glow Discharge Mass Spectrometry for Comprehensive Speciation Analysis JACOB L VENZIE, Clemson University, R Kenneth Marcus

61

9:10 (750-3) In-situ Fiber Optic Raman Sensor for Environmental Analysis TINA M BATTAGLIA, Arizona State University, Karl S Booksh 9:30 (750-4) Automated Spectrometric Phosphate Measurement AARON S BEATTY, Man-Tech Associates Inc., Tiffany Reid, Robert V Menegotto 9:50 (750-5) Novel Nitrate Reduction Technique for Use with Discrete Analysis JAMES R HARBRIDGE, Lachat Instruments 10:10 Recess 10:25 (750-6) Detection of E. coli O157: H7 in Water Using Immunomagnetic Separations and Colorimetric-Solid Phase Extraction CHIEN-JU SHIH, Iowa State University, Salma Rahman, Marc D Porter 10:45 (750-7) Detection of Harmful Algal Bloom Species Using Fiber Optic Microarrays SOOHYOUN AHN, Tufts University, Deana L Erdner, David M Kulis, Donald M Anderson, David R Walt 11:05 (750-8) A Low-Cost Optical Sensing Platform for Building Wireless (Chemical) Sensor Networks DERMOT DIAMOND, Dublin City University 11:25 (750-9) A Bacillus Sphaericus Based Biosensor for Monitoring Nickel Ions in Industrial Effluents and Foods NEELAM VERMA, Punjabi University, Minni Singh 11:45 (750-10) Withdrawn Session 752

(760-3 P) Monolithic Column with AGP Immobilized for Drug-Protein Binding Studies HAI XUAN, University of Nebraska - Lincoln, David S Hage (760-4 P) High-Precision Spotting System for MALDI Target Preparation EVERT-JAN SNEEKES, LC Packings, Remco van Soest (760-5 P) LC-MALDI MS Using Monolithic Capillary Columns ROBERT VAN LING, LC Packings, Mark van Gils (760-6 P) Determination of Allantoin in Various Samples by Hydrophilic Interaction Chromatography with Mass Spectrometry IWASAKI YUSUKE, Hoshi University, Ito Rie, Inoue Koichi, Saito Koichi, Nakazawa Hiroyuki (760-7 P) Silica-Coated Magnetic Particles for Bioseparation LIFANG SHI, University of New Orleans, Zeev Rosenzweig (760-8 P) Fast Analysis of Small MW Analytes in a Beverage and Serum Samples on a Zirconia-Based Strong Anion-Exchanger BINGWEN YAN, ZirChrom Separations, Inc., Clayton V McNeff (760-9 P) The Use of Aqueous Normal Phase Chromatography and LC/MS on Type C (Hydride) Based HPLC Columns JOSEPH J PESEK, San Jose State University, Maria T Matyska (760-10 P) Method Development and Validation for Determination of (2Ethylhexyl) Phthalate and Its Metabolite Mono (2-Ethylhexyl) Phthalate Using Reversed-Phase Liquid Chromatography JOHN S ALBAZI, Northeastern Illinois University, Yousef Atallah, William Pizzi, Eva Chugh, Debajit Sircar (760-11 P) Optimizing Preparative Scale Purification of Biosynthetic Human Insulin by High Performance Reversed-Phase Liquid Chromatography DEREK W CHAN, Grace Vydac, Reno T Nguyen (760-12 P) Development of Oligonucleotide Analysis with Reversed-Phase HPLC Column Designed for Separation of Highly Polar Compounds NORIKO SHOJI, YMC Co., Ltd., Chie Yokoyama, Naohiro Kuriyama (760-13 P) Development of a High-Performance Affinity Monolithic Column with AGP Immobilized for Drug-Protein Binding Studies HAI XUAN, University of Nebraska - Lincoln, David S Hage (760-14 P) The Characteristic of New Desalting Column for Biomolecule TOSHIAKI NISHI, TOSOH, Muranaka Kazuaki, Kosuke Araki, Yasutami Mitoma, Thomas J Higley, Nakatan Shigeru (760-15 P) Optimizing the Extraction of Aliphatic Amino Acids Using Threefold Mixtures of Hydrophilic Solvents and Titrimetric Analysis of the Concentrate NADEZHDA Y MOKSHINA, Voronezh (Russia) State University, Sabuhi I Niftaliev

NEW PRODUCT FORUM

Laboratory and Data Management
Tuesday Morning, Room S220A Manuel R Miller, PA Dept. of Environmental Protection, Presiding

10:25 (752-1) Nexxis LAB: Bringing Together Islands of Information STEVE BOLTON, Labtronics Inc. 10:45 (752-2) Nexxis ELN: Automate Management of SOP Forms STEVE BOLTON, Labtronics Inc. 11:05 (752-3) HORIZON Web PortalHORIZON Web Portal: Secure, Web-based Project Setup, Data Inquiry and Report Generation J. J TOMLINSON, ChemWare, Inc., W. Elliott-Smith, T. Radosta, M. Metivier 11:25 (752-4) Multivarate Statistical Process Control (MSPC) using STATISTICA ROBERT EAMES, StatSoft, Inc. 11:45 (752-5) StarLIMS Solution for Lab Certification/Licensing DIANNE C HOLLENBECK, StarLIMS

POSTER SESSION NEW PRODUCT FORUM

Quality and Validation
Tuesday Morning, Room S220A Hyman Schultz, The Pittsburgh Conference, Presiding 8:30 (751-1) Weighing and Dispensing Optimization JAMES SEXTON, Rice Lake Weighing Systems 8:50 (751-2) A New, Low-Cost Microsampling Accessory for FTIR Analysis KENNETH D KEMPFERT, PIKE Technologies, Scott C Little 9:10 (751-3) Advanced Validation Automation for a Total Organic Carbon Analyzer RIC HUTTE, Ionics Instruments 9:30 9:50 (751-4) (751-5) Withdrawn Withdrawn Session 760 Session 751

Session 770

LC-MS: Analysis of Foods, Toxins, Drugs, Proteins and Polymers

Tuesday Morning (770-1 P) The Analysis of Red Bell Pepper Constituents by Particle Beam Liquid Chromatography Mass Spectrometry JAMES M CHAPMAN, Rockhurst University, Matthew J Sullivan, Scott Niemann (770-2 P) LC/MS Determination of the Key Ingredients in Echinacea Dietary Supplements PEI CHEN, USDA (770-3 P) LC/MS Determination of Water Soluble Vitamins PEI CHEN, USDA, Wayne Wolf (770-4 P) Determination of Rimsulfuron, Nicosulfuron, Imazethapyr and Flumetsulam in Surface Water by LC-MS/MS NATHALIE DASSYLVA, Ministre de l'environnement du Qubec-CEAEQ, Franois Houde, Christian Deblois, Ginette Gaudreau, Ginette Ct, Isabelle Giroux (770-5 P) Separation, Detection, and Evaluation of Quinones in Medicinal Plants VIVIAN E FERNAND, Louisiana State University, Isiah M Warner, Jack Losso, David Dinh (770-6 P) Withdrawn (770-7 P) Identification of Sugars by Liquid Chromatography/Mass Spectrometry in Samples of Forensic Interest JEFFREY N LEIBOWITZ, Federal Bureau of Investigation , Jay A Clark, David A Henningsen, Lisa G Schumacher, Marc LeBeau (770-8 P) Atazanavir Plasma Quantification Using a Direct Injection Method Compared with Reversed-Phase Analytical Column Methodology by LC/MS/MS AKRAM W GORGI, Consolidated Laboratory Services, Amitina Noemi, Currall Benjamin, Peter R Wolfe, Anthony J Scarsella

POSTER SESSION

Morning posters will be on display from 9:30 AM to 12:30 PM with authors present from 9:30 AM to 11:30 AM. The posters will be located on the Southeast corner of the Exposition floor (beginning Aisle 2900).

Bioanalytical Separations
Tuesday Morning (760-1 P) Nonenzymatic Glycation of DNA Nucleobases with Reducing Sugars and Glyceraldehyde UDAYAN DUTTA, University of Rhode Island, Menashi A Cohenford, Joel A Dain (760-2 P) Analysis of Steroids and Shape Selectivity Using the Type C Silica Cholesterol Stationary Phase MARIA T MATYSKA, San Jose State University, Joseph J Pesek

62

(770-9 P) Sensitivity and Selectivity: A Case Study of LC/MS Enantioselective Resolution of Bupivacaine Using Bonded Vancomycin as a Chiral Stationary Phase J.T. LEE, Advanced Separation Technologies Inc. (Astec), Maria Esther Rodriguez Rosas, Thomas E Beesley (770-10 P) Determination of Trace-Level Actinides in Urine by LC-ICP-MS WENWAN ZHONG, Los Alamos National Laboratory, Wei Hang (770-11 P) Use of Internal Standards in IC/ESI-MS ROSANNE W SLINGSBY, Dionex Corporation, William C Schnute, Charanjit Saini, Chris Pohl, Steven C Wendelken (770-12 P) The Identification of Quaternary Amine Drugs by Time-of-Flight Tandem Mass Spectrometry LISA G SCHUMACHER, Federal Bureau of Investigation , Jeffrey Liebowitz, Eshwar Jagerdeo, David A Henningsen (770-13 P) Analysis of Blood Butyrylcholinesterase-Sarin Adduct Using LC-MS/MS KOUICHIRO TSUGE, National Research Institute of Police Science, Mieko Kanamori-Kataoka, Isaac Ohsawa, Yasuo Seto (770-14 P) Comparison of Dye Interaction Spectrophotometry with Mass Spectrometry for the Detection of Phospholipids NEIL D DANIELSON, Miami University, Brian D Eliason, B Jason Smith (770-15 P) Method Development for Analysis of N, N-diethyl-metatoluamide (DEET) and Some of Its Metabolites in Human Urine Using HPLC-MS/MS JESSICA E NORRGRAN, Centers for Disease Control and Prevention, Roberto Bravo , Dana B Barr (770-16 P) Identification of Forced Degradation Products of Irganox 1010 and Irgafos 168 by LC-MS and GC-MS TIAN-JING DENG, PPD Development, Xiaochun Yu, Harley Cliff, Xiaoya Ding (770-17 P) Two-Dimensional Separations of Intact Proteins Using Ultra High Pressure Liquid Chromatography CHARLES R EVANS, University of North Carolina at Chapel Hill, Jason C Link, James W Jorgenson (770-18 P) High-Performance Liquid Chromatographic and Electromigration Techniques in the Analysis of Biogenic Amines (Review) IBOLYA MOLNAR-PERL, L. Eotvos University (770-19 P) How To Maximize Serum Protein Identification KING C CHAN, SAIC-Frederick, Brian L Hood, David A Lucas, Zhen Xiao, Ming Zhou, Thomas P Conrads, Haleem J Issaq, Tim D Veenstra

POSTER SESSION
LC-MS: Sample Handling/Column Technology
Tuesday Morning (790-1 P) Withdrawn

Session 790

(790-2 P) Microfraction Collection as a Tool to Optimize LC-MS Workflows in Proteomics JOHANNES HIDDING, Spark Holland, Rob Van der Knaap, Bert Ooms (790-3 P) Comparison Between Lewis Acid-Deactivated Reversed-Phase Zironia- and Silica-Based Stationary Phase in LC/MS BINGWEN YAN, ZirChrom Separations, Inc., Clayton V McNeff (790-4 P) Enantiomeric Separation of Amino Acid Derivatized with 7Fluoro-4-Nitrobenzoxadiazole By Capillary Liquid Chromatograph /Tandem Mass Spectrometry YARU SONG, Jackson State University, Yi-Ming Liu (790-5 P) Fast On-line Electrochemical Synthesis of Pharmaceutical Degradants and Metabolites for Profiling, Identification, and Quantitation DARWIN J ASA, Esa Inc., David Meyer, Mike Granger, Rod Cole, Marjorie Soloman, Ian N Acworth, Ryan McCarthy, Paul Gamache (790-6 P) Electrochemically Assisted Ionization Broadens the Analytical Utility of Fast LC-MS in Pharmaceutical Analyses DARWIN J ASA, Esa Inc., Ryan McCarthy, Ian N Acworth, Ray Smith, Mike Granger, Paul Gamache, David Meyer (790-7 P) Chromatographic Resolution Studies of 18O Coded Peptides JULKA SAMIR, Purdue University, Fred E Regnier (790-8 P) Off-line Combination of the Multidimensional HPLC and the MALDI-TOF-MS for the Proteomic Analysis by the High-Throughput Spotting System YOSUKE IWATA, Shimadzu Corporation, Teruhisa Ueda, Sadanori Sekiya, Tomoko Yamaguchi, Helen Montgomery (790-9 P) Optimizing High Throughput Applications Using 20mm and 30mm Length HPLC Columns KENNETH JONES, Advanced Chromatography Technologies, Robert T Moody, Carl L Zimmerman

POSTER SESSION
Tuesday Morning

Session 810

POSTER SESSION
LC-MS: Instrumental Developments
Tuesday Morning

Session 780

Liquid Chromatography: New Developments and Applications

(780-1 P) On-line Sample Preconcentration Using a Monolithic Column for Measuring 16 Phthalate Metabolites in Urine KAYOKO KATO, Centers for Disease Control and Prevention, Manori J Silva, Larry L Needham, Antonia M Calafat (780-2 P) High-Flow Electrospray Ionization Source Optimization for a Multi-Anode Based Time-of-Flight Mass Spectrometer: Improved Performance for Fast Liquid Chromatography MATTHEW GIARDINA, LECO Corporation, Viatcheslav Artaev, Paul D Kennedy (780-3 P) Reduction of Carry-Over in Bioanalytical LC-MS/MS JOHANNES HIDDING, Spark Holland (780-4 P) Uniting Fast Chromatography with Rapid Data Acquisition: High Temperature Liquid Chromatography and Time-of-Flight Mass Spectrometry PAUL D KENNEDY, LECO Corporation, Matthew Giardina, Brian G Shofran (780-5 P) Effect of Key Instrumental Parameters and Solute Concentration on Particle Size Distributions of Solid Aerosols Produced Using an Oscillating Capillary Nebulizer and a Particle Beam Interface for Mass Spectrometry JOHN A CASANOVA, Georgia Institute of Technology, Richard F Browner (780-6 P) Packed Emitter Tip or Packed Column: An Investigative Study Comparing Sensitivity and Robustness for Liquid Chromatography / Mass Spectrometry Methods JOSHUA P KLINE, Thermo Electron Corporation, Scott Peterman, Ron Sherant, Eric Stover (780-7 P) Electron Ionization LC-MS with Supersonic Molecular Beams ORI GRANOT, Tel Aviv University, Tal Alon, Aviv Amirav (780-8 P) Comparing Atmospheric Pressure Photoionization and Atmospheric Pressure Chemical Ionization for the LC/MS Analysis of DNPH Derivatives SUZE M VAN LEEUWEN, University of Twente, Laurens Hendriksen, Uwe Karst

(810-1 P) Evaluation of a New Universal Detector for HPLC DARWIN J ASA, Esa Inc., Scott Freeto, Ian N Acworth, Ryan McCarthy, Rod Cole, Paul Gamache (810-2 P) Basic Interpretation of Retention Mechanism in Liquid Chromatography Using Molecular Dynamics Simulation KAZUHIRO BAN, Toyohashi University of Technology, Yoshihiro Saito, Kiyokatsu Jinno (810-3 P) Starting Points in Chromatographic Method Development: A Structure-Based Approach DAVID S BELL, Supelco, Inc., John Martin, Hugh M Cramer, Eduard Kolovanov, Alexey Danilov, Michael McBrien (810-4 P) Investigating the Performance of a Novel Saw-Tooth Gradient on a Reversed Phase Capillary HPLC GUIMEI CAI, West Virginia University, Aaron T Timperman (810-5 P) Designed Selectivity Enhancement WILLIAM CAMPBELL, Supelco/Sigma-Aldrich, Jacinth A McKenzie, Paul Raymond, Bei Chen (810-6 P) Molecular Interactions Contributing to Alternative Selectivity of Polar Embedded HPLC Stationary Phases BELL S DAVID, Supelco/SigmaAldrich, William Campbell, Paul Raymond, Jacinth A McKenzie (810-7 P) Development of a Microwave-Assisted Solvent Extraction with High Pressure Liquid Chromatography Method for the Determination of 10,10'-Oxybisphenoxarsine in Silicone Sealants CHRIS DAVIS, Dow Corning Corporation (810-8 P) The Advantages of Using Polymer-Based Weak Cation or Anion Exchange Sorbents in Solid Phase Extraction Prior to LC/MS Analysis ART DIXON, Phenomenex, Inc., A. Carl Sanchez, Tivadar Farkas (810-9 P) Fluorescence Detection of Pharmaceuticals Using Flow Injection or Liquid Chromatography with Totally Aqueous Alkylammonium Carboxylate Mobile Phases JUSTIN N GIBLER, Miami University, Erin M Myers, Neil D Danielson (810-10 P) Developments in Evaporative Light Scattering Detection for Gradient Elutions of Small Molecules INGA HENDERSON, SofTA Corporation (810-11 P) Computer-Aided Design and Analysis of Experiments for Robustness Validation of an HPLC Assay Method for Fentanyl JASON JENNISSEN, Cima Labs, Inc.

63

(810-12 P) Guidelines for Achieving Reproducible High Performance Preparative HPLC Separations KENNETH JONES, Advanced Chromatography Technologies, Carl L Zimmerman, Robert T Moody (810-13 P) Temperature Gradient Elution in High Performance Liquid Chromatography Using Thermo-Sensitive Stationary Phase TAKAEI KITAGAWA, Shimadzu Corporation, Yoshihiro Hayakawa, Yosuke Iwata, Shuzo Maruyama, Morimasa Hayashi, Teruhisa Ueda, Hideko Kanazawa (810-14 P) Evaporative Light Scattering Detection (ELSD) Design Improvements Enhance Detector Performance and Sensitivity ALEXANDRA M KUCH, Alltech Associates, Inc., Raaidah Saari-Nordhaus (810-15 P) Polar-Modified Phases for Retaining Polar Compounds GUANG QING LI, Varian, Inc., Ritu Arora, Dennis D Blevins (810-16 P) New HPLC Materials Designed for the Demands of Drug Discovery and Pharmaceutical Method Development GUANG QING LI, Varian, Inc., Ritu Arora, Dennis D Blevins (810-17 P) Theoretical Evaluation of Several Methods for Extracting Kinetic Rate Constants in Liquid Chromatography XIAOPING LI, Michigan State University, Victoria L McGuffin (810-18 P) Incorporate Single Wall Carbon Nanotubes into Organic Polymer Monolith as the Stationary Phase for Micro-HPLC YAN LI, Yale University, Yuan Chen, Rong Xiang , Dragos Ciuparu, Lisa D Pfefferle, James A Wilkins (810-19 P) Modification of Porous Carbons for Liquid Chromatography Separations Using a Solvent Free Technique ZUOJIANG LI, Oak Ridge National Laboratory, Sheng Dai (810-20 P) pH as a Powerful Tool for Manipulating Selectivity in Reverdes Phase HPLC LAWRENCE LOO, Phenomenex, Inc., Ismail Rustamov, Tivadar Farkas (810-21 P) Nano-Porous Diamonds as Novel Stationary Phases for Chromatographic Separations BHAVIK A PATEL, Imperial College London, Ken J Rutt, Vladimir I Padalko, Mikhalovsky V Sergey (810-22 P) Reduced Band Broadening on Short Narrow Bore HPLC Columns GEOFF TODOSIEV, Isolation Technologies, Inc., Jaime Martain (810-23 P) Withdrawn (810-24 P) Withdrawn (810-25 P) Mutual Automated Peak Matching in Chromatographic Method Development MICHAEL MCBRIEN, Advanced Chemistry Development, Inc., Andrey Bogomolov, Vitaly Lashin, Eduard Kolovanov (810-26 P) Development of Rigid Polymeric Packings to Optimise Selectivity JOHN A MCCONVILLE, Polymer Laboratories Inc., Linda L Lloyd, Keeley J Mapp, Adam J Croucher (810-27 P) Withdrawn (810-28 P) To Develop a GPC Method Using a Light Scattering/Viscometer/Refractive Index Triple Detection for Gelatin Analysis DONALD MIN, Cardinal Health (810-29 P) Correcting Peak Tailing Problems in Reversed Phase HPLC ROBERT T MOODY, MAC-MOD Analytical, Inc., Carl L Zimmerman (810-30 P) HPLC System Control and Data Acquisition Using NET and Embedded Web Service Technology in a Laboratory Network Environment TSUYOSHI MORIKAWA, Shimadzu Corporation, Teruhisa Ueda, Shuzo Maruyama , Naoki Osaka, Koji Okada (810-31 P) The Use of Multiangle Light Scattering (MALS) for the Analysis of Low Molecular Weight Compounds in OTC Products JAMES MURPHY, GSK, Lena John (810-32 P) Evaluation of Polar Stationary Phases in the Hydrophilic Interaction Chromatography (HILIC) Mode NORIKAZU NAGAE, Nomura Chemical Co., Ltd., Toshiyuki Enami, Naoki Fujita (810-33 P) Retention Behavior in Reverse-Phase HPLC with 100% Aqueous Mobile Phase NORIKAZU NAGAE, Nomura Chemical Co., Ltd., Naoki Fujita, Toshiyuki Enami (810-34 P) Retention of Charged Solutes on an Ionic Liquid Stationary Phase for High Performance Liquid Chromatography KEVIN PARKER, University of Cincinnati, Apryll M Stalcup (810-35 P) Advantage of a Nonlinear Detector (ELSD) versus a Linear Detector (UVD) in a Complex Mixture Analysis RODOLPHE PENNANEC, SEDERE Sa., Michel Dreux (810-36 P) Use of Ultra-High Temperature to Achieve High Efficiency, Fast LC LUISA PEREIRA, Thermo Electron Corporation, Mark Woodruff, Harold Ritchie, Steve Aspey (810-37 P) Withdrawn

(810-38 P) Withdrawn (810-39 P) The Adverse Effects of Thermal Mismatch on the Performance of 50 mm id Preparative HPLC Columns MATILAL SARKER, Supelco, Inc., William Campbell (810-40 P) Withdrawn (810-41 P) Analysis of Complex Molecular Weight Distributions with Multipore GPC/SEC Columns GREGORY D SAUNDERS, Polymer Laboratories Ltd., Andrew Penrose, Abbie C Wills, John A McConville (810-42 P) A Portable, Automated Ion Chromatography Based Analyzer for Monitoring Haloacetic Acids in Drinking Water PAUL S SIMONE, The University of Memphis, Gary L Emmert (810-43 P) Microbore Capillary-Channeled Polymer (C-CP) Fibers in High Performance Liquid Chromatography. RAYMAN D STANELLE, Clemson University, R Kenneth Marcus (810-44 P) Experimental Evaluation of Several Methods for Extracting Thermodynamic and Kinetic Information in Liquid Chromatography AMBER M TERRY, Michigan State University, Victoria L McGuffin (810-45 P) Modeling Chromatographic Dispersion: A Comparison of Popular Equations KARYN M USHER, Florida State University, Carolyn R Simmons, John G Dorsey (810-46 P) The Use of Sub 2 Particles to Achieve Enhanced Resolution and Speed MARK WOODRUFF, Thermo Electron Corporation, Harold Ritchie, Charlotte Blythe, Steve Aspey, Luisa Pereira (810-47 P) A HPLC Method to Analyze Acetic Acid and Glyoxylic Acid YING (TINA) YU, Advanced Sterilization Products, Johnson&Johnson, Uyen Nguyen, Yvonne Tran, XiaoLan Chen (810-48 P) Using Bonded Phase Selectivity to Optimize High Throughput HPLC Separations CARL L ZIMMERMAN, MAC-MOD Analytical, Inc., Robert T Moody (810-49 P) A Method Development Scheme for Chiral Analytes on Carbamoylated Quinidine and Quinine Stationary Phases CARL L ZIMMERMAN, MAC-MOD Analytical, Inc., Robert T Moody, Stefan Lamotte, Gerald Reindl (810-50 P) Simple HPLC-UV Method for Determination of Iohexol, Iothalamte, p-aminohippuric Acid and n-acetyl-p-aminohippuric Acid in Human Plasma and Urine Determination Using Colorimetric Analysis DON E FARTHING, VCU Medical Center, Terri L Larus, Dom A Sica, Todd W Gehr, Sid S Ghosh, Itaf Fakhry, Christine A Farthing, Michael Vranian (810-51 P) More Speed, More Resolution: No Dream, Reality STEFAN LAMOTTE, Bischoff Chromatography, Rainer Brindle, Peter G Dietrich, Gerald Reindl, Klaus D Bischoff (810-52 P) The Influence of Bonding Density of Silica Packings on Selectivity in RP HPLC STEFAN LAMOTTE, Bischoff Chromatography, Rainer Brindle, Peter G Dietrich, Gerald Reindl, Klaus D Bischoff (810-53 P) Ion Exchange Properties of a Zwitterionic Lysine Functionalised Silica Monolithic Column BRETT PAULL, Dublin City University, Edel Sugrue, Pavel N Nesterenko (810-54 P) Fluorinated Stationary Phases As An Alternatives to ODS and Phenyl Phases for HPLC MATTHEW PRZYBYCIEL, ES Industries (810-55 P) Development and Optimization of HPLC Method for the Separation of 16 Stereoisomers XIANDE WANG, Johnson & Johnson PRD (810-56 P) Optimum Gradient Steepness for Maximizing Peak Capacity in the Reversed-phase Gradient Elution Chromatography XIAOLI WANG, University of Minnesota, Dwight R Stoll, Peter W Carr (810-57 P) Comparison of Retention Behavior of Small Polar Compounds on Polar Stationary Phases in Hydrophilic Interaction Chromatography YONG GUO, Johnson & Johnson (810-58 P) Sugar-D: A Distinctly Improved Stationary Phase for Saccharide Separation TOMOYUKI SENO, Nacalai Tesque, Inc., Toshiyuki Ono, Tsunehisa Hirose, Kazuhiro Kimata

POSTER SESSION
Separation Science
Tuesday Morning

Session 820

(820-1 P) Purifying Very Large Samples Using Flash Chromatography by Using Peak Shaving and Peak Recycling ADAM C WILKINS, Gyan Srl (820-2 P) Extraction of Mercury (II) by Sol-Gel Sorbents Doped with Sulfur Containing Extractans FLORA E MERCADER, UNAM-CENAM, Josefina de Gyves, Eduardo Rodrguez de San Miguel

64

(820-3 P) Molecular Recognition Properties of Aminoquinoline-Imprinted Polymers FENG LIU, Peking University (820-4 P) Testosterone-Imprinted Polymer Films Grafted from Porous Silica FENG LIU, Peking University (820-5 P) Studies of Polymerization Reactions via Automatic Online Process Monitoring GREGORY D SAUNDERS, Polymer Laboratories Ltd., Stephen O'Donohue, John A McConville (820-6 P) Ionic Liquid-Based Aqueous Two-Phase System: A Novel System for Extraction of Drugs FENG LIU, Peking University (820-7 P) Study of Additive Effects on Retention Mechanisms in Packed Column Supercritical Fluid Chromatography Using Room Temperature Ionic Liquids YAN WU, Michigan Tech University, David Chesney, Richard Thompson, Nelu Grinberg (820-8 P) Evaluation of Column Characteristics in Packed Column Supercritical Fluid Chromatography Using Linear Solvation Energy Relationships YAN WU, Michigan Tech University, Richard Thompson, David Chesney (820-9 P) Solvatochromic Study of Modifier and Additive Effects on Retention Mechanisms in Packed Column Supercritical Fluid Chromatography Using Solvatochromic Dye-Nile Red YAN WU, Michigan Tech University, David Chesney, Richard Thompson (820-10 P) The Effect of Mobile Phase Additives on the Analysis of Peptides and Proteins JON R FISHER, Rohm and Haas Company, John J Maikner, Amie S Gehris, Andrew Rosenthal, Marlin K Kinzey, Mark Vander Hoff (820-11 P) Measurement of Bromate Ion Reduction in Gastric Juices Using Ion Chromatography JASON D KEITH, Miami University, Gilbert E Pacey, Gilbert Gordon, Joseph Cotruvo, Richard Bull (820-12 P) Assessing Technical Feasibility of Supercritical Extraction Processes of Naturally Occurring Materials Using Benchtop Laboratory Equipment KENNETH J JAMES, Supercritical Fluid Technologies, Inc. (820-13 P) Novel Polyethylene Glycol Coatings for LC and GC Solid Phase Micro Extraction CHRIS LINTON, Supelco, Inc., Robert E Shirey, Leonard M Sidisky (820-14 P) The Benefits of Evaporative Light Scattering Detection in Supercritical Fluid Chromatography JOHN A MCCONVILLE, Polymer Laboratories, Inc., Stephen Bullock (820-15 P) The Development of a New Resilient SPME Fiber Assembly Containing Coated Metal Fibers ROBERT E SHIREY, Supelco, Inc., Chris Linton, Leonard M Sidisky (820-16 P) Determination of Enantiomeric Composition by Fluorescence Anisotropy MATTHEW E MCCARROLL, Southern Illinois University, Yafei Xu

SYMPOSIUM

Session 850

Capillary Electrophoresis in the Biotechnology and Biopharmaceutical Industry - arranged by Andras Guttman, LeopoldFranzens University Innsbruck Tuesday Afternoon, Room S210E Andras Guttman, Leopold-Franzens University Innsbruck, Presiding 1:30 Introductory Remarks - Andras Guttman

1:35 (850-1) Determination of Low Abundance Urinary Peptides of Clinical Significance by Immunoaffinity Capillary Electrophoresis NORBERTO A GUZMAN, Johnson & Johnson 2:10 (850-2) Large Scale Profiling of Biopolymers by Capillary Array Electrophoresis in Bio-Industrial Settings JULIA KHANDURINA, The Gel Company, Greg Richardson 2:45 (850-3) Interplay of Chromatographic and Electrophoretic Processes in Capillary Electrochromatography ANURAG S RATHORE, Amgen Inc., Melvin R Euerby, Alex P McKeown 3:20 Recess 3:35 (850-4) Electromigration Techniques to Evaluate Genetic Polymorphism and Drug Metabolism HUBA I KALASZ, Semmelweis University 4:10 (850-5) Performance Analysis of Industrial Enzymes by Capillary Electrophoresis: Quantitative and Qualitative Aspects ANDRAS GUTTMAN, Leopold-Franzens University Innsbruck

SYMPOSIUM

Session 860

Determination of Residuals in Polymer for Pharmaceutical, Food, Personal Care and Industrial Applications - arranged by Chisan Wu, International Specialty Products Tuesday Afternoon, Room S230D Chi-san Wu, International Specialty Products, Presiding 1:30 Introductory Remarks - Chi-san Wu

1:35 (860-1) Determination of Monomeric and Other Impurities in Polymeric Excipients for Pharmaceutical Use: Method Choice and Validation Requirement RAYMOND R CHEN, Pfizer, Inc. 2:10 (860-2) Analysis of Residuals in Polymers Using HPLC and Capillary Electrophoresis SHYHCHANG S HUANG, Noveon, Michael Burk 2:45 (860-3) Determination of Residual Monomers, Solvents, and Additives in Adhesive Films by Headspace/Trap/GC/MS EDWARD H MARTI, Ashland Specialty Chemical Co. 3:20 Recess 3:35 (860-4) Determination of Low Level Residual Acrylamide and Acrylic Acid Monomers in Various Polymers LEONARD M VER VERS, Nalco 4:10 (860-5) Determination of Residual Vinylpyrrolidone in Homo and Co-Polymers of Vinylpyrrolidone by Size Exclusion Chromatography CHI-SAN WU, International Specialty Products

SYMPOSIUM
arranged by Allen J Sharkins, Alcoa retired Tuesday Afternoon, Room S210A Allen J Sharkins, Alcoa retired, Presiding 1:30 Introductory Remarks - Allen J Sharkins

Session 830

Pittsburgh Spectroscopy Award and Maurice F Hasler Award -

1:35 Presentation of the 2005 Pittsburgh Spectroscopy Award to John F Rabolt, University of Delaware, by Charles Perry, Chairman, Spectroscopy Society of Pittsburgh 1:40 (830-1) Planar Array Infrared (PA-IR): Evolution, Revolution or Back to the Future? JOHN F RABOLT, University of Delaware 2:15 (830-2) The Development of Focal Plane Array Infrared Spectroscopy BRUCE CHASE, DuPont, John F Rabolt, Christian Pellerin, Isabelle Pelletier, Chris Snively, Julia Liu 2:50 3:05 Recess Introductory Remarks - Allen J Sharkins

SYMPOSIUM
Minnesota Tuesday Afternoon, Room S220G Edgar A Arriaga, University of Minnesota, Presiding 1:30 Introductory Remarks - Edgar A Arriaga

Session 870

Subcellular Proteomics - arranged by Edgar A Arriaga, University of

3:10 Presentation of the 2005 Maurice F Hasler Award to James D Winefordner, University of Florida, by Daniel A Wilson, President, 2005 Pittsburgh Conference 3:15 (830-3) 40+ Years of Analytical Spectroscopy JAMES D WINEFORDNER, University of Florida 3:50 (830-4) Improving Chemical Analysis with Advanced Array Detector Technology M. BONNER DENTON, University of Arizona

1:35 (870-1) Contextual Proteomics in the Cellular Milieu STEVEN W TAYLOR, Amylin 2:10 (870-2) Mitochondrial Proteomics, Neurodegenerative Disease and Aging BRADFORD W GIBSON, Buck Institute 2:45 (870-3) Deciphering Networks of Protein Interaction at the Nuclear Pore Complex MICHAEL F REXACH, Stanford University 3:20 Recess

65

3:35 (870-4) Analysis of Organelles by Matrix-Assisted Laser Desorption/Ionization Time-of-Flight Mass Spectrometry and iTRAQ Technology EDGAR A ARRIAGA, University of Minnesota, Marian Navratil, Richard Walsh, Bobby G Poe 4:10 (870-5) Automated Learning of Protein Subcellular Locations from Fluorescence Microscope Images ROBERT F MURPHY, Carnegie Mellon University

2:45 (890-3) Archemix 3:20 3:35 (890-4)

Therapeutic Uses of Aptamers SHARON T CLOAD, Recess TBA

4:10 (890-5) Nonequilibrium Capillary Electrophoresis of Equilibrium Mixtures (NECEEM): A Swiss Army Knife for Selection of Aptamers SERGEY N KRYLOV, York University

SYMPOSIUM

Session 880

Using Forensic Science to Teach Undergraduate Analytical Chemistry - arranged by J David Jenkins, Georgia Southern University
Tuesday Afternoon, Room S230H J David. Jenkins, Georgia Southern University, Presiding 1:30 Introductory Remarks - J David Jenkins

ORAL SESSION
Atomic Spectroscopy: General Interest
Tuesday Afternoon, Room S230F N Curtis Radcliffe, PPG Industries, Inc., Presiding

Session 900

1:35 (880-1) Solving Crimes with Chemistry: Using Forensics to Teach Analytical Chemistry to Students at All Levels KIMBERLEY A FREDERICK, College of the Holy Cross, Kyle A Soucy 2:10 (880-2) Using Forensic Science to Teach Undergraduate Analytical Chemistry: Problem Solving in the Real World STEPHEN L MORGAN, University of South Carolina 2:45 (880-3) From Crime Scene to Trial: Using Forensics as a Centerpiece of the Analytical Chemistry Laboratory PAUL L EDMISTON, College of Wooster 3:20 Recess 3:35 (880-4) Using Forensic Analysis Experiments to Illustrate the Applications of Analytical Chemistry ROGER M SMITH, Loughborough University, Helen J Reid 4:10 (880-5) Forensic Science: Where Chemistry and Crime Collide in the Undergraduate Curriculum LAWRENCE J KAPLAN, Williams College

3:25 (900-1) A Low-Flow Geometry for the Liquid SamplingAtmospheric Pressure Glow Discharge Microplasma JACOB L VENZIE, Clemson University, R Kenneth Marcus 3:45 (900-2) Application of Fast Sequential AA to Complex Sample Matrices DOUG SHRADER, Varian, Inc., Christine M Rivera, Anna Tisinger 4:05 (900-3) Method Development Strategies Utilizing Axially Viewed ICP-OES when Samples Consist of Complex Matrices CHRISTINE M RIVERA, Varian, Inc., Doug Shrader, Michelle E Cree, Steve Wall 4:25 (900-4) High Sensitivity ICP-MS for Advanced Laser Ablation Performance MICHAEL PLANTZ, Varian, Inc., Michelle E Cree, Doug Shrader 4:45 (900-5) Elucidation of the Mechanism of Resonant Laser Ablation through Detection by Atomic Emission in a Microwave Plasma, and by Inductively Coupled Plasma Mass Spectrometry ROBERT G MICHEL, University of Connecticut, Danielle Cleveland, Peter Stchur, Xiandeng Dan Hou, Karl Xiadong Yang

ORAL SESSION
Bioanalytical on the Edge
Tuesday Afternoon, Room S230G Scott A Shippy, University of Illinois, Presiding

Session 910

SYMPOSIUM
Adrian C Michael, University of Pittsburgh Tuesday Afternoon, Room S230C Adrian C Michael, University of Pittsburgh, Presiding 1:30

Session 350

Watching Chemistry in the Central Nervous System - arranged by

1:30 (910-1) MALDI MS of Extracellular Perfusates of the Central Nervous System SCOTT A SHIPPY, University of Illinois at Chicago, Harsha Mudrakola, Ramil Francisco 1:50 (910-2) Fabrication of a Polymeric Electric Field Gradient Focusing Microdevice Using a Novel In-Situ Membrane Fabrication Technique JIKUN LIU, Brigham Young University, Xuefei Sun, Milton L Lee 2:10 (910-3) Integration of Giant Magnetoresistive Sensors with Microfluidic Systems: Direct On-Chip Sensing of Magnetically Labeled Pathogens NIKOLA PEKAS, Iowa State University, Marc D Porter, Mark Tondra, Anthony Popple, Albrecht Jander 2:30 (910-4) Development of a Microchip Real-Time PCR System with a Fluorescence Imaging Detector MAXIM N SLYADNEV, St. Petersburg State University, Vasilij A Kazakov, Marina V Sherbaeva, Alexander A Ganeev, Leonid N Moskvin 2:50 (910-5) Applications of Polymer-Based Microfluidic Devices for Biological Cell Transport, Manipulation and Capture MALGORZATA A WITEK, Louisiana State University, Andr A Adams, Suying Wei, Juan Feng, Michael C Murphy, Robin L McCarley, Steven A Soper 3:10 Recess 3:25 (910-6) Structure, Functional Properties, and Protein Functionalization of Poly(Lipid) Bilayer Membranes SCOTT SAAVEDRA, University of Arizona 3:45 (910-7) Nitric Oxide Metabolite Levels in the Rat Striatum SCOTT A SHIPPY, University of Illinois at Chicago, Jennifer A Barber-Singh, Leyi Gao 4:05 (910-8) Electrophoretic Focusing: A Separation Method for Micro-scale Applications ROBERT S SNYDER, New Century Pharmaceuticals, Inc., Percy H Rhodes 4:25 (910-9) Magnetic Nanotubes for Bioseparation SANG JUN SON, University of Maryland at College Park, Jonathan B Reichel, Bo He, Sang Bok Lee 4:45 (910-10) Rapid Analysis of Biomolecular Interactions Using Capillary Electrophoresis with Photolytic Injection SUMINDA HAPUARACHCHI, University of Arizona, Craig A Aspinwall

Introductory Remarks - Adrian C Michael

1:35 (350-1) Progress in Peptide Determination in Brain by HPLC STEPHEN G WEBER, University of Pittsburgh, Mats Sandberg, Amy Beisler, Rong Meng, Imants Zudans, Moon Chul Jung, Yifat Guy, Hongjuan Xu, Guoyue Shi 2:10 (350-2) Identifying Dopamine Measured with In Vivo Voltammetry R MARK WIGHTMAN, University of North Carolina at Chapel Hill, Michael L Heien 2:45 (350-3) New Strategies, Device Materials and Geometries, and Instrumentation for Electrochemical Detection of Dopamine INGRID FRITSCH, University of Arkansas, Padhmodhbhava Yoga Narashimhava, Prabhu U Arumugam, Walter R Vandaveer, Chien Nguyen, Yun Xi, Simon S Ang, Donald J Woodward 3:20 Recess 3:35 (350-4) Expanding the Tool-Box for Studying Brain Chemistry and Behavior ROBERT T KENNEDY, University of Michigan 4:10 (350-5) Watching Neurotransmitters and Related Substances in the Brain ADRIAN C MICHAEL, University of Pittsburgh, Laura M Borland, Guoyue Shi, Joseph J Mitala

WORKSHOP
Aptamers: Novel Molecular Probes for Genomics and Proteomics - arranged by Weihong Tan, University of Florida
Tuesday Afternoon, Room S220E Weihong Tan, University of Florida, Presiding 1:30 1:35 2:10 (890-1) (890-2) Introductory Remarks - Weihong Tan TBA TBA

Session 890

66

ORAL SESSION
Chemical Methods of Analysis
Tuesday Afternoon, Room S230F N Curtis Radcliffe, PPG Industries, Inc., Presiding

Session 920

2:50 (940-5) A Rapid Technique for the Extraction of Persistent Organic Pollutants (POPs) Using Accelerated Solvent Extraction (ASE) JENNIFER PETERSON, Dionex Corporation, Henderson Sheldon, Eric S Francis, Richard Carlson, Richter Bruce 3:10 Recess 3:25 (940-6) Using Headspace Trapping Technology with GC/MS for Measuring Environmental Volatile Organic Compounds (VOCs) by Method EPA8260b. HEIDI L GRIFFITH, PerkinElmer, Andrew Tipler 3:45 (940-7) The Simultaneous Analysis of Fuel Oxygenates and Traditional VOCs of US EPA Method 8260 by Purge and Trap GC/MS MARK E KRIGBAUM, Teledyne Instruments - Tekmar, Tom Hartlein 4:05 (940-8) Sampling and Determination of Volatile Organic Compounds by Needle Trap Devices AI PING WANG, University of Waterloo 4:25 (940-9) Microwave-Assisted Rapid Extraction of VOCs from Low Permeability Media YONGDONG LIU, University of Waterloo, Tadeusz Grecki, Beth L Parker 4:45 (940-10) Pursuit of Practical Particle Size Reduction and Subsampling for the Environmental Testing Laboratory MARK L BRUCE, Severn-Trent Laboratories

1:30 (920-1) Single Nucleotide Polymorphisms (SNPs) Detection Using Aqueous Solution-Based Atom Transfer Radical Polymerization (ATRP) LIN HE, North Carolina State University, Xinhui Lou 1:50 (920-2) Ultrasonic All Chemical Reaction Detection for Biotechnology and Biomedical Applications EVGENY KUDRYASHOV, Ultrasonic Scientific Ltd., Breda O' Driscoll, Vitaly Buckin 2:10 (920-3) Gravimetric Titration of Ammonia in AmmoniaNitrogen Gas Mixtures THOMAS W VETTER, National Institute of Standards and Technology 2:30 (920-4) Chemical Sensors for Monitoring the Efficiency of Electroless Plating Using Cyanide Free Gold Baths SAMUEL N KIKANDI, State University of New York at Binghamton, Omowunmi A Sadik 2:50 (920-5) Open-Vessel Microwave Assisted Extraction of Nicotine from Tobacco for Stable Isotope Measurements LAY-KEOW NG, Canada Border Services Agency, Marie-Josee Binnet, Pierre Lafontaine, Michel Hupe

ORAL SESSION

Session 410

ORAL SESSION
Environmental Mass Spectrometry
Tuesday Afternoon, Room S210C TBA, Presiding

Session 930

Fresh Frontiers in ICP Spectrometry and Electrospray Speciation - arranged by Akbar Montaser, The George Washington
University Tuesday Afternoon, Room S220B Akbar Montaser, The George Washington University, Presiding 1:30 (410-1) Advances in Instrumentation for ICP-MS ROBERT S HOUK, Iowa State University 1:50 (410-2) Advances in Laser Ablation Inductively Coupled Atomic Emission Spectrometry (LA-ICP-AES): Applications Integrating a Large Beam, Short Wavelength Laser with a Simultaneous Optical Detection System LAWRENCE M NEUFELD, New Wave Research 2:10 (410-3) Aerosol Characterization of Concentric Nebulizers Used in ICP Spectrometry JERRY DULUDE, Glass Expansion, Inc., Bobby Brezni, Salar Samii, Jonathan Levine, Kaveh Kahen, Akbar Montaser 2:30 (410-4) High Efficiency Nebulization and Aerosol Desolvation in Helium Inductively Coupled Plasma Mass Spectrometry KAVEH JORABCHI, George Washington University, Ryan McCormick, Jonathan Levine, Huiying Liu, Sang-Ho Nam, Akbar Montaser 2:50 (410-5) Progress in Coupling of Capillary and Nanoflow HPLC with ICP RYSZARD LOBINSKI, CNRS UMR 5034, Dirk Schaumloeffel, Pierre Giusti, Joanna Szpunar 3:10 Recess 3:25 (410-6) Cleaning ICP-MS Blanks Using Electrochemically Modulated Liquid Chromatography to Improve Detection Limits CORY T GROSS, Iowa State University, Robert S Houk 3:45 (410-7) Tunable Direct Injection Nebulization for Speciation of Palladium Compounds by High Performance Liquid ChromatographyInductively Coupled Plasma Mass Spectrometry KAVEH KAHEN, George Washington University, Levine A Jonathan, Samii Salar, Nechita M Cristina, SuAnn E OBrien Murdock, Akbar Montaser 4:05 (410-8) Innovative Sampling Techniques for Improving Productivity in Simultaneous CCD-Based ICP-OES CHRISTINE M RIVERA, Varian, Inc., Andrew Ryan 4:25 4:45 (410-9) (410-10) Withdrawn Withdrawn Session 950

1:30 (930-1) Determination of Phosphorus Speciation in Wetlands by High Resolution Mass Spectrometry with Complimentary Inductively Coupled Plasma and Electrospray Ionization WILLIAM T COOPER, Florida State University, Matt Heerboth, Vincent Salters 1:50 (930-2) Simultaneous Mass Spectrometry Using a Focal Plane Camera Array Detector GREGORY D SCHILLING, Indiana University, Francisco J Andrade, Roger P Sperline, M. Bonner Denton, Charles J Barinaga, David W Koppenaal, Gary M Hieftje 2:10 (930-3) Dealing with High Dissolved Solids in ICP-MS: A Comparison of Interfaces MANUEL VALIENTE, Universidad Autnoma De Barcelona, Jaime Pacheco, Isaac Brenner, Angel Vindel 2:30 (930-4) Rapid Determination of PBDE (Poly Brominated Diphenyl Ethers) without Extraction and GC YOSHIRO SHIOKAWA, ANELVA Technix Corporation, Harumi Maruyama, Masako Inoue, Yoshiki Hirano 2:50 (930-5) On the Potential Stir Bar Sorptive Extraction for Research, Investigation and Routine Analysis of Environmental Sample DAVID BENANOU, Anjou-Recherche Veolia Water, Elise Corbi, Dalel Benali, Carole Vincelet, John Cigana

ORAL SESSION
Environmental: Analysis of Organic Compounds
Tuesday Afternoon, Room S210D Howard (Skip) Kingston, Duquesne University, Presiding

Session 940

1:30 (940-1) Quadrupole GC/MS Identification and Quantification of Polybrominated Diphenyl Ethers (PBDE) JASON S COLE, Thermo Electron Corporation, Jessie Butler, Meredith Conoley, Eric Phillips, Trisa C Robarge 1:50 (940-2) Trace Level Determination of Organochlorine Pesticides in Environmental Samples Using Gas Chromatography: Negative Chemical Ionization Mass Spectrometry NIEVES SARRIN, KONIK-TECH, Ariadna Galve-Bosch, Jordi Reverter, Roger Gibert 2:10 (940-3) Capillary-Channeled Polymeric Fibers Employed as Solid Phase Extraction Media for Frontal Analysis of Phenol Solutions CHRISTINE STRAUT, Clemson University, R Kenneth Marcus 2:30 (940-4) Analysis of Steroid Hormones in Wastewater Treatment Plants JOHANNE BEAUSSE, CAE Veolia Environnement, Caroline Raulet, Gaela Herry, Francois Enguehard

ORAL SESSION

Fuels and Petrochemicals Characterization: Chromatographic Methods

Tuesday Afternoon, Room S230A John Baltrus, U.S. Department of Energy - NETL, Presiding 1:30 (950-1) Analysis of Oxygenates at Trace Levels in High Ethanol Content Gasoline Streams by Multi-Dimensional Gas Chromatography STEVE ELLIOTT, Separation Systems, Inc., Joaquin A Lubkowitz, Roberto I Meneghini

67

1:50 (950-2) Simultaneous GC/MS Analysis of Trace Oxygenates, Additive Oxygenates and Aromatic Compounds in Gasoline JAMES D MCCURRY, Agilent Technologies, Inc. 2:10 (950-3) Low Level Oxygenates in Ethylene: Methodology and Stability ROBERT BENESCH, Air Liquide, Laetotis Panquet, Malik Haouchine, Tracey Jacksier 2:30 (950-4) Faster GC Analysis of Denatured Ethanol with Simultaneous Water Content Determination JAMES MOTT, Shimadzu Scientific Instruments, Inc. 2:50 (950-5) Detailed Petroleum Analysis by GCxGC-TOFMS DONALD C HILTON, LECO Corporation, Tincuta Veriotti 3:10 Recess 3:25 (950-6) The On-line Simulated Distillation of Hydrocarbon Distillates ULRICH K GOKELER, Siemens 3:45 (950-7) Multi-Dimensional HPLC Determination of Aromatic Content and Mass Distributions in Asphalts and Heavy Distillates ASHRAF Z KHAN, Intertek Caleb Brett 4:05 (950-8) Enhancing the Performance and Reliability of Detailed Hydrocarbon Analysis with Two-Dimensional Gas Chromatography JAMES D MCCURRY, Agilent Technologies, Inc. 4:25 (950-9) Using Gas Chromatography and Curve Resolution to Quantify Contributions to Mixed Crude Oils SCOTT RAMOS, Infometrix, Inc., Brian Rohrback, Glenn Johnson, Russell Kaufman 4:45 (950-10) Improving Reliability of Detailed Hydrocarbon Analysis through Automated Alignment of Chromatograms SCOTT RAMOS, Infometrix, Inc., Brian Rohrback, Don Crider, Elizabeth Harvey

ORAL SESSION
Liquid Chromatography: General Applications
Tuesday Afternoon, Room S220D Luis A Colon, University at Buffalo, Presiding

Session 980

1:30 (980-1) Molecular Interactions Contributing to Aqueous Normal Phase Retention of Basic Analytes on Fluorinated and Other Polar HPLC Stationary Phases DAVID S BELL, Supelco/Sigma-Aldrich, Hugh M Cramer, Jacinth A McKenzie 1:50 (980-2) A Meaningful Protocol for Testing of the Silanol Activity of HPLC Columns BRIAN A BIDLINGMEYER, Agilent Technologies, Inc. 2:10 (980-3) Improving Reliability and Sensitivity of a Chromatographic Determination of Netilmicin JUN CHENG, Dionex Corporation, Petr Jandik, Xiaodong Liu 2:30 (980-4) Asymmertic Temperature Heating and Column Performance in HPLC Analysis SHUPING CHEN, Apotex Inc., Ken Mok, Anita Hui 2:50 (980-5) Determination of Protein Concentration Using AnionExchange Chromatography with Integrated Pulsed Amperometric Detection VALORAN P HANKO, Dionex Corporation, Jeffrey S Rohrer 3:10 Recess 3:25 (980-6) Procedure for Liquid Chromatographic Determination of Sulfonamides in Salmon with Postcolumn Derivatization and Fluorescence Detection MADELINE MCCOMISH, TIAX LLC 3:45 (980-7) Isocratic vs. Fast Gradient HPLC: Is There a Reason to do Isocratic HPLC? ADAM P SCHELLINGER, University of Minnesota 4:05 (980-8) 3D Amperometry: A Powerful New Detection Technology for HPLC JAMES A SCHIBLER, Dionex Corporation, Petr Jandik, Jun Cheng 4:25 (980-9) A New Specialty Column for Surfactant Analysis XIAODONG LIU, Dionex Corporation, Chris Pohl, Andrei Bordunov, Nebojsa Avdalovic 4:45 (980-10) Novel Polymer-Coated C18 Stationary Phase for Improved Peak Shapes of Basic Compounds under Neutral Conditions TAKETOSHI KANDA, Shiseido Company, Kazuko Takezawa, Atsushi Kobayashi, Xiami Xin, Hiroshi Kutsuna

ORAL SESSION
LC-MS Coupled with On-line Solid Phase Extraction
Tuesday Afternoon, Room S220C William L Budde, U.S. Environmental Protection Agency, Presiding

Session 960

3:25 (960-1) Reducing Sample Matrix Effects: An Argument for Solid Phase Extraction DIANE M DIEHL, Waters Corporation, Ziling Lu, Jeffrey R Mazzeo 3:45 (960-2) A Novel SPE Sorbent and a Novel LC-MS Method for Determination of Paraquat and Diquat In Environmental Samples MICHAEL S YOUNG, Waters Corporation, Kevin M Jenkins 4:05 (960-3) Trace Analysis of Sulfonylurea Herbicides in Environmental and Biological Samples Using Fully Automated On-line Solid Phase Extraction and Liquid Chromatography with Mass Spectrometry Detection MARIA ELENA Y CABUSAS, E.I. DuPont de Nemours & Co., Inc., Joseph P McClory, Timothy J Devine 4:25 (960-4) A New Air Sampling Technique Followed by On-line Desorbtion and LC-MS Analysis CARLO CRESCENZI, Stockholm University, Johanna Tollbck, Davide Tamburro, Carlsson Hkan 4:45 (960-5) Picogram Per Liter Level Determination of Estrogens in Natural Waters and Waterworks by a Novel, Fully Automated Online Solid-Phase Extraction-Liquid Chromatography-Electrospray Tandem Mass Spectrometry Method DAMI BARCEL, IIQAB-CSIC, Sara Rodriguez-Mozaz, Maria J Lopez de Alda

ORAL SESSION
Method Development in Gas Chromatography
Tuesday Afternoon, Room S210B Robert L Grob, Villanova University, Presiding

Session 1000

1:30 (1000-1) A MEMS Micro Gas Chromatograph EDWARD T ZELLERS, University of Michigan, William H Steinecker, Richard D Sacks, Joshua J Whiting, Michael P Rowe 1:50 (1000-2) Evaluation of a Single State Resistively Heated and Air-Cooled Thermal Modulator for Portable GC X GC MARK LIBARDONI, University of Michigan, Richard D Sacks 2:10 (1000-3) Technology to Validate the Adsorbent Packing Integrity of Thermal Desorption Tubes ANDREW TIPLER, PerkinElmer Life and Analytical Science, Neil T Plant, Michael D Wright 2:30 (1000-4) Headspace Analysis of Residual Solvents in Pharmaceuticals Using Flow-Modulation Gas Chromatography CHRISTOPHER M ENGLISH, Restek Corporation, Rebecca E Wittrig, Frank L Dorman 2:50 (1000-5) Statistical Peak Identification - Moving Beyond Retention Time to Improve Chromatographic Peak Identification JAMES D MCCURRY, Agilent Technologies, Inc. 3:10 Recess 3:25 (1000-6) A Novel Approach to the Electronic Control of the Flow Rate of Carrier Gas through a GC Capillary Column from a Thermal Desorption System Connected via a Fused Silica Transfer Line ANDREW TIPLER, PerkinElmer Life and Analytical Science, Richard G Edwards, Giuseppe N Coppola, Christopher G Mazza, Paul E Schallis, Neal R Green 3:45 (1000-7) Development of a Screening Analysis for a Wide Range of POPs Using GCxGC-ECD FRANK L DORMAN, Restek Corporation, Leslie A Vogt, Robert Grimminger, Paul D Schettler, Eric J Reiner, Jack Cochran

ORAL SESSION
LC-MS/Back to Basics
Tuesday Afternoon, Room S220C William L Budde, U.S. Environmental Protection Agency, Presiding

Session 970

1:30 (970-1) A Study of Ion Suppression Effects from Mobile Phase Additives and Solid Phase Extracts in Electrospray Ionization CLAUDE R MALLET, Waters Corporation, Jeffrey R Mazzeo, Ziling Lu 1:50 (970-2) Catch the HPLC Thief: Extra-Column Volume Steals Resolution DEREK SOUTHERN, Rheodyne LLC, Thomas Jupille 2:10 (970-3) A Systematic Look at Quantitative LC/MS Analysis YONGDONG WANG, Cerno Bioscience, Ming Gu 2:30 (970-4) A Critical Reagent for LC-MS: Ultrapure Water with Low Organic Content CECILIA REGNAULT , Millipore, Stephane Mabic 2:50 (970-5) Narrowing GPC Cleanup Elution Windows for PNAs, PCBs, PCDD/PCDFs Using Mobile Phase Modification DAVID THAL, Severn-Trent Laboratories, Kevin P Kelly

68

4:05 (1000-8) Advances in Stop-Flow GC x GC JAMES HARYNUK, University of Waterloo, Tadeusz Grecki, Zhiyue Zhu 4:25 (1000-9) Selection of Secondary Columns for Comprehensive Two-Dimensional Gas Chromatography ZHIYUE ZHU, University of Waterloo, James Harynuk, Tadeusz Grecki 4:45 (1000-10) Gas Chromatographic Method Development: The Scientific Method at Its Best ROBERT M HILLARD, GOW-MAC Instrument Company

3:25 (1020-6) Advances in Infrared Imaging Instrumentation AMANDA L JENKINS, Jasco, Inc., Richard A Larsen, Kenichi Akao 3:45 (1020-7) Direct Analysis of Precious Metals with a High Resolution Radio Frequency Glow Discharge Optical Emission Spectrometer PATRICK CHAPON, Jobin Yvon SAS, Olivier Bonnot, Emmanuel Fretel, Veronique Simeray, Mehalia Habaoudou 4:05 (1020-8) Applications Using a New CCD Simultaneous ICP Spectrometer GEOFF TYLER, Jobin Yvon SAS, Agnes Cosner, Sebastien Velasquez, Cendrine Dubuisson 4:25 (1020-9) Evaluation of Paper Deterioration in Library Materials by Pyrolysis-Gas Chromatography SHIN TSUGE, Frontier Laboratories , Chuichi Watanabe, Hajime Ohtani, Naoko Sonoda 4:45 (1020-10) Rapid Energy-Dispersive X-ray Fluorescence Techniques for Testing Compositional Variability in Materials STEVE J GOLDSTEIN, Los Alamos National Laboratory, Tim M Ellis, Stephen M Trujillo, Leisa B Davenhall, Dale Sivils

ORAL SESSION

Session 1010

Microfluidics: New Directions and Applications - arranged by Z Hugh Fan, University of Florida and Stephen C. Jacobson, Indiana University
Tuesday Afternoon, Room S230E Z Hugh Fan, University of Florida, Presiding 1:30 (1010-1) Microfluidic Architectures with Concentration Gradient and Cell Immobilization Functions for Cell-Based Assays MENGSU (MICHAEL) YANG, City University of Hong Kong, Cheuk Wing Li 1:50 (1010-2) Chemical Analysis of Subcellular Structures DANIEL T CHIU, University of Washington 2:10 (1010-3) Controlled Liposome Self-Assembly in Microfluidic Systems LAURIE E LOCASCIO, National Institute of Standards and Technology, Andreas Jahn, Wyatt N Vreeland, Michael Gaitan 2:30 (1010-4) Analyzing Genomes Using Microfluidics: Meeting the Demands of High Throughput for Clinical Applications MALGORZATA A WITEK, Louisiana State University, Steven A Soper 2:50 (1010-5) An Imaging System for Isoelectric Focusing of Proteins in Microfabricated Glass Devices HUGH FAN, University of Florida, Champak Das, Zheng Xia, Alexander Stoyanov 3:10 Recess 3:25 (1010-6) Microdialysis Sampling Coupled to Microchip CE for Monitoring Biochemical Processes SUSAN M LUNTE, University of Kansas, Bryan Huynh, Barbara A Fogarty, Pradyot Nandi 3:45 (1010-7) Microfabricated Devices for Chemical Analysis STEPHEN C JACOBSON, Indiana University 4:05 (1010-8) Novel Materials for the Coating of Microfluidic Devices CHRISTOPHER CULBERTSON, Kansas State University, Gregory T Roman 4:25 (1010-9) Development of Integrated Microchip Interface Technology for Automated Processing JEROME P FERRANCE, University of Virginia, James P Landers, Christelle Guillo, A. Bruno Frazier, Ki-Ho Han 4:45 (1010-10) Micro Analytical Systems by Composing Microfluidic Devices, Detection Devices, and Control Systems MANABU TOKESHI, Kanagawa Academy of Science and Technology

ORAL SESSION
Separation Science: Environmental Applications

Session 1030

Tuesday Afternoon, Room S210C Mary Ellen P McNally, E. I. DuPont de Nemurs and Company, Presiding 3:25 (1030-1) Determination of Trace Perchlorate Using a New Hyperbranched AS-20 Ion Exchange Separator Column and a New Cryptand Concentrator Column with EGC Generated NaOH Eluent LAURENCE A WOODRUFF, Dionex Corporation, Chris Pohl, Douglas Later, Rong Lin, Brian DeBorba 3:45 (1030-2) Preconcentration, Extraction, Separation, Sepciation and Trace Determination of Arsenic with Calix(6)-Fullerene-C60-61methanoformohydroxamic Acid JIGAR J SHAH, C.U. Shah Science College 4:05 (1030-3) Rapid Speciation of Chromium in Aqueous Samples by Colorimetric Solid Phase Extraction JAMES S FRITZ, Iowa State University, Steven A Steiner, Marc D Porter 4:25 (1030-4) Sol-Gel Organic-Inorganic Hybrid Materials for Selective Enrichment and Ultra-Trace Analysis of Organic Pollutants in Aqueous Media ABDUL MALIK, University of South Florida, Abuzar Kabir, Wen Li, Tae-Young Kim, Khalid Alhooshani 4:45 (1030-5) Pyrolysis-Comprehensive Two Dimensional GC-TOFMS Study of Complex Samples for the Mars Analytical Chemistry Experiment (MACE) MEGAN MCGUIGAN, University of Michigan, Richard D Sacks, Hunter Waite

ORAL SESSION

Session 1040

Single Molecule Detection and Spectroscopy: A 15-Year Perspective - arranged by Steven A Soper, Louisiana State University
Tuesday Afternoon, Room S230B Steven A Soper, Louisiana State University, Presiding 1:30 (1040-1) Microfluidics and Single Molecule Detection: A Logical Choice for Real-Time Reporting of BioMarkers STEVEN A SOPER, Louisiana State University 1:50 (1040-2) Single-Molecular Detection of Unamplifield Nucleic Acid Sequences PETER M GOODWIN, Los Alamos National Laboratory 2:10 (1040-3) Fluorescence Cross-Correlation Spectroscopy: New Perspectives on the Racetrack ALAN K VAN ORDEN, Colorado State University 2:30 (1040-4) Single-Molecule Study of Subcellular Function in Single Living Cells X, NANCY XU, Old Dominion University, William Brownlow, Sophia Kyriacou, Qian Wan, P Nallathamby 2:50 (1040-5) New Applications of Fluorescence Correlation Spectroscopy KENNETH D WESTON, Florida State University, Ying Xiao, Paul C Brister, William Milo, Abhijit Potnis, Volker Buschmann, Kalyan K Kuricheti 3:10 Recess 3:25 (1040-6) Design and Development of a Switchable Unidirectional Photonic Wire MARKUS SAUER, University of Bielefeld 3:45 (1040-7) Continuous Single-Molecule Detection without Immobilization or Photon Count Statistics of Intensity Traces: A New Perspective ZENO FOLDES-PAPP, Graz Medical University, Mamoru Tamura, Masataka Kinjo

ORAL SESSION
Novel Techniques in Materials Characterization

Session 1020

Tuesday Afternoon, Room S220F Steven B Dorn, General Electric Silicones Analytical Technology, Presiding 1:30 (1020-1) The Effect of sp2 Bonded Nondiamond Carbon Impurity on the Physical and Electrochemical Properties of Boron-Doped Polycrystalline Diamond Thin-Film Electrodes JASON A BENNETT, Michigan State University, Jian Wang, Yoshiyuki Show, Greg M Swain 1:50 (1020-2) Surface-Enhanced Raman Spectroscopy Studies of 1,4-Phenylene Diisocyanide Adsorption on Transition Metal Surfaces SHOUZHONG ZOU, Miami University, Scott Gruenbaum, Matthew W Henney, Sachin Kumar 2:10 (1020-3) Surface Modifications of a Bioactive Glass Immersed in TRIS-Buffered Solution: A Multi-technical Spectroscopic Study CLAUDIA L BIANCHI, University of Milan, Francesca Bonino, Marta Cerruti, Alessandro Damin, Claudio Morterra, Alessandra Perardi 2:30 (1020-4) Problem Solving Using Infrared Spectrochemical Imaging ELLEN V MISEO, Varian Inc, Wayne Jalenak 2:50 (1020-5) Materials Analysis Using a High Performance EDXRF Instrument RAVI YELLEPEDDI, Thermo Electron Corporation, Anton Kleyn 3:10 Recess

69

4:05 (1040-8) Trying to Track Single Fluorescent Molecules in 3 Dimensions JAMES H WERNER, Los Alamos National Laboratory, Peter M Goodwin, Mircea Cotlet 4:25 (1040-9) Monte Carlo Simulations for Single-Molecule Fluorescence Applications LLOYD M DAVIS, University of Tennessee Space Institute 4:45 (1040-10) Pulsed Interleaved Excitation (PIE) and Time Resolved Confocal Fluorescence Microscopy with Single Molecule Sensitivity FELIX KOBERLING, PicoQuant GmbH, Benedikt Kraemer, Matthias Patting, Michael Wahl, Uwe Ortmann, Rainer Erdmann

(1060-4 P) Effect of Physical Training in the Blood, Iron and Haemoglobin of Indian Female Long Distance Runners KAMALJIT SINGH , Govt. Medical College, Munish Kumar (1060-5 P) Multivariate 3-Way Data Analysis to Identify Specific Plants in the Diets of Free Ranging Herbivores CHARLOTTE N SISK, New Mexico State University (1060-6 P) Effect of Pantothenic Acid Administration on the Cardiovascular Fitness of State Level Long Distance Runners MANJIT S SOHAL, Punjabi University, Munish Kumar, Anju Bajaj (1060-7 P) Validating Browser-Based Applications: Debunking the Myths FERNANDO CASANOVA, LabVantage Solutions, Inc. (1060-8 P) Application of Near-Infrared and Multivariate Calibration for Detection of Infestation in Small Fruit BOYAN PESHLOV, University of Maine, Darrell W Donahue (1060-9 P) Surface Inspections with a Novel Hand Held IR Spectrometer MARTIN M SZCZESNIAK, Surface Optics Corporation, Michael Beecroft, John Matsumoto, Barry Smith (1060-10 P) Proficiency Testing Scheme for Quality Control in Laboratories ADRIANA C FERREIRA, SENAI-CETIND, Srgio L Motta (1060-11 P) How Do You Determine a Content of Aluminum in Parenteral Solutions? NAOKI FUJITA, Nomura Chemical Co., Ltd., Norikazu Nagae, Hideki Kobayashi, Toshiyuki Enami (1060-12 P) New Software Programs for the Activated Carbon Adsorption Industry HENRY G NOWICKI, PACS Testing, Consulting, and Training (1060-13 P) Electronic Nose for Wax Fragrance Throw Assessments VINCENT SCHMITT, Alpha M.O.S., Joey Viljoen, Laura Hein McElduff (1060-14 P) Characterization of Acryl Fiber as Industrial Polymer FAHIMA M HELALY, National Research Centre (1060-15 P) Development of Beryllium inorganic Standard Solution MIURA TSUTOMU, National Metrology Institute of Japan, Hioki Akiharu

NEW PRODUCT FORUM

Advances in Spectroscopic Instrumentation
Tuesday Afternoon, Room S220A Joanne H Smith, Edinboro University of Pennsylvania, Presiding

Session 1045

1:30 (1045-1) New Portable X-Ray Fluorescence Analyzer Uses PDA Software to Resolve Difficult Applications DONALD SACKETT, InnovX Systems, Inc. 1:50 (1045-2) 3-D Soil Characterization Via EDXRF and Advanced Cone Penetrometer Technology JOHN SCHINDLER, Austin AI, LLC 2:10 (1045-3) Innovations in ICP Sample Introduction JERRY DULUDE, Glass Expansion, Inc. 2:30 (1045-4) InfraLUM FT-NIR Whole Grain Analyzer SVETLANA BALASHOVA, Lumex International, Nikolay Sveshnikov 2:50 (1045-5) Multi-Channel, Multi-Spectral Imaging Spectrometer DAVID BANNON, Headwall Photonics, Inc.

POSTER SESSION

Session 1050

Afternoon posters will be on display from 1:30 PM to 4:30 PM with authors present from 1:30 PM to 3:30 PM. The posters will be located on the Southeast corner of the Exposition floor (beginning Aisle 2900).

(1060-16 P) SPME GC/MS Analyses of Perchloroethylene in Water Samples Generated from a Cleaning Line Product DIANA J KELLEY, Alcoa , Christopher Retarides, John P Auses (1060-17 P) Withdrawn (1060-18 P) Withdrawn (1060-19 P) Interpreting the Regulatory Basis for Computer Systems Validation: Where Does It Say What We Have to Do? JOHN L PETERSON, DCSS, Inc. (1060-20 P) An Approach to Validating Barcode Printers, Scanners, and Labels JOHN L PETERSON, DCSS, Inc. (1060-21 P) The Critical Document for Computer Validation JOHN READ, Thermo Electron Corporation (1060-22 P) Automating the Installation Qualification/Operational Qualification for Multi-vendor Instrumentation with a Laboratory Content Management System SOHEIL SAADAT, Scientific Software, Inc., Edward C Long (1060-23 P) Calibration of NDIR and NDUV Gas Analyzers with Internal Calibration Cells JOSEPH W WORTHINGTON, ABB, Inc. (1060-24 P) Multi-layer Imaging Techniques Applied to Plaster Porous Structures 3D Modeling BONIFAZI GIUSEPPE, Universit di Roma La Sapienza (1060-25 P) A Seamless System for Automated Computer Data Backup JAY S OSBORNE, Wright State University, Joseph G Solch, Roger K Gilpin (1060-26 P) Application of Computer Algorithms as a Tool in the Analysis of Mass Spectral Data EVALDO DEARMAS, Thermo Electron Corporation (1060-27 P) Lab Automation and the Human Element in the Continuing Evolution of the Quality Systems Program MICHAEL J HERDLICK, ATEL (1060-28 P) Creation and Utilization of a Cost Effective, Searchable Database Containing New and Legacy Toxicology and Chemistry GLP Studies and Data DENISE B TAYLOR, Arch Chemicals, Inc., George Polson, Nicholas P Skoulis, Nichelle M Oberson (1060-29 P) Techniques for Developing 21 CFR Part 11 Compliant Software Programs ERIC REFFETT, National Instruments (1060-30 P) Software Platform Simplifies Development of Analytical Instrumentation SHELLEY GRETLEIN, National Instruments

Chemometrics
Tuesday Afternoon (1050-1 P) Application of Emission-Excitation Fluorescence Spectrum for the Determination of Plants in Goat Diets CHERYL PEZZOTTI, New Mexico State University, Charlotte N Sisk, Safwan Obeidat, Gary D Rayson, Dean Anderson (1050-2 P) Model Validation in Chemical Images Produced by Multivariate Optical Elements RYAN PRIORE, University of South Carolina, Michael L Myrick (1050-3 P) Multivariate Spectral Calibration Using Regularization with Smoothing FORREST R STOUT, Idaho State University, John H Kalivas (1050-4 P) Application of Orthogonal Signal Correction and Partial Least Squre for the Simultaneous Determination of Aspirin, Caffeine and Acetaminophen Based on UV Spectra HUGH ZHANG, GlaxoSmithkline, WengLi Yoon, Janet Mashkovich, John Sienkiewicz, Benjamin Costa (1050-5 P) Determination of Water 17O and 18O Enrichment Using MS JOHN E KUO, Isotec, Sigma-Aldrich, Michael May, Michael Gray, Lisa Roth, Igor Knyazhansky, C T Tan

POSTER SESSION
Data Manipulation, Quality, and Validation
Tuesday Afternoon

Session 1060

(1060-1 P) A Comparative Study of Energy Intake and Energy Expenditure in Diabetes and Control Group MUNISH KUMAR, Punjabi University, Manjit S Sohal, Anju Bajaj (1060-2 P) AnIML and Academe: How Faculty Will Benefit from AnIML STUART J CHALK, University of North Florida (1060-3 P) Be Prepared for the Unexpected: Fast and Flexible Chromatography Data Mining Using a Combination of Advanced Searching and Reporting Tools JOZSEF MEDVE, Dionex Corporation, Wulff Niedner, Frank Arnold

70

(1060-31 P) Determination of the Spectral Characteristics of Confocal Spectral Imaging Systems and Comparability of Data UTE RESCHGENGER, BAM, Katrin Hoffmann, Roland Nitschke, Axel Engel, Dietmar Pfeifer, Angelika Hoffmann (1060-32 P) Traceable Emission Standards as Simple Tools for the Characterization of Fluorescence Measuring Systems UTE RESCHGENGER, BAM, Dietmar Pfeifer, Christian Monte, Angelika Hoffmann, Monika Spieles

(1070-23 P) LIMS in Chemical Analysis Section of Testing Center in Baosteel ZHAOHUI FAN, Baoshan Iron & Steel Co., Ltd., Yi Znag (1070-24 P) A Practice of LIMS Development and Application YINGYING CHEN, Baoshan Iron & Steel Co., Ltd. (1070-25 P) Implementing Business Logic within a LIMS to Reduce Manual Data Review and Increase Productivity ROBERT D WALLA, Astrix Technology Group, Michael S Zachowski (1070-26 P) Proposed International Standard for EMR Spectroscopic Data ROBERT J LANCASHIRE, The University of the West Indies (1070-27 P) Streamline Development of Instrument Control and Interface Applications DANY CHEIJ, National Instruments

POSTER SESSION
Laboratory Informatics and Management
Tuesday Afternoon

Session 1070

(1070-1 P) Minimizing Validation Cost in Chromatography Data Systems WOLFGANG R VOLMER, VWR International (1070-2 P) Achieving a Paperless Laboratory with Enterprise Content Management DALE YOUNG, Scientific Software, Inc., Edward C Long (1070-3 P) Open Automation in a Laboratory Software Framework STEVE MILLER, Scientific Software, Inc., Edward C Long (1070-4 P) 21 CFR Part 58: Managing People and Processes: How LIMS Helps in Compliance with Good Laboratory Practice (GLP) FERNANDO CASANOVA, LabVantage Solutions, Inc. (1070-5 P) Controlled Reports in Regulated Laboratory Environments CHAITANYA DIWADKAR, Applied Biosystems, Michael Wong (1070-6 P) Managing Multiple Instrument Types and Equipment Manufacturers within the Regulated Laboratory Environment DAN FURLANO, Thermo Electron Corporation (1070-7 P) Withdrawn (1070-8 P) Integration with Microsoft Excel and LIMS for Reporting ANSON ELLSTROM, Accelerated Technology Laboratories, Inc., David Schlabach, Mitch Garner (1070-9 P) A Laboratory Software Framework for Multi-vendor Chromatography Instrumentation KEVIN GEORGE, Scientific Software, Inc., Edward C Long (1070-10 P) Enhance Browser-Based LIMS Configuration with WEBFlows RALPH GOLDBERG, LabVantage Solutions, Inc. (1070-11 P) Operational Data Management: Completing the Protection of Your Data JIM JENKINS, LabVantage Solutions, Inc. (1070-12 P) Electronic Notebooks PATRICK J KELLY, Synnestvedt & Lechner LLP, Robert D Walla (1070-13 P) Application of Six Sigma to LIMS Implementation DONALD KOLVA, Accelerated Technology Laboratories, Inc., Fred Rider (1070-14 P) The Selection, Installation and Implementation of a COTS LIMS at the Birmingham Water Works and Sewer Board CHRISTINE PASZKO, Accelerated Technology Laboratories, Inc., David Schlabach, Desiree Alexander, Anton Jones, Drusilla Hudson (1070-15 P) Key Elements of a Laboratory Information Management (LIMS) Request for Proposal KIM PASZKO, Accelerated Technology Laboratories, Inc. (1070-16 P) Successful Use of Rapid Prototyping for Generating and Refining LIMS Requirements ELENA S PETERSON, Pacific Northwest National Laboratory, Gordon A Anderson (1070-17 P) Implementing A New Software Framework for the Laboratory SOHEIL SAADAT, Scientific Software, Inc., Edward C Long (1070-18 P) Technical Considerations in Remote LIMS Access via the World Wide Web DAVID SCHLABACH, Accelerated Technology Laboratories, Inc., William Ulma (1070-19 P) Integrating Analytical Laboratory Operations with Business Process Management (BPM) DAN SUDLIK, Scientific Software, Inc., Edward C Long (1070-20 P) Implementing A Paperless Laboratory by Extending the Functionality of a LIMS ROBERT D WALLA, Astrix Technology Group, Michael S Zachowski (1070-21 P) A Successful Approach to a LIMS Assessment and Upgrade MICHAEL S ZACHOWSKI, Astrix Technology Group, Robert D Walla (1070-22 P) Extending Chromatography Data System by Automation Capabilities TOSHINOBU YANAGISAWA, Shimadzu Corporation, Okiyuki Kunihiro, Yoshihiro Hayakawa, Atsushi Yoshida, Yasuhiro Funada, Takayuki Kihara, Teruhisa Ueda

POSTER SESSION
Preparation of Samples for Bioanalytical Applications
Tuesday Afternoon

Session 1080

(1080-1 P) Using Chemical Fractionation to Increase the Number of Resolved Protein Spots in Two Dimensional Electrophoresis G. REID ASBURY, GE Healthcare, Huang Jing (1080-2 P) A Novel SPE Resin for High Throughput Bioanalysis MATTHEW CLEEVE, Argonaut Technologies, Inc., Anne Howells, Stephen Plant, Scott Merriman, Geoff Davies, Rob Johnston, Helen Lodder, Owen Gooding, Jeff Labadie, Claire Desbrow, Richard Calverley, Michael F Burke (1080-3 P) Improved High Throughput Protein Precipitation Using a Novel Filtration Microplate MATTHEW CLEEVE, Argonaut Technologies, Inc., Anne Howells, Geoff Davies, Scott Merriman, Jeff Labadie, Richard Calverley, Claire Desbrow (1080-4 P) Pressurized Solvent Extraction of Nutritional Compounds from Herbal Teas AL KAZIUNAS, Applied Separations, Rolf Schlake, Martin Fetner, Elena Ostra, Pavel Karasek, Michal Roth (1080-5 P) (1080-6 P) Mass Transport Studies of Enhanced Microdialysis Relative Recovery of Proteins BRIAN M RUDDY, Rensselaer Polytechnic Institute, Xiaoping Ao, Timothy J Sellati, Julie Stenken (1080-7 P) Parameters Affecting Enhanced Microdialysis of Macromolecules JENNIFER S SILVERSTEIN, Rensselaer Polytechnic Institute, Xiaoping Ao, Xiangdan Wang, Julie Stenken (1080-8 P) Evaluation of a Calibratable Fluidic Blotting System DOYLE W STEWART, Hamilton Company (1080-9 P) Effect of Acetonitrile Concentration on In-gel Tryptic Digestions TERRY A STOMING, GE Healthcare, G. Reid Asbury, Stacey M Loyland (1080-10 P) Is Ion Exchange Based Solid Phase Extraction Efficient for Concentration/Clean-up of Quarternary Ammonium Compounds from Aqueous and Plasma Samples? KRISHNA KALLURY, Phenomenex, Inc., Shahana Huq, Art Dixon (1080-11 P) Fluorescence Spectroscopy: A Tool for the Simultaneous Determination of Enzymes CHRISTEL HEMPEN, University of Twente, Uwe Karst (1080-12 P) Novel Immunoassay Method: Detection of Hormones in Saliva Using Molecular Lighthouses PETKUS MATTHEW, Arizona State University (1080-13 P) The Behavior of Flexible Molecules Dissolved in Room Temperature Ionic Liquids TAYLOR A MCCARTY, University at Buffalo, Phillip M Page, Frank V Bright (1080-14 P) Optimization of Nitrogen Dioxide with a Chemiluminescence Aerosol Detector MARIA-PAMELA MONTEROLA, University of Florida, Ronald J Whiddon, Benjamin W Smith, Nicolo Omenetto, James D Winefordner (1080-15 P) Site Selective Energetics of Rare-Earth Metal in Binding to Plant Cell Walls Using Metal Luminescence Spectroscopy DEBBIE D SERNA, New Mexico State University, Amber C Telles, Gary D Rayson (1080-16 P) Toward the Development of Resorbable Laminated Repair Membranes LORAINE T TAN, State University of New York at Buffalo, Frank V Bright (1080-17 P) Apparent Binding Affinities of the Uranyl Ion to a Datura Innoxia Biomaterial AMBER C TELLES, New Mexico State University, Debbie D Serna, Gary D Rayson (1080-18 P) Indirect Fluorescence Determination of Amino Acids and Peptides via a Shielding Effect on the UV Photolysis of 2Phenylbenzimidazole-5-sulfonate CHRISTOPHER R WILSON, Miami University, Neil D Danielson

71

(1080-19 P) Development of a Real Time Bioaerosols Detection System XIHONG WU, University of Florida, Jonathan Merten, Nicolo Omenetto, Benjamin W Smith, James D Winefordner (1080-20 P) Quantum Dot Bioconjugates for Simultaneous Detection of Escherichia coli O157:H7 and Salmonella Typhimurium LIJU YANG, University of Arkansas, Xiaoli Su, Yanbin Li (1080-21 P) A Generic Approach for Beryllium and Ligand Binding Study XIAOMEI YAN, Los Alamos National Laboratory, Babetta L Marrone (1080-22 P) Monitoring the Phosphorylation of Nucleic Acids in Real-time Using Molecular Beacons TANG ZHIWEN, Hunan University (1080-23 P) Direct Synthesis of an Oligonucleotide-poly (Phenylene Ethynylene) Conjugate for Biosensing Applications CHAOYONG YANG, University of Florida, Mauricio Pinto, Kirk Schanze , Weihong Tan (1080-24 P) Withdrawn (1080-25 P) Towards the Development of Site Selectively Tagged and Templated Xerogels (SSTTXs) as Sensor Platforms ELLEN L SHUGHART, University at Buffalo, Frank V Bright (1080-26 P) The Importance of Ion-Exchange Capacity in Mixed-Mode SPE Technology for Pharmaceutical Bioanalysis AN TRINH, Supelco/SigmaAldrich, Yuhui Yang, David S Bell (1080-27 P) Enhanced Selectivity from Mixed-Mode SPE Technology for Pharmaceutical Bioanalysis DAVID S BELL, Supelco/Sigma-Aldrich, An Trinh, Carmen T Santasania, Yuhui Yang, Michael Ye (1080-28 P) Drug Screening Using MicroExtraction in Packed Syringe (MEPS)/ LC-MS Utilizing Monolithic-Based Sorbent Material MOHAMED ABDEL-REHIM, AstraZeneca, Zeki Altun, Jagerdeo Eshwar, Lars Blomberg (1080-29 P) Purification and Analysis of an Influenza Peptide Using Novel Reversed Phase Polymeric Supports FISHER R JON, Rohm and Haas Company, John J Maikner, Amie S Gehris, Marlin K Kinzey, Mark Vander Hoff (1080-30 P) Rapid Lysis of Bacillus subtilis Spores Followed by Detection by Real-Time PCR DAVID L PERKINS, University of South Carolina, Shanavaz L Nasarabadi, Jerry Chance Carter, Anthony J Makarewicz, Fred P Milanovich, Bill W Colston, Burt V Bronk, Michael L Myrick

(1090-11 P) Comparison and Assessment of Water Purification Technologies Using Ion Chromatography STEPHANE MABIC, Millipore, Elodie Castillo, Ichiro Kano (1090-12 P) Purification of Products of Organic Synthesis Using Flash Chromatography BORIS POLANUYER, Supelco/Sigma-Aldrich, Lew Kurtzman, Dan Vitksuke, Michael Ye, Tom Henderson, Brendan Nye, Becky Denham, Shaoyin Wang (1090-13 P) Flash Chromatography Method Development BORIS POLANUYER, Supelco/Sigma-Aldrich, Michael Ye, Dan Vitkuske, Tom Henderson (1090-14 P) High Throughput Digestion of Clinical, Biological and Environmental Materials in a Large Volume, High Pressure Microwave Reactor System KENNETH J BOROWSKI, Milestone Inc. (1090-15 P) Analysis of Trace Amount of Bank Dye and Lachrymator from Exploding Bank Devices by Solid Phase Microextraction/Mass Spectrometry ESHWAR JAGERDEO, Federal Bureau of Investigation , Jeffrey N Leibowitz, Lisa G Schumacher, David A Henningsen, Marc LeBeau (1090-16 P) Improving Automated Liquid Handler Performance through Reliable Volume Delivery Measurements JOHN T BRADSHAW, Artel, Inc. (1090-17 P) Multicapillary SPE Cartridges YURI P BELOV, ChromBA Inc., S. Ramachandran

WEDNESDAY, MARCH 2, 2005

SYMPOSIUM
Corporation Wednesday Morning, Room S210A Christine M Wehlburg, MITRE Corporation, Presiding 8:30 Introductory Remarks - Christine M Wehlburg Session 1100

Bomem-Michelson Award - arranged by Christine M Wehlburg, MITRE

POSTER SESSION
Sampling and Sample Preparation
Tuesday Afternoon

Session 1090

8:35 Presentation of the 2005 Bomem-Michelson Award to Paul W Bohn, University of Illinois by Christine M Wehlburg, MITRE Corporation 8:40 (1100-1) Nanofluidics and Mass-Limited Chemical Analysis: Lessons Learned from Spatially-Defined Molecular Spectroscopy PAUL W BOHN, University of Illinois at Urbana 9:15 (1100-2) Raman Spectroscopy: A Probe of Polymeric Fiber Structure at the Molecular Level BRUCE CHASE, DuPont 9:50 (1100-3) Surface Enzyme Kinetics for Ultrasensitive SPR Imaging Measurements of Biopolymer Microarrays ROBERT M CORN, University of California at Irvine 10:25 Recess 10:40 (1100-4) Preconcentration of DNA Using a Hydrogel-Based Transport Modulator RICHARD M CROOKS, Texas A&M University, Rahul R Dhopeshwarkar, Li Sun 11:15 (1100-5) Digital Microfluidics for Proteomics Analyses with MALDI-MS, Synthesis, and Analytical Assays ROBIN L GARRELL, University of California at Los Angeles

(1090-1 P) Determination of Atrazine and Selected Respective Metabolites Using Strong Cation Exchange Resins CIERRA CROSS, Western Kentucky University, Eric D Conte (1090-2 P) Cross-Contamination in the Analysis of VOCs in Rock Samples MARIA GRECKI, University of Waterloo, Beth L Parker (1090-3 P) New Challenging Organic Contaminant in High Purity Water: Endocrine Disrupters and Persistent Organic Pollutants NAOE ISHII, Millipore, Stephane Mabic, Cecilia Regnault (1090-4 P) A New Look at SPE for EPA Method 1664A AL KAZIUNAS, Applied Separations, Amy Kindland, Joe Stefkovich (1090-5 P) Air Monitoring at Parts Per Trillion Levels for Risk Assessment and Indoor Air Quality Studies VICKIE H PAUL, CDS Analytical, Inc., Thomas P Wampler, Charles P Zawodny (1090-6 P) Improved Method for Sampling and Analysis of Polynuclear Aromatic Hydrocarbons (PAH) VICKIE H PAUL, CDS Analytical, Inc., Thomas P Wampler, Charles P Zawodny (1090-7 P) Investigation of a Carbowax Surface-Coated Solid Phase Microextraction Device for GC/MS Analysis of Polar Volatile Organic Compounds MICHAEL J SAMIDE, Butler University, Olujide T Akinbo, Bryan E Frauhiger (1090-8 P) Removal of Calcium and Magnesium Ions in Solutions of Agricultural Waste RATANA SANANMUANG, Naresuan University, Sirinuch Jindaraksa (1090-9 P) Automated Liner-Exchange for GC-Injectors: New Concepts for Handling Dirty Samples EIKE KLEINE-BENNE, Gerstel GmbH & Co. KG, Andreas Hoffmann, Dirk Bremer, Bernd Rose, Volkmar Heinke, Karsten Kuhr (1090-10 P) Investigation of Elutions from a Surfactant Immobilized Solid Phase Extraction Sorbent Based Upon the Hydrophobicity of the Trapped Species QING ZHAO, Western Kentucky University, Sara A Huss, J. Kyle Autry, Kendra R Reid, Eric D Conte

SYMPOSIUM

Session 1110

Analytical Chemistry Challenges in the Study of Suspended Particles in the Troposphere - arranged by George Agnes, Simon
Fraser University Wednesday Morning, Room S210C George Agnes, Simon Fraser University, Presiding 8:30 Introductory Remarks - George Agnes

8:35 (1110-1) Laboratory Studies of the Impact of Mineral Dust Aerosol on Chemistry, Climate and Health VICKI GRASSIAN, University of Iowa 9:10 (1110-2) Phase Transitions of Atmospheric Aerosols: New Approaches and Results ALLAN K BERTRAM, University of British Columbia, Ben Murray, Matt Parsons, Daniel Knopf 9:45 (1110-3) Macromolecular Compounds in Tropospheric Aerosol Particles RENATO ZENOBI, ETH Zrich

72

10:20

Recess

SYMPOSIUM

Session 1140

10:35 (1110-4) Real-Time Measurements of Ambient Ultrafine Particle Composition: How Are They Performed and What Do They Tell Us about the Air We Breathe? MURRAY V JOHNSTON, University of Delaware 11:10 (1110-5) An Apparatus and Methodology for Discrete Particle Synthesis and Their Controlled Deposition onto Individual Lung Cells GEORGE R AGNES, Simon Fraser University, Allen Haddrell, Stephan van Eeden

Microfluidics: New Directions and Applications - arranged by Z Hugh Fan, University of Florida and Stephen C Jacobson, Indiana University
Wednesday Morning, Room S230E Z Hugh Fan, University of Florida, Presiding 8:30 Introductory Remarks - Z Hugh Fan

8:35 (1140-1) Microfluidic's Role in Analytical Biology D. JED HARRISON, University of Alberta

SYMPOSIUM

Session 1120

Bacteria Taxonomy and Protein Expression Studies by Mass Spectrometry - arranged by Charles L Wilkins, University of Arkansas
Wednesday Morning, Room S220E Charles L Wilkins, University of Arkansas, Presiding 8:30 Introductory Remarks - Charles L Wilkins

9:10 (1140-2) Microfluidic Devices for Health-Related Analyses MARK A BURNS, University of Michigan, Brian Johnson, Rohit Pal, Ming Yang, Rongsheng Lin, Nimisha Srivastava, S. Zafar Razzacki, Kenneth J Chomistek, Dylan C Heldsinger, Moon-Bin Yim, Victor M Ugaz, Madhavi Krishnan, Vijay Namasivayam, Oveta Fuller, Ronald G Larson, David T Burke 9:45 (1140-3) Microfluidics Based Chemical Separation and Reaction Schemes ANDREAS MANZ, ISAS - Institute for Analytical Sciences 10:20 Recess 10:35 (1140-4) Microfluidics: What is left? J MICHAEL RAMSEY, University of North Carolina at Chapel Hill 11:10 (1140-5) Microfluidics and Cell Behavior DAVID J BEEBE, University of Wisconsin at Madison

8:35 (1120-1) Proteomics Strategies for Rapid Characterization of Microorganisms VLADIMIR DOROSHENKO, Science and Engineering Services Inc., Gavin Black, Catherine Fenselau, Patrick Pribil, Stephen Swatkowski, Elizabeth Patton 9:10 (1120-2) Rapid Proteomics Analysis of Prokaryotic Organisms Using Accurate Mass Measurement JONATHAN AMSTER, University of Georgia 9:45 (1120-3) Proteome and Metabolome Profiling for Microbial Characterization ROY GOODACRE, University of Manchester, Seetharaman Vaidyanathan 10:20 Recess 10:35 (1120-4) A Proteomic Approach to the Discovery of New Molecular Targets for Differentiating Pathogenic Bacteria TRACIE L WILLIAMS, Food and Drug Administration, Steven M Musser 11:10 (1120-5) Characterization of Bacteria and Recombinant Bacteria Proteins by Fourier Transform Mass Spectrometry CHARLES L WILKINS, University of Arkansas, Jeffrey J Jones, Jackson O Lay

SYMPOSIUM
- arranged by Richard A Palmer, Duke University Wednesday Morning, Room S230B Richard A Palmer, Duke University, Presiding 8:30

Session 1150

New Approaches to Dynamic Infrared Using Sample Modulation

Introductory Remarks - Richard A Palmer

8:35 (1150-1) Dynamic Infrared Linear Dichroism Study of the Temperature-Dependent, Viscoelastic Behavior of a Poly(ester urethane) RICHARD A PALMER, Duke University, Yanqia Wang, Steven R Aubuchon, Jon R Schoonover 9:10 (1150-2) Dynamic Infrared Linear Dichroism Using Planar Array Infrared Spectroscopy CHRISTIAN PELLERIN, University of Montreal, John F Rabolt, Bruce Chase

SYMPOSIUM
arranged by Luis A Colon, University at Buffalo Wednesday Morning, Room S220D Luis A Colon, University at Buffalo, Presiding 8:30 Introductory Remarks - Luis A Colon

Session 1130

Breaking the Pressure Barriers: The New Directions in HPLC -

9:45 (1150-3) Acquisition of Mid-Infrared Spectra with Millisecond to Microsecond Temporal Resolution from Events that Are Not Necessarily Repeatable CHRIS SNIVELY, University of Delaware, Christian Pellerin, Bruce Chase, John F Rabolt 10:20 Recess 10:35 (1150-4) Dynamic Infrared Spectroscopies with the ACCoupled Dispersive Method; Nanosecond Time-Resolved Infrared Spectroscopy and Infrared Electro-Absorption Spectroscopy HIRO-O HAMAGUCHI, The University of Tokyo 11:10 (1150-5) Modulated Excitation Spectroscopy of Biological Samples URS P FRINGELI, University of Vienna, Dieter Baurecht, Michael Schwarzott, Norbert Hassler, Marko Jovanovic

8:35 (1130-1) Investigations of Column Performance in Ultra-High Pressure Capillary Chromatography JAMES W JORGENSON, University of North Carolina at Chapel Hill, Scott Mellors, Jason C Link, Dawn Stickle, John W Eschelbach, Will Thompson, Charles R Evans 9:10 (1130-2) Practicality of Ultrahigh Pressure LC for Fast Separations MILTON L LEE, Brigham Young University, Yanqiao Xiang, Yansheng Liu, Jikun Liu, Ales Plistil, Martin P Brisbin, Hal Barnett, Stanley D Stearns 9:45 (1130-3) Ultrahigh Pressure LC in Large Bore Columns LUIS A COLON, University at Buffalo, Jason A Anspach, Hector Colon 10:20 Recess 10:35 (1130-4) Obtaining Optimum Performance of Sub-2 m Particles at Elevated Pressure MARIANNA KELE, Waters Corporation, Kevin Wyndham, Pamela Iraneta, Jeffrey R Mazzeo, Uwe D Neue, Tom Walter 11:10 (1130-5) The Benefits of Extended LC Pressure for Proteomics and Metabolomics RICHARD D SMITH, Pacific Northwest National Laboratory, Yufeng Shen, Rui Zhang, Ronald J Moore, Thomas O Metz, Kim K Hixson, Rui Zhao, Eric A Livesay, Harold R Udseth, Konstantinos Petritis, Jennifer D Zimmer

SYMPOSIUM

Session 1160

PAT for Biopharmaceuticals: Analytical Technologies for Real Time Biological Process Monitoring - arranged by Elizabeth Fowler,
Xcellerex, LLC Wednesday Morning, Room S230D Elizabeth Fowler, Xcellerex, LLC, Presiding 8:30 Introductory Remarks - Elizabeth Fowler

8:35 (1160-1) Applying PAT to Biopharmaceuticals: Importance of Real-Time Monitoring of Biopharmaceutical Processes ELIZABETH FOWLER, Xcellerex 9:10 (1160-2) TBA 9:45 (1160-3) A High-Throughput Platform for Purification and Characterization of Monoclonal Antibodies SHUHONG ZHANG, Pfizer, Inc., Carolyn S Adams, Mark J Bailey, David C James 10:20 Recess

73

10:35 (1160-4) A Rapid and Non-Destructive Method for Enumerating Microbial Contaminants in Pharmaceutical Samples DON STRAUS, Genomic Profiling Systems 11:10 (1160-5) In Process Methods for Monitoring Residual Moisture Levels during Freeze Drying Process NICOLE DENKINGER, Boehringer Ingelheim Pharma GmbH & Co. KG

9:30 (1180-4) Temporally Resolved Diagnostics of a PlanarCathode Millisecond-Pulsed Glow Discharge via Laser-Scattering Techniques GERARDO GAMEZ, Indiana University, Gary M Hieftje 9:50 (1180-5) The Simultaneous Application of Zeeman Background Correction in Atomic Absorption Spectroscopy DAVID PFEIL, Teledyne Leeman Labs 10:10 Recess 10:25 (1180-6) Design Features of Continuous Flow Vapour Generator for Use with AA Spectrometry STEVE F MORTON, Thermo Electron Corporation, Adrian Holley 10:45 (1180-7) Nucleic Acid Determinations in Flowing Streams via Carbon and Phosphorous Atomic Emission TIMOTHY M BREWER, Clemson University, Beatriz Fernandez, Fuxia Jin, R Kenneth Marcus 11:05 (1180-8) Nitrogen Analysis from ppm to Percentage Level in Petroleum Products and Lubricants Using the Dumas Method ANDREA PASTORINO, Infineum Italia s.r.l., Claudio Marchi, Giuseppe Caire, Liliana Krotz, Luigi Ragaglia, Guido Giazzi 11:25 (1180-9) Speciation Analysis of Organolead and Organotin Compounds in Tobacco Smoke with GC/ICP-MS YINGTAO CHAI, Arkansas State University, Robyn Hannigan, Jon Russ, Mai Elobeid, David Clarke 11:45 (1180-10) Development of a GC-AFS for Routine US EPA Method 1630 Measurements WARREN T CORNS, P S Analytical Ltd.

WORKSHOP

Session 1170

Operating the Analytical Lab as a Business and Measuring Its Performance Part I - arranged by John Sadowski, Air Products and
Chemicals, Inc. and Lyn Faas Wednesday Morning, Room S210E John Sadowski, Air Products and Chemicals, Inc., Presiding 8:30 Introductory Remarks - John Sadowski

8:35 (1170-1) Operating Analytical as a Business LARRY M RYAN, E.I. DuPont de Nemours & Co., Inc. 9:10 (1170-2) Using Performance Metrics to Manage Your Analytical Laboratory PATRICK W LANGVARDT, Dow Corning Corporation, Thomas J Tolton 9:45 (1170-3) The Lab as a Business: Managing and Meeting Financial, Cultural and Customer Needs GORDON LOGAN, Labformatics Ltd, Simon N Wood 10:20 Recess 10:35 (1170-4) Redefining Your Laboratory with Customer Service in Mind WILLIAM (BILL) M ELLGAS, East Bay Municipal Utility District 11:10 (1170-5) Using LIMS to Integrate and Track Performance Metrics at the Bench FRANOIS RODIGARI, EBMUD

ORAL SESSION
Wednesday Morning, Room S230C X Nancy Xu, Old Dominion University, Presiding

Session 1190

Biomedical Analysis Using Various Spectroscopic Methods

ORAL SESSION
Analytical Developments for Materials Research
Wednesday Morning, Room S230F Richard V Crilley, Conneaut School District, Presiding

Session 1175

8:30 (1190-1) Laser Induced Breakdown Spectroscopy: Application to Hair and Nail JOHN W BRANCH, Mississippi State University, Akshaya Kumar, Fang-Yu Yueh, Jagdish P Singh 8:50 (1190-2) Improving Data Quality and Measurement Efficiency in Biomedical Elemental Analysis Using ICP-MS. SIMON M NELMS, Thermo Electron Corporation, Phil N Shaw, Martin Nash, Bill Spence 9:10 (1190-3) Metallomics, Biological, Clinical and Environmental Applications of In-torch Vaporization (ITV) Micro- and Nano- Sample Introduction System for ICP (inductively coupled plasma) Spectrometry VASSILI KARANASSIOS, University of Waterloo 9:30 (1190-4) Use of Multibed Absorption- Cryofocussation Technique for Detection of Ischemia/Reperfusion Injury WOLFRAM MIEKISCH, University of Rostock, Jochen K Schubert 9:50 (1190-5) Spectroscopic Detection of Glucose with Novel Surface Enhanced Raman Substrates DOUGLAS A STUART, Northwestern University, Chanda R Yonzon, Olga Lyandres, Nilam Shah, Mathew Glucksberg, Joseph T Walsh, Richard P Van Duyne 10:10 Recess 10:25 (1190-6) Chemical Microstructural Characterization of the COX II Genetic Mouse Aorta with Synchrotron Infrared Microspectroscopy DAVID L WETZEL, Kansas State University, Robert A Lodder, Lisa A Cassis 10:45 (1190-7) Development of Gold Nanoparticles and Nanoshells for Phototherapy Application in MCF-7 Cells PAUL KASILI, Oak Ridge National Laboratory, Tuan Vo-Dinh 11:05 (1190-8) Applications of Small Surface Plasmon Resonance Sensors for Biochemical Monitoring JEAN-FRANCOIS MASSON, Arizona State University, Tina M Battaglia, Margaret Barnhardt, Ronald Nieman, Stephen Beaudoin, Karl S Booksh 11:25 (1190-9) Bioanalytical Applications of Near-Infrared Fluorophores GABOR PATONAY, Georgia State University, Lucjan Strekowski, Amy Watson, Kim Jun Seok 11:45 (1190-10) Determination of Metal-Containing Proteins through Monitoring of Both Carbon and Metal Atomic Emission via Particle Beam/Hollow Cathode Emission Spectroscopy TIMOTHY M BREWER, Clemson University, Beatriz Fernanadez, Fuxia Jin, R Kenneth Marcus

10:25 (1175-1) Production of Polymeric Replicas From Porous Anodic Alumina Membranes DAMIAN J ODOM, University of Florida, Charles R Martin 10:45 (1175-2) Liquid Crystal Imaging of Self-Assembled Tubules of Chiral Phospholipids JIYU FANG, University of Central Florida, Yue Zhao, Nidhi Mahajan, Ruibo Lu 11:05 (1175-3) Infrared Microspectroscopy Analysis of Isolated Particles Significantly Below the Diffraction Limit: Optimization of the Technique MILO OVERBAY, Hewlett-Packard, Kenneth J Ward, John W Hellgeth 11:25 (1175-4) Cyclic Oxidation Behaviour of Ni-Mo-Cr Alloy at 800oC SAID S AL-JAROUDI, Saudi Aramco, Anwar H Ul-Hamid 11:45 (1175-5) The Spin-Probe ESR Study of Single-Walled Carbon Nanotubes at Low Temperatures AMARJOT DHAMI, Indian Institute of Science

ORAL SESSION
Wednesday Morning, Room S220B Allen J Sharkins, Alcoa retired, Presiding

Session 1180

Atomic Spectroscopy: New and Not-So-New Techniques

8:30 (1180-1) Nucleotide Determination via Sol-gel Immobilization for Detection by Radio Frequency Glow Discharge Optical Emission Spectrometry (rf-GD-OES) JULIA E COOPER, Clemson University, R Kenneth Marcus 8:50 (1180-2) Characterization and Application of a "Plasma-onLiquid" Spectroscopic Source FRANCISCO J ANDRADE, Indiana University, William C Wetzel, Michael R Webb, Gary M Hieftje 9:10 (1180-3) Characterization of a Liquid-Cathode Glow Discharge as an Atomic Spectroscopy Source MICHAEL R WEBB, Indiana University, Gerardo Gamez, Francisco J Andrade, Gary M Hieftje

74

ORAL SESSION
Wednesday Morning, Room S210B James de Haseth, University of Georgia, Presiding

Session 1200

Computational Approaches to Analyzing and Manipulating Data

11:25 (1210-9) Determining the Location of Activity in Graphitic Catalysts for NO2 Oxidation and Reduction JOHN R SAFFELL, Alphasense Ltd., Darryl H Dawson, Richard Compton, C Banks 11:45 (1210-10) The Mechanism of PEDOT Nanotube Synthesis and Its Electrochemical Properties RUI XIAO, University of Maryland, College Park, Seung Il Cho, Miriam Berdichevsky

8:30 (1200-1) Course Development Tools for Use with an Open Source Distance Learning Platform JOSEPH G SOLCH, Wright State University, Roger K Gilpin 8:50 (1200-2) System Level Simulation Based Design of Microfluidic Lab-On-A-Chip Devices ADITYA S BEDEKAR, CFD Research Corporation, Sachin S Siddhaye, Jerry J Feng, S (Krish) Krishnamoorthy, Shankar Sundaram 9:10 (1200-3) Rapid Optimization of Gradient IC Separations through Predictive Modeling JAMES A SCHIBLER, Dionex Corporation, Madden E John 9:30 (1200-4) Development and Selection of Generic Chromatographic Methods MARGARET ANTLER, Advanced Chemistry Development, Inc., Michael McBrien, Alexey Danilov 9:50 (1200-5) Wireless Connectivity and Control of Instrumentation Through Personal Digital Assistant Devices (PDA) NORA TUCKER, National Instruments, Eric Reffett 10:10 Recess 10:25 (1200-6) Multidimensional Analysis of Multitechnique Reference Data as an Aid to Structure Elucidation GREGORY M BANIK, Bio-Rad Laboratories, Inc., Ty Abshear, Victoria Rafalovsky 10:45 (1200-7) A Universal Data Repository Platform: Print-toDatabase Data Capture Technology for Pharmaceutical Drug Development JOHN P HELFRICH, Waters Corporation 11:05 (1200-8) Quantitative Laboratory Statistics: Let the Data Conquer the Audit and Win the Sale ROBERT M HILLARD, GOW-MAC Instrument Company 11:25 (1200-9) The Utilization On-line of Common Parameter Monitoring: A New System for Recognizing and Identifying Distribution System Incursions DAN J KROLL, Hach Homeland Security Technologies, Karl King 11:45 (1200-10) Flow Infinite Dilution Analysis: A New Method to Improve Analysis Accuracy in FIA STUART J CHALK, University of North Florida

ORAL SESSION
Environmental: Metals Analysis
Wednesday Morning, Room S210D Leo W Collins, Fisher Scientific Company L.L.C., Presiding

Session 1220

8:30 (1220-1) Determination of Heavy Metals in Cigarette Tobacco YURY G TATSY, Vernadsky Institute of Geochemistry and Analytical Chemistry, Vladimir A Sevryukov, Igor V Bezsudnov 8:50 (1220-2) A Simplified Procedure for Determination of Cr(VI) in Machine Components JOHN A MONTI, Shimadzu Instruments, Shannon Richard, Timothy Alt 9:10 (1220-3) Studies of the Speciation and Reactivity of Environmental Arsenicals JOSEPH H ALDSTADT, University of WisconsinMilwaukee, Aaron R Roerdink, Jason G Harb 9:30 (1220-4) Trace-Level Mercury Analysis of Snapping Turtles Collected from Erie County, Pennsylvania THOMAS SPUDICH, Mercyhurst College, Jeanette Schnars, Katie Ortmann, Jessica Sarver 9:50 (1220-5) Packed Bed Reactor for Continuous Monitoring and Bioscavenging of Nickel by Modified Prunus dulcis endocarp from Electroplating Industrial Effluent NEELAM VERMA, Punjabi University, Simmi Goel 10:10 Recess 10:25 (1220-6) Sample Preparation and Analysis of Toxic Metals in Consumer and Industrial Products RANJAN ROY, SCP Science 10:45 (1220-7) Determination of Trace Mercury in Environmental Samples by High Resolution Inductively Coupled Plasma - Mass Spectrometry JERZY MIERZWA, Tulane University 11:05 (1220-8) Fraunhofer Effect: Tungsten Coil Atomic Absorption Spectroscopy JENNIFER A RUST, Wake Forest University, Joaquim A Nbrega, Clifton P Calloway, Bradley T Jones 11:25 (1220-9) Withdrawn 11:45 (1220-10) Magnetically Assisted Self-Assembly into Strawberry-Like Microparticles HONGMEI HUANG, University of Michigan, Jeffrey N Anker, Brandon H McNaughton, Raoul Kopelman

ORAL SESSION
Electrochemistry: Tailoring Electrode Surfaces
Wednesday Morning, Room S220G Marc D Porter, Iowa State University, Presiding

Session 1210

ORAL SESSION
More Bioanalytical Sensors
Wednesday Morning, Room S230G Delana Nivens, Armstrong Atlantic State University, Presiding

Session 1230

8:30 (1210-1) Electrochemical Amplification Schemes Using SelfAssembled Monolayers: Determination, Variation, and Optimization of Amplification and Selectivity Mechanisms ADAM J BERGREN, Iowa State University, Marc D Porter 8:50 (1210-2) Molecularly Imprinted Polymer Composite Modified Electrodes for the Detection of Theophylline SHELLEY D MINTEER, Saint Louis University, Jenny V Ulyanova 9:10 (1210-3) Preconcentration and Electrochemical Detection of a Phospholipid at a Surface Modified by Layer-by-Layer Assembly MICHELLE WANDSTRAT, Miami University, James A Cox 9:30 (1210-4) Carbon Monoxide and Methanol Oxidation on Sulfur Covered Platinum Surfaces MATHEW A MATTOX, Miami University, Matthew W Henney, Adam C Johnson, Shouzhong Zou 9:50 (1210-5) Size-Dependence of Faradaic Current of Monodispersed Ferrocenyl- Anchored Polystyrene Particles JINGYUAN CHEN, University of Fukui, Zhang Zhijun, Liming Han 10:10 Recess 10:25 (1210-6) Development of an Optically Transparent Carbon Electrode SEBASTIAN DONNER, Iowa State University, Marc D Porter 10:45 (1210-7) Conducting Polymer Based Electrochemical Sensors for Detection of Target-DNA in the PCR Amplified Samples ARUNAS RAMANAVICIUS, Vilnius University, Almira Ramanaviciene, Irena Dumalakiene 11:05 (1210-8) Solid-Phase Microextraction of Cations Using New Conducting Polymer-DNA Composite Material MIAN JIANG, East Tennessee State University, Noor F Hussain, Christopher D Dickall

8:30 (1230-1) Determining the Levels of Glucose in Tear Fluid: Motivating a Non-Invasive Glucose Sensor JUSTIN T BACA, University of Pittsburgh, David N Finegold, Chris Taormina, Joseph Grabowski, Kasi Somayajula, Sanford A Asher 8:50 (1230-2) Cell Penetrating Peptide Coated Sensors for Intracellular Measurements GABRIELA BLAGOI, University of New Orleans, Abdul Hamide, Nitsa Rosenzweig, Zeev Rosenzweig 9:10 (1230-3) The Development of Diversified Biosensors RACHEL M BUKOWSKI, State University of New York at Buffalo, Frank V Bright 9:30 (1230-4) Detection of Small Organic Analytes Using Aptazymes and Rolling Circle Amplification EUN JEONG CHO, University of Texas at Austin, Litao Yang, Matt Levy, Scott Knudsen, Andrew D Ellington 9:50 (1230-5) Bioanalytical Applications of Microcantilever Sensor Arrays MARGARET J DOYLE, Georgia Institute of Technology, Lawrence A Bottomley, Andrew W McFarland, Jonathan S Colton 10:10 Recess 10:25 (1230-6) Manganese Superoxide Dismutase Expression in Human Breast Cancer Cells: An Investigative and Developmental Study on Tumor Suppression Using Molecular Beacon Probes TIMOTHY J DRAKE, University of Florida, Richard J Rogers, Arup Sen, Li Tan, Weihong Tan

75

10:45 (1230-7) A Quantum Dot-based Microarray for HighThroughput Multiplexed Detection JASON R EPSTEIN, New York State Department of Health 11:05 (1230-8) Antimicrobial Peptides for Pathogen and Toxin Detection NADEZHDA KULAGINA, Naval Research Laboratory, George Anderson, Kara Shaffer, Frances S Ligler, Chris Rowe Taitt 11:25 (1230-9) SERS Based Immuno-Nanosensor for Trace Protein Analyses HONGGANG LI, University of Maryland, Baltimore County, Brian M Cullum 11:45 (1230-10) Nanoscale Fiber Optic Oxygen Sensor for Monitoring Metabolism of Living Cells in a Microfluidic Platform KENDRA R REID, University of Michigan, Edwin J Park, Raoul Kopelman, Robert T Kennedy

9:10 (1250-3) Vapor Densities from Sensors Coated with GoldThiolate Nanoparticles WILLIAM H STEINECKER, University of Michigan, Edward T Zellers 9:30 (1250-4) Development of New Detection Schemes Using Colorimetric-Solid Phase Extraction for Formaldehyde and Other Trace Organic Contaminants in Water APRIL A HAZEN-BOSVELD, Iowa State University, Daniel B Gazda, Neil C Dias, James S Fritz, Marc D Porter 9:50 (1250-5) Detection of Low Doses of Endocrine Disruptors in Environmental Samples SANDRINE BIAU, Ecole Des Mines D'als , Gilda S Rigaud, Benoit Roig 10:10 Recess 10:25 (1250-6) The Development of an Electrochemical Sensor of Methanol QINFENG LIU, University of Toledo, Jon Kirchhoff 10:45 (1250-7) Reproducible Fabrication of SERS Substrates for High Sensitivity Chemical Detection DANIEL B LYSAK, Penn State University, David W Dwight, Danelle LeGault, Matthew C Dixon, David L Allara, David C Swanson, Daniel W Merdes, Shona Stewart, Patrick J Treado, Joseph Demuth 11:05 (1250-8) Explosive Residue Detection by Surface Laser Photofragmentation-Fragment Detection Spectroscopy at Ambient Conditions ROSARIO SAUSA, US Army Research Laboratory 11:25 (1250-9) New Generation of Flash Electronic Noses for Packaging Industry Based on Sensor Array and Improved Separative Technology JEAN-CHRISTOPHE MIFSUD, Alpha M.O.S. 11:45 (1250-10) High Sensitive Discrimination of Alkane Isomers Using an Improved SAW based Electronic Nose MICHAEL W RAPP, Forschungszentrum Karlsruhe GmbH, Nicole Barie

ORAL SESSION
Physical Measurement
Wednesday Morning, Room S230F Richard V Crilley, Conneaut School District, Presiding

Session 1240

8:30 (1240-1) In-situ Spectroscopic Cleaning Validation ROBERT A LODDER, University of Kentucky, Aaron Urbas 8:50 (1240-2) Assessment of Transmittance Characteristics of Oil Aerosols in the Visible and NIR Regions under Laboratory and Field Conditions RAMESH CHAND, University of Missouri-Rolla, Paul K Nam, Qiang Chen, Shubhen Kapila, Virgil Flanigan, William Rouse, Ernest Black 9:10 (1240-3) New Developments in High-Resolution Ultrasonic Measurements for the Analysis of Complex Polymer Systems VITALY BUCKIN, University College Dublin, Evgeny Kudryashov, Breda O'Driscoll, Kurt Van Durme, Laureen Delellio, Bruno Van Mele 9:30 (1240-4) Scanning Adiabatic Calorimeter for Chemical Reaction and Physical Property Measurement PETER J RALBOVSKY, TIAX LLC, Simon Chippett, Adam Brady-Myerov 9:50 (1240-5) Real-Time Thermal Devolatilization of Mercury and Mercury Compounds from CCBs Detected with Atomic Absorption Spectrometry DAVID J HASSETT, UND Energy & Environmental Research Center, Loreal V Heebink, Erick J Zacher

ORAL SESSION
Tools for Science Education
Wednesday Morning, Room S220C Susan K Zawacky, Sewickley Academy, Presiding

Session 1270

8:30 (1270-1) Problem-Based Learning and Forensic Case Study in the Instrumental Analysis Laboratory DOUGLAS E RAYNIE, South Dakota State University 8:50 (1270-2) Implementation of Laboratory Projects in the Second-Semester General Chemistry Laboratory at the University of Pittsburgh at Greensburg MARK T STAUFFER, University of Pittsburgh at Greensburg, Karla D Zaar 9:10 (1270-3) Chemistry and Spectroscopy Software as Teaching & Visualization Tools VICTORIA RAFALOVSKY, Bio-Rad Laboratories, Inc., Deborah Kernan 9:30 (1270-4) Determination of Iron in Acid Mine Drainage by UVVisible and Flame Atomic Absorption Spectrophotometries: A Pilot Student Project Involving Comparison of Results Obtained by Both Methods MARK T STAUFFER, University of Pittsburgh at Greensburg 9:50 (1270-5) Partners In Environmental Science SUZANNE K LUNSFORD, Wright State University 10:10 Recess 10:25 (1270-6) Electrons Make the World Go 'Round: Presenting Electrochemistry to High- and Middle-School Science Teachers MARK T STAUFFER, University of Pittsburgh at Greensburg, Nicholas F Barsic, Garry F Warnock 10:45 (1270-7) A Participant-Oriented, Research-Based Workshop on Molecular Genetics and Protein Structure and Function REBECCA L OWEN, Georgia State University, Emelita D Breyer, Donald K Price, Cedric C Muir 11:05 (1270-8) Curricular Integration of Regulatory Protocols in Instrumental Analysis SHIRLEY M HOENIGMAN, College of Mount St. Joseph, Michael J Navin 11:25 (1270-9) Roadmap for the University of Waterloo Initiative for Teaching, Training, Retraining and Research in Nanotechnology VASSILI KARANASSIOS, University of Waterloo 11:45 (1270-10) Teaching Toxicology Using Simple and Low Cost Analytical Experiments: A Brazilian Experience from a Pharmacy College PAULA F DE S, ANVISA, Elmo Resende, Jaime Rodrigues Jr

ORAL SESSION
Regulatory and Validation Issues
Wednesday Morning, Room S220F Vincent S Venturella, Presiding 8:30 (1245-1) Withdrawn

Session 1245

8:50 (1245-2) Biodefense Vaccine Applications of Process Analytical Technology (PAT) SANFORD B WEINBERG, GE Healthcare 9:10 (1245-3) Pressurized Liquid Dispensing Containers Use In Laboratories JAMES A WESTRA, Honeywell, James T Przybytek, Anthony R Kemperman, Karel A Snoble 9:30 (1245-4) Low-Cost 14-Day Diffusive Sampling for Ambient Benzene around the Perimeter of Oil Refineries ELIZABETH WOOLFENDEN, Markes International Ltd 9:50 (1245-5) Development and Implementation Issues with the AnIML ASTM E13.15 Analytical Data Exchange Standard MAREN FIEGE, Waters Informatics

ORAL SESSION

Session 1250

Sensors for Environmental and Explosive Chemical Detection

Wednesday Morning, Room S230H William R LaCourse, University of Maryland, Baltimore County, Presiding 8:30 (1250-1) Spectroscopic Detection of Halogenated Hydrocarbons using Modified Fujiwara Reactions DAVID L RODMAN, University of Tennessee at Knoxville, Nathan A Carrington, Kisholoy Goswami, Ziling Xue 8:50 (1250-2) Response Signatures for Nanostructured, Optically Probed, Functionalized Microcantilever Sensing Arrays MICHAEL J SEPANIAK, University of Tennessee at Knoxville, Pampa Dutta, Larry R Senesac, Nickolay V Lavrik, Panos G Datskos

76

ORAL SESSION
UV/VIS Instrumentation and Applications
Wednesday Morning, Room S230A Michael Dobrovolsky, Thermo Electron, Presiding

Session 1280

(1290-3 P) Rapid Screening and Confirmational Analysis of Residual Pesticides in Agricultural Samples by GC ECD/FPD and GC-MS/MS JESSIE BUTLER, Thermo Electron Corporation (1290-4 P) Fast, Direct and Reliable Analysis of Minor Component in Olive Oil by On-line Reversed Phase Liquid Chromatography: Gas Chromatography Using a Patented Automated Through Oven Transfer Adsorption Desorption (TOTAD) Interfase ARIADNA GALVE-BOSCH, KONIK-TECH, Raquel Snchez, Jos Manuel Cortes, Roger Gibert, Ana Vzquez, Jess Villn (1290-5 P) HPLC Analysis of Phosphonic Acid Containing Herbicides Without Derivatization MARK JACYNO, Alltech Associates, Inc. (1290-6 P) A Chiral LC-MS Assessment of Enantio-Enriched AlphaHydroxy Acids Obtained Through Lipase Catalyzed Hydrolysis of Hydroxy Acid Esters SAMIT KAPOOR, University of Missouri-Rolla, Arindam Roy, Shubhen Kapila, Paul K Nam, Virgil Flanigan (1290-7 P) A Blind Study of Pesticide Residues in Spiked and Unspiked Fruit Extracts Using Deconvolution Software CHINKAI MENG, Agilent Technologies, Inc., Chris Sandy, Philip L Wylie, Michael Szelewski (1290-8 P) Multiresidue Pesticide Analysis in Foods using GC/MS HARUHIKO MIYAGAWA, Shimadzu Corporation, Koki Tanaka, Katsuhiro Nakagawa, Charles R Lyle, Sonoe Kondo, Noriko Utagawa, Hiroshi Sakai (1290-9 P) Multiresidue Determination of Fluoroquinolone Antibiotics in Shrimp by Liquid Chromatography-Fluorescence-Mass Spectrometryn MARILYN J SCHNEIDER, USDA, Luz Vazquez Moreno (1290-10 P) High Performance ICP-OES: A Potential Primary Measurement Tool for Quantitation of Total Plant DNA MICHAEL R WINCHESTER, National Institute of Standards and Technology, Marcia N Holden, Ron Jenkins (1290-11 P) Withdrawn (1290-12 P) The Determination of Mercury in Seafood: A Comparison of Cold Vapor Atomic Absorption and Fluorescence Techniques DAVID PFEIL, Teledyne Leeman Labs, Bruce MacAllister

8:30 (1280-1) Processing Analytical Technology and Application: Using UV Fiber Optics for Pharmaceutical Manufacturing Control XUJIN LU, Bristol-Myers Squibb 8:50 (1280-2) UV-Visible Spectroscopy with Different for Different Wavelengths to Improve Dynamic Range THEODORE M GARVER, Alberta Research Council, Paul P Pastushak 9:10 (1280-3) Liquid-Liquid Extraction, Sequential Separation and Preconcentration of Pb(II), Hg(II) and Cd(II) SANJAY V HIRPARA, Gujarat University 9:30 (1280-4) Microparticle Colorimetry of Arsenic Using Ethyl Violet EMIKO KANEKO, Tohoku University, Keisuke Morita 9:50 (1280-5) Liquid Membrane Transportation of Fluoride Ions with Alizarin Based AZA Crown Ether-Zr Complex HITEN S MEHTA, Gujarat University 10:10 Recess 10:25 (1280-6) A Simple Integrated UV-Visible Approach for On-Site Monitoring of Water Quality of Lakes OLIVIER THOMAS, University of Sherbrooke, Marie-Florence Pouet 10:45 (1280-7) Supervanadophile: Complexation, Preconcentration and Transport Studies of Vanadium by Octa Functionalized Calix[4]resorcinarene-Hydroxamic Acid VINOD K JAIN, Gujarat University, Shibu G Pillai, Rujul A Pandya, Yaduvendra K Agrawal, Pranav S Shrivastav 11:05 (1280-8) Hard Plastic Clad Fibers for Medical/Materials Applications BOLESH J SKUTNIK, CeramOptec Industries, Inc., Kelly B Moran, Brian Foley, Cheryl Smith 11:25 (1280-9) Thermal Variation UV-Visible Spectroscopy for Characterization of Colloidal Systems THEODORE M GARVER, Alberta Research Council, Hongqi Yuan 11:45 (1280-10) Absorbance Detection of Immobilized Enzyme Microarray on Nylon Screen GUOXIN LU, Iowa State University, Edward S Yeung

POSTER SESSION
Food Science: GC and LC Techniques
Wednesday Morning

Session 1300

NEW PRODUCT FORUM

Innovations in Sample Handling and Preparation
Wednesday Morning, Room S220A Brian R Strohmeier, University of Pittsburgh, Presiding

Session 1285

(1300-1 P) Amino Acid Profile as Fingerprint for Natural Product Identity and Quality ALESYA BRADLEY, Phenomenex, Inc., Jafar Toulouee, Tivadar Farkas (1300-2 P) Application of 0.15 mm Fused Silica Columns with Individual Contributory Injection Techniques for Rapid GC Profiling of Distilled Spirits without Sample Preparation JAAP DE ZEEUW, Varian, Inc., Kevin MacNamara (1300-3 P) A New High Polarity bis (Cyanopropyl) Siloxane Stationary Phase for GC Resolution of Positional and Geometric Isomers of Fatty Acid Methyl Esters ROY R LAUTAMO, Agilent Technologies, Inc., Eberhardt Kuhn, Frank David (1300-4 P) The Analysis of BHT and BHA in Packaging Materials Using Dynamic Headspace CHARLES P ZAWODNY, CDS Analytical, Inc., Thomas P Wampler, Leticia A Mancini (1300-5 P) PDH: A New Method of Detecting Alky-Methoxypyrazine OffFlavors in Wine CHRIS J CASTEEL, Entech Instruments, Inc., Daniel B Cardin (1300-6 P) Supercritical Argon Decaffeination of Coffee DANIEL L HEGLUND, South Dakota School of Mines and Technology, Kristina M Grinnell (1300-7 P) Multi-residue Method for the Simultaneous Determination of five Groups of Pesticides in Food by Stir Bar Sorptive Extraction and Thermal Desorption GC-MS NOBUO OCHIAI, Gerstel K.K., Kikuo Sasamoto, Hirooki Kanda, Takashi Yamagami, Frank David, Pat Sandra (1300-8 P) Rapid Determination of Residuals Pesticides in Agricultural Products by On-line GCMS Equipped with GPC Clean Up Technique YA PING QING, Shimadzu (Hong Kong) Ltd., Yuki Hashi (1300-9 P) Analysis of Theanine in Dietery Suppliments and Different Varieties of Tea JAFAR TOULOUEE, Phenomenex, Inc., Tivadar Farkas (1300-10 P) Triglyceride Analysis by Ag-HPLC for Rapid Screening of Formulated Margarines and Spreads RICHARD O ADLOF, USDA, NCAUR, Gary List (1300-11 P) Optimization of the Pressurized Solvent Extraction and Analysis AL KAZIUNAS, Applied Separations, Rolf Schlake, Martin Fetner, Pavel Karasek, Elena Ostra, Michal Roth

8:30 (1285-1) The Development of Automated Equipment for Drying and Concentrating Environmental Extracts ROBERT S JOHNSON, Horizon Technology, Inc. 8:50 (1285-2) Multichannel Ovation BioNatural Pipette: Improving Ergonomics for Pipette Users Requiring Multichannel Functionality JEFF CALHOUN, VistaLab Technologies 9:10 (1285-3) Innovative New Chemical Scroll Vacuum Pump LOUIE R ASKEW, ILMVAC 9:30 (1285-4) Trace Level Analysis of Sulfur and Other Hetero Components by DMD RONALD TER HART, Varian BV 9:50 (1285-5) Withdrawn

POSTER SESSION

Session 1290

Morning posters will be on display from 9:30 AM to 12:30 PM with authors present from 9:30 AM to 11:30 AM. The posters will be located on the Southeast corner of the Exposition floor (beginning Aisle 2900).

Food Science: Agricultural Analysis

Wednesday Morning (1290-1 P) Hyperspectral Imaging Based Techniques for Soil Characterization GIUSEPPE BONIFAZI, Universit di Roma La Sapienza, Paolo Menesatti (1290-2 P) Improved Sensitivity with Simplified HPLC Analysis and Sample Preparation of Paraquat/Diquat VERNON BARTLETT, Restek Corporation, Katia M May, Rebecca E Wittrig, Lydia Nolan

77

(1300-12 P) Quantification of Organic Acids in Fruit Juice Using Ion Exchange Chromatography ASHLEIGH L PRINCE, West Virginia Wesleyan College, Steve K Johnson (1300-13 P) A Novel Reversed Phase HPLC Column for Separating Highly Water Soluble Organic Compounds LP RAMAN, Whatman, Inc., Patricia Vincent, Elaine Heilweil (1300-14 P) Effects of Rosemary Extracts on the Reduction of Heterocyclic Amines in Cooked Beef Patties J SCOTT SMITH, Kansas State University, Shin Yih Tsen (1300-15 P) Semi-micro Post-column Reaction System in HPLC for the Analysis of Bromate in Foods YAMAGUCHI TADAYUKI, Shimadzu Corporation, Ogaito Makoto, Mikami Hirohisa, Kawasaki Yoko, Kubota Hiroki, Yomota Chikako, Tanamoto Kenichi (1300-16 P) Degradation of Furanocoumarins Inhibiting CYP3A4 in Grapefruit Juice PAUL F CANCALON, Florida Department of Citrus (1300-17 P) Rapid Assay of Oleuropein in Virgin Olive Oil by APCI MS/MS and Isotope Dilution Method LEONARDO DI DONNA, Universit della Calabria/Dipartimento di Chimica, Fabio Mazzotti, Giovanni Sindona, Enzo Perri (1300-18 P) Development of a Novel C30 Phase: Improvement of Detection Sensitivity of Peptides and Amino Acids for High Performance Liquid Chromatography/Mass Spectrometry NORIKAZU NAGAE, Nomura Chemical Co., Ltd., Toshiyuki Enami, Naoki Fujita (1300-19 P) Analysis of Phenolic Compounds in Foods Using Fast HighPerformance Liquid Chromatography Time-of-Flight Mass Spectrometry BRIAN G SHOFRAN, LECO Corporation, Paul D Kennedy, Jack Cochran (1300-20 P) Dual Detector System for the Simultaneous Determination of Water Soluble Vitamins in Dietary Supplements WAYNE R WOLF, USDA, Denis E Lacroix, Regina M Johnson (1300-21 P) Determination of Pesticide Residues in Olives and Olive Oil by Matrix Solid Phase Dispersion (MSPD) Followed by GC/MS and LC/ESI/Ion Trap/MS/MS JUAN F GARCIA-REYES, University of Jan, Carmen Ferrer, Mara J Gmez-Ramos, Imma Ferrer, E Michael Thurman, Amadeo R Fernndez-Alba (1300-22 P) Identifying Non-targeted Pesticide Residues and Their Degradation Products in Food Using LC/TOF/MS Accurate Mass Combined with LC/Ion Trap/MS/MS JUAN F GARCIA-REYES, University of Jan, E Michael Thurman, Imma Ferrer, Antonio Molina-Daz, Amadeo R FernndezAlba

(1310-10 P) Use of Near Infrared Spectroscopy in the Food Industry HUI LI, Bruker Optics, Inc., Qian Wang (1310-11 P) Evaluation for Stability of Monoterpenes in the Oxygen Atmosphere by Chemluminescence Method YOSHIHIRO YOSHIMURA, , Mao Omori, Zhan-guo Lu

POSTER SESSION
Food Science: Sample Preparation
Wednesday Morning

Session 1320

(1320-1 P) Apply SPE and LC-MS to Determine Acrylamide in Potato Chips CRAIG AURAND, Supelco/Sigma-Aldrich, David S Bell, An Trinh, Michael Ye (1320-2 P) Withdrawn (1320-3 P) Determination of Flavor in Filtered Orange Juice Using Solid Phase Dynamic Extraction, Gas Chromatography and On-line Sample Filtration INGO CHRIST, CHROMSYS LLC, Ulrike Kuehn (1320-4 P) Alkali Carbonate Fusions and Elemental Analysis of Radioactive Glass CHARLES J COLEMAN, Westinghouse Savannah River Company, Damon R Click (1320-5 P) MSPD as Extraction Technique for Analysis of Pesticide Residues in Rice HAROLDO S DOREA , Federal University of Sergipe , Ledjane L Sobrinho (1320-6 P) Ion Analysis of Water-Immiscible Organic Solvents using Hydrophobic Membranes for Matrix Elimination WILLIAM R JONES, Horizon Technology, Inc. (1320-7 P) Ultra High Throughput Microwave Assisted Evaporations and Concentrations DEBRA KIEBACH, CEM Corporation, Elaine Hasty (1320-8 P) Analysis of Multi-pesticide Residues in Vegetables, Food and Fruits by SPE/GC-MS Method YANG YUHUI, Supelco/Sigma-Aldrich, An Trinh, Michael Ye (1320-9 P) Organic Acid Analysis of Brazilian Wine by Capillary Electrophoresis Using Indirect UV Detection RENATO G PERES, State University of Campinas - UNICAMP, Edgar P Moraes, Gustavo A Micke, Fernando G Tonin, Marina F. M Tavares, Delia Rodriguez-Amaya (1320-10 P) Withdrawn (1320-11 P) Analysis of PAHs in Edible Oils by Online Sample Preparation Coupled with HPLC Analysis and Fluorescence Detection GIOVANNI MAIO, Dionex Corporation, Frank Arnold (1320-12 P) Solid Phase Dynamic Extraction for the Determination of Tribromoanisole in Wine INGO CHRIST, CHROMSYS LLC, Ulrike Kuehn (1320-13 P) Thermal Desorption vs. Solid Phase Microextraction for the Analysis of Flavor Volatiles in Baked Cheese INGO CHRIST, CHROMSYS LLC, Ulrike Kuehn (1320-14 P) Qualitative Analysis of VOC Flavour Compounds in Fruit Pulps Using SPME Followed by HRGC-MS PEDRO A PEREIRA, Universidade Federal da Bahia, Manoela N Morais, Marcia C Veloso

POSTER SESSION
Food Science: Novel Analytical Approaches
Wednesday Morning

Session 1310

(1310-1 P) Determination of Brominated Phenols in Marine Fishes JAILSON B DE ANDRADE, Universidade Federal da Bahia, Marcia C Veloso, Aline Oliveira, Vilma M da Silva, Gislaine V Santos (1310-2 P) UltraFast GC Applied to Head Space Analysis of VOCs in Packaging Materials RICCARDO FACCHETTI, Thermo Electron , Giuseppe Catino, Paolo Magni, Thomas Porzano, Flavio Bedini (1310-3 P) Evaluation of Several Solvents for Post-Extraction Gel Permeation Chromatography Cleanup for Pesticides in Animal Fats MICHAEL R HALVORSON, O. I. Analytical, Laura Chambers (1310-4 P) Withdrawn (1310-5 P) Analysis of VOC Flavour Compounds in Brazilian Smell Peppers Using Static Headspace Followed by HRGC-MS JAILSON B DE ANDRADE, Universidade Federal da Bahia, Frederico M Rodrigues, Marcelino C Lobo, Zenira Vilas Boas, Nelson S Santos, Pedro A Pereira (1310-6 P) Discrimination, Authenticity and Maturation of Tequila by Electronic Nose and Tongue ERIC CHANIE, Alpha M.O.S. (1310-7 P) Determination of Amylose Content in Starches Using a Glucose Biosensor and Free Amyloglucosidase SUNG HYO CHOUGH, Chonnam National University, KiWoo Hyung, Hye Ryoung Park, Hyuick Cho, Keun seong Kim (1310-8 P) Maturity Monitoring of Fruit Using an Electronic Nose with Sensor Array and Fingerprint Mass Spectrometry JEAN-CHRISTOPHE MIFSUD, Alpha M.O.S., Shuji Watanabe, Koichi Yoshida (1310-9 P) Control of Quality of Milk-Based Products with a Gas Sensor Array (Electronic Nose) WOLF MUENCHMEYER, Airsense Analytics, Andreas Walte, Juergen Warrelmann

POSTER SESSION
GC-MS: New Developments and Applications
Wednesday Morning

Session 1330

(1330-1 P) Analysis of Nitrosamines in Drinking Water by GC-MS/MS JESSIE BUTLER, Thermo Electron Corporation, Meredith Conoley (1330-2 P) Rapid GC-Ion Trap-MS-MS for Simultaneous Determination of Polycyclic Aromatic Hydrocarbons (PAHs) and Organochlorinated Pesticides in Sewage Sludge Using Pressurized Liquid Extraction MURAD I HELALEH, Kuwait Institute for Scientific Research, Ali A Al-Omair (1330-3 P) Stability Studies and Fast GC/MS Analyses of Volatile Organics Reference Materials KATIA M MAY, Restek Corporation, Christopher M English, John Lidgett (1330-4 P) Assay of Organophosphate and Organochlorine Pesticides in Tyrrhenian Sea Sediment by GC-MS/MS Ion Trap and GC-ECDMS ANTONIO TAGARELLI, Universit della Calabria/Dipartimento di Chimica, Orazio Amata, Antonio De Nino, Giovanni Sindona, Edmondo Sessa

78

(1330-5 P) Using Electronic Pneumatic Control of the Carrier Gas with Method-Compliant Thermal Desorption and GC-MS for Enhanced Analysis of Trace Volatiles and Semi-Volatiles in Consumer Products ELIZABETH WOOLFENDEN, Markes International Ltd (1330-6 P) A Fast GCMS System for Mobile Laboratory Analysis of Toxic Compounds and Chemical Warfare Agents DANIEL B CARDIN, Entech Instruments, Inc., Chris J Casteel, Thomas X Robinson (1330-7 P) Signature Chemicals Used by Instrumental and Biological Detectors to Locate Items Containing Drugs and Drug Odors Including Currency KENNETH G FURTON, Florida International University, Alisha Latham, Ya-Li Hsu, Stefan Rose, Bradley Young (1330-8 P) Identification of Signature Microbial Volatile Organic Compounds from Toxic Molds Using SPME/GC/MS and Canine Detection ROBERT T GRIFFITH, Florida International University, Krish Jayachandran, Kenneth G Furton (1330-9 P) The Comparison of Data from Mass Spectrometry Hardware Modifications DAVID A HENNINGSEN, Federal Bureau of Investigation , David LeBeau, Jeffrey N Leibowitz, Lisa G Schumacher, Eshwar Jagerdeo (1330-10 P) Extending the Scope of Screening for Toxic Anions in Foods and Beverages Using SPME Sampling of Ethylation Products with Analysis by Gas Chromatography-Mass Spectrometry KEVIN J MULLIGAN, US Food and Drug Administration (1330-11 P) Improved Methods for Retrospective Analysis of Nerve Agent Exposure KERRY E PRESTON, Centers for Disease Control and Prevention, Maria I Solano, John R Barr (1330-12 P) Improvement of Peak Identification in Organic Acids Using the GC/MS Database KAWANA SHUICHI, Shimadzu Corporation, Sakamoto Yuki, Nakagawa Katsuhiro, Lyle Charkes R, Hasegawa Yuki, Kimura Masahiko, Yamaguchi Seiji (1330-13 P) Elimination of Contaminating Leaks at Interfaces in GC and GC/MS Systems DAN DIFEO, SGE Incorporated, Peter Dawes, Robert Western (1330-14 P) Compound Classification with Mass Spectral Data Filters for Comprehensive Two-Dimensional Gas Chromatography Time-of-Flight Mass Spectrometry (GCxGC-TOFMS) MARK F MERRICK, LECO Corporation, Jonelle Shiel, Jon M Ruppel, Donald C Hilton, Cochran Jack, Tincuta Veriotti (1330-15 P) Unknown Identification and Reporting through Use of Automated Spectral Extraction Software and Gas Chromatography/Mass Spectrometry TRISA C ROBARGE, Thermo Electron Corporation, Eric Phillips, Jessie Butler, Meredith Conoley, Jim Edwards, Jason S Cole (1330-16 P) GC/MS Database for Semi-quantitation of Pollutants and Agricultural Chemicals YUKI SAKAMOTO, Shimadzu Corporation, Haruhiko Miyagawa, Katsuhiro Nakagawa, Katsuyuki Taneda, Kiwao Kadokami, Kyoko Tanada, Charles R Lyle (1330-17 P) Dynamic Headspace-GC/MS Analysis of the Aroma of Fresh Flowers THOMAS P WAMPLER, CDS Analytical, Inc., Charles P Zawodny, Leticia A Mancini (1330-18 P) Analysis of Dijon Mustard Volatile Components Using Solid Phase Micro Extraction (SPME) with Separation and Identification by Gas Chromatography Mass Spectroscopy (GC-MS) CAROL J GAUDIO, Reckitt Benckiser NA, Mark Miller (1330-19 P) Fast Multidimensional GC Analysis of Complex Samples EDWARD A PFANNKOCH, Gerstel Inc., Jacqueline Whitecavage, Vanessa R Kinton (1330-20 P) Simultaneous Determination of Tocopherols and Phytosterols with Gas Chromatography-Mass Spectrometry NAGA MALLIKA SURAPANENI, University of Missouri-Rolla, Honglan Shi, Shubhen Kapila, Paul K Nam, Virgil Flanigan (1330-21 P) Rapid Determination of Quaternary Ammonium Cation Polymer Coated on Polyester Film Using Pyrolysis-GC/MS (Py-GC/MS) CHUICHI WATANABE, , Akihiko Hosaka, Hajime Ohtani, Tsuge Shin (1330-22 P) Quantitative Characterization of Gasket and Packing Material Using Py-GC/MS HONG KIL-HWAN, (1330-23 P) Quantification of Contamination in Drinking Water Plastic Bottle by Electronic Nose ERIC CHANIE, Alpha M.O.S., Vincent Schmitt, Louis Vivola (1330-24 P) Polymer Composition Analysis by SPME GC/MS WILLIAM ZHU, Johnson Polymer, James Allaway (1330-25 P) Characterization of Black Deposit Associated with Rock Paintings in Little Lost River Cave, Idaho using Pyrolysis GC/MS SARAH FEZZEY, AkzoNobel Coatings, Inc., Ruth Ann Armitage

(1330-26 P) Development of an Analytical Method for Low Level Acidic Pharmaceuticals in Sediment JOSEY GRABUSKI, National Laboratory for Environmental Testing, Ed Sverko (1330-27 P) Cosmetic Products Analysis by Pyrolysis-Comprehensive Two-Dimensional Gas Chromatography with Time-of Flight MS Detection (Py-GCxGC-TOFMS) TINCUTA VERIOTTI, Leco Corporation, Jack Cochran, Donald C Hilton

POSTER SESSION
Mass Spectrometry
Wednesday Morning

Session 1340

(1340-1 P) Direct Swab Analysis of Residual Pharmaceutical Compounds by Ion Mobility Spectrometry (IMS) JOHN J CARROLL, Smiths Detection, Reno DeBono (1340-2 P) Comparison of Ion Mobility Spectrometry (IMS) and HPLC Methods for the Determination of a Pharmaceutical Active JOHN J CARROLL, Smiths Detection, Reno DeBono (1340-3 P) Analysis of Organoselenium Compounds by Surface-Assisted Laser Desorption / Photoionzation Mass Spectrometry YANFENG CHEN, Georgia Institute of Technology, Tiffany T Hoang, Sheldon W May, Thomas M Orlando (1340-4 P) MALDI-MS Analysis of Derivatized Sugars GEORGE R DUBAY, Duke University, Alyssa L Keller, Jun Lu, Bertram O Fraser-Reid (1340-5 P) Top-Down Screening Class Specific Components from Complex Protein Mixtures: Precursor Ion Scan of Whole Phosphoproteins HARSHA P GUNAWARDENA, Purdue University, Scott A McLuckey (1340-6 P) Parallel Post Source Decay: A Novel Approach for the Enhanced Identification of Compounds by MALDI-TOF Mass Spectrometry JAMES LANGRIDGE, Waters Corporation, J Brown, Daniel Kenny, Marten Snel, Emmanuelle Claude, Robert H Bateman (1340-7 P) Employing Mass Spectrometry as Means of Detection for Bioassays ANDRE LIESENER, University of Twente, Tanja Steinkamp, Uwe Karst (1340-8 P) Ammonium Adducts of Brevetoxins in Nanoelectrospray Ionization Mass Spectrometry (ESI-MS) WEIQUN WANG, University of New Orleans, Richard B Cole (1340-9 P) Characterization of Gamma Carboxyglutamic Acid Proteins and Other Post Translationally Modified Proteins Associated with the Formation of Atherosclerotic Plaque in Human Thoracic Aortas and Coronary Arteries SAMUEL J WASHINGTON, Louisiana State University, James Robinson, Patrick A Limbach, Isiah M Warner (1340-10 P) Atmospheric Pressure Ion Mobility Spectrometry Coupled with Quadrupole Mass Spectrometry for Improved Trace Detection of Contraband DANIEL E AUSTIN, Sandia National Laboratories, Deborah E Hunka (1340-11 P) Instrument Response Measurements of Ion Mobility Spectrometers In situ: Maintaining Optimal System Performance of Fielded Systems MATTHEW T GRIFFIN, General Dynamics ATP, Norm Popkie, Jim McKinly, Michael A Eagan, Danet Vrazel, Eric Wallis, Robert F McAtee (1340-12 P) Determination of Beryllium in Workplace Swipes by Inductively Coupled Plasma Mass Spectrometry CHARLES R SHICK, JR., Savannah River National Laboratory, Paula R Cable-Dunlap (1340-13 P) Monitoring of Blister Agents in Air by Atmospheric Pressure Chemical Ionization Mass Spectrometry (APCI-MS) YASUAKI TAKADA, Hitachi, Ltd., Masao Suga, Hisashi Nagano, Izumi Waki, Hidehiro Okada, Tatsuo Nojiri, Yasuo Seto, Yasuhiro Sano, Shigeharu Yamashiro, Issac Ohsawa, Mieko Kanamori, Kouichiro Tsuge (1340-14 P) Finding a Niche for GC-TOF-MS for Determination of Organic Environmental Contaminants ROBERT SWARTHOUT, College of Charleston (1340-15 P) FT-ICR Mass Spectrometry Investigation of Metal-PAH Complex Ions HAIYAN WANG, University of Florida, Jose Valle, Jan Szczepanski, John Eyler, Martin Vala (1340-16 P) Composition of Jet Fuel Using Field Ionization Mass Spectrometry MICHAEL T CHENG, ChevronTexaco Research, James D Hudson (1340-17 P) The Development of a Robust, Discrete Dynode Electron Multiplier Utilizing Novel Secondary Electron Emissive Materials BRUCE N LAPRADE, BURLE Electro-Optics, Richard Prunier

79

(1340-18 P) New Collision-Induced Dissociation Methods for Ion Trap Mass Spectrometry LEI LI, Oak Ridge National Laboratory, Douglas C Duckworth, Goeringer E Goeringer, Glen Jackson (1340-19 P) Analysis of Poly(ethylene glycol) in Various Matrices Using Liquid Chromatography-Mass Spectrometry with Electrospray Ionization JOHN T ROY, Impact Analytical (1340-20 P) Performance Characterization of Common Electron Multipliers in Harsh Operating Conditions BRUCE N LAPRADE, BURLE Electro-Optics, Raymond Cochran (1340-21 P) Electrospray Mass Spectrometry of Room Temperature Ion Liquids DOUGLAS C DUCKWORTH, Oak Ridge National Laboratory, Yuchen Lu, Gary J Van Berkel, Glen Jackson, Fred L King (1340-22 P) A Quadrupole/Time-Of-Flight Mass Spectrometry Study on cisRu(bpy)2(CN)2 MIN LIU, University of Pittsburgh, Mingxiang Lin, Kasi Somayajula, David H Waldeck (1340-23 P) An Applicable Design of "Spot-on-a-Chip" MALDI-MS Sample Supports GUILIN JIANG, Brigham Young University

4:15 (1360-5) Raman and Fluorescence Spectroscopies in Homeland Security MIKE CARRABBA, Hach Homeland Security Technologies 4:50 (1360-6) Raman Spectroscopy: Today an Acknowledged Method in the Field of High Tech Analysis RUTH GEIGER, Jobin Yvon GmbH

SYMPOSIUM

Session 1370

Liquid Chromatography/Time-of-Flight Mass Spectrometry for Accurate Mass Analysis of Pesticides and Pharmaceuticals in Food and Water - arranged by Imma Ferrer, University of Almeria
Wednesday Afternoon, Room S220D Imma Ferrer, University of Almeria, Presiding 1:30 Introductory Remarks - Imma Ferrer and E Michael Thurman 1:35 (1370-1) Accurate Mass Measurements: A Rediscovered Resource for Qualitative Trace Organic Analysis in Pharmaceutical Development DANIEL L NORWOOD, Boehringer Ingelheim Pharmaceuticals, Inc., Keith B McKellop, Alice T Granger, James O Mullis 2:10 (1370-2) Importance of A+1 and A+2 Isotope Clusters in Mass Accuracy by LC/TOF/MS: Examples in Environmental Analysis of Pesticides and Pharmaceuticals in Food and Water E MICHAEL THURMAN, University of Almeria, Imma Ferrer, Amadeo R Fernndez-Alba 2:45 (1370-3) Multivariate Analysis of Accurate-Mass LC-TOF MS Data of Counterfeit Drugs FACUNDO M FERNANDEZ, Georgia Tech, Leonard Arthur, Krystyn Alter, Michael Green, Paul Newton 3:20 Recess 3:35 (1370-4) Analyses of Pesticides in Vegetable Samples by LC/TOF/MS AMADEO R FERNNDEZ-ALBA, University of Almera, Imma Ferrer, Milagros Mezcua 4:10 (1370-5) Measuring the Mass of an Electron by LC/TOF/MS: A Case Study of Twin Ions IMMA FERRER, University of Almera, E Michael Thurman

SYMPOSIUM

Session 1350

Charles N Reilley Award and Young Investigator Award arranged by Stephen W Feldberg, Brookhaven National Laboratory Wednesday Afternoon, Room S220G Stephen W Feldberg, Brookhaven National Laboratory, Presiding 1:30 Introductory Remarks Stephen W Feldberg

1:35 Presentation of the 2005 Charles N Reilley Award to Alan M Bond, Monash University, by Stephen W Feldberg, Brookhaven National Laboratory 1:40 (1350-1) A Unified Fourier Transform Based Approach to AC, Square Wave, Pulsed and Related Forms of Voltammetry and Impedance Spectroscopy ALAN M BOND, Monash University 2:15 (1350-2) Electron Transfer Chemistry of Metal Quantum Dots ROYCE W MURRAY, University of North Carolina at Chapel Hill 2:50 (1350-3) "Illuminating Electrochemistry: Electrogenerated Chemiluminescence on the Millisecond Time Scale R MARK WIGHTMAN, University of North Carolina at Chapel Hill 3:25 Recess 3:40 Presentation of the 2005 Young Investigator Award to David E Cliffel, Vanderbilt University, by Stephen W Feldberg, Brookhaven National Laboratory 3:45 (1350-4) Multianalyte Monitoring of Cell Metabolic Responses to CBW and Environmental Toxins DAVID E CLIFFEL, Vanderbilt University, Sven Eklund 4:20 (1350-5) Chemically Modified Nanopore Electrodes HENRY S WHITE, University of Utah, Bo Zhang, Ryan J White, Andrew Bohaty, Ilya Y Zharov, Yanhui Zhang

SYMPOSIUM

Session 1380

Microspectroscopic Characterization of Materials Using Synchrotron Radiation - arranged by Bruce Chase, E. I. DuPont
Wednesday Afternoon, Room S230B Bruce Chase, E. I. DuPont, Presiding 1:30 Introductory Remarks - Bruce Chase

1:35 (1380-1) Spectroscopy from Synchrotron and Free Electron Laser Sources GWYN P WILLIAMS, Jefferson Lab 2:10 (1380-2) Analysis with a Synchrotron X-ray Microscope GELSOMINA DE STASIO, University of Wisconsin at Madison 2:45 (1380-3) Synchrotron IR experiments: From Microanalysis to Pump-Probe Experiments PAUL DUMAS, SOLEIL Synchrotron 3:20 Recess 3:35 (1380-4) Synchrotron Studies of Materials at Extreme Conditions RUSSELL J HEMLEY, Carnegie Institution 4:10 (1380-5) Synchrotron Infrared Microspectroscopic Characterization of Biological Materials DAVID L WETZEL, Kansas State University

SYMPOSIUM
Williams-Wright Award
Wednesday Afternoon, Room S210A Becky Dittmar, 3M Center, Presiding 1:30 Introductory Remarks - Becky Dittmar

Session 1360

1:35 Presentation of the 2005 Williams-Wright Award to Fran Adar, Jobin Yvon, by Andre' Sommer, President, Coblentz Society 1:40 (1360-1) Raman Spectroscopy and Microscopy: Solutions in Search of Their Problems FRAN ADAR, Jobin Yvon Horiba 2:15 (1360-2) The History of Micro-Raman Analysis PAUL A DHAMELINCOURT, Lille 1 University 2:50 (1360-3) Vibrational Microspectroscopy Applications in CMOS Technology Materials Characterization NANCY KLYMKO, IBM Corporation 3:25 Recess 3:40 (1360-4) Infrared and Raman Microprobes: Fulfilling the Promise JOHN A REFFNER, Smiths Detection

SYMPOSIUM

Session 1390

Modern Analytical Measurements Using Nanoscale Materials arranged by Lin He, North Carolina State University and Sharron G Penn, Nanoplex Technologies, Inc. Wednesday Afternoon, Room S220F Lin He, North Carolina State University, Presiding 1:30 Introductory Remarks - Lin He

1:35 (1390-1) Nanoscale Optical Biosensors RICHARD P VAN DUYNE, Northwestern University, Douglas A Stuart, Chanda R Yonzon, Amanda J Haes, Xiaoyu Zhang 2:10 (1390-2) Nanotube-Based Artificial Voltage-Gated Ion Channels CHARLES R MARTIN, University of Florida

80

2:45 (1390-3) Encoded Nanoparticles for Multiplexed Bioassays SHARRON G PENN, Nanoplex Technologies 3:20 Recess 3:35 (1390-4) Nanomaterial-Based Bioelectronic Detection of Proteins and DNA JOSEPH WANG, Arizona State University 4:10 (1390-5) Ordered Nanofeatures in Desorption Ionization on Porous Silicon Mass Spectrometry (DIOS-MS) LIN HE, North Carolina State University, Nancy H Finkel

2:10 (1420-3) Electrotransfection of Mammalian Cells Using Multichannel Electroporation Microchip JEONG AH KIM, Digital Bio Technology Company, Young Shik Shin, Keunchang Cho, Sun Hee Lim, Chan Hee Park, Chanil Chung, Jun Keun Chang 2:30 (1420-4) Direct Detection of PCR Products and Genomic DNA by Enzymatically Amplified SPR Imaging Measurements of RNA Microarrays HYE JIN LEE, University of California at Irvine, Terry Goodrich, Robert M Corn 2:50 (1420-5) Fish in a Vial JI-YOUNG LEE, Iowa State University, Hung-Wing Li, Edward S Yeung 3:10 Recess 3:25 (1420-6) Determination of Cholesterol by Hyperspectral Integrated Computational Imaging ROBERT A LODDER, University of Kentucky, Bin Dai 3:45 (1420-7) Analysis of the Binding Modes of Metallated Porphyrazines to Nucleic Acids Using Atomic Force Microscopy and Gel Electrophoresis ERIC D HOROWITZ, Georgia Institute of Technology, Elizabeth D Gadsby, Lawrence A Bottomley, Carlos Ramirez 4:05 (1420-8) Infrared and Raman Microanalysis of Bacteria and Other Biological Samples MIKE P FULLER, Digilab, Ellen V Miseo, Jonah Kirkwood, Andrew Ghetler, Jacqueline Sedman, Ashraf A Ismail 4:25 (1420-9) Imaging of Cultured Neurons and Tissue Sections Using Time-of-Flight Secondary Ion Mass Spectrometry ERIC B MONROE, University of Illinois at Urbana, John Jurchen, Stanislav S Rubakhin, Jonathan V Sweedler 4:45 (1420-10) Mitomycin C Modified Dynamic Nano-Platfroms as Radiosensitizers and In Vitro Studies WENZHE FAN, University of Michigan, Yong-Eun L Koo, Raoul Kopelman, Mahaveer Bhojani , Alnawaz Rehemtulla

SYMPOSIUM

Session 1400

Speciation Analyses for Environmental, Food and Industrial Applications - arranged by Olivier F Donard, Laboratoire de Chimie
Analytique Bioinorganique et Environnement Wednesday Afternoon, Room S220B Olivier F Donard, Laboratoire de Chimie Analytique Bioinorganique et Environnement, Presiding 1:30 Introductory Remarks - Olivier F Donard

1:35 (1400-1) Speciation Analysis Today: State-of-the-Art, Legislation and Industrial Applications MICHAEL SPERLING, University of Muenster 2:10 (1400-2) Elemental Speciation in Environmental Exposure Assessment Matrices JOHN T CREED, US EPA, Patricia A Creed, Amy N Parks, Carol A Schwegel, Michael W Fricke, Douglas T Heitkemper, Noroha P Vela 2:45 (1400-3) Speciated Isotope Dilution Enabling Accurate and Precise Metal Species Measurements in Complex Samples H.M. "SKIP" KINGSTON, Duquesne University, Mizanur Rahman, John Kern 3:20 Recess 3:35 (1400-4) How Can We Use Speciation Methods to Characterize and Minimize Trace Element Emissions from Industrial Processes? DIRK WALLSCHLGER, Trent University 4:10 (1400-5) Advances in Bioinorganic Speciation Analysis: Metalloproteomics, Metallomics and Heteroatom-Tagged Proteomics RYSZARD LOBINSKI, CNRS

ORAL SESSION
Biomedical Analysis Using Fluorescence Techniques
Wednesday Afternoon, Room S230C Chin-I Shyr, Thermo Electron Corporation, Presiding

Session 1430

WORKSHOP

Session 1410

1:30 (1430-1) Sensitivity of 1,3-Diphenylisobenzofuran (DPIBF) Embedded in Organically Modified Silicate (ormosil) Nanoprobes towards Singlet Oxygen in Aqueous Media GWANGSEONG KIM, University of Michigan, Yong-Eun L Koo, Maria J Moreno, Raoul Kopelman 1:50 (1430-2) Auto Fluorescence of Bacillus Globigii: A Comparative Study of Dry Spores and Spores in Aqueous and Ethanol Suspensions JOSEPH KUNNIL, University of Canterbury, Sivanantha Sarasanandarajah, Easaw Chacko, Lou Reinisch 2:10 (1430-3) Optical Fiber Laser-Induced Fluorescence (LIF) Sensor for Breast Cancer Cell Diagnosis CHAN KYU KIM, Mississippi State University, Sunil K Khijwania, Scott Willard, Jagdish P Singh, Rajamohan R Kalluru 2:30 (1430-4) Recent Advancements in Fluorescence Imaging MORTEN JENSEN, National Instruments 2:50 (1430-5) Reversible Effect of Hydration on Bacillus globigii Spores Probed with Fluorescence Spectroscopy SIVANANTHAN SARASANANDARAJAH, University of Canterbury, Joseph Kunnil, Easaw Chacko, Burt V Bronk, Lou Reinisch 3:10 Recess 3:25 (1430-6) Real-Time Tuning Membrane Transport of Single Living Cells Using Electric Fields QIAN WAN, Old Dominion University, X, Nancy Xu, Schoenbach Karl 3:45 (1430-7) High Affinity Aptamers for Cell Surface Markers DIHUA SHANGGUAN, University of Florida, Steven W Suljak, Ying Li, Weihong Tan 4:05 (1430-8) Targeted Methylene Blue Loaded Nanoparticles for in vitro and in vivo Photodynamic Applications WEI TANG, University of Michigan, Raoul Kopelman, Hao Xu, Martin A Philbert, Jonathan Aylott 4:25 (1430-9) Real-Time Monitoring of Subcellular Mechanism Induced by Electric Fields QIAN WAN, Old Dominion University, X, Nancy Xu 4:45 (1430-10) An Investigation into the Adsorption of Fibronectin (Fn) onto a Series of Polysilane Films with and without Electrical Stimulation and the Effects of Gold Coatings on this Adsorption BARNABAS K GIKONYO, Southern Illinois University, Lori A Vermeulen

Operating the Analytical Lab as a Business and Measuring Its Performance Part II - arranged by John Sadowski, Air Products and
Chemicals, Inc. and Lyn Faas Wednesday Afternoon, Room S210E John Sadowski, Air Products and Chemicals, Inc., Presiding 1:30 Introductory Remarks - Lyn Faas

1:35 (1410-1) Maintaining (Growing?) Our Business: Understanding, Marketing, Sustaining STUART G BUSH, Rohm and Haas Company 2:10 (1410-2) Best Practices in Assessing Customer Satisfaction DENNIS B CRAWSHAW, International Paper 2:45 (1410-3) Investing in Employee Development ANDREW G MCFARLAND, ATOFINA Chemicals, Inc. 3:20 Recess 3:35 (1410-4) Should I Stay or Should I Go? The Dos and Donts of Knowledge Worker Management JO DOHL, GE Health 4:10 (1410-5) Prioritization Systems that Really Work to Improve Lab Production JOE WIEGEL, Novidea, Inc.

ORAL SESSION
Bioanalytical Microscopy/Imaging
Wednesday Afternoon, Room S230E Jonathan V Sweedler, University of Illinois, Presiding

Session 1420

1:30 (1420-1) pH Dependent Adsorption of DNAs with Sticky Ends on Fused Silica SLAVICA ISAILOVIC, Iowa State University, Hung-Wing Li, Edward S Yeung 1:50 (1420-2) Toxicity of Silica-based Nanoparticles to Living Cells JULIA XIAOJUN ZHAO, University of North Dakota, Min Wu, Yuhui Jin, Yanfu Huan, Shibichakravarthy Kannan

81

ORAL SESSION
Data Analysis and Manipulation
Wednesday Afternoon, Room S210D John W Timbario, PPG Industries, Inc., Presiding

Session 1435

2:10 (1450-3) Ion Chromatographic Determination of Perchlorate in Vegetation Using Accelerated Solvent Extraction with Integrated Clean-up SHELDON E HENDERSON, Dionex Corporation, Bruce E Richter, Richard E Carlson, Eric S Francis, Jennifer Peterson 2:30 (1450-4) Life after Freon: Will you Be Ready? Accurate, Precise and Cost Effective Oil and Grease Extractions with Hexane ROBERT S JOHNSON, Horizon Technology, Inc., Stephen J MacDonald 2:50 (1450-5) Standard in the Extraction Phase: A New Approach to Calibration of Microextraction Processes YONG CHEN, University of Waterloo, John O'Reilly, Yanxiang Wang, Janusz B Pawliszyn 3:10 Recess 3:25 (1450-6) Combined GPC and On-line Carbon Column Cleanup Technique for Isotope Dilution High Resolution PCDD/PCDF Methods KEVIN P KELLY, J2 Scientific, David Thal 3:45 (1450-7) The Development of Automated Equipment for Drying and Concentrating Environmental Extracts STEPHEN J MACDONALD, Horizon Technology, Inc., Robert S Johnson 4:05 (1450-8) Determination of Calibration Constants of Permeation Passive Samplers Based on the Linear TemperatureProgrammed Retention Index of the Analytes SURESH SEETHAPATHY, University of Waterloo, Tadeusz Grecki, Bozena Zabiegala, Jacek Namiesnik 4:25 (1450-9) Direct Vial Extraction of Environmental Pollutants from Water for High Resolution GC Analysis ROBERT H WOHLEB, VICI, Martin Okiro 4:45 (1450-10) Accelerated Solvent Extraction (ASE ) as a Sample Preparation Technique for Halogenated Flame Retardants in Polymeric Materials ERIC S FRANCIS, Dionex Corporation, Sheldon E Henderson, Jennifer Peterson, Richard E Carlson, Bruce E Richter

3:25 (1435-1) Data Processing of Voltammetric Measurements Based on the Hilbert Transform: Theory and Experiments COSTAS A ANASTASSIOU, Imperial College, Kim H Parker, Danny O'Hare 3:45 (1435-2) Markush Structure Handling, Storage and Searching MARKUS HEMMER, Waters Informatics 4:05 (1435-3) Opening the Road to Reuse and Long-term Asset Protection for Scientific and Technical Data RICHARD S LYSAKOWSKI, CENSA/GERA 4:25 (1435-4) Microbiological Functions in LIMS CHRISTINE PASZKO, Accelerated Technology Laboratories, Inc., David Schlabach, Rick Danielson, Robert Cattolica 4:45 (1435-5) Total Laboratory Informatics from Discovery through Development to Batch Release and PAT ANTONY N DAVIES, Waters Informatics

ORAL SESSION

Session 1440

Development of Process Analytical Technology (PAT) Applications - From Design Stage to Implementation - arranged by
Norman Wiggins, Astrazeneca Wednesday Afternoon, Room S230D Peter Brush, AstraZeneca Pharmaceuticals, Presiding 1:30 (1440-1) Process Analytical Technology (PAT): What's in a Name? CHRIS WATTS, FDA/CDER/OPS 1:50 (1440-2) Process Analytical Technology (PAT): An Industry Perspective SIGMUND WARASZKIEWICZ, AstraZeneca 2:10 (1440-3) Taking Process Analytical Technology from Research to Manufacturing and Vice Versa ANDREW J LANGE, Pfizer, Inc. 2:30 (1440-4) Strategies for Successful Implementation of PAT in Pharmaceutical Manufacturing WALTER DZIKI, Abbott Laboratories, Inc. 2:50 (1440-5) The Role of a Center of Excellence in Developing PAT Applications NILS-ERIK ANDERSSON, AstraZeneca, Staffan Folestad, Arne Torstensson 3:10 Recess 3:25 (1440-6) Realizing the Benefits of and Challenges to Process Analytical Technology (PAT) Implementation: A Generic Industry Perspective SU-CHIN LO, Barr Laboratories, Inc. 3:45 (1440-7) Meeting the Regulatory Challenges Associated with Process Analytical Technologies THOMAS P GARCIA, Pfizer, Inc. 4:05 (1440-8) PAT Methods: Integration of Equipment Qualification and Methods Validation CARL A ANDERSON, Duquesne University 4:25 (1440-9) Impact of PAT Implementation on Product and Process Specifications JEAN-MARIE M GEOFFROY, Abbott Laboratories, Inc. 4:45 (1440-10) The Ultimate Goal of PAT: Real Time Release THORSTEN HERKERT, AstraZeneca GmbH, Siegmund Kunz

ORAL SESSION
Environmental: Biological Assay and Detection
Wednesday Afternoon, Room S210D John W Timbario, PPG Industries, Inc., Presiding

Session 1460

1:30 (1460-1) Development of a Rapid Detection of Escherichia coli O157 in Water with a PCR-Assay Based on rfBE Gene: Prevalence in Municipal Wastewater in the Gard State (France) ROMAIN BERTRAND, Ecole Des Mines D'als , Gilda S Rigaud, Benoit Roig 1:50 (1460-2) Bacterial Cell Array Chips Using Bioluminescent Bacteria for Environmental Toxicity Analysis MAN BOCK GU, Gwangju Institute of Science and Technology, Jin Hyung Lee, Robert J Mitchell, Byung Chan Kim 2:10 (1460-3) Epiphyte-Retained Suspension as an Indicator of Technogenic Mercury Pollution YURY G TATSY, Vernadsky Institute of Geochemistry and Analytical Chemistry, Alexander A Volokh, Evgeny P Yanin 2:30 (1460-4) Catalytic DNA for the Detection of Nitroaromatic Molecules DONALD M CROPEK, ERDC-CERL, Sarah E Kobylewski, Tuling Lam, Yi Lu, Andrea K Brown 2:50 (1460-5) Development of Lipid Membrane-Based Immunoassay for Bacterial Toxins on PDMS Chips KENNETH S PHILLIPS, University of California Riverside, Yi Dong, Quan Cheng

ORAL SESSION
GC-MS/Method and Instrument Development
Wednesday Afternoon, Room S210B Aviv Amirav, Tel Aviv University, Presiding

Session 1470

ORAL SESSION
Environmental Sampling Preparation Tools
Wednesday Afternoon, Room S210C Scott Hazard, OI Analytical, Presiding

Session 1450

1:30 (1470-1) SPME for Rapid Field Separations of Chemical Agents LAILIANG ZHAI, Brigham Young University, James R Oliphant, H. Dennis Tolley, Edgar D Lee, Milton L Lee, Jeffrey L Jones 1:50 (1470-2) Method Development for the Sampling and Analysis of Blood from Sea Turtles and Marine Mammals for Organohalogen Compounds JOHN KUCKLICK, National Institute of Standards and Technology, Jennifer Keller, Robert Swarthout, Stacy Vander Pol, Jocelyn Flanary, Rebecca S Pugh, Paul Becker, Steven J Christopher, Michele M Schantz, Stephen Wise

1:30 (1450-1) Optimizing Solid Phase Extractions: Strategies and Useful Tips for Getting the Best Performance STEPHEN J MACDONALD, Horizon Technology, Inc., Robert S Johnson 1:50 (1450-2) Long-Term Storage of Air-Sampled Mercury on GoldCoated Quartz Tubes DAVID J HASSETT, UND Energy & Environmental Research Center, Erick J Zacher

82

2:10 (1470-3) Accurate Quantification of BETX in Whole Human Blood Amidst Relatively High Environmental Background Levels DAVID M CHAMBERS, CDC-NCEH/ASTDR, Benjamin C Blount, David O McElprang, Michael G Waterhouse 2:30 (1470-4) Measurement of Selenomethionine by Reaction with Cyanogen Bromide and Gas-Chromatography-Isotope Dilution Mass Spectrometry: Comparison of Two Sample Treatments WAYNE R WOLF, USDA, Robert J Goldschmidt 2:50 (1470-5) Strategies for Analyzing Policosanols in Rice Processing By-products STEVEN W LLOYD, USDA, Casey C Grimm, Elaine T Champagne 3:10 Recess 3:25 (1470-6) Screening of Drugs of Abuse in Human Hair by GCxGC-TOF MS JEAN-MARIE DIMANDJA, Spelman College, Miranda A Hallett 3:45 (1470-7) Rapid, Non-invasive Analysis of Biological Samples Using GC-TOFMS HEATHER L HOLMES, Eastern Michigan University, Steven J Pernecky, Mahrokh Soltani, Sudeepa Karunaratne, Daniel Clemans, Stephen MacGregor 4:05 (1470-8) Evaluation of a Software Tool Designed to Increase Productivity and Sample Throughput in the Toxicology Laboratory TRISA C ROBARGE, Thermo Electron Corporation, Jim Edwards, Eric Phillips, Meredith Conoley 4:25 (1470-9) Innovative, Electrically Cooled Thermal Desorption Technology for On- and Off-Line (near real time) On-site Analysis from Mobile Platforms GARETH M ROBERTS, Markes International Ltd 4:45 (1470-10) Supersonic GC-MS: The Quest for Ultimate Performance GC-MS AVIV AMIRAV, Tel Aviv University, Alexander Fialkov, Alexander Gordin

ORAL SESSION

Session 1490

LC-MS Analysis of Glycoproteins and Modified Peptides arranged by Shubben Kapila, University of Missouri-Rolla and Yinfa Ma, University of Missouri-Rolla Wednesday Afternoon, Room S220E Shubben Kapila, University of Missouri-Rolla, Presiding 1:30 (1490-1) Tandem Mass Spectrometry of Glycopeptides and Oligosaccharides: Implications for LC/MS JOSEPH ZAIA, Boston University 1:50 (1490-2) Shotgun Glycomics RON ORLANDO, University of Georgia 2:10 (1490-3) Assessment of Relative Susceptibility of Oligopeptides and Alpha-Hydroxy Acid Capped Oligopeptides to Enzymatic Hydrolysis MONTY KERLEY, University of Missouri-Columbia, William Kolath, Srinivasa Gorla, Hareesh Palli, Shubhen Kapila, Keesoo Lee, Paul K Nam 2:30 (1490-4) Enzymatic Synthesis and LC-MS and MS-MS Characterization of Tailored Oligopeptides ARINDAM ROY, IRIX Pharmaceuticals, Inc., Hareesh Palli, Shiva Garg, Shubhen Kapila, Paul K Nam, Virgil Flanigan 2:50 (1490-5) Synthesis and Characterization of Hydroxy Acid Capped Oligopeptides in Monophasic Aqueous Organic Media PAUL K NAM, University of Missouri-Rolla, Santhana Srinivasan, Shubhen Kapila 3:10 Recess 3:25 (1490-6) Identification and Quantification of Carbohydrates in Glycoproteins of Transgenic Corn by High Performance Liquid Chromatography-Fluorescence Detection and Liquid ChromatographySonic Spray Ionization Mass Spectrometry TONGWEN WANG, University of Missouri-Rolla, Paul K Nam, Yinfa Ma 3:45 (1490-7) LC-MS Characterization of Synthetic Cysteine Oligopeptides and Assessment of Their Antioxidant Activity CHUNYU LI, University of Missouri-Rolla, Hao Wang, Shubhen Kapila, Keesoo Lee, Paul K Nam 4:05 (1490-8) Separation of Alpha-Hydroxy Acid Enantiomers Through Lipase Catalyzed Esterification SHIVA GARG, University of Missouri-Rolla, Hareesh Palli, Shubhen Kapila, Paul K Nam, Virgil Flanigan 4:25 (1490-9) Synthesis and Application of Ultra-Stable Poly(ethyleneimine)-Bonded Silica for High-Performance Liquid Chromatography HAO LUO, University of Minnesota, Lianjia Ma, Peter W Carr 4:45 (1490-10) Dual Gradient Nano HPLC System for Multidimensional Separations and Increased Sensitivity KAREN M HAHNENBERGER, Eksigent Technologies, David W Neyer, Jason E Rehm

ORAL SESSION
ETH Zurich Wednesday Afternoon, Room S230G Erno Pretsch, ETH Zurich, Presiding

Session 1480

Ionophore-based Chemical Sensors I - arranged by Erno Pretsch,

1:30 (1480-1) Multipulse Galvanostatic Potentiometry: Pulstrodes SERGEY MAKARYCHEV-MIKHAILOV, Auburn University, Alexey Shvarev, Eric Bakker 1:50 (1480-2) An Electrochemical Impedance Spectroscopy Study of Polymer Membrane Ion-Selective Electrodes ROLAND DE MARCO, Nanochemistry Research Institute, Ryan Chester, Erno Pretsch, Karoly Tompa, Tamas Vigassy, Eric Bakker, Yida Xu, Alexey Shvarev 2:10 (1480-3) Pulsed Galvanostatic Surface Recognition at Liquidliquid Interface YIDA XU, Auburn University, Alexey Shvarev, Roland De Marco, Eric Bakker 2:30 (1480-4) Coulometric Release of Ions from Ion-Selective Polymeric Membranes in View of Automated Titrations in Confined Samples VISHNUPRIYA BHAKTHAVATSALAM, Auburn University, Alexey Shvarev, Eric Bakker 2:50 (1480-5) Biorecognition-Modulated Ion Fluxes through Functionalized Gold Nanotubules as a Novel Label-Free Biosensing Approach RBERT E GYURCSNYI, Budapest University of Technology and Economics, Erno Pretsch, Tamas Vigassy 3:10 Recess 3:25 (1480-6) Conducting Polymers Films as Model Biological Membranes: Membrane Potential Formation of Ca2+ and Mg2+ Sensitive Polypyrrole Films Doped by Amino Acids ANDRZEJ LEWENSTAM, Abo Akademi University, Beata Paczosa 3:45 (1480-7) Potentiometric Detection Limit in the Attomol Range ERNO PRETSCH, ETH Zurich, Tamas Vigassy, Rbert E Gyurcsnyi, Chrstian G Huber 4:05 (1480-8) Calcium Selective Electrodes with Lowered Detection Limit MAGDALENA MAJ-ZURAWSKA, Warsaw University, Anna Konopka, Iwona Bedlechowicz, Agata Michalska, Tomasz Sokalski, Andrzej Lewenstam 4:25 (1480-9) The Dynamic Interfacial Tension Measurements as a Tool to Study the Mechanism of Metal Ions Transport through the PLM Membranes KAMIL WOJCIECHOWSKI, , Jacques Buffle 4:45 (1480-10) Miniature Solid State Ion-Selective Electrodes with Solvent Polymeric Membrane RENATA PACIOREK, Warsaw University, Peter van der Wal, Przemyslaw Bieganowski, Nicolaas de Rooij, Magdalena Maj-Zurawska

ORAL SESSION
Wednesday Afternoon, Room S220C Ronald E Majors, Agilent Technologies, Presiding

Session 1500

Liquid Chromatography: Preparative LC and Reverse Phase LC

1:30 (1500-1) Preparative Liquid Chromatography: The Reverse Autocompress Columns Overloading Conditions FRANOIS DARDOIZE, UPMC, Gilles Clodic 1:50 (1500-2) The Feasibility of Performing RP-HPLC Separations at High pH on Silica and Hybrid Type Sorbents TIVADAR FARKAS, Phenomenex, Inc., Lawrence Loo, Ismail Rustamov 2:10 (1500-3) Synthesis and Characterization of Pitch-Based Colloid-Imprinted Carbons for HPLC Separations ZUOJIANG LI, Oak Ridge National Laboratory, Mietek Jaroniec, Sheng Dai 2:30 (1500-4) Polymer Coated Porous Titania for Reversed Phase and Preparative Liquid Chromatography CLAYTON V MCNEFF, ZirChrom Separations, Inc., Bingwen Yan, David S Bell 2:50 (1500-5) Efficient Chromatographic Purification of Combinatorial Libraries with New Software Algorithms for Automated PreAnalysis, Sample Culling, Purification and Fraction Analysis WULFF NIEDNER, Dionex Corporation, Thomas Piecha, Frank Arnold 3:10 Recess 3:25 (1500-6) Minimizing Time and Effort to Develop a Rugged Reverse Phase HPLC Method DEREK SOUTHERN, Rheodyne LLC, Terry J Braggins 3:45 (1500-7) Systematic Look at the Affects of Various Solvents, Injection Techniques and Sample Amounts on Preparative HPLC Columns JOAN M STEVENS, Gilson, Inc., Gary Scharrer, Alan Hamstra

83

4:05 (1500-8) Investigation of Resistance to Mass Transfer in Reversed Phase Liquid Chromatography KARYN M USHER, Florida State University, Carolyn R Simmons, John G Dorsey 4:25 (1500-9) Alkylammonium Formates as Organic Solvent Replacements for Reversed-Phase Liquid Chromatography MARTIN M WAICHIGO, Miami University, Neil D Danielson, Thomas L Riechel 4:45 (1500-10) Effects of Ultra-high Pressure RPLC on the Separation of Intact Proteins JOHN W ESCHELBACH, University of North Carolina at Chapel Hill, James W Jorgenson

2:50 (1520-5) Determining Explosive Odours Using Solid Phase Microextraction: Gas Chromatography (SPME-GC) and Explosive Detection Canines ROSS J HARPER, Florida International University, Jose R Almirall, Kenneth G Furton 3:10 Recess 3:25 (1520-6) Capillary Electrophoresis/Diode Array Detection/Mass Spectrometry for the Forensic Analysis of Dyes Extracted from Textile Fibers ALEX A NIEUWLAND, University of South Carolina, Brandi L Clelland, Amy R Stefan, Christopher Dockery, James E Hendrix, Stephen L Morgan, Mark L Miller 3:45 (1520-7) AED Analysis of Sulfur Containing Compounds in Flammable and Ignitable Liquids KIRK E LOKITS, Middle Tennessee State University, Gale J Clark 4:05 (1520-8) Contamination and Recontamination of Buildings around 'Ground Zero' MATTHEW S MATYJASZCZYK, RJ Lee Group, Inc., Steve R Badger, Casey Bunker, Richard J Lee, Keith P Rickabaugh, Albert F Vicinie 4:25 (1520-9) Fast Mapping of Gunshot Residues on Cloth and Skin to Determine Shot Distance DIRK WISSMANN, Spectro Analytical Instruments GmbH & Co. KG 4:45 (1520-10) A Near-Real-Time Air Monitoring System for Chemical Warfare Agents JAMES H CRABTREE, Agilent Technologies, Inc., Bruce D Quimby

ORAL SESSION
Wednesday Afternoon, Room S230F Mitchell E Johnson, Duquesne University, Presiding

Session 1510

Separation and Characterization of Biological Samples

1:30 (1510-1) A Dynamic Pre-coating for CE-MS Applications WILLIAM W CHANG, Target Discovery, Inc. 1:50 (1510-2) Liquid Chromatography-Mass Spectrometry as a Tool for Classification and Identification of Bacteria Using Amino Acid Sequences of Tryptic Peptides Derived from Cellular Proteins JACEK P DWORZANSKI, Geo-Centers, Inc., Rui Chen, Rhabih E Jabbour, Samir V Deshpande, A. Peter Snyder, Liang Li, Charles H Wick 2:10 (1510-3) Characterizing Venom Peptides in Cone Snails Using Liquid Chromatography-Mass Spectrometry JENNIFER A JAKUBOWSKI, University of Illinois at Urbana, Wayne P Kelley, Timothy A Richmond, Jonathan V Sweedler 2:30 (1510-4) Solid Phase Extraction of Trace Lipid Amides from Biological Samples TAMANNA SULTANA, Duquesne University, Mitchell E Johnson 2:50 (1510-5) Rigid Polymerics - Biomolecule Separations from ng to kg JOHN A MCCONVILLE, Polymer Laboratories Inc., Linda L Lloyd, Keeley J Mapp, Louise E Rochell 3:10 Recess 3:25 (1510-6) Retention Characteristics of a ButylimidazoliumBased Stationary Phase YAQIN SUN, University of Cincinnati, Apryll M Stalcup 3:45 (1510-7) Improved Throughput of Peptide Mapping on HPLC System DA REN, Waters Corporation, Paul Rainville, Kimvan Tran, Diane M Diehl, Jeffrey R Mazzeo 4:05 (1510-8) High Throughput Determination of Atrasentan (Xinlay) in Dog Plasma by LC/MS/MS PERRY G WANG, Abbott Laboratories, Inc., Hope Gregg, Min Chang, Tawakol El-Shourbagy, Jack S Wei 4:25 (1510-9) Rapid Analysis of Pemoline in Equine Plasma by Liquid Chromatography-Tandem Mass Spectrometry CORNELIUS E UBOH, University of Pennsylvania 4:45 (1510-10) Comparison of Mechanisms for Extracting Biomarkers BRIAN ROHRBACK, Infometrix, Inc., Scott Ramos, Julia Wingate

ORAL SESSION

Session 1530

Vibrational Spectroscopy: Proteomics and Bioanalytical Applications

Wednesday Afternoon, Room S230A Rohan A Thakur, Thermo Electron Corporation, Presiding 1:30 (1530-1) Development and Characterization of a SurfaceEnhanced Raman Scattering Based Immunoassay for Viral Pathogens JEREMY D DRISKELL, Iowa State University, Karen M Kwarta, John Neill, Julia Ridpath, Marc D Porter 1:50 (1530-2) Raman Detection of Protein, Peptide and Amino Acid Phosphorylation YONG XIE, Purdue University, Dongmao Zhang, Dor BenAmotz 2:10 (1530-3) Quantitative Analysis Using Isotopic SERS Tags DONGMAO ZHANG, Purdue University, Yong Xie, Vincent J Davisson, Shirshendu Deb, Dor Ben-Amotz 2:30 (1530-4) Raman Spectroscopic Imaging of Physical/Chemical Effects of Bone Fractures TSO-CHING CHEN, University of Michigan, Michael D Morris 2:50 (1530-5) Raman Detection of Insulin Fibril Formation DONGMAO ZHANG, Purdue University, Yong Xie, Dor Ben-Amotz 3:10 Recess 3:25 (1530-6) Electron Beam Lithography (EBL) Engineered Nanostructures for Biosensing TROY A ALEXANDER, Army Research Laboratory, Alma E Wickenden 3:45 (1530-7) Pharmaceutical Work Flow Improvement via Infrared Spectroscopy KENNETH J FREDEEN, Smiths Detection, David W Schiering, John C Corbett, Mark L Norman, John A Seelenbinder 4:05 (1530-8) A Novel Probe Design for in-situ and/or in-vivo Broadband Infrared Characterization Using Photothermal Detection ANGELA M GILLIKIN, Duke University, Richard A Palmer 4:25 (1530-9) Characterization of Leucine Fastener Formed between Peptide beta-Sheets by Infrared Multiple-Angle Incidence Resolution Spectroscopy TAKESHI HASEGAWA, College of Industrial Technology , Hiroyuki Kakuda, Norihiro Yamada 4:45 (1530-10) Rapid Polymorphic Screening for Accelerated Drug Development JOHN A SEELENBINDER, Smiths Detection, Kenneth J Fredeen, Mark L Norman

ORAL SESSION
Wednesday Afternoon, Room S230H Jack Cochran, Leco Corporation, Presiding

Session 1520

Separation, Sampling, and Identification of Terrorist Agents

1:30 (1520-1) Determination of Explosives by LC/MS and Micellar CE for Development of NIST Reference Materials WILLIAM MACCREHAN, National Institute of Standards and Technology, Mary Bedner 1:50 (1520-2) Analysis of Chemical Warefare Agent Simulants in Air Using Liquid Phase Microextraction (LPME) JOHN M KOKOSA, Kettering University, Shawnda Hollier, Andrzej Przyjazny 2:10 (1520-3) Gas Chromatography-Mass Spectrometric Characterization of an Oil Aerosol-Vapor Microbial Disinfectant KANISA KITTIRATANAPIBOON, University of Missouri-Rolla, Prakash Wadhwa, Keesoo Lee, Shubhen Kapila, Paul K Nam, Virgil Flanigan 2:30 (1520-4) Effective Emergency Toxicology Laboratory: Making it Work to Save Lives PADINJAREKUTTU R RAVIKUMAR, New York City Department of Health & Mental Hygiene, Sara T Beatrice

NEW PRODUCT FORUM

Novel Instrumentation for Environmental Analyses
Wednesday Afternoon, Room S220A Linda Wagner Rukavina, PPG Industries, Inc., Presiding

Session 1535

1:30 (1535-1) New Technology in Discrete Analysis for the Automated Testing of Inorganic Ions in Waters NINGLAN LIAO, O. I. Analytical, Michael L Duffy, William Lipps

84

1:50 (1535-2) A New, Elegent, Vacuum Distillation Instrument LOUIE R ASKEW, ILMVAC 2:10 (1535-3) Advancements in Low-Cost Discrete Analysis of Inorganic Ions in Waters DAVID RIESE, Westco Scientific Instruments 2:30 (1535-4) Automated Mercury Analysis: Including Digestion JASON P GRAY, AGS Scientific, Inc., Koji Tanida, Alvin Chua 2:50 (1535-5) User-friendly Gas Analysis Systems PHILIP L HANST, Infrared Analysis, Inc.

POSTER SESSION
Capillary Electrophoresis: Capillary Technology
Wednesday Afternoon

Session 1560

(1560-1 P) Examining the Behavior of Polyelectrolyte Multilayer Coated Capillaries in Capillary Electrophoresis PETER B BARTLINE, College of the Holy Cross, Aaron J Mancuso, Kimberley A Frederick (1560-2 P) Microemulsion Polymers for Achiral Separation in Microemulsion Electrokinetic Chromatography CHEERAPA BOONYAKONG, Georgia State University, Syed A Rizvi, Shahab A Shamsi (1560-3 P) Ionic Liquid Coated Capillaries for Separations in Open-Tubular Capillary Electrochromatography KRISTIN A FLETCHER, Louisiana State University, Aaron Tesfai, Sheila N Baker, Gary A Baker, Isiah M Warner (1560-4 P) Utility of Mixed Micelles for Simultaneous Chiral Separation of Structurally Similar Compounds in Micellar Electrokinetic Chromatography: An Approach towards High Throughput Chiral Analysis SHERON FRANKLIN TATE, Georgia State University, Rashid Iqbal, Syed A Rizvi, Shahab A Shamsi (1560-5 P) Separation of Prostaglandin E2 and E3 in MEKC Using a Polymeric Surfactant as a Pseudostationary Phase XIAODONG HUANG, Louisiana State University, Xiaofeng Zhu, Mary W Kamande, Yvonne Denkins, Isiah M Warner (1560-6 P) Analytical Separations Using Polymer-Coated Capillaries and Polymeric Surfactants in Micellar Electrokinetic Chromatography MARY W KAMANDE, Louisiana State University, Simon M Mwongela, Linda S Wabuyele, Isiah M Warner (1560-7 P) A Real Time Method for Studying Electroosmotic Flow in Coated Capillaries. AARON J MANCUSO, College of the Holy Cross, Peter B Bartline, Kimberley A Frederick (1560-8 P) Synthesis and Characterization of OT-CEC Ion-Exchange Ligands CHRISTIE M MCCLAIN, University of Redlands, David P Schrum (1560-9 P) Chiral Separations Using Polymeric Surfactants in Mixed-Mode Open-Tubular Capillary Electrochromatography ALEETA M POWE, Louisiana State University, Lunet E Luna, Ayse Demir, Isiah M Warner (1560-10 P) Affinity Capillary Electrophoresis of Vesicles of Amphiphilic Cyclodextrins TOBIAS REVERMANN, University of Twente, Choon Woo Lim, Bart J Ravoo, Uwe Karst, David N Reinhoudt (1560-11 P) Synthesis, Characterization and Application of Novel Polymeric Cationic Surfactant SYED A RIZVI, Georgia State University, Shahab A Shamsi (1560-12 P) In Situ Photopolymerization of Sol-gel Monolithic Column for Capillary Electrochromatography JIE ZHENG, Georgia State University, Jingguo Hou, Syed A Rizvi, Shahab A Shamsi (1560-13 P) Optimization of Gel Porosity in Sol-Gel Capillary Electrochromatography ERIKA M TEICHERT, U.S. Naval Academy, Christine L Copper, Braden C Giordano, Greg E Collins (1560-14 P) Effect of Functional Group Type on Sol-Gel Capillary Electrochromatographic Separations NICHOLAS A ROA, U.S. Naval Academy, Christine L Copper, Braden C Giordano, Greg E Collins

POSTER SESSION

Session 1540

Afternoon posters will be on display from 1:30 PM to 4:30 PM with authors present from 1:30 PM to 3:30 PM. The posters will be located on the Southeast corner of the Exposition floor (beginning Aisle 2900).

Capillary Electrophoresis: Applications and MS Detection

Wednesday Afternoon (1540-1 P) Ion Chromatography and Capillary Electrophoresis for Characterization of Pharmaceuticals, Foods and Polymers OLGA BERSHEVITS, ASIST Inc, Michael Markelov (1540-2 P) Solid Phase Extraction Method for Removal of Perchlorate from Biological Samples for CE Analysis MARK A WAKSMONSKI, Alltech Associates, Inc., Robert Pawlosky (1540-3 P) Rapid Determination of Methylphosphonic Acid Nerve Agent Degradation Product by Capillary Electrophoresis with UV Detection DAVID J WEISS, University of Colorado at Colorado Springs, Christopher R Anderton, Angela K Cook, Kristopher J McKee, Justin A Russak, Allen M Schoffstall (1540-4 P) Electrophoretic Mobility Analysis of Surface-Modified Semiconductor Nanocrystals JOHN T WILLIAMS, Duquesne University, Mitchell E Johnson (1540-5 P) A Novel Competitive Immunoassay of Morphine with Improved Sensitivity Using Online Immuno-affinity Column XIN-XIANG ZHANG, Peking University, Jian-Qiu Mi, Xiao-Hua Qi (1540-6 P) Enantiomeric Separation of Metolachlor and its Metabolites Using LC/MS and CZE CHRISTINE KLEIN, University at Buffalo, Diana S Aga (1540-7 P) Capillary Electrochromatography-Electrospray Ionization Mass Spectrometry (CEC-ESI-MS) of Alcohol Ethoxylate (AE) Type Brij Series Surfactants DEAN S NORTON, Georgia State University, Shahab A Shamsi (1540-8 P) Capillary Electrophoresis and Mass Spectrometric Analysis of Sulfonated Porphyrins ANILA F GILL, Georgia State University, Dabney W Dixon

POSTER SESSION
Capillary Electrophoresis: Bioanalytical Applications
Wednesday Afternoon

Session 1550

(1550-1 P) Reversible Guanosine Gels as Mobile Phases for DNA Separations in Capillary Electrophoresis WILLIAM S CASE, Duke University, Linda B McGown (1550-2 P) Development of Analytical Tools in Capillary Systems for Metabolic Analysis at Single Cell Volumes and Concentrations J. M. DRAGAVON, University of Washington, L. W. Burgess, A. C. Young, A. K.-Y. Jen, T. J. Hankins, J. B. Callis, T. J. Strovas, M. E. Lidstrom (1550-3 P) Monitoring the in vitro Advanced Glycation Endproduct (AGE) Formation of Glyoxylate with Lysine, Arginine and Glucosamine Using Capillary Electrophoresis. UDAYAN DUTTA, University of Rhode Island, Joel A Dain (1550-4 P) Separation of Recombinant Human Erythropoietin Glycoforms by Ionene-Coated Capillary Electrophoresis and On-line Capillary Electrophoresis- Electrospray Ionization-Mass Spectrometry HUWEI LIU, Peking University, Bing Yu (1550-5 P) Separation and Quantitation of Bifidobacterium Using Capillary Electrophoresis TIMOTHY WARD, Millsaps College, Jason Eastlack, Courtney Vowell, Aprile McGilvray, David Smith, Geoff Stone, Robert Nevins (1550-6 P) Application of Metal Nanoparticles for Capillary Electrophoresis Separations SHONTELL F WRIGHT, University of Toledo, Jon Kirchhoff, Olga Shulga, Claudine Lumibao (1550-7 P) Monitoring GABA in the Rodent Brain in Vivo Using Microdialysis Coupled to CE-LIF KRISTIN N SCHULTZ, University of Michigan

POSTER SESSION
Capillary Electrophoresis: UV/Fluorescence Detection
Wednesday Afternoon

Session 1570

(1570-1 P) Experimental and Theoretical Investigations Into Contactless Conductivity Detection and Capillary Electrophoresis PATTY J DENNIS, University of North Carolina at Chapel Hill, James W Jorgenson (1570-2 P) Evaluation of Thermodynamic and Kinetic Parameters for Peptidyl-Proline Isomerization by Capillary Electrophoresis CARL D NEWMAN, Michigan State University, Victoria L McGuffin (1570-3 P) Quantitation Study and Sample Preparation for High Throughput SDS-Protein Separations by Multiplexed Capillary Gel Electrophoresis with UV Absorption Detection HO-MING PANG, CombiSep, Inc., Siquan Luo, Jason Gruenhagen (1570-4 P) Analysis of Dietary Supplements Containing Green Tea Extracts DAVID J WEISS, University of Colorado at Colorado Springs, Eric J Austria, Suzanne M Bloemen, Richard W Hompesch (1570-5 P) Separation of Phenolic Acids in Maytenus obscura with Ionic Liquids as Modifiers by Use of Miceller Electrokinetic Chromatography ALICIA A WILLIAMS, Louisiana State University, Jane I Murungi, Isiah M Warner

85

(1570-6 P) Withdrawn (1570-7 P) Large Volume Stacking with Polarity Switching for the Analysis of Bacteria by Capillary Electrophoresis-Laser Induced Fluorescence LIJUN YU, The National University of Singapore (1570-8 P) The Study of Redox Reaction between Menadione and Reduced Glutathione by Capillary Electrophoresis MINGJIA WU, Changchun Institute of Applied Chemistry, Yajun Tang (1570-9 P) Protein Labeling with Red Squarylium Dyes for Analysis by Capillary Electrophoresis with Laser-Induced Fluorescence Detection CHRISTA L COLYER, Wake Forest University, Weiying Yan, Hiroyuki Nakazumi, Shigeyuki Yagi (1570-10 P) Argininosuccinate Assays of Individual Neurons Using Capillary Electrophoresis with Laser-Induced Fluorescence Detection XIAOYING YE, University of Illinois at Urbana, Won-Suk Kim, Stanislav S Rubakhin, Jonathan V Sweedler

POSTER SESSION
Microfluidics/Lab-on-a-Chip
Wednesday Afternoon

Session 1590

(1590-1 P) Rapid Microelectrophoretic Detection of Low Abundant Colorectal Point Mutations Using a Polymeric Microfluidic Device RONDEDRICK D SINVILLE, Louisiana State University (1590-2 P) A Novel Microfluidic Chip-Electrospray Mass Spectrometry Interface for Low Electroosmotic Flow Systems and Sensitive, Positive Ion Mode Mass Spectrometry Detection of High pH Tryptic Digests. TRUST T RAZUNGUZWA, West Virginia University, Aaron T Timperman (1590-3 P) Development of Miniaturized Electric Field Gradient Focusing for Protein Analysis RYAN T KELLY, Brigham Young University, Paul H Humble, Milton L Lee, Adam T Woolley (1590-4 P) A Microchip-Based Blood Brain Barrier Mimic for Monitoring the Fate of Endothelium-Derived Nitric Oxide MATTHEW K HULVEY, Saint Louis University, R. Scott Martin, Dana M Spence (1590-5 P) Towards Microchip Liquid Chromatography Using Electrochemical Micropumps HERNAN V FUENTES, Brigham Young University, Jason W Munyan, Adam T Woolley (1590-6 P) Chemistry on a Microchip: Fluorescence Derivatization of Fatty Amines KRISTIN M ADAMS, Duquesne University, Tara S Carpenter, Mitchell E Johnson (1590-7 P) A Miniaturized FIA Analyzer for Monitoring Total Trihalomethanes and Total Haloacetic Acids in Drinking Water GIJA GEME, University of Memphis, Lucy J Thurston, James J Aschberger, Gary L Emmert (1590-8 P) Electro-Driven Synchronized PCR on Polycarbonate Microchip JIFENG CHEN, Louisiana State University, Steven A Soper (1590-9 P) Culturing Neural Cells in Microfluidic Networks SAMUEL P FORRY, National Institute of Standards and Technology

POSTER SESSION
Fuels, Energy and Petrochemicals
Wednesday Afternoon

Session 1580

(1580-1 P) Evaluation of Coatings and Alloys to Extend the Lifetime of Equipment Used in Corrosive Environments GARY A BARONE, Restek Corporation, David A Smith (1580-2 P) Simplify the Analysis of Permanent Gases, Light Hydrocarbons and a Variety of Other Gases Using a Unique Micropacked Column. BARRY L BURGER, Restek Corporation (1580-3 P) Analysis of Saturated Paraffins in Petroleum by Fast Gas Chromatography LEI CAO, Shimadzu (Hong Kong) Ltd., Jie Wu, Ying Ming Li, Yuki Hashi (1580-4 P) Withdrawn (1580-5 P) Multidimensional Packed Column Analysis System for Hydrocarbon Type Analysis (ASTM D6839): A New Approach JOS M CURVERS, Varian, Inc., Hans van den Heuvel, Paul van den Engel, Willem van Raalte (1580-6 P) New Mass Spectrometric System for Combustion Engine Development: Ultra Fast Online-Measurement of HC-Components MARCUS GOHL, Airsense Automotive, Andreas Walte, Wolf Muenchmeyer, Gerhard Matz (1580-7 P) The Dense Gas Extraction of Paraffinic Distillates from Controlled Release Cellulose Fibers Using Carbon Dioxide AL KAZIUNAS, Applied Separations (1580-8 P) Long-Term Monitoring of New Odorants in Natural Gas with a Small Trap and Thermal Desorption System Combined with a Portable GC WOLF MUENCHMEYER, Airsense Analytics, Andreas Walte, Theo Anderbruegge (1580-9 P) Preparation of Sulfur Free Toluene for the Blank Solution of High SensitiveTotal Sulfur Analyzer MAEDA TSUNEAKI, National Institute of Advanced Industrial Science and Technology (AIST), Shimosaka Takuya, Kato Kenji, Sugiura Shouichi, Hayashi Norio (1580-10 P) New Method for the Supervision of Biogas Fermenter Using Gas-Sensor-Arrays (Electronic Nose) ANDREAS WALTE, Airsense Analytics, Wolf Muenchmeyer (1580-11 P) HT-Phases for High Temperature Chromatography: Extending the Temperature Limits of Common Stationary Phases Near 400C JAAP DE ZEEUW, Varian, Inc., Coen Duvekot (1580-12 P) Changes to the Standard PFPD Sulfur Configuration To Reduce Hydrocarbon Quenching in Gasoline Samples LAURA CHAMBERS, OI Analytical, Michael L Duffy (1580-13 P) Determination of Methyl Ester Contents in Biodiesel Blends by FTIR-ATR and FT-NIR JOEL C RUBIM, Universidade de Braslia, Paulo A Z Suarez, Rafael Montalvo, Jefferson S De Oliveira, Leila Daher (1580-14 P) Systematic Modeling of a Hydrodesulfurization Reactor Using Pilot Plant Experiments ENRIQUE ARCE-MEDINA, Esiqie, Instituto Politecnico Nacional, Fabian Mederos-Nieto (1580-15 P) Multi-Component Trace Level Sulfur Analysis in Hydrocarbon Streams RONALD TERHART, Varian B.V.

POSTER SESSION
New Approaches in Science Education
Wednesday Afternoon

Session 1600

(1600-1 P) Teaching General and Analytical Chemistry Students Successive Approximations MARK T STAUFFER, University of Pittsburgh at Greensburg (1600-2 P) Revisiting the Miller-Urey Experiment: A Topic Suitable for Undergraduate Research Projects and Laboratory Curricula MARK T STAUFFER, University of Pittsburgh at Greensburg, Almaan El-Attrache, Corey Yerace (1600-3 P) An Undergraduate Research Investigation of Iron Extraction and Chelation in Membranes MARK T STAUFFER, University of Pittsburgh at Greensburg, Yelena Volchansky (1600-4 P) On-line Evaluation of Training Needs and Customizable Modular Courses to Meet Them CHRISTINA S GILPIN, Selectosep, LLC, Joseph G Solch, Roger K Gilpin

POSTER SESSION
Spectroscopy: General Posters
Wednesday Afternoon

Session 1610

(1610-1 P) Responses of Polymer Surfaces to Protein Adsorption MATTHEW L CLARKE, University of Michigan, Chunyan Chen, Jie Wang, Zhan Chen (1610-2 P) Surface Enhanced Raman Spectroscopy of Bacterial Spores on Silver Colloids JOY D GUINGAB, University of Florida, Benjamin W Smith, Nicolo Omenetto, James D Winefordner (1610-3 P) Novel Fluorescence Biosensor Based on Energy Transfer between Fluorescently Labeled Peptides and Gold Nanoparticles YING LONG, University of New Orleans, Zeev Rosenzweig (1610-4 P) Photophysical and Photochemical Studies of Novel Near-IR Metallo-Phthalocyanine Dyes as Fluorescent Probes for DNA Sequencing VERA T VERDREE, Louisiana State University, Guif Su, Michael W Allen, Li (Julie) Zhu

86

(1610-5 P) Probing the Structure of Water and Aqueous Solutions Using Terahertz Pulsed Spectroscopy THOMAS LO, TeraView Limited, David A Newnham, Tom Blundell, Michael Pepper, Philip F Taday (1610-6 P) Withdrawn (1610-7 P) The Effect of Nanoparticle Core Size on the Exchange Dynamics of Ligands on the Clusters Au38(SC2Ph)24 and Au140(SC2Ph)53 RUI GUO, University of North Carolina at Chapel Hill, Yang Song, Gangli Wang, Royce W Murray (1610-8 P) Beyond C9H8 Carbene Mechanisms via 13C-NMR and 13CLabeling MOHAMMAD Z KASSAEE, Tarbiat Modarres University, Maryam, Ahmadreza Koohi,Bekhradnia (1610-9 P) Homogeneous Oxidative Coupling Catalysts: Mechanism of Catalysts Formation by Oxidation of [(Pip)[sub]nCuX]4, (n = 1 or 2, Pip = piperidine, X = Cl, Br or I) by Dioxygen in Aprotic Media HISHAM A ABOELDAHAB, University of Alexandria, Taher S Kassem, Mohamed A El-Sayed, Ali E El-kholy, Kamal Z Ismail (1610-10 P) Chemical,Thermal, and Ultrasonic Stability of Nanoparticles and Nanostructures STEVEN R ISAACS, Western Kentucky University, Nathan Whitely, Wei-Ping Pan, Ju-Hyun Ahn, Weon-Bae Ko, Young-Seok Shon (1610-11 P) Rapid Simple Method to Detect the Degradation of Povidone Iodine Solution REBECCA Y JAW, Regeneration Technologies, Inc., John W Howell, Chandra Nataraj (1610-12 P) Visualization of Immunoassay Based on a Spot Test and Its Application to CReactive Protein EMIKO KANEKO, , Keisuke Morita (1610-13 P) XRF with the XRD RODNEY A CLAPP, GBC Scientific Equipment Pty. Ltd. (1610-14 P) The Creation and Investigation of Quasimonochromatic Beamsof X-ray Radiation BAKHODIR KHAKBERDIEV, Samarkand State University (1610-15 P) Investigation of the Crystal-Crystal Transformations and the Crystallinity Changes in Olefin Nanocomposites Using XRD KATHERINE A MACCHIAROLA, PANalytical, Inc., Vasilis Gregoriou, Georgia Kandilioti, Spiros Tzavalas, Stavos Bollas (1610-16 P) PVC: A New Reference Material for Calibration of X-ray Fluorescence Analysis RAINER SCHRAMM, Fluxana (1610-17 P) Depth Profiling and X-ray Photoelectron Spectroscopy Analysis of a Black Deposit Associated with Rock Paintings in Little Lost River Cave, Idaho RUTH ANN ARMITAGE, Eastern Michigan University, Reshmi Perumplavil, Simon Garrett (1610-18 P) Concentration of Particulate Matter by Fluctuation Analysis VALERY BULATOV, Technion, Ding Sha, Israel Schechter (1610-19 P) Quantitative NMR Analysis for Compounds with Exceptionally Long T1 DAVID H SCHORY, Isotec, Sigma-Aldrich, Lisa Roth, John E Kuo, C T Tan (1610-20 P) Synthesis and Fluorescence Characterization of Dansyl Chloride in Polysiloxane/Silicate Core-Shell Nanoparticles JEFFREY L WONG, University of Florida, Jorge L Chavez, Randolph S Duran (1610-21 P) Homogeneous Oxidative Coupling Catalysis: From Tetranuclear Copper to Heteropolynuclear Resdox-Active Complexes KAMAL Z ISMAIL, Bronx Community College, Mohamed A El-Sayed, Ahmed H Abddel Salam, Tahani A El-Zayat, Ali El-Dissouky

(1620-5 P) Gas Visualization by Multispectral Infrared Imaging: First Results of Measurements with an Uncooled Detection System ROLAND HARIG, TU Hamburg-Harburg, Peter Rusch, Gerhard Matz, Falk Kirsche (1620-6 P) The Synthesis of a New Kind of Ag-Au-Si Nano Particle and its Application on SERS WEI HE, Peking University, Jian Qi, Limin Yang, Yizhuang Xu (1620-7 P) Instrument Resolution Effects for Open-Path FT-IR Spectra of Small Molecules MATTHEW J POLLARD, University of Idaho, Limin Shao, Peter R Griffiths (1620-8 P) An Automated Passive Scanning Infrared Remote Sensing System for Aircraft Exhaust Measurements PETER RUSCH, Technische Universitaet Hamburg-Harburg, Roland Harig, Gerhard Matz, Klaus Schaefer, Carsten Jahn, Selina Utzig (1620-9 P) Following Permeation through Polymer Electrolyte Membranes by Continuous Flow FT-IR-ATR JAMES M SLOAN, U.S. Army Research Laboratory, Eugene Napadensky (1620-10 P) Rapid Detection of Methylmethoxysilane Hydrolysis in a Biomatrix by Raman Spectroscopy MARY J TECKLENBURG, Central Michigan University, Martin Bennett, Kurt F Brandstadt (1620-11 P) Improving Colon Cancer Diagnosis Using IR Spectroscopy HOEIL CHUNG, Hanyang University, Hankyu Namkung, Sungjae Lee, JongJae Park, Chil Hwan Oh (1620-12 P) Microscopic FTIR Spectral Mapping of Salivary Mucoepidermoid Carcinoma YU-HAI LIU, Peking University, Cheng-feng Zhang, Yi-zhuang Xu, Yuan-yuan Song, Yushi Hashi , Jing Wang, Kai-hua Sun, Zhen-hua Xu, Shi-fu Weng, Duan-fu Xu, Jin-guang Wu (1620-13 P) The Use of Flexible Infrared Spectrometer Software to Address the Diverse Needs of a Liberal Arts Undergraduate Chemistry Program DAVID S TRIMBLE, Swarthmore College, Ellen V Miseo (1620-14 P) Case Studies of Determining Changes in Polymeric Supplier Materials or Products by FT-IR Spectroscopy KATHERINE ROBERTSON, Impact Analytical (1620-15 P) Critical Importance of the Junction in Metal Nanoparticles to Yield Single Molecule Detection in SERS MASAYUKI FUTAMATA, NARCAIST, Yoshihiro Maruyama (1620-16 P) Spectrum: Structure Correlations in Infrared and Raman Spectroscopy, A Corporate Resource MICHAEL BORUTA, Advanced Chemistry Development, Inc., Michel R Hachey, Antony J Williams (1620-17 P) Mid-Infrared Diffuse Reflection Spectrometry of Chemical Warfare Agent Simulants on Absorbing Substrates LACEY A AVERETT, University of Idaho, Peter R Griffiths (1620-18 P) Modern Photoacoustics - Ultrasensitive Tool for FTIR Spectroscopy VESA KOSKINEN, University of Turku, Jyrki Kauppinen, Ismo Kauppinen

POSTER SESSION
Spectroscopy: Near Infrared
Wednesday Afternoon (1630-1 P) Withdrawn

Session 1630

(1630-2 P) Prediction of Quality Components in Baking Formulations by NIR RONALD L RUBINOVITZ, Buchi Analytical Inc.

POSTER SESSION
Spectroscopy: Infrared and Raman
Wednesday Afternoon

Session 1620

(1630-3 P) Development of an On-line Method for the Determination of Ammonium Bicarbonate in an Advanced Aqueous Ammonia-CO2 Scrubbing System STUART C BURRIS, Western Kentucky University, Holt Bui, Lingyu Meng, Wei-Ping Pan (1630-4 P) High Intensity Tunable Sources for Near-Infrared Spectroscopy RICHARD A CROCOMBE, Axsun Technologies, Walid Atia, Dale F Flanders (1630-5 P) Depth-profiling of Skin in the Near Infrared Region Using a Newly Developed Near Infrared Spectrometer and Fiber Optic Probes HYO-JIN KIM, Dongduk Women's University, Young-Ah Woo (1630-6 P) Expanding the Role of NIR in Identification through Analysis of New Materials and Software Tools RONALD L RUBINOVITZ, Buchi Analytical Inc. (1630-7 P) Elucidation of Chiral Activated Membranes by Microscopy Techniques and NIR CRISTINA PALET, Universitat Autonoma de Barcelona, Aleix Conesa, Tania Gumi, Manuel Valiente, Jordi Coello (1630-8 P) Effects of Near Infrared Resolution on Multivariate Optical Element Design and Performance LUISA T PROFETA, University of South Carolina, Michael L Myrick

(1620-1 P) Development of Standards for Raman Analysis of Bone Mineral AYORINDE AWONUSI, Central Michigan University, Dennis Sharhoda, Mary J Tecklenburg (1620-2 P) Far-IR Analysis via ATR MICHAEL S BRADLEY, Thermo Electron Corporation, Federico Izzia (1620-3 P) Paramater Selection for Applications of High Speed FT-Raman Spectroscopy FRANCIS J DECK, Thermo Corporation (1620-4 P) Development of Evanescent Wave IR Sensor for Determination of Chirality of Amino Acids GENIN HUANG, National Chung-Hsing University, Yang Jyisy

87

POSTER SESSION

Session 1640

Spectroscopy: Surface Analysis and Microscopic Imaging Techniques

Wednesday Afternoon (1640-1 P) Probing Polarity Distribution in Chromatographic Stationary Phase by Confocal Ratiometric Imaging of Nile Red ZHENMING ZHONG, University of Iowa, M Lei Geng (1640-2 P) Synthesis, Characterization, and Prospective Use of Polysilane Films in Neuronal Attachment Studies BARNABAS K GIKONYO, Southern Illinois University, Lori A Vermeulen (1640-3 P) Dielectrophoresis Force Microscopy AL M HILTON, Purdue University, Brian M Lynch, Garth J Simpson (1640-4 P) Surface Characterization of GOPS Film on Silicon Substrates for the Development of Optical DNA Biosensors APRIL WONG, University of Toronto, Ulrich J Krull (1640-5 P) Increasing the Measurement Precision in Widefield Chemical Imaging: A Pharmaceutical Tablet Content Uniformity Study RYAN PRIORE, University of South Carolina, Michael L Myrick

10:35 (1660-4) Mineralogy at Meridiani Planum and Gusev Crater from the Mssbauer Spectrometers on Spirit and Opportunity GSTAR KLINGELHFER, Johannes Gutenberg-University Mainz, Richard V Morris 11:10 (1660-5) In-situ Chemical Analysis on the 2007 Phoenix Mars Scout Mission SAMUEL P KOUNAVES, Tufts University

SYMPOSIUM

Session 1670

High Performance Separations are Entering the Age of Systems Biology - arranged by Andras Guttman, Leopold-Franzens University
Innsbruck Thursday Morning, Room S210E Andras Guttman, Leopold-Franzens University Innsbruck, Presiding 8:30 Introductory Remarks - Andras Guttman

8:35 (1670-1) HPLC: The Past, the Present and the Future ANDRAS GUTTMAN, Leopold-Franzens University Innsbruck 9:10 (1670-2) A Systems Approach to Bioseparations for Systems Biology BARRY L KARGER, Northeastern University 9:45 (1670-3) New Stationary Phases for On-line and Off-Line Chromatographic Separation Systems for the Analysis of Complex Samples GUENTHER K BONN, University of Innsbruck, Guenther Stecher, Christian W Huck 10:20 Recess 10:35 (1670-4) The Understanding of the Theoretical Backgrounds of Ion Selective Electrodes ERNO PUNGOR, Bay Zoltan Foundation 11:10 (1670-5) TBA

THURSDAY, MARCH 3, 2005

SYMPOSIUM
Session 1650

Analytical Chemistry Award for Young Investigators in Separation Science - arranged by Victoria L McGuffin, Michigan State
University Thursday Morning, Room S210a Victoria L McGuffin, Michigan State University, Presiding 8:30 Introductory Remarks - Victoria L McGuffin

SYMPOSIUM

Session 1680

Miniature Spectrometers for Process Analytical Chemistry: Towards a Spectroscopic Sensor - arranged by Richard A Crocombe,
AXSUN Technologies Thursday Morning, Room S230H Richard A Crocombe, AXSUN Technologies, Presiding 8:30 Introductory Remarks - Richard A Crocombe

8:35 Presentation of the 2005 Analytical Chemistry Award for Young Investigators in Separation Science to Andre M Striegel, Florida State University, by Victoria L McGuffin, Michigan State University 8:40 (1650-1) Influence of Long-Chain Branching on Mechanochemical Polymer Degradation in a Transient Elongational Flow ANDRE M STRIEGEL, Florida State University 9:15 (1650-2) Characterization of Branching in Polyolefins and Ethylene Copolymers PATRICIA M COTTS, DuPont 9:50 (1650-3) Polymer Characterization Using SEC-FTIR PAUL J DESLAURIERS, Chevron Phillips Chemical Company, LP 10:25 Recess 10:40 (1650-4) Polyolefin Microstructure Characterization Using 3DGPC-TREF WALLACE W YAU, Equistar Chemicals, LP 11:15 (1650-5) Intracolumn Dynamics in Reversed-Phase Chromatography JOHN G DORSEY, Florida State University

8:35 (1680-1) Shrinking Spectrometers Down to Spectral Sensors: The Wave of the Future for Applied Spectroscopy JOHN COATES, Coates Consulting 9:10 (1680-2) Advantages of Application Specific Measurement Systems MARTIN WARMAN, Pfizer, Inc., Steve V Hammond 9:45 (1680-3) Chip-Sized Optical Spectrometers in Process Analysis RICHARD A CROCOMBE, Axsun Technologies 10:20 Recess 10:35 (1680-4) Spectroscopic Monitoring of Unit Operations JAMES RYDZAK, GlaxoSmithKline, Ricard Escott, Christian Airiau, Jill Parris 11:10 (1680-5) Rapid Applications Development for On-line Process Analysis W. MICHAEL DOYLE, Axiom Analytical, Inc., Michael M Power

SYMPOSIUM
Nanomat, Inc. Thursday Morning, Room S220B David F Pensenstadler, Nanomat, Inc., Presiding 8:30

Session 1660

Analytical Chemistry on Mars - arranged by David F Pensenstadler,

SYMPOSIUM

Session 2170

New Spectroscopic Methods to Investigate Membrane Bilayer Structure and Function - arranged by Joel M Harris, University of Utah
Thursday Morning, Room S230B Joel M Harris, University of Utah, Presiding 8:30 Introductory Remarks - Joel M Harris

Introductory Remarks - David F Pensenstadler

8:35 (1660-1) The History - Past, Present, and Future of Mars Exploration JAMES B GARVIN, NASA 9:10 (1660-2) Objectives of Surface Operations of the Mars Rover Mission JENNIFER HARRIS TROSPER, NASA 9:45 (1660-3) Martian Soil and Rocks Analyses with the Athena Payload on Spirit and Opportunity Rovers THANASIS E ECONOMOU, University of Chicago 10:20 Recess

8:35 (2170-1) Molecular Devices Based on Planar Lipid Bilayers, Conductive Polymers, and Electroactive Waveguides SCOTT SAAVEDRA, University of Arizona 9:10 (2170-2) Microfluidics for Protein-Membrane Interactions PAUL S CREMER, Texas A&M University 9:45 (2170-3) New Spectroscopic Methods to Investigate Membrane Bilayer Structure and Function RICHARD A DLUHY, University of Georgia, Saratchandra Shanmukh 10:20 Recess

88

10:35 (2170-4) Lipid Transbilayer Transport Measured Directly by Sum-Frequency Vibrational Spectroscopy JOHN C CONBOY, University of Utah, Jin Liu 11:10 (2170-5) Optical-Trapping Raman Microscopy of Single Lipid Vesicles JOEL M HARRIS, University of Utah, Christopher Fox, Robert Horton, Daniel Cherney

ORAL SESSION
Chemometrics
Thursday Morning, Room S210B Husheng Yang, AstraZeneca Pharmaceuticals LP, Presiding

Session 1710

SYMPOSIUM

Session 1690

8:30 (1710-1) Multivariate Modeling of Dual Scanion and Differential Mobility Spectra PING CHEN, Ohio University, Peter B Harrington 8:50 (1710-2) Chemometric Discrimination of Honeys as a Function of Origin Using Visible, Mid- and Near-Infrared Spectra and Their Combinations NATHALIE ESTEPHAN, INA-PG, Gerard Downey, Doug Rutledge 9:10 (1710-3) The IUPAC - NIST Chemical Identifier Project - INChI STEPHEN HELLER, National Institute of Standards and Technology, Stephen Stein, Dmitrii Tchekhovskoi 9:30 (1710-4) Group Baseline Correction for Multivariate Analysis MICHEL R HACHEY, Advanced Chemistry Development, Inc., Michael Boruta, Andrey Bogomolov 9:50 (1710-5) A Miniaturized Analyzer Design for Process and Handheld Chemical Composition Measurements THOMAS HAGLER, Advanced Photometrics Inc. 10:10 Recess 10:25 (1710-6) Conversion of NIR Spectra between Different Spectrometers and its Application to Calibration Transfer of Qualitative and Quantitative Multivariate Calibration Models HUSHENG YANG, AstraZeneca Pharmaceuticals LP, Norman A Wiggins, Thorsten Herkert, Igor Nazarov 10:45 (1710-7) Spatial Simplicity as an Optimization Criterion in Multivariate Image Analysis MICHAEL R KEENAN, Sandia National Laboratories, Paul G Kotula 11:05 (1710-8) Integrated Sensing and Processing (ISP) with a Tailored Excitation Signal for Acoustic Resonance Spectrometry JOSEPH P MEDENDORP, University of Kentucky, Robert A Lodder 11:25 (1710-9) Coerced Convergence of Multivariate Curve Resolution DAVID K MELGAARD, Sandia National Laboratories, David M Haaland, Michael R Keenan, Paul G Kotula 11:45 (1710-10) Calibration Methods and Error Analysis for a Dual Luminophore Pressure Sensitive Paint (PSP) Data MUHAMMET E KOSE, University of Florida

Updates to Environment Canada and U.S. EPA Solid Waste and Air Methods - arranged by Richard Turle, Environment Canada
Thursday Morning, Room S210C Richard Turle, Environment Canada, Presiding 8:30 Introductory Remarks - Richard Turle

8:35 (1690-1) Current Status of, and New Developments in, EPA's RCRA BARRY LESNIK, U.S. Environmental Protection Agency 9:10 (1690-2) Final Rule Approving New and Revised EPA Wastewater Methods MARION KELLY, U.S. Environmental Protection Agency 9:45 (1690-3) Analytical Methods in the Context of the Canadian Environmental Protection Act and Canadian Fisheries Act RICHARD TURLE, Environment Canada 10:20 Recess 10:35 (1690-4) Highlights of Environmental Protection Agency Air Emission Test Method and Monitoring Development/Evaluation Activities for 2004 LARA AUTRY, U.S. Environmental Protection Agency 11:10 (1690-5) Interlaboratory Validation of a Reference Method for the Measurement of Hexachlorobutadiene and Chlorobenzenes in Chlorinated Solvents CHUNG CHIU, Environment Canada, Anivis Sanchez, Ying Jiang, Mylaine Tardif, Gary Poole

ORAL SESSION
Bioanalytical Spectroscopy I
Thursday Morning, Room S230C Zeev Rosenzweig, University of New Orleans, Presiding

Session 1700

8:30 (1700-1) Molecular Interactions between Fibrinogen and Biomedical Polymers MATTHEW L CLARKE, University of Michigan, Jie Wang, Zhan Chen 8:50 (1700-2) Probing the Intact Structure of Heme Protein Using Surface-enhanced Raman spectroscopy MANLIANG FENG, Jackson State University, Hiroyasu Tachikawa 9:10 (1700-3) Toward Rationally Designed SERS Substrates KATHLEEN S GIESFELDT, University of Tennessee at Knoxville, Marco A De Jesus, Nahla Abu-Hatab, Michael J Sepaniak 9:30 (1700-4) FTIR Microspectroscopy, Immunocytochemistry and Histochemistry of Post-Surgical Scar Tissue Formation KATHLEEN M GOUGH, University of Manitoba, Richard Wiens, Rak Margaret, Fred Zeiler, Bernhard H Juurlink, William M Kulyk 9:50 (1700-5) In-situ FTIR Spectromicroscopy of Brain Tissue from a Transgenic Mouse Model of Alzheimer Disease KATHLEEN M GOUGH, University of Manitoba, Meghan Gallant, Margaret Rak, Adam Bookatz, Marc R Del Bigio, Sabine Mai, David A Westaway 10:10 Recess 10:25 (1700-6) In-Vivo Skin NIR Spectra in the 1400 nm and 1900 nm Regions WEI G HANSEN, Uniqema, Marchel Snieder, Nico Dekker, Johann Wiechers 10:45 (1700-7) Development of a UV Raman Spectrometer with Acousto-Optic Tunable Filters KAHO KWOK, Northern Illinois University, Jon W Carnahan 11:05 (1700-8) Metal Nanoparticles Near Metal Surfaces: Properties Relevant to Surface Enhanced Raman Scattering-Based Immunoassays ROBERT J LIPERT, Iowa State University, Hye-Young Park, Jeremy D Driskell, Betsy Jean Yakes, Jill Uhlenkamp, Deepak Dibya, Marc D Porter 11:25 (1700-9) Lipobead-Based Fluorescence Biosensor for Urea AIHUI MA, University of New Orleans, Zeev Rosenzweig 11:45 (1700-10) Real-Time Monitoring of Adsorption and Retention of DNA on Patterned Self-Assembled Monolayers (SAMs) Using Total Internal Reflection Fluorescence Microscopy (TIRFM) HYE-YOUNG PARK, Iowa State University, Hung-Wing Li, Edward S Yeung, Marc D Porter

ORAL SESSION
Clinical Chemistry/Toxicology
Thursday Morning, Room S220F David N Rahni, Pace University, Presiding

Session 1720

8:30 (1720-1) Determination of Mercury in Whole Blood and Urine by Inductively Coupled Plasma Mass Spectrometry (ICP-MS): Developing Robust Methods for Challenging Matrices CHRISTOPHER D PALMER, New York State Department of Health, Patrick J Parsons 8:50 (1720-2) Analysis of Unknowns: Viscous Liquid PADINJAREKUTTU R RAVIKUMAR, New York City Department of Health & Mental Hygiene, Gar Ming Chan, Lewis Nelson, Robert S Hoffman, Michael Heller, Sara T Beatrice 9:10 (1720-3) Mobile Phase Ionic Liquid Additives for Separation of Biologically Important Molecules in Liquid Chromatography PALLAVI DESHPANDE, Duquesne University, Sejal Iyer 9:30 (1720-4) Evolution of XML/ HL7 Methods of Data Exchange for LIMS CHAITANYA DIWADKAR, Applied Biosystems, Vinc Woodall 9:50 (1720-5) Rapid Separation of Protein Glycoforms by CZE Using Dynamic Coatings WILLIAM W CHANG, Target Discovery, Inc., David C Bomberger, Luke V Schneider 10:10 Recess 10:25 (1720-6) The Determination of Homocysteine in Plasma Using High-Performance Liquid Chromatography and Electrochemical Detection HENDRIK-JAN BROUWER, , Khalid Tafrasti, Nico Reinhoud, Cees van Valkenburg 10:45 (1720-7) Metabolites in Human Breath: Ion Mobility Spectrometers as Diagnostic Tools for Lung Diseases JOERG INGO BAUMBACH, ISAS - Institute for Analytical Sciences, Wolfgang Vautz, Vera Ruzsanyi, Fang Li

89

11:05 (1720-8) The Cytotoxicity and Mechanisms of Selected Metal Oxide Nanoparticles Against Lung Cancer Cells WEISHENG LIN, University of Missouri-Rolla, Yue-wern Huang, Xiao-dong Zhou, Harlan Anderson, Yinfa Ma 11:25 (1720-9) Metabolomics: Applications for Drug Development and Diagnostics-a Method Transfer from Plant Metabolite Profiling RALF LOOSER, Metanomics GmbH & Co. KGaA, Bianca Bethan, Volker Haake, Michael Herold, Tilmann Walk, Arno Krotzky, Lilian Vakalopoulou 11:45 (1720-10) Disputed Case Study of a Novel Hallocinogen:5Methoxy-alpha-methyltryptamine PADINJAREKUTTU R RAVIKUMAR, New York City Department of Health & Mental Hygiene, Beth Y Ginsburg, Lewis Nelson, Robert S Hoffman, Michael Heller, Sara T Beatrice

11:25 (1740-9) Dansylated Amino-Propyl Controlled Pore Glass: A Model for Silica-Liquid Solvation PHILLIP M PAGE, University at Buffalo, Frank V Bright 11:45 (1740-10) Magnetically Modulated Optical Nanoprobes (MagMOONS) for Detection and Quantification of pH and Calcium Ion in Liposomes as a Model for Intracellular Environment TERESA G ROBERTS, University of Michigan, Jeffrey N Anker, Raoul Kopelman

ORAL SESSION
High-Throughput Chemical Analysis
Thursday Morning, Room S220G Donald G Patterson, DLS/NCEH/ATSDR/CDC, Presiding

Session 1750

ORAL SESSION
Drug Discovery
Thursday Morning, Room S230F Alice Chen, Presiding

Session 1730 8:30 (1750-1) Practical Considerations When Desiring Fast Separations in HPLC BRIAN A BIDLINGMEYER, Agilent Technologies, Inc. 8:50 (1750-2) Sequential and Simultaneous Injection: Techniques to Increase Sample Throughput and Productivity PETER A BODSKY, Dionex Corporation, Mike Kinderman 9:10 (1750-3) Syringe Pumps in Ultra-High Performance Liquid Chromatography PHILLIP B LIESCHESKI, Teledyne Isco, Inc., Dale Clay 9:30 (1750-4) Accuracy and Precision of Temperature Programmed HPLC JOHN RIZZO, Selerity Technologies, Dale Felix, Stephanie J Marin, Brian A Jones, Jody Clark 9:50 (1750-5) Evaluation of a Combined Electrospray and Photoionizaiton Source KARL HANOLD, Syagen Technology, Inc. 10:10 Recess 10:25 (1750-6) Measurement of Halogenated Contaminants in Human Serum and Milk Using GCxGC-IDTOFMS DONALD G PATTERSON , Centers for Disease Control and Prevention, Jean-Francois Focant, Andreas Sjodin, Wayman E Turner 10:45 (1750-7) Electrospray Ionization Reduced-pressure Ion Mobility Spectrometry for Fast Separations LI ZHOU, Brigham Young University, David C Collins, Edgar D Lee, Milton L Lee 11:05 (1750-8) Practical Strategies for Managing and Mining Large Datasets of Chemical, Spectral, and Biological Data VICTORIA RAFALOVSKY, Bio-Rad Laboratories, Inc., Deborah Kernan 11:25 (1750-9) Transforming Development Productivity COLIN M TOOMBS, PA Consulting Group 11:45 (1750-10) Withdrawn

8:30 (1730-1) Analytical Strategies for the Rapid Characterization of Diacylglycerol-Lactone Combinatorial Libraries JAMES A KELLEY, National Cancer Institute, Christopher C Lai, Dehui Duan, Lawrence R Phillips, Tracy L Wolfe, Victor E Marquez 8:50 (1730-2) Rapid Pre-Screening of Natural Products for Bioavailability by Hydrophobicity and Molecular Weight Cutoffs DEEPAK DIBYA, Iowa State University, Adam J Bergren, Nikola Pekas, Neil C Dias, Marc D Porter 9:10 (1730-3) Structure-Based Metabolite Identification Using InSilico Metabolite Prediction and Automated Interpretation of Mass Spectral Data DAVID D STRANZ, Sierra Analytics, Inc., Scott Campbell, Michelle L D'Souza 9:30 (1730-4) Micro Parallel Liquid Chromatography a HighThroughput Variant of HPLC for Routine Purity and Solubility Assessment of Small Molecule Compounds STEVE HOBBS, Nanostream, Paren Patel 9:50 (1730-5) Membrane on a Chip: Applications of Tethered Bilayers INGO KOEPER, Max Planck Institute for Polymer Research, Wolfgang Knoll, Randolph S Duran

ORAL SESSION
Thursday Morning, Room S220E Stephen L Morgan, The University of South Carolina, Presiding

Session 1740

Fluorescence in Proteomics, Forensics and Nanotechnology

8:30 (1740-1) FRET-Based DNA Sequencing Using Novel Near-IR Dyes MICHAEL W ALLEN, Louisiana State University, Steven A Soper, Vera T Verdree, Robert P Hammer 8:50 (1740-2) Improving FRET Bio-probe Sensitivity with Dendrimeric Superquencher CHAOYONG YANG, University of Florida, Weihong Tan 9:10 (1740-3) Fluorescence Decay of Tissue Phantoms: Potential in Tissue Classification for Cancer Diagnosis ANAMIKA MUBAYI, University of Iowa 9:30 (1740-4) Simultaneous Multiple Gene Monitoring Inside a Single Cell COLIN D MEDLEY, University of Florida, Timothy J Drake, Weihong Tan 9:50 (1740-5) Determination of Composition Boundary for Cancer Diagnosis Using Tissue Phantoms IOULIA A SKVORTSOVA, University of Iowa, Ed Crowell, M Lei Geng 10:10 Recess 10:25 (1740-6) A Fluorescence Based Assay for DNA Damage Induced by Toxic Industrial Chemicals SRIVIDYA KAILASAM, US-EPA, Kim R Rogers 10:45 (1740-7) Quantitative Determination of PhotofrinQuantitative Determination of Photofrin Following Periocular Subcutaneous Injection in Horses ELIZABETH J MORGAN, University of Missouri-Columbia, Elizabeth A Giuliano, Philip J Johnson, Sheryl A Tucker 11:05 (1740-8) Single Molecule Imaging of Immunochemical Reactions ISAAC A STAYTON, University of Missouri-Rolla, Bingcheng Lin, Yinfa Ma

ORAL SESSION
Buhlmann, University of Minnesota Thursday Morning, Room S230G Philippe Buhlmann, University of Minnesota, Presiding

Session 1760

Ionophore-based Chemical Sensors II - arranged by Philippe

8:30 (1760-1) Perfluorinated Matrixes as New Materials for Receptor-Doped Chemical Sensors with Extreme Robustness and Selectivity PHILIPPE BUHLMANN, University of Minnesota, Paul Boswell, Elizabeth Lugert 8:50 (1760-2) Transport of Organic Molecules through Fluorous Solvent-Containing Membranes NITHYA VAIDYANATHAN, University of Pittsburgh, Hong Zhao, Floyd Snyder, Jie Zhang, Marvin Yu, Stephen G Weber 9:10 (1760-3) Direct Detection of Heparin in Whole Blood with Reversible Electrochemical Sensors ALEXEY SHVAREV, Auburn University, Eric Bakker 9:30 (1760-4) Changes in the Composition of Hydrogen IonSelective Electrode and Optode Membranes Followed by Spectroelectrochemical Microscopy ERNO LINDNER, The University of Memphis, Jan Langmaier 9:50 (1760-5) Ionophores for Anion Recognition Based on Chiral Building Blocks AMANDA S WATTS, University of Kentucky, Sihui Long, Vasilis G Gavalas, Arthur Cammers, Leonidas G Bachas 10:10 Recess 10:25 (1760-6) Semiconductor Gallium Nitride-Based Anion Sensor NIKOS CHANIOTAKIS, University of Crete, Jiannis Alifragis, Alexandros Georgakilas, Giorgos Kostantinidis

90

10:45 (1760-7) Design and Synthesis of MS Probes for the Detection of Ions and Biomolecules by Mass Spectrometry KOJI SUZUKI, Keio University, Yoshio Suzuki, Aki Honda 11:05 (1760-8) Synthesis and Characterization of Novel Types of Ionophores KLRA TTH, Budapest University of Technology and Economics, Rbert E Gyurcsnyi, Rbert Bereczki, Istvn Bitter 11:25 (1760-9) Cobalt (II) Phthalocyanine as an Ionophore for the Detection of Potassium ANDREW R DE CARLO, Purdue University, D. Marshall Porterfield 11:45 (1760-10) Pt(II)TPP and Pt(IV)TPPCl2 as Ionophores for Polymeric Membrane Sensors. Potentiometric and Theoretical Study LARISA LVOVA, University of Rome "Tor Vergata", Giorgio Verrelli, Roberto Paolesse, Corrado Di Natale, Arnaldo D'Amico, Sergey Makarychev-Mikhailov

10:25 (1780-6) The Double Reciprocal Hypothesis: A New Concept for Designing Universal Chiral Stationary Phases XIAOLI WANG, University of Minnesota, Kent R Mann, Peter W Carr 10:45 (1780-7) Streamlining Chiral Method Development with Software Tools MARGARET ANTLER, Advanced Chemistry Development, Inc., Michael McBrien, Patrick Piras, Bernhard Koppenhoefer 11:05 (1780-8) A Global Collaboration for the Sharing of Liquid Chromatographic Column Information MICHAEL MCBRIEN, Advanced Chemistry Development, Inc., Robin Martin, Melvin R Euerby, Patrik Petersson 11:25 (1780-9) New Possibilities in Ion Chromatography Using Porous Monolithic Stationary Phase Media BRETT PAULL, Dublin City University, Pavel N Nesterenko 11:45 (1780-10) Screening of Inhibitors of Influenza: A Virus by a Combination of High Performance Affinity Chromatography and Peptide Libraries RUI ZHAO, Chinese Academy of Sciences, Canliang Fang, Xiao Yu, Yang Liu, Jia Luo, Dihua Shangguan, Shaoxiang Xiong, Guoquan Liu

ORAL SESSION
Laboratory Informatics I
Thursday Morning, Room S210D Thomas J Conti, Bayer MaterialScience, Presiding

Session 1770

ORAL SESSION

Session 1790

8:30 (1770-1) Integrating Instrument Control into a Laboratory Software Framework FRANK J TONTALA, Scientific Software, Inc. 8:50 (1770-2) Emerging Market for Electronic Laboratory Notebooks MICHAEL H ELLIOTT, Atrium Research 9:10 (1770-3) Global LIMS and CDS Projects: Are They Worth It? STUART M MILLER, Taratec Development Corporation 9:30 (1770-4) A Practical Guide to True Requirements Gathering for a Successful LIMS Implementation DON CROSSETT, Thermo Electron Informatics & Services, Todd Pollack 9:50 (1770-5) LIMS: Dump It or Deal with It-the Case for Integrated Systems JOHN G HUNTINGTON, Gateway Enterprises 10:10 Recess 10:25 (1770-6) The New Age of Configurability and Flexibility in LIMS Design for Life Sciences and High Throughput Screening DON CROSSETT, Thermo Electron Informatics & Services 10:45 (1770-7) The Emergence of Internet-Enabled Instrumentation ERIC REFFETT, National Instruments 11:05 (1770-8) Enterprise Standardization to Lower the Total Cost of Ownership of LIMS CATHY BROWN, Thermo Electron Informatics & Services 11:25 (1770-9) Instrument Integration in Pharmaceutical Quality Assurance Labs: Is It Worth It? KYLE MCDUFFIE, CSols, Inc. 11:45 (1770-10) Building a Business Case for LIMS MARK FISH, Thermo Electron Informatics & Services

Liquid Chromatography: Time-of-Flight Mass Spectrometry for Accurate-Mass Analysis of Pesticides and Pharmaceuticals in Food and Water - arranged by E Michael Thurman, University of Almeria
Thursday Morning, Room S220D E Michael Thurman, University of Almeria, Presiding 8:30 (1790-1) Identification of Fungicide Residues from Citrus Using Accurate Mass Measurement by LC/TOF MS MICHAEL WOODMAN, Agilent Technologies, Inc., Jerry A Zweigenbaum 8:50 (1790-2) Evaluation of LC/TOF/MS for the Quantitative Analyses of Pesticide Residues in Fruits and Vegetables JUAN F GARCIAREYES, University of Jaen, Milagros Mezcua, Imma Ferrer, Amadeo R Fernndez-Alba 9:10 (1790-3) Combining LC/MS Ion Trap and LC/MS Accurate Mass Analysis for the Identification of Unknown Fungicides in Fruit E MICHAEL THURMAN, University of Almeria, Imma Ferrer, Amadeo R Fernndez-Alba 9:30 (1790-4) HPLC/MS and HPLC/MS/MS as Routine Analytical Tools for Trace Analysis of Polar Organic Compounds in Complex Matrices EDWARD T FURLONG, U.S. Geological Survey, Jeffery D Cahill, Chad A Kinney, Stephen L Werner 9:50 (1790-5) Using Accurate Mass to Identify Compounds in Complex Matrices DOUGLAS E MCINTYRE, Agilent Technologies, Inc., Linda Lopez, Xiangdong Li 10:10 Recess 10:25 (1790-6) Investigation of Combination Medicines (Yaa-chut) in SE Asia via Accurate-Mass LC-TOF MS KRYSTYN ALTER, Georgia Institute of Technology, Colleen McShane, Saurabh Vishnubhakat, Paul Newton, Michael Green, Facundo M Fernandez 10:45 (1790-7) Considerations for LC-MS Determination of Antibiotic Residues in Animal Products MICHAEL S YOUNG, Waters Corporation, Kevin M Jenkins 11:05 (1790-8) Abundance-Ratio Dependent Global Quantitative Proteomic Analysis Using Differential Stable Isotope Labeling and Microbore LC MALDI QqT MS CHENGJIE JI, University of Alberta, Mulu Gebre, Hui Dai, Liang Li 11:25 (1790-9) Liquid Chromatography/Time-of-Flight/Mass Spectrometry for the Quantitative Analyses of Herbicide Residues in Olive Oil JUAN F GARCIA-REYES, University of Jan, Imma Ferrer, Carmen Ferrer, E Michael Thurman, Amadeo R Fernndez-Alba 11:45 (1790-10) Withdrawn

ORAL SESSION

Session 1780

Liquid Chromatography: Bioanalytical Applications, Chiral Separations and Data Base Management
Thursday Morning, Room S220C Christopher Pohl, Dionex Corporation, Presiding 8:30 (1780-1) HPLC-Pulsed Electrochemical Detection of Aminoglycosidic Antibiotics WILLIAM R LACOURSE, University of Maryland, Baltimore County 8:50 (1780-2) Synthesis and Surface Modification of Monolithic Carbon Columns CHENGDU LIANG, Oak Ridge National laboratory, George Guiochon, Sheng Dai 9:10 (1780-3) Analysis of Sorbate in Protein Formulations ELANGO MINNOOR, Medtronic Minimed, Inc., Sarnath Chattaraj, Poonam Gulati 9:30 (1780-4) Capillary-Channeled Polymer (C-CP) Fibers as Stationary Phases for Rapid Protein Separations DWELLA M NELSON, Clemson University, R Kenneth Marcus 9:50 (1780-5) Screening Method for Chiral Selectors that Does Not Require Covalent Attachment ZHI CHEN, University of Pittsburgh, Yanhong Yang, Hong Zhao, Stephen G Weber, Jingbo Xiao, Peter Wipf 10:10 Recess

ORAL SESSION
Neurochemistry: Amino Acids and Peptides as Neurotransmitters
Thursday Morning, Room S230F Alice Chen, The Pittsburgh Conference, Presiding

Session 1800

10:25 (1800-1) New Technologies and Applications for In Vivo Sampling of Amino Acid Neurotransmitters in the Rat Brain NICHOLAS A CELLAR, University of Michigan, Robert T Kennedy

91

10:45 (1800-2) Detecting D-Amino Acid Containing Neuropeptides in the CNS of Aplysia californica MICHAEL A EWING, University of Illinois at Urbana 11:05 (1800-3) Determination of Neurotransmitters by High Performance Liquid Chromatography with Electrochemical Detection BHAVIK A PATEL, Imperial College, Martin Arundell, Kim H Parker, Mark S Yeoman, Danny O'Hare 11:25 (1800-4) Fast Changes in Amino Acid Neurotransmitters are Correlated with Stress Behaviors: A Microdialysis with Online Capillary Electrophoresis Study JILL VENTON, University of Michigan, Terry E Robinson, Robert T Kennedy 11:45 (1800-5) Extracellular Amino Acids Collected in vivo from Freely Behaving Rats KONGTHONG THONGKHAO-ON, University of Illinois at Chicago, Scott A Shippy

9:10 (1830-3) Direct Monitoring of Dynamic Oligo-Chitosan Uptake by Plant Cells and Determination of Km of P-Glycoprotein in K562 Cells with Single Molecule and Single Cell Fluorescence Imaging System YINFA MA, University of Missouri-Rolla, Hongwei Gai, Xiaoming Zhao, Yulin Wang, Ling Yang, Yuguang Du, Bingcheng Lin 9:30 (1830-4) Long-Range Electrostatic Repulsion of Single Molecules at a Liquid/Solid Interface YAN HE, Iowa State University, HungWing Li, Edward S Yeung 9:50 (1830-5) Analyzing Aqueous Systems Using Gas Discharge Visualization KENNETH S MOMOH, Aveda Corporation, Alex Vainshelboim, Michael T Hayes, John W Chapman 10:10 Recess 10:25 (1830-6) Microminiaturized Immunosensing Platform by Patterning Bacteria into Specific Addresses SALMA RAHMAN, Iowa State University, Robert J Lipert, Marc D Porter 10:45 (1830-7) Hyperspectral Fluorescence Image Analysis: Correction of Spectral Biases in Multivariate Curve Resolution Results DAVID M HAALAND, Sandia National Laboratories, Howland Jones, Jerilyn A Timlin, Michael B Sinclair 11:05 (1830-8) Nonlinear Optical Null Ellipsometric Studies of Chiral Systems RYAN M PLOCINIK, Purdue University, Garth J Simpson 11:25 (1830-9) Application of K-Harmonic Means Clustering to Qualitative Analysis in Infrared Chemical Imaging FREDERICK W KOEHLER, Spectral Dimensions, Inc., Kenneth S Haber, Eunah Lee, Linda H Kidder, E. Neil Lewis 11:45 (1830-10) NIR-NSOM Using Hyperspectral Integrated Computational Imaging ROBERT A LODDER, University of Kentucky, Clay Harris

ORAL SESSION
by Nancy Lewen, Bristol-Myers Squibb Company Thursday Morning, Room S230D Nancy Lewen, Bristol-Myers Squibb Company, Presiding

Session 1810

Pharmaceutical Applications of Atomic Spectroscopy - arranged

8:30 (1810-1) Atomic Spectroscopy in the Pharmaceutical Industry NANCY LEWEN, Bristol-Myers Squibb 8:50 (1810-2) The Process For Bringing New Analytical Technology into the USP EDWARD M COHEN, Consultant, USP 9:10 (1810-3) Pharmaceutical Applications of Atomic Spectroscopy ASSAD KAZEMINY, IAL 9:30 (1810-4) Elemental Analysis for Evaluation of Pharmaceutical Product Authenticity KAREN A WOLNIK, US Food and Drug Administration, Barbara S Barnes 9:50 (1810-5) An Alternative to the USP Heavy Metals Test: A Robust Method for the Rapid Determination of Residual Metals in Active Pharmaceutical Ingredients by Axial ICP-OES Using Dimethylsufoxide Solvent MARK S SAULTER, GlaxoSmithKline 10:10 Recess 10:25 (1810-6) The Use of ICP-OES and ICP-MS for Troubleshooting in the Pharmaceutical Industry MARTHA SCHENKENBERGER, BristolMyers Squibb 10:45 (1810-7) A General ICP-MS Method as an Alternative to Compendial Methods for Heavy Metals Analyses NANCY LEWEN, BristolMyers Squibb 11:05 (1810-8) The Determination of Residual Catalytic Metals in 4Hydroxyphenyl Acetamide: A Comparison of X-ray Fluorescence and ICPMS Techniques GRACE M VANDAL, Pfizer, Inc., Naomi Kirkpatrick, Joshua Denette, Dirk Wissmann, Michael Preigh 11:25 (1810-9) Development of Dimethyl Formamide and Aqueous Solvent System for ICP-AES Analysis of Pharmaceuticals. JEFFREY W WEBER, Pfizer, Inc. 11:45 (1810-10) Applications of Plasma Spectrochemistry in the Pharmaceutical Industry TIMOTHY L SHELBOURN, Eli Lilly and Company, Inc., Robert M Montgomery

ORAL SESSION
arranged by Joachim Oelichmann, Buchi Laboretechnik AG Thursday Morning, Room S230A TBA, Presiding 8:30 Introductory Remarks - John Poling

Session 1840

Tomas B Hirschfeld Award: Near Infrared Spectroscopy -

8:35 Presentation of the 2005 Tomas B Hirschfeld Award for Near Infrared Spectroscopy to Ana Garrido-Varo, University of Cordoba, by John Poling, Buchi Analytical Inc. 8:40 (1840-1) The Role of Near Infrared Spectroscopy to Verify Label Information in Agro-Food Products ANA GARRIDO-VARO, University of Crdoba 9:20 (1840-2) Identification of Glucose and Urea Spectral Signatures in In Vivo Rat Skin Tissue with Near-Infrared Spectroscopy LINGZHI LIU, University of Iowa, Jonathon T Olesberg, Mark A Arnold 9:40 (1840-3) A New Modeling Approach to Performing Raw Material Identification by FT-NIR JEREMY A LINOSKI, ABB, Inc. 10:00 Recess 10:15 (1840-4) Portable and Stable Near Infrared Spectroscopic System for Chemometrics-Based In Vivo Monitoring BABS R SOLLER, University of Massachusetts, Patrick Phillipps, Michael Phllipps, Olusola Soyemi, Michael Parker, Sherry Grobstein, William Perry 10:35 (1840-5) Acousto-Optic Tunable Filter Based Near-Infrared Spectrometer for Organic Vapor Detection JOHN E CARR, Northern Illinois University, Jon W Carnahan 10:55 (1840-6) Evaluation of Infrared Techniques for the Analysis of Anhydrous HF Mixtures VALERIE BOSSOUTROT, Air Liquide, Eric Coffre, Josyane Bruat, Stphane Richard 11:15 (1840-7) The PAT Front End: Streamlining Raw Material Inspection by FT-NIR and Feeding Forward into Manufacturing Processes SCOT ELLIS, Thermo Electron Corporation, Dave Edwards 11:35 (1840-8) Visible NIR-MIR Industrial Strength Spectroscopy: The Static Instant Measure Multiplexing Spectromers (SIMMS). Will It Measure UP? RICHARD A DEVERSE, Plain Sight Systems, Inc., Frank B Geshwind, Andreas C Coppi, Ronald R Coifman, Robert M Hammaker, William G Fateley

ORAL SESSION

Session 1830

Surface Analysis and Microscopic Imaging Techniques: Bioanalytical Applications

Thursday Morning, Room S230E William R Morgan, Consultant, Technical Product Sales, Presiding 8:30 (1830-1) Advanced Biomolecular Microscopy Based on Innovative Mass Spectrometry Techniques: Tagless, Comprehensive, and Adaptable STACY D SHERROD, Texas A&M University, John A McLean, David H Russell 8:50 (1830-2) Immunoassays Utilizing Atomic Force Microscopy as a Readout Method: A Platform for the Detection of Viral Pathogens KAREN M KWARTA, Iowa State University, Jeremy D Driskell, John Neill, Julia Ridpath, Marc D Porter

92

POSTER SESSION

Session 1850

Morning posters will be on display from 9:30 AM to 12:30 PM with authors present from 9:30 AM to 11:30 AM. The posters will be located on the Southeast corner of the Exposition floor (beginning Aisle 2900).

(1860-3 P) Inversion Voltamperometric Determination of Chromium by Coal Pasta Electrode ARTUR M GEVORGYAN, National University of Uzbekistan, Azamat T Artikov, Ziyadulla Normuradov (1860-4 P) Characterization of the Interaction of Poly(3-methylthiophene) with Redox Couples Using Cyclic Voltammetry ANDREA L KELLEY, Xavier University, Brian Angolia, Isam Marawi (1860-5 P) Investigation of the Interaction of Poly(3-methylthiophene) Electrodes with Inorganic Redox Couples ISAM MARAWI, Xavier University, Andrea L Kelley, Brian Angolia (1860-6 P) Electrochemically Induced Derivatization of Poly(2,2bithiophene) and Characterization of Functionalized Polymers GIOVANNI MORI, University of Parma, Marco Giannetto, Alessandra Bello (1860-7 P) Determination of Se(IV) in Natural Water as Piaselenole Using Poly(3,3'-diaminobenzidine) Modified Gold Electrode by Differential Anodic Stripping Voltammetry MOHAMMED REZA NATEGHI, Azad University of Yazd, Hamid Hadjimohammadi (1860-8 P) Estimation of Environmental Contamination by Detection of Circulating Immune Complexes ARUNAS RAMANAVICIUS, Vilnius University, J Acaite, Arunas Ramanavicius (1860-9 P) Non-Invasive Imaging of Ion Channels via Scanning Electrochemical Microscopy JEREMY P WILBURN, Vanderbilt University, David E Cliffel (1860-10 P) Separation of Dopamine and Epinephrine by a Novel Electrophoresis WUMING ZHANG, Wuhan University (1860-11 P) Direct Detection of Nucleic Acid Based on Electrocatalytic Oxidation of Guanine by Ru(bpy)2-Grafted Intercalator NATALIA C TANSIL, Institute of Bioengineering and Nanotechnology, Zhiqiang Gao, Hong Xie, Fang Xie (1860-12 P) Optimization of Bath Composition for the Electrodeposition of Fe-W-B Alloy SHIVA PRASAD, Universidade Federal De Campina Grande, Renato A. C Santana, Ana Regina N Campos, Ambrsio Almeida Neto, Valder D Leite (1860-13 P) Optimization and Control of the Process for Electrodeposition of Ni-Mo-B Amorphous Alloy SHIVA PRASAD, Universidade Federal de Campina Grande, Renato A. C Santana, Ana Regina N Campos, Elisngela S Moura, Valder D Leite (1860-14 P) Direct and Indirect Amperometric Detection of Chlorinated Phenols Separated by Capillary Electrophoresis Using Boron-Doped Diamond Microelectrodes GRACE W MUNA, Michigan State University, Greg M Swain, Veronika Quaiserova (1860-15 P) Use of an Electrochemical/ELSD Combination System for Forced Degradation Studies DARWIN J ASA, Esa Inc., Ian N Acworth, John Waraska, Paul Gamache (1860-16 P) Use of an Electrochemical/ELSD Combination System for Forced Degradation Studies DARWIN J ASA, Esa Inc., Ian N Acworth, John Waraska, Paul Gamache (1860-17 P) Photoelectrochemical Generation of Hydrogen from Water by a Carbon Modified n-TiO2 Thin Film Electrode YASSER A SHABAN, Duquesne University, Shahed U. M Khan (1860-18 P) Direct Modification of Reticulated Vitreous Carbon Electrodes for Use in Metal Ion Complexation ROSS STRONG, Butler University, Michael J Samide, Brad W Fravel, Allison R Knauff

Developments in Materials Characterization

Thursday Morning (1850-1 P) Ni and Ti-base Alloy Analysis by High Resolution ICP-OES GEOFF TYLER, Jobin Yvon SAS, Agnes Cosner, Sebastien Velasquez, Nathalie LeCorre (1850-2 P) Vacuum Applications of Silicon-Based Coatings on Stainless Steel GARY A BARONE, Restek Corporation, David A Smith, Bruce Kendall (1850-3 P) Characterization of Coal by Pyrolysis-GC/MS INGER ERICSSON, Pyrol AB, Helena E Jonsson (1850-4 P) A Comparative Fourier Transform Infrared Spectroscopic Characterization of Aluminum Surfaces Using Various FTIR Accessories LORI A SCHNEIDER, Alcoa Technical Center, John P Auses (1850-5 P) A Study of the Tantalum-Resorcinol Complex for the Spectroscopic Analysis of Tantalum CHARLES M EARNEST, Berry College, Madoka Hasegawa, Aitana Vargas (1850-6 P) New Single Reflection ATR for Depth Profiling Studies KENNETH D KEMPFERT, PIKE Technologies, Gabor Kemeny (1850-7 P) Crystalline Carbonate Assemblies Matrix-Mediated at AirPolyaminosiloxane Interface JOO-WOON LEE, University of Texas at Austin, J M White (1850-8 P) Photosynthetic Production of Biologically Active NADH on Fluorescein-DNA Monolayer YITAO LONG, University of Saskatchewan, Todd C Sutherland, Kraatz Heinz-Bernhard, Jeremy S. Lee (1850-9 P) Metal Carbide Catalyzed Decomposition of Ester Based Lubricants DAVID W JOHNSON, University of Dayton, Eric Hils, Carolyn Iacullo, David C Huffnagle, Costandy S Saba, Nelson Forster (1850-10 P) Revolutionary Sine-wave Vibro Viscometer for Low Viscosity Measurements TERU MORIYA, A&D Engineering, Inc. (1850-11 P) X-ray Characterization of Nanometer a-Si/Sc2O3 Interface SANDEEP KOHLI, Colorado State University, Patrick R McCurdy, Christopher D Rithner, Peter K Dorhout, Ann M Dummer, Fernando Brizuela , Carmen C Menoni (1850-12 P) X-ray Tomography Applied to Plaster Characterization GIUSEPPE BONIFAZI, Universit di Roma La Sapienza (1850-13 P) Pigments Analysis of Mural Paintings by a Portable XRF YASUHIRO HAYAKAWA, National Research Institute for Cultural Property (1850-14 P) Determination of the Viscoelastic Constants of Continuous Carbon Fiber/Polyamide 6/6 Composite by Free Vibration Method EDSON C BOTELHO, Centro Tcnico Aeroespacial, Michelle L Costa, Rezende C Mirabel, Luiz C Pardini, Carlos I Braga (1850-15 P) Monitoring of Curing of Carbon Fiber/Epoxy F155 Prepreg by Rheologcal and Thermal Analysis MICHELLE L COSTA, Centro Tcnico Aeroespacial, Edson C Botelho, Andreza Moura, Carlos I Braga, Mirabel C Rezende (1850-16 P) GD TOF-MS SERGEY V POTAPOV, Lumex Ltd., Alexander A Ganeev, Maxim N Voronov, Anatoly I Drobushev, Michail A Kuzmenkov, Evgeny K Izrailov, Maxim N Sliadnev (1850-17 P) The Study of Vitreous Carbons Resulting by Foundry Synthetic Resins Pyrogenation PARASCHIV MARIA, Metallurgical Research Institute (1850-18 P) XPS Studies of Chemical States on Porous Silicon Carbide Surface upon Annealing Conditions KI-HWAN LEE, Kongju National University, Ki-Seok Jeon, Seung-Koo Lee, Hae-Kwon Jeon, Tae-Ho Lee, Chang-Shik Choi

POSTER SESSION
High-Throughput Chemical Analysis
Thursday Morning

Session 1870

(1870-1 P) Ultra High Throughput Microwave Assisted Solvent Extraction DAVID BARCLAY, CEM Corporation, Bob Revesz (1870-2 P) High Throughput Microwave Digestion of Fertilizer Samples ELAINE HASTY, CEM Corporation, David Barclay, Debra Kiebach (1870-3 P) High Throughput Chiral Separations Using Multiplexed Capillary Electrophoresis with Absorbance Detection JEREMY KENSETH, CombiSep, Inc., Andrea Bastin (1870-4 P) Quantitation Study for High Throughput Drug Purity and Degradation by Multiplexed Micellular Electrokinetic Chromatography with UV Absorption Detection HO-MING PANG, CombiSep, Inc., Yan He, Jeremy Kenseth (1870-5 P) Fast GC Analysis of Flammable and Ignitable Liquids KIRK E LOKITS, Middle Tennessee State University, Gale J Clark

POSTER SESSION
Electrochemistry
Thursday Morning

Session 1860

(1860-1 P) Electrochemistry on a High-Density Gold Nanoparticle-Modified ITO Surface Prepared Using a 'Touch' Seed-Mediated Growth Approach AKRAJAS ALI UMAR, Kyoto Institute of Technology, Munetaka Oyama (1860-2 P) Electron Transfer of Aquated Iron Ions and Dopamine at Carbon Surfaces Modified with Aromatic Carboxylic Acid Groups KRISTIN K CLINE, Wittenberg University, Jerilyn R Vrabel, Heather A Griffith

93

(1870-6 P) Direct Determination of Trace Elements in Organic Solvent Soluble Alq3(tris-8-hydroxyquinoline Aluminum) by GF-AAS CHOI YOUNG RAK, Cheil Industries, Inc. (1870-7 P) How to Do Sub-Minute Gradient Elution HPLC Using Small Particles and Short Columns ADAM P SCHELLINGER, University of Minnesota (1870-8 P) Monolithic Nanocolumns for Rapid Protein Separations IRINA DRAGAN, LC Packings, Remco Swart (1870-9 P) Column Design for High Throughput GPC GREG SAUNDERS, Polymer Laboratories Ltd, John McConville (1870-10 P) Preparative LC-MS at Neutral pH: Comparison of Volatile Mobile Phase Modifiers VIVEK JOSHI, ArQule, Inc., Pam McCarthy, Joe Twomey, Marc Towle, Wolfgang Goetzinger (1870-11 P) Interactions of Image Sticking and Anion Impurities in Polyimide Alignment Film for Thin Film Transitor-Liquid Crystal Display by ICP-MS Coupling Mixed Plasma and Electrical Properties Measurements YOUNSUNG KIM, Cheil Industries, Inc. (1870-12 P) Applications of a Flash GC with Infrared Heating ANDREAS WALTE, Airsense Analytics, Wolf Muenchmeyer (1870-13 P) Developments in Evaporative Light Scattering Detection for High Throughput HPLC SAM AZLEIN, SofTA Corporation (1870-14 P) High Speed GPC Comparison of Polydivinylbenzene vs. Fluorinated Polydivinylbenzene HOWARD JORDI, Jordi FLP (1870-15 P) Guidelines for Optimizing Reversed Phase HPLC Separations for High Throughput Applications ROBERT T MOODY, MAC-MOD Analytical, Inc., Carl L Zimmerman (1870-16 P) HPLC Instruments for the Use of Small Particles in HPLC: How Much Optimization is Needed? STEFAN LAMOTTE, Bischoff Chromatography, Rainer Brindle, Gerald Reindl, Klaus D Bischoff (1870-17 P) On-line Metal Preconcentration Using a Modified Chloromethylated Resin VALFREDO A LEMOS, UESB, Sergio L Ferreira, Patricia X Baliza, Rennan G Araujo, Juracir S Santos (1870-18 P) A Rapid Automated Approach to the Generation and Visualization of In-vitro Metabolism, Solubility and Log D Using LC/MS/MS and UPLC/MS/MS UPLC/MS/MS WARREN POTTS, Waters Corporation, Robert Plumb, Kate Yu (1870-19 P) A Simple and Robust LC/MS/MS Configuration for HighThroughput ADME Screening TAO WANG, Pfizer Global Research and Development, Kelly Jenkins (1870-20 P) Software-Assisted Selection of Generic Separation Methods in the High-Throughput Laboratory MICHAEL MCBRIEN, Advanced Chemistry Development, Inc., Mark Woodruff, Charlotte Blythe, Rhiannon Jones, Margaret Antler (1870-21 P) Scaled-Up Synthesis in a Large Volume Microwave Reactor System KENNETH J BOROWSKI, Milestone Inc.

(1880-7 P) An Accurate Method for the Quantitation of Cyanide in BloodBased Standards KAREN MURPHY, National Institute of Standards and Technology, Michele M Schantz, Greg C Turk, Therese A Butler, Bruce A Benner, Laura J Wood, Robert J Kobelski, Rachael E Trimpert, Phil Holt, Elizabeth Hamelin, William McShane (1880-8 P) Raman Spectroscopic Analysis of Illicit Drug Mixtures in Fingerprints, Paper Currency, and Plastic Bags KATHRYN Y NOONAN, College of the Holy Cross, Kimberley A Frederick (1880-9 P) Breath Analysis Using Photoionization Mass Spectrometry HARALD OSER, SRI International, Steven Young, Michael J Coggiola (1880-10 P) Automated Cold-on-Column Injection and the Analysis of Explosive Residues by Negative Chemical Ionization GC/MS TRISA C ROBARGE, Thermo Electron Corporation, Eric Phillips, Jessie Butler, Jason S Cole, Meredith Conoley (1880-11 P) Improving Electronic Nose Technology for Applications in Detecting JOHN F SCHNEIDER, Argonne National Laboratory, Carrie M Thomas (1880-12 P) Detection of Canis Familiaris Signature Odor Chemicals in Human Remains Using Derivitization/SPME/GC/MS SAMANTHA TOLLIVER, Florida International University, Kenneth G Furton (1880-13 P) Fluorescent Nanometer Microsphere Labels for Antibodies: Detection in Suspension Arrays LILI WANG, National Institute of Standards and Technology, Kenneth D Cole, Adolfas K Gaigalas, Yu-Zhong Zhang (1880-14 P) Nitric Oxide Detection by Chemiluminescent Reaction with Ozone in a Parabolic Chamber RONALD J WHIDDON, University of Florida, James D Winefordner, Nicolo Omenetto, Benjamin W Smith (1880-15 P) Sampling Alternatives for FTIR Microscopy of Fingerprint Deposits JOHN A MONTI, Shimadzu Instruments, Shannon Richard, Timothy Alt (1880-16 P) Solid Phase Extraction Methodologies for Enhancing Fourier Transform Infrared Attenuated Total Reflection Measurements MARK L NORMAN, Smiths Detection, David V Dewey, David W Schiering (1880-17 P) Development and Characterization of a Mobile Disposable Air Sampler for Capturing Airborne Biological and Chemical Agents WALTER L ZIELINSKI, Signature Science, LLC, Brian J Schimmoller (1880-18 P) Applications of MC-ICP-MS: Determining Individuals Life Histories Using Pb Isotope Analysis in Forensic Anthropology NATHAN W BOWER, Colorado College, Sarah A McCants, Michael E Ketterer, Michael Hoffman (1880-19 P) Fingerprint Identification of Cocaine Adulterants by HPLC and GC KRISTI J SELLERS, Restek Corporation, Rick Morehead (1880-20 P) Withdrawn (1880-21 P) Fate of the Chemical Warfare Agent VX in Asphalt: A Novel Approach for the Quantitation of VX in Organic Surfaces SIGALIT GURA, Israel Institute for Biological Research (IIBR), Miriam Hershkovitz, Nitzan Tzanani, Shai Dagan (1880-22 P) Supercritical Fluid Extraction of Organic Compounds Present in Adsorbents Used in Human Scent Evidence Collection PAOLA A PRADA, Florida International University, Allison M Curran, Kenneth G Furton (1880-23 P) A Micromachined Preconcentrator for Trace Detection of Explosives STUART K ROSS, Dstl Porton Down, Andrew McGill, Michael Martin, Jennifer L Stepnowski, Stanley V Stepnowski, Eric J Houser, Kevin Walsh, Mark Crain, Viet Nguyen (1880-24 P) Development of a Quantitative, Retention Time Locked Thermal Desorption GCMS Method with Automated Compound Spectral Deconvolution (AMDIS), and Nist Confirmation for Target Chemical Agent Analysis in Air GARETH M ROBERTS, Markes International Ltd (1880-25 P) Thermal Effects on the Detection of a Chemical Warfare Agent Simulant in Various Aerosol Matrices: Ion Mobility Time-of-Flight Mass Spectrometry IM(tof)MS WES E STEINER, Washington State University, Steve J Klopsch, William A English, Herbert H Hill

POSTER SESSION
Homeland Security and Forensics
Thursday Morning

Session 1880

(1880-1 P) Field Sampling and Analysis Methods for Arson Investigation LAURA CONNER, Florida International University, Kenneth G Furton (1880-2 P) Determination of the Volatile Organic Compounds Present in a Human Scent Profile through SPME-GC/MS ALLISON M CURRAN, Florida International University, Kenneth G Furton, Adee A Schoon (1880-3 P) Gas Chromatographic Analysis of Explosives and Other Components in Single Base Propellants VIVEK R DHOLE, Chemito Technologies Pvt. Ltd., Balasubramanian Sitharaman, Inderjit Kaur (1880-4 P) Fluorescence Identification of Substances of Abuse DANIEL L HEGLUND, South Dakota School of Mines and Technology, Richard Wold, Kristina M Grinnell (1880-5 P) Structural Characterizations of Protein Antigens for the NextGenerationVaccines Against Anthrax and Plague BRADFORD S POWELL, USAMRIID (1880-6 P) On-site Detection of Chemical Warfare Agents by Monitoring Tape Method MIEKO KANAMORI-KATAOKA, National Research Institute of Police Science, Yasuhiro Sano, Shigeharu Yamashiro, Kouichiro Tsuge, Isaac Ohsawa, Yasuo Seto, Nobuo Nakano, Tetsuya Kawabe, Satomi Abe, Gaku Ishiguro

POSTER SESSION
Nanotechnology
Thursday Morning

Session 1890

(1890-1 P) Chemistry of Small Silver Nanoparticles: What Is so Different? MATTHEW R BRANHAM, University of North Carolina at Chapel Hill, Royce W Murray (1890-2 P) Stabilizing Lipid Membrane Sensing Platforms with a Cytoskeletal Network DANIEL L BURDEN, Wheaton College, Wayland Cheng, Daniel Kim

94

(1890-3 P) Analytical Size Exclusion Chromatography of Gold Nanoclusters KUNIKO IGARASHI, Shodex, Showa Denko K.K., Yoshiji Okada, Kazunori Iwata, Kuniaki Shimbo, Yosuke Iwata, Yoshihiro Hayakawa, Keiko Yamabe, Katsuaki Konishi (1890-4 P) Potential Switchable Smart Electrode Surface DOROTA KOWALSKA, Miami University, Wolfgang U Spendel, Gilbert E Pacey (1890-5 P) Capillary Electrophoresis Lithography KRIM L MORGAN, Vanderbilt University (1890-6 P) Detection of Gaseous Ozone Utilizing Gold Nano Islands SEAN PUCKETT, Miami University, Justin A Heuser, Gilbert E Pacey (1890-7 P) Nonaqueous Capillary Electrophoretic Separation and Detection of Aromatic Organic Nanowires MARTIN PUMERA, Universitat Autonoma De Barcelona, Jindrich (1890-8 P) Chemical Modifications of Silica Core-Shell Nanocapsules: Biomedical and Therapeutical Implications RANDOLPH S DURAN, University of Florida, Aleksa V Jovanovic (1890-9 P) Mesoporous Thin Film Electrocatalytic Polyoxometalate Electrode For Sensor and Catalysis Applications WOLFGANG U SPENDEL, Miami University, Sean Puckett, James A Cox, Gilbert E Pacey (1890-10 P) Anomalously Surface-Enhanced Infrared Spectra of Manganese (III) Tetraphenylporphine Chloride Physisorbed on Gold Island Films JITRAPORN VONGSVIVUT, Chulalongkorn University, Tamitake Itoh, Akifumi Ikehata, Sanong Ekgasit, Yukihiro Ozaki (1890-11 P) Study of Analysis of Doped Hydrogenated Nano Crystalling Silicon Film by Glow Discharge Spectrometry YI ZHANG, Baoshan Iron & Steel Co., Ltd., Yingying Chen (1890-12 P) Nanoparticles in Solutions of Cellulose Acetates HAMDAM I AKBAROV, National University of Uzbekistan (1890-13 P) Terahertz (THz) Spectroscopic Determination of Water Bonding In Zeolites JUSTIN A HEUSER, Miami University, Wolfgang U Spendel, Gilbert E Pacey (1890-14 P) Direct Electrochemistry of Methanol Dehydrogenase at Carbon Nanotube Modified Electrodes HIROYASU TACHIKAWA, Jackson State University, Heyou Han (1890-15 P) Temperature Dependence of the Rate Constants for the Deexcitation of Ne(3P1) and Ne(3P2) by O2, CO2 and CH4 DEBA B KHADKA, Tribuvan University, N Kouchi, Y Hatano (1890-16 P) Terahertz Spectroscopy of Gases ANITA R TAULBEE, Miami University, Justin A Heuser, Gilbert E Pacey (1890-17 P) Nanosensor for Sensitive Determination of Inorganic Selenium JULIA XIAOJUN ZHAO, University of North Dakota, Song Liang, Yanfu Huan, David T Pierce (1890-18 P) Rate and Selectivity of Transport in Silane-Modified Nanopore Alumina Membranes DAMIAN J ODOM, University of Florida (1890-19 P) Functionalized Silica Tubes as Biochemical Delivery Vehicles FATIH BUYUKSERIN, University of Florida, Punit Kohli, Myungchan Kang, Miguel O Mota, Charles R Martin (1890-20 P) Control of the Morphologies of AuAg Nanorods Prepared from Gold Seeds by Varying Glycine Concentration and pH YU-FEN HUANG, Tiawan University

(1900-6 P) Development of a Novel Reaction Calorimeter MAMORU NOMURA, Fukui University, Kazumi Fujita, Syuzaemon Sato, Norihiro Yamauchi (1900-7 P) Investigation of the Environmental Fate of Toxic Chemicals by Measurement of Vapor Concentrations and Weight Loss in Laboratory Wind Tunnels WENDEL SHUELY, GEO-Centers, Inc. (1900-8 P) Development of Evolved Gas Analysis-Mass Spectrometry (EGA-MS) Using Skimmer Interface and Ion Attachment Mass Spectrometry (IAMS) TAKAHISA TSUGOSHI, AIST, Takaaki Nagaoka, Nanaka Ito, Sachiko Nakagi, Koji Watari

POSTER SESSION
Process Chemistry
Thursday Morning

Session 1910

(1910-1 P) Comparison of Different Analytical Methods for Carbonate Impurity Detection in Pharmaceutical Intermediates SHAOHUA (SARAH) CHEN, Merck & Co., Inc. (1910-2 P) Integration of TOC Analyzers in Support of 40CFR112 Spill Prevention, Control and Countermeasures (SPCC) GARY L ERICKSON, O. I. Analytical (1910-3 P) An Easy and Efficient Method for the Automatic Analysis of Trace BTEX in Beverage Grade Carbon Dioxide ROBERT M HILLARD, GOW-MAC Instrument Company, Willie T Robertson, Lee M Longmore (1910-4 P) Vibrational Spectra and Conformational Inhomogeneity of Phosphasocompounds SH. ISMAILOV, Samarkand State University, I. Boldeskul (1910-5 P) A Packed Column Realized on a 1 cm2 Sized Silicon Glass Chip for Permanent Gas Separation UWE LEHMANN, SLS Micro Technology GmbH, Martin Sussiek, Joerg Ing. Mueller (1910-6 P) Targeted Spectral Range Near-Infrared Analysis LARRY MCDERMOTT, Axsun Technologies, Richard A Crocombe, Matthew Smith (1910-7 P) Optical Emission Spectrometer Studies on High Cr Cast Iron TAO ZHAO, Shanghai Baoshan Iron & Steel Co., Ltd. (1910-8 P) Residual Solvent Drying Endpoint Detection Using Process Mass Spectrometry GREG F GLASIER, Wyeth Research, Warren Chew (1910-9 P) Analytical Scheme for Evaluation of Hydrogen Permeation in Metals at High Temperatures and Pressures KURT S ROTHENBERGER, U.S. Department of Energy NETL, Bret H Howard, Anthony V Cugini, Michael V Ciocco, Bryan D Morreale, William J Graham

POSTER SESSION
Sensors: Bioanalytical Applications
Thursday Morning

Session 1920

(1920-1 P) Development of Palm-Sized SPR Meter for Multi-Measurement HEMMI AKIHIDE, Mebius Advanced Technology Ltd., Harada Yuuki, Nakajima Hizuru, Asano Yasukazu, Nakagama Tatsuro, Uchiyama Katsumi, Kaneki Noriaki, Shimada Koji, Eguchi Tetsuya, Imato Toshihiko, Nobuaki Soh (1920-2 P) High Throughput DOX Biosensor System for Monitoring Cells and Bacteria JASON E KARASINSKI, State University of New York at Binghamton, Silvana Andreescu, Omowunmi A Sadik (1920-3 P) Amperometric Sensing of Biological Polyions at Polarized Liquid/Liquid Interfaces YI YUAN, University of Pittsburgh, Lei Wang, Shigeru Amemiya (1920-4 P) Novel Fluorescent Microsphere Optical Sensors for Ions Based on Doped Silica Gel Particles CHAO XU, Auburn University, Katarzyna Wygladacz, Yu Qin, Eric Bakker (1920-5 P) A Miniature Fan-Based Biocollector for Bioagent Detection JENNIFER L STEPNOWSKI, Nova Research, Inc (Contractor at US NRL), Robert A McGill, Stanley V Stepnowski, Viet Nguyen, Derrick J Thiel, Evgueni A Sokolovski, Hylton G McWhinney (1920-6 P) The Behavior of Acrylodan-Labeled Human Serum Albumin (HSA-Ac) Sequestered within a Series of Sol-Gel-Derived Xerogels ZUNYU TAO, State University of New York at Buffalo, Rachel M Bukowski, Elizabeth C Tehan, Ying Tang, Frank V Bright (1920-7 P) Creating a Chemically Diverse Sensor Platform Based on Xerogels ELIZABETH C TEHAN, State University of New York at Buffalo, Rachel M Bukowski, Gyeonghwan Kim, Venu Govindaraju, Frank V Bright

POSTER SESSION
Physical Measurement
Thursday Morning

Session 1900

(1900-1 P) Measurement of Electrical Resistivity of Ceramic Materials at High Temperature GUILLAUME BES, Ecole Des Mines, Jean Paul VIiricelle, Christophe Pijolat (1900-2 P) Analysis of Food Colloids Using High-Resolution Ultrasonic Spectroscopy: New Capabilities CATHERINE DWYER, Ultrasonic Scientific Ltd., Breda O'Driscoll, Evgeny Kudryashov, Lauren Lehman, Vitaly Buckin (1900-3 P) New Applications of High-Resolution Ultrasonic Spectroscopy for Analysis of Molecular Process In Pharmaceutical Research and Industry CORMAC SMYTH, Ultrasonic Scientific Ltd., Kudryashov Evgeny , O'Driscoll Breda, Rogueda Philippe, Lawrence Jayne, Hickey Sinead (1900-4 P) A Study of the Crosslinking Reaction of Polymeric Systems Using Rheometry RUNHUI HUANG, Brewer Science, Inc. (1900-5 P) Effect of Various Instrumental Parameters on Material Properties Studied Using TGA, DSC and Rheometer KEVIN EDWARDS, Brewer Science, Inc., Bharath Chandra

95

(1920-8 P) Carbon Paste Biosensors for Clinical Analysis DAVID J WEISS, University of Colorado at Colorado Springs, Megan K Dorris, Laura Peterson (1920-9 P) Electrochemical Biosensor Based on Tyrosinase-Conjugated Polysacchride Film: Selective Detection of Nanomolar Neurotransmitters Metabolite of 3,4-Dihydroxyphenylacetic Acid (DOPAC) AIHUA LIU, National Institute of Advanced Industrial Science and Technology (AIST), Haoshen Zhou (1920-10 P) Nanosensors for the Detection of Intracellular Reactive Oxygen Species VICTORIA J HAMMOND, The University of Hull, Gillian M Greenway, Paul Watts, Jonathan Aylott (1920-11 P) Application of Surface Plasmon Resonance Biosensor to Selection of Humanized-GPX scFv by Combination of Phage Displayed Antibody Library with Chemical Modification YING MU, Jilin University, Qinhan Jin, Fendi Wang (1920-12 P) Use of Epoxy Resin to Enhance Durability of Polyurethane Membrane of Implantable Glucose Biosensors BAZHANG YU, University of South Florida, Yvonne Moussy, Francis Moussy (1920-13 P) A Low-Cost Reagentless Multi-Analyte Metabolic Monitor LEAH TOLOSA, University of Maryland, Baltimore County, Amelita Bartolome, Yordan Kostov, Govind Rao (1920-14 P) Withdrawn (1920-15 P) Carbon Nanotube and Graphite Composites for (Bio)Electrochemical Sensing MERKOI ARBEN, GSB, UAB, Alegret Salvador, Pumera Martin (1920-16 P) Hand-held Electrochemical Biosensors for Detection and Quantification of Marine Microorganisms MICHAEL J LAGIER, University of Miami/CIMAS, Jack W Fell, Kelly D Goodwin

SYMPOSIUM
Auses, Alcoa Technical Center Thursday Afternoon, Room S210A John P Auses, Alcoa Technical Center, Presiding 1:30 Introductory Remarks John P Auses

Session 290

Pittsburgh Conference Achievement Award - arranged by John P

1:35 Presentation of the 2005 Pittsburgh Conference Achievement Award to Boris Mizaikoff, Georgia Tech University, by John P Auses, The Pittsburgh Conference 1:40 (290-1) From Chemical Sensors to Multifunctional Analytical Platforms BORIS MIZAIKOFF, Georgia Institute of Technology, Christine Kranz 2:15 (290-2) BioChemical Sensor on a Chip Integrated Nano and Micro Systems NAN M JOKERST, Duke University 2:50 3:25 (290-3) TBA Recess

3:40 (290-4) Analytics/Sensing at Cell Surfaces DOUGLAS C EATON, Emory University School of Medicine, Kranz Cristine, Boris Mizaikoff, Angelika Kueng 4:15 (290-5) Optical Gas Sensing Based on Quartz Enhanced Photoacoustic Spectroscopy: Fundamentals and Applications ANATOLIY A KOSTEREV, Rice University, Frank K Tittel

SYMPOSIUM
Brown, University of Rhode Island Thursday Afternoon, Room S230D Chris W Brown, University of Rhode Island, Presiding 1:30 Introductory Remarks - Chris W Brown

Session 1950

Analysis of Polymorphic Pharmaceuticals - arranged by Chris W

POSTER SESSION
Sensors: New Developments and Applications
Thursday Morning

Session 1930

(1930-1 P) A Direct and Rapid Detection Scheme at an Electrochemical Immunosensor MOHAMMAD AKRAM, Macquarie University, Danny K Wong, Margaret C Stuart (1930-2 P) Liquid Phase Biocide Monitoring with the Electronic Nose JOACHIM GOSCHNICK, Forschungszentrum Karlsruhe GmbH, Thomas Walter, Daniel Haeringer (1930-3 P) High-Sensitivity Detection of Salmonella spp. with an Optical Grating Coupler Immunosensor NAMSOO KIM, Korea Food Research Institute, Kyung-rim Park, In-Seon Park, Dong-Kyung Kim, Woo-Yeon Kim (1930-4 P) Cyclodextrin Modified Infrared Chemical Sensor for Determination of the Chirality of Aromatic Acids CHUNG-JAY LEE, National Chung-Hsing University, Jyisy Yang (1930-5 P) Microdialysis Sampling Probes as Glucose Sensor Mimics for Measurement of Glucose Uptake Variations XIAODUN MOU, Rensselaer Polytechnic Institute, Julie Stenken (1930-6 P) Development of a Cholinesterase-Based Inhibition Sensor for Pesticide Detection IN-SEON PARK, Korea Food Research Institute, DongKyung Kim, Kyung-rim Park, Namsoo Kim (1930-7 P) A Strategic Approach to Develop Ideal Sensor Platforms YING TANG, State University of New York at Buffalo, Elizabeth C Tehan, Zunyu Tao, Frank V Bright (1930-8 P) Constructing Libraries of Sol-Gel-Derived Xerogels for Chemical Sensing WILLIAM G HOLTHOFF, University at Buffalo, Elizabeth C Tehan, Rachel M Bukowski, Zunyu Tao, Frank V Bright (1930-9 P) New Gas Sensor Arrays for Detection of Critical Situations Such as Hazardous Solvents or Smoldering Fires in Passenger Cabins ANDREAS WALTE, Airsense Analytics, Wolf Muenchmeyer (1930-10 P) Subminiature Photoionization VOC Sensor BORIS N DOLGOV, Baseline-MOCON (1930-11 P) Using of Hydride Technique in Sensors SHAHISTA A ISHNIYAZOVA, Samarkand Agricultural Institute, Abdumalik Y Khudayberdiev, Shahista A Ishniyazova, Shahista A Ishniyazova (1930-12 P) Total Determination of Microamounts of Phenol and Formaldehyde in the Air Using a Matrix of Modified Piezosensors YAKOV I KORENMAN, Voronezh (Russia) Technological Academy, Tatyana A Kuchmenko, Julia E Silina, Katrin Y Strigunova, Denis A Kuodinov

1:35 (1950-1) Polymorphs and Patents: A Chemist's Point of View JOEL BERNSTEIN, Ben-Gurion University of the Negev 2:10 (1950-2) Forensic Polymorphs and Pseudo Polymorphs: Mysticism, True Lies, and the Expert Witness STEPHEN B JUDLOWE, Morgan Lewis & Bockius, Janet B Linn 2:45 3:20 (1950-3) TBA Recess

3:35 (1950-4) Determinations in Mixtures of Polymorphs Using Infrared Spectroscopy THOMAS M NIEMCZYK, University of New Mexico, Yanga K Dijiba 4:10 (1950-5) Good Data/Bad Data for Polymorphic Pharmaceuticals: Can the Courts Be Fooled? CHRIS W BROWN, University of Rhode Island

SYMPOSIUM
arranged by Nicholas Winograd, Penn State University Thursday Afternoon, Room S230E Nicholas Winograd, Penn State University, Presiding 1:30

Session 1960

Chemical Imaging of Biomaterials Surfaces and Interfaces -

Introductory Remarks - Nicholas Winograd

1:35 (1960-1) Chemical Imaging of Biomaterial Surfaces and Interfaces BIRGIT HAGENHOFF, TASCON GmbH 2:10 (1960-2) Enzymatic SPR Imaging Methods for Protein and DNA Microarrays ROBERT M CORN, University of California at Irvine 2:45 (1960-3) Physical Models of Membrane-Cytoskeleton and Membrane-Surface Interactions PAUL S WEISS, The Pennsylvania State University, Anne Milasincic Andrews, Anne Counterman, Susan Gillmore, Julia Heetderks 3:20 Recess 3:35 (1960-4) Imaging Biological and Organic Surfaces with Xrays: PEEM and XPS Studies DAVID G CASTNER, University of Washington 4:10 (1960-5) Prospects for 3-Dimensional Chemical Imaging of Single Biological Cells with Cluster SIMS NICK WINOGRAD, Penn State University

96

SYMPOSIUM

Session 1970

EPA Waste Water and Superfund Environmental Methods Updates - arranged by William A Telliard, U.S. Environmental Protection
Agency Thursday Afternoon, Room S210C William A Telliard, U.S. Environmental Protection Agency, Presiding 1:30 Introductory Remarks - William A Telliard

3:35 (1990-4) High Resolution Mass Spectrometers Are the Only Sure Route to Spectral Interference-Free ICP-MS NORBERT JAKUBOWSKI, Institute for Analytical Sciences 4:10 (1990-5) Get Real! Quadrupole Filters and Scanned Sector Instruments are Obsolete GARY M HIEFTJE, Indiana University

ORAL SESSION
Bioanalytical Applications of LC-MS
Thursday Afternoon, Room S220C Bryan C Castle, Eli Lilly & Company, Presiding

Session 2000

1:35 (1970-1) Modernization of EPAs Superfund Contract Laboratory Program (CLP) Through Method Customization, Electronic Data Delivery, and Client Support TERRY SMITH, U.S. Environmental Protection Agency 2:10 (1970-2) New EPA OSW SW 846 Methods for Mercury Speciation and Metal Cyanide Complexes SHEN-YI YANG, U.S. Environmental Protection Agency 2:45 (1970-3) EPA's Final Notice on Detection and Quantitation WILLIAM TELLIARD, U.S. Environmental Protection Agency 3:20 Recess 3:35 (1970-4) Evaluation and Examination of Thermal/dual-Optical Carbon Analysis Method for Air Pollution Monitoring in Canada LUYI DING, Environment Canada 4:10 (1970-5) Multiple Single-laboratory Validations of EPA Method 1614: Polybrominated Diphenyl Ethers by HRGC/HRMS DALE RUSHNECK, Interface, Inc.

3:25 (2000-1) Identification of Bacteria Using Automated Biological Sample Processing-Liquid Chromatography-Electrospray Ionization Mass Spectrometry System RABIH E JABBOUR, Geo-Centers, Inc., Jacek P Dworzanski, Samir V Deshpande, A. Peter Snyder, Charles H Wick 3:45 (2000-2) Stability Study of a PEGylated Drug Delivery Agent Using Liquid Chromatography-Mass Spectrometry (LC-MS)Stability Study of a PEGylated Drug Delivery Agent Using Liquid Chromatography-Mass Spectrometry (LC-MS) JOSEPH FOTSO, Emisphere Technologies, Inc., Pingwah Tang, Karen Brazzillo, Puchun Liu 4:05 (2000-3) Comparing the In-Vivo to In-Vitro Sustained Release Pharmacokinetics for a Novel Class of Drug Releasing Bioerodible Polymers MICHAEL NEU, Polymerix Corporation, Bryan Pudil, John Paul Gutierrez, Steve Goodrich, Suseela Kanamathareddy, Michael B Hicks 4:25 (2000-4) Measurement of Selenium-Containing Proteins of Clinical Interest by HPLC-UV-Collision Cell ICP-MS MARIANA ARCEOSUNA, National Institute of Standards and Technology, David M Bunk, Stephen E Long, Peter C Uden 4:45 (2000-5) Monitoring a Multiplex Protease Activity Assay by Means of Mass Spectrometry UWE KARST, University of Twente, Andre Liesener

SYMPOSIUM
arranged by Richard A Yost, University of Florida Thursday Afternoon, Room S230F Richard A Yost, University of Florida, Presiding 1:30 Introductory Remarks - Richard A Yost

Session 1980

Ion Mobility: Innovations in Instrumentation and Applications -

ORAL SESSION
Bioanalytical Electrochemistry
Thursday Afternoon, Room S220G Rose Ann Clark, Saint Francis University, Presiding

Session 2010

1:35 (1980-1) Electrospray Ion Mobility Spectrometry: Past, Present, and Future HERBERT H HILL, Washington State University, Steve J Klopsch, Feng Hong, Brian H Clowers, Wes E Steiner 2:10 (1980-2) Improvements in Differential Mobility Spectrometry and Applications for Determining Volatile Organic Compounds in Air and Other Vapor Samples GARY A EICEMAN, New Mexico State University 2:45 (1980-3) Innovations in High-Field Ion Mobility (FAIMS): Instrumentation and Applications RICHARD A YOST, University of Florida 3:20 Recess 3:35 (1980-4) The Use of Ion Mobility Mass Spectrometry (IMS-MS) Approaches to Measure Protein Conformation: Development of a Diagnostic Probe JAMES SCRIVENS, University of Warwick, K. Thalassinos, J. P Williams, S. Slade, K. Giles, Robert H Bateman, Michael T Bowers 4:10 (1980-5) Intelligent Biomolecular Imaging Based on Novel MALDI Methodology Coupled with Ultrafast Two-Dimensional Separations by Ion Mobility-Mass Spectrometry DAVID H RUSSELL, Texas A&M University

1:30 (2010-1) Effect of Ionic Atmosphere on Immobilized Cytochrome c Electrochemistry ROSE A CLARK, Saint Francis University, Jelena Petrovic, Hongjun Yue, David H Waldeck 1:50 (2010-2) Quantitative Analysis of Exocytotic Events Using Single Cell Amperometry CHRISTY L HAYNES, University of North Carolina at Chapel Hill, R. Mark Wightman 2:10 (2010-3) Fast Scan Cyclic Voltammetry Used to Investigate Dose Effects of Cocaine BRIDGET L MAHON, University of Pittsburgh 2:30 (2010-4) The Genetic Basis of Longevity: HPLC-EC of Catecholamines in Drosophila ALLISON ROBINSON, University of Maryland, Baltimore County, Swati J Modi, William R LaCourse, Saritha Pasham, Hir Dalwadi, Jeffery Leips 2:50 (2010-5) Simultaneous Measurement of Vesicular Release and Calcium Influx in Chromaffin Cells MELISSA VILLANUEVA, University of North Carolina at Chapel Hill, R. Mark Wightman 3:10 Recess 3:25 (2010-6) ChitosanGlucose OxidaseGold Nanoparticles Biocomposite Formed by One-Step Electrodeposition for Glucose Sensing JING-JUAN XU, Nanjing University, Xi-Liang Luo, Hong-Yuan Chen 3:45 (2010-7) Highly Selective Antibody-Based Nanoporous Membranes LACRAMIOARA TROFIN, University of Florida, Punit Kohli, Miguel Mota, Charles R Martin 4:05 (2010-8) Biosensing with Artificial Ion Channels ZUZANNA S SIWY, University of Florida, Lacramioara Trofin, Chad Harrell, Punit Kohli, Elizabeth Heins, Charles R Martin 4:25 (2010-9) Preparation of Chitosan Stabilized Gold Nanoparticles and Its Application to Direct Electrochemistry of Horseradish Peroxidase HONG-YUAN CHEN, Nanjing University, Jiu-Ju Feng 4:45 (2010-10) Assessing Dynamics of Multidrug Resistance (MDR) Mediated Drug Efflux at Live Cells Using Voltammetry at a Carbon Fiber Microelectrode SUMITHA P NAIR, Case Western Reserve University, Miklos Gratzl

SYMPOSIUM
M Hieftje, Indiana University Thursday Afternoon, Room S220B Gary M Hieftje, Indiana University, Presiding 1:30 Introductory Remarks - Gary M Hieftje

Session 1990

Shootout in Plasma-Source Mass Spectrometry - arranged by Gary

1:35 (1990-1) Throw Away that Nebulizer: There Are Better Routes to Sample Introduction JAMES A HOLCOMBE, University of Texas at Austin 2:10 (1990-2) The ICP Is Not the Only - or Even Best - Source for Atomic Mass Spectrometry VAHID MAJIDI, Los Alamos National Laboratory, Chris Hassell, Cris Lewis, Ruth Waddell 2:45 (1990-3) Reaction-collision Cells are the Answer to Overcoming Spectroscopic Interferences in Inductively Coupled Plasma Mass Spectrometry (ICP-MS) ISAAC BRENNER, Environmental Analytical Laboratory 3:20 Recess

97

ORAL SESSION
Bioanalytical Spectroscopy II
Thursday Afternoon, Room S230C Ibolya Molnar-Perl, L. Eotvos University, Presiding

Session 2020

4:25 (2030-9) Patterned Chemical Functionality Inside MicronSized Capillaries ELISABETH MANSFIELD, University of Arizona, Eric E Ross, Craig A Aspinwall 4:45 (2030-10) Liquid-Phase Microextraction as an On-Line Preconcentration Method in Capillary Electrophoresis DOO SOO CHUNG, Seoul National University, Kihwan Choi, Su Ju Kim, Yang Gi Park

1:30 (2020-1) Biophysical Investigations of the Mtu RecA Miniature Intein Cleavage and Splicing Mechanisms TARA M SNYDER, Rensselaer Polytechnic Institute, John Dansereau, Victoria Derbyshire, Marlene Belfort, Georges Belfort 1:50 (2020-2) Molecular Beacon Design Improvements for Intracellular Applications LI TAN , University of Florida, Timothy J Drake, Weihong Tan 2:10 (2020-3) Fluorescent Aptamer Bioassay for Platelet Derived Growth Factor (PDGF) Detection MARIE C VICENS, University of Florida, Andrew C Vanderlaan, Chaoyong Yang, Arup Sen, Weihong Tan 2:30 (2020-4) Beta-hairpin Peptide Conformational Dynamics Studied Using Nanosecond Fluorescence Correlation Spectroscopy YING XIAO, Florida State University, Paul C Brister, William Milo, Kenneth D Weston 2:50 (2020-5) Molecular Computing-Based Remote Ethanol Sensing ROBERT A LODDER, University of Kentucky, Bin Dai 3:10 Recess 3:25 (2020-6) Diagnostic Tools to Characterize Near-infrared Spectra for Multivariate Analysis DONG XIANG, The University of Iowa, Wenjiao Lin, Mark A Arnold 3:45 (2020-7) Adaptive Silver Films for Bio-Array Applications VLADIMIR M SHALAEV, Purdue University, Vladimir P Drachev, Vishal Nashine, Mark D Thoreson, Eldar N Khaliullin, Dor Ben-Amotz, V. J Davisson 4:05 (2020-8) Manipulation of DNA as a Probe to Surface Heterogeneity HUNG-WING LI, Iowa State University, Edward S Yeung, HyeYoung Park, Marc D Porter 4:25 (2020-9) Single Molecule Ag:Ab Binding Kinetics Measured by Total-Internal-Reflection-Fluorescence Microscopy JOSHUA R WAYMENT, University of Utah, Joel M Harris 4:45 (2020-10) Bioanalysis Application of Dendrimeric Linkers DIHUA SHANGGUAN, University of Florida, Chaoyong Yang, Hui Lin, Weihong Tan

ORAL SESSION
Fluorescence Applications in Bioanalysis
Thursday Afternoon, Room S230B Jagdish P Singh, Mississippi State University, Presiding

Session 2040

1:30 (2040-1) Automated Specific Detection of RNA Sequences Using Sequential Injection Analysis KATIE A EDWARDS, Cornell University, Antje J Baeumner 1:50 (2040-2) Ultrasensitive Detection and Identification of Native DNA Nucleotides PAULA E COLAVITA, University of South Carolina, Laura Bridgman, Maria V Schiza, Annabelle C Molliet, Michael L Myrick 2:10 (2040-3) A Prototype of Automated Two-Dimensional Gel Electrophoresis of Proteins with Native Fluorescence Detection AOSHUANG XU, Iowa State University, Edward S Yeung 2:30 (2040-4) Electrochemiluminescence Quenching of Tris(2,2bipyridine) Ruthenium by Ferrocene and Its Application in Quantitative DNA Detection JEROME P FERRANCE, University of Virginia, Weidong Cao, James P Landers 2:50 (2040-5) The Novel Free Radical Trapping Reagent for Determination of Specific Nitric Oxide by High-Performance Liquid Chromatography with Fluorescence Detection YUJI ISHII, Hoshi University, Rie Ito, Koichi Inoue, Koichi Saito, Hiroyuki Nakazawa 3:10 Recess 3:25 (2040-6) Multidimensional Fluorescence Detection for Fast On-Chip Detection SEBASTIAN GTZ, University of Twente, Uwe Karst 3:45 (2040-7) Calibration of Probe Volume in Fluoresce Correlation Spectroscopy Using Single Molecule Photon Bursts YI GAO, University of Iowa, Zhenming Zhong, M Lei Geng 4:05 (2040-8) Why Calibrate Fluorescence Intensity? Qualification of Fluorescence Spectrometers for Relative and Absolute Intensity Measurements PAUL DEROSE, National Institute of Standards and Technology, R. David Holbrook, Gary W Kramer 4:25 (2040-9) Monitoring Biomolecular Interactions in Living Cells Using Fluorescence Anisotropy Imaging ZEHUI CAO, University of Florida, Chih-Ching Huang, Weihong Tan 4:45 (2040-10) Messenger RNA Expression Studies Using Polymer Linked DNA Probes KAREN MARTINEZ-DIAZ, University of Florida, Chaoyong Yang, Weihong Tan

ORAL SESSION
Capillary Electrophoresis: Capillary Technology
Thursday Afternoon, Room S210E Fu-Tyan Lin, Presiding

Session 2030

1:30 (2030-1) Enhanced Stability Self-Assembled Coatings for Protein Separations by Capillary Zone Electrophoresis CHARLES A LUCY, University of Alberta, Mahmoud M Yassine 1:50 (2030-2) Vesicle Affinity Capillary Electrophoresis: A Model System for Apolipoprotein-Lipid Binding and Transport KIRTAN N KOTICHA, Georgia State University, Emelita D Breyer, Sean W Davidson, William V Brown 2:10 (2030-3) A Guanosine Gel Phase for Chiral Separations in Capillary Electrophoresis VICTORIA A DOWLING, Duke University, Linda B McGown 2:30 (2030-4) Stable Surfactant Coatings for Inorganic Anion Analysis in Capillary Electrophoresis with Mixed Organic-Water Solvents ABEBAW G DIRESS, University of Alberta, Charles A Lucy 2:50 (2030-5) Use of a Flow Gate for Improved Push-Pull Perfusion Temporal Resolution ERIC E PATTERSON, University of Illinois at Chicago, Leyi Gao, Scott A Shippy 3:10 Recess 3:25 (2030-6) Study on Rapid Determination of Aristolochic Acids in Aristolochia Medicinal Plants HUWEI LIU, Peking University, Wei Li 3:45 (2030-7) Single Molecule Immuno-Electrophoresis in Submicrometer Pipettes and in Lab-on-Chip Technology RENE J PUESCHL, , Bernd W Wenclawiak, Christoph Zander 4:05 (2030-8) Application of Vesicle Affinity Capillary Electrophoresis in Quantitative Structure-Activity Relationship (QSAR) Studies and Drug Design EMELITA D BREYER, Georgia State University, Yali Jia, Rebecca L Owen, Binghe Wang, Richard Plemper

ORAL SESSION
Auburn University Thursday Afternoon, Room S230G Eric Bakker, Auburn University, Presiding

Session 2050

Ionophore-based Chemical Sensors III - arranged by Eric Bakker,

1:30 (2050-1) Sliver Sensor: Three-Color Processing of Optical Information for in vivo Metabolic Monitoring MIKLOS GRATZL, Case Western Reserve University, Sumitha P Nair, Koji Tohda 1:50 (2050-2) Sliver Sensor: An Ionophore Based Optical Sensor Array for Glucose and Electrolytes KOJI TOHDA, Case Western Reserve University 2:10 (2050-3) Chromoreactive Films and LEDs: How to Realise Ultra Low-Cost Chemical Sensors DERMOT DIAMOND, Dublin City University 2:30 (2050-4) Highly Selective and Sensitive Na⁺ and K⁺ Fluorescent Sensors Based on Conformational Restriction KOJI YAMADA, Keio University, Yuki Nomura, Naoko Iwasawa, Koji Suzuki 2:50 (2050-5) Potentiometric and Optical Fluoride Selective Sensors Based on Group 13 Metallo-Porphyrin and Salophen Complexes JEREMY T MITCHELL-KOCH, University of Michigan, Ibrahim Badr, Crystal Wong, Elzbieta Malinowska, Lukasz Gorski, Mark E Meyerhoff 3:10 Recess

98

3:25 (2050-6) Fluorescent Microarrays Based on Bulk Optode Microspheres KATARZYNA WYGLADACZ, Auburn University, Chao Xu, Eric Bakker 3:45 (2050-7) Ion-Selective Nanospheres for Cell Sensing ELIZABETH (LISA) A HALL, University of Cambridge, Lee Y Heng, Alan Tunnacliffe 4:05 (2050-8) Selective and Sensitive Fluorophore-Based PEBBLE Nanosensors for Copper and Iron JAMES P SUMNER, University of Michigan, Nissa M Westerberg, Andrea K Stoddard, Michele Cramer, Carol A Fierke, Richard B Thompson, Raoul Kopelman 4:25 (2050-9) Dye Doped Sol-gels for Chemical Sensors ANNE OKAFOR, St. John's University, Enji Wang, Neil Jespersen, Wenqun Wang, Kwok-Fan Chow, Cynthia Yee 4:45 (2050-10) Artificial Neural Network Analysis and Classification of Beverage Tastes with Solid-State Sensor Array HAKHYUN NAM, Kwangwoon University, Jong Dae Kim, Seong Suk Seo, Jae Hoon Shim, Young Ho Jeon, Jun Ho Shim, Geun Sig Cha

ORAL SESSION
LC Conditions Optimization for Bioanalytical LC-MS
Thursday Afternoon, Room S220C Bryan C Castle, Eli Lilly & Company, Presiding 1:30 (2080-1) Withdrawn

Session 2080

1:50 (2080-2) Optimizing Organelle Enrichment for Proteomic Analysis of Mouse Liver RANDY J ARNOLD, Indiana University, Petra Hrncirova, Chet Linson, Milos V Novotny 2:10 (2080-3) Combining Lectin Microcolumns with HIghResolution Separation Techniques for Effective Enrichment of Glycoproteins Originating from Biological Samples MILAN MADERA, Indiana University, Yehia Mechref, Milos V Novotny 2:30 (2080-4) Zirconia: The Ideal Substrate for Ion-Exchange LC and LC-MS RICHARD A HENRY, Supelco/Sigma-Aldrich, David S Bell 2:50 (2080-5) A Novel Thermally and Chemically Stable Lewis-Acid Deactivated Carbon-Based Zirconia Stationary Phase for RPLC and MS CLAYTON V MCNEFF, ZirChrom Separations, Inc., Bingwen Yan, David S Bell

ORAL SESSION
Laboratory Informatics II
Thursday Afternoon, Room S210D Singh Manocha, PPG Industries, Inc., Presiding

Session 2060

ORAL SESSION

Session 2090

1:30 (2060-1) Leveraging the Power of an Enterprise LIMS Solution CATHY BROWN, Thermo Electron Informatics & Services 1:50 (2060-2) Using Molecular Biology Examples to Analyze LIMS in the Life Science Laboratory DON CROSSETT, Thermo Electron Informatics & Services 2:10 (2060-3) Best Practices and Lessons Learned in Multi-site Deployment of LIMS: A Technical Perspective MARK EVANS, Thermo Electron Informatics & Services 2:30 (2060-4) Laboratory System Integration in Biopharmaceuticals KYLE MCDUFFIE, CSols, Inc. 2:50 (2060-5) Enterprise Integration of Data Acquisition System and LIMS DONALD KOLVA, Accelerated Technology Laboratories, Inc., Joanne Dussourd 3:10 Recess 3:25 (2060-6) Using LIMS and VBA to Meet Regulatory Compliance and Operational Reporting Needs of a Water System MICHAEL LEHTOLA, PerkinElmer, Sisay Mengistu 3:45 (2060-7) LIMS Beyond the Laboratory Walls DEVENDER GANDHI, PerkinElmer- LABWORKS LIMS 4:05 (2060-8) Common Data Architecture: A New Approach to Data Collection, Storage, and Retrieval CLIFFORD R GLOWACKI, Technikon LLC, Mark Quinsland, William Walden 4:25 (2060-9) Risk-Based Approach to Validating Laboratory Systems GEORGE GALLATIG, Taratec Development Corporation 4:45 (2060-10) Remediation Services for MS Excel KATHLEEN O'DEA, Scientific Software, Inc.

Liquid Chromatography: Detection and High Temperature Techniques

Thursday Afternoon, Room S220D Annie M Warner, Eli Lilly and Company, Presiding 1:30 (2090-1) Automated Baseline Reduction in High Performance Liquid Chromatographic Diode Array Signals MICHAEL MCBRIEN, Advanced Chemistry Development, Inc., Andrey Bogomolov, Eduard Kolovanov, Alexander Ivanov 1:50 (2090-2) Requirements For and Applications of A Temperature-Programmed Heating System for Liquid Chromatography THORSTEN TEUTENBERG, , Thekla Kiffmeyer 2:10 (2090-3) Immunoaffinity SPE Method Optimization by HPLC: The Influence of Tube Material and Sample Matrix on Mycotoxin Recovery DARSA P SIANTAR, Alcohol & Tobacco Tax and Trade Bureau, Maria N Ofitserova, Sareeta Nerkar, Michael V Pickering, Erika Wadleigh, Nancy A Zabe, Barb A Cohen, Maria S Cardozo, George F Peterson, Norma R Hill 2:30 (2090-4) Analysis of Microperoxidases Using Liquid Chromatography, Post-Column Substrate Conversion and Fluorescence Detection CHRISTEL HEMPEN, University of Twente, Rob Haselberg, Suze M van Leeuwen, Martin Vogel, Uwe Karst 2:50 (2090-5) Optimized Instrument Parameters for a High Temperature HPLC System with Flame Ionization Detection JODY CLARK, Selerity Technologies, Stephanie J Marin, Brian A Jones, Dale Felix 3:10 Recess 3:25 (2090-6) Exploring the Use of High Temperature HPLC for the Development of High Throughput Purity Methods in the Pharmaceutical Analytical Lab IVELISSE COLON, Pfizer, Inc., Juan R Gozalez 3:45 (2090-7) Improving Speed and Resolution of Separations by Utilizing High Temperature and Temperature Programming in Liquid Chromatography PAT SANDRA, Selerity Technologies, Dale Felix, Stephanie J Marin, Brian A Jones, Jody Clark, John Rizzo 4:05 (2090-8) Silica-Based Columns for Reversed-Phase HPLC Separations at Temperature and pH Extremes BRIAN A JONES, Selerity Technologies, Jody Clark, Stephanie J Marin, Dale Felix 4:25 (2090-9) Solvent Effects in Molecularly Imprinted Polymer HYUNJUNG KIM, University of Tennessee at Knoxville, George Guiochon 4:45 (2090-10) Correlation of Retention in Reversed-Phase Liquid Chromatography as a Function of Varying Temperature Versus Polarity of a Molecule KENNETH NORRIS, Pfizer, Inc., Mark Olivier, Hugh Clarke, Andrew Jensen, William Lunn

ORAL SESSION
Laboratory Management
Thursday Afternoon, Room S210B Penny R Gardner, The Pittsburgh Conference, Presiding

Session 2070

1:30 (2070-1) Enhanced Monitoring Programs through Automated Sample Scheduling and Palm Units MATHEW ABRAHAM, Accelerated Technology Laboratories, Inc., Steve Rayburn, Russ Vranken, Fred Rider 1:50 (2070-2) The Optimal Maintenance Solution JOHN DEMEO, Thermo Electron Informatics & Services 2:10 (2070-3) The New Quality Assurance: The Case for I-QAS JOHN G HUNTINGTON, Gateway Enterprises 2:30 (2070-4) Methods for Selecting the Optimum Laboratory Gas STEVE S SCHEURING, Airgas, Inc. 2:50 (2070-5) Withdrawn

99

ORAL SESSION
Nanotechnology: Methods
Thursday Afternoon, Room S220F Stephen K Gozo, Bristol-Myers Squibb Company, Presiding

Session 2100

4:25 (2110-9) Correlation of Water Content in Powders, Coated and Core Tablets by NIR and Karl Fischer SEEMA TOMER, Novartis Pharmaceuticals, Venkat S Tumuluri, James E Mullins, Richard Vivilecchia, James Pazdan 4:45 (2110-10) Analysis of the Adsorption Evolution of Water Molecules on Silica Gel Surface by Near infrared Spectrometry and Chemometrics: An Alternative Way to Determine Silanol Number ALFRED A CHRISTY, Agder University College, Per K Egeberg

1:30 (2100-1) Electrocatalysis at a Controlled Array of Gold Nanoparticles DIEP V CA, Miami University, James A Cox 1:50 (2100-2) Nanostructured Pt as a Catalyst by Underpotential Deposition Combined Chemical Replacement for Dioxygen Reduction SHAOJUN DONG, Changchun Institute of Applied Chemistry 2:10 (2100-3) SFINKS: A New and Versatile Technique for Single Micron Scale Biopatterning DALE M WILLARD, Colorado State University 2:30 (2100-4) Low Temperature Heterogeneous Process for Synthesis of Luminescent CdX (X= Se, and Te) Quantum Dots MITSURU ISHIKAWA, AIST, Rajan Jose, Zhivko Zhelev, Nagase Toshimi, Yoshinibu Baba 2:50 (2100-5) Electro-oxidation of Carbon Monoxide and Methanol on Gold and Platinum-Coated Gold Nanoparticles SACHIN KUMAR, Miami University, Shouzhong Zou 3:10 Recess 3:25 (2100-6) New Nano-Porous Sensing Materials for SAW Sensors Using Organically Modified Silicates MICHAEL W RAPP, Forschungszentrum Karlsruhe GmbH, Karlheinz Lubert 3:45 (2100-7) Analytical Applications of Palladium Nanoparticles Using Polyamic Acid as Reducing Agent OMOWUNMI A SADIK, State University of New York at Binghamton, Omole M Wanekaya 4:05 (2100-8) Gold Nanoparticle Stabilized Acetylcholine Esterase Enzyme Electrode OLGA SHULGA, The University of Toledo, Jon Kirchhoff 4:25 (2100-9) Electrochemically Fabricated Functionalized Conducting Polymer Nanowires Electrode Junctions that Function as Electronic Biosensors JUN WANG, University of California at Los Angeles, Hsain-Rong Tseng 4:45 (2100-10) Fabrication and Characterization of Nanometer-Sized Probes Based on Selectively Etched Optical Fibers for Scanning Electrochemical Microscopy HUI XIONG, University of Pittsburgh, Jidong Guo, Kazuyoshi Kurihara, Shigeru Amemiya

ORAL SESSION
Proteomics and Genomics

Session 2120

Thursday Afternoon, Room S220E Kerry W Holzworth, University of Pittsburgh at Greensburg, Presiding 1:30 (2120-1) Raman Detection of Protein Post-Translational and Conformational Modifications FRAN ADAR, Jobin Yvon Horiba, Dongmao Zhang, Yong Xie, Dor Ben-Amotz 1:50 (2120-2) Bioinformatics and Mass Spectrometry for Neuropeptide Discovery in the Honey Bee, Apis mellifera ANDINET AMARE, University of Illinois at Urbana, Amanda B Hummon, Timothy A Richmond, Michael A Ewing, Jonathan V Sweedler 2:10 (2120-3) On-line Monolithic Preconcentrator-CZE for the Enrichment of Proteins in Human Plasma JENNY M ARMENTA, Brigham Young University, Binghe Gu, Milton L Lee 2:30 (2120-4) High-Throughput, Genome-Scale Protein Production Free Expression System TATSUYA SAWASAKI, Ehime University, Ryo Morishita, Masatoshi Fujiwara, Motoo Watanabe, Yaeta Endo 2:50 (2120-5) A Totally Integrated 2D System Incorporating IonExchange via SPE and RP-HPLC Chromatography for Natural and Biological Products JOAN M STEVENS, Gilson, Inc., Luke Roenneburg, Kirby Reed 3:10 Recess 3:25 (2120-6) Membrane Chromatography Purification of Adenovirus and Adeno-Associated Viral Vectors AJAY R LAJMI, Pall Lif Sciences, Jakob Reiser, Andrew Davidoff 3:45 (2120-7) Chip CE as a Tool for Multi-dimensional Separation of Proteins JAMES H LENKE, West Virginia University, Manoj V Warrier, Aaron T Timperman 4:05 (2120-8) The Role of Telomere Maintenance in Oxidative DNA Damage Response in Primary Human Fibroblasts NANCY L LY, Yale University 4:25 (2120-9) High-Speed and High-Sensitivity Analysis of Protein Sizing and Quantitation Using a Microfluidic System BAHRAM FATHOLLAHI, Caliper Life Sciences 4:45 (2120-10) Advantages of a New Direct-flow NanoLC/MS/MS System Optimized for Use with 1.7 Micron Particles JEFFREY W FINCH, Waters Corporation, Hongji Liu, Martha D Staples, Geoff Gerhardt, Keith Fadgen, John C Gebler, Theodore A Dourdeville, Dennis DellaRovere, Christopher Benevides

ORAL SESSION
NIR Spectroscopy
Thursday Afternoon, Room S230A Seetha Ananthaiah, Bristol-Myers Squibb, Presiding

Session 2110

1:30 (2110-1) Near-infrared Spectroscopy: A Universal Tool for Quality and Process Control HEINZ W SIESLER, University of DuisburgEssen 1:50 (2110-2) In-Line Near-Infrared for Control of Fatty Acid Distillation: Feasibility Study MARCHEL SNIEDER, Uniqema, Sophie S Wiedemann, Wei G Hansen 2:10 (2110-3) Dimensionality Reduction of NIR Spectral Data Using Global and Local Implementations of PCA for Neural Network Calibrations IGOR V KOVALENKO, Iowa State University, Glen R Rippke, Charles R Hurburgh 2:30 (2110-4) Blend Uniformity Monitoring Using NIRS: Qualitative and Quantitative Analysis PROMIT DAS, Control Development, Inc., Ross Herrold, Terrance R Kinney 2:50 (2110-5) A Process Analytical Near IR Chemical Imaging Instrument KENNETH S HABER, Spectral Dimensions, Inc., Fiona Clarke, Eunah Lee, Linda H Kidder, E. Neil Lewis 3:10 Recess 3:25 (2110-6) Exploiting Process Analytical Technology Benefits through Deep Business Integration BRIAN DAVIES, Thermo Electron Corporation, Zafar Kamal, Scot Ellis, John Dickson 3:45 (2110-7) Integration of a Near IR Analyzer into the Process Control Loop-OPC-based Solutions for PAT JEFFREY HIRSCH, Thermo Electron Corporation 4:05 (2110-8) New Generation of AOTF-NIR Analyzers for On-line Applications IGOR NAZAROV, Brimrose Corporation of America

ORAL SESSION
Thursday Afternoon, Room S230H Garry Lynch, Bechel-Bettis, Inc., Presiding

Session 2130

Sensors for Biological and Chemical Weapons Detection

1:30 (2130-1) Detection of Bio-warfare Agents with Multiplexed High-Density DNA Arrays LINAN SONG, Tufts University, David R Walt 1:50 (2130-2) Progress in the Use of Laser Induced Breakdown Spectroscopy (LIBS) for Bio Hazard Detection and Identification ANDRZEJ W MIZIOLEK, US Army Research Laboratory, Frank C DeLucia, Chase A Munson 2:10 (2130-3) Investigation of Nucleic Acid Aptamers for Food Pathogen Detection DIMITRA STRATIS-CULLUM, US Army Research Laboratory, Kellie Wade, Paul M Pellegrino, Aaron S Wilson 2:30 (2130-4) A Carbon Nanotubes Based Biosensor for Sensitive and Direct Detection of VX Analog and Degradation Products KANCHAN A JOSHI, University of California at Riverside 2:50 (2130-5) Investigation of Common Fluorophores for Detection of Nitrated Explosives by Fluorescence Quenching MELISSA S MEANEY, Michigan State University, Victoria L McGuffin

100

3:10

Recess

3:25 (2130-6) Microcantilever Gas Sensors with Custom Drive Electronics for Detection of Chemical Warfare Agents STANLEY V STEPNOWSKI, US Naval Research Lab, Eric J Houser, Robert A McGill, Evgueni A Sokolovski, Jennifer L Stepnowski, Ioana Voiculescu 3:45 (2130-7) An Ion Mobility Spectrometry Chemical Warfare Agent Detection and Sampling System Operated in an Unmanned Aerial Vehicle for Interrogation of Chemical Clouds in Real Time VINCENT M MCHUGH, US Army ECBC, Charles S Harden, Donald B Shoff, Brian S Ince, Stephen E Harper, Gretchen E Blethen, Robert J Schafer, Paul D Arnold, Simon W Pavitt, Martin A Thomas, William R Espander, Steven M Ciborowski 4:05 (2130-8) Using an Array of Ion Mobility Spectrometers for Real-Time Ground Truth Concentration Measurements in the Field CHARLES S HARDEN, GEO-Centers, Inc., Vincent M McHugh, Donald B Shoff, Brian S Ince, Stephen E Harper, Gretchen E Blethen, Robert J Schafer, Paul D Arnold, Simon W Pavitt, Martin A Thomas, William R Espander, Steven M Ciborowski 4:25 (2130-9) CASPAR, A Micromachined Preconcentrator for Enhanced Detection of Chemical Agents ANDREW MCGILL, Naval Research Laboratory, Stuart K Ross, Michael Martin, Jennifer L Stepnowski, Stanley V Stepnowski, Eric J Houser, Kevin Walsh, Mark Crain, Viet Nguyen, Evgueni A Sokolovski 4:45 (2130-10) Magnetic Bead Based High Throughput Viral RNA Isolation for Molecular Diagnosis XINGWANG FANG, Ambion, Inc., Roy C Willis, Mangkey Bounpheng, Weiwei Xu, Quoc Hoang, Angela Burrell

10:35 (2150-4) Microdialysis in Drug Development MARTIN BRUNNER, Medical University of Vienna 11:10 (2150-5) Seeing is Believing: The Chemistry of Biological Molecular Imaging THOMAS J MEADE, Northwestern University

SYMPOSIUM

Session 2160

Laser Induced Breakdown Spectroscopy: An Emerging Analytical Tool - arranged by Jagdish P Singh, Mississippi State University
and Fang-Yu Yueh, Mississippi State University Friday Morning, Room S230B Jagdish P Singh, Mississippi State University, Presiding 8:30 Introductory Remarks - Jagdish P Singh

8:35 (2160-1) LIBS: Applications to Army FRANK C DE LUCIA, US Army Research Laboratory, Andrzej W Miziolek, Chase A Munson, Thuvan Nguyen, Kevin L McNesby 9:10 (2160-2) Laser-Induced Breakdown Spectroscopy for Biological Aerosol Detection STEVEN G BUCKLEY, University of California at San Diego 9:45 (2160-3) Comparison of ns and fs Laser-Induced Breakdown Spectroscopy (LIBS) for Spectrochemical Analysis of Material MOHAMAD SABSABI, NRC 10:20 Recess

FRIDAY, MARCH 4, 2005

SYMPOSIUM
Session 2140

10:35 (2160-4) LIBS Application to Material Analysis SURYA N THAKUR, Banaras Hindu University 11:10 (2160-5) Sequential and Ultra-short Pulse LIBS: Application to High Pressure Solution Measurements MICHAEL S ANGEL, The University of South Carolina, Jonathan P Scaffidi, Marion J Lawrence-Snyder, William F Pearman, Anna P Michel, Alan D Chave

Bioanalysis of DNA Microarrays: Correlating Surface Properties with Assay Performance - arranged by David G Castner,
University of Washington Friday Morning, Room S220C David G Castner, University of Washington, Presiding 8:30 Introductory Remarks - David G Castner

ORAL SESSION
Analytical Techniques for Proteomics and Genomics Applications
Friday Morning, Room S220A TBA, Presiding

Session 2175

8:35 (2140-1) Bioanalytical Challenges to Improve Performance of DNA Microarrays in Bioassays DAVID GRAINGER, Colorado State University, Ping Gong 9:10 (2140-2) Multitechnique Surface Analysis of DNA Microarrays LARA J GAMBLE, University of Washington 9:45 (2140-3) Controlling the Structure of DNA Monolayers on Gold MICHAEL J TARLOV, National Institute of Standards and Technology 10:20 Recess 10:35 (2140-4) Kinetics and Thermodynamics of DNA Binding at Surfaces ROSINA GEORGIADIS, Boston University 11:10 (2140-5) Surface Engineering for Improved DNA Microarray Performance MICHAEL J LOCHHEAD, Accelr8 Technology Corporation

8:30 (2175-1) Electrochemical Coding for Multiplexed Immunoassays of Proteins GUODONG LIU, Pacific Northwest National Laboratory, Joseph Wang, Yuehe Lin 8:50 (2175-2) Electro-Kinetic Behavior of Nucleotides and Quantitative Measurements in Authentic DNA Samples by Osteryoung Square Wave Voltammetry CHIA-YU LI, East Carolina University, Huayan Wang 9:10 (2175-3) Development of Cap/Nano Monolithic LC Columns and Its Application in Bioseparations JIANG TAO, Teledyne Isco, Inc., Xie Shaofeng 9:30 (2175-4) Characterization of Frankia Hydrogen Evolving Enzyme Through Proteomics Approach ANASUYA MOHAPATRA, Umea Plant Science Centre (Upsc), Anita Sellstedt 9:50 (2175-5) Withdrawn Session 2180

SYMPOSIUM

Session 2150

In Vivo Analytical Chemistry: From Glucose to 'Omics' - arranged

by David D Cunningham, Abbott Laboratories and Julie A Stenken, Rensselaer Polytechnic Institute Friday Morning, Room S230E David D Cunningham, Abbott Laboratories, Presiding 8:30 Introductory Remarks - David D Cunningham

ORAL SESSION
Atomic Spectroscopy: Mercury and Arsenic Analysis

Friday Morning, Room S230D Joseph E Wreen, Association for the Coastal Environment, Presiding 8:30 (2180-1) An Accurate and Sensitive Method for the Determination of Methylmercury in Biological Specimens Using GC-ICPMS with Solid Phase Microextraction CLAY DAVIS, National Institute of Standards and Technology, Colleen E Bryan, Russell D Day, Steven J Christopher 8:50 (2180-2) Speciation of Methylmercury and Inorganic Mercury in Environmental and Biological Samples by Flow Injection Cold Vapor Generation from Tetrachlorotin(II) and Tetrahydroborate-Form AnionExchange Columns with Atomic Absorption Spectrometry WIPHARAT CHUACHUAD, University of Massachusetts, Julian F Tyson

8:35 (2150-1) Noninvasive In Vivo Sensing with Near Infrared Spectroscopy MARK A ARNOLD, University of Iowa 9:10 (2150-2) Transdermal and Subcutaneous Approaches to Glucose Monitoring DAVID D CUNNINGHAM, Abbott Laboratories, Inc., Timothy P Henning, Ben Feldman 9:45 (2150-3) In Vivo Detection of Macrophage Activation Products Caused by the Foreign Body Response to Implanted Sensor Devices JULIE STENKEN, Rensselaer Polytechnic Institute 10:20 Recess

101

9:10 (2180-3) A Method for Determining Microbiologically Mediated Release of Elemental and Organomercury Compounds from CCBs Using SPME, Gas Chromatography, and Atomic Fluorescence DAVID J HASSETT, UND Energy & Environmental Research Center, Loreal V Heebink, Erick J Zacher 9:30 (2180-4) Rapid Analysis of Mercury in Fish Tissue Using Direct Mercury Analysis MICHAEL A LEVINE, RTI International, Keith E Levine, Frank X Weber, Peter M Grohse 9:50 (2180-5) Determination of Mercury in an Assortment of Dietary Supplements Using an Inexpensive Combustion Atomic Absorption Spectrometry Technique KEITH E LEVINE, RTI International, Michael A Levine, Frank X Weber, Jason M Perlmutter, Peter M Grohse 10:10 Recess 10:25 (2180-6) Fully Automated Mercury Analysis: Just Press 'Start' JASON P GRAY, AGS Scientific, Inc., Koji Tanida, Alvin Chua 10:45 (2180-7) Addressing the Challenges of Total Arsenic Determination in Various Environmental Samples Using-Hydride Generation- Atomic Fluorescence Spectrometer (HG-AFS) OLUJIDE T AKINBO, Butler University, Jon Clark, Megan Bergauff 11:05 (2180-8) Quantification of Organic and Inorganic Arsenic and Selenium Species in Standard Reference Materials and Clinical Marine Samples by High Performance Liquid Chromatography Collision Cell Inductively Coupled Plasma Mass Spectrometry CLAY DAVIS, National Institute of Standards and Technology, Rebecca S Pugh, Steven J Christopher 11:25 (2180-9) Separation, Preconcentration and Trace Determination of Cr(VI), As(III) and Tl(I) in Natural Water Samples by Polymer Supported Calix[4]arene-o-vanillinthiosemicarbazone Resin VINOD K JAIN, Gujarat University, Rujul A Pandya, Shibu G Pillai, Pranav S Shrivastav, Yaduvendra K Agrawal 11:45 (2180-10) The "A-B-C"s of Arsenic, Bangladesh and Cancer JERRY DEMENNA, Buck Scientific, Eid Al-Khatib

11:25 (2190-9) Simultaneous, Quantitative Analysis of Choline, Betaine Aldehyde, and Glycine Betaine Using Capillary Zone Electrophoresis-Electrospray Mass Spectrometry (CZE-ESI-MS): Kinetic Studies of Choline Oxidases JIE ZHENG, Georgia State University, Ghanem Mahmoud, Giovanni Gadda, Shahab A Shamsi 11:45 (2190-10) Rapid Analysis of Biomolecular Interactions Using Multiplexed Capillary Electrophoresis With Photolytic Injection CRAIG A ASPINWALL, University of Arizona, Suminda Hapuarachchi, Kevin L Braun, Facundo M Fernandez

ORAL SESSION

Session 2200

Electrochemistry for Bioanalytical and Biomedical Detection

Friday Morning, Room S220G William R LaCourse, University of Maryland, Baltimore County, Presiding 8:30 (2200-1) Thin Layer Electrogenerated Chemiluminescence JACOB B KETTER, University of North Carolina at Chapel Hill, R. Mark Wightman 8:50 (2200-2) Controlling the Electrochemically Active Surface Area of Microelectrodes BRADLEY A LAMBIE, University of Pittsburgh, Stephen G Weber 9:10 (2200-3) Electrochemistry Studies of Cu(II) Complexes of Bioactive Peptides RONG MENG, University of Pittsburgh, James Becker, Marco Bonora, Fu-Tyan Lin, Sunil K Saxena, Stephen G Weber 9:30 (2200-4) Multianalyte Assays Based on Microfabricated Amperometric Cells Immobilized with Multiple Enzymes YING LIU, The University of Memphis, Clint Watts, Erno Lindner 9:50 (2200-5) Trace Metal Analysis on Boron-Doped Diamond Electrodes for Water Quality Monitoring ELIZABETH A MCGAW, Michigan State University, Prerna Sonthalia, Greg M Swain 10:10 Recess 10:25 (2200-6) Simultaneous Detection of Ethanol and Smoking ByProducts with Fuel Cell Based Sensors JOHNA LEDDY, University of Iowa, Luke Haverhals 10:45 (2200-7) Monitoring Beta-glucosidase Enzymatic Hydrolysis of Carbohydrates by Quantitative In Vitro Microdialysis SWATI J MODI, University of Maryland, Baltimore County, William R LaCourse 11:05 (2200-8) The Determination of Ethyl Glucuronide in Urine Using Reversed-Phase High Performance Liquid Chromatography and Pulsed Electrochemical Detection ROMINA KAUSHIK, University of Maryland, Baltimore County, William R LaCourse 11:25 (2200-9) Novel pH Sensor Based on Pulse Laser Deposited Iridium Coated with H+ Permeable Polymer Modified Electrode XUEJI ZHANG, University of South Florida 11:45 (2200-10) Engineered Single Chain Recombinant Antibody Biosensors XIANGQUN ZENG, Oakland University, Zhihong Shen, Gabrielle A Stryker, Ray Mernaugh, Lei Yu, Heping Yan

ORAL SESSION
Bioanalytical Capillary Electrophoresis
Friday Morning, Room S230A Thomas E Wheat, Waters Corporation, Presiding

Session 2190

8:30 (2190-1) Investigating the Effect of Drug Delivery System on the Subcellular Localization of Doxorubicin Metabolites ANGELA R EDER, University of Minnesota, Christopher V Eddy, Hossein Ahmadzadeh, Edgar A Arriaga 8:50 (2190-2) High Sensitivity, Mobility Shift Immunoassays in Microchips Utilizing DNA-Conjugated Antibodies to Accelerate the Separation of Antigen-Antibody Complexes HENRY G WADA, Wako Pure Chemical Industries, Ltd., Tomohisa Kawabata, Irina Kazakova, Anton Simeonov, Charles Park, Persefoni Kechagia, Michael Spaid, Mitsuo Watanabe, Shinji Satomura 9:10 (2190-3) In Vitro Selection of Aptamers for Tumor Promoting Proteins using Capillary Electrophoresis PRABODHIKA R MALLIKARATCHY, University of Florida, Jessica Smith, Zehui Cao, Tan Weihong 9:30 (2190-4) Withdrawn 9:50 (2190-5) Capillary Electrophoretic Analysis of Liposome Incorporated Membrane Proteins MICHELE D PYSHER, Arizona State University, Mark A Hayes 10:10 Recess 10:25 (2190-6) Determination of Norepinephrine and Metabolites in Physiological Fluids Using CE-EC with Boron-Doped Diamond Microelectrodes VERONIKA QUAISEROVA-MOCKO, Michigan State University, Greg D Fink, James J Galligan, Greg M Swain 10:45 (2190-7) In vitro Selection of DNA Aptamers for the Detection of a Cancer Biomarker JESSICA SMITH, University of Florida, Prabodhika R Mallikaratchy, Zehui Cao, Weihong Tan 11:05 (2190-8) A Study of Serotonin Catabolism in the Central Nervous System of Mammals Using Capillary Electrophoresis and LaserInduced Fluorescence (CE-LIF) LEAH N SQUIRES, University of Illinois at Urbana, Jeffery N Stuart, Stanislav S Rubakhin, Jonathan V Sweedler

ORAL SESSION
Environmental: General Papers
Friday Morning, Room S220B TBA, Presiding 8:30 (2205-1) GFS Chemicals, Inc.

Session 2205

What is Toxilytical Relativity(TM) ? JOHN R LONG,

8:50 (2205-2) Using Automated Deconvolution Software to Find Needles in a Haystack CHINKAI MENG, Agilent Technologies, Inc., Philip L Wylie, Michael Szelewski 9:10 (2205-3) PGE Bearing Cr-Spinel Chemical Analysis for Trace and REE Using ICP-MS: A Comparison of Digestion Techniques PERUMALA SUNDER RAJU, Epma Lab, K V Anjaiaha , T Gnaneswar 9:30 (2205-4) A Novel Type of Distributed Feedback Lasers for Sensing Applications JOHANNES KOETH, Nanoplus Nanosystems and Technologies Gmbh 9:50 (2205-5) Removal of Nickel(II) Ions From Industrial Waste Water by Using a Low Cost Biosorbent and a Microbial Bisorbent CHARU KHOSLA, Punjabi University, Neelam Verma, A.L.J. Rao

102

10:10

Recess

ORAL SESSION
Mass Spectrometry and Bio-application
Friday Morning, Room S230F Richard Schultz, Bar-Ilan University, Presiding

Session 2230

10:25 (2205-6) A FTIR Study on Environmental-friendly Polymer Blends of Poly(3-hydroxybutyrate) and Polyvinyl alcohol with Different Degree of Saponification HE HUANG, Kwansei Gakuin University, Jianming Zhang, Harumi Sato, Yun Hu, Xiansu Cheng, Isao Noda, Yukihiro Ozaki, He Huang

ORAL SESSION
Industrial Hygiene Sampling and Analysis
Friday Morning, Room S220F Sarah L Shockey, Consultant, Presiding

Session 2210

8:30 (2230-1) Lossless Ion Mobility Spectroscopy/Mass Spectrometry Using Electrodynamic Ion Funnel Interfaces ALEXANDRE SHVARTSBURG, Pacific Northwest National Laboratory, Keqi Tang, Hak-No Lee, David C Prior, Michael A Buschbach, Gordon A Anderson, Richard D Smith 8:50 (2230-2) High-Throughput Determination of the Pharmaceutical Active Diazepam by Ion Mobility Spectrometry (IMS) JOHN J CARROLL, Smiths Detection, Reno DeBono 9:10 (2230-3) Affinity Mass Spectrometry Using AptamerEnhanced MALDI LAWRENCE W DICK, Duke University, Linda B McGown 9:30 (2230-4) Selective Single Photon Ionization of a Derivatized Peptide LUKE HANLEY, University of Illinois at Chicago, Praneeth D Edirisinghe, Jerry F Moore, Igor V Veryovkin, Wallis F Calaway, Michael J Pellin 9:50 (2230-5) Implementation of a Protein Species Quantitation Method DAVID P IONADI, Duquesne University, H.M. "Skip" Kingston 10:10 Recess 10:25 (2230-6) A SUPREX Based General Method to Study ProteinDNA Interactions LIYUAN MA, Duke University, Anne M Augustus, Leonard D Spicer, Michael C Fitzgerald 10:45 (2230-7) Fast Small-Scale Permethylation Procedure for the Structural Characterization of Oligosaccharides by MALDI/TOF/TOF Tandem Mass Spectrometry YEHIA MECHREF, Indiana University, Pilsoo Kang, Milos V Novotny 11:05 (2230-8) Rapid Analysis of Complex Protein and Peptide Mixtures with a Dual Reflectron MALDI TOF Mass Spectrometer KIRK S BORAAS, Indiana University, James P Reilly, Noah P Christian 11:25 (2230-9) Discovery of Novel Neuropeptides by Matrix Assisted Laser Desorption/Ionization Mass Spectrometry (MALDI-TOFM) Using Monolayer Modified Target Plates HUI WEI, University of Michigan, Robert T Kennedy, Mark C Parkin 11:45 (2230-10) Two-Dimensional Mass Spectrometry for Improved Proteome Analysis HONGYING ZHONG, University of Alberta, Sandra Marcus, Liang Li

8:30 (2210-1) A High Sensitivity Portable GC for VOC's JOHN N DRISCOLL, PID Analyzers, LLC 8:50 (2210-2) Diffusive Sampling of Isocyanates HARTMUT HENNEKEN, University of Twente, Uwe Karst 9:10 (2210-3) Passive Sampling of Airborne Peroxyacetic Acid MARTIN VOGEL, University of Twente, Hartmut Henneken, Uwe Karst 9:30 (2210-4) Designed Enhancement of Olefin Detection with Thiolate Protected Gold Nanoparticle Chemiresistors MICHAEL P ROWE, University of Michigan, Edward T Zellers 9:50 (2210-5) Detection and Quantification of Microbial Metabolites JOERG INGO BAUMBACH, ISAS - Institute for Analytical Sciences, Vera Ruzsanyi, Fang Li, Stefanie Sielemann, Wolfgang Vautz

ORAL SESSION
Liquid Chromatography: LC/MS et al
Friday Morning, Room S230C Dutt V Vinjamoori, Monsanto Company, Presiding

Session 2220

8:30 (2220-1) HPLC Instrument Configuration and Modifications Required to Optimize Performance of Sub-Two Micron, High-Throughput HPLC Columns WILLIAM E BARBER, Agilent Technologies, Inc., Stefan Schuette, Anabel Fandino 8:50 (2220-2) Transformations of Pharmaceutical Compounds by Reaction with Chlorine MARY BEDNER, National Institute of Standards and Technology, William MacCrehan 9:10 (2220-3) Understanding Anionic Additive Effects in the Reversed Phase Separation of Basic Pharmaceuticals JUN DAI, University of Minnesota, Peter W Carr 9:30 (2220-4) Design of High Purity Blends for Chromatography Utilizing Six Sigma Methodology ANTHONY R KEMPERMAN, Honeywell, Matthew A Bosma, James T Przybytek, Karel A Snoble 9:50 (2220-5) An HPLC Autosampler of Ultimately Reduced Carryover Equipped with an Ultrasonic Cleaning Device OSAMU SHIROTA, Shiseido Company, Yuki Togashi, Masashi Mita, Tsuneaki Kaneko, Xiaomi Xin 10:10 Recess 10:25 (2220-6) An LC-MS Method to Better Define Asparagine Deamidation as Developed for the Protective Antigen of the NextGeneration Anthrax Vaccine BRADFORD S POWELL, USAMRIID 10:45 (2220-7) Electrochemically Modulated Liquid Chromatography: A Macroscopic Approach to Investigating Electrified Interfaces DAVID W KELLER, Iowa State University, Marc D Porter 11:05 (2220-8) Novel Injection Valve Assembly for UHPLC YANSHENG LIU, Brigham Young University, Yanqiao Xiang, Greg Henry, Jikun Liu, Stanley D Stearns, Ales Plistil, Martin P Brisbin, Milton L Lee 11:25 (2220-9) Transferring Yesterdays Methods to Tomorrows Technology: The Evolution from HPLC to UPLC ERIC S GRUMBACH, Waters Corporation, Diane M Diehl, Jeffrey R Mazzeo 11:45 (2220-10) Deconvolution of Mobile Phase Contributions to Chromatographic Band Broadening CAROLYN R SIMMONS, Florida State University, Karyn M Usher, John G Dorsey

ORAL SESSION
Sample Preparation in Bioanalytical and Forensics
Friday Morning, Room S230H Allen K Vickers, Agilent Technologies, Presiding

Session 2240

8:30 (2240-1) In Vivo Microdialysis Sampling of Inflammatory Cytokines XIAOPING AO, Rensselaer Polytechnic Institute, Robert F Rotundo, Daniel J Loegering, Julie Stenken 8:50 (2240-2) Multi-Inlet Technique Utilizing GC and Direct SPME Sample Introduction for Trace, Mixture, and Rapid Bulk Analysis by Portable MS GARTH E PATTERSON, Griffin Analytical Technologies, Inc., John W Grossenbacher, Anthony J Cochran, James M Wells, Brent A Knecht, Brent D Rardin, Mark A Gregory, Jason L Springston 9:10 (2240-3) Applications of Pressure Cycling Technology (PCT) in Proteomics RICHARD T SCHUMACHER, Boston Biomedica, Inc. 9:30 (2240-4) Macromolecule Calibration During Microdialysis Sampling XIANGDAN WANG, Rensselaer Polytechnic Institute, Julie Stenken 9:50 (2240-5) Microextraction in Packed Syringe (MEPS)/ LC-MS: An Application for Metabolites Screening MOHAMED ABDEL-REHIM, AstraZeneca, Zeki Altun, Lars Blomberg, Moustapha Hassan

103

ORAL SESSION
Sensor Developments and Applications
Friday Morning, Room S230G Melissa C Rhoten, Longwood College, Presiding

Session 2250

10:25 (1820-6) Two-Dimensional Miniaturized Electrophoresis of Phycoerythrin Protein with Native Fluorescence Using Side Entry Excitation HUI ZHANG, Iowa State University, Edward S Yeung 10:45 (1820-7) Elucidation of Enantiomeric Separation Mechanisms via a Linear Solvation Energy Relationship CLIFFORD R MITCHELL, Iowa State University 11:05 (1820-8) Study of Ligand-Receptor Interactions Using SPME: Simultaneous Assay of Receptor, Free and Total Ligand Concentrations FLORIN MARCEL MUSTEATA, University of Waterloo, Janusz B Pawliszyn 11:25 (1820-9) Selective Extraction of Lipid Classes Using Packed Beds on Microfluidic Chips TAMANNA SULTANA, Duquesne University, Chris Ferrenc, James P Landers, Mitchell E Johnson 11:45 (1820-10) Functional Barriers for Stable Electrophoresis: Beam, Unstirred Conductive Layer and Sill KATSUNORI AIZAWA, Advance Company Ltd., Masamitsu Seo

8:30 (2250-1) High Performance Surface-Micromachined PolymerMetal Composites Based Biochemical Sensor Platform XULIANG HAN, Brewer Science, Inc., Michael J Weigand, Norman J Dobson, Matthew T Curry, Ryan E Giedd 8:50 (2250-2) Fabrication and Characterization of Gold Microelectrodes and Microelectrode Arrays Produced by Sequential Deposition in Capillaries DAVID J MONK, Tufts University, David R Walt 9:10 (2250-3) Carbohydrate-Based Sensor for Detection of Toxins and Pathogens MIRIAM M NGUNDI, Naval Research Laboratory, Chris R Taitt, Frances S Ligler 9:30 (2250-4) Versatile Applications of an Electronic Nose Microsystem JOACHIM GOSCHNICK, Forschungszentrum Karlsruhe GmbH, Christina Arnold, Daniel Hringer, Ilja Kiselev, Markus Frietsch, Carsten Natzeck 9:50 (2250-5) PCR/DNA Quartz Crystal Microbalance Biosensor for Detecting Bacteria in Environmental Water Samples Y.S. FUNG, Hong Kong University, W.C. Yam, Y.Y. Zhang, Hui Sun 10:10 Recess 10:25 (2250-6) Harnessing Acidithiobacillus Ferrooxidans in Microscale Transport and Biosensor Technology SAMIRA G MOORJANI, State University of New York at Binghamton 10:45 (2250-7) New Approach to Moisture Measurement with Al2O3 Sensors LAWRENCE TALARICO, COSA/Xentaur 11:05 (2250-8) An Ultrasensitive Electrochemical Enzyme Immunoassay for Proteins NATALIA C TANSIL, Institute of Bioengineering and Nanotechnology, Van Dong Le, Fang Xie, P Gopalakrishnakone, Zhiqiang Gao 11:25 (2250-9) Pin Printing Strategies for the Development of Ultra High Density Microarrays in Sensor Technology ELIZABETH C TEHAN, State University of New York at Buffalo, Frank V Bright 11:45 (2250-10) Optical Fiber Raman Sensor for Concentration Ratio Measurement of N2 and O2 in a High-Pressure Gas Mixture VIDHU S TIWARI, Mississippi State University, Sunil K Khijwania, Fang-Yu Yueh, Jagdish P Singh, Rajamohan R Kalluru

ORAL SESSION
Separation Science:Techniques and Applications
Friday Morning, Room S220E Chi-san Wu, International Specialty Products, Presiding

Session 2260

8:30 (2260-1) Cross-Flow Ion Mobility Analysis NOSA AGBONKONKON, Brigham Young University, Alan L Rockwood, James R Oliphant, H. Dennis Tolley, Edgar D Lee, Milton L Lee 8:50 (2260-2) Characterization of Flow and Voltage Profiles in Planar Electrochromatography PETER A TATE, Florida State University, John G Dorsey 9:10 (2260-3) Novel Methodology to Characterize Chiral Stationary Phases KIRAGU IRENE, Southern Illinois University, Montgomery Shavonne, Matthew E McCarroll 9:30 (2260-4) Carbon Nanoparticles and Monoliths for Selective Separations of Biomarkers and Environmental Pollutants SUSAN V OLESIK, Ohio State University, Justin Shearer, Luhan Ding, Christopher W Gribble 9:50 (2260-5) Protein Separations on Capillary-Channeled Polymer (C-CP) Fiber Stationary Phases: Column Loading Studies DWELLA M NELSON, Clemson University, R Kenneth Marcus

ORAL SESSION
Separation Science: Bioanalytical Applications
Friday Morning, Room S220D Michael Woodman, Agilent Technologies, Presiding

Session 1820

8:30 (1820-1) Preparation of Poly (Ethylene Glycol Methyl Ether Acrylate-co-Polyethylene Glycol Diacrylate) Monolith for Use in Electric Field Gradient Focusing BINGHE GU, Brigham Young University, Paul H Humble, Milton L Lee, Jenny M Armenta 8:50 (1820-2) Protein Separation Using Voltage-Controlled Electric Field Gradient Focusing with On-line UV Absorption Detection SHU-LING LIN, Brigham Young University, Jikun Liu, Milton L Lee, Paul H Humble 9:10 (1820-3) Withdrawn 9:30 (1820-4) Unique Electrokinetic Behaviors of Liposomes and Bioparticles MICHELE D PYSHER, Arizona State University, Mark A Hayes 9:50 (1820-5) Gel Protein Extraction Platform for Ultrasensitive Gel Protein Identification CHENG S LEE, University of Maryland at College Park, Jonathan W Cooper, Frederick Rosenberger 10:10 Recess

104

39

39