Group 3: Diem.Truong Hau.Bui Hieu.Le Linh.

Kien
August 20, 2012

Outline
Overview

Oxygen Scavenging Technologies

Oxygen Scavenging Sachets

Oxygen Scavenging Bottles Closure

Oxygen Scavenging Films

Conclusion
8/20/2012 Oxygen Scavenging Technologies 2

Overview

Development of Oxygen Scavenging Technologies

Oxygen Scavenging Sachets

Oxygen Scavenging Bottles Closure

Oxygen Scavenging Films

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Overview
Patent Mapping According To Technologies

34

Oxygen Scavenging Sachets 42

24

Oxygen Scavenging Bottles Closure

Oxygen Scavenging Films

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Oxygen Scavenging Technologies

Oxygen Scavenging Sachets

These materials, that absorb or have an oxygen affinity are blended and placed in gaspermeable sachets to be inserted into high gas barrier packages.
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Oxygen Scavenging Sachets

Patent mapping according to Year
4.0

3.0 2.0 1.0

0.0 1976

1980

1984

1988

1992 Years

1996

2000

2004

2008

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Oxygen Scavenging Technologies

Scavenging Sachets
Patent mapping according to Assignees
Sumitomo Chemical Company Partiv Corporation Ueno Seiyaky Co, Ltd

Multisorb Technologies, Inc.

Toppan Printing Co., Ltd.

bishi Gas Chemical Company, Inc. 0 2 4 6 Number of patents 8 10 12 14 16

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Oxygen Scavenging Technologies

Scavenging Sachets

Mapping of Absorbents in Sachets

16.0 14.0 12.0 10.0 8.0

15

6
6.0 4.0 2.0 0.0

Metallic Absorber

Organic Absorber

Type of Absorbents

Chemicals

Applications

Metallic

Iron based

Cakes, nuts, beef, Dry foods, medicine and drugs

Organic Compound Ascorbic acid, Ascorbate salts or Catechol, Fatty acid,

8/20/2012 Oxygen Scavenging Technologies

Scavenging Sachets Iron based

Chemicals Packet olefins (TYVEK), poly vinyl acetate, polyester Poly

Absorbent Additives

Iron powder Metal salts (NaCl, CaCl2, CuCl2,)

Activated carbon, silicagel, zeolite, hydrate crystalines

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Scavenging Sachets
Organic compound
Chemicals Poly olefins (TYVEK), poly vinyl acetate, polyester Packet

Absorbent Ascobic acid, salt of ascobic Catalyst Transition metals Alkaline salts (Na2CO3, K2CO3, CaCO3,) Additives Activated carbon, silicagel, zeolite, hydrate crystalines

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Scavenging Sachets
Development of Sachets Technology

Sachets

Firstly marketed with Ageless of MGC Inc, 1978

Problems: possible accidental ingestion

Sheet Multisorb Technology Inc market an or adhesive label : FreshMax, FreshPax labels
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Scavenging Sachets

abel: US 6821594

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venging Bottles Closure

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13

venging Bottles Closure

Patent mapping according to Year
3

2 1 0

Year
8/20/2012 Oxygen Scavenging Technologies 14

venging Bottles Closure

Patent Mapping According to Assignees
Ethyl Corporation Owens-Illimois Closure Inc. Amcor Limited Nippon Steel Corporation, Suntory Limited, Metal Box Limited American Air Liquide Mitsubishi Gas Chemical Company, Inc. Multiform Desiccants, Inc. Tri-Seal Holdings, Inc.

Tetra Laval Holdings & Finance, S. A. White Cap, Inc. Toyo Seikan Kaisha, Ltd.
Phoenix Closures, Inc. W. R. Grace & Co.Conn.

8
15

Number of patents
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venging Bottles Closure

Main component of Bottles closure

Polymer material

Oxygen Scavenger

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venging Bottles Closure

Polymer

Oxygen Scavenger

Forming techniques

PE US 5806681

Iron powder US 4849280

Inject mold US 7399425

PVC US 5492742

Iron complex of salicylic acid US 5492742

Laminated US 4740402

PTFE US 4849280

Sodium ascorbate US 5204389 Hydroxyethyl cellulose US 4740402

Extruded US 5381914

PE and PVA US 5381914

Coating US 5839593

PP US 7399425

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Scavenging Films

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18

Scavenging Films
Patent Mapping According To Year
4 3 2 1 0

Year

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19

Scavenging Films
Patent Mapping According To Assignees
Cryovac, Inc. Chevron Chemical Company W. R. Grace & Co.-Conn. M&G USA Corporation DSM IP Assets B. V.

Eastman Chemical Company Ciba Specialty Chemicals Corporation Multisorb Technologies, Inc. Mitsubishi Gas Chemical Company, Inc. 0 2 4 6 8 Number of patents 10 12 14 16

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Scavenging Films

The same of patented technologies

OSL

OBL

Other layers

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Scavenging Films
OSL

Oxidizable polymer
Polymers and copolymers of allylamine (US 5,942,297) EMTF (US 5,660,761) EMAC(US 6,057,013)

Iron based Iron powder US 6,369,148

Catalyst
Co (US 5,811,027)

Photoinitiator
4-alkoxybenzophenone (US 6,254,802) Benzoylated styrene oligomer (US 6,139,770) Benzoylated m-terphenyl (US 6,139,770) Benzophenone (US 5,811,027)
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Scavenging Films

Cryovac OS1000TM, OS2000 polymer based oxygen scavenging film

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gen Scavenger Systems

Manufacturer

Country
Japan USA

Trade name
Ageless FreshPax Fresh Pack FreshMax PureSeal OS2000 OS1000 Shelfplus O2

Scavenger mechanism
Iron based Iron based Iron based Iron based Ascorbate/ Metallic salts Cobalt catalysed Polymer oxidation PET copolyester

Packaging form
Sachets and labels Labels Labels Labels Bottle crowns Plastic films Plastic film

subishi Gas Chemical Co. Ltd

ltisorb Technologies, Inc.

W.R. Grace Co. Ltd

USA USA Switzerland

Cryovac Sealed Air Corporation Ciba Speciality Chemicals

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Conclusion

The most develop Overcome problems of sachets. Films Applied to the broadest range of food packaging applications.

Closure
The earliest Have a lot of patents. Applications in sliced cooked meats, Exist many disadvantages.

Sachets

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References
Brody, A. L.; Kline, L. R. and Strupinsky, E. R. Active packaging for food applications. Originally Published by Technomic Published [Online], 2001. Joshep, K. ; Paul, B. Smart Packaging Technologies for Fast Moving Consumer Goods. John Wiley & Sons, Ltd [Online], 2008, pp 4-7. Jung Han. Innovations in Food Packaging. Elsevier Science & Technology Books [Online], 2005, 123. http://www.packagingnetwork.com/doc.mvc/An-overview-of-oxygen-scavengingpackaging-an-0003 http://www.cryovac.com/na/en/food-packaging-products/oxygen-scavengingheadspace.aspx http://www.see-the-forest.com/G4/Main.act http://pminer.org/home.do?m=home http://www.freepatentsonline.com/
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